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Tytuł:
Hexammine Nickel Complex: Cooperative Rotation of Six NH$\text{}_{3}$ Groups
Autorzy:
Sczaniecki, P. B.
Powiązania:
https://bibliotekanauki.pl/articles/1931836.pdf
Data publikacji:
1994-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
Opis:
Electrostatic interactions between NH3 groups undergoing a correlated rotation are calculated with reference to the nickel hexammine complexes [Ni(NH$\text{}_{3}$)$\text{}_{6}$]$\text{}^{2+}$ The results demonstrate the angular dependence of the cis and trans arrangements of the model ammonia triangles. The previously defined four maxima and four minima are identified.
Źródło:
Acta Physica Polonica A; 1994, 86, 6; 1021-1026
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Angular Dependences of ESR Parameters in Antiferroquadrupolar Phase of CeB₆
Autorzy:
Semeno, A.
Gilmanov, M.
Sluchanko, N.
Krasnorussky, V.
Shitsevalova, N.
Filipov, V.
Flachbart, K.
Demishev, S.
Powiązania:
https://bibliotekanauki.pl/articles/1032654.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
76.30.Kg
Opis:
Angular dependences of ESR line parameters (g-factor and linewidth Δ H) were experimentally explored in the antiferroquadrupolar phase of heavy fermion system CeB₆ at T=1.8 K. The data were obtained in two experimental geometries with different mutual directions of the wavevector k and the external magnetic field H at frequency of f=60 GHz. A g-factor anisotropy was found: while g-factors for [110] and [111] directions are close to each other (g ≈1.6), it is considerably higher (g ≈1.75) for [100]. The obtained angular dependence g(Θ) was compared with the theoretically predicted g-factor behavior for the Γp₈ state of Ce³⁺ ion in antiferroquadrupolar phase of CeB₆. It turns out that the experimental g-factor is considerably smaller at all angles than the theoretically calculated limits (2
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 1060-1062
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zero-Field Splitting Parameters of $Cr^{3+}$ in Lithium Potassium Sulphate at Orthorhombic Symmetry Site
Autorzy:
Pandey, S.
Kripal, R.
Powiązania:
https://bibliotekanauki.pl/articles/1400393.pdf
Data publikacji:
2013-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
76.30.Fc
Opis:
The superposition model is used to investigate the crystal field parameters, $B_{kq}$ of $Cr^{3+}$ in lithium potassium sulphate. The zero field splitting parameters D and E are then determined using microscopic spin Hamiltonian theory and compared with the experimental values obtained by electron paramagnetic resonance. Both zero field splitting parameters D and E evaluated theoretically are in good agreement with the experimental values. The results suggest that the $Cr^{3+}$ ion occupies substitutional K^{+} site in lithium potassium sulphate.
Źródło:
Acta Physica Polonica A; 2013, 123, 1; 101-105
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Paramagnetic Resonance Study of Organic Radicals in Some Herbal Plants
Autorzy:
Krupska, A.
Wojtowicz, E.
Augustyniak-Jabłokow, M.
Powiązania:
https://bibliotekanauki.pl/articles/1398973.pdf
Data publikacji:
2016-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
76.30.Rn
Opis:
In this work we show the impact of the roasting process on the properties of organic radicals in some herbal products added to cereal coffee. The EPR study shows the presence of radicals in dried herbal products, both natural and roasted. Changes in the relative intensity of the EPR signal and in the g-factor for unroasted and roasted plant material can be observed. This indicates to the recombination processes of radicals. Roasting process increases the number of radicals. The analysis of EPR spectra show that they consist of two Gaussian lines which indicate that there are at least two different kinds of radicals. The values of g-factor about 2 may be derived from a number of very different radicals. For this reason the identification of such radicals is not strictly possible.
Źródło:
Acta Physica Polonica A; 2016, 129, 6; 1201-1204
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanisms of Nonuniform Line Broadening
Autorzy:
Wilamowski, Ż.
Przybylińska, H.
Jantsch, W.
Powiązania:
https://bibliotekanauki.pl/articles/1931943.pdf
Data publikacji:
1995-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.20.+q
76.30.-v
Opis:
When the spin relaxation time of paramagnetic impurities at different magnetic sites differs by orders of magnitude then instead of resonance line broadening, rather a decay of the line amplitude is expected. In particular, the sp-d coupling of magnetic impurities to shallow impurities leads to a nonuniform distribution of the longitudinal relaxation rates of local spins.
Źródło:
Acta Physica Polonica A; 1995, 87, 1; 181-184
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pretransition Phenomena in Fast-Proton Conductors
Autorzy:
Waplak, S.
Bednarski, W.
Ostrowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2043554.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
66.30.-h
Opis:
In this paper we present recent experimental results related to nonlinear crystal field fluctuations and current flow in K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ fast-proton conductor far below the transition temperature T$\text{}_{g}$. The results for crystalline and powdered samples are quantitatively explained in the framework of soliton model of charge transport.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 261-270
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Binding of the Trace Elements: Cu(II) and Fe(III) to the Native and Modified Nutritive Potato Starches Studied by EPR
Autorzy:
Śmigielska, H.
Lewandowicz, G.
Goslar, J.
Hoffmann, S. K.
Powiązania:
https://bibliotekanauki.pl/articles/2043599.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
87.15.-v
Opis:
The Cu(II) and Fe(III) ions have been adsorbed by four potato starches of different degrees of oxidation (different numbers of COOH groups replacing host CH$\text{}_{2}$OH groups): native (no oxidized), white (pudding) with oxidation degree of 0.04%, gelating (0.1%), and LUBOX starch (0.5%). Concentration of the ions in starches was determined from atomic absorption and EPR spectrum intensity. For small concentration of the adsorbed ions (below 4 mg/g) nearly all ions are adsorbed from the solution. EPR shows that adsorbed copper(II) ions are chemically bonded to the starch molecules (preferably) at COOH sites and uniformly dispersed in the starch structure. The complexes are typical of octahedral or square-quadratic coordination with spin-Hamiltonian parameters g$\text{}_{ǁ}$=2.373, g$\text{}_{⊥}$= 2.080, A$\text{}_{ǁ}$=12.1 mT, A$\text{}_{⊥}$=1.0 mT. For higher concentrations the Cu(II) displays a tendency to clustering. Iron(III) ions are introduced into starch in a form of clusters mainly, even for the smallest concentration. The highest concentrations of both Cu(II) and Fe(III) were observed in LUBOX starch having the highest degree of oxidation.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 303-310
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optical Detection of Paramagnetic Centres in Activated Oxyfluoride Glass-Ceramics
Autorzy:
Rogulis, U.
Fedotovs, A.
Antuzevics, A.
Berzins, Dz.
Zhydachevskyy, Ya.
Sugak, D.
Powiązania:
https://bibliotekanauki.pl/articles/1029682.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.70.Hb
76.30.-v
Opis:
Electron paramagnetic resonance (EPR), magnetic circular dichroism (MCD) and EPR detected via MCD (MCD-EPR) investigations have been performed on rare-earth activated oxyfluoride glasses and glass-ceramics. Er³⁺, Gd³⁺, and Mn²⁺ activators in oxyfluoride glass-ceramics show paramagnetic MCD behaviour and the MCD-EPR has been detected. The results of the MCD-EPR measurements for the Er-doped oxyfluoride glass-ceramics showed that Er³⁺ ions in the CaF₂ crystallites in these ceramics embed only in the cubic symmetry environment, similarly to the previous observations of cubic Gd³⁺ centres in the glass-ceramics containing CaF₂. Finally, the correlation of optics and paramagnetic centres is discussed for Mn-doped YAlO₃ ceramics.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 785-788
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
$\text{}^{13}$C High Resolution NMR Study of Methyl-Diethyl Sulfonium TCNQ 1:2 Complex
Autorzy:
Firlej, L.
