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Tytuł:
Effect of Pre-Sintering on the Diffusion Treatment of HRE for Coercivity Enhancement of a NdFeB Sintered Magnet
Autorzy:
Lee, M. W.
Lee, J. K.
Jang, T. S.
Powiązania:
https://bibliotekanauki.pl/articles/355250.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
grain boundary diffusion process
GBDP
NdFeB magnet
coercivity
pre-sintering
Opis:
We investigated the effect of pre-sintering process on the penetration behavior of Dy in a NdFeB sintered magnet which was grain boundary diffusion treated with Cu/Al mixed Dy source. The pre-sintering of a magnet was performed at 900°C in vacuum and then the pre-sintered body was dipped in the solutions of DyH2, DyH2 + Cu, and DyH2 + Al, respectively. The dipped pre-sintered body were then fully sintered 4 hours at 1060°C followed by a subsequent annealing. The pre-sintering apparently improved the diffusivity of Dy atoms. The penetration of Dy into the magnet extended almost to 2,000 μm from the surface, about four times deeper than that of the normally sintered and diffusion treated one, when the DyH2 + Al solution was used as a Dy source. However, the resulting increase of coercivity was about 4 kOe, somewhat lower than that of the normally treated one, mostly due to excessive oxide formation that hindered to make a continuous Nd-rich grain boundary phase and a core-shell type structure.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 2; 597-601
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics Of The Porous Body Sintered By Nano-Sized Fe-Cr-Al Alloy Powder
Charakterystyka porowatego korpusu spiekanego z nanometrycznego proszku stopu Fe-Cr-Al
Autorzy:
Lee, S.-I.
Lee, S.-H.
Gu, B.-U.
Lee, D.-W.
Kim, B.-K.
Powiązania:
https://bibliotekanauki.pl/articles/356635.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Fe-Cr-Al powder
metallic sponges
sintering temperature
oxidation resistance
proszek Fe-Cr-Al
proszek nanometryczny
temperatura spiekania
odporność na utlenianie
Opis:
Porous metal with uniform honeycomb structure was successfully produced by sintering using Fe-Cr-Al nano powder, which was prepared by the pulsed wire evaporation (PWE) in ethanol. Its process consisted of the several steps; 1) coating on the surface of polyurethane sponge with the liquid droplets generated from the ethanol-based slurry where the Fe-Cr-Al nano powders were uniformly dispersed, 2) heat treatment of debinding to remove the polyurethane sponge and 3) sintering of the porous green body formed by Fe-Cr-Al nano powders. The strut thickness of porous Fe-Cr-Al was increased by the increase of spraying times in ESP step. Also, The shrinkages and the oxidation resistance of the sintered porous body was increased with increase of sintering temperature. The optimal sintering temperature was shown to 1450°C in views to maximize the oxidation resistance and sinterability.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1275-1279
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure and Magnetic Properties of NdFeB Sintered Magnets Diffusion-Treated with Cu/Al Mixed Dyco Alloy-Powder
Autorzy:
Lee, M.-W.
Bae, K.-H.
Lee, S.-R.
Kim, H.-J.
Jang, T.-S.
