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Tytuł:
Quantitative processing of situation awareness for autonomous ships navigation
Autorzy:
Zhou, X. Y.
Liu, Z. J.
Wu, Z. L.
Wang, F. W.
Powiązania:
https://bibliotekanauki.pl/articles/117424.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
autonomous vessel
autonomous ship
autonomous ships navigation
situation awareness (SA)
quantitative processing
navigation safety
remotely controlled vessel
maritime unmanned navigation through intelligence in networks (MUNIN)
Opis:
The first ever attempt at fully autonomous dock-to-dock operation has been tested and demonstrated successfully at the end of 2018. The revolutionary shift is feared to have a negative impact on the safety of navigation and the getting of real-time situation awareness. Especially, the centralized context onboard could be changed to a distributed context. In navigation safety domain, monitoring, control, assessment of dangerous situations, support of operators of decision-making support system should be implemented in real time. In the context of autonomous ships, decision-making processes will play an important role under such ocean autonomy, therefore the same technologies should consist of adequate system intelligence. At the same time, situation awareness is the key element of the decision-making processes. Although there is substantial research on situation awareness measurement techniques, they are not suitable to directly execute quantitative processing for the situation awareness of autonomous ships navigation. Hence, a novel quantitative model of situation awareness is firstly proposed based on the system safety control structure of remotely controlled vessel. The data source is greatly limited, but the main result still indicates that the probability of operator lose adequate situation awareness of the autonomous ship is significantly higher than the conventional ship. Finally, the paper provides a probabilistic theory and model for high-level abstractions of situation awareness to guide future evaluation of the navigation safety of autonomous ships.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2019, 13, 1; 25-31
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental and optimization design of offshore drilling seal
Autorzy:
Zhang, Y.
Zhang, X.
Chang, X.
Wu, Q.
Powiązania:
https://bibliotekanauki.pl/articles/260627.pdf
Data publikacji:
2017
Wydawca:
Politechnika Gdańska. Wydział Inżynierii Mechanicznej i Okrętownictwa
Tematy:
offshore drilling
design optimization
seals
finite element analysis
MATLAB
Opis:
Three-cone bit is the key equipment in the exploration of the oil in offshore drilling and exploration, the bearing system and the seal system are the critical components for the bit. Especially in the offshore drilling environment, the seal design need to be carefully considered. A multi-objective optimization design including orthogonal design method and F-test with finite element analysis for a three-cone bit seal is proposed. Firstly, the calculation method of optimization targets are given, including the minimization of maximum contact pressure and leakage rate analyzed by ANSYS and MATLAB respectively, to maximize seal life and reliability. Then, an orthogonal experiment approach is used to investigate the effects of the eleven parameters on the seal performance, and the influence degrees of the seal factors on the optimization targets have been confirmed by F-test, and the reasonable factors can be determined by the trend of the targets. Finally, in order to validate the analysis results, a new seal was designed and tested on a seal tester compared to the previous seal. In this test, the seal maximum interface temperature that reflects the position of maximum contact pressure can be obtained by using three high precision thermocouples. Both the experiment results and the numerical analyses proved that the maximum contact pressure and leakage rate of the improved seal have been reduced compared to the previous.
Źródło:
Polish Maritime Research; 2017, S 3; 72-78
1233-2585
Pojawia się w:
Polish Maritime Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Genetic diversity and relationship of Hunan province of China local tree peonies based on SSR markers
Autorzy:
Zhang, M.-H.
Jin, X.-L.
Wen, Y.-F.
Shen, S.
Wen-Xing
Wu, S.
Lu, J.-H.
