- Tytuł:
- Theoretical Explanations of the Optical Band Positions and Local Structure for $Cu^{2+}$ Centers in $ZnO-Bi_{2}O_{3}-B_{2}O_{3}-CuO$ Glasses
- Autorzy:
- Yuan, M.
- Powiązania:
- https://bibliotekanauki.pl/articles/1377767.pdf
- Data publikacji:
- 2014-12
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
61.72.Bb
75.10.Dg
76.30.-v
76.30.Fc - Opis:
- The local structure, two optical band positions and three electronic spin resonance parameters for $Cu^{2+}$ centers at the tetragonally-distorted octahedral sites in $ZnO-Bi_2O_3-B_2O_3-CuO$ glasses are calculated from the high-order perturbation method based on the two-spin-orbit-parameter model, where the contributions from both the spin-orbit coupling parameters of central $d^{n}$ ion and ligand ion are included. The theoretical results are in good agreement with the experimental values. The calculations show that the high-order perturbation method based on the two-spin-orbit-parameter model is effective in the explanations of optical spectra, electronic spin resonance parameters and local distortion structure for $d^{9}$ ions in glasses.
- Źródło:
-
Acta Physica Polonica A; 2014, 126, 6; 1293-1295
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł