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Tytuł:
FT-IR, Thermal and NLO Studies on Amino Acid (L-Arginine and L-Alanine) Doped KDP Crystals
Autorzy:
Muley, G.
Rode, M.
Pawar, B.
Powiązania:
https://bibliotekanauki.pl/articles/1585044.pdf
Data publikacji:
2009-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Hq
Opis:
Single crystals of pure and amino acid (L-arginine and L-alanine) doped potassium dihydrogen phosphate (KDP) for second harmonic generation have been grown from low temperature solution growth method by employing slow evaporation of the solvent. FT-IR spectrum of pure and doped KDP crystals confirms qualitatively the doping of the L-arginine and L-alanine in the host crystals. UV-visible spectroscopy shows the improvement in the transparency. Crystal structure has been studied by powder X-ray diffraction. Modification in the lattice parameters has been observed. Improvement in the SHG efficiency was studied by the Kurtz and Perry method. Thermal analysis has been performed on the grown crystals.
Źródło:
Acta Physica Polonica A; 2009, 116, 6; 1033-1038
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Energy Transfer to Trace Impurities in Cs$\text{}_{2}$NaY$\text{}_{1-x}$Pr$\text{}_{x}$Cl$\text{}_{6}$: Consequences for Interpretation of Emission Decay Curves
Autorzy:
Vasquez, S. O.
Flint, C. D.
Powiązania:
https://bibliotekanauki.pl/articles/1945620.pdf
Data publikacji:
1996-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
13.40.Hq
31.70.Hq
61.72.Ss
78.55.Hx
Opis:
We report the $\text{}^{3}$P$\text{}_{0}$ → $\text{}^{3}$H$\text{}_{4}$ and $\text{}^{3}$P$\text{}_{0}$ → $\text{}^{3}$H$\text{}_{4}$ luminescence decay curves of Cs$\text{}_{2}$NaY$\text{}_{1-x}$Pr$\text{}_{x}$Cl$\text{}_{6}$ at 20 K as a function of excitation wave number in the region of the transitions to the $\text{}^{3}$P$\text{}_{0}$ state near 20602 cm$\text{}^{-1}$, the $\text{}^{3}$P$\text{}_{1}$ state near 21200 cm$\text{}^{-1}$ and the six components of the $\text{}^{1}$I$\text{}_{6}$ state distributed over the region 21164 to about 22000 cm$\text{}^{-1}$. For x = 0.001 and excitation into the absorption maxima, the decay curves are independent of excitation wave number and of the emission transition monitored, and are exactly exponential. Excitation at regions of weak absorption between the main absorption bands produces markedly different decay curves characterised by a prominent very fast relaxation at short times and a long exponential tail. The fast decay is strongly non-exponential. On increasing the temperature, this fast process becomes less prominent, and it is not detectable in the 298 K curves. For x>=0.05 the fast process is not present at any temperature. We propose that this fast process is due to emission from PrCl$\text{}_{6}^{3-}$ ions perturbed by a nearby water molecule.
Źródło:
Acta Physica Polonica A; 1996, 90, 2; 315-322
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Energy Transfer and Up-Conversion in the Erbium Elpasolites Cs$\text{}_{2}$NaEr$\text{}_{x}$Y$\text{}_{1-x}$Cl$\text{}_{6}$
Autorzy:
Campbell, M.
Flint, C. D.
Powiązania:
https://bibliotekanauki.pl/articles/1945497.pdf
Data publikacji:
1996-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
13.40.Hq
31.70.Hq
34.30.+h
61.72.Ss
78.55.Hx
Opis:
The luminescence decay curves from the $\text{}^{4}$F $\text{}_{9}\text{}_{/}\text{}_{2}$ and $\text{}^{4}$I $\text{}_{9}\text{}_{/}\text{}_{2}$ states of the cubic hexachloroelpasolite crystals Cs$\text{}_{2}$NaEr$\text{}_{x}$Y$\text{}_{1-x}$Cl$\text{}_{6}$ (x = 0.001÷1) have been measured over the temperature range 10-300 K. The $\text{}^{4}$I $\text{}_{9}\text{}_{/}\text{}_{2}$ state undergoes an electric dipole vibronic-electric dipole vibronic cross-relaxation process at 300 K, but this mechanism is inefficient below 165 K. Excitation into the $\text{}^{4}$F $\text{}_{9}\text{}_{/}\text{}_{2}$ state, results in emission in the green, blue and ultra violet regions. The up-conversion processes which could account for the ultraviolet emission are discussed.
