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Tytuł:
Solubility of a pharmacological intermediate drug Isatin in different solvents at various temperatures
Autorzy:
Baluja, S.
Bhalodia, R.
Bhatt, M.
Vekariya, N.
Gajera, R.
Powiązania:
https://bibliotekanauki.pl/articles/412531.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Isatin
solubility
Thermodynamic parameters
Opis:
The solubility of isatin in different solvents was studied by a gravimetrical method from (298.15 to 318.15) K under atmospheric pressure and the solubility data were correlated against temperature. The solvents selected for the present study are: water, methanol, ethanol, 1-butanol, dichloromethane, dichloroethane, chloroform and carbon tetra chloride. Among chlorinated solvents, solubility is observed to be maximum in 1, 2-dichloroethane and minimum in dichloromethane whereas in alcohols, maximum solubility is observed in methanol. In water, solubility is found to be minimum. Further, some thermodynamic parameters such as Gibb’s energy (ΔGsol), heat of solution (ΔHsol) and entropy of solution (ΔSsol) have also been evaluated.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 12; 36-46
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
STABILITY STUDIES OF CEFTIOFUR SODIUM IN AQUEOUS SOLUTIONS AND IN THE SOLID PHASE
Autorzy:
Dołhań, Agnieszka
Sobczak, Agnieszka
Muszalska, Izabela
Medenecka, Beata
Garbacki, Piotr
Tomczak, Szymon
Jelińska, Anna
Powiązania:
https://bibliotekanauki.pl/articles/895368.pdf
Data publikacji:
2018-12-31
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
stability
kinetic parameters
thermodynamic parameters
solid phase
Opis:
Ceftiofur sodium (CFT), a third-generation cephalosporin for parenteral use, is commonly used in veterinary medicine against aerobic Gram-positive and Gram-negative bacteria as well as certain anaerobes. Its broad spectrum of activity and resistance to beta-lactamases result from the presence of methoxyimino and aminothiazole moieties at C-7 in the cephalosporin structure. The aim of this study was a comprehensive evaluation of the stability of CFT in the solid phase and in aqueous solutions. A fast and sensitive HPLC isocratic method was used for the determination of CFT degradation in the solid phase and in aqueous solutions. CFT degradation occurred according to a first-order reaction depending on the substrate concentration. The kinetic and thermodynamic parameters of CFT degradation in the solid phase were calculated. General acid-base hydrolysis of CFT was not observed in the solutions of hydrochloric acid, sodium hydroxide, phosphate (pH 5.84 – 7.25), acetate (pH 3.65 – 5.48) and borate (pH 7.49 – 10.07) buffers. CFT was the most stable in the pH range 2 – 6. The susceptibility of CFT to degradation under the influence of stress factors (pH, temperature, buffer components concentration, relative air humidity) should be considered in terms of storage conditions and the preparation of the product for administration.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2018, 75, 6; 1279-1286
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption and adsorption isotherm: application to corrosion inhibition studies of mild steel in 2 M HCl
Autorzy:
Abeng, F. E.
Idim, V. D.
Obono, O. E.
Magu, T. O.
Powiązania:
https://bibliotekanauki.pl/articles/1178372.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Adsorption isotherm
inhibition mechanism
mild steel
thermodynamic parameters
Opis:
Ethanollic extract of Phyllanthus amarus (EEPA) was tested as corrosion inhibitor for mild steel in 2 M HCl solution using gravimetric and gasometric methods at 303, 313, 323 K and 333 K. The results revealed that the corrosion rate increases with temperature and time. Addition of the concentration of ethanollic extract of Phyllanthus amarus to the corroding environment lowered the corrosion rate of mild steel and increased inhibition efficiency (IE %) of ethanollic extract. Inhibition efficiency was found to decreased with temperature. Fitting of the experimental data to the Arrhenius and Transition state equations revealed that the Organic constituents of the extract were physically adsorbed on the corroding surface of the steel and adsorption of ethanollic extract of Phyllanthus amarus (EEPA) on mild steel surface was found to obey the Langmuir adsorption isotherm and Freundlich adsorption isotherm and sign of the Gibb’s fee energy of the adsorption obtained suggested that inhibitor molecules have been spontaneously adsorbed onto the mild steel surface. Positive values obtained for enthalpy change indicated that the adsorption of inhibitor is endothermic.
