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Tytuł:
The influence of a static, homogeneous magnetic field on the sorption properties of soybean meal during maritime transport
Autorzy:
Ocieczek, A.
Kaizer, A.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2063955.pdf
Data publikacji:
2021
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
cargo transportation
magnetic field
soyabean meal
maritime transport
sea transportation
sorption properties
brunauer
bulk cargo
Opis:
Providing safety and maintaining high quality of dry cargo, transported by sea, is associated with the necessity of taking into consideration their specific property, which is hygroscopicity. Susceptibility to the impact of water, which also occurs in vapour state, concerns mainly dry cargo, which are organic matter, containing carbohydrates and protein in their composition. This is because these substances have strong connection with water. The example of a bulk cargo often transported by sea is soybean meal, which is mainly produced in the USA, Brazil and Argentina. Due to its economic importance, the quality of soybean meal, which is globally used in the animal nutrition (poultry and swine), remains an important research issue. This product is obtained by subjecting the soybeans to cracking and dehulling processes, in order to facilitate the extraction of the oil. Water absorption of soybean meal causes reactions taking place in it, which leads to the changes in its chemical composition and, consequently, also in its nutritional values. Moreover, increasing the water content, leading to the increase of water activity, may significantly deteriorate the microbiological safety of the meal. Therefore, the research was undertaken to determine whether the sorption properties of soybean meal will change due to the influence of a static, homogeneous magnetic field. This aim has been achieved by determining and comparing the water vapour adsorption isotherms. The comparison of the isotherms determined under normal conditions and under the influence of a static, homogeneous magnetic field with an induction of 10 mT has been made on the basis of empirical data. Furthermore, using the Brunauer, Emett and Teller equation (BET), the monolayer and the energy constant of the sorption process have been estimated. The isotherms were determined at 20°C. The study lasted 9 days. Desiccators with aqueous supersaturated solutions of substances and a generator of a static magnetic field were used in the research. The obtained results have indicated that the influence of the magnetic field is a factor that causes the differentiation between the sorption properties of soybean meal expressed in the volume of the monolayer and the energy associated with the sorption phenomenon. The inferred findings show, that the magnetic field has an impact on the course of the sorption phenomenon in organic samples, and may determine the stability of the cargo during long-term maritime transport.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2021, 15, 3; 649--657
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of a magnetic field on water desorption from the surface of potato starch
Autorzy:
Ocieczek, A.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/13925586.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
starch
potato starch
magnetic field
water desorption
desorption
surface property
surface chemistry
kinetics
Źródło:
Acta Agrophysica; 2019, 26, 3; 43-55
1234-4125
Pojawia się w:
Acta Agrophysica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Light absorption properties of ‘Petrobaltic’ oil-in-water emulsion present in seawater
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246640.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
crude oil, absorbance
absorption spectra of dispersed oil
absorption coefficient
oil-in-water emulsion
Opis:
In the article, the characteristic of crude oil ‘Petrobaltic’ potentially present in the Baltic Sea water masses is considered in relation to the protection of marine environment. The main spectroscopic method to characterize various oils (crudes and refinery products like fuels and lubricating oils) is fluorescence. However, the absorbance measurements of oils are necessary due to the partial overlapping the spectra of natural seawater components and oil substances. Therefore, properties of crude oil are considered to expand the basis of spectroscopic properties of oils – typical marine organic pollutants – based on absorption measurements. Oils potentially found in the marine environment are, in addition to surface forms, also in-depth ones as oil-in-water emulsion. Therefore, in the article crude oil as oil-in-water emulsion form is considered. As a solvent demineralised water with salinity, corresponding to Baltic Sea salinity was used. Several concentrations of dispersed crude oil were prepared. The absorbance spectra in the UV and visual range of the light in the range from 240 to 600 nm, for each prepared samples are discussed. Based on the Lambert-Beer law for each wavelength of excitation, in the range 240-600 nm, the specific parameter absorption coefficient was determined. Obtained results indicate the rapid decreasing of the absorbance for this kind of oil in the wavelength range from 240 nm to 420 nm. However, in the shape of absorbance spectra is observed the characteristic wide and flat peak located at 260 nm for excitation wavelength, which could be a specific point for this kind of oil.