Źródło:
Acta Physica Polonica A; 1996, 90, 1; 151-160
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Monte Carlo Study of Chain Entanglements in Polymer MeltDOI
Autorzy:
Sikorski, A.
Romiszowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/2028878.pdf
Data publikacji:
2001-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.50.Ng
61.25.Hq
Opis:
The new multibond algorithm for the Monte Carlo simulations of polymers developed for an isolated chain was extended for the case of dense polymer melts. Polymer chains were confined to a simple cubic lattice with excluded volume and no attractive interactions (good solvent conditions). The simulations were carried out by the means of the classical Metropolis scheme. The algorithm was verified by the analysis of static and dynamic properties of polymer melts. The dependence of the longest relaxation time and the self-diffusion coefficient on the chain length and the polymer concentration was discussed and the proper scaling laws were formulated. The number of entanglements, their distribution, and lifetimes were determined for different chain lengths and melt concentrations using the new algorithm.
Źródło:
Acta Physica Polonica A; 2001, 100, 4; 477-484
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photophysical Properties of Diphenylacetylene and Diphenylbutadiyne Derivatives in Solution Phase
Autorzy:
Hirata, Y.
Okada, T.
Nomoto, T.
Powiązania:
https://bibliotekanauki.pl/articles/1992658.pdf
Data publikacji:
1998-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
31.70.Hq
78.47.+p
Opis:
By using the femtosecond and picosecond transient absorption measurement techniques, we have investigated diphenylacetylene, diphenylbutadiyne, and their methoxy and cyano derivatives in the solution phase. Both the rapid S$\text{}_{2}$ → S$\text{}_{1}$ internal conversion in the subpicosecond time scale and the triplet formation in the tens of picosecond region were observed for diphenylbutadiyne and its methoxy derivatives, while the dynamic behavior of dimethoxy-diphenylacetylene was quite similar to that of diphenyl acetylene. The level inversion of the lowest excited singlet states of dicyano-diphenylbutadiyne was observed. The thermally activated S$\text{}_{2}$ ← S$\text{}_{1}$ internal conversion was not negligible and the sum of the rate constants of S$\text{}_{2}$ → S$\text{}_{1}$ and S$\text{}_{2}$ ← S$\text{}_{1}$ internal conversions was estimated to be about 5 × 10$\text{}^{11}$ s$\text{}^{-1}$ at room temperature.
Źródło:
Acta Physica Polonica A; 1998, 94, 4; 627-636
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New Multi-Bond Algorithm for Monte Carlo Simulation of Lattice Chains
Autorzy:
Romiszowski, P.
Sikorski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2011150.pdf
Data publikacji:
1999-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.50.Ng
61.25.Hq
Opis:
The new algorithm for the Monte Carlo simulations of polymer lattice chains was developed. The model chains were constructed on a simple cubic lattice. The simulations were carried out on chains with and without excluded volume effect using the Metropolis scheme. The basic concept of the new algorithm is the multi-bond modification of the chain conformation instead of applying the classical set of elementary micromodifications. The correctness of the algorithm was verified by studying both static and dynamic properties of the chains. The new algorithm was found to be 3 to 8 times faster than the classical one.
Źródło:
Acta Physica Polonica A; 1999, 96, 6; 691-697
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of pH on Paramagnetic Centers in Cladosporium cladosporioides Melanin
Autorzy:
Pilawa, B.
Buszman, E.