Pęcherz, J.
Bernier, P.
Powiązania:
https://bibliotekanauki.pl/articles/1933380.pdf
Data publikacji:
1995-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
76.30.-v
Opis:
Solid state high resolution $\text{}^{13}$C NMR studies of a 1 : 2 charge transfer complex of TCNQ with diethyl-methyl sulfonium S + Et$\text{}_{2}$Me(TCNQ)$\text{}_{2}$ are presented. The metallic shifts of TCNQ resonances are interpreted as due to the Pauli paramagnetism of conducting electrons and quantitatively connected with inhomogeneous spin density distribution over (TCNQ2)¯ dimer. A singularity of NMR parameters at T = 330 K is observed and described as a structural phase transition occurring in the S + Et$\text{}_{2}$Me cation sublattice.
Źródło:
Acta Physica Polonica A; 1995, 87, 4-5; 829-834
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigations of Phase Transitions in (NH$\text{}_{4}$)$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ Crystal by Means of Mn$\text{}^{2+}$ EPR Spectra
Autorzy:
Bednarski, W.
Waplak, S.
Powiązania:
https://bibliotekanauki.pl/articles/1952756.pdf
Data publikacji:
1996-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.50.-f
76.30.-v
Opis:
EPR of Mn$\text{}^{2+}$ impurity ion in the (NH$\text{}_{4}$)$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ crystal is studied in the temperature range 80-420 K. It is shown that Mn$\text{}^{2+}$ substitutes NH$\text{}_{4}^{+}$(I) ion and is coordinated in deformed oxygen octahedron in which takes two "off-center" positions. Its spin-Hamiltonian parameters and direction cosines of crystal field are determined. The successive EPR line splitting for three phase transitions is discussed.
Źródło:
Acta Physica Polonica A; 1996, 90, 6; 1185-1192
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR and MMMA Study of C$\text{}_{60}$ upon K-Doping
Autorzy:
Kempiński, W.
Stankowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/1933662.pdf
Data publikacji:
1995-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.70.Wz
76.30.-v
Opis:
EPR and ΜΜMΑ studies of C$\text{}_{60}$ upon K-doping have been performed. Two different and well separated EPR narrow lines were detected for C$\text{}_{60}^{1-}$ and C at temperatures below 100 K. Time dependent changes in the intensities of both and C$\text{}_{60}^{3-}$ lines were observed when the system undergoes an eutectoid transformation. The evolution of superconductivity with two T$\text{}_{c}$ related to different valences (v) of C$\text{}_{60}^{v}$ ion radicals have been found.
Źródło:
Acta Physica Polonica A; 1995, 88, 3; 549-552
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Vibronic Effects in EPR Spectra of (NH$\text{}_{4}$)$\text{}_{2}$Cu(BeF$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$0 Single Crystal
Autorzy:
Hoffmann, S.
Gomółka-Marciniak, M.
Powiązania:
https://bibliotekanauki.pl/articles/1929355.pdf
Data publikacji:
1993-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
71.70.Ej
Opis:
Angular variations of the g-factors and linewidth value were recorded at X-band, at room temperature, and at 77 K. The temperature dependence of the g-factors was measured along the principal g-tensor axes in the temperature range from 4.2 K to 300 K. The rigid lattice g-factors at 4.2 K are: g$\text{}_{z}$ = 2.428, g$\text{}_{y}$ = 2.138, and g$\text{}_{x}$ = 2.058. The g$\text{}_{x}$ value very slowly increases linearly on heating, whereas g$\text{}_{z}$ and g$\text{}_{y}$ nonlinearly tend towards their average value. This is a typical behaviour of Cu(II) EPR in Tutton salt crystals, however the g(T) dependence is much less pronounced in (NH$\text{}_{4}$)$\text{}_{2}$Cu(BeF$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$0 as compared to the Cu(II) doped salts. The results are described in terms of the two vibronic coupling models of the strong Jahn-Teller effect. It is shown that the models are not adequate to describe the vibronic g-factor behaviour in paramagnetic Cu(II) crystals which is attributed to the cooperative Jahn-Teller effect existing in these crystals.
Źródło:
Acta Physica Polonica A; 1993, 83, 6; 817-830
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electronic Properties of High-Temperature Superconductor DyBa$\text{}_{2}$Cu$\text{}_{3}$O$\text{}_{7}$ from Critical Fields and Specific Heat Studies
Autorzy:
Kołodziejczyk, A.
Kozłowski, A.
Chmist, J.
Zalecki, R.
Ściężor, T.
Tarnawski, Z.
Woch, W. M.
Powiązania:
https://bibliotekanauki.pl/articles/1929388.pdf
Data publikacji:
1993-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.70.-b
76.30.-v
Opis:
The lower and upper critical fields, as well as the specific heat were measured as a function of temperature for good quality DyBa$\text{}_{2}$Cu$\text{}_{3}$O$\text{}_{7}$ high-temperature superconductor in the vicinity of superconducting transition temperature T$\text{}_{c}$ = 91.2 K. The number of superconducting and normal state electronic quantities were determined basing on the Ginzburg-Landau-Abrikosov-Gorkov theory. It is argued that on the basis of this BCS-like theory one can describe the superconducting properties and, in combination with some information on the electronic structure, also the magnetic properties of high-temperature superconductors.
Źródło:
Acta Physica Polonica A; 1993, 84, 1; 127-138
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Application in the Study of K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ Proton Conductor Doped with Mn$\text{}^{2+}$ or VO$\text{}^{2+}$ Ions
Autorzy:
Waplak, S.
Powiązania:
https://bibliotekanauki.pl/articles/1931810.pdf
Data publikacji:
1994-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.50.-f
76.30.-v
Opis:
The EPR of Mn$\text{}^{2+}$- or VO$\text{}^{2+}$-doped superprotonic conductor K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ is studied in the 80-471 K temperature range. VO$\text{}^{2+}$ EPR spectrum reveals diffusion induced merging of proton transferred superhyperfine structure above 380 K. Line width anomaly is observed in Mn$\text{}^{2+}$ EPR spectrum which is attributed to the intrabond and interbond proton motions, these lead to high protonic conductivity. It is shown that paramagnetic centers namely of electronic spin greater than 1, with excess charge compensated by the protonic vacancy, are good probes to monitor the protonic conductivity on molecular level.
Źródło:
Acta Physica Polonica A; 1994, 86, 6; 939-945
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Study of Cu$\text{}^{2+}$ Doped Fast-Proton Conductor K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ in the Temperature Range 100-450 K
Autorzy:
Ostrowski, A.
Bednarski, W.
Waplak, S.
Powiązania:
https://bibliotekanauki.pl/articles/2037037.pdf
Data publikacji:
2003-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.50.-f
76.30.-v
Opis:
The K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ doped with Cu$\text{}^{2+}$ ion was studied in detail by X-band CW EPR. Two kinds of Cu$\text{}^{2+}$ complexes (magnetically and structurally nonequivalent) denoted as Cu$\text{}^{2+}$(I) and Cu$\text{}^{2+}$(II) were found. Spin-Hamiltonian parameters, direction cosines, and coordination of Cu$\text{}^{2+}$ ion were determined at room temperature. The superhyperfine structure was observed below 250 K as a result of interacting of Cu$\text{}^{2+}$ ion with four equivalent protons (I=1/2). Temperature studies of K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ crystal show that interbond motion as a precursor of superprotonic phase transition occurs at above≈250 K.