Ye-Ye
Powiązania:
https://bibliotekanauki.pl/articles/12665369.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Przyrodniczy w Lublinie. Wydawnictwo Uniwersytetu Przyrodniczego w Lublinie
Tematy:
China
Hunan Province
plant cultivation
tree peony
Paeonia suffruticosa
ornamental plant
genetic diversity
genetic relationship
SSR marker
Opis:
Paeonia sect. Moutan is a wide known ornamental plant in the world. The objective of this study was to provide the theoretical basis for scientific preservation and utilization of tree peony resources of Hunan province of China. Simple sequence repeat (SSR) markers were applied to reveal the genetic diversity and relationship of 21 tree peony resources and 45 domestic and foreign tree peony cultivars. Clear bands, the size of which ranged from 115 bp to 379 bp, were detected with 14 primers. In total, 90 alleles were detected and the number of alleles detected with one primer varied between 5 and 13; the number of effective alleles ranged from 1.183 to 2.070; the polymorphism ratio of each locus was 100%. The observed heterozygosity, which ranged from 0.120 to 0.851 with an average of 0.532, was larger than the expected one, which ranged from 0.090 to 0.470 with an average of 0.300. Shannon index ranged from 0.137 to 0.695 and fixation index ranged from −0.332 to −0.869. The results show abundant genetic diversity in tree peony of Hunan province and SSR markers distinguishing homonymous tree peony resources successfully.
Źródło:
Acta Scientiarum Polonorum. Hortorum Cultus; 2019, 18, 4; 213-223
1644-0692
Pojawia się w:
Acta Scientiarum Polonorum. Hortorum Cultus
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reconstruction of oviraptorid clutches illuminates their unique nesting biology
Autorzy:
Yang, T.-R.
Wiemann, J.
Xu, L.
Cheng, Y.-N.
Wu, X.-C.
Sander, P.M.
Powiązania:
https://bibliotekanauki.pl/articles/19933.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Opis:
Oviraptorosaurs, a group of non-avian theropod dinosaurs from the Cretaceous of Asia and North America, left behind the most abundant and informative fossil evidence of dinosaur reproductive biology. Previous studies had suggested that oviraptorosaur reproductive biology represents an intermediate stage and exhibited unique modern avian traits. For instance, the adult-associated clutches were predominantly considered as evidence for brooding/thermoregulatory contact incubation (TCI) behaviors, whereas the hypotheses of laying or protection were neglected. Despite numerous oviraptorid egg clutches uncovered from China and Mongolia, their nest architecture and clutch arrangement were rarely investigated in detail. Here we present a comprehensive reconstruction of an oviraptorid clutch based on five new oviraptorid clutches from Jiangxi Province, China. A detailed examination of the new clutches reveals a partially-open oviraptorid nest that contains 3–4 rings of paired eggs (more than 15 pairs total) whose blunt end points toward the center devoid of eggs at an angle of 35–40°. Our detailed three-dimensional reconstruction indicates that the oviraptorid clutch has a unique architecture unknown from extant bird clutches, implying an apomorphic nesting mode. Such a unique nest architecture further contradicts the TCI hypothesis in oviraptorids, hindering sufficient heat transfer to the inner (lower) ring(s) of eggs. Moreover, the size of the new oviraptorid clutches (>30 eggs) is significantly larger than that of the adult-associated clutches (<22 eggs), raising the alternative hypothesis that the adult-associated clutches were uncompleted. This clue thus supports the hypothesis that the clutch-associated oviraptorid adults possibly represent females after an oviposition before a catastrophic sandstorm/flooding burial.
Źródło:
Acta Palaeontologica Polonica; 2019, 64, 3
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Luminescence of hydrothermally fabricated PbF2:Er3+ particles and their application in bifacial silicon solar cells
Autorzy:
Yang, F
Wu, C.
Hao, X
Chen, Y.
Lu, J.
Yang, Sh.
