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Wyszukujesz frazę "betanin" wg kryterium: Wszystkie pola


Tytuł:
Spectrophotometric study on betanin photodegradation
Autorzy:
Skopińska, A.
Tuwalska, D.
Wybraniec, S.
Starzak, K.
Mitka, K.
Kowalski, P.
Szaleniec, M.
Powiązania:
https://bibliotekanauki.pl/articles/115905.pdf
Data publikacji:
2012
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
betanin
betacyanins
photodegradation
Beta vulgaris L.
Opis:
The most commonly occurring betacyanin plant pigment in nature is betanin (5-O-glucoside of betanidin). Its main source is red beet root (Beta vulgaris L.), used for production of food colorants on a commercial scale [1]. Due to photo-lability of betacyanins, an eff ect of UV-irradiation on betanin degradation in various solutions containing organic solvents was investigated. Organic solvents are used frequently in many stages of pigment preparation or isolation, therefore, knowledge of betalain stability and degradation characteristics in these solutions is essential. Pigment solutions at a concentration of 1 mg/ml were prepared in diff erent solvents: water as well as aqueous solutions of 50% (v/v) acetonitrile, 50% (v/v) methanol or 50% (v/v) ethanol, at the pH range 3–8. Acetate, phosphate and citrate buff ers were used for the experiments. As a result of the pigment photo-decomposition, numerous decarboxylated and dehydrogenated derivatives were formed. Spectrophotometric studies enabled determination of the pigment retention (percentage of the pigment residue relative to its initial concentration after decomposition time). The studies demonstrated betanin high lability in all solvents, not only at extreme pH values, but also in the middle pH range which, in general, provides higher stability of betalains.
Źródło:
Challenges of Modern Technology; 2012, 3, 4; 34-38
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of citric acid on stabilization of betanin solutions
Autorzy:
Skopińska, A.
Szot, D.
Tuwalska, D.
Starzak, K.
Osiadło, M.
Wybraniec, S.
Powiązania:
https://bibliotekanauki.pl/articles/115716.pdf
Data publikacji:
2014
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
betanin
betacyanins
citric acid
Beta vulgaris L.
betanina
betacyjaniny
kwas cytrynowy
Opis:
Elevated temperature is known to be the most crucial factor influencing betanin integrity during food processing and storage. Nevertheless, certain chelating agents or antioxidants, such as acetic acid, may act as stabilizers. Therefore, the effect of citric acid on the stability of betanin – basic betacyanin – was investigated during the heating experiments in water as well as 50% and 95% (v/v) aqueous-organic solutions of methanol, ethanol and acetonitrile. The presence of citric acid in tested solutions affects betanin stability, especially in the 95 % solutions, in which the stabilizing effect of this compound is significantly higher than in aqueous solutions. However, some decrease of retention in 50% methanol was also observed. The main products of betanin thermal degradation in aqueous and aqueous-organic solutions were compounds characterized by absorption bands around the wavelength at 420 nm.
Źródło:
Challenges of Modern Technology; 2014, 5, 2; 19-24
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal degradation of 17-decarboxy-betanin monitored by LC-MS
Autorzy:
Szot, D.
Starzak, K.
Skopińska, A.
Tuwalska, D.
Wybraniec, S.
