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    Wyświetlanie 1-45 z 45
    Tytuł:
    Assessing influence of hydrochloric acid leaching on structural changes and bleaching performance of Nigerian clay from Udi
    Autorzy:
    Ajemba, R. O.
    Onukwuli, O. D.
    Powiązania:
    https://bibliotekanauki.pl/articles/110317.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    acid leaching
    adsorption
    bleaching
    hydrochloric acid
    isotherm
    Opis:
    Clay from Udi in Nigeria was mined, ground, and acid-leached at different concentrations of hydrochloric acid to produce adsorbents of varying properties. The raw and acid-leached samples were characterized using x-ray fluorescence (XRF) and Fourier transforms infra-red spectroscopy (FTIR) to examine the structural modifications in the clay as a result of acid-leaching. The analysis showed that the acid-leaching process caused several modifications of the clay samples. The surface area, Si/[Al + Fe + Mg] ratio, adsorption capacity were found to have increased in the acid-leached samples. The acid-leached samples were tested in order to ascertain their performance in bleaching palm oil and it was observed that the bleaching efficiency increased from 29.8% to 66.7%. The acid-leached sample prepared with 7M hydrochloric acid yielded an adsorbent that was efficient in bleaching palm oil under the experimental conditions. The isotherm analysis showed that the bleaching process followed the Freundlich equation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 1; 349-358
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Zinc extraction from Ghazouat leach residues by using jarosite method
    Autorzy:
    Begar, Abdelhakim
    Djeghlal, Mohamed El Amine
    Ould Hamou, Malek
    Powiązania:
    https://bibliotekanauki.pl/articles/2016450.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Wydział Geoinżynierii, Górnictwa i Geologii. Instytut Górnictwa
    Tematy:
    sphalerite
    Zn
    zinc
    acid leaching
    leaching residue
    extraction
    Opis:
    In this paper, it was aimed to select and propose a feasible as well as an applicable method, for the extraction of zinc that was present in the disposed GHAZOUAT leach residues having 17.82 wt. % Zn and 20.82 wt. % Fe. After the determination of the components of the residue, the acid leaching was performed to reclaim Zn sequentially. The acid leaching experiments were carried out for Zn extraction by controlling acid concentration, reaction duration and temperature. At the optimum conditions, 240 g/L H2SO4 at 90 °C for 210 min, 80% of initial iron content was removed, and the resultant overall zinc extraction was usually superior than 96%.
    Źródło:
    Mining Science; 2021, 28; 117-126
    2300-9586
    2353-5423
    Pojawia się w:
    Mining Science
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    An experimental study of removing impurity from a quartz ore by microbial flotation-acid leaching
    Autorzy:
    Zhu, Jujian
    Dai, Shujuan
    Li, Pengcheng
    Yang, Shuyong
    Powiązania:
    https://bibliotekanauki.pl/articles/1448443.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    quartz purification
    flotation
    acid leaching
    waste bacteria
    Opis:
    The purity of a quartz ore is relatively low at a $SiO_2$ content of 97.18%, and the main impurity in the ore is $Fe$, $Al$, and $Ca$ bearing minerals. The main component in an industrial waste bacteria (WJ) is polysaccharides, which may be used as depressors for inhibiting iron minerals in quartz flotation. Moreover, WJ belongs to microbial inhibitors because it is mainly composed of bacteria. As a result of this study, a concentrate grade of 99.88% at recovery over 80% was obtained under the condition of 2000 g/Mg WJ dosage, a grinding fineness of 70% -0.074 mm, pH 11.7, 400 g/Mg $CaCl_2$, and 800 g/Mg $NaOL$ in the flotation experiments for the quartz ore. Moreover, a $SiO_2$ grade of 99.97% at a recovery of 68.85% was obtained at an acid dosage of 40 kg/Mg by using mixed acid of $H_2SO_4$, $HCl$, $HNO_3$, and $HF$ in mass ratios of 20%, 30%, 20%, and 30%, respectively, in subsequent acid leaching of the quartz flotation concentrate. Zeta potential analysis before and after the interaction of quartz and hematite with WJ showed that WJ increased the zeta potential of hematite significantly but had little impact on the zeta potential of quartz, indicating stronger adsorption of WJ on hematite than on quartz. FTIR analysis showed that there exist not only –$COOH$, –$CH_2$–, and –$CH_3$, which are the functional groups of starch but also $NH_2$ and –$C=O-NH$– in WJ. The $NH_2$ and –$C=O-NH$– in WJ are the important groups for adsorption, so the depressing effect on hematite was better for WJ than starch.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 18-28
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Process improvement and kinetic study on copper leaching from low-grade cuprite ores
    Autorzy:
    Bai, S.
    Fu, X.
    Li, C.
    Wen, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/109660.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cuprite
    dissolution kinetics
    sulfuric acid leaching
    SCM
    Opis:
    Process improvement and kinetic study on copper leaching from low-grade cuprite ores in sulfuric acid solution are presented in this paper. Effects of major leaching parameters on copper leaching efficiency are determined. The results indicate that copper minerals in the raw ores are mainly cuprites. The reaction rate of this ore increases with an increase in temperature, reaction time, sulfuric acid concentrations and decrease in the particle size of ore. Leaching of about 92.5% of copper is achieved using 0.125-0.074 mm ore particle size at a reaction temperature of 353 K for 180 min reaction time with 150 g/dm3 sulfuric acid. The solid/liquid ratio was maintained constant at 1:15. Leaching kinetic indicates experimental data complies with shrinking core mode (SCM). It is found in the study that agitation rate is not an influential factor on leaching rate and that the dissolution rate is controlled by surface chemical reaction. The average activation energy of the process is determined to be 45.28 kJ mol-1, and the reaction order of H2SO4 is 0.8093.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 300-310
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Chalcopyrite leaching by amino acid solutions in the presence of hydrogen peroxide
    Autorzy:
    Nurtazina, Nargiza
    Uvarov, Nikolai
    Azhigulova, Ryskul
    Tyapkin, Pavel
    Powiązania:
    https://bibliotekanauki.pl/articles/2175441.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    chalcopyrite
    amino acid leaching
    glycine
    betaine
    lysine
    Opis:
    It is demonstrated that amino acids such as glycine, betaine, and lysine may be applied as selective copper leaching agents in the process of hydrochemical oxidation of chalcopyrite at atmospheric pressure and in the temperature range 25÷65 °C. The advantage of the proposed method is its relative environmental friendliness. Solid samples of the initial mineral and leached chalcopyrite residues were analyzed by X-ray diffraction analysis, and Mössbauer and Raman spectroscopy. The results of the atomic absorption analysis showed that copper's extraction efficiency increased when the experiment's duration was raised and when the process temperature was higher. The leaching ability of amino acids was evaluated by the specific leaching rate of chalcopyrite in these reagents. Amino acid leaching was thought to be mainly due to the complexation of copper (II) glycinates, copper (II) betainates and copper (II) lysinates. This reaction can be enhanced by adding hydrogen peroxide to the system as an oxidant. It was determined that glycine was more effective as a leaching agent than betaine and lysine. Based on experimental data, it was assumed that the most possible mechanism is selective copper leaching due to the formation of chalcopyrite-based solid solution Cu1-XFeS2.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 157067
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Trace muscovite dissolution separation from vein quartz by elevated temperature and pressure acid leaching using sulphuric acid and ammonia chloride solutions
    Autorzy:
    Lin, M.
    Pei, Z.-Y.
    Lei, S.-M.
    Liu, Y.-Y.
    Xia, Z.-J.
    Xie, F.-X.