Powiązania:
https://bibliotekanauki.pl/articles/174503.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
PbF2
Er3+ particles
hydrothermal method
upconversion
Opis:
We report the synthesis of PbF2:Er3+ particles using a hydrothermal method. The structure and upconversion emission properties of the products are investigated by scanning electron microscopy, X-ray diffractometer, Raman spectrophotometer and fluorescence spectrometry. An increase in Er3+ concentration in the crystals changes the PbF2 structure from a mixed phase to a cubic phase and decreases the grain size to nanoscale levels. Enhanced upconversion efficiency is achieved after annealing resulted from the formation of the cubic phase and the increase of grain size. The optimal Er3+ concentration is found to be 4% after annealing, and applied to the back of a bifacial silicon solar cell, maximum external quantum efficiencies of 0.38% and 0.79% are respectively obtained under 0.77 W/cm2 laser excitation (1560 nm) and AM1.5 + laser co-excitation.
Źródło:
Optica Applicata; 2014, 44, 3; 463-473
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A polarization selective beam splitter based on a subwavelength multisubpart profile grating structure
Autorzy:
Xiao, Y.
Huang, L.
Wu, H.
Sun, X.
Xiao, W.
Duan, J.
Powiązania:
https://bibliotekanauki.pl/articles/174760.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
diffraction and gratings
polarizing beam splitter
PBS
leaky-mode resonance
LMR
Opis:
In this study, a polarization selective beam splitter constructed by only a single layer subwavelength multisubpart profile grating is presented. Rigorous coupled-wave analysis is adopted to investigate the properties of the structure. It is shown that for a transverse electric polarized wave, the device demonstrates very high reflectivity (>97%) from 1.46 to 1.58 μm; and for a transverse magnetic polarized wave, at the wavelength of 1.55 μm, it exhibits about 50/50 beam ratio under normal incidence. To evaluate the response of the polarizing beam splitters under variation in structure parameters, we also investigated the fabrication tolerances of the device.
Źródło:
Optica Applicata; 2016, 46, 4; 665-672
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fatigue life prediction for Ni-based superalloy GH4169 considering machined surface roughness and residual stress effects
Autorzy:
Wu, Z. R.
Wang, S. Q.
Yang, X.
Pan, L.
Song, Y. D.
Powiązania:
https://bibliotekanauki.pl/articles/1839712.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
surface roughness
residual stress
fatigue crack
life prediction
GH4169
Opis:
Establishing a fatigue life prediction model considering the machined surface state is of great significance to improve fatigue life prediction accuracy. Fatigue tests with different machined surface states of GH4169 alloy were conducted firstly. The influence of surface state parameters on the fatigue life was analyzed. Then, the machined surface stress concentration factor and residual stress were introduced into the fatigue crack initiation and propagation models. Finally, the fatigue life prediction model of GH4169 material considering the surface states was established. The prediction results based on the proposed model are almost within a factor of two scatter band of the test results.
Źródło:
Journal of Theoretical and Applied Mechanics; 2021, 59, 2; 215-226
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Manifestations of sustainable development in China: based on policy study
Przejawy zrównoważonego rozwoju w Chinach: na podstawie analizy strategii politycznych
Autorzy:
Wu, Y.
Zhong, X.
Powiązania:
https://bibliotekanauki.pl/articles/2164632.pdf
Data publikacji:
2022
Wydawca:
Akademia Bialska Nauk Stosowanych im. Jana Pawła II w Białej Podlaskiej
Tematy:
China
sustainable development
policy
strategy
cooperation
Opis:
Subject and purpose of work: This article aims to better understand China’s actions and challenges encountered in sustainable development due to the COVID-19 crisis, economic difficulties, and the war between Russia and Ukraine. It also aims to provide valuable recommendations for China or other countries concerning future sustainable development work. Materials and methods: We reviewed extensive literature and made a policy content analysis as the research methodology. Results: We concluded that China has put emphasis on sustainable development since ancient times. China has made notable progress in sustainable development both domestically inside China and worldwide. However, China also faces challenges related to sustainable development within China itself. Conclusions: Although China has launched effective policies that have received positive feedback, there is still a long way to go to achieve truly sustainable development. We suggest that all countries, regions, and individuals take a joint action in order to achieve a sustainable planet for us and future generations.