Powiązania:
https://bibliotekanauki.pl/articles/115566.pdf
Data publikacji:
2014
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
17-decarboxy-betanin
betacyanins
thermal degradation
17-dekarboksy-betanina
betacyjaniny
degradacja termiczna
Opis:
A thermal stability study on 17-decarboxy-betanin depending on physicochemical process conditions was conducted. 17-decarboxy-betanin is one of betacyanin, natural origin pigments applied in food and pharmaceutical industry instead of artificial colorants. There is a need for searching of new non-toxic natural food components and this is a reason of increasing interest of betacyanins. As most derivatives of betanin obtained by decarboxylation, 17-decarboxy-betanin tends to degrade in the presence of some factors such as increased temperature or other conditions of the reaction environment [1]. This subject was investigated in this study because the stability of the pigments is still a significant issue limiting their wide application. The degradation of 17-decarboxy-betanin during heating in selected solutions: water as well as aqueous solutions of ethanol 50% (v/v), methanol 50% (v/v) and acetonitrile 50% (v/v) at pH in the range 3-8 was tested. As UV-Vis spectra indicate, 17-decarboxy-betanin tends to degrade mostly at pH 3, notwithstanding a type of solution. The products of degradation were identified by LC-DAD-ESI-MS. As a result of incubation at 85°C in different solutions, various mono-, bi- and tridecarboxylated as well as dehydrogenated derivatives were obtained. The dominant product of 17-de-carboxy-betanin degradation is 2,15,17-tridecarboxy-2,3-dehydro-betanin.
Źródło:
Challenges of Modern Technology; 2014, 5, 3; 32-36
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Cu (II) Cations on 2-Decarboxy-betanin Stability in Aqueous-Organic Solutions
Autorzy:
Skopińska, A.
Szot, D.
Starzak, K.
Wybraniec, S.
Powiązania:
https://bibliotekanauki.pl/articles/115534.pdf
Data publikacji:
2015
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
betacyanins
2-decarboxy-betanin
copper ions
betalain stability
Beta vulgaris L.
betacyjaniny
2-dekarboksy-betanina
jony miedzi
stabilność betalainy
Opis:
Several important factors, such us pH, exposure to light, oxygen or temperature affect significantly the betalain stability. In particular, the heavy metal ions exert negative effect on stability of betalain colorants and accelerate pigment decomposition. Trace amounts of metal ions may be present in the food products, as well as in food packaging, leading to undesirable colour changes or even discoloration of betalainic foodstuffs. Decarboxylated betalains, such as 2-decarboxy-betanin, generated, e.g. during betalain thermal treatment, may exhibit greater stability than parent pigments. Moreover, obtained derivatives retain attractive color, making them the promising material for study of pigment stability. An effect of Cu2+ cations as the most degradative metal ions on 2-decarboxy-betanin stability was investigated in ethanolic and methanolic solutions. The increase of the concentration of copper cations has a negative impact on stability of 2-decarboxy-betanin. The cations of Cu (II) in the presence of organic solvents induce the pigment degradation, while the increase of the concentration of organic solvents enhances the pigment decomposition. The main degradation products of the 2-decarboxy-betanin are compounds possessing absorption maxima at λmax ca. 430 nm. These studies allow obtaining the information needed for proper isolation and treatment of pigments, as well as proper storage of products containing betalains.
Źródło:
Challenges of Modern Technology; 2015, 6, 3; 24-29
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High salt-solvent systems in separation of betanin and its derivatives from red beet (Beta vulgaris L.) by high-performance countercurrent chromatography (HPCCC)
Autorzy:
Spórna-Kucab, A.
Ignatova, S,
Garrard, I.
Wybraniec, S.
Powiązania:
https://bibliotekanauki.pl/articles/115564.pdf
Data publikacji:
2012
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
betanin
betalains
betacyanins
countercurrent chromatography
Beta vulgaris L.
Opis:
A study on a separation of betanin and its decarboxy- and dehydro-derivatives obtained from red beet roots (Beta vulgaris L.) using analytical high-performance countercurrent chromatography (HPCCC — Dynamic Extractions Ltd., UK) was performed. The HPCCC process was accomplished in the ‘tail to head’ mode with three highly polar solvent systems with high salt concentrations: 1-propanol-acetonitrile-saturated ammonium sulphate-water (v/v/v/v, 1:0.5:1.2:1); ethanol-acetonitrile-1- propanol-saturated ammonium sulphate-water (v/v/v/v/v, 0.5:0.5:0.5:1.2:1) and ethanol-1-butanol-acetonitrile-saturated ammonium sulphate-water (volume ratio), 0.5:0.5:0.5:1.2:1). HPLC analysis was performed in a conventional reversed phase mode with diode-array (DAD) detection to characterize the composition of obtained fractions. The applied solvent systems enabled the separation of the betalain pigments with high efficiency for the first time. In the mode of separation selected, the more hydrophobic compounds eluted first as expected. Moreover, for the first time, the applied HPCCC solvent systems generated a separation of 2-decarboxy-betanin from 17- and 2,17-bidecarboxy-betanin as well as from neobetanin and betanin.