Źródło:
Acta Physica Polonica A; 2003, 104, 6; 549-558
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Paramagnetic Resonance Study of the [(CH$\text{}_{3}$)$\text{}_{2}$NH$\text{}_{2}$]$\text{}_{5}$Cd$\text{}_{3}$Cl$\text{}_{11}$ Monocrystal Doped with Cu$\text{}^{2+}$ ion
Autorzy:
Ostrowski, A.
Bednarski, W.
Waplak, S.
Czapla, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2030763.pdf
Data publikacji:
2002-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
05.70.Fh
Opis:
The paper reports the electron paramagnetic resonance investigation of Cu$\text{}^{2+}$ doped [(CH$\text{}_{3}$)$\text{}_{2}$NH$\text{}_{2}$]$\text{}_{5}$Cd$\text{}_{3}$Cl$\text{}_{11}$ (DMACC) monocrystal. DMACC:Cu$\text{}^{2+}$ was studied in the temperature range (6÷293) K. We did not observe any anomalies of spin-Hamiltonian parameters of Cu$\text{}^{2+}$ ion corresponding to the temperature anomalies observed in dielectric studies. The electron paramagnetic resonance anomaly recorded at about 40 K results from the subtle changes in bonds angles and Cu-Cl distances and suggests the smooth second order transition.
Źródło:
Acta Physica Polonica A; 2002, 101, 6; 893-899
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Effect in Magnetic Dependent Dissipation in High Temperature Superconductors
Autorzy:
Stankowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/2043552.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.72.-h
76.30.-v
Opis:
Electron paramagnetic resonance in ac dissipation was observed due to the Cooper pairs breaking up to their quasiparticle state. This phenomenon is the result of a flux motion on a pinning centers in high temperature superconducting materials. The detection of ac dissipation was performed in a low ac field (15 and 22 MHz) as well as in microwave range. Vortex motion hysteresis loop with magnetic field modulation of 15 Hz was recorded. Besides V-shaped dependence of ac power dissipation P(B), a direct electron paramagnetic resonance signal related to Cooper pairs → quasiparticle fluctuation was observed.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 243-246
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Dating of Hydroxyapatite from Fossil Bones. Transient Effects after γ and UV Irradiation
Autorzy:
Wencka, M.
Hoffmann, S. K.
Hercman, H.
Powiązania:
https://bibliotekanauki.pl/articles/2043612.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
65.90.+i
Opis:
ESR measurements at room temperature have been performed on fossil bones of cave bear (from Magurska Cave of the Tatra Mountains) and mammoth (from Dniestr River). Various paramagnetic centres related to defects in hydroxyapatite were identified. The ESR spectrum is dominated by Mn$\text{}^{2+}$ lines and free radical centres CO$\text{}_{2}^{-}$ and CO$\text{}_{3}^{-}$. Suitability of various EPR lines for the dating was evaluated. The spectra are affected by γ-ray and UV irradiation which produce new relatively unstable (transient) radical centres. From their decay curves we determined the delay period (waiting time) between irradiation and ESR dating measurements. For γ-rays the period is about 15 days and depends on the chosen ESR line. UV generates mainly surface O$\text{}^{-}$ centres which decay practically after a few days. The ESR dating of the bear bones using an additive dose method given the age t = 21.7 kiloyears (ky), whereas from radionuclide Th/U method t= 34 ky and from radiocarbon $\text{}^{14}$C method t > 33.1 ky.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 331-337
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Temperature Effects in ESR Spectra of Radical Centres in Dripstone Calcite Samples Used for ESR Dating
Autorzy:
Wencka, M.
Hoffmann, S. K.
Krzyminiewski, R.
Mielcarek, S.
Powiązania:
https://bibliotekanauki.pl/articles/2043694.pdf
Data publikacji:
2005-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
65.90.+i
Opis:
Natural calcite samples were collected from the dripstone layers of the Black Cave of the Tatra Mountains. ESR spectra, thermal analysis, and thermoluminescence data were analysed to obtain a consistent picture of the calcite properties. The ESR spectra were analysed using computer enhanced resolution spectra and an influence of the thermal annealing on intensity of individual ESR lines was measured. These results together with the effects of γ-irradiation in ESR spectra allowed one to discriminate between ESR lines from various paramagnetic centres. A general conclusion of the paper is that in the ESR dating the outer ESR lines of CO$\text{}_{3}^{-}$ (g=2.0125) and CO$\text{}_{2}^{-}$ (g=1.9980) radicals should be used instead of the commonly used multicomponent central line.
Źródło:
Acta Physica Polonica A; 2005, 108, 3; 491-503
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Vibronic Dynamics of Cu(H$\text{}_{2}$O)$\text{}_{6}$ Complexes and Electron Spin Relaxation in Temperature Dependence of EPR Linewidth in Diamagnetic Tutton Salt Single Crystals
Autorzy:
Hoffmann, S. K.
Goslar, J.
Powiązania:
https://bibliotekanauki.pl/articles/2047171.pdf
Data publikacji:
2006-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.90.+t
76.30.-v
Opis:
EPR linewidth of Cu$\text{}^{2+}$ in the Tutton salt crystals weakly depends on temperature at low temperatures and then it rapidly grows above 60 K. We present detailed results of measurements and analysis for $\text{}^{63}$Cu$\text{}^{2+}$ in K$\text{}_{2}$Zn(SO$\text{}_{4}$)$\text{}_{2}$·6 H$\text{}_{2}$O, K$\text{}_{2}$ Zn(SO$\text{}_{4}$)$\text{}_{2}$·6D$\text{}_{2}$O, (NH$\text{}_{4}$)$\text{}_{2}$Mg(SO$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$O and Cs$\text{}_{2}$Zn (SO$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$O in a temperature range of 4.2-300 K and compare them with already published electron spin-lattice relaxation data. The relaxation contributes weakly to the linewidth which is dominated by molecular dynamics and grows exponentially with temperature. To describe this we are discussing the influence of jumps between two sites of Cu$\text{}^{2+}$ complexes in a slow motion region where the sites are differently thermally populated. This case has not been considered so far. We have derived appropriate expressions describing the contribution of jumps to the linewidth which allows the determination of the jump rate and energy difference δ$\text{}_{A,B}$ between the two sites being two Jahn-Teller distorted configurations of the vibronic Cu(H$\text{}_{2}$O)$\text{}_{6}$ complexes. The jump rate 1/τ strongly depends on temperature and reaches 10$\text{}^{9}$ s$\text{}^{-1}$ at room temperature, whereas theδ$\text{}_{A,B}$ varies from 117 cm$\text{}^{-1}$ for K$\text{}_{2}$Zn(SO$\text{}_{4}$)$\text{}_{2}$·6D$\text{}_{2}$O to 422 cm$\text{}^{-1}$ for Cs$\text{}_{2}$Zn(SO$\text{}_{4}$)$\text{}_{2}$·6 H$\text{}_{2}$O. The comparison with vibronic level splitting, which varies in the range of 67-102 cm$\text{}^{-1}$, indicates that the reorientation mechanism involves phonon induced tunnelling via excited vibronic levels. These reorientations do not contribute, however, to the spin-lattice relaxation which is governed by ordinary two-phonon relaxation processes in the whole temperature range. Thus, the reorientations and spin relaxation are two independent phenomena contributing to the total linewidth.
Źródło:
Acta Physica Polonica A; 2006, 110, 6; 807-816
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of the Magnetic Field Distribution in the Bi2212 superconducting Single Crystal by the Scanning EPR-Probe
Autorzy:
Drulis, H.
Folcik, L.
Drulis, M.
Zaleski, A.
Suleimanov, N. M.