    Powiązania:
    https://bibliotekanauki.pl/articles/110755.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    vein quartz
    muscovite
    sulphuric acid
    ammonium chloride
    acid leaching
    Opis:
    Effects of sulphuric acid and ammonia chloride on muscovite dissolution were studied in acid leaching of vein quartz under elevated temperature and pressure. The leaching processes have been studied in detail by analyzing sources of impurity minerals, optimizing leaching process, analyzing leaching kinetics of Al in muscovite and charactering leaching mechanism of muscovite. The results showed that elements of Al and K mainly occurred in muscovite, and 98.10% or more of muscovite could be removed by acid leaching, while the process had limited influence on the particle size of quartz sand. Leaching of Al in the quartz ore was mainly controlled by chemical reaction. A calcination process and ammonia chloride were used for reducing chemical reaction resistance by damaging crystal structure of muscovite and providing stable acid leaching environment. Combined with the calcination process, muscovite, as a main gangue mineral, was effectively extracted during acid leaching of vein quartz at elevated temperature and pressure.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 448-458
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Comparative study on removal of metallurgical silicon impurities by different acid leaching methods
    Autorzy:
    Gao, Zijie
    Luo, Dawei
    Powiązania:
    https://bibliotekanauki.pl/articles/24085856.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    metallurgical-grade silicon
    hydrometallurgy
    acid leaching
    impurity removal efficiency
    Opis:
    Hydrometallurgy is considered a promising method to produce solar-grade silicon (SOG-Si) from metallurgical-grade silicon (MG-Si) due to its advantages of low cost, simple operation, and easy control. In this paper, the effects of particle size of MG-Si, type of acid, leaching time, temperature, and liquid-to-solid ratio on the purification efficiency were investigated in an external field environment with the addition of ultrasound. The purification efficiencies of the two acid-leaching methods were compared. It was found that the simultaneous use of HCl + HNO3 was more effective than using only HCl for impurity removal in MG-Si: the extraction efficiencies of impurities Fe and Al were increased by 2.2% and 13.4%, respectively. The impurity contents in MG-Si before and after calcination pretreatment were also compared. This paper is expected to help researchers select the appropriate hydrometallurgical technique to reduce the impurity content in MG-Si.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 162331
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Hydrochloric acid leaching for upgrading flotation concentrate from a low-grade bauxite ore
    Autorzy:
    Guan, C.
    Chen, L.
    Zheng, Y.
    Sun, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/110259.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    bauxite ore
    hydrochloric acid leaching
    concentrate upgrading
    carbonate minerals
    Opis:
    Bauxite is the major raw material for alumina production, and its Al2O3 grade improvement or desilication is a necessary process for production of high-grade alumina concentrates from bauxite ores. In practice, flotation presents an effective method for the processing of such ores. However, it is not sufficient to produce a concentrate product with high Al2O3 grade from the ores with a single flotation process, especially from these containing abundant carbonate minerals. In this investigation, hydrochloric acid leaching was used to remove dolomite impurity from the flotation concentrate of a bauxite ore, to improve its Al2O3 grade and Al2O3/SiO2 (A/S) ratio. Effects of three dominant parameters on the leaching performance, that is leaching time, leaching temperature and hydrochloric acid concentration, were investigated in details. When these parameters were optimized, the aluminum concentrate assaying 67.41% Al2O3 with 66.84% recovery and 7.44 A/S ratio was obtained from the bauxite ore assaying 42.94% Al2O3 with 2.48 A/S ratio. It was concluded that hydrochloric acid leaching proved an effective method for upgrading of flotation concentrate from a low-grade bauxite ore containing carbonate minerals.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1038-1046
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Selective extraction of vanadium from vanadium-titanium magnetite concentrates by non-salt roasting of pellets-H2SO4 leaching process
    Autorzy:
    Luo, Yi
    Che, Xiaokui
    Wang, Haixia
    Zheng, Qi
    Wang, Lei
    Powiązania:
    https://bibliotekanauki.pl/articles/1445902.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    vanadium-titanium magnetite
    pellets
    selective extraction
    sulfuric acid leaching
    Opis:
    In this work, a novel process of pellet non-salt roasting and H2SO4 leaching was proposed for the selective extraction of vanadium from vanadium–titanium magnetite concentrate. Vanadium can be leached but the iron impurity was maintained in the pellets. Moreover, the leached pellets can meet the quality requirements of the iron-making process after secondary roasting, realizing comprehensive utilization. The maximal vanadium leaching efficiency was up to 60.3%, whereas 0.17% of the iron impurity was leached. The optimum conditions of pellet roasting and leaching were obtained by single-factor experiments. The X-ray diffraction and scanning electron microscopy–energy disperse X-ray spectrometry analyses showed that the vanadium iron spinel can be oxidized and decomposed into Fe2O3 and vanadate during the roasting process. Given that dilute sulfuric acid can react with vanadate without reacting with Fe2O3 in the leaching process, selective vanadium extraction was realized. This work provides new insights into the industrial production of vanadium–titanium magnetite concentrate involving the direct extraction of vanadium.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 36-47
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Calcination of Aluminum Chloride Hexahydrate (ACH) for Alumina Production: Implications for Alumina Extraction from Aluminum Rich Fly Ash (ARFA)
    Autorzy:
    Zhao, L.
    Powiązania:
    https://bibliotekanauki.pl/articles/354384.pdf
    Data publikacji:
    2018
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    calcination
    aluminum chloride hexahydrate
    alumina rich fly ash
    acid leaching
    Opis:
    Alumina rich fly ash (ARFA) has been regarded as the alternative to bauxite in China. Hydrochloric acid process could be favored for alumina extraction, necessitating calcination of aluminum chloride hexahydate (ACH). In this work, the TGA/DSC results of ACH were used to suggest calcination procedures. Two-step calcinations of 200-1000°C and 350-1000°C did not increase the surface area of alumina, by comparison with one step 1000°C calcination, and a slow heating rate could improve the surface area. Calcination temperature was increased from 950 to 1250°C in a step of 50°C, and XRD, XRF, BET and gas pycnometer were used to characterize the alumina from calcinated ACH. Consistent results were obtained by these different techniques, and two groups of impurities were identified and related to alumina purity and surface area. By comparison with clays, it was suggested to remove impurities such as MgO, Na2 O, K2 O, P2 O5 and SO3 in hydrochloric acid leaching of ARFA.
    Źródło:
    Archives of Metallurgy and Materials; 2018, 63, 1; 235-240
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A comparison of uranium recovery from low-grade ore by bioleaching and acid leaching
    Autorzy:
    Szolucha, M. M.
    Chmielewski, A. G.
    Powiązania:
    https://bibliotekanauki.pl/articles/109808.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    bioleaching
    acid leaching
    column leaching
    low-grade ore
    uranium
    recovery
    shrinking core model
    Opis:
    The objective of this work was to compare the bioleaching with the acid leaching of uranium under similar process conditions within 65 days. The low-grade uranium ore used in the experiments was collected from Radoniow’s ‘small’ dump, Poland. Bioleaching and acid leaching studies were carried out in identical columns. The isolated bacterial consortium from the Radoniow’s mine was used for the bioleaching process. A solution of sulphuric acid and H2O2 as oxidizing agent was used for the acid leaching. The extraction of uranium under acid leaching conditions reached maximum of 64±13 % w/w after 31 days. The bioleaching of uranium achieved a maximum extraction of 75±15 % w/w after 55 days. In this study an attempt was made to demonstrate the relationship between the shrinking-core model and the experimental data by plotting the fractional conversion of uranium against time.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 1; 136-149
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Optimizing the removal of iron oxide from Egyptian feldspar ore
    Autorzy:
    Yassin, E. Khaled
    Elbendari, A.M.
    Hassan, El-Sayed R. E.