Gondzik, A.
Wilczyński, S.
Zdybel, M.
Witoszyńska, T.
Wilczok, T.
Powiązania:
https://bibliotekanauki.pl/articles/2043413.pdf
Data publikacji:
2005-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Hq
76.30.Rn
Opis:
Paramagnetic centers in melanin existing in pigmented soil fungi Cladosporium cladosporioides cultured at acidic (4, 5, 6), neutral (7), and alkaline (8) pH were studied by EPR method. o-semiquinone free radicals (g: 2.0032-2.0040) concentration in melanin biopolymer increased for pH from 4 to 6, decreased at pH 7, and reached the maximum value at pH 8. It may be expected that melanin free radicals reactions with small molecules (metal ions, drugs) are the most effective at pH between 6 and 8. Slow spin-lattice relaxation processes exist in the all studied melanin samples.
Źródło:
Acta Physica Polonica A; 2005, 108, 1; 147-150
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Paramagnetic Centers in DOPA-Melanin-Dihydrostreptomycin Complexes
Autorzy:
Buszman, E.
Pilawa, B.
Zdybel, M.
Wrześniok, D.
Grzegorczyk, A.
Wilczok, T.
Powiązania:
https://bibliotekanauki.pl/articles/2043624.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Hq
76.30.Rn
Opis:
DOPA-melanin-dihydrostreptomycin complexes with drug concentrations 1×10$\text{}^{-4}$-1×10$\text{}^{-2}$ M were examined by the use of electron paramagnetic resonance spectroscopy at X-band (9.3 GHz). Dihydrostreptomycin was chosen for studies, because this aminoglycoside antibiotic causes strong toxic effects in organism. It was stated that dihydrostreptomycin generates o-semiquinone free radicals with g=2.0038 in melanin. Free radicals formation increases with increase in the antibiotic concentration. Changes of EPR lines with microwave powers pointed out that slow spin-lattice relaxation processes exist in DOPA-melanin and in its complexes with dihydrostreptomycin. The measured EPR lines were homogeneously broadened.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 353-356
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Multi-Component EPR Spectra of Coals with Different Carbon Content
Autorzy:
Pilawa, B.
Więckowski, A. B.
Pietrzak, R.
Wachowska, H.
Powiązania:
https://bibliotekanauki.pl/articles/2043651.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Hq
76.30.Rn
Opis:
EPR spectra of lignite"Mequinenza" (Spain) (62.3 wt% C) and Polish orthocoking coal (87.8 wt% C) were compared. The spectra were superpositions of broad Gaussian, broad Lorentzian 1, and narrow Lorentzian 3 lines. Concentration of paramagnetic centers - mainly delocalizedπ electrons - responsible for narrow Lorentzian 3 lines increases with increase in carbon content in coal. Coal units with slow and fast spin-lattice relaxation processes exist in the two studied samples. Slow spin-lattice interactions occur in simple aromatic coal units with broad Gaussian and Lorentzian 1 lines. Fast spin-lattice relaxation processes are characteristic of large aromatic units with narrow Lorentzian 3 lines.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 403-407
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Laser Radiation on Free Radicals in Human Cancer G361 Cells
Autorzy:
Latocha, M.
Pilawa, B.
Zdybel, M.
Wilczok, T.
Powiązania:
https://bibliotekanauki.pl/articles/2043652.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.77.Hq
76.30.Rn
Opis:
EPR spectroscopy was used to the examination of free radicals evolution in cancer G361 cells during photodynamic therapy. The cancer cells were cultured with photosensitizer ALA and irradiated with 635 nm light by laser. The number of cells was determined microscopically. The decrease in the cell number and the increase in free radicals, obtained for G361 cells cultured with ALA and irradiated with laser, were stronger than relevant changes for the cells which were only irradiated with laser. The studied melanotic cells susceptible for photodynamic therapy differ from the other melanotic SK human cancer cells by fast spin-lattice relaxation processes. Slow spin-lattice relaxation processes exist in the studied earlier non susceptible for photodynamic therapy SK cells.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 409-412
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Transmission matrix and Faraday rotation in a structure composed of over-dense magnetized plasma, dielectric, and prism layers
Autorzy:
Nejati, M.
