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Tytuł:
Synthesis, spectroscopic and thermogravimetric interpretations of UO2(II), ZrO(II), Zr(IV), VO(II) and V(V) ciprofloxacin antibiotic drug complexes
Autorzy:
Albedair, Lamia A.
Powiązania:
https://bibliotekanauki.pl/articles/1849331.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ciprofloxacin
complexation
FTIR
Fourier transform infrared spectroscopy
diamagnetic
TEM
transmission electron microscopy
nanoscale
Opis:
New five ciprofloxacin (CIP) complexes of dioxouranium(II), oxozirconium(II), zirconium(IV), oxovanadium(II) and vanadium(IV) in the proportion 1:2 have been prepared using CIP as a drug chelate with UO2(NO3)2. 6H2O, ZrOCl2. 8H2O, ZrC4, VOSO4. xH2O and V2O5 respectively. The CIP complexes have been characterized based on the elemental analysis, molar conductance, magnetic, (FTIR & 1HNMR) spectral and thermal studies. The molar conductance studies of the synthesized complexes in DMSO solvent with concentration of 10–3 M indicate their non-electrolytic properties. At room temperature, the magnetic moment measurements revealed a diamagnetic behavior for all CIP prepared complexes. The different formulas of the new complexes can be represented as [UO2(CIP)2(NO3)2] (I), [VO(CIP)2(SO4)(H2O)] (II), [V2(O)(O2)2(CIP)2] (III), [Zr(O)(CIP)2(Cl)2] (IV), and [Zr(CIP)2(Cl)4] (V). The thermal analysis data of the complexes indicates the absence of coordinated water molecules except for vanadyl(II) complex (II). The CIP chelate is a uni-dentate ligand coordinated to the mentioned metal ion through terminal piperazinyl nitrogen. The transmission electron microscopy (TEM) investigation confirms the nano-structured form of the complexes.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 1; 45-52
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Petrology of nepheline syenite pegmatites in the Oslo Rift, Norway: Zr and Ti mineral assemblages in miaskitic and agpaitic pegmatites in the Larvik Plutonic Complex
Autorzy:
Andersen, Tom
Erambert, Muriel
Larsen, Alf Olaf
Selbekk, Rune S.
Powiązania:
https://bibliotekanauki.pl/articles/127623.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
alkaline rocks
nepheline syenite pegmatite
agpaitic rocks
zirconium minerals
titanium minerals
Oslo Rif
Opis:
Agpaitic nepheline syenites have complex, Na-Ca-Zr-Ti minerals as the main hosts for zirconium and titanium, rather than zircon and titanite, which are characteristic for miaskitic rocks. The transition from a miaskitic to an agpaitic crystallization regime in silica-undersaturated magma has traditionally been related to increasing peralkalinity of the magma, but halogen and water contents are also important parameters. The Larvik Plutonic Complex (LPC) in the Permian Oslo Rift, Norway consists of intrusions of hypersolvus monzonite (larvikite), nepheline monzonite (lardalite) and nepheline syenite. Pegmatites ranging in composition from miaskitic syenite with or without nepheline to mildly agpaitic nepheline syenite are the latest products of magmatic differentiation in the complex. The pegmatites can be grouped in (at least) four distinct suites from their magmatic Ti and Zr silicate mineral assemblages. Semiquantitative petrogenetic grids for pegmatites in log aNa2SiO5 – log aH2O – log aHF space can be constructed using information on the composition and distribution of minerals in the pegmatites, including the Zr-rich minerals zircon, parakeldyshite, eudialyte, låvenite, wöhlerite, rosenbuschite, hiortdahlite and catapleiite, and the Ti-dominated minerals aenigmatite, zirconolite (polymignite), astrophyllite, lorenzenite, titanite, mosandrite and rinkite. The chemographic analysis indicates that although increasing peralkalinity of the residual magma (given by the activity of the Na2Si2O5 or Nds component) is an important driving force for the miaskitic to agpaitic transition, water, fluoride (HF) and chloride (HCl) activity controls the actual mineral assemblages forming during crystallization of the residual magmas. The most distinctive mineral in the miaskitic pegmatites is zirconolite. At low fluoride activity, parakeldyshite, lorenzenite and wöhlerite are stable in mildly agpaitic systems. High fluorine (or HF) activity favours minerals such as låvenite, hiortdahlite, rosenbuschite and rinkite, and elevated water activity mosandrite and catapleiite. Astrophyllite and aenigmatite are stable over large ranges of Nds activity, at intermediate and low water activities, respectively.