Źródło:
World Scientific News; 2017, 77, 2; 298-313
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Acoustical studies of binary liquid mixtures of p-chlorotoluene in benzene at different temperatures
Autorzy:
Kumar, G. P.
Babu, Ch. P.
Samatha, K
Jyosthna, A. N.
Showrilu, K.
Powiązania:
https://bibliotekanauki.pl/articles/412275.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ultrasonic velocity
thermodynamic parameters
p-chlorotoluene
molecular interactions
Opis:
Ultrasonic velocities (U), densities (ρ), and coefficient of viscosities (η) are measured for binary mixtures containing (i) p-chlorotoluene and (ii) benzene at 303.15 K, 308.15 K, 313.15 K and 318.15 K to understand the molecular interaction. Various acoustical parameters such as adiabatic compressibility (βad), free length (Lf), acoustic impedance (Z), free volume (Vf), molar volume (Vm), Rao’s constant (R), Wada’s constant (W) and internal pressure (πi), are calculated from the measured values of U, ρ, and η. The trend in acoustical parameters also substantiates to asses strong molecular interactions.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 10; 25-37
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and evaluation of thermodynamic solubility of triazolo quinolone class derivatives in various solvents at 298.15-328.15 K
Autorzy:
Baluja, Shipra
Pithiya, Mona
Lava, Divyata
Powiązania:
https://bibliotekanauki.pl/articles/1031268.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Triazolo quinolone
alcohols
ethyl acetate
solubility
thermodynamic parameters
Opis:
The solubility of triazolo quinolone class derivatives in methanol, ethanol, n-propanol, n-butanol and ethyl acetate was measured using a gravimetrical method at temperature ranging from 298.15 K to 328.15 K. The results of these measurements were correlated with semi empirical equations. Some thermodynamic parameters such as dissolution enthalpy, Gibb’s free energy and entropy of mixing have also been calculated.
Źródło:
World Scientific News; 2021, 151; 16-30
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of CO2 by surface modified coal-based activated carbons: kinetic and thermodynamic analysis
Autorzy:
Xinzhe, Liu
Mingyang, Zhang
Juan, Chen
Zhengyu, Hu
Shuaifei, Xian
Mingxuan, Tang
Chenchen, Zhang
Powiązania:
https://bibliotekanauki.pl/articles/2174813.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Surface modification
CO2 adsorption capacity
adsorption kinetics
thermodynamic parameters
Opis:
The effects of different surface modifiers on the CO2 adsorption capacity of coal-based activated carbons were studied, and the diffusion behavior, adsorption kinetics and thermodynamic parameters of CO2 in activated car-bons were analyzed. The results show that compared with ethylene glycol, 1,2-propylenediamine and zinc chloride, potassium hydroxide and sodium hydroxide can greatly improve CO2 adsorption capacity. The adsorption rate is faster, and the adsorption capacity is larger, with the maximum CO2 adsorption capacity being 33.54 mL/g. Fick’s law can well describe the diffusion behavior of CO2 in activated carbon. The addition of a surface modifier can increase the diffusion coefficient. The diffusion of CO2 in activated carbon falls into the category of crystal diffusion. The adsorption kinetics of CO2 before and after surface modification follow the Bangham equation. During the adsorption process, δ H < 0, δ G < 0, δ S < 0. Surface modification can reduce adsorption heat and promote adsorption, and the adsorption process is dominated by physisorption.
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 3; 19--28
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Temperature influence on the electrode process in the presence of 6-thioguanine and surfactants
Autorzy:
Nosal-Wiercińska, Agnieszka
Kaliszczak, Waldemar
Martyna, Marlena
Szabelska, Anna
Gołębiowska, Beata
Wiśniewska, Małgorzata
Powiązania:
https://bibliotekanauki.pl/articles/1845199.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
catalytic effect
Bi(III) electroreduction
6-thioguanine
surfactants
thermodynamic parameters
kinetic parameters
Opis:
The measurements concerning the process of the electroreduction of Bi(III) ions in the presence of 6–thioguanine (6TG) and Triton X-100 as well as Tween 80 in the 2 $mol·dm^{-3}$ chlorates(VII) demonstrate a dependence of the process rate on temperature. The applied electrochemical techniques (DC polarography, cyclic and SWV voltammetry) allowed to determine the kinetic and thermodynamic parameters as well as their correlation with changes in kinetics of the electrode process. The catalytic activity of 6TG was confirmed by the decrease of overall enthalpies of activation. Different values of $\DeltaH^{\ne}$ and $\DeltaS^0$ for Bi(III) electroreduction in the presence of 6–thioguanine as well as Triton X-100 and Tween 80 suggest changes in kinetics of the electrode process towards inhibition.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 14-21
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics of natural and synthetic molecular sieves and study of their interactions with fragrance compounds
Autorzy:
Kasperkowiak, M.