Źródło:
Journal of KONES; 2018, 25, 3; 59-64
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties of the Baltic crude oil in the oil-in-water emulsion form : excitation-emission spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246400.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
crude oil
excitation-emission spectra
fluorescence
seawater
ropa naftowa
fluorescencja
woda morska
Opis:
Due to the fact that marine environment contamination by oil substances are not uncommon, it is necessary to improve the ability of determine their origin. Therefore, research on the possibility of recognizing the type of oil using its individual characteristic manifested in the processes of fluorescence excitation has been undertaken. Oil pollutants present in seawater mainly coming from ship drives, tankers, pipelines or sea bottom seeps, moreover oil leaks from offshore extraction equipment also are possible. For this reason, the crude oil extracted from the Baltic Sea deposit in the Polish Maritime Areas has been chosen for tests. Fluorescence properties of water containing small amounts of oil (concentrations from 5.59 to 55.4 ppm) in the form of oil-in-water emulsion were tested. Individual samples were assigned matrices of fluorescent values for different wavelengths, while excited by monochromatic light also for different wavelengths. The obtained matrices were visualized as a contour maps and 3D charts. For considered concentrations of crude oil dispersed in water, the wavelength-independent fluorescence maximum was determined. Obtained result indicates that in the studied wavelength range, the total fluorescence intensity is proportional to the oil concentration only for the lowest oil concentrations. The analysis of the objective parameter of the difference between the shapes of spectra indicates the similarity of the spectral shape for the lowest oil concentrations. These results are the methodological suggestion, that for the purpose of identifying the type of oil dispersed in water, spectra should be determined for sequences of different dilutions, until the excitation-emission spectra shapes become independent from the oil concentration.
Źródło:
Journal of KONES; 2018, 25, 1; 7-14
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrofluorimetry of chosen distillates of oil after pyrolysis of scrap tires
Autorzy:
Otremba, Z.
Ambrosewicz-Walacik, M.
Powiązania:
https://bibliotekanauki.pl/articles/245271.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fuels
used car tires
pyrolysis
fluorescence
excitation-emission spectra
Opis:
One of way to obtain liquid hydrocarbons can be pyrolysis of scrap tires. The hydrocarbon substances produced by this method may be an addition to traditional fuels, i.e. gasolines or fuels for diesel engines. In laboratory conditions at Department of Mechatronics of University of Warmia and Mazury there were obtained pyrolytic products and prepared three distillates related to temperatures 160, 204 and 350ºC. Analyses of shapes of fluorescence spectra were carried out in Department of Physics of Gdynia Maritime University. Spectra of fluorescence were prepared applying the spectrofluorimeter Hitachi F-7000 FL, which allows applying of excitation wavelength from 200 nm until 600 nm, whereas analysing of emitted, can be performed until 750 nm. In here reported study excitation and emission range for the most intense fluorescence are presented. There were prepared four solutions of pyrolytic products in the n-hexane: 4 ppm, 20 ppm, 100 ppm and 500 ppm. In order to show dependence of intensity fluorescence and shapes of excitation-emission spectra on type of distillate and concentration both kind of visualization – three-dimensional and as contour maps – are shown in this article. In analysed range of wavelengths, intensity of fluorescence grows with concentration of oil, whereas structure of the shape of spectra simplify when concentration increases. The presented effects associated with the fluorescence of pyrolysis products allow to predict the possibility of developing a method for determining the content of these substances in mixtures with petroleum refining products and other liquid hydrocarbons.
