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Tytuł:
Study of the influence of the binary mixtures of fluorocarbon surfactants on the surface tension of water
Autorzy:
Taraba, Anna
Szymczyk, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/764007.pdf
Data publikacji:
2017
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
fluorocarbon surfactants, surface tension, binary mixtures of surfactants
Opis:
Influence of the binary mixtures of fluorocarbon surfactants Zonyl FSO-100  (FSO100) and Zonyl FSN-100 (FSN100) on the surface tension of the water was studied. The effectiveness of adsorption process of the surfactant at the water-air interface was calculated from the obtained values of the surface tension of studied mixtures. Also the maximum surface area per molecule of surfactant in the interfacial area  and the free energy at the water-air interface  were determined. Moreover, the existence of synergetizm or antagonism effect, which reduces the surface tension of the water was examined. On the basis of the Rosen's model parameter the values of intermolecular interactions in the mixed monolayer adsorption were calculated.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2017, 72, 1
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The use of surfactant from the Tween group in toluene biofiltration
Autorzy:
Miller, Urszula
Sówka, Izabela
Adamiak, Waldemar
Powiązania:
https://bibliotekanauki.pl/articles/205431.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
toluene
surfactants
biofiltration
VOC
Opis:
Due to the lower energy consumption and waste production compared to traditional methods, the environmental bioremediation methods based on natural processes have been gradually becoming more prevalent in environmental engineering. Biological methods are used in waste management, wastewater treatment, gas treatment or soil remediation. For the low solubility of some pollutants and lower bioavailability, the use of biological methods may be hampered. This problem might be mitigated with the use of surfactants. This paper presents the results of studies regarding the effect of dosing a selected surfactant from the Tween group (Tween 20) on the efficiency of toluene elimination from the air by biofiltration. The obtained maximum biofiltration rate was 21.2 g/m3/h and 19.8 g/m3/h for the control bed and for the bed to which the Tween 20 solution was dosed, respectively. The effect of Tween was neutral (the effectiveness of toluene removal was insignificantly comparable to the effectiveness of the control series), it did not affect the effectiveness or limited the development of the biofilter microflora.
Źródło:
Archives of Environmental Protection; 2020, 46, 2; 53-57
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zastosowanie spektometrii UV-Vis do oznaczania surfaktantów anionowych
Application of UV-Vis spectrometryfor determination of anional surfactants
Autorzy:
Hernet, Julia
Czyżewska, Magda
Kilimnik, Sebastian
Powiązania:
https://bibliotekanauki.pl/articles/2055888.pdf
Data publikacji:
2019
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydawnictwo PB
Tematy:
surfaktanty
surfaktanty anionowe
spektrofotometria UV-Vis
surfactants
anionic surfactants
UV-Vis spectrophometry
Opis:
W dzisiejszych czasach dążenia do życia bardziej ekologicznego bardzo ważnym aspektem jest kontrolowanie szkodliwego wpływu związków chemicznych na nasz ekosystem. Surfaktanty to grupa związków, która jest stosowana bardzo powszechnie w wielu gałęziach przemysłu, dziedzinach życia codziennego, a także w badaniach laboratoryjnych. Mają jednak negatywny wpływ na środowisko naturalne, dlatego nadal trwają badania nad tymi związkami. W artykule przedstawiono zagadnienia dotyczące zastosowania metod spektroskopii do oznaczania surfaktantów anionowych, wykorzystywanych zarówno w przemyśle maszynowym, samochodowym i elektronicznym, jak i przy produkcji artykułów spożywczych, kosmetycznych i włókienniczych.
Nowadays striving for a greener life is a very important aspect of controlling the harmful effects of chemical compounds on our ecosystem. Surfactants are a group of compounds that is widely used in many areas of daily life and laboratory tests. In contrast to their wide spectrum of applications, their negative impact on the environment stands, which is why research on these compounds is still ongoing. The article presents issues related to the use of spectroscopy methods for the determination of anionic surfactants, which are widely used both in the machinery, automotive and electronics industries, as well as in the production of food, cosmetics and textile.
Źródło:
Postępy w Inżynierii Mechanicznej; 2019, nr 14(7); 105--113
2300-3383
Pojawia się w:
Postępy w Inżynierii Mechanicznej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ surfaktantów niejonowych na koalescencję kropel
Influence of non-ionic surfactants on drops coalescence
Autorzy:
Bąk, A.