Powiązania:
https://bibliotekanauki.pl/articles/1968771.pdf
Data publikacji:
1998-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.72.-h
76.30.-v
Opis:
The profile of the magnetic field distribution over the surface of superconducting sample is studied by the scanning an electron paramagnetic resonance microprobe. The magnetic field distribution is mapped from the measurements of the spin probe EPR-signal shift.
Źródło:
Acta Physica Polonica A; 1998, 93, 2; 403-407
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Spin Resonance Spectra of Fe$\text{}^{3+}$ Ions in SrLaAlO$\text{}_{4}$ and SrLaGaO$\text{}_{4}$ High-T$\text{}_{c}$ Substrates
Autorzy:
Jabłoński, R.
Pajączkowska, A.
Powiązania:
https://bibliotekanauki.pl/articles/1964358.pdf
Data publikacji:
1997-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
61.72.Hh
Opis:
New results concerning paramagnetic defects in SrLaAlO$\text{}_{4}$ and SrLaGaO$\text{}_{4}$ high-T$\text{}_{c}$ substrates connected with unavoidable impurity Fe$\text{}^{3+}$ are reported. The identification was checked by measuring the spectra in SrLaAlO$\text{}_{4}$ crystals intentionally doped with 0.5 at.% Fe. Angular dependences of three lines were distinguished at X-band frequency in the temperature range from 4 K to 300 K. We attribute these lines to the transitions inside the doublets ±1/2, and "forbidden" doublets ±3/2, ±5/2, respectively. By diagonalization of spin-Hamiltonian, parameters |D| > 1.2 cm$\text{}^{-1}$, |E| ≈ 0.1 cm$\text{}^{-1}$ and g$\text{}_{x}$=g$\text{}_{y}$=g$\text{}_{z}$= 1.987(13) for SrLaAlO$\text{}_{4}$ and SrLaGaO$\text{}_{4}$ were calculated and within the margin of error they were of the same value.
Źródło:
Acta Physica Polonica A; 1997, 92, 1; 173-176
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Spectra of the Genuine-Organic and Metal-Organic TCNQ-Based Anion Radical Salts
Autorzy:
Botko, M.
Čižmár, E.
Kajňaková, M.
Feher, A.
Powiązania:
https://bibliotekanauki.pl/articles/1368637.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Xx
76.30.-v
Opis:
We have measured the electron paramagnetic resonance spectra of genuine-organic anion-radical salts $[Me-2,6-di-Me-Py](TCNQ)_{2}$, $[Me-3,5-di-Me-Py](TCNQ)_{2}$, $[N-Me-OH-Me-Py](TCNQ)_{2}$, $[N-Et-OH-Me-Py](TCNQ)_{2}$, and metal-organic anion-radical salt $[Mn-phen_{3}](TCNQ)_{2}$·$H_{2}O$ in the temperature range from 2 K to 300 K in the X-band frequency range. A comparison study of the shape of spectra, g-factors and linewidths with respect to the composition and crystal structure of studied compounds is presented. While the genuine-organic anion-radical salts display a typical EPR response originating from TCNQ pairs, the spectra of metal-organic anion-radical salt are dominated by the contribution of transition metal.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 252-253
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of DI-Hydrogen-Monovacancy Defect in Silicon
Autorzy:
Stallinga, P.
Nielsen, B. B.
Powiązania:
https://bibliotekanauki.pl/articles/1968423.pdf
Data publikacji:
1997-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.Lh
76.70.Hb
76.30.-v
Opis:
A careful analysis of the alleged electron paramagnetic resonance spectrum of VH$\text{}_{2}$ in silicon is made. The parameters of this spectrum coincide with those of the well-known excited state (S=1) spectrum of the oxygen vacancy defect. The conclusion is reached that they are one and the same.
Źródło:
Acta Physica Polonica A; 1997, 92, 5; 989-992
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR and Impedance Measurements of Graphene Oxide and Reduced Graphene Oxide
Autorzy:
Kempiński, M.
Łoś, S.
Florczak, P.
Kempiński, W.
Jurga, S.
Powiązania:
https://bibliotekanauki.pl/articles/1033701.pdf
Data publikacji:
2017-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
72.80.Vp
76.30.-v
Opis:
We report the observations of electron paramagnetic resonance and impedance measurements of graphene oxide and reduced graphene oxide performed in the wide temperature range in order to get insight into the electronic properties of graphene-based materials and the role of oxygen functionalities in the charge carrier transport phenomena. In such systems the strong spin localization, hopping charge carrier transport as well as the formation of adsorption layers are observed, all the phenomena changing significantly after the heavily oxidized graphene is reduced.
Źródło:
Acta Physica Polonica A; 2017, 132, 1; 81-85
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
XANES Experiments for High-Temperature Superconductors
Autorzy:
Kołodziejczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/1920888.pdf
Data publikacji:
1992-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.70.-b
76.30.-v
Opis:
The paper presents the results of XANES (X-ray Absorption Near Edge Structure) experiments, of the high-temperature superconductors of Y-Ba-Cu-O-type carried out at the Cu L$\text{}_{II,III}$- and O K$\text{}_{I}$-edges using synchrotron radiation and the KMC double monochromator and SX-700 grading monochromator beamlines of BESSY/Berlin synchrotron storage ring. The aim of the paper is to show that the XANES studies are well suited for characterization of the local electronic structure of the high-temperature superconductors.
Źródło:
Acta Physica Polonica A; 1992, 82, 2; 273-281
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Study of Monoclinic RbD$\text{}_{2}$PO$\text{}_{4}$ Monocrystal Doped with Cr$\text{}^{5+}$ Ion
Autorzy:
Waplak, S.
Shuvalov, L. A.
Powiązania:
https://bibliotekanauki.pl/articles/1932129.pdf
Data publikacji:
1995-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
64.60.-i
Opis:
Deuterated monoclinic RbD$\text{}_{2}$PO$\text{}_{4}$ (DRDP) doped with chromium Cr$\text{}^{5+}$ is studied by EPR in 90 K to 400 K temperature range. EPR reveals two types of paramagnetic centers: single Cr$\text{}^{5+}$ (S = 1/2) complex and Cr$\text{}^{5+}$-Cr$\text{}^{5+}$ coupled pairs with effective spin S = 1. The EPR line splitting of single Cr$\text{}^{5+}$ complex in DRDP versus temperature agrees with the unit cell multiplication. The splitting of EPR line of pair spectrum appears at T* = 160 K, far below the phase transition temperatures and is due to the anisotropy of the exchange interaction. The clustering effect in the low-dimensional DRDP is suggested.
Źródło:
Acta Physica Polonica A; 1995, 87, 3; 643-648
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Restricted Validity of the Two-State Model Describing a Vibronic EPR g-Factors Averaging in Cs$\text{}_{2}$Zn(SO$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$O Tutton Salt Crystals Doped with Cu$\text{}^{2+}$ Ions
Autorzy:
Hoffmann, S. K.
Kaszyński, R.
Augustyniak, M. A.
Hilczer, W.
Powiązania:
https://bibliotekanauki.pl/articles/2011161.pdf
Data publikacji:
1999-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.90.+t
76.30.-v
Opis:
Single crystals and powder EPR spectra of Cu$\text{}^{2+}$ ions in Cs$\text{}_{2}$Zn(SO$\text{}_{4}$)$\text{}_{6}$·6H$\text{}_{2}$O were recorded in the temperature range of 4.2-300 K and the g-factor temperature variations were determined. The g$\text{}_{z}$ and g$\text{}_{y}$ have the values of 2.443 and 2.134, respectively, at the rigid lattice limit below 20 K, and then continuously tend to an average value on heating. This vibronic averaging produced by reorientations of Cu(H$\text{}_{2}$O)$\text{}_{6}$-complexes between Jahn-Teller distorted octahedral configurations is described in terms of a two-state Silver-Getz model which is known as a good model for diamagnetic non-ammonium Tutton salts. We found, however, that this model is only a crude approximation in Cs$\text{}_{2}$Zn(SO$\text{}_{4}$)$\text{}_{6}$·6H$\text{}_{2}$O below 150 K. Above this temperature the model works better and describes the vibronic dynamics between the two lowest energy potential wells in the adiabatic potential surface differing in the energy of δ$\text{}_{12}$=318(9) cm$\text{}^{-1}$=3.7 kJ/mol.