Źródło:
Economic and Regional Studies; 2022, 15, 3; 269-283
2083-3725
2451-182X
Pojawia się w:
Economic and Regional Studies
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of provenance and water stress on biomass and polyphyllin content in the medicinal plant Paris polyphylla Smith var. yunnanensis
Autorzy:
Wu, X.
Zuo, .
Zhang, Q.
Wang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/12304075.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Przyrodniczy w Lublinie. Wydawnictwo Uniwersytetu Przyrodniczego w Lublinie
Tematy:
plant cultivation
Paris polyphylla
medicinal plant
herbal plant
water stress
biomass
polyphyllin content
Opis:
Water stress and provenance could affect the secondary metabolites synthesis and accumulation in herbs. Thus, this study explored the effect of soil water moisture and provenance on the growth of Paris polyphylla Smith var. yunnanensis (PPY). Three provenances (Jinping, Luquan and Weixi in Yunnan, China) of PPY samples were grown in different soil water moisture conditions [0.80, 0.70 and 0.50 field capacity (FC)] during Dec. 2015 to Sep. 2017. Results showed that the highest biomass weight was presented in 0.70 FC for Luquan and Weixi samples. Biomass weight for Jinping provenance presented a decreasing tendency with the decreased soil water moisture and the highest biomass were shown in 0.80 FC. However, quantitative analysis revealed that the total content of polyphyllin increased with decreasing the soil water moisture for Jinping and Weixi samples. The highest total content of polyphyllin in rhizome was inclined to show in Jinping samples, while the stem and leaf tissues were shown in Weixi samples. Additionally, results of ANOVA combined with PCA indicated that the difference among these three provenances were significant. Correlation analysis results revealed that 0.50 FC induced the competitive relationship occurrence for polyphyllin distribution. Thus, 0.70 FC was the most suitable soil-water condition for PPY growth. Besides, provenance collected from Jinping could consider as a good quality germplasm. Consequently, this study might provide a preliminary foundation for irrigation project formulated and provenance screened for PPY cultivation.
Źródło:
Acta Scientiarum Polonorum. Hortorum Cultus; 2019, 18, 2; 171-191
1644-0692
Pojawia się w:
Acta Scientiarum Polonorum. Hortorum Cultus
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prokaryotic expression, purification and antigenicity analysis of African swine fever virus pK205R protein
Autorzy:
Wu, X.
Xiao, L.
Peng, B.
Wang, Y.
Yang, Z.
Yao, X.
Hu, L.
Lin, X.
Powiązania:
https://bibliotekanauki.pl/articles/30963.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
African swine fever is an acute, febrile and highly virulent porcine disease causing serious economic losses worldwide. The pK205R protein of the African swine fever virus (ASFV) is largely expressed in the early stages of infection, which has given the K205R gene extensive attention. In this study, the ASFV K205R was cloned and expressed in Escherichia coli BL21 (DE3). Expression of histidine-tagged pK205R with a molecular mass of 44 kDa was determined by 12% sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) and Western blot analysis. Optimisation of culture conditions allowed induction of the recombinant protein with 0.4 mM Isopropyl β-D-thiogalactoside (IPTG) at 37oC for 2 h. The protein existed in cellular supernatant and was purified using a Ni-NTA resin column. The purified protein was used to immunize rabbits four times to enable the production of polyclonal antibodies, and the antiserum titre was detected by ELISA. The results showed that the purified pK205R can react with ASFV positive serum specifically by Western blotting. The pK205R had high antigenicity, which indicated that pK205R could be used as an antigen for detection of ASFV-specific antibodies in ELISA testing, and the recombinant protein could contribute to further research of the action and structure of pK205R.
Źródło:
Polish Journal of Veterinary Sciences; 2016, 19, 1
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
pUC18-CpG stimulates RAW 264.7 via TBK1-mediated pathway and presents adjuvanticity in mice
Autorzy:
Wu, J.