    Powiązania:
    https://bibliotekanauki.pl/articles/27323643.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    feldspar ore
    iron oxide contamination
    ball mill
    Carpco magnetic separator
    acid leaching
    whiteness
    Opis:
    The demand for feldspar as a raw material for various industrial applications continuously increases. Feldspar is a primary raw material in manufacturing ceramics, glass, fillers, welding electrodes, and enamel. Feldspar is often associated with iron oxide, which decreases its economic value and hinders its industrial application. The present work aimed at reducing iron oxide content in Egyptian feldspar ore from the Wadi Zerabi locality. Ball milling was used for preparing feldspar feed of size -250+45μm. Carpco dry high-intensity magnetic separation followed by acid leaching processes were carried out in order to decrease the iron contamination and increase the feldspar content. A Box-Behnken statistical design was used to optimize the magnetic separation results. From a feldspar feed containing 1.40% Fe2O3, a non-magnetic concentrate of 0.25% Fe2O3 was obtained. The Fe2O3 removal reached up to 82% with a high yield as the % weight of non-magnetic feldspar reached up to 97.5%. The leaching process further reduced the iron oxide content down to 0.19 %. Also, the feldspar whiteness was improved from 65.17% in the original ore to 85.60% in the leached product.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 176420
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Non-reductive acidic leaching as a method for recovery of zinc and manganese from Zn-C and Zn-MnO2 battery waste
    Autorzy:
    Sobianowska-Turek, Agnieszka
    Banaszkiewicz, Kamil
    Pasiecznik, Iwona
    Marcinkowski, Tadeusz
    Urbańska, Weronika
    Powiązania:
    https://bibliotekanauki.pl/articles/2032912.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    alkaline battery
    Mn
    Zn
    acid leaching
    spent battery
    bateria alkaliczna
    kwaśne ługowanie
    bateria zużyta
    Opis:
    The dynamic growth of mobile technologies is a driving need for portable power sources. The most popular division of electrochemical cells relies on the type of chemical reaction within the cell. Current data coming from the Polish market show that despite the growth in the sale of secondary power sources, zinc-carbon and alkaline batteries are still the most popular. The results of non-reductive acidic leaching of zinc and manganese from the waste batteries stream have been presented. Manganese was leached with almost 100% yield in an experiment with a solid to liquid ratio equal to 4/1, pH of 1.04, and H2SO4 concentration of 72.5 wt. %. High yields were also obtained for zinc recovery from the waste stream (100% for two series with solid to liquid ratio 4/5, pH of 0.80; H2SO4concentration of 37.2 wt. %, and solid to liquid ratio 1/2; pH of 1.01; H2SO4 concentration of 27.3 wt. %). Besides, the quantitative and qualitative analysis of Zn-C and Zn-Mn batteries introduced to the Polish market and waste generated in the years 2010-2018 has been presented.
    Źródło:
    Environment Protection Engineering; 2021, 47, 2; 17-29
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Hydrometallurgical treatment of non-sulfide zinc ore for precipitation of zinc oxide nanoparticles
    Autorzy:
    Abdel-Aal, E.-S. A.
    Rashad, M. M.
    El-Shazly, A. N.
    Ibrahim, I. A.
    El-Shahat, M. F.
    Powiązania:
    https://bibliotekanauki.pl/articles/110748.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    zinc ore
    sulfuric acid leaching
    filtration rate
    zinc sulfate
    zinc oxide nanoparticles
    MB photocatalytic degradation
    Opis:
    Acid leaching of Egyptian zinc ore from the Um Gheig area was carried out with sulfuric acid. This study determines the optimum conditions for dissolution of non-sulfide zinc ore. The optimum conditions are 25% -74m particle size, 45 °C temperature, 2 h leaching time, 1.1 stoichiometric molar ratio of H2SO4 to Zn, 1:3 solid/liquid ratio. The maximum filtration rate is 1.6 Mg Zn•m-2•day-1at pressure difference of 0.80 bar. The zinc recovery is about 90%. As the zinc ore contains zinc silicate, some additives were tested to enhance filtration and prevent formation of silica gel. To increase the added value of the product, zinc oxide was precipitated by a co-precipitation method in a nanosize powder with average particle size ~ 20 nm. Photocatalytic degradation of methylene blue dye under UV light using ZnO nanopowders produced at different conditions was investigated. Photocatalytic efficiency with methylene blue (MB) concentration was reduced as much as 85% in 240 min with the produced nanoparticles.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 729-737
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The optimization of low-magnesium zinc concentrate production process
    Autorzy:
    Jarosiński, A.
    Fela, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/779226.pdf
    Data publikacji:
    2009
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    koncentraty cynku
    usuwanie magnezu
    obróbka chemiczna
    ługowanie
    Zn-concentrate
    magnesium removal
    chemical treatment
    acid leaching
    Opis:
    In this paper the result of the study on chemical leaching of zinc concentrate with H2SO4 solution was presented. The object of this work was to assess the effect of some parameters such as acid concentration, the leaching agent amount /stoichiometry amount or excess of acid were applied/, reaction time and temperature on the process. The investigation was performed as a active experiment according to Hartley's plan. The process optimisation procedure was based on the fuzzy logic system. Mainly, the parameters such as magnesium leaching efficiency and zinc losses were taken into account. It was stated that the highest magnesium leaching efficiency of 77.8% with low Zn-losses was reached when H2SO4 solution concentration was 2.5% for 20%-excess of acid, at temperature 25°C and process time of 1 hour.
    Źródło:
    Polish Journal of Chemical Technology; 2009, 11, 1; 20-23
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Wydzielanie związków żelaza z roztworu po ługowaniu odpadów poflotacyjnych Zn-Pb
    Precipitation of iron compounds from a solution after Zn-Pb post flotation tailings leaching
    Autorzy:
    Siedlecka, E.
    Sobik-Szołtysek, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/297387.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Częstochowska. Wydawnictwo Politechniki Częstochowskiej
    Tematy:
    acid leaching
    selective precipitation of iron compounds
    goethite
    pigments
    ługowanie kwaśne
    selektywne wydzielanie związków żelaza
    getyt
    pigmenty
    Opis:
    Iron is usually present in the leaching solutions and its elimination is a major problem in hydrometallurgy. The recovery of iron from such solutions is usually carried out by precipitation as jarosite, goethite or hematite. Together with the iron other undesirable metals, mainly Zn, Mg, Pb are precipitated. The impact of the following parameters: temperature, time, type and dose of oxidant on selective separation the iron compounds from the leaching solution of Zn-Pb post-flotation tailings were investigated. The leaching solution was obtained in the process of dynamic neutralization the accumulator electrolyte with the Zn-Pb flotation tailings and separation of the precipitate from the solution. Using the set conditions of iron compounds precipitation from the leaching solution, the post-processed solutions were obtained in which the content of Mg, Zn, Fe were analyzed. It was found that the process of iron compounds precipitation causes co-precipitation of the accompanying metals that contaminate the resulting precipitates. The coprecipitation of magnesium, together with iron compounds is particularly disadvantageous process results in a reduced yield of metal in the final product. In order to minimize these losses, the oxidizing precipitation of iron from the leach solution in the form of goethite was carried out. This led to significant loss of Mg+2 ions from the solution in an amount of 0.24% positively influencing technological process of magnesium sulphate recovery from the waste. The goethite precipitate formed in a simple single stage process is a commercial product or an intermediate product (after ignition) for the preparation of a red pigment.
    Żelazo jest często obecne w roztworach po ługowaniu, a jego eliminacja jest głównym problemem w procesach hydrometalurgicznych. Odzysk żelaza z takich roztworów polega najczęściej na jego wydzieleniu w postaci jarosytu, getytu lub hematytu. Wraz z żelazem wytrącają się inne niepożądane metale, głównie Zn, Mg, Pb i inne. W pracy zbadano wpływ takich parametrów, jak temperatura, czas, typ i dawka utleniacza na selektywne wydzielanie związków żelaza z roztworu po ługowaniu odpadów poflotacyjnych Zn-Pb. Roztwór po ługowaniu pozyskano w procesie dynamicznej neutralizacji elektrolitu akumulatorowego odpadem poflotacyjnym i oddzieleniu osadu od roztworu. Stosując ustalone warunki wydzielania związków żelaza z roztworu po ługowaniu, otrzymano roztwory poprocesowe, w których oznaczono zawartość metali: Mg, Zn, Fe. Stwierdzono, iż proces wydzielania związków żelaza, w zależności od warunków, powoduje współstrącanie się towarzyszących metali, które zanieczyszczają powstałe osady. Szczególnie niekorzystnym procesem jest współstrącanie się magnezu wraz ze związkami żelaza powodujące zmniejszenie uzysku metalu w produkcie końcowym. W celu zminimalizowania tych strat przeprowadzono strącanie utleniające żelaza z roztworu po ługowaniu w postaci getytu, uzyskując nieznaczne straty jonów Mg+2 z roztworu w ilości 0,24%, co jest bardzo korzystne dla procesu technologicznego pozyskiwania siarczanu magnezu z odpadów. Wydzielony osad getytu w prostym procesie jednostopniowym stanowi produkt handlowy, a po wyprażeniu - półprodukt do otrzymywania pigmentu czerwonego.