Rajaei, L.
Powiązania:
https://bibliotekanauki.pl/articles/1058194.pdf
Data publikacji:
2016-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
52.25.Xz
52.59.Hq
Opis:
In this study, the anomalous transmission of wave through over-dense magnetized plasma is investigated. Electromagnetic waves propagate in over-dense matter through an excitation of the surface waves. For excitation of the surface waves, the structure of the prism, dielectric and magnetized over-dense plasma are considered. Variations in the transmitted and reflected amplitudes with the incident angle θ is investigated. Moreover, the effect of the thicknesses of the dielectric and plasma layers and that of the plasma and cyclotron frequencies on the transmitted wave amplitude are studied. In addition, the Faraday rotation of the transmitted and reflected waves as functions of the incident angle is investigated. The effect of various parameters on the Faraday rotation is considered. The prism currently deployed in this structure decreases the restriction of dielectric constant and provides conditions for actual construction.
Źródło:
Acta Physica Polonica A; 2016, 130, 6; 1346-1351
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simulation of Radiation Effects in SiO₂/Si Structures
Autorzy:
Komarov, F.
Zayats, G.
Komarov, A.
Miskiewicz, S.
Michailov, V.
Komsta, H.
Powiązania:
https://bibliotekanauki.pl/articles/1402212.pdf
Data publikacji:
2015-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.30.Hq
02.60.Cb
Opis:
The space-time evolution of electric charge induced in the dielectric layer of simulated metal-insulator-semiconductor structures due to irradiation with X-rays is discussed. The system of equations used as a basis for the simulation model is solved iteratively by the efficient numerical method. The obtained simulation results correlate well with the respective data presented in other scientific publications.
Źródło:
Acta Physica Polonica A; 2015, 128, 5; 857-860
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Geometry of the Excited Charge Transfer States: Flattening or Twisting?
Autorzy:
Dobkowski, J.
Sazanovich, I.
Powiązania:
https://bibliotekanauki.pl/articles/1813988.pdf
Data publikacji:
2007-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.50.-j
61.66.Hq
Opis:
Numerous molecules built of an electron acceptor and electron donor units linked together by single bond exhibit a peculiar behavior in their low-lying electronically excited states. N,N-diethylaminoacetophenone and 4-acetyl-4'-dimethylamino-biphenyl, having acetophenone as the acceptor and differentiated by the donors groups $N(CH_3)_2$ and dimethylaniline, respectively, were selected as the subject of study. To recognize the excited state relaxation paths the stationary and time-resolved spectroscopy in absorption and emission was applied. Experimental results indicate that after excitation in polar solvents N,N-diethylaminoacetophenone reduces to minimum the overlap between π-electron systems of the donor and acceptor groups relaxing to the twisted internal charge-transfer state; contrary to that, flattening of the 4-acetyl-4'-dimethylamino-biphenyl skeleton generates increase in the overlap of the π-electron systems.
Źródło:
Acta Physica Polonica A; 2007, 112, S; S-127-S-142
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Studies of Carbonized Cellulose - Oxygen Interactions
Autorzy:
Pilawa, B.
Pietrzak, R.
Wachowska, H.
Babeł, K.
Powiązania:
https://bibliotekanauki.pl/articles/2043418.pdf
Data publikacji:
2005-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Hq
76.30.Rn
Opis:
EPR examination of cellulose carbonized at 400ºC and 600ºC has been performed. The aim of this work was to search a sample useful as the oximetric probe in biology and medicine. The higher paramagnetic centers concentration characterizes cellulose carbonized at 600ºC, which was found as the sensitive oximetric probe. Quasi-chemical bonds between cellulose molecules and paramagnetic O$\text{}_{2}$ molecules decrease paramagnetic centers concentration. A linear increase in paramagnetic centers concentration and a linear decrease in EPR linewidth with increasing time of sample evacuation were observed for cellulose carbonized at 600ºC. Oxygen affects spin-lattice interactions in carbonized cellulose.
