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Tytuł:
Crystallization Behavior of Zr62Al8Ni13Cu17 Metallic Glass
Autorzy:
Jo, M. S.
Lee, J. K.
Powiązania:
https://bibliotekanauki.pl/articles/353070.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
metallic glass
crystallization
kinetics
amorphous
Zr-based
Opis:
The crystallization behavior has been studied in Zr62Al8Ni13Cu17 metallic glass alloy. The Zr62Al8Ni13Cu17 metallic glass crystallized through two steps. The fcc Zr2Ni phase transformed from the amorphous matrix during first crystallization and then the Zr2Ni and residual amorphous matrix transformed into a mixture of tetragonal Zr2Cu and hexagonal Zr6Al2Ni phases. Johnson- Mehl-Avrami analysis of isothermal transformation data suggested that the formation of crystalline phase is primary crystallization by diffusion-controlled growth.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1023-1026
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on Viscoelastic, Thermal and Morphological Properties of Vinyl Ester - Mixed Diluents System
Autorzy:
Ranjan, J. K.
Raghu Raja Pandiyan, K.
Goswami, S.
Powiązania:
https://bibliotekanauki.pl/articles/354420.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
vinyl ester resin
dynamic mechanical analysis
TGA
DSC
morphology
Opis:
Vinyl ester resin networks formed by using mixture of diluents were prepared. Methyl methacrylate (MMA) diluent was mixed in various proportions with vinyl ester resin which was already premixed with styrene diluent (45 wt. %). Weight ratios e.g. 80:20, 70:30 and 60:40 of VE resin: MMA diluents were studied. Viscoelastic properties of the cross-linked resin were studied by dynamic mechanical analyzer in terms of storage modulus and tanδ. Thermal analysis was performed using non-isothermal mode of Differential scanning calorimetry. The samples with mixed diluents, showed higher modulus, and glass transition temperature in comparison to that of the pure vinyl ester-styrene resin cross-linked in presence of styrene only. The difference in thermal stability between vinyl ester-styrene and vinyl ester-MMA-styrene was checked. Vinyl Ester – 20 wt. % MMA-Styrene samples have the best thermal property among all other prepared samples. Multiphase morphology was formed for the thermoset crosslinked with mixed diluents in contrast to that formed with single diluent. With increase in MMA content in the resin dispersed domain size increased.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 3; 1845-1850
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Pre-Sintering on the Diffusion Treatment of HRE for Coercivity Enhancement of a NdFeB Sintered Magnet
Autorzy:
Lee, M. W.
Lee, J. K.
Jang, T. S.
Powiązania:
https://bibliotekanauki.pl/articles/355250.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
grain boundary diffusion process
GBDP
NdFeB magnet
coercivity
pre-sintering
Opis:
We investigated the effect of pre-sintering process on the penetration behavior of Dy in a NdFeB sintered magnet which was grain boundary diffusion treated with Cu/Al mixed Dy source. The pre-sintering of a magnet was performed at 900°C in vacuum and then the pre-sintered body was dipped in the solutions of DyH2, DyH2 + Cu, and DyH2 + Al, respectively. The dipped pre-sintered body were then fully sintered 4 hours at 1060°C followed by a subsequent annealing. The pre-sintering apparently improved the diffusivity of Dy atoms. The penetration of Dy into the magnet extended almost to 2,000 μm from the surface, about four times deeper than that of the normally sintered and diffusion treated one, when the DyH2 + Al solution was used as a Dy source. However, the resulting increase of coercivity was about 4 kOe, somewhat lower than that of the normally treated one, mostly due to excessive oxide formation that hindered to make a continuous Nd-rich grain boundary phase and a core-shell type structure.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 2; 597-601
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biodegradable Poly(Lactic Acid)/Multiwalled Carbon Nanotube Nanocomposite Fabrication Using Casting And Hot Press Techniques
Wytwarzanie biodegradowalnych nanokompozytów typu poli(kwas mlekowy)/wielościenne nanorurki węglowe technikami odlewania i prasowania na gorąco
Autorzy:
Park, S. G.
Abdal-Hay, A.
Lim, J. K.
