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Tytuł:
Spectrophotometric determination of copper as copper Piperazine
Autorzy:
Kavitha, Ch.
Babu, M. S.
Saraswathi, K.
Powiązania:
https://bibliotekanauki.pl/articles/412355.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
spectophotometry
Cu(II)
piperazine
Opis:
Spectrophotometric method for determination of Cu(II) in the trace quantities was developed by using piperazine as ligand in ammonium acetate medium. The Procedure developed was applied for the estimation Cu(II) in microgram quantities in the samples of alloys and the method was found to be simple, rapid and comparable to routine analytical methods for trace level analysis of metal ions in environmental samples in any laboratory where sophisticated and expensive instruments are not available. UV visible spectrophotometer is cost effective and available in almost all laboratories. The complexes of piperazine in aqueous solutions are not reported so far and this is the first attempt in this area of spectrophotometric analysis.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 8, 3; 205-209
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ocena zawartości smektytu w niektórych ceramicznych surowcach ilastych na podstawie spektrofotometrycznych badań sorpcyjnych
Analysis of smectite content in certain raw clay minerale based on sorption-spectrophotometric studies
Autorzy:
Panna, W.
Prosowicz, G
Wyszomirski, P.
Powiązania:
https://bibliotekanauki.pl/articles/141795.pdf
Data publikacji:
2014
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
iły krakowieckie
smektyty
sorpcja TETA Cu(II)
sorpcja błękitu metylenowego
Krakowiec clays
smectites
TETA Cu(II) sorption
methylene blue sorption
Opis:
Przedmiotem badań była ocena zawartości smektytu w wybranych iłach krakowieckich, stanowiących podstawowy surowiec przemysłu ceramiki budowlanej w południowo-wschodniej Polsce. Badania te przeprowadzono stosując głównie spektrofotometryczne metody sorpcyjne przy użyciu trietylenotetraaminy miedzi (II) (TETA Cu(II)) oraz błękitu metylenowego. Uzyskane wyniki różniły się względem siebie, a różnice w oznaczeniach dochodziły do 6%. Stwierdzono, że bardziej dokładną ocenę zawartości smektytu uzyskuje się przy zastosowaniu sorpcji jonowymiennej kompleksu miedzi. Badane iły charakteryzują się zmienną zawartością tego minerału mieszczącą się w przedziale 13 – 20%. W celu weryfikacji wyników oznaczeń wykonano również analizy: rentgenograficzną i składu ziarnowego. Podwyższona zawartość chlorytu w badanych próbkach i częściowa koincydencja jego najbardziej diagnostycznego, niskokątowego refleksu 14 Å z refleksem smektytu 12,5÷15 Å uniemożliwiła jednak jednoznaczne oszacowanie udziału tego drugiego minerału.
The object of the study is the analysis of smectite content in selected Krakowiec clays that are basic materials for construction ceramics industry in south-eastern Poland. The studies were carried out mainly by means of sorption-spectrophotometric methods with copper (II) triethylenetetramine (TETA Cu(II)) and methylene blue. The results differed in respect to each other and differences of determination were as high as 6%. It was found that more accurate analysis of smectite content can be achieved using ion-exchange sorption of copper complex. Studied clays have variable content of smectite in the range of 13 – 20%. In order to verify determination results, X-ray and particle size distribution analysis were also performed. The increased chlorite content in studied samples and the partial coincidence of its most diagnostically useful low-angle reflection (14 Å) with the smectite reflection 12.5-15 Å have made it impossible to accurately estimate content of the latter.
Źródło:
Chemik; 2014, 68, 7; 612-619
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Lignocellulosic fraction of the pericarps of the acorns of Quercus suber and Quercus ilex: isolation, characterization, and biosorption studies in the removal of copper from aqueous solutions
Autorzy:
Mébarki, Moubarek
Hachem, Kadda
Harche, Meriem Kaid
Powiązania:
https://bibliotekanauki.pl/articles/779763.pdf
Data publikacji:
2019
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
adsorption
Cu(II)
lignocellulosic fraction
pericarp
Quercus sp.