Powiązania:
https://bibliotekanauki.pl/articles/353351.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Nd-Fe-B sintered magnets
grain boundary diffusion process
low melting point element
DyCo alloy-powder diffusion
Opis:
We investigated the microstructural and magnetic property changes of DyCo, Cu + DyCo, and Al + DyCo diffusion-treated NdFeB sintered magnets. The coercivity of all diffusion treated magnet was increased at 880ºC of 1st post annealing(PA), by 6.1 kOe in Cu and 7.0 kOe in Al mixed DyCo coated magnets, whereas this increment was found to be relatively low (3.9 kOe) in the magnet coated with DyCo only. The diffusivity and diffusion depth of Dy were increased in those magnets which were treated with Cu or Al mixed DyCo, mainly due to comparatively easy diffusion path provided by Cu and Al because of their solubility with Ndrich grain boundary phase. The formation of Cu/Al-rich grain boundary phase might have enhanced the diffusivity of Dy-atoms. Moreover, relatively a large number of Dy atoms reached into the magnet and mostly segregated at the interface of Nd2 Fe14 B and grain boundary phases covering Nd2 Fe14 B grains so that the core-shell type structures were developed. The formation of highly anisotropic (Nd, Dy)2Fe14B phase layer, which acted as the shell in the core-shell type structure so as to prevent the reverse domain movement, was the cause of enhancing the coercivity of diffusion treated NdFeB magnets. Segregation of cobalt in Nd-rich TJP followed by the formation of Co-rich phase was beneficial for the coercivity enhancement, resulting in the stabilization of the metastable c-Nd2O3 phase.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1263-1266
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation Of Fine Grained SiC At Reduced Temperature By Two-Step Sintering
Wytwarzanie drobnoziarnistego SiC w obniżonej temperaturze przez dwuetapowe spiekanie
Autorzy:
Kim, K.-W.
Oh, K.-S.
Lee, H.
Kim, B. S.
Chung, T.-J.
Powiązania:
https://bibliotekanauki.pl/articles/353772.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
SiC
liquid phase
two step sintering
coarsening
hardness
faza ciekła
spiekanie dwuetapowe
odporność
twardość
Opis:
Two-step sintering route was applied for the densification SiC by promoting the role of liquid phase. The specimen contained 8 vol% of liquid phase composed of Al2O3 and Y2O3. The heating schedule consisted with initial rapid heating to 2000°C and immediate quenching to 1700 or 1750°C. By heating at elevated temperature, even distribution of the liquid phase was intended. The heat treatment at reduced temperature was to suppress the evaporative loss of the liquid and to secure the time for densification. The two-step sintering effectively suppressed loss of mass and coarsening. The resultant SiC was thus dense and was composed of fine grains exhibiting hardness of 2321 kgf/mm2.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1539-1542
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects Of Environmental Factors On The Dispersion Behavior Of Iron Oxide In Aqueous Solutions With Poly Acrylic Acid
Wpływ parametrów charakteryzujących wodne roztwory poli(kwasu akrylowego) na dyspersję tlenku żelaza
Autorzy:
Lee, E.-H.
Kim, K.-M.
Maeng, W.-Y.
Hur, D.-H.
Powiązania:
https://bibliotekanauki.pl/articles/354513.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
polyacrylic acid
dispersion stability
magnetite
nanoparticles
suspension
poli(kwas akrylowy)
stabilność dyspersji
magnetyt
nanocząstki
zawiesina
Opis:
After preparing aqueous suspensions from magnetite particles with a poly-acrylic acid, we investigated the effects of several experimental parameters. We characterized the stability of the suspensions using visual inspection, sedimentation, adsorption, and thermal stability of the dispersant. The dispersion stability is affected by the solution pH, the concentrations of magnetite particles, the molecular weight, the concentration of the dispersants, and the temperature. The stability of the suspensions increased as the concentration of the dispersant and the temperature increased. In terms of the molecular weights of the dispersant, the suspensions with dispersant of low-molecular weight (1800) were more stable than those of high-molecular weight (250000) at room temperature. However, at high temperature the suspensions with high-molecular weight showed stability. The adsorption efficiency of the dispersant was very low. The dispersant of high-molecular weight showed a higher thermal integrity than that of low-molecular weight. From this work, we obtained the optimum conditions for stable aqueous suspensions of magnetite particles.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1561-1564
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation Mechanism of Ti5Si3 Compact Obtained by Electro-Discharge-Sintering Directly from Physically Blended Ti-37.5 At.% Si Powder Mixture
Autorzy:
Chang, S. Y.
Cheon, Y. W.
Yoon, Y. H.
Kim, Y. H.
Kim, J. Y.