Źródło:
Mineralogia; 2013, 44, 3/4; 61-98
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure and magnetic properties of Fe-B-Si-Zr metallic glasses
Autorzy:
Babilas, R.
Radoń, A.
Gębara, P.
Powiązania:
https://bibliotekanauki.pl/articles/1054824.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.45.+x
61.05.cp
64.70.pe
75.50.Kj
Opis:
Fe-based amorphous alloys were characterized by X-ray diffraction, transmission Mössbauer spectroscopy and vibrating sample magnetometry. The studies were performed on (Fe_{0.75}B_{0.15}Si_{0.1})_{100-x}Zr_{x} (x=0, 1, 3) metallic glasses in the form of ribbons. The glassy samples were prepared by the "melt spinning" technique in argon protective atmosphere. The XRD patterns show the broad diffraction halo that is typical for amorphous Fe-based alloys. The Mössbauer spectroscopy allows to study the local environments of the Fe atoms in the glassy state, showing the changes in the amorphous structure due to the changing of Zr addition. From hysteresis loops obtained from vibrating sample magnetometry measurements, coercive force and saturation magnetization were determined versus different Zr content. The obtained magnetic properties allow to classify the studied amorphous alloys in as-cast state as soft magnetic materials.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 726-728
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrothermal metasomatism of a peralkaline granite pegmatite, Khaldzan Buragtag massif, Mongolian Altai; complex evolution of REE-Nb minerals
Autorzy:
Bagiński, B.
Jokubauskas, P.
Domańska-Siuda, J.
Kartashov, P.
Macdonald, R.
Powiązania:
https://bibliotekanauki.pl/articles/139319.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Khaldzan-Buragtag Nb-REE-Zr deposit
hydrothermal alteration
composition of fluids
Chevkinite group minerals
REE minerals
złoże
przeobrażenia hydrotermalne
skład płynów
minerały
Opis:
The low-temperature hydrothermal alteration of certain rare-metal minerals is recorded in a quartz-epidote metasomatite from the Tsakhirin Khuduk occurrence in the Khaldzan-Buragtag Nb-REE-Zr deposit, Mongolian Altai. A peralkaline granitic pegmatite was metasomatized by hydrothermal fluids released from associated intrusions, with the formation of, inter alia, chevkinite-(Ce), fergusonite-(Nd) and minerals of the epidote group. The textural pattern indicates recrystallization and coarsening of these phases. Later, low-temperature alteration byfluids resulted in the chevkinite-(Ce) being replaced by complex titanite-TiO2-cerite-(Ce)-hingganite-hydroxylbastnäsite-(Ce) assemblages. Calcite formed late-stage veins and patches. The hydrous fluids were poor in F and CO2 but had high Ca contents.
Źródło:
Acta Geologica Polonica; 2016, 66, 3; 473-491
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of Refractive Index Variations of TiO₂:SiO₂:Zr Thin Films by Molar Ratio
Autorzy:
Bahsi Oral, Z.
Powiązania:
https://bibliotekanauki.pl/articles/1401367.pdf
Data publikacji:
2015-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.20.Fw
Opis:
Zr-doped and undoped TiO₂-SiO₂ thin films were fabricated by using sol-gel dip coating. TiO₂:SiO₂:Zr films with different molar ratio were coated on glass substrates. Refractive indexes and the thicknesses of thin films were measured with Metricon 2010 Prism Coupler. The theoretical and measured refractive indexes of thin films were found to be consistently changing with molar ratio. The measured refractive indexes of thin films were lower than the theoretical ones due to the porosity of the structure.
Źródło:
Acta Physica Polonica A; 2015, 127, 4; 1314-1316
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studying of Nickel Alloys with 1 at.% of Ge, Zn, In, Zr and Pb by Positron Annihilation Methods
Autorzy:
Baranowski, A.
Kostrzewa, M.
Szuszkiewicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/2024150.pdf
Data publikacji:
2001
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
78.30.Er
Opis:
The measurements of cold rolled nickel alloys with 1 at.% of Ge, Zn, In, Zr, Pb and additionally Ti and Sb by positron lifetime and Doppler broadening techniques have been done. Monovacancies were a dominating type of defects in the alloys. The authors of the present paper connect the differences between the annihilation parameters of the investigated samples with the existence of the vacancy-impurity atom pairs. A direct proportionality between the vacancy lifetime and the product of vacancy-impurity binding energy and atomic radius of impurity atom has been found.