    Źródło:
    Inżynieria i Ochrona Środowiska; 2017, 20, 2; 263-276
    1505-3695
    2391-7253
    Pojawia się w:
    Inżynieria i Ochrona Środowiska
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of sulphuric(VI) acid leaching for magnesium removal from zinc concentrate
    Autorzy:
    Jarosiński, A.
    Fela, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/779955.pdf
    Data publikacji:
    2007
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    koncentraty cynku
    usuwanie magnezu
    ługowanie kwasem siarkowym
    ruda cynku
    zinc concentrate
    magnesium removal
    chemical treatment
    sulphuric(VI) acid leaching
    Opis:
    In this paper the results of investigation of magnesium removal from raw zinc concentrate have been presented. The raw materials derive from ZG Trzebionka and ZGH Bolesław. The differences in zinc and magnesium contents are characteristic of these materials. The experiments were carried out in the periodical reactor at 25°C using the H2SO4 solution of 20, 50, and 70% (v/v) concentration. The weight ratio of the solid phase to the liquid phase was 1:10 and 1:2. On the basis of the experimental results it can be stated that the application of sulphuric(VI) acid leaching permits to increase the zinc yield in Zn-Pb ore processing. This method permits to obtain zinc concentrate containing more than 60% Zn and MgO below 0.3% and CaO about 1.4%.
    Źródło:
    Polish Journal of Chemical Technology; 2007, 9, 2; 19-22
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Long-term planning for open pits for mining sulphide-oxide ores in order to achieve maximum profit
    Planowanie długoterminowe wydobycia rudy siarczkowej w kopalniach odkrywkowych w celu uzyskania maksymalnego poziomu zysków
    Autorzy:
    Krzanovic, D.
    Conic, V.
    Stevanovic, D.
    Kolonja, B.
    Vaduveskovic, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/220057.pdf
    Data publikacji:
    2017
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    planowanie długoterminowe
    optymalizacja
    bio-wypłukiwanie
    ługowanie kwasowe
    wartość bieżąca netto (NPV)
    long term planning
    optimisation
    bioleaching
    acid leaching
    net present value
    Opis:
    Profitable exploitation of mineralised material from the earth’s crust is a complex and difficult task that depends on a comprehensive planning process. Answering the question of how to plan production depends on the geometry of the deposit, as well as the concentration, distribution, and type of minerals in it. The complex nature of mineral deposits largely determines the method of exploitation and profitability of mining operations. In addition to unit operating costs and metal prices, the optimal recovery of and achievement of maximum profit from deposits of sulphide-oxide ores also depend, to a significant extent, on the level of technological recovery achieved in the ore processing procedure. Therefore, in defining a long-term development strategy for open pits, special attention must be paid to the selection of an optimal procedure for ore processing in order to achieve the main objective: maximising the Net Present Value (NPV). The effect of using two different processes, flotation processing and hydrometallurgical methods (bioleaching acid leaching), on determining the ultimate pit is shown in the case of the Kraku Bugaresku-Cementacija sulphide-oxide ore deposit in eastern Serbia. Analysis shows that the application of hydrometallurgical methods of processing sulphide-oxide ore achieved an increase in NPV of 20.42%.
    Przynosząca zyski eksploatacja kopalin wydobywanych ze skorupy ziemskiej jest zadaniem złożonym i trudnym, wymagającym całościowego planowania. Aby określić w jaki sposób zaplanować prace wydobywcze, należy uwzględnić geometrię złoża, a także rozkład, koncentrację i rodzaj zawartych w złożu minerałów. Złożony charakter złóż minerałów w dużej mierze determinuje wybór metod wydobycia oraz poziom zysków. Obok jednostkowych kosztów produkcji oraz cen metali, optymalna eksploatacja złóż rud siarczkowych i osiągniecie maksymalnych zysków w dużej mierze zależą także od zastosowanych technologii uzyskiwania metalu z rud. Przy definiowaniu długoterminowej strategii wydobycia rud w kopalni odkrywkowej uwzględnić także należy wybór optymalnej metody obróbki rud w celu uzyskania założonego celu: maksymalizacji wartości bieżącej netto (NPV – Net Present Value). Wykorzystanie dwóch procesów: flotacji oraz metod hydro-metalurgicznych (bio-wypłukiwanie, ługowanie) przedstawiono dla rozważanego przypadku kopalni odkrywkowej rudy siarczkowej eksploatującej złoże w regionie Kraku-Bugaresku-Cementacija we wschodniej Serbii. Analizy wskazały, że zastosowanie metod hydro-metalurgicznych zapewnia wzrost wartości bieżącej netto o 20.42%.
    Źródło:
    Archives of Mining Sciences; 2017, 62, 4; 807-824
    0860-7001
    Pojawia się w:
    Archives of Mining Sciences
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Production of high quality magnesium chloride from recycled waste magnesite powder
    Autorzy:
    Erdogan, N.
    Yersel, E.
    Celebi, C.
    Kavakli, N.
    Batar, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/110185.pdf
    Data publikacji:
    2013
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    waste magnesite powder
    leaching hydrochloride acid
    magnesium chloride
    MgCl2
    Opis:
    This study investigates the production of high-quality MgCl2 from recycled waste magnesite powder with an average particle size of d50 0.079 mm using the HCl acid leaching method. The experimental parameters were, leaching temperature, leaching time, amount of the acid, liquid-to-solid ratio, scale-up factor, acid concentration, particle size and mixing speed. The experiments were performed under reproducible conditions. The results showed that optimum leaching parameters were: temperature of 70 °C, 180 min leaching time, 130 cm3 acid consumption, 3.6 cm3/g liquid-to-solid ratio, scale-up factor of 1, 10.17 M acid concentration, 0.079 mm average particle size and a mixing speed 60 rpm. Under these optimum conditions, the leaching yield was 96.72%. The produced MgCl2 solution contained 0.04% SiO2, 0.36% CaO, 0% Fe2O3, 0% Al2O3, 46.73% MgCl2, 52.87% L.O.I. and 99.60% MgCl2+L.O.I. (= MgCl2·6H2O). These results indicated that high-quality magnesium chloride can be produced from waste magnesite powder.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2013, 49, 2; 557-566
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Odzysk niklu, kadmu i kobaltu ze zużytych baterii
    Nickel, cadmium and cobalt recovery from spent batteries
    Autorzy:
    Kończyk, J.
    Sobianowska-Turek, A.
    Sobianowska, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/103498.pdf
    Data publikacji:
    2016
    Wydawca:
    Uniwersytet Humanistyczno-Przyrodniczy im. Jana Długosza w Częstochowie. Wydawnictwo Uczelniane
    Tematy:
    zużyte baterie
    kwaśne ługowanie
    ekstrakcja rozpuszczalnikowa
    nikiel
    kadm
    kobalt
    rezorcyn[4]aren
    spent batteries
    acid leaching
    solvent extraction
    nickel
    cadmium
    cobalt
    resorcin[4]arene
    Opis:
    W pracy zaproponowano czteroetapowy proces odzysku niklu, kadmu i kobaltu ze zużytych baterii niklowo-kadmowych (Ni-Cd) oraz niklowo-wodorkowych (Ni-MH) obejmujący obróbkę mechaniczną, kwaśne ługowanie odpowiednio przygotowanych odpadów bateryjnych, ekstrakcję rozpuszczalnikową badanych metali przy użyciu tetratiofosforylowanego rezorcyn[4]arenu oraz reekstrakcję metali do fazy wodnej. Ponadto, w celu optymalizacji procesu, określono wpływ wybranych parametrów, takich jak: temperatura początkowa i czas prowadzenia ługowania, rodzaj kwasu mineralnego oraz pH fazy wodnej i stężenie ekstrahenta na wydajność i selektywność odzysku badanych metali.