Pacholewska, A.
Podgórska, W.
Powiązania:
https://bibliotekanauki.pl/articles/2070592.pdf
Data publikacji:
2009
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
koalescencja
surfaktanty niejonowe
surfaktanty polimerowe
Tween 20
PVA
coalescence
nonionic surfactants
polymeric surfactants
Opis:
Rozważono proces koalescencji kropel toluenu w układzie z surfaktan-tem niejonowym Tween 20 i z surfaktantem polimerowym PVA. Z analizy wyników można przypuszczać, że mimo obecności środka po-I wierzchniowo czynnego powierzchnie dużych kropel pozostajączęścio-wo ruchliwe w przeciwieństwie do nieruchomych powierzchni kropel małych. Zwiększając stężenia PVA i Tweenu 20 otrzymano lepszą stabilizację dyspersji.
Coalescence of toluene droplets in the system containing non-ionic surfactant Tween 20 and polymeric surfactant PVA was considered. According to the received results it is supposed that, in spite of the presence of surface active agents, larger droplets have partially mobile interfaces while the smallest ones are immobilized. The increase of the Tween 20 and PVA concentration results in better stabilization of liquid — liquid dispersions.
Źródło:
Inżynieria i Aparatura Chemiczna; 2009, 6; 23-24
0368-0827
Pojawia się w:
Inżynieria i Aparatura Chemiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison between surface and volumetric properties of short-chain alcohols and some classical surfactants
Autorzy:
Bielawska, Magdalena
Zdziennicka, Anna
Jańczuk, Bronisław
Powiązania:
https://bibliotekanauki.pl/articles/764079.pdf
Data publikacji:
2016
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
alcohols, surfactants, micelles, aggregates, CMC
Opis:
Measurements of the dynamic surface tension of the aqueous solutions of methanol, ethanol, propanol, CTAB and SDDS at their given concentrations were made. From the obtained results and the literature data it was concluded that the adsorption of short-chain alcohols at the water-air interface is somewhat similar to that of classical surfactants. For that reason the relationship between the Gibbs standard free energy of adsorption of short-chain alcohols and classical surfactants at that interface was established. The correlation between the chemical potential of mixing of alcohols and surfactants was also analysed. This analysis concerned the critical aggregation concentration (CAC) of alcohols and the critical micelle concentration (CMC) of surfactants. The chemical potential of surfactant mixing was calculated from the literature CMC data for the homologous series of alkyl sulfates, alkyl sulfonates, alkyl ammonium chlorides, alkyl trimethylammonium bromides, and alkyl pyridinium bromides. The influence of the hydrophobic chain length of alcohol and surfactant molecules on the Gibbs standard free energy of their adsorption at the water-air interface and their chemical potential of mixing were considered. It appeared that there is a linear dependence between these thermodynamic functions and the number of carbon atoms increased by 1 in the hydrocarbon chains of these compounds. This confirms clearly our conclusion that the behaviour of short-chain alcohols and classical surfactants at the water-air interface and in the bulk phase of aqueous solutions is similar. 
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2016, 71, 1
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bioługowanie metali ciężkich z odpadów pogalwanicznych przy neutralnym pH środowiska, w obecności bakterii produkujących biosurfaktanty
Bioleaching of heavy metals from galvanic wastes at neutral pH in the presence of biosurfactant producing bacteria
Autorzy:
Karwowska, E.