Źródło:
Journal of KONES; 2018, 25, 2; 262-268
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Description of diesel fuel based on synchronous fluorescence spectroscopy
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/242632.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
synchronous fluorescence spectroscopy
total synchronous spectra
diesel fuel
wavelength-interval
offset
fluorescencyjna spektroskopia synchroniczna
widmo synchroniczne
olej napędowy
długość fali
Opis:
The purpose of the study is spectrally characterise fuel Diesel used in diesel ship engine. For description of Diesel fuel the techniques of total synchronous fluorescence spectroscopy was applied. To characterise the oil, the spectrofluorometer ‘Aqualog Horiba’, which allows performing precise measurement in a short time, was applied to measure the excitation-emission spectra. Total synchronous fluorescence spectra of oil were obtained using various wavelength intervals basing on the measured excitation-emission spectra of Diesel fuel. Total synchronous spectra of Diesel oil are considered for several oil concentration. Synchronous fluorescence spectra were used to describe the detected maxima of Diesel fuel fluorescence by the wavelength-interval fluorescence maximum, containing information about the excitation wavelength and the wavelength-interval describing the characteristic fluorescence peak position for each considered fuel sample. That approach is discussed in relation to find a universal indicator – the wavelength-interval – as a possible tool proposed to Diesel fuel description independent from the fuel concentration. Therefore, we discuss the changes of the total synchronous fluorescence spectra for different oil concentration. Obtained results indicate that the best indicator for this kind of oil characterisation seems to be the wavelength-interval for 60 nm due to the independence of the synchronous spectra from the oil concentration.
Źródło:
Journal of KONES; 2017, 24, 1; 39-45
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Engine fuel characterisation based on excitation-emission spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246580.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fuel
diesel
engine
excitation-emission spectra
fluorescence
Opis:
Considering that correctly functioning of diesel ship engine depends on the composition of applied fuel, it is necessary to easy characterise fuels in terms of quality. Therefore taking into account above mentioned, appropriate analyses have been undertaken and the intention of this article is to inform that characterisation of fuel used in marine transport can be described by the specific parameter based on fluorescence excitation-emission spectroscopy. Therefore, for this study fuel typically used in ship engine – Diesel fuel – is considered. For analysis, Diesel fuel dissolved in n-hexane was used and several oil samples for various oil concentration were prepared. Spectrofluorometer Aqualog Horiba was used to record the excitation-emission spectra (EEMs). EEM spectra determined for each of oil concentration were described by two specific peaks for this kind of oil. Based on registered EEMs, the specific indicator - the wavelength-independent fluorescence maximum – coded in two specific wavelengths – excitation and emission, respectively, described as Exmax/Emmax was determined for considered oil concentration. Obtained results indicate the independence from oil concentration only for one detected peak described by Exmax/Emmax = 240/332. Taking into account obtained results, we can conclude that the wavelength-independent fluorescence maximum detected for excitation wavelength at 240 nm corresponds to the emission wavelength at 332 nm due to the independence from the oil concentration, could be a good indicator to characterise this kind of oil – Diesel fuel. We can conclude that the changes in the composition of fuel could be detected in EEM spectra by the change of detected peaks position.
Źródło:
Journal of KONES; 2017, 24, 2; 25-30
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Engine fuel characterisation through ultraviolet absorption spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/245537.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fuel
spectroscopy
absorptivity
diesel engine system
Opis:
In the article, light absorption properties of the fuel oil are considered with a view to create basis for establish optical indicator of the type and quality of this kind of crude oil derivative, in this case the Diesel fuel. The organic solvent – n-hexane – was chosen as a solvent to prepare samples of dilutions of Diesel fuel in several oil concentration. Spectrophotometer Aqualog Horiba were applied to record the absorbance spectra in the ultraviolet and visual range of the light (from 240 to 600 nm) for each previously prepared samples. Obtained results allow concluding that the changes of absorbance occur primarily in the wavelength range from 240 nm to 355 nm. Moreover, the absorbance spectra are characterized by the characteristic sharp peak located at 270 nm for excitation wavelength. Spectra of absorbance were converted to spectra of absorption coefficient based on Lambert-Beer law. Due to the independence the absorption coefficient from the fuel concentration, this parameter could be used as a potential indicator to access composition and quality Diesel fuel used in the diesel engine system. Therefore, preliminary tests allow concluding that absorption coefficient for selected wavelength located at 270 nm could be a sensitive indicator for quick access to fuel quality.
