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Wyświetlanie 1-8 z 8
Tytuł:
Thermal Desorption Studies of $Ar^{+}$ Implanted Silicon
Autorzy:
Drozdziel, A.
Wojtowicz, A.
Turek, M.
Pyszniak, K.
Maczka, D.
Slowinski, B.
Yushkevich, Y.
Zuk, J.
Powiązania:
https://bibliotekanauki.pl/articles/1382778.pdf
Data publikacji:
2014-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.Vx
61.72.uf
Opis:
Thermal desorption spectrometry measurements were performed for Ar implanted Si samples. Implantation energy $E_{i}$ varied in the range 85-175 keV. The release of implanted Ar in two steps was observed in the temperature range 930-1300 K: the relatively narrow peak at lower temperature ( ≈ 930 K for implantation fluence 5 × $10^{16}$ $cm^{-2}$) is due to the release of Ar from the agglomerations (bubbles) while the broader peak observed for higher temperatures ( ≈ 950 K for implantation fluence 5 × $10^{16}$ $cm^{-2}$) comes from Ar atoms diffusing out of the sample. Inverse order of peaks is observed compared to the results for lower energy implantations (< 50 keV). Analyzing the thermal desorption spectra collected for different heating ramp rates enabled estimation of the desorption activation energy (2 eV for $E_{i}$ = 85 keV and 1.7 eV for $E_{i}$ = 115 keV).
Źródło:
Acta Physica Polonica A; 2014, 125, 6; 1400-1403
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Desorption of Krypton Implanted into Silicon
Autorzy:
Turek, M.
Droździel, A.
Wójtowicz, A.
Filiks, J.
Pyszniak, K.
Mączka, D.
Yuschkevich, Y.
Powiązania:
https://bibliotekanauki.pl/articles/1030211.pdf
Data publikacji:
2017-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.Vx
61.72.uf
Opis:
The thermal desorption spectrometry studies of krypton implanted Si samples are presented. Implantations (with the fluence 2×10¹⁶ cm¯²) were done with the energies 100, 150, and 200 keV. Additionally, a 200 keV and 100 keV Kr⁺G double implantation was performed. A sudden Kr release was observed in the ≈1100-1400 K range, most probably coming from the gas bubbles in cavities. The desorption activation energy varies from 2.5 eV (100 keV) to 0.8 (200 keV). The peak splitting suggests existence of two kinds of cavities trapping the implanted noble gas. Two Kr releases are observed for the 200 and 100 keV double-implanted samples. The peak shift of the release corresponding to 100 keV implantation could be a result of both introduced disorder and higher effective Kr concentration. The desorption activation energy is risen to ≈3.2 eV for both releases.
Źródło:
Acta Physica Polonica A; 2017, 132, 2; 249-253
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Desorption of Helium from Defected Silicon
Autorzy:
Turek, M.
Droździel, A.
Pyszniak, K.
Wójtowicz, A.
Mączka, D.
Yuschkevich, Y.
Vaganov, Y.
Żuk, J.
Powiązania:
https://bibliotekanauki.pl/articles/1402210.pdf
Data publikacji:
2015-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.Vx
61.72.uf
Opis:
The thermal desorption spectroscopy measurements of He implanted silicon samples are reported. The He implantation energy was 90 keV (at 45° tilt) while the fluence was 10¹⁶ cm¯². Additionally, the influence of Si pre-implantation (fluences in the range 10¹⁴-10¹⁶ cm¯², E=260 keV) was under investigation. The He releases from both interstitials/vacancies (β peak) and cavities (α peak or rather band consisting probably of at least two peaks) were observed. The α peak disappears for the pre-implantation fluences larger than 10¹⁵ cm¯², while β peak becomes broader and shifts toward higher temperatures. The thermal desorption spectra were collected using heating ramp rates in the range 0.3-0.7 K/s. Desorption activation energy of the β peak for different pre-implantation fluences was found using the Redhead analysis of the β peak shift. It varies from 0.97 eV for the sample that was not pre-implanted up to 1.3 eV for the sample pre-implanted with the fluence 10¹⁶ cm¯².
Źródło:
Acta Physica Polonica A; 2015, 128, 5; 849-852
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Desorption of Au from W(001) Surface
Autorzy:
Błaszczyszyn, R.
Chrzanowski, J.
Godowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/2035647.pdf
Data publikacji:
2002-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.Vx
68.55.Ac
68.60.Dv
Opis:
Adsorption of Au on W(001) at 450 K up to multilayer structures was investigated. Temperature programmed desorption technique was used in determination of coverage dependent desorption energy (region up to one monolayer). Results were discussed in terms of competitive interactions of Au-Au and Au-W atoms. Simple procedure for prediction of faceting behavior on the interface, basing on the desorption data, was postulated. It was deduced that the Au/W(001) interface should not show faceting tendency after thermal treatment.
Źródło:
Acta Physica Polonica A; 2002, 102, 6; 785-794
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Desorption of Gasses Induced by Ferroelectric Transition in SbSI Nanowires
Autorzy:
Szperlich, P.
Nowak, M.
Jesionek, M.
Starczewska, A.
Mistewicz, K.
Szala, J.
