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Tytuł:
Ordering of alfa-FeCo phase in the nanocrystalline Fe83-xCoxNb3B13Cu1 (x = 6, 25 or 41.5) alloy
Autorzy:
Zbroszczyk, J.
Młyńczyk, A.
Olszewski, J.
Ciurzyńska, W.
Wysłocki, B.
Perduta, K.
Lelątko, J.
Nabiałek, M.
Powiązania:
https://bibliotekanauki.pl/articles/148219.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
nanocrystalline alloys
microstructure
ordering
Mössbauer spectroscopy
Opis:
The microstructure and ordering of alfa-FeCo phase of the nanocrystalline Fe83 xCoxNb3B13Cu1 (x = 6, 25 or 41.5) alloys were investigated. We have stated that á-FeCo phase is atomically ordered in the Fe83 xCoxNb3B13Cu1 (x = 25 or 41.5) samples crystallized by the heat treatment in a furnace. However, after flash annealing (by current or laser) that phase is disordered. Moreover, we have found that Co concentration in the crystalline alfa-FeCo phase strongly depends on Co content in the as-quenched ribbons. The annealing conditions influence also the grain diameter of the crystalline phase. In the nanocrystalline alloys obtained by a flash annealing of the amorphous ribbons finer grains are present.
Źródło:
Nukleonika; 2007, 52, supl. 1; 29-32
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer study of the El Hammami olivine-bronzite meteorite
Autorzy:
Zarek, W.
Popiel, E.
Tuszyński, M.
Teper, E.
Powiązania:
https://bibliotekanauki.pl/articles/147220.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
meteorite
XRD
scanning electron microscopy
Mössbauer spectroscopy
kamacite
Opis:
The phase composition of the El Hammami meteorite was investigated by X-ray, magnetostatic, Mössbauer effect and environmental scanning electron microscopy methods. Performed investigations indicated that this meteorite consists of aluminosilicates, olivine (Mg,Fe)2SiO4, pyroxene (Ca,Mg,Fe)SiO3, kamacite (bcc Fe-Ni alloy) and troilite (FeS). Some inclusions of Ti and Cr were observed by scanning electron microscopy. The concentration of Ni in kamacite was determined by comparison of the Mössabauer spectra of Fe-Ni phase in the meteorite with those for synthetic bcc Fe-Ni alloys (5, 10, 25% Ni).
Źródło:
Nukleonika; 2004, 49,suppl.3; 59-62
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of Ti content on α martensite phase transformation, and magnetic properties by Mössbauer spectroscopy in Fe-30%Ni-x%Ti (wt%) alloys
Autorzy:
Yaşar, E.
Erdem, U.
Akif Tuna, M.
Armağan, O.
Kırındı, T.
Powiązania:
https://bibliotekanauki.pl/articles/1050927.pdf
Data publikacji:
2018-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
martensitic transformation
Mössbauer spectroscopy
isomer shift
internal magnetic field
Opis:
In this study, the influence of Ti content on the microstructure of the martensite bcc α'), which was formed by thermal effect, was investigated by scanning electron microscope and transmission electron microscope observations, in Fe-30Ni-xTi (x=0.8, 1.8, 2.6) alloys. The crystallographic orientation relationship between austenite fcc (γ) and thermally induced bcc (α') martensite was found to be as (111)_{γ}/(011)_{α} (Kurdjumov-Sachs (K-S)), by the electron diffraction analysis. The martensitic transformation temperature (M_{s}) of α' martensite was determined as -41°, -62°, and -76 ° in the alloys with 0.8%, 1.8%, and 2.6% Ti concentration, respectively. The Mössbauer spectrometer analysis has been revealed by a paramagnetic character for the austenite phase and magnetically order character for α' martensite phase. Hyperfine magnetic field, isomer shift and volume fractions of phases were determined by the Mössbauer spectroscopy.