Chen, Q.
Xin, T.
Sun, Y.
Jia, H.
Hou, S.H.
Guo, X.Y.
Powiązania:
https://bibliotekanauki.pl/articles/2087554.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
adjuvant
CpG DNA
Echinococcus granulosus
TBK1
type I interferons
Źródło:
Polish Journal of Veterinary Sciences; 2019, 2; 195-201
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Failure mechanism and supporting measures for large deformation of soft rock roadway in Baluba copper mine
Mechanizm pękania skał i kroki zapobiegawcze podejmowane w celu przeciwdziałania odkształceniom chodnika prowadzonego w skałach miękkich w kopalni miedzi Baluba
Autorzy:
Wu, A.
Chen, S.
Wang, Y.
Chen, X.
Powiązania:
https://bibliotekanauki.pl/articles/219772.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
chodnik prowadzony w skałach miękkich
analiza teoretyczna
symulacje numeryczne
eksperymenty w terenie
parametry podpór stropu
soft rock roadway
theoretical analysis
numerical simulation
field experiments
support parameters
Opis:
To solve the problem of large deformation soft rock roadway with complicated stress condition in Baluba copper mine, the characteristics of roadway deformation and failure modes are analyzed deeply on the basis of geological survey. Combined with the theoretical analysis and numerical simulation, the new reinforcement technology with floor mudsill and grouting anchor cable is proposed. Moreover, the three dimension numerical simulation model is established by the software FLAC-3D, the support parameter is optimized by it. The results show that the optical array pitch of the U-steel shelf arch is 0.8 m, and the optical array pitch of the grouting anchor cable is 2.4 m. At last, the field experiments are done all over the soft rock roadway. Engineering practice shows that the deformation of soft rock roadway in Baluba copper mine is effectively controlled by adopting the new reinforcement technology, which can provide certain references for similar engineering.
W celu rozwiązania problemu powstawania znacznych odkształceń chodnika biegnącego w skale miękkiej w skomplikowanym układzie naprężeń, przeprowadzono dogłębną analizę warunków odkształceń i pękania skał w oparciu o badania geologiczne. W oparciu o rozważania teoretyczne i symulacje numeryczne, zaproponowano nową technologię wzmocnienia progu spągowego z iłowców z linami kotwiącymi osadzonymi w zaprawie. Na podstawie trójwymiarowego modelu do symulacji numerycznych opracowanego z wykorzystaniem oprogramowania FLAC-3D dokonano optymalizacji parametrów podpór. Wyniki pokazują, że optymalne rozmieszczenie stalowych podpór wykonanych z profili w kształcie U wyniesie 0.8 m, zaś optymalny rozstaw mocowań lin wynosi 2.4 m. W końcowym etapie przeprowadzono eksperymenty terenowe na całej długości chodnika. Praktyka inżynierska wskazuje, że odkształcenia chodników prowadzonych w skałach miękkich w kopalni Baluba mogą być skutecznie kontrolowane poprzez zastosowanie nowej metody wzmocnienia, która stanowić może podstawę dla opracowywania skutecznych technik wzmacniania stropu w chodnikach prowadzonych w podobnych warunkach geologicznych.
Źródło:
Archives of Mining Sciences; 2018, 63, 2; 449-464
0860-7001
Pojawia się w:
Archives of Mining Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phase features of several typical blood cells and their identification without unwrapping
Autorzy:
Wang, Y.
Chen, Y
Lü, C.
Shang, X.
Xu, Y.
Wu, H.
Zhu, X.
Jin, W.