Opis:
Pericarps of Algerian Quercus ilex (Q. ilex) and Quercus suber (Q. suber) were used as copper adsorbents in artifi cially contaminated solutions. Exposing accessible lignocellulosic binding sites enhanced adsorption. The lignocellulosic fractions of Q. suber and Q. ilex (36.47±9.1 and 47.66±9.3, respectively) were characterized by FTIR before and after adsorption. The aim was to identify the functional groups adsorbing Cu(II). SEM/EDX determined lignocellulose surface morphology and composition. The amount of adsorbent-bound Cu(II) increased with initial [Cu(II)]. Cu(II) adsorption range was 23.59–48.06 mg.g–1 for Q. Suber and 22.56–38.19 mg.g–1 for Q. ilex when [Cu(II)] was 100–500 mg.L–1. Adsorption isotherms and Langmuir and Freundlich models of the Q. suber and Q. ilex lignocellulosic fractions indicated natural Cu(II)adsorption capacities (Qmax) of 53.76 mg.g–1 and 36.06 mg.g–1 and KF of 5.9 mg.g–1 and 7.43 mg.g–1, respectively.
Źródło:
Polish Journal of Chemical Technology; 2019, 21, 3; 40-47
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simultaneous removal of phenol and Cu(II) from wastewater by tallow dihydroxyethyl betaine modified bentonite
Autorzy:
Hu, Xiangyang
Wang, Bao
Yan, Gengsheng
Ge, Bizhou
Powiązania:
https://bibliotekanauki.pl/articles/2203123.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
simultaneous adsorption
tallow dihydroxyethyl betaine
bentonite
Cu(II)
phenol
Opis:
An organobentonite modified with an amphoteric surfactant, tallow dihydroxyethyl betaine (TDHEB), was used as an adsorbent to simultaneously remove Cu(II) and phenol from wastewater. The characteristic of the organobentonite (named TDHEB-bentonite) was analyzed by X-ray diffraction, Fourier-transform infrared spectra and nitrogen adsorption-desorption isotherm. Batch tests were conducted to evaluate the adsorption capacities of TDHEB-bentonite for the two contaminants. Experiment results demonstrated that the adsorption of both contaminants is highly pH-dependent under acidic conditions. TDHEB-bentonite had about 2.0 and 5.0 times higher adsorption capacity toward Cu(II) and phenol, respectively, relative to the corresponding raw Na-bentonite. Adsorption isotherm data showed that the adsorption processes of both contaminants were well described by Freundlich model. Kinetic experiment demonstrated that both contaminants adsorption processes correlated well with pseudo-second-order model. Cu(II) had a negative impact on phenol adsorption, but not vice versa. Cu(II) was removed mainly through chelating with the organic groups (-CH2CH2OH and -COO-) of TDHEB. Otherwise, partition into the organic phase derived from the adsorbed surfactant was the primarily mechanism for phenol removal. Overall, TDHEB-bentonite was a promising adsorbent for removing Cu(II) and phenol simultaneously from wastewater.