Lee, Y. K.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/353022.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sintering
mechanical alloying
powder consolidation
intermetallic compounds
titanium silicide
Opis:
Characteristics of electro-discharge-sintering of the Ti-37.5at.% Si powder mixture was investigated as a function of the input energy, capacitance, and discharge time without applying any external pressure. A solid bulk of Ti5Si3 was obtained only after in less than 129 μsec by the EDS process. During a discharge, the heat is generated to liquefy and alloy the particles, and which enhances the pinch pressure can condensate them without allowing a formation of pores. Three step processes for the self-consolidation mechanism during EDS are proposed; (a) a physical breakdown of oxide film on elemental as-received powder particles, (b) alloying and densifying the consolidation of powder particles by the pinch pressure, and (c) diffusion of impurities into the consolidated surface.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1299-1302
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spontaneous Formation of Titanium Nitride on the Surface of a Ti Rod Induced by Electro-Discharge-Heat-Treatment in an N2 Atmosphere
Autorzy:
Lee, W. H.
Yoon, Y. H.
Kim, Y. H.
Lee, Y. K.
Kim, J. Y.
Chang, S. Y.
Powiązania:
https://bibliotekanauki.pl/articles/352477.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium
surface modification
diffusion
heat treatment
XPS
Opis:
A single pulse of 2.0 to 3.5 kJ of input energy from a 450 mF capacitor was applied to a commercially pure Ti rod in a N2 atmosphere. The surface of the Ti rod transformed from TiO2 into titanium nitride in times as short as 159 msec, providing a bimodal morphology of the cross-section. A much higher value of hardness that was observed at the edge of the cross-section was attributed to nitrogen-induced solid-solution hardening that occurred during the electrical discharge process. The activation energy (Ea) for the diffusion process was estimated to be approximately 86.9 kJ/mol. Results show that the electrical discharge process is a possible potential method for the nitriding of Ti; advantages include a short processing time and control of the nitrided layer without dimensional changes.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1281-1285
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation and Surface Modification of Mechanical Alloyed Ti-25.0 at.% Al Powder Mixture by Using an Electro-Discharge Technique
Autorzy:
Chang, S. Y.
Jang, H. S.
Yoon, Y. H.
Kim, Y. H.
Kim, J. Y.
Lee, Y. K.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/354212.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sintering
mechanical alloying
powder consolidation
intermetallic compounds
titanium aluminides
Opis:
Electrical discharges using a capacitance of 450 μF at 0.5, 1.0, and 1.5 kJ input energies were applied in a N2 atmosphere to obtain the mechanical alloyed Ti3Al powder without applying any external pressure. A solid bulk of nanostructured Ti3Al was obtained as short as 160 μsec by the Electrical discharge. At the same time, the surface has been modified into the form of Ti and Al nitrides due to the diffusion process of nitrogen to the surface. The input energy was found to be the most important parameter to affect the formation of a solid core and surface chemistry of the compact.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1293-1297
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High-temperature Oxidation Behavior and Kinetics of Forged 12Cr-MoVW Steel
Autorzy:
Kim, Y. H.
Oak, J.-J.
Bae, K.-C.
Lee, W-J.
Park, Y. H.
Powiązania:
https://bibliotekanauki.pl/articles/351450.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ferritic/martensitic stainless steels
forging
oxidation kinetics
oxide layer
Opis:
The oxidation kinetics of forged 12Cr-MoVW steel was investigated in an air (N2+O2) atmosphere at 873-1073 K (Δ50 K) using thermogravimetric analysis. The oxidized samples were characterized using X-ray diffraction, and the surface and cross-sectional morphologies were examined using scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. The forged 12Cr-MoVW steel samples exhibited parabolic behavior and a low oxidation rate compared with their as-cast counterparts. A protective oxide layer was uniformly formed at relatively low temperature (≤973 K) for the forged samples, which thus exhibited better oxidation resistance than the as-cast ones. These oxides are considered solid-solution compounds such as (Fe, Cr)2O3.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1099-1104
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication and Characterization of CoCrFeNiMn High Entropy Alloy Powder Processed by Gas Atomization
Autorzy:
Park, T. G.