Źródło:
Acta Physica Polonica A; 2018, 133, 5; 1165-1169
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metoda 4M – nowe zastosowanie spektroskopii mössbauerowskiej w klasyfikacji zrównoważonych chondrytów zwyczajnych
4M method – the new application of Mössbauer spectroscopy for classification of equilibrated ordinary chondrites
Autorzy:
Woźniak, Marek
Karwowski, Łukasz
Gałązka-Friedman, Jolanta
Duda, Przemysław
Jakubowska, Martyna
Bogusz, Patrycja
Powiązania:
https://bibliotekanauki.pl/articles/1033156.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Meteorytowe
Tematy:
4M method
Cluster Analysis
Mahalanobis distance
Multidimensional Discriminant Analysis
Mössbauer spectroscopy
Principal Components Analysis
meteorites
meteorites classification
ordinary chondrites
Opis:
The 4M method aims to determine the type of equilibrated ordinary chondrite only on the basis of the Mössbauer spectrum of the investigated meteorite. Mössbauer spectrum of non-weathered ordinary chondrite is comprised of four sub-spectra: two doublets and two sextets. One of the doublets consists of a signal from iron present in olivine and the other consists of a signal from iron present in pyroxene. Sextets on the other hand, contain signals from magnetically ordered iron. One sextet is related to the metallic phase (kamacite, taenite), whereas the second is related to troilite. A third of doublets, which emerges in weathered ordinary chondrites, is related to products of the oxidation of iron present in metallic phase. The spectral areas of olivine, pyroxenes, metallic phase and troilite, which were obtained from Mössbauer spectrum are proportional to the number of iron atoms present in relevant mineral phases. Some Mössbauer groups were inspired by this fact to construct different methods to determine the type (H, L, or LL) of investigated meteorites (Gałązka-Friedman et al. 2019, Hyp. Inter. 241(1)). However, these methods, based on subjective criteria, were only qualitative. Our group elaborated a quantitative method, which is based on objective criteria. We called it the "4M method" (where M are derived from meteorites, Mössbauer spectroscopy, multidimensional discriminant analysis (MDA), Mahalanobis distance) (Woźniak et al. 2019). This method was using only the Mössbauer experimental data, to which it applied advanced statistical methods. The base, which was created from Mössbauer data, consisted of three clusters H, L, LL. These clusters were constructed with sets of 4-dimensional vectors. The vectors are comprised of spectral areas of Mössbauer spectrum: ol (value proportional to iron present in olivine), pyr (value proportional to iron present in pyroxene), met (value proportional to iron present in metallic phase), tr (value proportional to iron present in troilite). To determine the type of investigated ordinary chondrite, its ol, pyr, met and tr values with average values of variables obtained for clusters H, L and LL need to be compared. The comparison can be performed with the use of MDA and Mahalanobis distance. Once Mahalanobis distance of the investigated meteoriteis is known, the level of similarity to three types of ordinary chondrites can be calculated. Examples of such calculations were performed for seven ordinary chondrites: Goronyo, Carancas, New Concord, NWA 7733, Leoncin, Sołtmany and Pułtusk. They were made with the use of the new base composed of 62 non-weathered ordinary chondrites. All results obtained with the 4M method yielded results consistent with traditional mineralogical methods.
Źródło:
Acta Societatis Metheoriticae Polonorum; 2020, 11; 125-140
2080-5497
Pojawia się w:
Acta Societatis Metheoriticae Polonorum
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phase structure of the nanocrystalline Nd2Fe14B/alfa-Fe magnets with different grain
Autorzy:
Wnuk, I.
Wysłocki, J.
Przybył, A.