Źródło:
Acta Physica Polonica A; 2005, 108, 1; 151-154
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Laguerre polynomial solutions of a class of initial and boundary value problems arising in science and engineering fields
Autorzy:
Gürbüz, B.
Sezer, M.
Powiązania:
https://bibliotekanauki.pl/articles/1061583.pdf
Data publikacji:
2016-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.30.Gp
02.30.Hq
02.70
Opis:
In this study, we consider high-order nonlinear ordinary differential equations with the initial and boundary conditions. These kinds of differential equations are essential tools for modelling problems in physics, biology, neurology, engineering, ecology, economy, astrophysics, physiology and so forth. Each of the mentioned problems are described by one of the following equations with the specific physical conditions: Riccati, Duffing, Emden-Fowler, Lane Emden type equations. We seek the approximate solution of these special differential equations by means of a operational matrix technique, called the Laguerre collocation method. The proposed method is based on the Laguerre series expansion and the collocation points. By using the method, the mentioned special differential equations together with conditions are transformed into a matrix form which corresponds to a system of nonlinear algebraic equations with unknown Laguerre coefficients, and thereby the problem is approximately solved in terms of Laguerre polynomials. In addition, some numerical examples are presented to demonstrate the efficiency of the proposed method and the obtained results are compared with the existing results in literature.
Źródło:
Acta Physica Polonica A; 2016, 130, 1; 194-197
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Stabilized 1D Metal in TTF(Ni(dmit)$\text{}_{2}$)$\text{}_{2}$ through Very Weak Coupling between Phonons and Weakly Correlated Fermions
Autorzy:
Doublet, M. L.
Malfant, I.
Hebrard, S.
Canadell, E.
Gaultier, J.
Chasseau, D.
Legros, J. P.
Brossard, L.
Powiązania:
https://bibliotekanauki.pl/articles/1933351.pdf
Data publikacji:
1995-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.Hk
71.45.Lr
61.66.Hq
Opis:
Extended Hückel band structure calculations derived from low temperature X-ray structural data, provide evidence, as temperature decreases, for an increasing 1D character of the multiparallel bands of the TTF(Ni(dmit)$\text{}_{2}$)$\text{}_{2}$ compound. This result is discussed within the monotonous metallic behaviour of the weakly correlated fermions gas, despite condensations of charge density wave instabilities.
Źródło:
Acta Physica Polonica A; 1995, 87, 4-5; 781-784
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Response of Superconductor Bolometer to Phonon Fluxes
Autorzy:
Danilchenko, B. A.
Jasiukiewicz, Cz.
Paszkiewicz, T.
Wolski, S.
Powiązania:
https://bibliotekanauki.pl/articles/2035733.pdf
Data publikacji:
2003-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
07.57.Kp
02.30.Hq
66.70.+f
Opis:
A metallic film bolometer with heat capacity C is in contact with thermal bath and with crystalline specimen and is biased by a constant current I$\text{}_{b}$. The thermal contact of the bolometer is characterized by the thermal conductance G. The bolometer operates in the linear regime of dependence of resistance on temperature characterized by a constantα. Experiments which allow one to measureα, C, and G are proposed. The characteristic timeτ=C/G and characteristic current I$\text{}_{m}=\sqrt{\text{G/α}}$ affect the effective relaxation rateΛ of the bolometer resistance R$\text{}_{b}$(t). The knowledge of the power W(t) absorbed by detector allows one to calculate R$\text{}_{b}$(t). The inverse problem of calculation of W(t) from known R$\text{}_{b}$(t) is also solved. The suitable algorithms are proposed. Deconvoluted absorbed power is obtained for experiments performed on GaAs and compared with phonoconductivity signal of two-dimensional electron gas structure as well as with results of Monte Carlo computer experiments.