Lee, S. H.
Lee, B.
Cho, H. M.
Choi, W. J.
Kim, B. S.
Shin, K. S.
Kim, T.-S.
Powiązania:
https://bibliotekanauki.pl/articles/353649.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high entropy alloy
gas atomization
spark plasma sintering
CoCrFeNiMn
Opis:
In this study, precisely controlled large scale gas atomization process was applied to produce spherical and uniform shaped high entropy alloy powder. The gas atomization process was carried out to fabricate CoCrFeNiMn alloy, which was studied for high ductility and mechanical properties at low temperatures. It was confirmed that the mass scale, single phase, equiatomic, and high purity spherical high entropy alloy powder was produced by gas atomization process. The powder was sintered by spark plasma sintering process with various sintering conditions, and mechanical properties were characterized. Through this research, we have developed a mass production process of high quality and spherical high entropy alloy powder, and it is expected to expand applications of this high entropy alloy into fields such as powder injection molding and 3D printing for complex shaped components.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 1055-1059
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect Of The Desorption-Recombination Temperature On The Microstructure And Magnetic Properties Of HDDR Processed Nd-Fe-B Powders
Wpływ temperatury desorpcji-rekombinacji na mikrostrukturę i właściwości magnetyczne proszków Nd-Fe-B przetwarzanych metodą HDDR
Autorzy:
Lee, J.-G.
Cha, H.-R.
Liu, S.
Yu, J.-H.
Baek, Y.-K.
Kwon, H.-W.
Powiązania:
https://bibliotekanauki.pl/articles/353723.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Nd-Fe-B
HDDR
permanent magnet
grain boundary
metoda HDDR
magnes trwały
granica ziarna
Opis:
The effect of the desorption-recombination temperature on the microstructure and magnetic properties of hydrogenation-disproportionation-desorption-recombination (HDDR) processed Nd-Fe-B powders was studied. The NdxB6.4Ga0.3Nb20.2Febal (x=12.5-13.5, at.%) casting alloys were pulverized after homogenizing annealing, and then subjected to HDDR treatment. During the HDDR process, desorption-recombination (DR) reaction was induced at two different temperature, 810°C and 820°C. The higher Nd content resulted in enhanced coercivity of the HDDR powder, and which was attributed to the thicker and more uniform Nd-rich phase along grain boundaries. But this uniform Nd-rich phase induced faster grain growth. The remanence of the powder DR-treated at 820°C is higher than that DR-treated at 810°C. In addition, it was also confirmed that higher DR temperature is much more effective to improve squareness.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1499-1501
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface Modification of Self-Consolidated Microporous Ti Implant Compacts Fabricated by Electro-Discharge-Sintering in Air
Autorzy:
Jo, Y. J.
Yoon, Y. H.
Kim, Y. H.
Chang, S. Y.
Kim, J. Y.
Lee, Y. K.
Van Tyne, C. J.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/356790.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium
implant
porous
sintering
X-ray photoelectron spectroscopy (XPS)
Opis:
A single pulse of 0.75-2.0 kJ/0.7g of atomized spherical Ti powders from 300 mF capacitor was applied to produce a microporous Ti implant compact by electro-discharge-sintering (EDS). A solid core in the middle of the compact surrounded by a microporous layer was found. X-ray photoelectron spectroscopy was employed to study the surface characteristics of the EDS Ti compact and it revealed that Ti, C and O were the main constituents on the surface with a smaller amount of N. The surface was lightly oxidized and was primarily in the form of TiO2 resulting from the air oxidation during EDS processing. The lightly oxidized surface of the EDS compact also exhibited Ti nitrides such as TiN and TiON, which revealed that the reaction between air constituents and the Ti powders even in times as short as 128 msec.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1287-1291
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Compositional Dependence of Hardness of Ge-Sb-Se Glass for Molded Lens Applications
Zależność stężeniowa twardości szkła Ge-Sb-Se do zastosowań na formowane soczewki
Autorzy:
Park, J. K.