Źródło:
Challenges of Modern Technology; 2012, 3, 1; 57-61
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spiral-coil countercurrent chromatographic separation of betanin and betanidin ethyl-esters monitored by continuous ESI-MS/MS injection and LC-ESI-MS/MS
Autorzy:
Tuwalska, D.
Szot, D.
Wybraniec, S.
Winterhalter, P.
Jerz, G.
Powiązania:
https://bibliotekanauki.pl/articles/115897.pdf
Data publikacji:
2013
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
spiral-coil countercurrent chromatography (spCCC)
betacyanin ethyl-esters
betalains
betacyanins
betanin
betanidin
Opis:
Betalains present in Beta vulgaris L. (Chenopodiaceae) have a high potential as natural pigments for food applications. They have been used as a substitute of synthetic dyes in processing of gelatine, strawberry yogurts, ice creams, fruits cocktails, candies and biscuits. The stability of betalains is strongly influenced by numerous factors – sugar content, and impact of light, oxygen, water activity, pH and temperature. A mixture of betacyanin mono-, di- and tri-ethyl-esters was separated by a large-volume spiral-coil countercurrent chromatography (spCCC) prototype which yielded fractions continuously off-line injected to an ESI-MS/MS device. This method yielded a reconstituted pigment profile and finally enabled the MS-target-guided isolation procedure for the whole spCCC-experiment. The individual fractions were analyzed by LC/ESI-MS/MS. Betanin and betanidin mono-, di- and tri-ethyl-esters as well as other decarboxylated derivatives were detected in the chromatograms. The ethyl-esters of betanin were only partially fractionated, but clearly fractionated from the ethyl-esters of betanidin which will be of great value for biological evaluations.
Źródło:
Challenges of Modern Technology; 2013, 4, 4; 21-25
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reduction of Selected Betacyanins
Autorzy:
SZOT, DOMINIKA
STARZAK, KAROLINA
SKOPIŃSKA, ANNA
WYBRANIEC, SŁAWOMIR
Powiązania:
https://bibliotekanauki.pl/articles/1034140.pdf
Data publikacji:
2014
Wydawca:
Uniwersytet Jagielloński. Wydawnictwo Uniwersytetu Jagiellońskiego
Tematy:
1
7-diazaheptamethin
LC-MS
betanin
chromophore
decarboxy-betacyanins
reduction
Opis:
Betacyanins are conjugates of betalamic acid and glycosylated cyclo-DOPA which bring about the creation of a specific chromophoric system, the 1,7-dia- zaheptamethin chain. Betanin, a betacyanin pigment from red beet (Beta vulga- ris L.), as well as its decarboxylated derivatives were subjected to reduction with the use of NaBH4. The pigment structures contain a vinyl linker which is postu- lated to be protonated during reaction with NaBH4. In this study, 17-decarboxy- betanin and 2,17-bidecarboxy-betanin were obtained from betanin, which had been previously isolated from red beet root (Beta vulgaris L.). Purified pigments were tested in the presence of the reduction reagent while looking for the prod- ucts of the reaction identified by LC-MS.
Źródło:
Zeszyty Naukowe Towarzystwa Doktorantów Uniwersytetu Jagiellońskiego. Nauki Ścisłe; 2014, 8; 265-273
2082-3827
2084-977X
Pojawia się w:
Zeszyty Naukowe Towarzystwa Doktorantów Uniwersytetu Jagiellońskiego. Nauki Ścisłe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Aberrations of Betanin Sensitized Gelatin Microlenses
Autorzy:
Vasiljević, D.