Andrzejewska-Morzuch, D
Powiązania:
https://bibliotekanauki.pl/articles/1819284.pdf
Data publikacji:
2012
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
microbial surfactants
sludge
extraction
acid
Opis:
Precipitates and sludges from the galvanic industry are one of the sources of the environment contamination with heavy metals. Therefore, the investigations are carried out in order to developer the effective method of metals elimination from these wastes. The promising results are obtained in case of the application of microbial leaching. Up to now results concerned mainly the metals bioleaching in acidic environment. In this research work the possibility of heavy metals removal from galvanic wastes using the culture of sulphur oxidizing bacteria (pH 2-4) and a mixed culture of both sulphur oxidizing bacteria and biosurfactant producing bacteria (pH 6.5-8) was examined. It allowed to compare the process effectiveness in acidic and neutral environment. The cultures were prepared based on the activated sludge from the municipal wastewater treatment plant. The presence of sulphur oxidizing bacteria Acidithiobacillus ferrooxidans was confirmed using the PCR method. Bacillus subtilis and B. cereus strains were applied as biosurfactant producers. Three galvanic wastes, different in grain size, water content and heavy metal concentration, were bioleached. The research revealed that the metal release from galvanic wastes was more effective in presence of biosurfactant, especially in case of copper, but also for cadmium and chromium. The process effectiveness in acidic condition was comparatively lower. Zinc was the only metal that was bioleached faster in acidic environment, with similar final metal removal after 25 days of the process. The maximum values of metals elimination in the presence of biosurfactant depended on the bioleached waste type and were: 7.1-100% for copper, 3.7-50.3% for zinc, 30-50.5% for chromium, 34.1-71.9% for cadmium. The effectiveness of the nickel and lead removal was lower than 5%. The prolongation of the bioleaching period up to 40 days in case of waste C (the less susceptible to the bioleaching) resulted in elimination of 67.9% of Cu, 34.7% of Zn, 100% of Cr and 39.1% of Pb, while the effectiveness of nickel removal was still very low.
Źródło:
Rocznik Ochrona Środowiska; 2012, Tom 14; 597-606
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Współczesne surfaktanty i ich struktury micelarne tworzone w roztworach wodnych
Currently available surfactants and their micellar structures formed in aqueous solutions
Autorzy:
Jakubowska, A.
Powiązania:
https://bibliotekanauki.pl/articles/172031.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
surfaktanty
ciecze jonowe
surfaktanty funkcjonalizowane surfaktanty polimerowe
techniki pomiarowe
struktury micelarne
surfactants
ionic liquids
functionalized surfactants
polymeric surfactants
measurement techniques
micellar structures
Opis:
This article presents currently available surfactant ionic liquids as well as functionalized and polymeric surfactants. Ionic liquids (ILs) are organic salts of melting points below 100°C. They have attracted much attention due to their unique physicochemical properties such as low volatility, high thermal stability, low toxicity, high ionic conductivity, capacity to dissolve organic, inorganic and polymeric materials [1]. ILs can be used as “green” solvents in electrochemistry, extraction, chromatography, catalysis, chemical and enzymatic reactions, and synthesis of new materials [2–4]. Ionic liquids are less corrosive than classical molten salts and therefore are used as electrolytes in batteries or solar cells [5]. Like other salts, ionic liquids are formed by ions but at least one of them is an organic ion. Moreover cations and anions differ significantly in their geometrical characteristics [1]. ILs with long alkyl chains and pronounced hydrophilic and lipophilic molecular fragments have an obvious amphiphilic nature and are called the surface active ionic liquids, SAILs, because they show combined properties of ILs and surfactants [6]. Recently, there is ever-increasing interest in SAILs based on gemini surfactants (Figs 6 and 7 [21, 22]), dodecyl sulfate, DS (Fig. 8a) and aerosol-OT, AOT (Fig. 8b) anions [23–25], alkylpyridinium (Fig. 1b [11]), imidazolium (Figs 1a and 3 [13, 14, 16]), alkylpyrrolidinium [17, 18], and diisopropylethylammonium, DIPEA [19] cations. Apart from SAILs, in recent years an attention has also been paid to functionalized surfactants such as: bolaform surfactants [32], supra-long chain surfactants [35, 36], calixarene-based surfactants (Fig. 9 [33]). Surfactants of the above types of SAILs and functionalized surfactants have been synthesized and their micellar structures formed in water have been studied. For example, very interesting vesicle systems were observed in aqueous solutions of diisopropylethylamine alkyl carboxylates, [DIPEA]+[CnH2n+1COO]–, for n = 3–9 (Fig. 5 [19]) and in aqueous solutions of the surfactant mixture composed of N-dodecyl-N-methyl-pyrrolidinium and sodium dodecyl sulfate (Fig. 4 [18]). It was found that 1-hexadecyl-3-methyl-imidazolium chloride in aqueous solutions underwent the phase (micellar) transformations upon cooling (Fig. 2 [13]). An important group of polymeric surfactants attracting a great interest in literature is that of triblock copolymers of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO), often abbreviated as [EO]a-[PO]b-[EO]a. Recently, these copolymers, also called poloxamers, have been proposed for pharmaceutical use [37–40]. These nonionic surfactants form micelles in aqueous solutions with a core containing the hydrophobic PO blocks and a shell made up of the hydrated EO blocks [41]. The subject of current studies include: the interactions between poloxamers and anionic surfactant, SDS in aqueous solutions [ 42–47], micellization of poloxamers in mixtures of water and organic solvents [48], comparison of association properties of diblock and triblock copolymers [49]. The paper also presents the experimental methods used recently to study surface activity, aggregation behaviors, and micellar structures of surfactants in water.