Powiązania:
https://bibliotekanauki.pl/articles/148342.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Nd2Fe14B + alfa-Fe nanocrystalline magnets
Mössbauer spectroscopy
magnetic properties
Opis:
The effect of the contents of the magnetically hard and magnetically soft phases on the magnetic properties of Nd2Fe14B + alfa-Fe nanocrystalline magnets, as produced by the method of mechanical alloying, has been established. The phase composition of specimens was determined using X-ray diffractometry and Mössbauer spectroscopy. The Mössbauer examination showed that as the powder milling times increased, the content of the Nd2Fe14B phase increased from 42.8% (after the milling time of 10 h, with a grain size of 44.8 nm) to 66.3% (after the milling time of 48 h, with a grain size of 37.3 nm) and then decreased to 40.3% after 120 h of milling. On the other hand, the content of the magnetically soft phase alfa-Fe initially decreased (from 27.7%), reaching a minimum after the milling time of 48 h (17.4%) and then increasing to 36.9% after 120 h of milling.
Źródło:
Nukleonika; 2007, 52, supl. 1; 85-88
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer studies of single crystal gamma-Mn-Fe
Autorzy:
Szymański, K.
Olszewski, W.
Dobrzyński, L.
Satuła, D.
Jankowska-Kisielińska, J.
Powiązania:
https://bibliotekanauki.pl/articles/147239.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
gamma-Mn-Fe alloys
iron alloys
manganese alloys
Mössbauer spectroscopy
Opis:
Mössbauer measurements were performed on single crystals gamma-Mn60Fe37Cu3 in an external field of 1.3 T at room temperature. The hyperfine field distribution can be described as a vector sum of the external and internal fields. In addition, anisotropic response of magnetic moments was detected. The anisotropy, due to Fe atoms, has Fe-rich surroundings.
Źródło:
Nukleonika; 2004, 49,suppl.3; 75-78
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Średni ciężar atomowy chondrytu Vicência (LL3.2)
Mean atomic weight of Vicência LL3.2 chondrite
Autorzy:
Szurgot, Marian
Powiązania:
https://bibliotekanauki.pl/articles/1033113.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Meteorytowe
Tematy:
LL3 chondrites
Mössbauer spectroscopy
Vicência chondrite
grain density
iron to silicon ratio
mean atomic number
mean atomic weight
ordinary chondrites
troilite content
Opis:
Mean atomic weight Amean of Vicência (LL3.2 S1W0, fall 2013) ordinary chondrite has been calculated using literature data (Keil et al. 2015) on chemical composition of the meteorite and using relationships: between mean atomic weight and Fe/Si atomic ratio, between Amean and grain density, and between Amean and magnetic susceptibility. It was shown that Vicência’s Amean = 22.91 for composition without water. This value is close to the mean atomic weight of LL chondrite falls, is close to Amean value of LL3 chondrite falls, and is close to Amean value of Semarkona LL3.0 chondrite. Vicência’s Fe/Si atomic ratio (0.492±0.050) leads to Amean = 23.06–23.26, which is close to the value determined by bulk composition. Vicência’s Fe/Si atomic ratio is close to the value for Semarkona’s (Fe/Si = 0.511), and is close to LL’s mean Fe/Si ratio (0.520). This confirms that Vicência belongs to LL chondrites, as previously classified. Using dependence between mean atomic weight and grain density leads to Amean = 21.89±0.54 (dgr = 3.28 g/cm3, Keil et al. 2015), and using dependence between Amean and magnetic susceptibility gives Amean = 23.01±0.24 (logc = 4.30, Keil et al. 2015). Arithmetic mean of Amean (dgr), Amean (logc), and Amean(Fe/Si), gives 22.72±0.73, the value close to Amean(bulk composition) determined using compositional data. Mean atomic number Zmean, and Amean/Zmean ratio of the meteorite have been also calculated. Vicência’s Zmean = 11.37, and Amean/Zmean ratio is: 2.015 for composition without water. Vicência’s silicates shown the values: Amean = 21,67, Zmean = 10.76, Amean/Z mean = 2.014, Fe/Si = 0.318, Amean(Fe/Si) = 22.07–22.18, and Fe, Ni metal values: Amean = 56.63, Zmean = 26.53, and Amean/Z mean = 2.135. Two dependences: i) grain density dgr on Amean, and ii) grain density dgr on Fe/Si atomic ratio, were used to determine/verify grain density of Vicência chondrite. It was established that dgr(Amean) leads to the values: 3,42 g/cm3 for Vicência chondrite, 3,25 g/cm3 for silicates, and 7,90 g/cm3 for Fe, Ni metal of Vicência meteorite. Dependence dgr(Fe/Si) predicts density for Vicência chondrite: 3,47–3,49 g/cm3, and for silicates: 3,32–3,35 g/cm3.