Źródło:
Journal of KONES; 2017, 24, 3; 15-19
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Maritime transport other than shipping: electrical energy case
Autorzy:
Otremba, Z.
Andrulewicz, E.
Jakubowska, M.
Powiązania:
https://bibliotekanauki.pl/articles/241948.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
maritime transport
submarine energy transfer
marine environment
wind farm
Polish Exclusive Economic Zone
transport morski
podmorski transfer energii
środowisko morskie
farma wiatrowa
polska specjalna strefa ekonomiczna
Opis:
Large demand for energy results in necessity for its transportation in various ways. On land areas, energy media transfer consists mainly of transport in tanks by rail, road or river routs as well as pipeline systems for liquid or gasified hydrocarbons. A part of energy media in the world is electric energy flowing though metallic conductors of overhead and cable networks. If sea areas are considered, ship navigation routs crosses with pipelines and electrical energy transfer systems. Furthermore, every transport system can interfere with other. Marine areas occupied by pipelines and submarine cables must be excluded from use of anchors and bottom fishing gear. On the other hand, pipeline systems interfere with the free development of navigation, particularly in areas near ports. Power transfer systems modify the natural force fields in the water column, surface water and even in near-water layer of atmosphere. In this article, we show the main ways of transferring electricity in the sea and the resulting modifications of physical fields: electrical, magnetic and electromagnetic ones. We also discuss the probable impact of modifications of natural fields on ship traffic as well as corrosion of hulls of ships and marine structures. The considerations presented in the article are related primarily to the Polish Exclusive Economic Zone of the Baltic Sea.
Źródło:
Journal of KONES; 2017, 24, 1; 275-280
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Light absorption spectra for lubricate oil quality tracking in the combustion engine
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/243648.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
lubricate oil
dissolved oil
absorption spectroscopy
absorption coefficient
engine system
Opis:
The important role in the proper functioning of combustion engines plays the quality of lubricates oil. However, the quality of oil changes with the time of exploitation. Therefore, several parameters for examination of oil quality were determined; however, the indicator for quick and efficient tracking of evolution of oil with exploitation time is still searched. Taking into account the complex composition of oils, the ability of oils components to absorb light in various wavelengths is considered. In the article absorption properties of oils is discussed in relation to the time of circulation of oil in the engine lubricate system. For this study, two lubricate oils designated to lubricate the cylinder of vessel engines with different brightness and transparency were used. Oil samples were dissolved in organic solvent –n-hexane and several oil concentration were prepared based on dilution method. Absorbance spectra for eachsamples of oil were registered in the range of wavelength 240-600 nm. Obtained results indicate the changes of value of absorbance in relation to the kind of oil; however, the shape of absorbance spectra is independent from the kind of oil. For studied kinds of oil, characteristic peak independent from the kind of oil located at 260 nm was determined. Based on Lambert-Beer law absorption coefficient was identified as a potential indicator to oil quality evaluation with the time of exploitation in the engine system. Preliminary test for two fresh lubricate oils allow to conclude that absorption coefficient for selected wavelength located at 260 nm could be a sensitive parameter for quick estimating the degree of deterioration of the oil in engine system.