Źródło:
Wiadomości Chemiczne; 2013, 67, 11-12; 981-1001
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fertilizers and Pesticides Impact on Surface-Active Substances Accumulation in the Dark Gray Podzolic Soils
Autorzy:
Litvinova, Olena
Tonkha, Oksana
Havryliuk, Oleksandr
Litvinov, Dmytrо
Symochko, Lyudmyla
Dehodiuk, Stanislav
Zhyla, Roman
Powiązania:
https://bibliotekanauki.pl/articles/27323836.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
mineral fertilizer
soil
pesticides
anionic surfactants
non-ionic surfactants
crop rotation
biogenic elements
agroecosystem
Opis:
The article reports on a study that examined the impact of agrochemicals on the levels of surfactants in soil. Specifically, the study found that the use of mineral fertilizers and pesticides led to an increase in the levels of anionic surfactants (ASA) in the soil. Furthermore, the simultaneous application of fertilizers and pesticides had a greater effect on ASA levels than either factor alone. The use of pesticides also led to an increase in non-ionic surfactants (NSA), while the use of fertilizers resulted in a decrease in NSA levels. The study also found that the increase in the levels of mobile forms of key nutrients in the soil was associated with the accumulation of ASA in lower layers of the soil profile.The amount of alkaline hydrolyzed nitrogen under the low protection system increased by 3.0–23.2 mg kg-1 soil, mobile phosphorus by 14.0–144.0 mg P2O5, and exchangeable potassium by 9.0–222.0 mg K2O per kg soil, compared to the control. With the complex use of fertilizers and pesticides in one block, a trend of increasing mobile forms of nutrients in the soil was observed. The distribution of ASA amount in the soil profile is descending. The clear presence of ASA was established only in the soil layer of 0–40 cm. An increase of ASA content in the soil due to the use of agrochemicals and fertilizers is observed up to a depth of 60–80 cm. Using biological elements in agriculture significantly reduces the amount of these substances in the soil profile.
Źródło:
Journal of Ecological Engineering; 2023, 24, 7; 119--127
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Separation and concentration of cationic surfactant solutions with the use of ceramic modules
Autorzy:
Klimonda, Aleksandra
Kowalska, Izabela
Powiązania:
https://bibliotekanauki.pl/articles/207592.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
surfaktanty
nanofiltracja
membrana
surfactants
nanofiltration
membrane
Opis:
This paper presents the findings of experimental research on employing ultrafiltration and microfiltration ceramic modules (150 kDa, 0.14 μm, 0.45 μm) for removal and concentration of the cationic surfactant Tequat LC90i (TEAQ) from water solutions. The filtration tests were performed at a semi-pilot installation in a crossflow regime. The feed solution parameters (surfactant concentration, pH of the treated solution, the presence of inorganic salt), and process conditions (transmembrane pressure and linear velocity) on the membrane filtration efficiency were evaluated. In all tests, very satisfactory TEAQ retention coefficients (in the range of 70–95) have been achieved. However, surfactant fouling occurred resulting in deterioration of the permeability of the modules. Modules characterized by the pore sizes greater than the size of surfactant particles (i.e., 0.45 μm modules) proved to be the most fouling resistant ones. It was also proven that process performance at high linear flow velocity can efficiently reduce the intensity of membrane pore blocking.