Źródło:
Acta Societatis Metheoriticae Polonorum; 2018, 9; 126-144
2080-5497
Pojawia się w:
Acta Societatis Metheoriticae Polonorum
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hyperfine fields and magnetoelastic surface effects in Fe72Cu1.5Nb4Si13.5B9 nanocrystalline alloy
Autorzy:
Szumiata, T.
Gawroński, M.
Górka, B.
Brzózka, K.
Blázquez-Gámez, J.
Kulik, T.
Żuberek, R.
Ślawska-Waniewska, A.
Powiązania:
https://bibliotekanauki.pl/articles/148767.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
FINEMET
Mössbauer spectroscopy
nanocrystalline alloys
surface effects
surface magnetostriction
Opis:
In this work hyperfine fields of two-phase nanocrystalline Fe72Cu1.5Nb4Si13.5B9 alloys were studied in order to verify the existence of surface effects. To obtain a series of nanocrystalline samples with small grains of different sizes, a special non- -isothermal annealing procedure of an initially amorphous ribbon was applied. In the case of samples with a significant amount of crystallites, a high field (about 27.5 T) component of continuous part of the hyperfine field distribution was found that could be attributed to boundary regions between the grains and rest of the sample. The existence of the surface effects was confirmed in the magnetostrictive experiment.
Źródło:
Nukleonika; 2003, 48,suppl.1; 85-88
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Porównawcze badania mössbauerowskie meteorytów: Sołtmany (L6), Chelyabinsk (LL5) i Grzempy (H5)
Mössbauer comparative studies of the Sołtmany (L6), Chelyabinsk (LL5) and Grzempach (H5) meteorites
Autorzy:
Szlachta, Karol
Gałązka-Friedman, Jolanta
Woźniak, Marek
Powiązania:
https://bibliotekanauki.pl/articles/1033011.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Meteorytowe
Tematy:
Chelyabinsk (LL5)
Grzempy (H5)
Mössbauer spectroscopy
Sołtmany (L6)
classification of ordinary chondrites
meteorites
Opis:
Mössbauer studies of Chelyabinsk (LL5), Sołtmany (L6) and Grzempy (H5) show that the main iron bearing minerals in these meteorites are: Fe-Ni, troilite, olivine and pyroxene. Based on Mössbauer absorption area of different mineral phases, new set of parameters for classification of the ordinary chondrities were introduced. The most promising parameters are: the ratio of the olivine to pyroxene areas and the ratio of the silicate to metallic areas.
Źródło:
Acta Societatis Metheoriticae Polonorum; 2014, 5; 115-120
2080-5497
Pojawia się w:
Acta Societatis Metheoriticae Polonorum
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Position of Fe ions in MgO crystalline structure
Autorzy:
Szczerba, J.
Prorok, R.
Stoch, P.
Śnieżek, E.
Jastrzębska, I.