Źródło:
Archives of Environmental Protection; 2022, 48, 3; 37--47
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dobry amyloid β? Właściwości chemiczne peptydów Aβ4-x wskazują na ich znaczenie biologiczne
Good β-amyloid? Chemical properties of Aβ4-x peptides indicate their biological relevance
Autorzy:
Bal, Wojciech
Powiązania:
https://bibliotekanauki.pl/articles/172163.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
peptydy β-amyloidowe
choroba Alzheimera
ATCUN/NTS
wiązanie Cu(II)
aktywność redoks
amyloid β peptides
Alzheimer’s disease
Cu(II) binding
redox reactivity
Opis:
Alzheimer’s Disease is a neurodegenerative condition, an irreversible progressive dementia caused by death of neurons in brain structures responsible for memory related processes. Despite many years of research and numerous trials, no therapy succeeded that could stop the development of this disease, which affects tens of millions of patients worldwide. The amyloid cascade prevails among a variety of possible mechanisms of its development proposed in the scientific literature. It proposes that death of neurons, preceded by dysfunction of their synaptic activity is caused by the incremental formation of structures (fibrils, oligomers) composed of Aβ peptides. In its copper variant the processes of aggregation and oxidative stress, causing the inflammation and neuronal damage are related to the formation of reactive Cu(II) complexes with Aβ peptides. Aβ peptides are a family of molecules with similar amino acid sequences, differing mainly by the presence of longer or shorter terminal sequences. Their physiological role of is unclear. Aβ1-42 and Aβ1-40 have been mostly studied, but most studies have ignored a very abundant N-terminally truncated species Aβ4-42. We recognized it, and more gene-rally the Aβ4-x peptide family as potentially strong Cu(II) ligands, due to the presence at their N-termini of the Phe-Arg-His amino acid sequence, comprising the ATCUN/NTS structural motif. This observation was followed by vigorous research performed in our laboratory. We studied the ability of Aβ4-x peptides to bind Cu(II) ions, their electrochemical properties and redox reactivity, interactions with proteins which bind copper under physiological conditions, their aggregation properties in the Cu(II) presence and susceptibility to proteolysis. Additionally, we investigated their interaction with a molecule of a therapeutic potential. We demonstrated that Aβ4-x peptides can be primary copper bin-ding agents in extracellular spaces in the brain, able to instantaneously intercept copper from Aβ1-x peptides studied so far. Cu(II) complexes of Aβ4-x peptides are highly resistant to oxidation and reduction, release copper ions to other molecules slowly and reluctantly, and do not produce reactive oxygen species. In accordance with these properties we proposed a physiological role for the Aβ4-42 peptide as a molecule cleansing the synaptic cleft from Cu2+ ions and thereby assuring the correct neurotransmission. This function can however be disturbed by an inappropriate pharmacological intervention. The results of studies of the effect of cupric ions on the aggregation and membrane interactions of the Aβ4-40 peptides suggest that copper can inhibit the Aβ4-x peptides toxicity, thereby providing an additional support for our concept. Studies of hydrolysis of Aβ peptides and properties of its products revealed a possibility for a significant role of short fragments in the brain copper physiology. Our hypothesis awaits verification by biological studies. The issue of metabolism of the studied complexes is a key issue remaining to be solved.
Źródło:
Wiadomości Chemiczne; 2019, 73, 5-6; 351-366
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of tetrazole moiety on coordinating efficiency of deltorphin.
Autorzy:
Łodyga-Chruścińska, Elżbieta
Ołdziej, Stanisław
Micera, Giovanni
Sanna, Daniele
Chruściński, Longin
Olczak, Jacek
Zabrocki, Janusz
Powiązania:
https://bibliotekanauki.pl/articles/1043323.pdf
Data publikacji:
2004
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
Cu(II) complexes
opiod peptides
tetrazole analogues of deltorphin I
Opis:
A study of the effect of the tetrazole moiety, a cis-amide bond surrogate, on the Cu(II) coordinating properties of oligopeptides is reported. Insertion of the tetrazole moiety Ψ[CN4] into the peptide sequence of [D-Ala2]deltorphin I changes considerably the coordination ability of the peptide. Potentiometric and spectroscopic results show that if the tetrazole moiety is in a suitable position in the peptide chain, i.e. it follows the second residue, a stable CuL species involving 3N coordination is formed in the physiological pH range. The tetrazole Ψ[CN4] ring provides one of these nitrogens. The data indicate that Cu(II) ions are strongly trapped inside a bent peptide backbone. The peptide conformation changes achieved by Cu(II) coordination may be essential for the binding of tetrazole deltorphins at opiate receptors.
