EMR Study of Electronic and Magnetic Ordering in Doped CaMn$\text{}_{1-x,y}$M$\text{}_{x,y}$O$\text{}_{3}$ (M = Ru, Mo) Perovskites

X-band electron magnetic resonance measurements of polycrystalline CaMn$\text{}_{1-x,y}$M$\text{}_{x,y}$O$\text{}_{3}$ (M = Ru, 0≤x≤0.5; M = Mo, 0≤y≤0.14) samples were performed at 120 K≤ T≤540 K. The observed anomalies of electron magnetic resonance parameters correlate pretty well with the temperatures of antiferro-, ferromagnetic-like, and orbital/charge-ordering transitions in these systems and specify phase diagrams obtained by other techniques. However, a strong difference between resonant properties of Ru- and Mo-doped series is observed in both paramagnetic and magnetically ordered states. To describe such a difference, the energy bands diagrams, which comprise the deep impurity t$\text{}_{2g}$-like states + e$\text{}_{g}$-like conductive band for CaMn$\text{}_{1-x}$Ru$\text{}_{x}$O$\text{}_{3}$ and shallow impurity states + conductive band, both having e$\text{}_{g}$-like symmetry, for CaMn$\text{}_{1-y}$Mo$\text{}_{y}$O$\text{}_{3}$, are proposed. Specific electrons' contribution to the electron magnetic resonance line width explains concentration and temperature dependences of this parameter in the paramagnetic state in considered systems.