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Wyszukujesz frazę "Kinetic analysis" wg kryterium: Temat

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    Wyświetlanie 1-7 z 7
    Tytuł:
    Kinetic modeling of chromium(III) extraction with aliquat 336 from alkaline aqueous solutions containing chlorides
    Autorzy:
    Wionczyk, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/110327.pdf
    Data publikacji:
    2013
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    extraction
    chromium(III) chloride
    Aliquat 33
    kinetic analysis
    Opis:
    The effects of time, composition and history of preparation of the aqueous phase on the liquidliquid extraction of chromium(III) with Aliquat 336 from the aqueous alkaline solutions containing chlorides were studied. At time far from the equilibrium the yield and initial rate of the chromium(III) extraction depend on NaOH concentration, ionic strength of the aqueous phase and the way of its preparation. At the constant composition of the feed solution, rate of the Cr(III) extraction in approach to the equilibrium is higher when chromium(III) is extracted from the alkaline aqueous phase freshly prepared by direct dissolution of a weighted sample of CrCl3 than from that obtained by dilution of aged stock solution of CrCl3. Kinetic analysis by the mathematical models showed that within the whole period of time needed to reach the equilibrium, the rate of the Cr(III) extraction is limited by the second-, and third-order chemical reaction towards Cr(III), irrespective of composition and preparation history of the aqueous phase. The three-dimensional diffusion and chemical reaction at phase boundary substrateproduct (the contracting volume) models have a significant effect on the chromium(III) extraction within the initial extent of the process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2013, 49, 2; 587-605
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermal and kinetic analysis of pure and contaminated ionic liquid: 1-butyl-2.3-dimethylimidazolium chloride (BDMIMCl)
    Autorzy:
    Muhammad, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/949468.pdf
    Data publikacji:
    2016
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    ionic liquid
    thermal stability
    kinetic analysis
    activation energy
    Opis:
    In this research work, thermal decomposition and kinetic analysis of pure and contaminated imidazolium based ionic liquid (IL) has been investigated. As thermal decomposition and kinetics evaluation plays a pivotal role in effective process design. Therefore, thermal stability of pure 1-butyl-2,3-dimethylimidazolium chloride (BDMIMCl) was found to be higher than the sample of IL with the addition of 20% (wt.) NH4Cl as an impurity. The activation energy of thermal degradation of IL and other kinetic parameters were determined using Coats Redfern method. The activation energy for pure IL was reduced in the presence of NH4Cl as contaminant i.e., from 58.7 kJ/mol to 46.4 kJ/mol.
    Źródło:
    Polish Journal of Chemical Technology; 2016, 18, 2; 122-125
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermal behavior and kinetic decomposition of sweet potato starch by non-isothermal procedures
    Autorzy:
    Liu, Ying
    Yang, Liutao
    Zhang, Yingzhe
    Powiązania:
    https://bibliotekanauki.pl/articles/240460.pdf
    Data publikacji:
    2019
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    starch
    kinetic analysis
    thermal degradation
    activation energy
    mechanism
    Opis:
    In this study, X-ray diffraction, thermogravimetric analysis and differential scanning calorimetry (DSC) method were used to analyze the main characteristics of sweet potato starch, and to analyze the thermal degradation process of sweet potato starch. Specifically, X-ray diffraction to study its structure, thermogravimetric analysis to study the thermal degradation kinetics, and differential scanning calorimetry to study the thermogram of sweet potato starch. The thermal decomposition kinetics of sweet potato starch was examined within different heating rates in nitrogen atmosphere. Different models of kinetic analysis were used to calculate the activation energies using thermogravimetric data of the thermal degradation process. Activation energies obtained from Kissinger, Flynn-WallOzawa, and Šatava-Šesták models were 173.85, 174.87 and 174.34 kJ/mol, respectively. The values of activation energy indicated that the thermal degradation of the sweet potato starch was a single reaction mechanism or the combination of multi-reaction mechanisms. The differential scanning calorimetry analysis show that two decomposition stages were presented: the first at a low temperature involves the decomposition of long chain; and the second at a high temperature represents the scission of glucose ring. This information was helpful to design the processing process of many natural polymers. Thermogravimetric Fourier transform-infrared (TG–FTIR) analysis showed that the main pyrolysis products included water, methane, carbon dioxide, ammonia, and others.
    Źródło:
    Archives of Thermodynamics; 2019, 40, 4; 67-82
    1231-0956
    2083-6023
    Pojawia się w:
    Archives of Thermodynamics
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Activity and kinetic properties of phosphotransacetylase from intestinal sulfate-reducing bacteria
    Autorzy:
    Kushkevych, Ivan
    Powiązania:
    https://bibliotekanauki.pl/articles/1039142.pdf
    Data publikacji:
    2015
    Wydawca:
    Polskie Towarzystwo Biochemiczne
    Tematy:
    sulfate-reducing bacteria
    phosphotransacetylase
    kinetic analysis
    inflammatory bowel diseases
    Opis:
    Phosphotransacetylase activity and the kinetic properties of the enzyme from intestinal sulfate-reducing bacteria Desulfovibrio piger and Desulfomicrobium sp. has never been well-characterized and has not been studied yet. In this paper, the specific activity of phosphotransacetylase and the kinetic properties of the enzyme in cell-free extracts of both D. piger Vib-7 and Desulfomicrobium sp. Rod-9 intestinal bacterial strains were presented at the first time. The microbiological, biochemical, biophysical and statistical methods in this work were used. The optimal temperature and pH for enzyme reaction was determined. Analysis of the kinetic properties of the studied enzyme was carried out. Initial (instantaneous) reaction velocity (V0), maximum amount of the product of reaction (Pmax), the reaction time (half saturation period, τ) and maximum velocity of the phosphotransacetylase reaction (Vmax) were defined. Michaelis constants (Km) of the enzyme reaction (3.36 ± 0.35 mM for D. piger Vib-7, 5.97 ± 0.62 mM for Desulfomicrobium sp. Rod-9) were calculated. The studies of the phosphotransacetylase in the process of dissimilatory sulfate reduction and kinetic properties of this enzyme in intestinal sulfate-reducing bacteria, their production of acetate in detail can be perspective for clarification of their etiological role in the development of the humans and animals bowel diseases. These studies might help in predicting the development of diseases of the gastrointestinal tract, by providing further details on the etiology of bowel diseases which are very important for the clinical diagnosis of these disease types.