Źródło:
Acta Physica Polonica A; 2003, 103, 4; 325-338
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Shape of Confined Polymer Chains
Autorzy:
Sikorski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2035734.pdf
Data publikacji:
2003-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.50.Ng
05.10.Ln
61.25.Hq
Opis:
The linear polymer chains were modeled on a simple cubic lattice. The excluded volume was included into the model while the system remained athermal (no attractive interactions) which simulated the good solvent conditions. The polymer chain was located between two parallel impenetrable walls and the distance between the walls was changing. No interaction between walls and polymer segments was assumed. These models of polymer chains were simulated by the means of the Monte Carlo method. In the sampling algorithm we used the micromodifications of chain's conformations to sample efficiently the conformational space. The size of the chain did not change monotonically for all lengths under consideration (up to 800 statistical segments). For distances between the plates close to the double value of chain's radius of gyration the size of the chain approached its minimum value. It was shown that scaling of chain dimensions with its length changed from N$\text{}^{1.18}$ to N$\text{}^{1.5}$ while the distance between the walls was decreasing. The behavior of the asymmetry of the chain was found to be analogous to that of the radius of gyration.zapisz i p
Źródło:
Acta Physica Polonica A; 2003, 103, 4; 339-347
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Time Differential Perturbed Angular γγ-Correlation Studies of Diethylenetriaminepentaacetic Acid Complexes with $\text{}^{111}$In and $\text{}^{111m}$Cd
Autorzy:
Shpinkova, L. G.
Carbonari, A. W.
Nikitin, S. M.
Mestnik-Filho, J.
Powiązania:
https://bibliotekanauki.pl/articles/2029030.pdf
Data publikacji:
2001-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
23.20.En
23.40.-s
61.66.Hq
Opis:
Static and dynamic electric quadrupole interactions of $\text{}^{111}$Cd in complexes with diethylenetriaminepentaacetic acid were studied by the time differential perturbed angular γγ-correlation technique using two parent isotopes, $\text{}^{111}$In(EC)$\text{}^{111}$Cd and $\text{}^{111 m}$Cd. The measurements were carried out using neutral aqueous solutions of the diethylenetriaminepentaacetic- acid-complexes with initial isotopes at 293 K and 77 K. It was shown that the $\text{}^{111}$Cd-diethylenetriaminepentaacetic-acid-complex in aqueous solutions at pH = 7.0 is characterised by the re-orientational correlation time of 7.7×10$\text{}^{-11}$ s and an electric field gradient V$\text{}_{zz}$=6.7(2)×10$\text{}^{21}$ V/m$\text{}^{2}$ with an asymmetry parameter η=0.75(5). A direct comparison of the electric quadrupole interaction parameters for diethylenetriaminepentaacetic- acid-complexes with $\text{}^{111}$In and $\text{}^{111m}$Cd confirmed the proposal about the fragmentation of the complexes caused by the after-effects of electron capture in $\text{}^{111}$In. An observed difference in the electric quadrupole interaction parameters obtained for the solutions with $\text{}^{111}$In and $\text{}^{111m}$Cd complexes reflects a process of a chemical rearrangement of the complex structure after the In decay into Cd
Źródło:
Acta Physica Polonica A; 2001, 100, 5; 799-805
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photoinduced Charge Separation Processes in Supramolecular Triad Systems
Autorzy:
Pirowska, K.
Najbar, J.