Murić, B.
Pantelić, D.
Panić, B.
Powiązania:
https://bibliotekanauki.pl/articles/1795610.pdf
Data publikacji:
2009-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
42.15.Fr
42.70.Gi
81.05.Zx
42.79.Bh
Opis:
Aberrations of the concave aspherical microlenses are presented. Microlenses are produced by using betanin sensitized gelatin and 532 nm laser irradiation (2nd Nd:YAG harmonic). Aberrations are analyzed by calculation of the longitudinal spherical aberration and the root mean square RMS spot radius. Three presented microlenses had good image quality for the large F number and the moderate field angle.
Źródło:
Acta Physica Polonica A; 2009, 116, 4; 592-594
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reactions of decarboxylated betanins under influence of halogen light
Autorzy:
Skopinska, A.
Szot, D.
Starzak, K.
Wybraniec, S.
Powiązania:
https://bibliotekanauki.pl/articles/115710.pdf
Data publikacji:
2014
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
betanin
decarboxylated betacyanins
photolability
mass spectrometry
betanina
dekarboksylacja betacyjaniny
spektrometria masowa
Opis:
Betalains as natural plant pigments are very sensitive to several factors, including light, therefore, studies on stability of their derivatives which retain their attractive color, are crucial for their potential application in pharmaceutical, food or cosmetic industries. An effect of irradiation by halogen light on reactivity of main decarboxylated derivatives of betacyanins (2-decarboxy-betanin, 17-decarboxy-betanin and 2,17-decarboxy-betanin) was investigated in aqueous and organic-aqueous solutions: 50% (v/v) acetonitrile, 50% (v/v) methanol and 50% (v/v) ethanol, at pH range 3-8. The double decarboxylation of betanin (at C-2 and C-17 position of carbon) significantly increases the stability of this pigment in the acidic media. As a result of pigments reactions induced by light, some betacyanin derivatives with different decarboxylation and dehydrogenation levels were identified by chromatography with tandem mass spectrometry (LC-MS/MS) and diode array detection (LC-DAD).
Źródło:
Challenges of Modern Technology; 2014, 5, 3; 37-43
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Decarboxylation of Betacyanins in Red Beet Betalain-Rich Extract
Autorzy:
Kumorkiewicz, Agnieszka
Sutor, Katarzyna
Nemzer, Boris
Pietrzkowski, Zbigniew
Wybraniec, Sławomir
Powiązania:
https://bibliotekanauki.pl/articles/1369582.pdf
Data publikacji:
2020
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
decarboxylation
red beet root
colorants
betanin
betalain-rich extract
decarboxy-betacyanins
Opis:
Betalains are one of the most common groups of plant pigments found in nature, especially in red beetroot (Beta vulgaris L.) which is the main commercially exploited source of betalains produced in the form of concentrates or powders. This report presents results of thermal decarboxylation studies on betacyanins present in a specifically purified highly concentrated betalain-rich extract (BRE). The first tentative structures formed by decarboxylation of the main pigment present in BRE, betanin and its diastereomer, were established by means of liquid chromatography coupled to diode array detection and electrospray ionization tandem mass spectrometry (LC-DAD-ESI-MS/MS). In the extract, two new isomeric bidecarboxylated betanins were tentatively identified. A high rate of generation of 2-decarboxy-betanin/-isobetanin which are present in the BRE extract at very low level was observed, which was dependent on the starting concentration of the BRE substrate. The bidecarboxylated derivatives were generated at a higher rate mostly from 17-decarboxy-betanin/-isobetanin as well as 15-decarboxy-betanin by further decarboxylation at carbon C-2. Further studies will be performed to demonstrate if the decarboxylated betanins being products of heating B. vulgaris preparations can be used for various food applications with new health-promoting actions and colorant properties.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2020, 70, 1; 7-14
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł

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