    Presented work describes four-step recovery process of nickel, cadmium and cobalt from Ni-Cd and Ni-MH batteries. The process consists of mechanical treatment, acid leaching, solvent extraction with the use of tetratiophosphorylated resorcin[4]arene and reextraction of the metal ions to aqueous phase. Additionally, in order to optimize the process, effect of some parameters, such as temperature and duration time of the leaching, the type of mineral acid, pH of aqueous phase and extractant concentration on efficiency and selectivity of metal recovery was determined.
    Źródło:
    Prace Naukowe Akademii im. Jana Długosza w Częstochowie. Technika, Informatyka, Inżynieria Bezpieczeństwa; 2016, T. 4; 233-246
    2300-5343
    Pojawia się w:
    Prace Naukowe Akademii im. Jana Długosza w Częstochowie. Technika, Informatyka, Inżynieria Bezpieczeństwa
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of oxalic acid as an efficient leaching agent of aluminum from industrial waste
    Autorzy:
    Pospiech, Beata
    Warzecha, Marek
    Powiązania:
    https://bibliotekanauki.pl/articles/109904.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    aluminum
    leaching
    oxalic acid
    Opis:
    The leaching with acids is one of many methods used for recovery of valuable components from industrial wastes. The processing and neutralization of this type of waste is very difficult due to toxic properties. This work shows the results of aluminum leaching from industrial black dross with oxalic acid depending on temperature, acid concentration, effect of liquid to solid ratio (L/S) and time process. The oxalic acid has not been used so far for processing of aluminum black dross. The main purpose of this work was to determine the optimal conditions of this process. The results show that the maximum leaching efficiency of aluminum (75.2 %) was obtained with a liquid to solid ratio of 20:1 using 0.5 mol·dm-3 oxalic acid at 75 °C for 3 h.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 2; 264-270
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Jiroft refractory manganese ore leaching using oxalic acid as reducing agent in sulfuric acid solution
    Autorzy:
    Sobouti, Arash
    Shafaat, Niosha
    Abdollahzadeh, Ali A.
    Powiązania:
    https://bibliotekanauki.pl/articles/110395.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    manganese
    oxalic acid
    sulfuric acid
    leaching
    optimization
    Jiroft
    Opis:
    Leaching process of Jiroft refractory manganese ore was investigated. The effects of operating parameters such as liquid to solid ratio, pulp temperature, sulfuric acid concentration, and oxalic acid concentration were studied and the optimization was done through the response surface methodology (RSM) based on central composite design (CCD) model. The recoveries of Mn, Fe and Si were selected as response of design. The optimum condition was determined by ANOVA, indicating that the liquid to solid ratio, oxalic acid concentration and pulp temperature for Mn recovery and liquid to solid ratio, pulp temperature and sulfuric acid concentration for Fe recovery and liquid to solid ratio for Si recovery were the most effective parameters, respectively. Under the optimum conditions of liquid to solid ratio= 11.8%, pulp temperature= 700 C, sulfuric acid concentration= 40 g/L and oxalic acid concentration= 35 g/L, 71.1%, 4.67% and 0.6% of Mn, Fe and Si were recovered, respectively.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 2; 374-385
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dissolution and precipitation of zinc and manganese obtained from spent zinc-carbon and alkaline battery powder
    Autorzy:
    Kursunoglu, S.
    Kaya, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/109337.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    leaching
    ascorbic acid
    manganese
    zinc
    precipitation
    Opis:
    The aim of this study was to investigate manganese and zinc recoveries from spent zinc-carbon and alkaline battery powder. The effect of sulfuric acid concentration, ascorbic acid dosage, reaction temperature and leaching time on zinc and manganese dissolutions was investigated. The optimum reductive acid leaching conditions were determined as: 3 hours, 70 °C, 0.5 M of sulfuric acid concentration, 13 g/dm3 of ascorbic acid dosage, 1/20 g/cm3 of solid/liquid ratio and 200 rpm of stirring speed. Under these conditions, dissolution efficiencies were 99.99% for Zn and 99.25% for Mn. In addition, dissolution kinetics of manganese was undertaken, and the activation energy was found to be 7.04 kJ/mol. Using 3 M NaOH as precipitating agent at room temperature, 95.35% of Zn (at pH 8) and 93.66% of Mn (at pH 10) were precipitated from the leaching solution. Under the same conditions, using 3 M KOH, precipitations of Zn and Mn were 91.63% and 96.39%, respectively. Based on the experimental results, a flowsheet of zinc and manganese recovery was proposed.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 1; 41-55
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Investigation of kinetics and mechanism of priceite leaching in sulphuric acid solutions
    Autorzy:
    Gur, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/110631.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    boron minerals
    priceite
    sulphuric acid
    leaching kinetics
    boric acid
    Opis:
    The leaching kinetics and mechanism of priceite having the formula of 4CaO5B2O37H2O was investigated in sulphuric acid solutions. For the dissolution process, the effects of reaction temperature, sulphuric acid solution concentration, solid/liquid ratio, particle size, and stirring speed were investigated as effective parameters for the experiments. The experimental data indicated that the dissolution rate increased with the increasing reaction temperature, the decreasing particle size, and the solid/liquid ratio. The conversion rate increased up to 1.0 mol/dm3 with the increasing acid concentration, and then decreased with the increasing acid concentration over concentrations of 1 mol/dm3. It was also determined that the stirring speed had no significant effect on the dissolution rate. The dissolution process of priceite in sulphuric acid solution was tested with regard to heterogeneous and homogeneous reaction models, and it was found that the dissolution rate was controlled by first order pseudo-homogeneous reaction model. The activation energy of the dissolution process was determined as 26.07 kJmol-1. The results were evaluated graphically and statistically. The experimental data were found to fit well with the mathematical model.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2015, 51, 2; 719-730
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on the mechanism and kinetics of sulfuric acid leaching scandium from rich scandium anatase
    Autorzy:
    He, Fei
    Gao, Likun
    Chen, Long
    Rao, Bing
    Shen, Hairong
    Peng, Kebo
    Gao, Guangyan
    Powiązania:
    https://bibliotekanauki.pl/articles/2146896.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    anatase ore
    sulfuric acid
    leaching
    kinetics
    scandium
    Opis:
    Scandium and its compounds have excellent properties, and are widely used in cutting-edge fields such as optics, electronics, and alloys. Thus, scandium is an important strategic metal. However, scandium is extremely sparsely distributed in the earth's crust, rarely occurs as an independent mineral, and requires a complex recovery process. Therefore, the study of the extraction of scandium is of great practical significance. This study examined the leaching test and kinetics of scandium under the acid leaching system of refractory anatase ore. Under appropriate two-stage countercurrent leaching conditions, the first stage of the particle size of fraction of -0.074 mm 82.6%, initial H2SO4 concentration of 6 mol/L, leaching temperature of 100 °C, acid/solid ratio of 3 ml/g, stirring speed of 300 rpm, and leaching time of 50 min; and the second stage of the initial H2SO4 concentration of 11 mol/L, leaching temperature of 150 °C, acid/solid ratio of 4 ml/g, stirring speed of 300 rpm, and leaching time of 50 min, a scandium leaching rate of 96.98% was achieved. The kinetics of scandium leaching conformed to a shrinking-core model, and sulfuric acid concentration and temperature were the most important parameters affecting the scandium leaching rate. The kinetic analysis of scandium leaching at different sulfuric acid concentrations showed that as the concentration increased, the sulfuric acid leaching of scandium changed from being chemical reaction-controlled to internal diffusion-controlled, and the apparent reaction order was 1.2429. The kinetics of scandium leaching at different temperatures showed that the sulfuric acid leaching of scandium was reaction-controlled and the apparent activation energy was 42.21 kJ-mol-1.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 146171
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Recovery of copper from smelting slag by sulphation roasting and water leaching
    Autorzy:
    Dimitrijevic, M. D.
    Urosevic, D. M.
    Jankovic, Z. D.
    Milic, S. M.