Powiązania:
https://bibliotekanauki.pl/articles/1992700.pdf
Data publikacji:
1998-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
31.70.Hq
82.30.Fi
87.15.Rn
Opis:
The nonadiabatic electron transfers in donor-acceptor-acceptor systems are investigated using three potential energy surfaces and two reaction coordinates via the stochastic Liouville equation to describe time evolution of the three excited electronic states: (1) D*-A-A, (2) D$\text{}^{+}$-A$\text{}^{-}$-A and (3) D$\text{}^{+}$-A-A$\text{}^{-}$. The electronic dephasing processes are taken into account phenomenologically in terms of dephasing constants. The couplings between surfaces are effective along the intersections of pairs of surfaces in the two-dimensional coordinate space. Special situations occur in the reaction coordinate space when three surfaces are nearly degenerate. The interplay between the sequential electron transfer processes and the superexchange process is analysed for different: reorganization energies, electronic coupling, free energies for the electron transfer, dephasing rates, and temperature. The time dependent contribution of the superexchange process to the charge separation in the triad system is analysed using the time dependent rate functions. It is shown that in the nonadiabatic limit of electron transfer the influence of the electronic dephasing processes for low barrier reactions can be accounted for by appropriate changes in the reorganization energies. The present model is compared with the experimental results concerning the charge separation in the bacterial photosynthetic reaction centers.
Źródło:
Acta Physica Polonica A; 1998, 94, 4; 637-654
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Development of Free Volumes in Nafion Membrane
Autorzy:
Melikhova, O.
Čížek, J.
Košinová, L.
Hruška, P.
Powiązania:
https://bibliotekanauki.pl/articles/1033913.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
61.66.Hq
82.35.Lr
Opis:
In this work we employed positron lifetime spectroscopy for investigation of the thermal development of free volumes in H⁺ Nafion membrane over a broad range of temperatures from -150 to 150°C. Positron lifetime studies were combined with differential scanning calorimetry. Size distribution of free volumes was determined from ortho-positronium contribution to positron lifetime spectra. Our investigations revealed that the mean size of free volume holes strongly increases with temperature. On the other hand, the width of the size distribution and the positronium yield decreases with temperature. Transition temperatures corresponding to a change in the slope of the temperature dependence of ortho-positronium lifetime were identified. Results of positron lifetime spectroscopy agree well with the curve obtained by differential scanning calorimetry.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1538-1542
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Casimir Force between Nanoparticles Immersed in a Crosslinked Polymer Blend
Autorzy:
El Fassi, S.
Benhamou, M.
Boughou, M.
Kaidi, H.
El Yaznasni, M.
Ridouane, H.
Powiązania:
https://bibliotekanauki.pl/articles/1535673.pdf
Data publikacji:
2010-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.25.Hq
64.75.+g
82.70.Gg
Opis:
We consider a crosslinked polymer blend made of two polymers of different chemical nature. We suppose that such a system incorporates small colloidal particles, which prefer to be attracted by one polymer, close to the spinodal temperature. This is the so-called critical adsorption. As assumption, the particle diameter, $d_0$, is considered to be small enough in comparison with the size of microdomains (mesh size) ξ* ~ $an^{1//2}$, with a - the monomer size and n - the number of monomers between consecutive crosslinks. The critical fluctuations of the crosslinked polymer mixture induce a pair-potential between particles located in the non-preferred phase. The purpose is the determination of the Casimir pair-potential, $U_2 (r)$, as a function of the interparticle distance r. To achieve calculations, use is made of an extended de Gennes field theory that takes into account the colloid-polymer interactions. Within the framework of this theory, we first show that the pair-particle is attractive. Second, we find for this potential the exact form: $U_2(r)//k_{B}T = - A_{H}(d_0//r)^2 exp(-r//ξ*) - B_{H}(d_0//r)^4 exp(-2r//ξ*)$, with the known universal amplitudes $A_{H}$ > 0 and $B_{H}$ > 0 (the Hamaker constants). This expression clearly shows that the pair-potential differs from its homologue with no crosslinks only by the two exponential factors exp(-r/ξ*) and exp(-2r/ξ*). The main conclusion is that the presence of reticulations reduces substantially the Casimir effect in crosslinked polymer blends.
Źródło:
Acta Physica Polonica A; 2010, 118, 4; 606-612
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Evidence for Thermally Excited Triplet States in Exinite, Vitrinite and Inertinite Separated from Bituminous Coal
Autorzy:
Słowik, G. P.