Źródło:
Acta Physica Polonica A; 1999, 96, 6; 733-740
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Low-Temperature Structural Phase Transition in Monoclinic RbDy(WO$\text{}_{4}$)$\text{}_{2}$ Crystal
Autorzy:
Borowiec, M. T.
Dyakonov, V.
Kamenev, V.
Nabiałek, A.
Prokhorov, A.
Szymczak, H.
Załęski, M.
Powiązania:
https://bibliotekanauki.pl/articles/1968975.pdf
Data publikacji:
1998-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
75.20.-g
Opis:
The ESR spectrum of Dy$\text{}^{3+}$ ion in the low-symmetry RbDy(WO$\text{}_{4}$)$\text{}_{2}$ crystal has been studied in the temperature region of T=4.2 ÷ 30K. The ESR linewidth was found to increase from 130 mT up to the maximum value of 190 mT at T=9K and then to decrease down to 150 mT at 4.2K. The components of the g-tensor change considerably without change of their spatial orientation in the temperature range from 12K to 7 K: g$\text{}_{z}$=2.5, g$\text{}_{x}$≈0, g$\text{}_{y}$=1.41 at T>12 K; g$\text{}_{z}$=1.53, g$\text{}_{x}$≈0, g$\text{}_{y}$=1.2 at T<7K. The observed λ-shaped behaviour of absorption linewidth and the decrease in the g-factor are assumed to be due to the low-temperature structural phase transition (T$\text{}_{SPT}$≈9 K). The width of the transition area is of about 5K. It is suggested that the symmetry of high- and low-temperature phases is identical.
Źródło:
Acta Physica Polonica A; 1998, 94, 1; 71-77
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photo-EPR Investigations of Thermal Donors in Silicon
Autorzy:
Bagraev, N. T.
Bekman, Η.H.Ρ.Τh.
Gregorkiewicz, T.
Ammerlaan, C. A. J.
Powiązania:
https://bibliotekanauki.pl/articles/1887165.pdf
Data publikacji:
1991-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
72.20.Jv
Opis:
Two thermal donor related EPR centers Si-NL8 and Si-NL10 were studied by the photo-EPR technique. The spectral dependence of the intensity of the EPR signals was determined for the region from 0.6 to 1.4 eV in several samples with different Fermi level position. The quenching of the Si-NL8 signal with the coinciding enhancement of the Si-NL10 signal has been observed with possible indication of some metastable behavior of the NL8 center. For the heavily aluminum doped material strong generation of photocurrent upon band gap illumination has been observed. The results of the study provide further evidence for mutal correlation of both thermal donor related EPR centers since the observed spectral dependences could be understood by relating both NL8 and NL10 spectra to different paramagnetic states of basically the same center.
Źródło:
Acta Physica Polonica A; 1991, 79, 2-3; 397-400
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Superconductivity of Carbon Materials - Unstable Phases
Autorzy:
Kempiński, W.
Powiązania:
https://bibliotekanauki.pl/articles/2038391.pdf
Data publikacji:
2004-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
74.70.Wz
Opis:
Different intercalated carbon systems: K$\text{}_{x}$C$\text{}_{60}$, Rb$\text{}_{x}$C$\text{}_{60}$ as well as highly oriented pyrolytic graphite + potassium with unstable structural and superconducting behavior were investigated with the EPR and magnetically modulated microwave absorption techniques. Three characteristic, well-separated EPR signals were observed for A$\text{}_{x}$C$\text{}_{60}$ (A = K or Rb) systems at the early stages of doping process. We ascribed these signals to C$\text{}_{60}^{+}$, C$\text{}_{60}^{1-}$, and C$\text{}_{60}^{3-}$ radicals. Evolution of the EPR spectrum characterizes different phases of K$\text{}_{x}$C$\text{}_{60}$ system including superconducting one. Two superconducting phases with T$\text{}_{c}^{(1)}$=(21±0.5) K (unstable) and T$\text{}_{c}^{(2)}$=(18.5±0.5) K (final, stable) were distinctly separated for K$\text{}_{x}$C$\text{}_{60}$ system. For C$\text{}_{60}$ intercalated by rubidium a similar evolution of EPR spectrum is observed. Prior to well-defined superconducting Rb$\text{}_{3}$C$\text{}_{60}$ phase was created, strong instabilities of the magnetically modulated microwave absorption signal were observed at the narrow part of the doping process. For potassium intercalated highly oriented pyrolytic graphite, EPR oscillations below 100 K were observed as well as Josephson hysteresis loops were registered at 5 K.
Źródło:
Acta Physica Polonica A; 2004, 106, 5; 627-636
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Applications of the Transport Integrals in Solid-State Physics and in Electron Spin Relaxation
Autorzy:
Radczyk, T.
Hoffmann, S. K.
Goslar, J.
Powiązania:
https://bibliotekanauki.pl/articles/2036991.pdf
Data publikacji:
2003-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.90.+t
76.30.-v
Opis:
Transport integrals I$\text{}_{n}$(Θ$\text{}_{D}$/T) are reviewed with their applications in solid-state physics, molecular dynamics, and electron spin-lattice relaxation. Analytical approximations of I$\text{}_{n}$ for n=2-8 are proposed as applicable for computer fitting procedures in the range of the variable x=Θ$\text{}_{D}$/T from 0.1 to 40. The results are applied for description of the spin-lattice relaxation data collected for Cu$\text{}^{2+}$ ions in triglycine sulphate and are compared with relaxation data for Cu$\text{}^{2+}$ and Mn$\text{}^{2+}$ in (NH$\text{}_{4}$)$\text{}_{2}$Mg(SO$\text{}_{4}$)$\text{}_{2}$·6H$\text{}_{2}$O.
Źródło:
Acta Physica Polonica A; 2003, 104, 5; 469-477
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Role of Ferric(III) Oxide in Poly-(1,4-Phenylene Sulphide) Curing. EPR and X-ray Studies
Autorzy:
Wejchan-Judek, M.
Hoffmann, S. K.
Goslar, J.
Garbarczyk, J.
Powiązania:
https://bibliotekanauki.pl/articles/2043404.pdf
Data publikacji:
2005-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
61.41.+e
Opis:
Commercially available poly-(1,4-phenylene sulfide) = PPS with trade names TEDUR and RYTON contain a great amount of Fe(III) (order of 10$\text{}^{20}$ Fe/gram) as shown by electron spin resonance spectra. The curing of the pure and Fe-doped (0.2% Fe$\text{}_{2}$O$\text{}_{3}$) PPS polymers proves that Fe(III) can be used for improvement of the PPS strength by increasing the polymer cross-linking and a decrease in the polymer crystallinity degree as shown by X-ray diffraction.
Źródło:
Acta Physica Polonica A; 2005, 108, 1; 107-112
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Study of VO$\text{}^{2+}$ Center in Fast Proton Conductor K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$
Autorzy:
Ostrowski, A.
Waplak, S.
Bednarski, W.