Strzemiecka, B.
Voelkel, A.
Powiązania:
https://bibliotekanauki.pl/articles/110548.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
molecular sieves
fragrance compounds
adsorption properties
thermodynamic parameters
thermal stability
Opis:
Structural, physicochemical and adsorption properties of two natural and one synthetic molecular sieves were investigated by various techniques: X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, low-temperature nitrogen adsorption and inverse gas chromatography. The influence of these properties on the ability to adsorb two model fragrances: p-cymene and menthol was studied. The free enthalpy, entropy and Gibbs free energy of adsorption of fragrance molecules on the surface of zeolite and zeolite-like materials were estimated by using inverse gas chromatography. Also, the influence of temperature on the stability of solid-fragrance compound systems as well as the release of the adsorbed fragrance compounds was studied. The obtained results exhibit that both porosity and chemical composition of molecular sieves influence the size and strength of adsorption of fragrance compounds. The study indicated different release characteristics for p-cymene and menthol.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 789-802
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanism and kinetics oxidation of inconel 617 and 625 alloys
Autorzy:
Staszewska, K.
Scendo, M.
Powiązania:
https://bibliotekanauki.pl/articles/134738.pdf
Data publikacji:
2016
Wydawca:
ADVSEO
Tematy:
inconel alloy
thermogravimetric analysis
thermodynamic parameters
parabolic rate constants
activation energy
Opis:
The mechanism and kinetics of oxidation of Inconel 617 and 625 alloys in air atmosphere were investigated. Materials were examined by the thermogravimetric method. The X-ray diffraction spectrometer (XRD) was used to observation change in chemical composition the oxide scales of Inconel alloys specimens. Oxidation kinetics was determined from weight-change measurements. The surface and microstructure of the sample were observed in an optical microscope (OM) and a scanning electron microscope (SEM). The results showed that the oxide scales of the alloys were compact and continuous. The layer were contained as the outer of Cr2O3, and the internal of NiCr2O4 spinel, NiO and other oxides. Oxides’ scales with good adherence were formed on the surface of alloys. The kinetics and thermodynamic parameters of oxides formation were calculated and discussed for both alloys.
Źródło:
Technical Issues; 2016, 1; 82-89
2392-3954
Pojawia się w:
Technical Issues
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Degradation Behaviour and Kinetics of aged TNT-based Melt Cast Composition B
Autorzy:
Singh, Arjun
Sharma, Tirupati Chander
Singh, Vasundhara
Mukherjee, Niladri
Powiązania:
https://bibliotekanauki.pl/articles/358256.pdf
Data publikacji:
2019
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
composition B
thermal degradation
thermogravimetry
Differential Scanning Calorimetry
kinetics
thermodynamic parameters
Opis:
In the present paper, three kinds of aged and freshly prepared 2,4,6-trinitrotoluene (TNT) based Composition B stockpiled, for a period of 20 and 32 years, were investigated for the effect of natural ageing on their thermal degradation behaviour and kinetic parameters. The properties investigated indicated that there was no significant change in the thermal stability of the samples aged under natural environmental conditions. The kinetic parameters were studied by means of the Kissinger method using the peak temperature at maximum reaction rate from DSC data, and the isoconversional Kissinger-Akahira-Sunnose (KAS) and ASTM E689 methods from TGA data. The apparent activation energies calculated by the Kissinger method were 173.8 kJ·mol–1 for fresh, 170.4 kJ·mol–1 for 20 y old and 187.1 kJ·mol–1 for 32 y old Composition B, respectively. The values calculated by the KAS method were found to be in the range 77.2-235.8 kJ·mol–1 for fresh Composition B, 75.7-224.0 kJ·mol–1 for 20 y old and 70.4-196.0 kJ·mol–1 for 30 y old Composition B, respectively. The activation energies obtained from the KAS methods are in good agreement and consistent with the isoconversional ASTM E689 kinetic method. The thermodynamic parameters, such the Gibbs free energy of activation (ΔG#), activation enthalpy (ΔH#) and activation entropy (ΔS#) for the formation of activated complexes were also studied and are discussed.