Wojtowicz, W.
Więckowski, A. B.
Powiązania:
https://bibliotekanauki.pl/articles/2043436.pdf
Data publikacji:
2005-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Hq
76.30.Rn
87.64.Hd
Opis:
In this work we have made an electron spin resonance (EPR) study of macerals obtained from the lithotype clarain separated from Polish medium-rank coal (85.6 wt.% C). For three macerals:~exinite, vitrinite, and inertinite, the temperature dependence of intensity of EPR spectra in the temperature range of 100-373 K was investigated. The experimentally obtained EPR spectra of macerals were fitted by curves of the derivatives of the Gaussian and Lorentzian functions. The best fitting was obtained, when the experimental EPR spectra were assumed to be a superposition of three lines, for exinite and vitrinite - a broad Gaussian (G), a broad Lorentzian (L1) and a narrow Lorentzian (L3) line, but for inertinite of two lines - a narrow Lorentzian (L2) and a narrow Lorentzian (L3) line. The computer-assisted fitting has shown that each individual component line has similar values of resonance field, but different linewidths and amplitudes. The temperature dependence of line intensity I of the broad Gaussian (G) and narrow Lorentzian (L2 and L3) lines fulfils the Curie law in the form I=C/T or IT=C, whereas the broad Lorentzian (L1) line does not fulfil the Curie law. In the last case the temperature dependence of the Lorentzian (L1) component was fitted by the relation I=C/T+B/[T(3+exp(J/kT))] or IT=C+B/[3+exp(J/kT))], valid for thermally excited triplet states (S=1). For exinite and vitrinite the curves presenting the temperature dependence of the product IT versus temperature T were resolved into two curves, one for paramagnetic centres in the doublet state (S=1/2), and the other for paramagnetic centres in the thermally excited triplet state (S=1).
Źródło:
Acta Physica Polonica A; 2005, 108, 1; 171-176
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure of Dense Polymer Systems Confined to a Slit
Autorzy:
Sikorski, A
Powiązania:
https://bibliotekanauki.pl/articles/2044630.pdf
Data publikacji:
2006-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.50.Ng
05.10.Ln
61.25.Hq
Opis:
The linear polymer chains were approximated as series of identical segments on a simple cubic lattice. The excluded volume was included into the model with no attractive interactions which corresponded to the good solvent conditions. The polymer chains were put into a slit formed by a pair of parallel surfaces. These walls were impenetrable for polymer segments and no other interactions between walls and chains were assumed. The models chains were studied by the means of the Monte Carlo method. The sampling algorithm was Metropolis-type and employing micromodifications of chain's conformation to sample efficiently the conformational space. The influence of the chain length, density of the polymer system, and the distance between the surfaces on the shape of macromolecules was studied. It was found that the decrease in the size of the slit and the decrease in the polymer density led to the formation of more spherical macromolecules. This is partially caused by the interpenetration of polymer chains.
Źródło:
Acta Physica Polonica A; 2006, 109, 2; 133-141
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solution of a Class of Optimization Problems Based on Hyperbolic Penalty Dynamic Framework
Autorzy:
Evirgen, F.
Powiązania:
https://bibliotekanauki.pl/articles/1031640.pdf
Data publikacji:
2017-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
02.60.Pn
02.70.-c
02.30.Hq
Opis:
In this study, a gradient-based dynamic system is constructed in order to solve a certain class of optimization problems. For this purpose, the hyperbolic penalty function is used. Firstly, the constrained optimization problem is replaced with an equivalent unconstrained optimization problem via the hyperbolic penalty function. Thereafter, the nonlinear dynamic model is defined by using the derivative of the unconstrained optimization problem with respect to decision variables. To solve the resulting differential system, a steepest descent search technique is used. Finally, some numerical examples are presented for illustrating the performance of the nonlinear hyperbolic penalty dynamic system.
Źródło:
Acta Physica Polonica A; 2017, 132, 3; 1062-1065
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
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