Powiązania:
https://bibliotekanauki.pl/articles/356593.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
CNTs
biodegradable polymer
advanced polymer matrix composites
hot press
mechanical properties
polimer biodegradowalny
zaawansowane kompozyty polimerowe
prasowanie na gorąco
właściwości mechaniczne
Opis:
Biodegradable advanced polymer composites have recently received a large amount of attention. The present study aimed to design poly(lactic acid) multiwalled carbon nanotube nanocomposites (PLA/MWCNTs) using a simple fabrication technique. A PLA sheet was first dissolved in dichloromethane, and MWCNTs were subsequently added at various concentrations (0.5, 1.5 and 5%) while applying shear strain stirring to achieve dispersion of carbon nanotubes (CNTs). These solutions were then molded and a hot press was used to generate sheets free of voids with entrapped solvent. The prepared samples were characterized using field emission scanning electron microscopy (FE-SEM), x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). Our data showed composite samples free of defects and voids, indicating that the hot press is capable of generating sufficiently compact polymer matrices. Additionally, TGA and FTIR showed significant bonding interactions between the PLA matrix and the nano-fillers. Collectively, our results suggest that incorporation of CNTs as nano-fillers into biodegradable polymers may have multiple applications in many different sectors.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1557-1559
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Formation And Stabilization Of Silver Nanoparticles In Ethanol By Phosphinic Acid
Redukcja i stabilizacja nanocząstek srebra w etanolu przez kwas fosforowy
Autorzy:
Kim, J.-K.
Shim, H.-M.
Park, M. J.
Koo, K.-K.
Powiązania:
https://bibliotekanauki.pl/articles/356073.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
silver
nanoparticle
kinetic analysis
phosphinic acid
reduction
srebro
nanocząstki
analiza kinetyczna
kwas fosforowy
redukcja
Opis:
Although phosphinic acid (H3PO2) has a powerful reduction potential, the reduction of silver ions by phosphinic acid salt has not yet been reported. In this work, colloidal silver has successfully synthesized by reducing silver ions in ethanol with phosphinic acid as a reducing agent. The effects of [AgNO3]/[H3PO2] ratios and reaction temperature were considered. Spherical silver nanoparticles with cubic structure were successfully prepared and their diameters were measured to be 8.5±0.9 nm − 11.3±0.2 nm. Half-life analysis showed that the reduction of silver ions proceeded with the reaction order of 1.30 on concentration of phosphinic acid and activation energy of 120.7 kJ/mol.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1293-1296
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enhanced Microwave Absorption of CNT Composites Mixing with Fe3O4 and Carbonyl Iron
Autorzy:
Park, J. H.
Choi, J.
Lee, K.
Park, J.
Song, J. K.
Jeon, E.
Powiązania:
https://bibliotekanauki.pl/articles/351106.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
magnetic powders
complex permittivity
complex permeability
composite materials
microwave absorption
Opis:
We fabricated two different kinds of composite materials for absorbing microwave in a frequency range of 2 to 18 GHz using coaxial airline and thru-reflect-line (TRL) method. The composite materials having carbon nanotube (CNT) with carbonyl iron (CI) or iron oxide (Fe3 O4 ) were fabricated by mixing each components. Magnetic properties were measured by SQUID equipment. Complex permittivity and complex permeability were also obtained by measuring S-parameters of the toroidal specimen dispersing CI/CNT and Fe3 O4 /CNT into the 50 weight percent (wt%) epoxy resin. The real permittivity was improved by mixing the CNT however, the real permeability was same as pure magnetic powders. The CI/CNT had a maximum value of real permittivity and real permeability, 11 and 1.4 at 10 GHz, respectively. The CNT composites can be adapted to the radar absorbing materials, band width 8-12 GHz.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1513-1516
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure Evolution of Ni-Based ODS Superalloy Powders During Horizontal Rotary Ball Milling
Autorzy:
Lee, H.-E.
Kim, Y. S.
Park, J. K.
Oh, S.-T.
Powiązania:
https://bibliotekanauki.pl/articles/355552.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high energy ball milling
Ni-base ODS superalloy
particle and crystalline size
microstructure
Opis:
Microstructure evolution of Ni-based oxide dispersion-strengthened alloy powders with milling time is investigated. The elemental powders having a nominal composition of Ni-15Cr-4.5Al-4W-2.5Ti-2Mo-2Ta-0.15Zr-1.1Y2O3 in wt % were ball-milled by using horizontal rotary ball milling with the change of milling velocity. Microstructure observation revealed that large aggregates were formed in the early stages of ball milling, and further milling to 5 h decreased particle size. The average crystalline size, estimated by the peak broadening of XRD, decreased from 28 nm to 15 nm with increasing milling time from 1 h to 5 h. SEM and EPMA analysis showed that the main elements of Ni and Cr were homogeneously distributed inside the powders after ball milling of 5 h.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1253-1255
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect Of Carbon Nanotubes On The Properties Of Spark Plasma Sintered ZrO2/CNT Composites
Wpływ nanorurek węglowych na właściwości spiekanych metodą sps kompozytów ZrO2/CNT
Autorzy:
Shim, D. H.
Jung, S. S.
Kim, H. S.
Cho, H.
Kim, J. K.
Kim, T. G.
Yoon, S. J.