Powiązania:
https://bibliotekanauki.pl/articles/2043409.pdf
Data publikacji:
2005-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.50.-f
76.30.-v
Opis:
The pretransitional phenomena of superprotonic phase transition (T$\text{}_{sp}$=471 K) were studied in detail by X-band continuous wave EPR spectra of K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ crystal doped with VO$\text{}^{2+}$ ions. Three kinds of VO$\text{}^{2+}$ complexes (magnetically equivalent but structurally non-equivalent) denoted as VO$\text{}^{2+}$(I), VO$\text{}^{2+}$(II), and VO$\text{}^{2+}$(III) were found. "Smearing out" of the superhyperfine structure was observed as a result of interbond proton motion. VO$\text{}^{2+}$ impurity replaces K$\text{}^{+}$ ion and experiences the same average crystal field gradient at T$\text{}_{sp}$=471 K for I- and II-type complexes. The increase in interbond proton frequency hopping above 360 K is a reason of significant line broadening.
Źródło:
Acta Physica Polonica A; 2005, 108, 1; 127-135
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Spin Relaxation of Cu(II) Ions in ZnGeF$\text{}_{6}$·6H$\text{}_{2}$O Crystal with Strong Jahn-Teller Effect
Autorzy:
Idziak, S.
Hoffmann, S. K.
Goslar, J.
Powiązania:
https://bibliotekanauki.pl/articles/2043479.pdf
Data publikacji:
2005-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.90.+t
76.30.-v
Opis:
Cu$\text{}^{2+}$ ions doped to ZnGeF$\text{}_{6}$·6H$\text{}_{2}$O substitute the host Zn$\text{}^{2+}$ ions and undergo a strong Jahn-Teller effect producing nearly axial elongation of the Cu(H$\text{}_{2}$O)$\text{}_{6}$ octahedra with equal population of the three possible deformations at low temperatures as shown by the EPR spectra. Reorientations between these distorted configurations are observed as a continuous shift of EPR lines leading to averaging of the g- and A-tensors. The full averaging is observed at the phase transition temperature 200 K. Electron spin relaxation was measured up to 45 K only, where the electron spin echo signal was detectable. Electron spin-lattice relaxation is governed by the Raman two-phonon process allowing to determine the Debye temperature asΘ$\text{}_{D}$=99 K. There is no contribution of the Jahn-Teller dynamics to the spin-lattice relaxation rate. Electron spin echo decay is strongly modulated by dipolar coupling to the $\text{}^{1}$H and $\text{}^{19}$F nuclei. The phase memory time is governed by instantaneous diffusion at helium temperatures and then by spin-lattice relaxation processes and excitation to the first vibronic level of energyΔ=151 cm$\text{}^{-1}$.
Źródło:
Acta Physica Polonica A; 2005, 108, 1; 177-185
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spin Transition Diagram of (2Me-5Et-PyH)[Fe(Th-5Cl-Sa)$\text{}_{2}$] Studied by EPR
Autorzy:
Krupska, A.
Augustyniak-Jabłokow, M. A.
Yablokov, V. Yu.
Zelentsov, V. V.
Powiązania:
https://bibliotekanauki.pl/articles/2043563.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
33.35.+r
Opis:
The high-spin↔ low-spin transition in (2Me-5Et-PyH)[Fe(Th-5Cl-Sa)$\text{}_{2}$] was studied by EPR under hydrostatic pressure in the temperature range of 80-310 K. Two modifications of the low-spin complexes: low-pressure (LS-1) and high-pressure (LS-2) ones were revealed. The low-spin complexes are associated in domains. Under atmospheric pressure LS-1 appears or disappears at 220 K. The hydrostatic pressure shifts the transition to high temperatures. Above 410 MPa the abrupt changes of the g-factor and width Δ B of the EPR line are observed. The pressure-induced transition LS-1 ↔ LS-2 is almost independent of T up to 275 K where under pressure 420 MPa a triple point is observed. When the pressure has been decreased the reverse transition from LS-2 to LS-1 or to high spin phase (at T>260 K) occurs with a large hysteresis about 95 MPa.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 291-296
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pulsed EPR and ENDOR Study of SiC Nanopowders
Autorzy:
Savchenko, D.
Powiązania:
https://bibliotekanauki.pl/articles/1375684.pdf
Data publikacji:
2014-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
76.70.Dx
81.07.Wx
Opis:
In this work field-sweep electron spin echo and pulsed electron nuclear double resonance study of the silicon carbide (SiC) nanoparticles (np-SiC) of different sizes is presented. Nitrogen (N) triplet lines due to the isolated N donor state was observed in np-SiC with grain size d>100 nm. With a decrease of the particle size up to 50 nm the N triplet lines transforms into one single exchange line due to the delocalization of the donor wave function caused by the size confinement effect. Along with N donors the carbon vacancy ($V_{C}$) located in cubic phase was observed in np-SiC with d < 100 nm. The further decrease of the grain size to d < 50 nm leads to the appearance of the $V_{C}$ located in hexagonal crystalline phase and carbon dangling bonds located in the carbon excess phase of np-SiC. The fact that only N donor center at "k2" quasi-cubic position substituting Si site was observed in the field-sweep electron spin echo and pulsed electron nuclear double resonance spectra of np-SiC was explained by high compensation degree of the samples and the presence of carbon excess in np-SiC. The appearance of the proton electron nuclear double resonance signal in no-SiC with d < 100 nm indicates that the hydrogen retention in np-SiC increases with decreasing of grain size.
Źródło:
Acta Physica Polonica A; 2014, 126, 5; 1063-1065
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thin Films Investigations by Means of Spin-Wave Resonance
Autorzy:
Maksymowicz, A. Z.
Maksymowicz, L. J.
Whiting, J. S. S.
Powiązania:
https://bibliotekanauki.pl/articles/1891792.pdf
Data publikacji:
1991-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.50.+g
76.30.-v
73.90.+f
Opis:
Magnetic resonance technique may successfully be applied to determine some basic parameters such as g-factor, magnetization M$\text{}_{s}$ or anisotropy energy constant K$\text{}_{u}$ in thin magnetic films. These parameters are obtained from a ferromagnetic resonance experiment when uniform precession of M$\text{}_{s}$ takes place. From spin-wave resonance one may extract very valuable information on the exchange constant A or the surface conditions characterized by the surface anisotropy energy (or pinning parameters ρ). In fact, it is only spin-wave resonance or similar techniques which allow for measurements of A, ρ or the coupling constant K$\text{}_{c}$ between ferromagnetic sublayers in multi-layered structure. The magnetic phase diagram, temperature dependence of the spin-waves stiffness constant, and the anisotropy energy constant may also be listed as less common examples of spin-wave resonance technique application for the investigation of thin films. This paper presents a theoretical approach to typical examples of experimental results and their interpretation from spin-wave resonance measurements.
Źródło:
Acta Physica Polonica A; 1991, 80, 5; 665-673
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EMR Spectra Thin Films Doped with High Concentration of Co and Cr on Quartz and Sapphire Substrates
Autorzy:
Cieniek, B.
Stefaniuk, I.
Virt, I.
Powiązania:
https://bibliotekanauki.pl/articles/1030218.pdf
Data publikacji:
2017-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.35.bg
75.30.Gw
76.30.-v
Opis:
We have studied magnetic properties of zinc-oxide composite doped with high concentration (up to 20%) of Co and Cr ions. The pulsed laser deposition method was used to obtain samples on quartz glass and sapphire substrates. Samples were annealed at 100-250°C for ZnO on quartz substrate, and 300-700°C on sapphire substrate. EMR measurements were carried out and temperature dependence of the EMR spectra was obtained. The angular dependence in two samples orientation, vertical and horizontal, were also obtained. Analysis of the temperature dependences of the integral intensity of EMR spectra was carried out using the Curie-Weiss law.