Źródło:
Acta Physica Polonica A; 2001, 99, 3-4; 329-336
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wettability of carbon and silicon carbide ceramics induced by their surface alloying with Zr and Cu elements using high intensity pulsed plasma beams
Autorzy:
Barlak, M.
Piekoszewski, J.
Sartowska, B.
Waliś, L.
Starosta, W.
Kierzek, J.
Pochrybniak, C.
Kowalska, E.
Powiązania:
https://bibliotekanauki.pl/articles/146789.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
wettability
ceramic-metal joints
high intensity pulsed plasma beams (HIPPB)
Opis:
Joining of metals with ceramics is very difficult, because properties of these materials are very different. One of the methods of improving mechanical strength of the obtained joints is the introduction of an additional interlayer to the joining area. This paper presents the Zr and Cu-rich layers in C and SiC substrates obtained using the high intensity pulsed plasma beams method. The results of Zr plasma modifications were beneficial and similar to the results obtained in previous works with Ti. The measured contact angles were below 90 centigrade. The results with Cu plasma were unfavourable with contact angles close to 180 centigrade. Apart from the sessile-drop test and to extend the range of analysis, the investigated samples were examined by stereoscopic optical microscopy (OM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDXS), grazing angle X-ray diffraction (GXRD), and Rutherford back scattering (RBS) measurements.
Źródło:
Nukleonika; 2012, 57, 4; 477-483
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Soft Magnetic Properties and Temperature Stability of Co-Fe-Zr-B Metallic Glasses
Autorzy:
Bednarčík, J.
Kováč, J.
Roth, S.
Fűzer, J.
Kollár, P.
Varga, L.
Franz, H.
Powiązania:
https://bibliotekanauki.pl/articles/1813531.pdf
Data publikacji:
2008-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Kj
Opis:
In the present work multicomponent Co-based alloys with nominal composition $Co_{72-x}Fe_xZr_8B_{20}$ (x=10, 15, and 20 at. %) were synthesized by single-roller melt-spinning. The measurement of coercivity, $H_c$, reveals the soft magnetic behavior of investigated alloys. The value of $H_c$ increases from 23 A/m for alloy with x=10 at. % up to 32 A/m for alloy with x=20 at. %. Further it was found that crystallization temperature of as-quenched alloys slightly varies with iron content and lays between 605 and 625°C. From the temperature dependence of magnetization it follows that partial substitution of cobalt by iron has positive influence on the Curie temperature of amorphous phase, $_cT^{am}$, which increases from 300°C up to 462°C for alloy with x=10 at. % and x=2 0 at. %, respectively.
Źródło:
Acta Physica Polonica A; 2008, 113, 1; 83-86
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Decomposition Processes in the Anomalous Supersaturated Solid Solution of Binary and Ternary Aluminium Alloys Alloyed with~Sc and~Zr
Autorzy:
Berezina, A.
Monastyrska, T.
Molebny, O.
Nosenko, V.
Kotko, A.
Powiązania:
https://bibliotekanauki.pl/articles/1418937.pdf
Data publikacji:
2012-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
64.70.dg
81.07.Bc
81.10.Fq
Opis:
Decomposition of supersaturated solid solution of aluminium alloys alloyed with Sc and Zr have been studied in the work. The binary hypereutectic Al-Sc alloys, hyperperitectic Al-Zr alloys and ternary Al-Sc-Zr alloys were chosen. Alloys were obtained by the melt-spinning. Melts were quenched from temperatures of T = 1000C and T = 1400°C. The crystallization of anomalously supersaturated solid solution ($T_\text{quen.}$ = 1400°C) or the crystallization with the formation of "fan" structure ($T_\text{quen.}$ = 1000°C) are possible. The decomposition of anomalously supersaturated solid solution is continuous, with the precipitation of nanosized spherical $Al_3X$ (X = Sc, Zr) particles. The loss of thermal stability of Al-Sc alloys is due to the loss of coherence of the strengthening $Al_3Sc$ phase. In Al-Zr alloys the loss of strength is due to the formation of a stable tetragonal $DO_{23}$-ordered $Al_3Zr$ phase. After co-alloying of Al by Sc and Zr a bimodal grained structure was observed for the hypereutectic ternary alloy ($T_\text{quen.}$ = 1400°C). Nanosized grains of 50-60 nm were present on the boundaries of 1-2 μm large-sized grains. Transmission electron microscopy shows the formation of nanocomposite $Al_3Zr//Al_3Sc$ particles. The formation of $Al_3Zr$ shell changes the nature of the interfacial fit of the particle with the matrix and slows down the decomposition during the coalescence.