Powiązania:
https://bibliotekanauki.pl/articles/1376059.pdf
Data publikacji:
2014-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.Vx
77.84.-s
68.43.-h
62.23.Hj
Opis:
For the first time the thermal desorption of $H_2$, $N_2$, $O_2$ and $CO_2$ is presented for antimony sulfoiodide (SbSI) xerogel made up of large quantity nanowires. The desorption has been observed near ferroelectric phase transition established at $T_{c}$=293.0(2) K. The Sievert measurements have shown that the hydrogen uptake is linear function of $H_2$ pressure (when p < 1.1×$10^5$ Pa). The hydrogen storage density in SbSI gel amounted 1.24× $10^{-2}$ wt% (for p = 1.08×$10^5$ Pa at room temperature).
Źródło:
Acta Physica Polonica A; 2014, 126, 5; 1110-1112
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Local Rigidity as a Criterion of Gas Permeation of Polymer and Composition Materials; PAL and TSL Experiments
Autorzy:
Shantarovich, V.
Gustov, V.
Belousova, E.
Polyakova, A.
Bekeshev, V.
Kevdina, I.
Yampolskii, Yu.
Pastukhov, A.
Powiązania:
https://bibliotekanauki.pl/articles/1196455.pdf
Data publikacji:
2014-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
61.43.Fs
68.43.Vx
78.70.Bj
82.35.Lr
Opis:
Various commercial and industrial properties of polymeric materials can be developed by the way of purposeful synthesis. For example, there are polymeric materials of extremely developed intrinsic microporosity. In attempts to further develop membrane properties (permeability and selectivity), the researchers artificially increase the pore sizes by various external influences, such as plastification by saturation of polymers with gases, sometimes in supercritical state, filling of a polymer with some non-organic components (zeolites). Sometimes, porosity of the composition appears to become higher than that of the components. This porosity, in difference with intrinsic one, can be called externally affected. The reason of these phenomena is not always clear, and in order to get some ideas in this field we suggest an experimental study using a combination of the two genetically interconnected (by spur processes) methods: positron annihilation lifetime spectroscopy and thermostimulated luminescence. This paper summarizes recently published and completely new results of the authors in order to illustrate the benefits of this experimental approach.
Źródło:
Acta Physica Polonica A; 2014, 125, 3; 806-811
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sorption of Neodymium and Gadolinium on Transcarpathian Clinoptilolite
Autorzy:
Vasylechko, V.
Stechynska, E.
Stashkiv, O.
Gryshchouk, G.
Patsay, I.
Powiązania:
https://bibliotekanauki.pl/articles/1029699.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.-h
07.60.Dq
82.75.Vx
Opis:
The sorption properties of Transcarpathian clinoptilolite towards Nd(III) and Gd(III) under dynamic condition have been studied. Nd(III) was sorbed with the best efficiency on the uncalcined clinoptilolite samples from the solutions at pH 6.5. Clinoptilolite samples that were previously calcined at 250°C exhibit the maximal sorption capacity towards Gd(III) from the solutions at pH 9.5. Nd(III) and Gd(III) sorption on clinoptilolite mechanisms are different: Nd(III) is sorbed according to the ion-exchange mechanism, and the sorption of Gd(III) is carried out mainly by means of the adsorption of soluble hydrolyzed forms of Gd(III) on the zeolite surface. The differences in sorption mechanisms of these lanthanides give an opportunity to separate Nd(III) and Gd(III) from the solutions at pH 9.5. The maximal sorption capacity of the clinoptilolite regarding Nd(III) and Gd(III) at the optimal conditions was found to be 1810 and 6500 μg/g. The best desorbent of Nd from the clinoptilolite is 7 M HNO₃ solution. The best desorbent of Gd is 1 M solution of KCl acidified to pH 2.6, which provides a 100% withdrawal of Gd from the zeolite matrix. Transcarpathian clinoptilolite is proposed as a sorbent for the preconcentration of trace amounts of Nd(III) and Gd(III) from aqueous solutions in a solid phase extraction mode.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 794-797
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR Study of Dealuminated HY Zeolite and Silica Containing Cu-Mn-Zn Spinels: The Effect of Support
Autorzy:
Decyk, P.
Więckowski, A.
Najder-Kozdrowska, L.
Bilkova, I.
Ziółek, M.
Powiązania:
https://bibliotekanauki.pl/articles/1030220.pdf
Data publikacji:
2017-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.43.-h
76.30.-v
76.30.Fc
82.75.Vx
Opis:
A mixture of antiferromagnetic Cu_{1.4}Mn_{1.6}O₄ and Cu_{0.5}Zn_{0.5}Mn₂O₄ or/and ZnMn₂O₄ spinels was prepared. Dealuminated HY zeolite and silica were doped by these Cu-Mn-Zn spinels. The materials were investigated by X-ray diffraction, the Fourier transform infrared spectroscopy and EPR spectroscopy. Additionally, all the samples were tested for their activity for isopropyl alcohol dehydration/dehydrogenation. Three EPR signals were observed for Cu-Mn-Zn/dealuminated HY and Cu-Mn-Zn/SiO₂ samples at 293 K. In contrast to the spectra recorded at 293 K, only one broad line attributed to Cu-Mn-Zn spinels was visible at 77 K. The EPR signal from pure Cu-Mn-Zn spinels consists only of a single broad line when recorded at 293 K, whereas at 77 K the line is narrower. For all samples subjected to evacuation at high vacuum up to 573 K, the Cu-Mn-Zn spinels were stable. The evacuation at 673 K resulted in a rapid lowering of the intensity of EPR spectrum.
Źródło:
Acta Physica Polonica A; 2017, 132, 1; 38-44
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-8 z 8

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