    Powiązania:
    https://bibliotekanauki.pl/articles/110627.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    copper
    slag
    sulphation
    roasting
    acid baking
    leaching
    Opis:
    In this work extraction of copper and iron from a reverberatory furnace slag was studied. A two-step extraction procedure was followed. The first step was roasting of the slag in the presence of sulphuric acid at temperatures between 150 and 800oC. The second step was leaching of the resulting calcine with distilled water. The maximum copper extraction of about 94% was achieved. In this case, the slag was roasted at 250oC with sulphuric acid higher of about 33% than that stoichiometrically required, followed by water leaching of calcine at 50oC. About 55% of iron was also dissolved under these conditions. On the other hand, for the calcine obtained at sulphation temperature of 600oC, extraction of copper in a water leaching stage was still relatively high (about 79%), whereas that of iron was comparatively low (about 6%). Dissolution of copper and iron from the calcine was found to be very fast and was complete within the first few minutes. The water temperature in the leaching step was found to have no effect on extraction of copper and iron from the calcine in the range of 30 to 85oC.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 409-421
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Leaching of zinc from low grade oxide ore using organic acid
    Autorzy:
    Irannajad, M.
    Meshkini, M.
    Azadmehr, A. R.
    Powiązania:
    https://bibliotekanauki.pl/articles/110892.pdf
    Data publikacji:
    2013
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    leaching
    zinc oxide ore
    citric acid
    smithsonite
    Opis:
    The leaching of low grade zinc oxide mining tailings by organic acid as a leaching agent was investigated. Zinc was extracted successfully from sample by citric acid leaching. The effects of solid-to- liquid ratio, acid concentration, reaction time, temperature and ore particle size on the leaching efficiency were studied. The results obtained showed that particle sizes and reaction time had not any significant effect on the leaching recovery of zinc from smithsonite in the sizes range of 40-350 μm. Under conditions: temperature of 80ºC, reaction time of 60 min, citric acid concentration of 0.5 mol/L, and solid to liquid ratio of 1:10, 82% of zinc could be recovered.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2013, 49, 2; 547-555
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Leaching of coal by trioxoboric acid for coal clearing
    Autorzy:
    Bilgin, Oyku
    Hacıfazlıoğlu, Hasan
    Sert, Dilara
    Powiązania:
    https://bibliotekanauki.pl/articles/2146861.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    trioxoboric acid
    coal beneficiation
    leaching
    work index
    Opis:
    Trioxoboric acid (H3BO3) is a white weakly soluble acid produced from boron minerals. This acid type was used for the first time in this study for ash and sulfur removal from coal. Ash and sulfur are the most important impurities in the content of coal and have significant effects on environmental pollution. It is possible to remove ash and sulfur by H3BO3 leaching. However, there have not been enough studies in this area and the performance of trioxoboric acid has not been fully demonstrated. In this study, leaching performance of trioxoboric acid and other strong acids (hydrofluoric, hydrochloric and sulfuric acids) has been demonstrated. Trioxoboric acid removed ash and sulfur from coal by 41.18% and 32.16%, respectively. This acid can compete especially with hydrochloric and sulfuric acid in sulfur removal. However, hydrofluoric acid provided the best results in ash and sulfur removal.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 5; 129--136
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Oxidative pressurized acid leaching of waste printed circuit boards
    Autorzy:
    Lundstrom, M.
    Seisko, S.
    Jascisak, J.
    Orac, D.
    Aromaa, J.
    Havlik, T.
    Forsen, O.
    Powiązania:
    https://bibliotekanauki.pl/articles/109824.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    batch leaching
    sulfuric acid
    copper
    tin
    gas formation
    Opis:
    The amount of waste printed circuit board (WPCB) increases continuously. There is an economic and environmental need to recover valuable metals from WPCBs. In this study, the applicability of oxidative pressurized acid leaching of WPCBs rich in copper and tin was investigated. The effect of leaching parameters such as temperature, partial oxygen pressure and chloride concentration on metal dissolution from WPCBs was studied in sulfuric acid media. It was shown that non-metallic elements present in WPCBs initiated gas formation, namely CO2 and CO, during oxidized pressure acid leach. Decomposition of plastic components already started at 90 °C with 1.5 MPa oxygen overpressure in the presence of 1 g/dm3 chlorides. Gas formation was shown to have a negative impact on the process since copper extraction was reduced to 27% compared to 80-90% extraction achieved from anode slimes used as a reference material. It was suggested that gas formation related to plastic components could have a severe impact on metal yields. The highest dissolution of tin equal to 36% was achieved at room temperature. It was found that higher temperature promoted tin hydrolysis.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 781-792
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Kinetics of sulphuric acid leaching of titanium from refractory anatase under atmospheric pressure
    Autorzy:
    Gao, Likun
    Rao, Bing
    Dai, Huixin
    Xie, Haiyun
    Wang, Peng
    Ma, Fangtong
    Powiązania:
    https://bibliotekanauki.pl/articles/109701.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    anatase ore
    kinetics
    sulphuric acid
    leaching
    titanium dioxide
    Opis:
    Anatase, as an important titanium resource, is attracting more and more attention in research and application. In this study, an efficient process of comprehensively extracting the titanium and other valuable elements from the anatase mineral was proposed. The effect of particle size, stirring speed, initial sulphuric acid concentration, solid-to-liquid ratio, and reaction temperature on the leaching rate of titanium from anatase was investigated. Under appropriate two-stage countercurrent leaching conditions, with the first stage of the liquid-to-solid ratio of 1/3 g/cm3, reaction temperature of 120 °C, initial acid concentration of 11 mol/dm3, residence time of 30 min, stirring speed of 200 rpm, and the second stage of the liquid-to-solid ratio of 1/3 g/cm3, reaction temperature of 200 °C, initial acid concentration of 13 mol/dm3, residence time of 30 min, and stirring speed of 200 rpm, over 99% TiO2, 99% Al2O3, and 97% Sc2O3 were extracted respectively with quartz still remained in the residue. X-ray diffraction, X-ray fluorescence spectrometer, and scanning electron microscopy/energy-dispersive spectroscopy were used to characterize the anatase samples before and after the leaching. Additionally, the leaching kinetics analysis indicated that both acid concentration and temperature were the most significant parameters for the leaching process. And, the titanium leaching reaction rate was controlled by the diffusion of reactants through the residual layer.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 2; 467-478
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of chemical and biogenic leaching on surface area and particle size of laterite ore
    Autorzy:
    Pawlowska, A.
    Sadowski, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/110297.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    nickel
    laterite ores
    leaching
    citric acid
    Aspergillus niger
    Opis:
    Currently there is a decline in the world’s nickel sulfide deposits, which are the main source of this metal. Due to the fact, that more than 70% of nickel reserves are in the form of oxide ores, more attention is nowadays paid on laterites. Leaching processes using different organic acids are widely described in the literature, but there is a lack of works linking influence of leaching process with the surface area and particle size distribution. Therefore, the main aim of this study was to examine how citric acid produced by microorganisms and citric acid added as chemical affected the specific surface and particle size distribution of mineral particles. The laterite ore was obtained from Szklary deposit, Poland. This study also compared the effect of chemical citric acid and filtrate after cultivation of Aspergillus niger on nickel extraction. It was observed that higher nickel recovery correspond to higher surface area of particles. The highest yield of nickel extraction was observed for a citric acid concentration of 1 mol/dm3 (67%). The specific surface area after leaching was 159 m2/g. An analysis of particle size distribution showed increase in the median particle size of particles after leaching with citric acid. It may suggest that dissolution of Polish laterites follows a shrinking core-shrinking particle model.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 869-877
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Recovery of cobalt and nickel by atmospheric leaching of flotation sulfide concentrate from lubin concentrator
    Autorzy:
    Gibas, K.
    Borowski, K.
    Chmielewski, T.