Powiązania:
https://bibliotekanauki.pl/articles/146372.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Mössbauer spectroscopy
MgO
Fe ions
crystal structure
Opis:
Magnesium oxide (MgO) is one of the most important raw materials in many branches of industry. Magnesium oxide is a popular refractory raw material because of its high refractoriness and high resistance to basic slags and environment. In many cases, use of MgO is limited by its properties, especially the presence of secondary phases like iron oxides. The amount and distribution of iron oxides can strongly infl uence the technological properties of MgO and depend on the manufacturing method, particularly the heat-treatment process. The aim of the study was to evaluate the infl uence of the heat-treatment process on amount and distribution of iron ions in a magnesium oxide lattice. The 57Fe Mössbauer effect measurements of fused and sintered magnesium oxide samples doped by the iron oxide were conducted. Investigation reveals in both cases the presence of Fe2+ as well as Fe3+ ions. Fe2+ ions occupy Mg2+ octahedral sites in the MgO lattice, whereas the Fe3+ ions are located in highly distorted octahedral coordination. The amount of Fe2+ varies from around 66% for fused samples to 30% for sintered samples.
Źródło:
Nukleonika; 2015, 60, 1; 143-145
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The role and position of iron in 0.8CaZrO3-0.2CaFe2O4
Autorzy:
Szczerba, J.
Śnieżek, E.
Stoch, P.
Prorok, R.
Jastrzębska, I.
Powiązania:
https://bibliotekanauki.pl/articles/146129.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
calcium ferrite
calcium zirconate
Mössbauer spectroscopy
perovskite
spinel
Opis:
The aim of the study was to characterize the 0.8CaZrO3-0.2CaFe2O4 composite structure with particular emphasis on the role and position of iron in the function of sintering temperature. The paper presents the results of 57Fe Mössbauer effect at room temperature. It was found that the increase of sintering temperature causes an increase in the amount of incorporated iron ions in the CaZrO3-crystal structure. Based on Mössbauer spectroscopy analysis, it was found that three different environments of Fe3+ ions were observed in the obtained materials. Two of them corresponded to CaFe2O4 phase and one was associated with the substitution of Zr4+ by Fe3+ in the CaZrO3 structure.
Źródło:
Nukleonika; 2015, 60, 1; 147-150
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass
Autorzy:
Stoch, P.
Ciecińska, M.
Zachariasz, P.
Suwalski, J.
Górski, L.
Wójcik, T.
Powiązania:
https://bibliotekanauki.pl/articles/147350.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron phosphate glass
Mössbauer spectroscopy
nuclear waste
waste glass
Opis:
A 57Fe Mössbauer spectroscopy study is presented. The main goal of the research was to investigate the structural information of the glass-like the coordination numbers and redox ratio of the iron. Most of the iron, about 80%, is present in the glass as Fe3+, which is composed of tetrahedral (57%) and octahedral (23%) coordinated iron. The rest of the iron, about 20%, is in the oxidation state Fe2+. This iron could be mostly present as VIFe2+, but five-fold coordinated iron is also possible. Finally, the structural model of the synthesized 60P2O5-40Fe2O3 glass was proposed.
Źródło:
Nukleonika; 2013, 58, 1; 63-66
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass crystallization
Autorzy:
Stoch, P.
Stoch, A.
Powiązania:
https://bibliotekanauki.pl/articles/146169.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
crystallization
iron phosphate glass
Mössbauer spectroscopy
nuclear waste
waste glass
Opis:
60P2O5-40Fe2O3 glass was synthesized and 57Fe Mössbauer spectroscopy study was presented. The main goal of the research was to investigate structural changes of local environment of iron ions during gradual crystallization of the glass. It was observed that some changes were evidenced at temperature of heat treatment higher than 400°C, above which content of tetrahedrally coordinated Fe3+ was increased in cost of octahedral sites. This led to formation of areas of nucleation of α-FePO4. Crystallization of α-Fe3(P2O7)2 and Fe2P2O7 was also observed.
Źródło:
Nukleonika; 2015, 60, 1; 133-136
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural and Mössbauer effect studies of Dy(Fe0.4Co0.6-x Alx)2 intermetallics
Autorzy:
Stoch, P.
Pszczoła, J.
Suwalski, J.