Źródło:
Journal of KONES; 2016, 23, 1; 55-60
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrum of light absorption as the indicator of lubricate oil dispsersed in the natural water
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/247346.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
lubricate oil
absorption
absorption spectra of dispersed oil oil-in-water emulsion
Opis:
Oil pollutants in the natural water masses – especially in the seawater column – can be found in two forms, namely as dissolved oil or as dispersed one. With a broad set of methods, for studying the complex structure of petroleum products, due to the ability of petroleum products to absorb UV-light, absorbance spectra could be a relevant indicator to oil identification in aquatic environment and could support methods provided by the fluorescence technique. The intention of the study described in this article is to characterise the absorption properties of lubricate oil possible to found in the marine environment. Two types of oil as the representative of lubricate oils using in the ship engines are considered. One form of oil possible to found in the marine environment – oil-in-water emulsion was taken into account for analysis. Dispersed in water lubricate oil samples were prepared for several oil concentration for each type of oil. Spectrofluorometer Aqualog Horiba was used to register the absorbance spectra of oils. Based on the Lambert-Beer law the absorbance spectra were derived and specific parameter – absorption coefficient – for each wavelength of excitation, in the range 240-600 nm, was determined. Obtained results indicate decreasing of the oil absorbance value when excitation wavelength increases. Moreover, basing on the absorbance spectra it could be concluded that the main maximum for this kind of oils is located below 240 nm. However, in the considered range of excitation wavelength small flat peak, centred about 265 nm for both types of oils, was detected. Therefore one could conclude that absorbance of oils could be used as the indicator to detect of oil pollution in the natural environment omitting the labour intensive chemical methodology.
Źródło:
Journal of KONES; 2016, 23, 1; 61-66
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Test of the suitability of chosen materials in terms of their use for removing oil spillage from the water environment
Autorzy:
Guźlińska, E.
Kończewicz, W.
Otremba, Z.
Trojnar, D.
Powiązania:
https://bibliotekanauki.pl/articles/241568.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
sorbents
fuel
seawater
maritime engineering
environmental protection
Opis:
The paper presents the study about impregnability of various loose materials dedicated as the fillers of oil absorbent socks and booms. Purpose of the survey was finding the material, which is characterized with the smallest hygroscopicity and the highest absorptivity towards typical fuels used in the marine techniques. The cause of take up the topic is the fact, that the contamination of sea areas with petroleum substances are unfortunately very often, are dangerous for natural environment and first of all are so hard to remove from the sea surface. The natural, mineral and synthetic sorbents were studied under laboratory conditions. Samples of the ten kinds of sorbent, each of 2 grams, were treated with the same amount of the diesel fuel, heavy fuel oil and the sea water also, each time in the same period-time (5 minutes). In order to determine the reliability of the results the authors carried out the test fivefold for the one of searched sorbents (recognized as the most hydrophobic-oleophilic substance). The results are presented in graphical form, based on which we are able to select sorbent that fulfils the greatest extent of required expectations. The results of performed tests show that the method that was described in the paper could be used to test the suitability of various materials for the production of devices for collecting the oil film from the surface of the water.
Źródło:
Journal of KONES; 2016, 23, 3; 171-176
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Testing of the synchronous fluorescence in application to used lubricate oil characterisation
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/243560.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine fleet exploitation
lubricate oil
fluorescence spectroscopy
synchronous fluorescence spectra
Opis:
Reliability of the ship propulsion system depends, inter alia, on the quality of lubricate oils. Research indicates that exploitive features of oil are reduced with it runtime in the ship engine circuit. At the present the basic parameters representing exploitive features of oil are: water content, total acid number and total base number or viscosity vs. temperature, anti-wear performance, further: content of additives and their concentrations, reaction products, and other contaminating substances, also magnetically separated large ferromagnetic particles, the size, the shape, the composition and concentration of the abnormal wear particles. Additional properties of oil are described based on atomic emission spectroscopy, granulometry of separated from the lubricant sample by magnets and gravity, permeability changes, as well as rheometric and tribometric characteristics. Complexity of composition of lubricate oil raises the idea to use changes of relative content of any compounds for characterization of oil exploitive features. Fluorescence method is possible to use for oil properties characterisation due to the presence mono and polycyclic compounds in oil that induces fluorescence phenomenon. Therefore identification the fluorescence spectra when exploitation time of oil increases could be novel indicator to monitor of lubricate oil exploitive quality. In this study we present changes of oil fluorescence expressed by synchronous spectra, taking into account working time of exemplary lubricate oil in the ship engine.