    Wejman, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/951849.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    atmospheric leaching
    cobalt
    nickel
    sulphuric acid
    Lubin copper concentrate
    Opis:
    An experimental study on leaching of cobalt and nickel from a Lubin (Poland) sulfide flotation copper concentrate with oxygenated sulphuric acid solution in the presence of iron(III) sulfate is presented. The effect of temperature, iron(III) concentration, initial sulphuric acid concentration, oxygen flow rate and chloride ions addition on cobalt and nickel leaching were examined. The obtained results show, that enhancing investigated leaching parameters increases both the rate and leaching recovery of nickel and cobalt. The effect of iron(III) ions concentration is particularly significant. Additionally, a significant correlation between copper and nickel/cobalt leaching recovery was observed. Due to the fine dissemination of nickel and cobalt, they were leached remarkably faster when copper leaching recovery exceeded 90%.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2015, 51, 1; 191-203
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on leaching kinetics of laterite ore using hydrochloric acid
    Autorzy:
    Li, Jinhui
    Xu, Zhifeng
    Wang, Ruixiang
    Gao, Yang
    Yang, Yang
    Powiązania:
    https://bibliotekanauki.pl/articles/110911.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    nickel laterite
    hydrochloride acid
    kinetics analysis
    hydrometallurgy
    leaching mechanism
    Opis:
    The process of atmosphere-pressure acid leaching of laterites has attracted considerable attention in the nickel industry in recent years. However, the leaching kinetics of laterite using hydrochloride acid has not yet been fully researched. In this paper, the mineral analysis of the ore was carried out, and the leaching mechanism of different minerals at different time was studied comprehensively. The kinetics analysis of the leaching process of nickel, cobalt and manganese showed that the kinetics model of diffusion controlling was suitable and could be described by the linear equation, 1-3(1-a)2/3+2(1-a)=k2t. Based on the linear equation and the Arrhenius equation, the values of activation energy of metal leaching can be deduced (11.56 kJ/mol for nickel, 11.26 kJ/mol for cobalt and 10.77 kJ/mol for manganese). Study of leaching mechanism shows that the order of these minerals dissolution is: goethite, lizardite, magnetite and hematite. Due to the original or product of silica, magnetite, hematite and talc, they can form the solid film which hinders the leaching of valuable metals. Thus, the diffusion controlling step is inner diffusion, namely solid film diffusion controlling.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 3; 711-720
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Removal of vanadium, potassium and iron from spent vanadium catalyst by leaching with citric acid at atmospheric pressure
    Autorzy:
    Mazurek, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/778659.pdf
    Data publikacji:
    2014
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    citric acid
    sulphur oxide
    spent vanadium catalysts
    leaching
    recovery
    Opis:
    The effect of time, temperature, the catalyst particle size and the ratio of the catalyst weight to the leaching solution volume (S:L) on the treatment of spent vanadium catalyst components was determined using citric acid solutions at atmospheric pressure. The optimal parameters of catalyst leaching in 10% acid solutions at atmospheric pressure are: T = 323 K, t = 4 h, the particle size of less than 0.160 mm, the S:L ratio below 0.1. Under these conditions it was possible to dissolve about 90% of vanadium and potassium compounds and more than 60% of iron compounds contained in the catalyst. These results fall within the scope of research on a comprehensive method for recovering spent vanadium catalyst components.
    Źródło:
    Polish Journal of Chemical Technology; 2014, 16, 1; 59-62
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Leaching kinetics of iron from coal-series kaolin by oxalic acid solutions
    Autorzy:
    Shao, Hui
    Ji, Mengjiao
    Yu, Mingming
    Powiązania:
    https://bibliotekanauki.pl/articles/1449978.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    coal-series kaolin
    leaching kinetics
    iron removal rate
    oxalic acid
    Opis:
    Removal of iron from coal-series kaolinite and its kinetics by chemical leaching were investigated in this paper. The optimal removal rate of iron reaches 29.09% (the content of $Fe_2O_3$ decreased from 0.55 to 0.39%) under the conditions of 100 °C, 0.4 M $C_2H_2O_4$, and liquid-to-solid ratio of 4 cm3/g for 120 min. The leaching process was successfully described by the Avrami model and mainly controlled by internal diffusion control of shrinking core model, the apparent activation energy is 18.46 kJ/mol. The experimental results were consistent with the internal diffusion control of shrinking core model, improving acid concentration and leaching temperature could promotes the removal of iron from coal-series kaolin.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 1; 134-146
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Characterization and treatment of clayey waste using a sulfuric acid roasting-water leaching process for the extraction of lithium
    Autorzy:
    Obut, Abdullah
    Aktosun, Zeynep
    Girgin, İsmail
    Deveci, Hacı
    Yörükoğlu, Abdulkerim
    Powiązania:
    https://bibliotekanauki.pl/articles/2146902.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    Kırka boron plant
    lithium
    smectite
    sulfuric acid roasting
    water leaching
    Opis:
    In this study, a detailed characterization of the clayey waste of the Kırka boron plant was undertaken before the development of a sulfuric acid roasting-water leaching process for the extraction of lithium from this waste. The effects of roasting temperature (650-800°C) and sulfuric acid/waste ratio (90-260 kg H2SO4/1000 kg waste on a dry basis) on the extraction of lithium were investigated. By roasting the waste sample, which contained 0.37% Li2O with dolomite, smectite and borax as the main phases, at temperatures between 650°C and 800°C in the absence of sulfuric acid as the additive, CaMgSiO4 was found to form as the dominant phase after the decomposition of dolomite and smectite present in the sample. On the other hand, the X-ray diffraction analyses of the waste sample subjected to sulfuric acid treatment without roasting showed the in-situ formation of various hydrated calcium sulfate phases for all sulfuric acid/waste ratios tested. Besides, at the highest acid/waste ratio of 260, a hydrated magnesium sulfate phase was also identified in the sample. The application of the sulfuric acid roasting-water leaching process under the optimum roasting temperature of 750°C and the acid/waste ratio of 180 was found to lead to a lithium extraction of 85.7%. The applied sulfuric acid roasting-water leaching process appeared to be an attractive process with its attributes including low roasting temperature, high extraction percentage and no requirement for gypsum as the external sulfation agent.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149635
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Experimental and kinetic study of zinc leaching from metallurgical slag by 5-sulfosalicylic acid
    Autorzy:
    Wang, Long
    Gao, Hanyu
    Song, Shimin
    Xue, Na
    Zhang, Jinxia
    Yang, Siyuan
    Liu, Cheng
    Powiązania:
    https://bibliotekanauki.pl/articles/1447397.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    zinc metallurgical slag
    5-sulfosalicylic acid
    leaching kinetics
    resource recover
    Opis:
    As an organic acid with the characters of low corrosivity and extensive source, 5-sulfosalicylic acid (5-SSA) was firstly utilized as a potential leaching reagent for the recovery of zinc from metallurgical slag. Effects of stirring speed, leaching temperature, 5-SSA concentrations and size fraction on the leaching zinc leaching rate were investigated. A zinc leaching efficiency of 94.2% was achieved under the appropriate operating conditions (450 rpm of stirring speed, 50 ℃ of leaching temperature, 0.3 mol/L of 5-SSA concentration and d90=65 µm of size fraction), indicating that 5-SSA was an excellent leaching reagent of zinc oxide. SEM-EDS and specific surface aperture analyzer further reveal the well-developed micropores and cracks from zinc metallurgical slag, which could be assigned to the removal of zinc oxide encapsulated in the sample. In addition, the leaching kinetics of zinc metallurgical slag in the 5-SSA was studied. It was found that the surface chemical reaction model satisfactorily predicted the zinc leaching rate. A reaction kinetic equation was finally established for the zinc leaching rate.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 3; 8-20
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Considering the influence of calcium on EAF dust acid leaching
    Autorzy:
    Havlik, Tomas
    Miskufova, Andrea
    Turek, Peter
    Urban Kobialkova, Ivana
    Powiązania:
    https://bibliotekanauki.pl/articles/110605.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    EAF-dust
    leaching
    sulphuric acid
    industrial waste
    zinc
    iron
    calcium
    hydrometallurgy
    Opis:
    This work focuses on the hydrometallurgical processing of EAF steelmaking dust in laboratory conditions. The behavior of calcium under the influence of sulphuric acid as the leaching agent is discussed. Due to calcium presence the acid is continuously consumed, gradually leaching the calcium phase from EAF dust as well as other zinc- and iron-containing phases. A thorough composition analysis of the input sample of EAF dust was performed. A kinetic study of calcium showed that its leaching is a very fast process, but most of the calcium reacting with sulphuric acid is precipitated from the solution in the form of CaSO4∙2H2O. This causes greater sulphuric acid consumption, and therefore it is necessary to study the calcium behavior during processing of EAF dust. This work is narrowed with calcium behavior during leaching of EAF dust in sulphuric acid and effect of calcium to extraction other metals into solution.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 2; 528-536
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A study on the dissolution kinetics of iron oxide leaching from clays by oxalic acid
    Autorzy:
    Arslan, Volkan
    Powiązania:
    https://bibliotekanauki.pl/articles/1447278.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    clay
    physico-chemical characterization
    chemical leaching
    oxalic acid
    dissolution kinetics
    activation energy
    Opis:
    Clay is widely used in a number of industries due to its special properties like fine particle size, brightness and whiteness, chemical inertness, platy structure, etc. In this study, the general characteristics of clays have been investigated by XRF, XRD, FT-IR, TG-DTA and SEM. The presence of iron as an impurity decreases its commercial value due to giving unwanted colors to clay mineral. Therefore, the dissolution capacity of clay ore was investigated by oxalic acid leaching. Under optimized leaching conditions (0.8 M oxalic acid concentration, 85°C reaction temperature, 1.75 ambient pH, 106+75 µm particle size, 15% w/v solids concentration and 150 min. leaching time) with 250 rpm stirring, 83.90% of $Fe_2O_3$ was removed. The amount of iron oxide, the main impurity in the clay, has been reduced from 2.70 to 0.40%. The iron dissolution kinetics was mainly controlled by internal diffusion control of shrinking core model and activation energy, $E_a$, of 26.29 kJ/mol was obtained for the process. The results also showed that the studied clays have adequate characteristics for ceramics industry, earthenware and porcelain production.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 3; 97-111
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Recovery of copper from copper slag and copper slag flotation tailings by oxidative leaching
    Autorzy:
    Urosevic, D. M.