Źródło:
Acta Biochimica Polonica; 2004, 51, 1; 93-106
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reactivity of nZVI in the removal of Cu(II) and Zn(II) from synthetic mine drainage
Autorzy:
Suponik, Tomasz
Neculita, Carmen Mihaela
Powiązania:
https://bibliotekanauki.pl/articles/2032928.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
mining industry
nZVI
zero-valent iron
Cu(II)
Zn(II)
przemysł wydobywczy
Opis:
Adsorption properties, including isotherms and kinetics, of nano zero-valent iron (nZVI) for Cu(II) and Zn(II) removal from synthetic mine drainage were evaluated in batch tests. The influence of contact time, nZVI doses, pH, ionic strength, temperature, and concentration on nZVI adsorption properties was assessed. The removal of Cu(II) and Zn(II) increased with pH from 3 to 7 and then stabilized up to pH 10. Moreover, the increased Cu(II) adsorption capacity upon increasing temperature and a positive enthalpy change (ΔH) indicate that the adsorption process is endothermic. The results also showed that the adsorption equilibrium for Cu(II) and Zn(II) was achieved after 50 and 30 min, respectively. Kinetics were best described by a pseudo-nth order model, with the order of sorption of 2.231 and 1.363, and the rate constants of 0.0008 and 0.0679 mg1-n·gn-1/min, for Cu(II) and Zn(II), respectively. The correlation between the amount of metals adsorbed on nZVI surface and the residual amount of metals in water during isothermal tests was best described by the nonlinear Sips model. Using this model, high q maxS were found: 286.6 mg/g and 142.6 mg/g, for Cu(II) and Zn(II), respectively, as indication of their high sorption capacity.
Źródło:
Environment Protection Engineering; 2021, 47, 2; 93-108
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reduction of NO with methane over metal ion-exchanged mordenite
Autorzy:
Ćwikła-Bundyra, W.
Powiązania:
https://bibliotekanauki.pl/articles/346983.pdf
Data publikacji:
2011
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
selective catalytic reduction of NO
mordenite
catalysts
Co(II)
Ni(II)
Cu(II)
Opis:
This article presents the results of research studies on the possibilities of application of natural zeolite-mordenite for the reduction of nitrogen oxide. Various kinds of metal ions were added to the zeolite samples using the ion-exchange method. The effect of metal contents was shown for the mordenite and related to their catalytic properties. The catalytic properties of Cu-, Co-, Ni- were compared for NO reduction with methane. High nitric oxide conversions were observed for copper and cobalt-mordenite, especially in the temperature range between 400 and 500 C degree. Copper- and cobaltmordenite catalysts showed higher activities and selectivities than catalysts composed of nickel-exchanged mordenite.
Źródło:
Ars Separatoria Acta; 2011, 8; 109-119
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructural and Equilibrium Adsorption Study of the System of Waste Foundry Molding Sand/Cu (II) Ions
Autorzy:
Strkalj, A.
Glavas, Z.
Slokar, L.
Powiązania:
https://bibliotekanauki.pl/articles/354568.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
waste foundry molding sand
Cu (II) ions
adsorption
SEM/EDS analysis
Opis:
This paper deals with the waste foundry molding sand which originally comes from the casting production. Adsorption of Cu (II) ions on the waste foundry molding sand was studied. Experimental data were processed using adsorption isotherms. Obtained results show that the experimental data are best described by the Langmuir isotherm. The following adsorption capacities are obtained: 7.153 mg/g to 293 K, 8.403 mg/g at 333 K and 9.208 mg/g at 343 K. The kinetics and thermodynamics of the process were analysed. The obtained results indicate that the adsorption process takes place according to the pseudo second order kinetic model with the following constants: 0.438 g/mg min at 293 K, 0.550 g/mg min at 333 K and 1.872 g/mg min at 343 K. The following values of ΔG° were obtained: − 95.49 J/mol at 293 K, − 736.99 J/mol at 333 K and − 1183.46 J/mol at 343 K. The value of ΔH° is − 4.16 kJ/mol and the value of ΔS° is 15.17 J/molK. These results were confirmed by microscopic examinations. The results indicate that the adsorption process of Cu (II) ions on waste foundry molding sand is possible. Results of microscopic examinations show the homogeneity of the surface, which is proof of the chemisorption. Cu (II) ions on the surface of the waste foundry molding sand were detected after adsorption by EDS analysis, which proves the existence of the adsorption process.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 4; 1805-1812
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A modified nanoporous stir bar for simultaneous determination of Cu(II) and Cd(II) ions in natural samples prior to flame atomic absorption spectroscopy
Autorzy:
Karimi, M.