Źródło:
Acta Physica Polonica A; 2012, 122, 3; 539-543
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Approach to Ferromagnetic Saturation for the Bulk Amorphous Alloy: $(Fe_{0.61}Co_{0.10}Zr_{0.025}Hf_{0.025}Ti_{0.02}W_{0.02}B_{0.20})_{97}Y_{3}$
Autorzy:
Błoch, K.
Nabiałek, M.
Powiązania:
https://bibliotekanauki.pl/articles/1386293.pdf
Data publikacji:
2015-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.-y
75.50.Kj
75.30.Ds
75.20.En
75.47.Np
75.50.Bb
75.60.Ej
Opis:
The aim of this paper was to conduct studies concerning the magnetization of bulk amorphous $(Fe_{0.61}Co_{0.10}Zr_{0.025}Hf_{0.025}Ti_{0.02}W_{0.02}B_{0.20})_{97}Y_{3}$ alloy when subjected to strong magnetic fields: the specific focus of the paper is the area known as the approach to ferromagnetic saturation. The investigated alloy samples were produced using the suction-casting method, resulting in plates of dimensions 10 mm × 5 mm × 0.5 mm and rods of length 20 mm and diameter 1 mm. The structure was studied using X-ray diffractometry. It was found that investigated samples were amorphous in the as-cast state. The magnetization was measured in a strong magnetic field using a vibrating sample magnetometer. On the basis of the obtained results, the type of structural defects having influence on magnetization in high magnetic fields were determined for the bulk metallic glasses manufactured with different cooling rates.
Źródło:
Acta Physica Polonica A; 2015, 127, 2; 413-414
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Isothermal Stability and Selected Mechanical Properties of Zr48Cu36Al8Ag8 Bulk Metallic Glass
Autorzy:
Błyskun, P.
Latuch, J.
Kulik, T.
Powiązania:
https://bibliotekanauki.pl/articles/353937.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bulk metallic glasses
isothermal stability
mechanical properties
TTT curve
Opis:
The aim of this work was to investigate the influence of isothermal annealing on the amorphous structure stability of the Zr48 Cu36 Al8 Ag8 alloy. A series of continuous heating examinations was performed on the differential scanning calorimeter in order to determine the temperature limits for isothermal annealing series where the time to crystallization was measured. The obtained results were calculated and a time-temperature-transformation diagram was created and discussed. Static compression test as well as microhardness measurements of the as-quenched samples gave a mechanical properties results supplement. The measured properties (σc = 1800 MPa and 614 HV0.05) are comparable to the literature results for this alloy. Fractographic observations with the scanning electron microscope were also performed in order to prove some plasticity observed during the strength tests.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 3; 1749-1753
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Infulence of recrystallization on damping properties of alloy Fe75Zr4Ti3B17Cu1
Autorzy:
Bocian, M.
Mech, R.
Myszka, W.
Przybylski, M.
Powiązania:
https://bibliotekanauki.pl/articles/348167.pdf
Data publikacji:
2016
Wydawca:
Akademia Wojsk Lądowych imienia generała Tadeusza Kościuszki
Tematy:
experimental mechanics
metallic glass
amorphous alloy
material properties
material science
Opis:
It is expected that damping in amorphous metals change after its recrystallization. For this purpose study of this phenomena was investigated. An alloy Fe75 Z r4Ti3B17Cu1 was manufactured in a very specific conditions to obtain amorphous structure. To confirm structure of the manufactured material basic testing was conducted including XRD, AFM, LFM and SEM with EDS attachment. The study showed that the structure in fact is partially amorphous and partially nanocrystalline. To determine expected change of damping sample in form of rod was tested for bounce height in controlled conditions before and after heat treatment that changed materials structure. Obtained results indicate decrease of damping after heat treatment and therefore confirms initial assumption.
Źródło:
Zeszyty Naukowe / Wyższa Szkoła Oficerska Wojsk Lądowych im. gen. T. Kościuszki; 2016, 4; 123-134
1731-8157
Pojawia się w:
Zeszyty Naukowe / Wyższa Szkoła Oficerska Wojsk Lądowych im. gen. T. Kościuszki
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ rekrystalizacji na właściwości tłumiące stopu Fe75Zr4Ti3B17Cu1
Influence of recrystallization on damping properties of Fe75Zr4Ti3B17Cu1 alloy
Autorzy:
Bocian, M.
Mech, R.
Myszka, W.
Przybylski, M.