Źródło:
Journal of KONES; 2016, 23, 2; 39-44
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of fluorometric signatures of oil residues in both marine environment and in organic diluent
Autorzy:
Otremba, Z.
Baszanowska, E.
Powiązania:
https://bibliotekanauki.pl/articles/243211.pdf
Data publikacji:
2015
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
seawater
excitation-emission spectra
fluorescence spectroscopy
Opis:
The significant part of petroleum substances is transferred to the marine environment after technical activities (inevitable exploitive spills, illegal discharges). However a certain part of petroleum in seawater coming from the natural sources. Therefore, to develop the safety of natural marine environment it is necessary to track not only the anthropogenic pollutants but also the natural sources of petroleum. To distinguish both source of oil the fluorescence properties of oil can be used as the tools to oil identification. The aim of the study is to describe the optical properties of crude oil after it contact with aquatic environment based on fluorescence spectroscopy. For the study, crude oil ‘Petrobaltic’ type potentially found in marine environment due to coming from natural source was applied. To dissolve oil, two different solvent – hexane and Baltic seawater form the Gdynia coast were used. To measure the excitation-emission spectra (EEMs) of oil spectrofluorometer Hitachi F-7000 FL was applied. In the paper, we discuss the changes of oil EEMs in two cases for oil dissolved in n-hexane and for oil dissolved in seawater for various oil concentration. Obtained EEMs for oil dissolved in seawater indicate that EEMs spectrum contain the main peak – describing by the wavelength – independent fluorescence maximum, which was detected for oil dissolved in n-hexane (typical for this kind of oil). However, the intensity of oil fluorescence decreases after oil contact with seawater. This approach could allow expanding the description of complex mixtures of oils as a possible tool proposed for identification the type and origin of oil found in marine environment.
Źródło:
Journal of KONES; 2015, 22, 3; 175-179
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of nonwoven fabrics in terms of usefulness for oil spill combat
Autorzy:
Kończewicz, W.
Otremba, Z.
Sałek, K.
Walaszkowska, N.
Powiązania:
https://bibliotekanauki.pl/articles/244169.pdf
Data publikacji:
2015
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil spill combat
sorbents
nonwoven fabrics
Opis:
The petroleum substances (oil) spilled on the hard surface can be easily neutralized and collected by using powdery or granular sorbents. We are dealing with more difficult situation when oil spill appears on the soft ground or on the surface of the water. Extremely difficult is removing the oil from body of water polluted by dispersed one. In such cases useful are various balls, sleeves and mats filled by nonwovens. It is important to identify a material, which strongly absorbs different type of oil in a wide temperature range. At the same time, such material should have physical properties allowing easy and rapid contact with the spilled oil and then its removal from the environment. This paper provides an overview of impregnability of nonwoven fabrics made from two materials – polypropylene and cotton. The impregnability was tested against the water and the used lubricate oil. The tests were carried out by using experimental device constructed by members of the student’s scientific society at Faculty of Marine Engineering (Gdynia Maritime University). Principle of construction of testing device takes into account aspect of placing the sorbent in the package as well as possibility of repeating the experiment in precisely defined measurement conditions. Among tested materials, the best in terms of oil sorptivity proved to be polypropylene. The same material was the least absorbing water. It can therefore be assumed that this material is the most suitable for removing oil from the polluted water.
Źródło:
Journal of KONES; 2015, 22, 3; 99-103
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł

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