Aboufazeli, F.
Zadeh Zhad, H. R. L.
Sadeghi, O.
Najafi, E.
Powiązania:
https://bibliotekanauki.pl/articles/780050.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
stir bar sorptive extraction
nanoporous structure
Cd(II) and Cu(II) determination
FAAS
Opis:
In this work, the application of stir bar sorptive extraction (SBSE), as a fast and conventional method, has been investigated for the simultaneous preconcentration and determination of trace amounts of Cd(II) and Cu(II) ions in natural samples. For this purpose, the surface of stir bar was functionalized by amine functionalized nanoporous silica and characterized by IR spectroscopy, X-ray powder diffraction (XRD), Atomic force microscopy (AFM) and N2 adsorption. In this approach, after the preconcentration of Cd(II) and Cu(II) ions and removing the matrix interferences using modified stir bar, the amounts of these ions were determined in eluent by flame atomic absorption spectroscopy (FAAS). Various parameters on adsorption and elution steps including pH of sample, adsorption kinetic, eluent parameters (type, volume and concentration) and elution time, have been optimized in this study. The limits of detection (LOD) were 1.6 and 13.8 ng mL-1 (recovery of 83.5 and 88.1%) for cadmium and copper ions, respectively. The preconcentration factors were 133 and 137 and the relative standard deviations (RSD) of the method were 5.7 and 4.6% for Cd(II) and Cu(II) ions, respectively. As the key point in this study seems to be stir bar nanoporous structure, the analytical performance of this stir bar was compared to non-porous ones. The accuracy of this novel method has been confirmed using some standard references materials. Finally the potential of this method was investigated by determination of Cd(II) and Cu(II) ions in some real samples with complicated matrixes.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 2; 86-93
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of Cu(II) and Pb(II) from aqueous solutions by lactic acid bacteria
Usuwanie Cu(II) I Pb(II) z roztworów wodnych przez bakterie kwasu mlekowego
Autorzy:
Wierzba, S.
Powiązania:
https://bibliotekanauki.pl/articles/127425.pdf
Data publikacji:
2015
Wydawca:
Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:
biosorption
Cu(II)
Pb(II)
isotherm
lactic acid bacteria
biosorpcja
izoterma
bakterie kwasu mlekowego
Opis:
The aim of the study was to compare the removal of Cu(II) and Pb(II) from aqueous solution by lactic acid bacteria (LAB). Effect of various process parameters, viz., initial metal ions concentration, pH, and contact time has been studied for the removal of copper and lead ions. Langmuir and Freundlich models were applied to describe the biosorption isotherm of the metal ions by LAB biomass. Langmuir model fitted the equilibrium data better than the Freundlich isotherm. The sorbent showed the maximum sorptive capacity amounting to be 11.07 and 10.51 mg · g–1 for Cu(II) and Pb(II) ions, respectively. The optimum conditions were pH 6.0 with equilibrium time of 40 min for both metal ions. The involvement of functional groups on the surface of dried biomass in biosorption process is also discussed.