Źródło:
Acta Physica Polonica A; 2017, 132, 1; 30-34
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
$CuBr_2(C_{10}H_8N_2) - S = 1//2$ Two-Dimensional Rectangular Heisenberg Antiferromagnet
Autorzy:
Čižmár, E.
Kajňaková, M.
Orendáčová, A.
Orendáč, M.
Feher, A.
Anders, A.
Park, J.
Meisel, M.
Powiązania:
https://bibliotekanauki.pl/articles/1534990.pdf
Data publikacji:
2010-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Et
75.50.Ee
76.30.-v
Opis:
Magnetic susceptibility and X-band electron spin resonance study of a two-dimensional Heisenberg antiferromagnetic system $CuBr_2$(bipy), where bipy = $C_{10}H_8N_2$ is 4,4'-bipyridyl, has been performed in the temperature range from 300 K down to 2 K. A rhombic anisotropy of the g-factor was obtained from X-band EPR measurements with $g_{x}$ = 2.037, $g_{y}$ = 2.100 and $g_{z}$ = 2.219. The temperature dependence of the magnetic susceptibility with a round maximum observed at 28 K suggests antiferromagnetic type of short-range order. No signature of the magnetic long-range order in studied compound was observed. The comparison of the magnetic susceptibility data with a two-dimensional rectangular Heisenberg model yields the values of intralayer exchange couplings J/$k_{B}$ = - 47 K and J'/$k_{B}$ = - 9.4 K.
Źródło:
Acta Physica Polonica A; 2010, 118, 5; 973-974
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Frustrated zig-zag spin chains formed by hydrogen bonds in [Cu(H₂O)(OH)(tmen)]₂[Pd(CN)₄]·2H₂O
Autorzy:
Čižmár, E.
Orendáčová, A.
Orendáč, M.
Kuchár, J.
Feher, A.
Park, J.
Meisel, M.
Powiązania:
https://bibliotekanauki.pl/articles/1054768.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Et
76.30.-v
75.40.-s
Opis:
The magnetic properties of the novel dimeric compound [Cu(H₂O)(OH)(tmen)]₂[Pd(CN)₄]·2H₂O (tmen=N,N,N',N'-tetramethylethylenediamine) with modulated crystal structure were studied in the temperature range from 95 mK to 300 K. Magnetic measurements revealed a presence of weak antiferromagnetic exchange coupling in the compound. The temperature dependence of specific heat is characterized by the presence of a Schottky-like maximum at 0.47 K and a λ-anomaly at 0.28 K, indicating the formation of long-range order in the system. The comparison of the experimental data with theoretical predictions revealed the presence of antiferromagnetic intradimer exchange coupling J/k_{B}= -1.2 K and interdimer coupling of a similar strength mediated via hydrogen bonds between dimeric units forming a frustrated magnetic zig-zag chain structure.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 940-942
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Study of Dealuminated HY Zeolite and Silica Containing Cu-Mn-Zn Spinels: The Effect of Support
Autorzy:
Decyk, P.
Więckowski, A.
Najder-Kozdrowska, L.
Bilkova, I.
Ziółek, M.
Powiązania:
https://bibliotekanauki.pl/articles/1030220.pdf
Data publikacji:
2017-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.-h
76.30.-v
76.30.Fc
82.75.Vx
Opis:
A mixture of antiferromagnetic Cu_{1.4}Mn_{1.6}O₄ and Cu_{0.5}Zn_{0.5}Mn₂O₄ or/and ZnMn₂O₄ spinels was prepared. Dealuminated HY zeolite and silica were doped by these Cu-Mn-Zn spinels. The materials were investigated by X-ray diffraction, the Fourier transform infrared spectroscopy and EPR spectroscopy. Additionally, all the samples were tested for their activity for isopropyl alcohol dehydration/dehydrogenation. Three EPR signals were observed for Cu-Mn-Zn/dealuminated HY and Cu-Mn-Zn/SiO₂ samples at 293 K. In contrast to the spectra recorded at 293 K, only one broad line attributed to Cu-Mn-Zn spinels was visible at 77 K. The EPR signal from pure Cu-Mn-Zn spinels consists only of a single broad line when recorded at 293 K, whereas at 77 K the line is narrower. For all samples subjected to evacuation at high vacuum up to 573 K, the Cu-Mn-Zn spinels were stable. The evacuation at 673 K resulted in a rapid lowering of the intensity of EPR spectrum.
Źródło:
Acta Physica Polonica A; 2017, 132, 1; 38-44
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EMR Study of Electronic and Magnetic Ordering in Doped CaMn$\text{}_{1-x,y}$M$\text{}_{x,y}$O$\text{}_{3}$ (M = Ru, Mo) Perovskites
Autorzy:
Shames, A. I.
Auslender, M.
Rozenberg, E.
Gorodetsky, G.
Martin, C.
Maignan, A.
Powiązania:
https://bibliotekanauki.pl/articles/2043550.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Kz
75.47.Lx
76.30.-v
76.50.+g
Opis:
X-band electron magnetic resonance measurements of polycrystalline CaMn$\text{}_{1-x,y}$M$\text{}_{x,y}$O$\text{}_{3}$ (M = Ru, 0≤x≤0.5; M = Mo, 0≤y≤0.14) samples were performed at 120 K≤ T≤540 K. The observed anomalies of electron magnetic resonance parameters correlate pretty well with the temperatures of antiferro-, ferromagnetic-like, and orbital/charge-ordering transitions in these systems and specify phase diagrams obtained by other techniques. However, a strong difference between resonant properties of Ru- and Mo-doped series is observed in both paramagnetic and magnetically ordered states. To describe such a difference, the energy bands diagrams, which comprise the deep impurity t$\text{}_{2g}$-like states + e$\text{}_{g}$-like conductive band for CaMn$\text{}_{1-x}$Ru$\text{}_{x}$O$\text{}_{3}$ and shallow impurity states + conductive band, both having e$\text{}_{g}$-like symmetry, for CaMn$\text{}_{1-y}$Mo$\text{}_{y}$O$\text{}_{3}$, are proposed. Specific electrons' contribution to the electron magnetic resonance line width explains concentration and temperature dependences of this parameter in the paramagnetic state in considered systems.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 235-242
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical Explanations of the Optical Band Positions and Local Structure for $Cu^{2+}$ Centers in $ZnO-Bi_{2}O_{3}-B_{2}O_{3}-CuO$ Glasses
Autorzy:
Yuan, M.
Powiązania:
https://bibliotekanauki.pl/articles/1377767.pdf
Data publikacji:
2014-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.72.Bb
75.10.Dg
76.30.-v
76.30.Fc
Opis:
The local structure, two optical band positions and three electronic spin resonance parameters for $Cu^{2+}$ centers at the tetragonally-distorted octahedral sites in $ZnO-Bi_2O_3-B_2O_3-CuO$ glasses are calculated from the high-order perturbation method based on the two-spin-orbit-parameter model, where the contributions from both the spin-orbit coupling parameters of central $d^{n}$ ion and ligand ion are included. The theoretical results are in good agreement with the experimental values. The calculations show that the high-order perturbation method based on the two-spin-orbit-parameter model is effective in the explanations of optical spectra, electronic spin resonance parameters and local distortion structure for $d^{9}$ ions in glasses.
Źródło:
Acta Physica Polonica A; 2014, 126, 6; 1293-1295
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Spin-Lattice Relaxation in Polymers and Crystals Related to Disorder and Structure Defects
Autorzy:
Hoffmann, S. K.
Hilczer, W.
Radczyk, T.
Polus, I.