Powiązania:
https://bibliotekanauki.pl/articles/173588.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
digital holographic phase
nucleated cell
phase model
wrapped phase features
identification
Opis:
The digital holographic phase microscopy (DHPM) technique which has been proposed for cellular morphology and dynamic analysis yielded highly desirable results. However, for nucleated cells (especially white blood cells (WBCs)), their submicroscopic structure has not yet been deconstructed through a phase unwrapping method due to the heterogeneity of an internal phase. By analyzing the phase heterogeneity of subclasses of WBCs, the typical phase models of them are built first in this paper; using the simulation method, the wrapped phase distributions of these models are obtained. However, by optimizing the wrapped phase maps and analyzing the relationships between them and typical blood cells, their features are selected and extracted. Then the models built are sorted out from each other successfully without unwrapping via analyzing these extracted features, which provides a valuable approach and technological base for the classification and identification of blood cells.
Źródło:
Optica Applicata; 2013, 43, 3; 505-514
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ship domain model for multi-ship collision avoidance decision-making with COLREGs based on artificial potential field
Autorzy:
Wang, T.F.
Yan, X.P.
Wang, Y.
Wu, Q.
Powiązania:
https://bibliotekanauki.pl/articles/116475.pdf
Data publikacji:
2017
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
ship domain
ship domain model
collision avoidance
colregs
Artificial Potential Field (AFP)
decision-making
Predicted Area of Danger (PAD)
Closest Point of Approach (CPA)
Opis:
A multi-ship collision avoidance decision-making and path planning formulation is studied in a distributed way. This paper proposes a complete set of solutions for multi-ship collision avoidance in intelligent navigation, by using a top-to-bottom organization to structure the system. The system is designed with two layers: the collision avoidance decision-making and the path planning. Under the general requirements of the International Regulations for Preventing Collisions at Sea (COLREGs), the performance of distributed path planning decision-making for anti-collision is analyzed for both give-way and stand-on ships situations, including the emergency actions taken by the stand-on ship in case of the give-way ship’s fault of collision avoidance measures. The Artificial Potential Field method(APF) is used for the path planning in details. The developed APF method combined with the model of ship domain takes the target ships’ speed and course in-to account, so that it can judge the moving characteristics of obstacles more accurately. Simulation results indicate that the system proposed can work effectiveness.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2017, 11, 1; 85-92
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational Investigation on the Structure and Performance of Novel 4,7-dinitro-furazano-[3,4-d]-pyridazine Derivatives
Autorzy:
Wang, K.
Shu, Y.
Liu, N.
Ding, X.
Wu, Z.
Lu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358090.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
4,7-dinitro-furazano-[3,4-d]-pyridazine
heat of formation
density
detonation performance
bond dissociation energy
Opis:
Seven novel energetic 4,7-dinitro-furazano-[3,4-d]-pyridazine derivatives were designed, and their optimized structures and performances were studied by density functional theory (DFT) at B3LYP/6-311g(d,p) level. The detonation performances were estimated by the Kamlet-Jacobs equations. The results show that these compounds have high crystal densities (1.818-1.925 g·cm−3), detonation velocities (8.51-9.56 km·s−1) and detonation pressures (32.28-41.70 GPa). The bond dissociation energies (BDEs) of the weakest bond (N–O bond) vary from 70.889 kJ·mol−1 to 173.283 kJ·mol−1, and some of them exhibit higher BDEs than that of RDX (N–NO2 bond, 149.654 kJ·mol−1) and HMX (N–NO2 bond, 154.905 kJ·mol−1). M4 and M5 exhibit similar and higher detonation performance than RDX (8.81 km·s−1, 34.47 GPa). The detonation performance of M7 (9.56 km·s−1, 41.70 GPa) even surpasses that of HMX (9.10 km·s−1, 39.00 GPa). Otherwise, the specific impulse values of M1-M7 (266-279 s) outperform HMX (266 s) by 0-13 s, which indicates that M1-M7 may show better performance as monopropellants. It is concluded that density, heat of formation, stability, detonation performance and specific impulse of the designed compounds depend on the position and number of the N→O oxidation bonds.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 26-46
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 35

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