Celem pracy było porównanie zdolności usuwania Cu(II) i Pb(II) z roztworu wodnego przez bakterie kwasu mlekowego (LAB). Badano wpływ różnych parametrów, tj. stężenia jonów metali, pH i czas kontaktu, na proces usuwania jonów miedzi i ołowiu. Do opisu izoterm adsorpcji jonów metali przez biomasę LAB zastosowano modele Langmuira i Freundlicha. Uzyskane dane doświadczalne były lepiej dopasowane do modelu Langmuira niż Freundlicha. Sorbent wykazał maksymalną zdolność sorpcyjną, wynoszącą 11,07 i 10.51 mg · g–1 odpowiednio dla jonów Cu(II) i Pb(II). Optymalne warunki biosorpcji obu jonów metali wynosiły: pH 6,0 i czas równowagi 40 minut. Omówiono również udział grup funkcyjnych na powierzchni biomasy w procesie biosorpcji.
Źródło:
Proceedings of ECOpole; 2015, 9, 2; 505-512
1898-617X
2084-4557
Pojawia się w:
Proceedings of ECOpole
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Use of synthetic zeolite materials from fly ash to remove copper(II) ions from aqueous solutions
Autorzy:
Ulatowska, Justyna
Stala, Łukasz
Nowakowska, Alicja
Polowczyk, Izabela
Powiązania:
https://bibliotekanauki.pl/articles/1450167.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fly ash
copper oxide (II)
Cu(II)
modification of fly ashes
zeolite materials
adsorption
Opis:
Water quality and waste management are two chief problems that the modern world is struggling with. Intensified development of the industry not only leads to the production of large amounts of solid waste that must be stored in landfills but can also result in contaminant emissions into the environment. Enormous quantities of ash produced from coal combustion have been a long-term problem of the industry. Literature studies show that fly ash can be used as a material to produce cheap and efficient zeolite-type adsorbents due to abundance of alumina-silicates in their composition. Fly ashes which were processed into zeolites as a result of alkaline hydrothermal treatment were obtained from two power plants in Poland (in Turów and Zgierz). The obtained zeolite materials and raw fly ash samples were characterised in terms of specific surface area, particle size distribution and density. The structure was also investigated using Fourier transform infrared spectroscopy (FTIR) in the mid- infrared wavenumber range. Two raw fly ashes and two zeolite materials were examined for their ability to remove Cu(II) ions from aqueous solutions. The results showed that the amount of adsorbed copper ions by alkaline-modified fly ash was higher than for unmodified fly ash. The ion removal efficiency is high and exceeds 95%.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 114-124
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Struktura pochodnych benzo[ b]furanu i kumaryny oraz ich kompleksów z miedzią (II) i cynkiem(II)
The structure of benzo[b]furan and courmarin derivatives and their copper (II) and zinc (II) complexes
Autorzy:
Drzewiecka, A.
Powiązania:
https://bibliotekanauki.pl/articles/172518.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
pochodne benzo[b]furanu
pochodne kumaryny
kompleks Cu(II)
kompleks Zn(II)
struktura kryształu
badania XAS
benzo(b)furan derivatives
coumarin derivatives
Cu(II) complex
Zn(II) complex
crystal structure
XAS study
Opis:
Selected benzo[b]furan and coumarin derivatives with proven and potential antibacterial, anticancer and antiarrhythmic activities have been investigated [1–3] (Figs. 1 and 2). The stereochemical description of their molecules in the solid and gas phase as well as intra- and intermolecular-interactions in crystals have been determined [4–6]. The structural studies of analyzed molecules indicated the planarity of the benzo[b]furan and coumarin ring systems. The oxygen or carbon atoms of the substituents, –OH, –OCH3, –C(=O)CH3 and –COO H, are nearly coplanar with the aromatic ring. The hydroxyl and acetyl groups, being in the ortho position, are coplanar with the aromatic ring and the formation of the intramolecular O–H…O hydrogen bond in all three states of matter is observed. Its strength is around 18 kcal/mol. Several conformers of studied compounds, differing in the orientation of the methoxy, acetyl and/or carboxyl groups, were analyzed. Next, the electrochemical method was used to synthesize novel copper and zinc