    Dimitrijevic, M. D.
    Jankovic, Z. D.
    Antic, D. V.
    Powiązania:
    https://bibliotekanauki.pl/articles/109899.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    copper slag
    copper slag flotation tailings
    leaching
    sulphuric acid
    ferric sulphate
    hydrogen peroxide
    Opis:
    Copper smelter slag and copper smelter slag flotation tailings were leached using sulphuric acid solutions, without or with the addition of either ferric sulphate or hydrogen peroxide. Copper extraction from the slag was typically found to be twice as high as that from the slag flotation tailings. Hydrogen peroxide was determined to be the best lixiviant. Thus, copper and iron extractions were 63.4% and 48.6%, respectively, when leaching the slag with 3 M H2O2, after 120 minutes of reaction at room temperature. Copper dissolution was generally found to be the dominant process within the first 60 minutes of reaction, whereas iron dissolution dominated afterwards.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2015, 51, 1; 73-82
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Utilization of used contact masses from the oxidation state of sulfur(IV) oxide to suIfur(VI) oxide
    Autorzy:
    Trypuć, M.
    Mazurek, K.
    Kiełkowska, U.
    Drużyński, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/777950.pdf
    Data publikacji:
    2007
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    kwas siarkowy
    tlenek siarki
    mocznik
    katalizator wanadowy
    ługowanie
    sulfuric acid
    sulfur oxide
    urea solutions
    used vanadium catalysts
    leaching process
    Opis:
    The research was conducted to determine the influence of the urea concentration in the leaching solutions on the efficiency of recovery of vanadium and iron compounds from the used vanadium catalyst from the node of oxidation of sulfur dioxide to sulfur trioxide.
    Źródło:
    Polish Journal of Chemical Technology; 2007, 9, 3; 26-28
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Extraction of vanadium compounds from the used vanadium catalyst with the potassium hydroxide solution
    Autorzy:
    Mazurek, K.
    Białowicz, K.
    Trypuć, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/778384.pdf
    Data publikacji:
    2010
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    katalizator wanadowy
    ługowanie
    wanad
    żelazo
    kwas siarkowy
    wodorotlenek potasu
    vanadium catalyst
    leaching
    recovery
    vanadium
    iron
    sulfuric acid
    potassium hydroxide
    Opis:
    The paper presents the results of the research on the degree of the recovery of vanadium(V) from the used vanadium catalyst with the use of KOH solution. The extraction was performed at 293 - 323 K, for 0.5 to 4 h and the catalysts of the variable grain diameter. The concentration of the extracting solution was varied in the range 5 - 20%. The optimal ratio of solid to liquid phase S/L was determined. Additionally the degree of the recovery of total iron ions was presented.
    Źródło:
    Polish Journal of Chemical Technology; 2010, 12, 1; 23-28
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The influence of leaching solution pH and addition of peroxide hydrogen on the recovery of some components from the used vanadium catalyst with urea solutions
    Autorzy:
    Mazurek, K.
    Trypuć, M.
    Białowicz, K.
    Drużyński, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/779484.pdf
    Data publikacji:
    2008
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    kwas siarkowy
    tlenek siarki
    mocznik
    katalizator wanadowy
    ługowanie
    sulfuric acid
    sulfur oxide
    urea solutions
    used vanadium catalysts
    leaching process
    Opis:
    The research was conducted to determine the influence of the pH of the leaching solutions and hydrogen peroxide addition on the efficiency of the recovery of vanadium, potassium and iron compounds from the used vanadium catalyst from the node of oxidation of sulfur dioxide to sulfur trioxide.
    Źródło:
    Polish Journal of Chemical Technology; 2008, 10, 4; 34-36
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Extraction of vanadium and potassium compounds from the spent vanadium catalyst from the metallurgical plant
    Autorzy:
    Mazurek, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/779744.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    kwas siarkowy
    tlenek siarki
    katalizatory wanadu
    ługowanie
    wanad
    potas
    miedź
    cynk
    arsen
    ołów
    XRF
    sulfuric acid
    sulfur oxide
    spend vanadium catalysts
    leaching
    recovery
    vanadium
    potassium
    copper
    zinc
    arsenic
    lead
    Opis:
    A spent vanadium catalyst, from the plant of metallurgical type, was leached in a sulfuric acid solution to recover vanadium and potassium compounds. The effect of time, temperature, concentration of acid, catalyst particle size and phase ratio was studied. Additionally the concentration of iron, copper, zinc, arsenic and lead compounds was determined. The flow sheet for the proposed process of spent vanadium catalyst leaching is presented.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 2; 49-53
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ocena wielkości wymywania jonów K+, Ca2+ i Mg2+ w wybranych drzewostanach w warunkach kwaśnej depozycji
    Assessment of K+, Ca2+ and Mg2+ volume leaching in selected tree stands under conditions of acidic deposition
    Autorzy:
    Kozłowski, R.
    Jóźwiak, M.
    Jóźwiak, M.A.
    Bochenek, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/1008701.pdf
    Data publikacji:
    2012
    Wydawca:
    Polskie Towarzystwo Leśne
    Tematy:
    lesnictwo
    gory
    Gory Swietokrzyskie
    Beskid Niski
    pogorze
    drzewostany
    sklad gatunkowy
    jony wapnia
    jony magnezu
    jony potasu
    wymywanie jonow
    depozycja kwasna
    zanieczyszczenia powietrza
    zanieczyszczenia chemiczne
    opady atmosferyczne
    odczyn opadow atmosferycznych
    acid deposition
    forest ecosystems
    canopy leaching
    throughfall
    stemflow
    Opis:
    The study was conducted in the central part of the Świętokrzyskie Mountains as well as in the Beskid Niski Mountains in the years 2008−2010. Canopy budget model according to Ulrich was used. Paper presents analysis and assessment of the differences between two forest ecosystems under of acidic deposition.
    Źródło:
    Sylwan; 2012, 156, 08; 607-615
    0039-7660
    Pojawia się w:
    Sylwan
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-45 z 45

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