Źródło:
Central European Journal of Energetic Materials; 2019, 16, 3; 360-379
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chalcones: A Solubility study at different temperatures
Autorzy:
Bhalu, A. A.
Bhesaniya, K. D.
Vekariya, N. J.
Baluja, S. H.
Powiązania:
https://bibliotekanauki.pl/articles/412118.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Chloroform
dichloromethane
thermodynamic parameters
dissolution enthalpy
Gibb’s energy and en tropy
Opis:
Some new chalcones are synthesized by the condensation of aryl ketones with aromatic aldehydes and solubility of these synthesized chalcones is determined in chloroform and dichloromethane at temperatures ranging between 293.15 K and 313.15 K by gravimetric method. The experimental data was correlated well with modified Apelblat equation. Further, from the experimental solubility data, some thermodynamic parameters such as dissolution enthalpy, Gibb’s energy and entropy etc. were evaluated using van’t Hoff equation. The positive Gibb’s energy and negative entropy suggests spontaneous dissolution and more ordered structure in solution.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 12; 7-19
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of thermal degradation behavior and kinetics of ABS/PC blend
Autorzy:
Bano, Saira
Ramzan, Naveed
Iqbal, Tanveer
Mahmood, Hamayoun
Saeed, Farhan
Powiązania:
https://bibliotekanauki.pl/articles/778844.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ABS/PC blend
thermal degradation
iso-conversional analysis
activation energy
thermodynamic parameters
Opis:
This work investigated kinetics and thermal degradation of acrylonitrile butadiene styrene and polycarbonate (ABS/PC) blend using thermogravimetric analysis in the range of 25 to 520°C. For thermal degradation of blend, activation energy (Ea) and pre-exponential factor (A) were calculated under various heating rates as 5, 10, 15 and 20°C/min using iso-conversional model-free methods (Kissinger, Flynn-Wall- Ozawa and Friedman). Mass loss of the blend as a function of temperature was plotted as thermogravimetric curve (TG) while derivative values of mass loss were drawn as derivative thermogravimetric (DTG) curve. Using Kissinger method, Ea was 51.4 kJ/mol, while values calculated from FWO and Friedman method were 86–161 and 30–251 kJ/mol respectively. Results showed increasing trend of Ea with higher conversion values indicating different degradation mechanisms at the initial and final stages of the experiment. Thermodynamic parameters such as enthalpy change (ΔH), Gibbs free energy (ΔG) and entropy change (ΔS) were also calculated.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 3; 64-69
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wyniki prób zastosowania materiałów wybuchowych emulsyjnych Hydromite 100 i Emulexu 100 AL w KGHM Polska Miedź S.A. Oddział Zakłady Górnicze „Rudna”
Results of tests on the use of Hydromite 100 and Emulex 100 AL emulsion explosives at the Branch of the „Rudna” Mining Plant
Autorzy:
Maranda, Andrzej
Gołąbek, Barbara
Suszka, Jacek
Pawłowicz, Jerzy
Powiązania:
https://bibliotekanauki.pl/articles/1861206.pdf
Data publikacji:
2020
Wydawca:
Stowarzyszenie Inżynierów i Techników Górnictwa
Tematy:
materiały wybuchowe emulsyjne
kopalnia miedzi
parametry termodynamiczne
parametry detonacyjne
emulsion explosives
thermodynamic parameters
detonation parameters
copper ore mines
Opis:
Materiały wybuchowe emulsyjne (MWE) są jednym z dominujących środków strzałowych stosowanych w kopalniach rud miedzi. W pracy przedstawiono parametry termodynamiczne i detonacyjne dwóch MWE oraz podano parametry techniczne urządzenia mieszalniczo-załadowczego UGPL-1 stosowanego podczas eksperymentów do ich produkcji i załadunku do otworu strzałowego. Opisano technologię formowania materiałów wybuchowych i wyniki prób kopalnianych.