complexes with the oxygen donor benzo[b]furan and coumarin derivatives. The Cu(II) and Zn(II) complexes have been obtained with carboxylic acids as ligands whereas hydroxy ligands reacted only with copper [6]. The geometry of metal-ligand interaction of new compounds has been determined using a single crystal X-ray crystallography and an X-ray absorption spectroscopy [7, 8]. The combination of these two methods revealed that for some compounds cation environment could depend on the form of the solid sample. In the microcrystalline zinc complexes (studied by EXAFS) the cation is penta-coordinated (ZnO5) with the Zn–O distances being ca 1.98(3) Ĺ. In the recrystallized complex (analyzed by the X-ray diffraction) it was found that zinc is tetra-coordinated (ZnO4). The Cu(II) cation in the singlecrystal form of the complex with the carboxylic acid 5 is penta-coordinated to the carboxylate groups and the ethanol molecule. The bridging COO – groups stabilize the dinuclear complex center Cu2O10. The powdered form of this complex is based on the Cu2O8 units, indicating the absence of the ethanol molecule in the coordination sphere. In the series of the Cu(II) complexes with the hydroxy derivatives of benzo[b]furan and coumarin a centrosymmetric coordination polyhedron of metal exhibits a square-planar geometry (CuO4). Two ligands are bonded to the copper cation via the acetyl and deprotonated hydroxyl O atoms.
Źródło:
Wiadomości Chemiczne; 2012, 66, 3-4; 355-369
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New application of D-π-A molecules as a sensor for recognition of Cu2+ in polluted water
Autorzy:
Niu, H.
Zhu, G.
Zhu, M.
Li, X.
Powiązania:
https://bibliotekanauki.pl/articles/207782.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
polluted water
nuclear magnetic resonance spectroscopy
Cu(II)
woda zanieczyszczona
spektroskopia magnetycznego rezonansu jądrowego
Opis:
Novel chromophore GZP1 with D-π-A structure was designed and prepared for its application as a sensor for the recognition of Cu2+ ions in polluted water. Reaction of aldimine condensation was used to synthesize chromophore GZP1. Its chemical structure of was characterized by mass spectrum, nuclear magnetic resonance spectroscopy and ultraviolet-visible absorption spectrum. Cu2+ ions were recognized via fluorescence spectra. Chromophore GZP1 showed specific detection ability of Cu2+. 14 other metal ions were used as reference. The detection limit was estimated to be 0.06 μmol/dm3 in aqueous solution, which was significantly lower than the typical concentration of blood Cu2+ in normal individuals and the limit of copper(II) in drinking water.
Źródło:
Environment Protection Engineering; 2017, 43, 4; 67-72
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of modified maize hull for removal of Cu(II) ions from aqueous solutions
Autorzy:
Ghasemi, S. M.
Mohseni-Bandpei, A.
Ghaderpoori, M.
Fakhri, Y.
Keramati, H.
Taghavi, M.
Moradi, B.
Karimyan, K.
Powiązania:
https://bibliotekanauki.pl/articles/208248.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
heavy metal ions
waste water
Cu(II)
ions
adsorption
biomass
jony metali ciężkich
ścieki
biomasa
adsorpcja
Opis:
Discharge of industrial waste containing heavy metals to the environment is a main concern because of their toxicity to many life forms. Adsorption process is one of the conventional methods in order to adsorb heavy metals from wastewater effluents. Therefore, the removal of Cu(II) from aquatic solutions using modified maize hull was investigated. All experiments were performed in batch conditions. The residual Cu(II) concentration was measured by AAS. Upon increasing the adsorbent dosage, pH, and contact time and decreasing Cu(II) concentration, the removal efficiency of Cu(II) ions increased. In optimum conditions, 50% of copper was removed by modified maize hull. The experimental data were best fitted by the Langmuir type 2 model and the adsorption kinetic model followed a pseudo-second order type 1 model. It seems that the use of the modified maize hull to remove Cu(II) ions is very suitable, low-cost, and efficient.
Źródło:
Environment Protection Engineering; 2017, 43, 4; 93-103
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
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