Lee, J. H.
Shin, S. Y.
Yi, J. H.
Lee, W. H.
Park, B. J.
Choi, J. H.
Kim, N. Y.
Choi, Y. G.
Powiązania:
https://bibliotekanauki.pl/articles/352228.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
chalcogenide glasses
Ge-Sb-Se glass
infrared lens
molded lens
infrared camera
szkło
Ge-Sb-Se
soczewki formowane
twardość szkła
kamera termowizyjna
Opis:
Chalcogenide glass in the ternary Ge-Sb-Se system is inherently moldable, thus being considered as a strong candidate material for use in infrared-transmitting lens applications from the viewpoint of thermal and mechanical stability. In an effort to experimentally determine compositional region suitable for the molded lens applications, we evaluate its compositional dependence of hardness. Among the constituent atoms, Ge content turns out to exert a most conspicuous correlation with hardness. This phenomenological behavior is then explained in connection with the structural evolution that Ge brings about.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1205-1208
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication of a Spherical Titanium Powder by Combined Combustion Synthesis and DC Plasma Treatment
Autorzy:
Choi, S. H.
Ali, B.
Hyun, S. K.
Sim, J. J.
Choi, W. J.
Joo, W.
Lim, J. H.
Lee, Y. J.
Kim, T. S.
Park, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/356067.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
combustion synthesis
DC plasma treatment
titanium powder
3D printing process
combustion parameters
Opis:
Combustion synthesis is capable of producing many types of refractory and ceramic materials, as well as metals, with a relatively lower cost and shorter time frame than other solid state synthetic techniques. TiO2 with Mg as reductant were dry mixed and hand compacted into a 60 mm diameter mold and then combusted under an Ar atmosphere. Depending on the reaction parameters (Mg concentration 2 ≤ α ≤ 4), the thermocouples registered temperatures between 1160°C and 1710°C . 3 mol of Mg gave the optimum results with combustion temperature (Tc) and combustion velocity (Uc) values of 1372°C and 0.26 cm/s respectively. Furthermore, this ratio also had the lowest oxygen concentration in this study (0.8 wt%). After combustion, DC plasma treatment was carried out to spheroidize the Ti powder for use in 3D printing. The characterization of the final product was performed using X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, and N/O analysis.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1057-1062
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reaction Kinetics and Morphological Study of TiNb2O7 Synthesized by Solid-State Reaction
Autorzy:
Choi, S. H.
Ali, B.
Choi, K. S.
Hyun, S. K.
Sim, J. J.
Choi, W. J.
Joo, W.
Lim, J. H.
Lee, T. H.
Kim, T. S.
Park, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/355326.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
solid state reaction
kinetic analysis
quantitative phase analysis
TiNb2O7 synthesis
Opis:
Although TiNb2O7 is regarded as a material with high application potential in lithium-ion batteries (LIBs) and solid-oxide fuel cells (SOFCs), it has been difficult to find suitable cost-effective conditions for synthesizing it on a commercial scale. In this study, TiNb2O7 compounds were synthesized by a solid state synthesis process. For stoichiometrically precise synthesis of the TiNb2O7 phase, the starting materials, TiO2 and Nb2O5 were taken in a 1:1 molar ratio. Activation energy and reaction kinetics of the system were investigated at various synthesis temperatures (800,1000,1200, and 1400°C) and for various holding durations (1,5,10, and 20 h). Furthermore, change in the product morphology and particle size distribution were also evaluated as a function of synthesis temperature and duration. Additionally, quantitative phase analysis was conducted using the Rietveld refinement method. It was found that increases in the synthesis temperature and holding time lead to increase in the mean particle size from 1 to 4.5 μm. The reaction rate constant for the synthesis reaction was also calculated.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1051-1056
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
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