Powiązania:
https://bibliotekanauki.pl/articles/131330.pdf
Data publikacji:
2016
Wydawca:
Uczelnia Jana Wyżykowskiego
Tematy:
mechanika eksperymentalna
szkło metaliczne
stop amorficzny
właściwości materiałowe
inżynieria materiałowa
experimental mechanics
metallic glass
amorphous alloy
material properties
material science
Opis:
Uważa się, że tłumienie w przypadku metali o strukturze amorficznej powinno ulec zmianie po ich rekrystalizacji. W niniejszej pracy przedstawiono wyniki badań tego zagadnienia. Badania przeprowadzono na stopie Fe75Zr4Ti3B17Cu1 wykonanym w taki sposób, aby otrzymać materiał o strukturze amorficznej. W celu określenia oczekiwanej zmiany w tłumieniu badanego materiału, przeprowadzono badania polegające na pomiarze wysokości odbicia, dla próbki przed obróbką termiczną i po takiej obróbce. Otrzymane rezultaty pokazały, że względne tłumienie próbki uległo zmniejszeniu po poddaniu jej obróbce cieplnej, tym samym potwierdzając wstępne założenia.
It is expected that damping in amorphous metals changes after their recrystallization. For this purpose a study of this phenomena was investigated. A Fe75Zr4Ti3B17Cu1 alloy was manufactured in very specific conditions to obtain amorphous structure. To determine expected change of damping, a sample in form of a rod was tested for bounce height in controlled conditions before and after heat treatment that changed the material structure. The obtained results indicate a decrease of damping after heat treatment and therefore confirm the initial assumption.
Źródło:
Zeszyty Naukowe Uczelni Jana Wyżykowskiego. Studia z Nauk Technicznych; 2016, 5; 65-74
2543-6740
Pojawia się w:
Zeszyty Naukowe Uczelni Jana Wyżykowskiego. Studia z Nauk Technicznych
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Ti on Selected Properties of AlSi7Mg0.3Cu0.5 Alloy with Constant Addition of Zr
Autorzy:
Bolibruchová, D.
Kuriš, M.
Matejka, M.
Major-Gabryś, K.
Vicent, M.
Powiązania:
https://bibliotekanauki.pl/articles/2049632.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
AlSi7Mg0.3Cu0.5
investment casting
zirconium
titanium
increasing mechanical properties
Opis:
The article is focused on the synergic effect of constant content of Zr and higher content of Ti on mechanical properties Al-Si alloy. The Ti additions were in proportions of 0.1, 0.2 and 0.3 wt.% Ti. The casting process was carried out in ceramic molds, created for the investment casting technology. Half of the experimental samples were processed by precipitation curing T6. The measured results were compared with primary alloy AlSi7Mg0.3 and experimental alloy AlSi7Mg0.3Cu0.5Zr0.15. In variant with addition 0.1 wt. %, the tensile strength Rm increased by 1,5% but the elongation AM decreased to 40%. Variants with 0.2 and 0.3 wt. % addition of Ti achieved similar Rm but approximately 40% decrease in AM. However, it is interesting that yield strength Rp0.2 increased for all variants by approximately 14 to 20%. The results point out the possibility of developing a more sophisticated alloy for automotive industry.
Źródło:
Archives of Metallurgy and Materials; 2021, 66, 1; 65-72
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure, Mechanical Properties and Corrosion Behavior of Zr-Containing AlSi5Cu2Mg Alloy
Autorzy:
Bolibruchová, Dana
Širanec, Lukáš
Kajánek, Daniel
Chalupová, Mária
Powiązania:
https://bibliotekanauki.pl/articles/28099514.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
mechanical properties
zirconium
microstructure
corrosion
AlSi5Cu2Mg
Opis:
The aim of this paper was to analyze the impact of varying zirconium addition on selected properties of AlSi5Cu2Mg alloy. The results of this research showed that zirconium addition in the range of 0.05 to 0.20 wt. % caused a decrease in ultimate tensile strength and yield strength of the experimental alloys after T7 heat treatment, probably due to the formation of primary Al3Zr intermetallic phases. These phases were observed as an individual plates or as a formation of two crossed plate-like phases. Potentiodynamic polarization tests in 3.5% NaCl solution revealed that addition of Zr had a positive effect on thermodynamic corrosion stability of the AlSi5Cu2Mg alloy due to shift of the corrosion potential to a more positive values for all as-cast samples. Addition of Zr in the as-cast alloys improved corrosion kinetics by lowering of corrosion current density.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 2; 749--756
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł

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