Emulsion explosives are one of the dominant blasting agents used in copper ore mines. The paper presents thermodynamic and detonation parameters of two emulsion explosives and technical parameters of the UGPL-1 mixing and loading device used during experiments for their production and loading into the blast hole. The technology of preparation explosives and the results of mine tests are described.
Źródło:
Przegląd Górniczy; 2020, 76, 8; 39-44
0033-216X
Pojawia się w:
Przegląd Górniczy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Stanowisko laboratoryjne do wyznaczania parametrów termodynamicznych sprężarki tłokowej
Laboratory stand for determining piston compressor thermodynamic parameters
Autorzy:
Gawędzki, W.
Dziekan, A.
Hajto, P.
Powiązania:
https://bibliotekanauki.pl/articles/157042.pdf
Data publikacji:
2008
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
sprężarka tłokowa
parametry termodynamiczne
cykl termodynamiczny
pomiar szybkozmiennej temperatury
piston compressor
thermodynamic parameters
thermodynamic cycle
fast-variable temperature measurement
Opis:
W artykule omówiono stanowisko laboratoryjne do automatycznego wyznaczania parametrów i charakterystyk termodynamicznych sprężarki tłokowej, które może być również wykorzystane do badania innych typów obiektów, w których zachodzą przemiany termodynamiczne względnie dla celów dydaktycznych. Omówiono opracowane metody wyznaczania parametrów termodynamicznych, zastosowane układy kondycjonowania sygnałów oraz sposoby kalibracji torów pomiarowych. Opracowany system umożliwia pomiar chwilowych wartości temperatury, objętości czynnej w cylindrze sprężarki, ciśnień oraz przepływu powietrza, a także wyznaczenie cyklu termodynamicznego (p=f(V)) oraz wyznaczenie bilansu energetycznego i określenie sprawności sprężarki.
The paper presents the laboratory stand for automatic measurements of thermodynamic parameters and characteristics of a piston compressor. The stand can also be used for investigations of thermodynamic parameters of other systems as well as for didactics. The methods used for determining the thermodynamic parameters and calibrating the measurement equipment are discussed. The system enables measurements of the instantaneous values of temperature, active volume of a compressor cylinder, pressure and air flow velocity. The thermodynamic cycle (p=f(V)), energy balance and compressor efficiency factor can also be determined.
Źródło:
Pomiary Automatyka Kontrola; 2008, R. 54, nr 12, 12; 883-886
0032-4140
Pojawia się w:
Pomiary Automatyka Kontrola
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
In situ methanolic solvent synthesis, spectroscopic and thermogravimetric characterizations of three new transition metal complexes of trimethoprim drug
Autorzy:
Refat, Moamen S.
Al-Humaidi, Jehan Y.
El-Sayed, Mohamed Y.
Hassan, Reham F.
Powiązania:
https://bibliotekanauki.pl/articles/1849325.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
complexation
trimethoprim
transition metals
TGA
thermogravimetric analysis
FTIR
Fourier transform infrared spectroscopy
ESR
kinetic thermodynamic parameters
Opis:
Trimethoprim drug (TMP) complexes of copper (II), cobalt (II), and nickel (II) were prepared and discussed by using elemental analysis (C, H, N analysis), magnetic, molar conductance, FTIR, Raman spectroscopy, electron spin resonance (ESR) and UV-vis spectroscopy analyses. TMP drug coordinated as a tridentate ligand towards the respected three metal ions through two nitrogen atoms of amino groups and nitrogen atom of pyrimidine ring which flanked between –NH2 groups, these assignments confirmed by spectroscopic, magnetic, ESR and thermogravimetric analyses with formulas [Cu(TMP)(H2O)3]Cl2, [Co(TMP)(H2O)3]Cl2 and [Ni(TMP) (H2O)]Cl2. Copper (II) and cobalt (II) complexes have an octahedral geometrical structure included one TMP molecule, three coordinated water molecules and two uncoordinated chlorine atoms while, nickel(II)–TMP complex has a tetrahedral geometric configuration that involved one TMP molecule, one coordinated water molecule and two uncoordinated chlorine atoms. The activation energies and other kinetic thermodynamic parameters were estimated based on the employed of the Coats-Redfern and Horowitz-Metzger equations. The nano–structured form of the synthesized TMP complexes was confirmed dependent on the transmission electron microscopy (TEM).
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 1; 60-67
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
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