Powiązania:
https://bibliotekanauki.pl/articles/2035737.pdf
Data publikacji:
2003-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
61.80.-x
76.30.-v
Opis:
Temperature dependences (4-300 K) of the electron spin-lattice relaxation have been determined by electron spin echo technique for free radicals in two polymeric systems: phenol-formaldehyde resin and polyhydrazodisulphide. The dependences are described in terms of dynamics specific for amorphous systems involving two-level tunnelling states at low temperatures, exchange-coupled clusters of paramagnetic centres and local oscillators. Some universal temperature behaviour of the spin-lattice relaxation of amorphous systems is suggested, with a strong increase in relaxation rate with temperature at low temperatures and much weaker increase above 50 K with characteristic linear temperature dependence in a broad temperature range and cosech(Δ/kT) -type behaviour. It is also shown that the amorphous-type behaviour appears in low temperatures relaxation studies of single crystals but it is due to a non-uniform distribution of doped paramagnetic ions. Such behaviour we have found in Tutton salt crystals doped with Cu$\text{}^{2+}$, as well as for free radical centres produced by ionising irradiation in (NH$\text{}_{4}$)$\text{}_{3}$H(SeO$\text{}_{4}$)$\text{}_{2}$ and Li(N$\text{}_{2}$H$\text{}_{5}$)SO$\text{}_{4}$ single crystals, where extended phonons are suppressed around radiation damage centres suggesting a local amorphisation of the crystal structure.zapisz i p
Źródło:
Acta Physica Polonica A; 2003, 103, 4; 373-385
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electric Dipole and Current Induced Spin Resonances of Shallow Donor in ZnO
Autorzy:
Michaluk, E.
Błoniarz, J.
Pabich, M.
Wilamowski, Z.
Mycielski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2046940.pdf
Data publikacji:
2006-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.55.Gs
76.30.-v
71.70.Ej
Opis:
In this paper we present our observation of electric dipole spin resonance and current induced spin resonance in ZnO bulk crystals, both effects result from spin-orbit coupling. Electric dipole spin resonance originates from admixture of spin state due to spin-orbit interaction which leads to probability of spin-flip caused by electric component of microwave field. In current induced spin resonance phenomenon the electric component of microwave field induces electron motion leading to mean ac spin-orbit field that acts on electron spin. Spin-orbit interaction can be described in terms of the Rashba field, an effective magnetic field that induce spin resonance. In contrast to magnetic and electric dipole spin resonances the current induced resonance is characterized by dispersive-like line shape.
Źródło:
Acta Physica Polonica A; 2006, 110, 2; 263-270
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Spin Resonance Study of Thermal Defects in SrLaAlO$\text{}_{4}$ and SrLaGaO$\text{}_{4}$ High-T$\text{}_{c}$ Substrates
Autorzy:
Jabłoński, R.
Gloubokov, A.
Pajączkowska, A.
Powiązania:
https://bibliotekanauki.pl/articles/1964356.pdf
Data publikacji:
1997-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
61.72.Hh
61.72.Ji
Opis:
The effect of annealing SrLaAlO$\text{}_{4}$ (SLA) and SrLaGaO$\text{}_{4}$ (SLG) crystals in oxidizing and reducing atmospheres in the temperature range of 950°C-1300°C was investigated. Three kinds of anisotropic defects D$\text{}_{1}$, D$\text{}_{2}$, and E at the temperature range of 4-300 K were found. By diagonalization of orthorhombic spin-Hamiltonian parameters: |D|=0.0541(10) cm$\text{}^{-1}$, |E|=0.0108(10) cm$\text{}^{-1}$, g$\text{}_{∥}$=0.883(5), and g$\text{}_{⊥ }$=1.922(5) for D$\text{}_{1}$ defects for SLG and SLA were calculated and they had the same values within the margin of error.
Źródło:
Acta Physica Polonica A; 1997, 92, 1; 169-172
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calculation of Optical and Spin-Hamiltonian Parameters for $Mn^{4+}$ Doped in $LiGa_{5}O_{8}$
Autorzy:
Ciresan, M.
Stanciu, M.
Avram, N.
Powiązania:
https://bibliotekanauki.pl/articles/1791234.pdf
Data publikacji:
2009-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.25.Jb
74.25.nd
76.30.-v
Opis:
The aim of this paper is to investigate, from theoretical point of view, the optical spectra and EPR (g-factors) parameters for $Mn^{4+}:LiGa_{5}O_{8}$. The optical energy levels scheme has been obtained by the diagonalization of the Hamiltonian of the system, using all 50 wave functions of the LS terms of $3d^{3}$ electron configuration. The crystal field parameters have been obtained in the exchange charge model of crystal field, taking into account the structure of the host matrix and effects of the covalent bond formation between the $Mn^{4+}$ with $O^{2-}$. The satisfactory agreement with experimental data is obtained.
Źródło:
Acta Physica Polonica A; 2009, 116, 4; 547-549
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Conversions of the Second-Rank Zero Field Splitting Parameters Measured Assuming the Fictitious Spin S=1 to those for the Effective Spin S̃=2
Autorzy:
Kozanecki, M.
Rudowicz, C.
Powiązania:
https://bibliotekanauki.pl/articles/1030215.pdf
Data publikacji:
2017-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.70.Ch
75.10.Dg
76.30.-v
76.30.Fc
Opis:
We investigate feasibility of comparison between the zero field splitting parameters obtained experimentally based on the spin Hamiltonian with the fictitious spin S'=1 and those with the effective spin S̃=2. The former zero field splitting parameters have recently been measured for Fe²⁺ ions in forsterite Mg₂SiO₄, whereas the latter zero field splitting parameters are available in literature, e.g. for Fe²⁺ and Cr²⁺ (S̃=2) ions. It turns out that no unique direct comparison is feasible and hence appropriate conversion relations need to be derived. Methodology for such conversions is outlined. Various combinations of the possible energy level schemes for the spin S̃=2 and S'=1 are briefly described. Illustrative preliminary results concerning appropriate conversions of the second-rank zero field splitting parameters measured by high-frequency EMR for Fe²⁺ in natural and synthetic forsterite are presented. Detailed results and full analysis will be given elsewhere.
Źródło:
Acta Physica Polonica A; 2017, 132, 1; 11-14
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Implications of Invalid Conversions between Crystal-Field Parameters and Zero-Field Splitting Ones Used in Superposition Model
Autorzy:
Rudowicz, C.
Karbowiak, M.
Powiązania:
https://bibliotekanauki.pl/articles/1365340.pdf
Data publikacji:
2014-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.-v
76.30.Fc
71.70.Ch
75.10.Dg
Opis:
The methodology used in recent study of the zero-field splitting parameters of $Cr^{3+}$ ions at various orthorhombic symmetry sites in $LiKSO_4$ by Pandey and Kripal is critically commented on. We argue that the crystal field parameters, $B_{kq}$, in the Wybourne notation, which were calculated using the superposition model for $Cr^{3+}$ ions in $LiKSO_4$, may only be converted into the crystal field parameters in the Stevens notation. Regrettably, the authors have also converted the latter parameters supposedly into the zero-field splitting parameters D and E in the conventional notation. Such direct conversions are fundamentally incorrect and constitute factual invalid usage of the conversion relations between the crystal field (ligand field) parameters and the zero-field splitting ones. The cases of an implied usage of the invalid conversion relations between the crystal field parameters and the zero-field splitting parameters occurring in recent literature are also outlined. Pandey and Kripal have found the zero-field splitting parameters theoretically evaluated in this way to be in good agreement with the experimental values. However, the faulty methodology renders the conclusion that $Cr^{3+}$ ions enter into the $LiKSO_4$ lattice at the substitutional $K^{+}$ sites unjustified. Several other conceptual problems arising from misinterpretations of the crucial notions identified therein are also discussed and clarified.
Źródło:
Acta Physica Polonica A; 2014, 125, 5; 1215-1219
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-50 z 83

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