    Źródło:
    Acta Biochimica Polonica; 2015, 62, 1; 103-108
    0001-527X
    Pojawia się w:
    Acta Biochimica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Reaction Kinetics and Morphological Study of TiNb2O7 Synthesized by Solid-State Reaction
    Autorzy:
    Choi, S. H.
    Ali, B.
    Choi, K. S.
    Hyun, S. K.
    Sim, J. J.
    Choi, W. J.
    Joo, W.
    Lim, J. H.
    Lee, T. H.
    Kim, T. S.
    Park, K. T.
    Powiązania:
    https://bibliotekanauki.pl/articles/355326.pdf
    Data publikacji:
    2017
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    solid state reaction
    kinetic analysis
    quantitative phase analysis
    TiNb2O7 synthesis
    Opis:
    Although TiNb2O7 is regarded as a material with high application potential in lithium-ion batteries (LIBs) and solid-oxide fuel cells (SOFCs), it has been difficult to find suitable cost-effective conditions for synthesizing it on a commercial scale. In this study, TiNb2O7 compounds were synthesized by a solid state synthesis process. For stoichiometrically precise synthesis of the TiNb2O7 phase, the starting materials, TiO2 and Nb2O5 were taken in a 1:1 molar ratio. Activation energy and reaction kinetics of the system were investigated at various synthesis temperatures (800,1000,1200, and 1400°C) and for various holding durations (1,5,10, and 20 h). Furthermore, change in the product morphology and particle size distribution were also evaluated as a function of synthesis temperature and duration. Additionally, quantitative phase analysis was conducted using the Rietveld refinement method. It was found that increases in the synthesis temperature and holding time lead to increase in the mean particle size from 1 to 4.5 μm. The reaction rate constant for the synthesis reaction was also calculated.
    Źródło:
    Archives of Metallurgy and Materials; 2017, 62, 2B; 1051-1056
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Formation And Stabilization Of Silver Nanoparticles In Ethanol By Phosphinic Acid
    Redukcja i stabilizacja nanocząstek srebra w etanolu przez kwas fosforowy
    Autorzy:
    Kim, J.-K.
    Shim, H.-M.
    Park, M. J.
    Koo, K.-K.
    Powiązania:
    https://bibliotekanauki.pl/articles/356073.pdf
    Data publikacji:
    2015
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    silver
    nanoparticle
    kinetic analysis
    phosphinic acid
    reduction
    srebro
    nanocząstki
    analiza kinetyczna
    kwas fosforowy
    redukcja
    Opis:
    Although phosphinic acid (H3PO2) has a powerful reduction potential, the reduction of silver ions by phosphinic acid salt has not yet been reported. In this work, colloidal silver has successfully synthesized by reducing silver ions in ethanol with phosphinic acid as a reducing agent. The effects of [AgNO3]/[H3PO2] ratios and reaction temperature were considered. Spherical silver nanoparticles with cubic structure were successfully prepared and their diameters were measured to be 8.5±0.9 nm − 11.3±0.2 nm. Half-life analysis showed that the reduction of silver ions proceeded with the reaction order of 1.30 on concentration of phosphinic acid and activation energy of 120.7 kJ/mol.
    Źródło:
    Archives of Metallurgy and Materials; 2015, 60, 2B; 1293-1296
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Kinetic Analysis of Aluminium Evaporation from the Ti-6Al-7Nb Alloy
    Analiza kinetyczna procesu parowania aluminium ze stopu Ti-6Al-7Nb
    Autorzy:
    Blacha, L.
    Golak, S.
    Jakovics, A.
    Tucs, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/353782.pdf
    Data publikacji:
    2014
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    kinetic analysis
    evaporation
    Ti-6Al-7Nb alloy
    liquid titanium meniscus area
    liquid titanium mean velocity
    analiza kinetyczna
    parowanie
    stop Ti-6Al-7Nb
    powierzchnia menisku ciekłego tytanu
    średnia prędkość ciekłego tytanu
    Opis:
    In the present paper, kinetics of aluminium evaporation from the Ti-6Al-7Nb alloy during smelting by means of the VIM method at 5 to 1000 Pa has been discussed. To determine the liquid titanium meniscus area and the liquid titanium mean velocity for the experimental conditions of the study, a methodology based on the coupled model of the electromagnetic field and the hydrodynamic field of liquid metal was applied.
    W prezentowanej pracy omówiono kinetykę procesu odparowania aluminium ze stopu Ti-6Al.-7Nb wytapianego metodą VIM w zakresie ciśnień od 5 do 1000Pa. Do wyznaczenia powierzchni| menisku ciekłego tytanu oraz średniej prędkości ciekłego tytanu wykorzystano model matematyczny procesu topienia i nagrzewania ciekłego metalu w piecu indukcyjnym uwzględniający sprzężenie pola elektromagnetycznego i pola hydrodynamicznego ciekłego metalu.
    Źródło:
    Archives of Metallurgy and Materials; 2014, 59, 1; 275-279
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

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