Źródło:
Environment Protection Engineering; 2020, 46, 2; 41-51
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wetting properties of biosurfactant (rhamnolipid) with synthetic surfactants mixtures in the context of soil remediation
Autorzy:
Elżbieta Hallmann, Elżbieta
Mędrzycka, Krystyna
Powiązania:
https://bibliotekanauki.pl/articles/764029.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
biosurfactant
nonionic surfactant
surfactants mixtures
soil remediation
Opis:
Wetting properties of synthetic surfactant Rokanol NL6, biosurfactant JBR 425 and their mixture have been investigated. On the basis of these investigations, the ability of used surfactants to remove the synthetic base oil (PAO6) from sandy soil and clay loam was evaluated. Surfactant solutions were applied for soil flushing in batch experiments. The results show that synthetic surfactant addition worsens physicochemical properties of pure biosurfactant but exhibits much higher oil removal efficiency than biosurfactant does.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2015, 70, 1
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biodegradation of alkyl ethoxylates and alkylphenol ethoxylates in river water in a static die-away test as studied by HPLC-ESI/MS
Autorzy:
Zembrzuska, J.
Frańska, M.
Schroeder, G.
Frański, R.
Powiązania:
https://bibliotekanauki.pl/articles/347027.pdf
Data publikacji:
2010
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
non-ionic surfactants
biodegradation
HPLC-ESI-MS
Opis:
Biodegradation of nonylphenol ethoxylates and dodecyl ethoxylates (C9H19-C6H4- (OCH2CH2)n-OH and C12H25-(OCH2CH2)n-OH, respectively) in river water in a static die-away test was analyzed by using high performance liquid chromatography with mass spectrometric detection using the Applied Biosystems quadrupole-linear ion trap mass spectrometer Model 4000 QTrap. Surfactants containing 2-4 ethoxylene units may be regarded as persistent metabolites of longer surfactants. Homologues C9H19-C6H4- (OCH2CH2)5-OH and C12H25-(OCH2CH2)5-OH underwent substantial biodegradation till the 9th day of the test, their further biodegradation proceeded very slowly. The longer homologues (n > 5) were fully biodegraded during the test. Although the biodegradation of the surfactants studied consisted in shortening the ethoxylene chain (hydrophilic part), it was found that the hydrophobic part also affected their biodegradation.
Źródło:
Ars Separatoria Acta; 2009-2010, 7; 69-76
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption effectiveness and adsorption efficiency of chosen surfactants
Autorzy:
Rekiel, Edyta Ada
Powiązania:
https://bibliotekanauki.pl/articles/2079921.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
surfactants
biosurfactants
adsorption
adsorption effectiveness
adsorption efficiency
Opis:
Surfactants are various types of chemical compounds that are present in almost every aspect of our life. They are used in many branches of industry, especially in food, cosmetics, pharmaceuticals and even in confectionery. They are considered one of the best solutions for oil residues, soil bioremediation and dealing with PAHs contaminations. Their versatility comes from their amphiphilic build – one part of the compound has hydrophilic properties (head), the other has hydrophobic properties (tail). This fact causes surfactants affinity both to polar and nonpolar compounds. Some of the classical surfactants still can affect fauna and flora by accumulating in ground waters or simply by causing allergies. In that case, many companies decide to limit their surfactant usage and reach for substances present in nature which have very similar, if not better, properties. Biosurfactants are surface active agents produced mainly by microorganisms such as bacteria, fungi and yeasts. There are many papers related to different properties (CMC, aggregation number, surface excess concentration) of various types of surfactants. However, it is difficult to find papers describing the same properties for different surfactants. In this study, adsorption effectiveness and adsorption efficiency at the water-air interface of chosen surfactants: sodium dodecylsulfate (SDDS), cationic: cetyltrimetylammonium bromide (CTAB), nonionic: Triton X-100 (TX-100) and biosurfactants: surfactin (SF) and monorhamnolipid (RL)  has been compared. Both efficiency and effectivenes decide about the practical surfactants application.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2019, 74, 2; 25-39
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation and elimination of surfactant-induced interferences in anodic stripping voltammetry for the determination of trace amounts of cadmium
Autorzy:
Grabarczyk, Malgorzata
Wardak, Cecylia
Wawruch, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/24085686.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cadmium
stripping voltammetry
surfactants
Amberlite resins
Opis:
This article aims to investigate in detail to what extent surfactants affect the determination of cadmium by anodic stripping voltammetry. In recent years, the production and use of surfactants have been steadily increasing, so that their concentration in environmental water samples is rising. At the same time, it is known that organic compounds, such as surfactants, often hinder the voltammetric determination of trace elements by stripping. Non-ionic (Triton X-100, Brij 35, Tween 20, Tween 60, Tween 80), cationic (CTAB, CTAC, DTAB, HPC) and anionic (DSS, SDS) compounds were selected to investigate the effect of surfactants on the voltammetric signal of cadmium. At the same time, the extent to which the addition of Amberlite resins to the analysed solution eliminates the interfering effect of surfactants was tested. Three types of Amberlite resins XAD-2, XAD-7 and XAD-16 were selected for the study and the ratio of resin weight to solution volume was determined. Finally, the determination of cadmium in surfactant-enriched environmental samples was carried out. The recoveries obtained between 95.5 and 107%, with RSD between 3.4 and 6.2%, confirm the validity and correctness of the proposed procedure All measurements were carried out by anodic stripping voltammetry using a CNTs/SGC electrode modified with a bismuth film as the working electrode.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 4; art. no. 170717
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Critical Coalescence Concetration (CCC) as a parameter for evaluation of selected quaternary ammonium compounds
Krytyczne stężenie koalescencji (CCC) jako parametr oceny czwartorzędowych związków amoniowych
Autorzy:
Szyszka, D.