Pańta, A.
Powiązania:
https://bibliotekanauki.pl/articles/148809.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
crystal structure
hyperfine interactions
Mössbauer spectroscopy
rare earth
Slater-Pauling curve
transition
Opis:
The magnetic hyperfine fields observed at the 57Fe nuclei (77 K) in the Dy(Mn1-xFex)2 and Dy(Fe1-xCox)2 intermetallics form a Slater-Pauling curve. In order to study the effect of cobalt atoms on crystal structure and hyperfine interactions, the new Co/Al substituted series Dy(Fe0.4Co0.6-xAlx)2 was prepared and data of X-ray powder analysis are presented (300 K). From the 57Fe Mössbauer measurements at 77 K the hyperfine parameters were obtained. The magnetic hyperfine fields form a branch of the Slater-Pauling curve.
Źródło:
Nukleonika; 2003, 48,suppl.1; 75-77
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
X-ray diffraction and Mössbauer spectroscopy investigations of the (Al, Ni, Co)-doped AgFeO2synthesized by hydrothermal method
Badania metodą dyfrakcji promieniowania Xoraz spektroskopii efektu Mössbauera AgFeO2domieszkowanego jonami Co, Ni i Al wytwarzanego metodą hydrotermalną
Autorzy:
Siedliska, Karolina
Powiązania:
https://bibliotekanauki.pl/articles/1841355.pdf
Data publikacji:
2020
Wydawca:
Politechnika Lubelska. Wydawnictwo Politechniki Lubelskiej
Tematy:
delafossites
hydrothermal synthesis
X-ray diffraction
Mössbauer spectroscopy
delafosyty
synteza hydrotermalna
dyfrakcja rentgenowska
spektroskopia mössabuerowska
Opis:
Delafossite AgFeO2, AgFe0.9Al0.1O2, AgFe0.9Ni0.1O2, and AgFe0.9Co0.1O2 powders were synthesized by hydrothermal method. The structural analysis and hyperfine interactions investigations were performed by X-ray diffraction and the Mössbauer spectroscopy. It was found that the (Al, Ni, Co)-doped delafossite phases with traces of metallic silver can be obtained during hydrothermal synthesis. Investigations revealed that the type of the incorporated element has an impact on the structural properties of the obtained delafossites. However, doping of cobalt, nickel, and alumina ions to the AgFeO2 delafossite structure does not cause significant changes in the values of the hyperfine interactions parameters. The of the Mössbauer spectra confirm the paramagnetic character of the obtained compounds at room temperature.
Proszkowe próbki delafosytów AgFeO2, AgFe0.9Al0.1O2, AgFe0.9Ni0.1O2, and AgFe0.9Co0.1O2 zostały wytworzone metodą hydrotermalną. Badania pozwalające na analizę strukturalną oraz oszacowanie parametrów oddziaływań nadsubtelnych przeprowadzono z wykorzystaniem dyfrakcji rentgenowskiej oraz spektroskopii efektu Mössbauera. Udowodniono, że za pomocą metody hydrotermalnej istnieje możliwość wytworzenia delafosytu AgFeO2 domieszkowanego jonami glinu, niklu i kobaltu z niewielką ilością zanieczyszczeń metalicznym srebrem. Badania wykazały, że rodzaj domieszki ma wpływ na właściwości strukturalne otrzymanych materiałów. Domieszkowanie jednak nie wpłynęło znacząco na zmiany wartości parametrów oddziaływań nadsubtelnych. Kształt zarejestrowanych widm mössbauerowskich potwierdza paramagnetyzm otrzymanych materiałów w temperaturze pokojowej.
Źródło:
Informatyka, Automatyka, Pomiary w Gospodarce i Ochronie Środowiska; 2020, 10, 4; 15-18
2083-0157
2391-6761
Pojawia się w:
Informatyka, Automatyka, Pomiary w Gospodarce i Ochronie Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 130

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