Powiązania:
https://bibliotekanauki.pl/articles/89122.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Wydział Geoinżynierii, Górnictwa i Geologii. Instytut Górnictwa
Tematy:
flotation
surfactants
Critical Coalescence Concentration (CCC)
Opis:
The objective of this paper was to determine the Critical Coalescence Concentration (CCC) of surfactants such as N(dodecyloxycarboxymethyl) N,N,N(trimethylammonium) bromide (DMGM-12), N-[2-(dodecyoxycarboxy)ethyl] N,N,N-(trimethylammonium) bromide (DMALM-12) and N-[3-(dodecanoyloxycarboxy)prophyl] N,N,N-(trimethylammonium) bromide (DMPM-11). The surfactants used represent quaternary ammonium compounds containing a hydrophobic moiety with an ester group (commonly known as “esterquats”). The CCC value was determined by analysis of the relationship between concentration of surfactant and average air bubble diameter. The values of the critical coalescence concentration (CCC) were estimated using a graphical method.
Celem pracy było wyznaczenie krytycznego stężenia koalescencji CCC surfaktantów, takich jak: bromek N-(dodecylooksykarboksymetylo)-N,N,N-trimetyloamoniowy (DMGM-12), bromek N-[2-(dodecylooksykarboksy)etylo]-N,N,N-trimetyloamoniowy (DMALM-12) oraz bromek N-[3-(dodekanoylooksy)propylo]-N,N,N-trimetyloamoniowy (DMPM-11). Zastosowane odczynniki to czwartorzędowe związki amoniowe, zawierające hydrofobową grupę zawierającą grupę estrową (powszechnie nazywane, jako „esterquaty”). Określenie wartości krytycznego stężenia polegało na przeanalizowaniu zależności stężenia badanego surfaktantu od średniej średnicy pęcherzyka powietrza. Wartości krytycznego stężenia koalescencji (CCC) określono za pomocą metody graficznej.
Źródło:
Mining Science; 2013, 20; 101-113
2300-9586
2353-5423
Pojawia się w:
Mining Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of hydroperoxides in aqueous solutions containing surfactants by the ferrous oxidation-xylenol orange method
Autorzy:
Meisner, Piotr
Gębicki, Jerzy
Powiązania:
https://bibliotekanauki.pl/articles/1040551.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
surfactants
FOX method
hydroperoxides
gamma-irradiation
Opis:
Some surfactants widely used as additives in food, pharmaceuticals, and cosmetic formulations are susceptible to peroxidation resulting in accumulation of hydroperoxides (HP). Our investigation was aimed to study the possible influence of different surfactants on the proportionality and reproducibility of the ferrous oxidation-xylenol orange method developed originally for the determination of hydroperoxides. We also attempted to apply this method to determine hydroperoxides produced radiolytically in surfactant molecules. From our preliminary studies we conclude that the method can be applied for determination of hydroperoxides in systems containing non-ionic or anionic surfactants provided careful calibration is performed for each surfactant.
Źródło:
Acta Biochimica Polonica; 2009, 56, 3; 523-527
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 100

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