Powiązania:
https://bibliotekanauki.pl/articles/351266.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
CNT
ZrO2
composite
SPS
kompozyty
Opis:
Zirconia matrix ZrO2/CNT composite materials reinforced with multiwall carbon nanotubes were fabricated using a spark plasma sintering technique. The effects of the amount of CNTs addition, sintering temperature and sintering pressure on the properties of the resulting ZrO2/CNT composites were examined. 0 to 9 vol. % CNTs were dispersed in zirconia powder, and the resulting mixture was sintered. The electrical conductivity, hardness, flexural strength, and density were measured to characterize the composites. The friction and wear properties of the composites were also tested. The flexural strength and friction coefficient of the composites were improved with up to 6 vol.% of CNT addition and the flexural strength showed a close relationship with the relative density of the composite. The electrical conductivity increased with increasing proportion of the CNTs, but the efficiency was reduced at more than 6 vol.% CNTs.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1315-1318
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improvement of mechanical properties of a nanoaluminium alloy by precipitate strengthening
Poprawa właściwości mechanicznych nanokrystalicznego stopu aluminium poprzez umocnienie wydzieleniowe
Autorzy:
Wawer, K.
Lewandowska, M.
Kurzydłowski, K. J.
Powiązania:
https://bibliotekanauki.pl/articles/356469.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
wytrzymałość stopów aluminium
SPD
wciskanie hydrostatyczne
aluminium alloys
nanostructured metals
severe plastic deformation
Opis:
In the present study, severe plastic deformation (SPD) processing was combined with pre- and post processing heat treatment to investigate the possibility of synergic grain size and precipitation strengthening. Samples of 7475 alloy were solution heat treated and water quenched prior to hydrostatic extrusion (HE) which resulted in a grain refinement by 3 orders of magnitude, from 70 μ to about 70 nm. The extruded samples were subsequently aged at temperatures resulting in formation of nanoprecipitates.
W pracy zbadano możliwość zwiększania wytrzymałości stopów aluminium poprzez połączenie zabiegów rozdrobnienia ziaren z wykorzystaniem metod SPD z obróbką cieplną. Próbki stopu aluminium 7475 poddano wciskaniu hydrostatycznemu w stanie przesyconym, co spowodowało znaczące rozdrobnienia ziarna, z 70 μ do 70 nm. Wyciśnięte próbki poddano starzeniu w celu wytworzenia nanowydzieleń.
Źródło:
Archives of Metallurgy and Materials; 2012, 57, 3; 878-881
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanical behaviour of ultrafine grained Al-Mg alloys obtained by different processing routes
Właściwości mechaniczne ultra drobnoziarnistych stopów Al-Mg otrzymanych różnymi metodami
Autorzy:
Bazarnik, P.
Lewandowska, M.
Kurzydłowski, K. J.
Powiązania:
https://bibliotekanauki.pl/articles/356425.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
stopy aluminium
konsolidacja plastyczna
nanoproszki
transmission electron microscopy
Portevin-Le Chatelier effect
Strengthening mechanisms
ultrafine grained
Opis:
The subject of the study were microstructure and mechanical properties of two commercial 5xxx aluminium alloys obtained by Plastic Consolidation (PC) of nanopowders and Hydrostatic extrusion (HE). It has been observed that HE samples exhibit a higher strength whereas PC samples higher ductility. The two types of samples also differ in the type and intensity of serrations on stress-strain curves. The microstructures of samples processed were found to differ significantly in terms of size and shape of grains, grain boundary characteristics, second phase particles content and density of dislocations. The results are discussed in terms of the influence of microstructure on mechanical behaviour of 5xxx aluminium alloys processed by severe plastic deformation.
W poniższej pracy badano właściwości mechaniczne dwóch komercyjnych ultra drobnoziarnistych stopów aluminium serii 5xxx otrzymanych przez Konsolidację Plastyczną (PC) nanoproszków oraz przez Wyciskanie Hydrostatyczne (HE). Mikrostruktury badanych próbek znacząco sie różniły, w szczególności pod względem wielkości ziarna i charakteru granic ziaren. Badania właściwości mechanicznych pokazały, że obie próbki wykazują znakomite właściwości wytrzymałościowe (w obu próbkach granica plastyczności przekracza 450 MPa), jednakże próbki HE wykazują wyższa wytrzymałość, podczas gdy próbki PC większą plastyczność. Wyniki przedstawiono w formie analizy wpływu mikrostruktury na właściwości mechaniczne stopów aluminium serii 5xxx otrzymanych technikami dużego odkształcenia plastycznego. Wysokie właściwości mechaniczne przypisano różnorodnym mechanizmom umacniającym i funkcjonującym w tych próbkach, włączając w to: umocnienie roztworowe, umocnienie wydzieleniowe oraz umocnienie granicami ziaren i dyslokacyjne. Uzyskane wyniki wskazują na to, ze mikrostruktura ma znaczący wpływ nie tylko na właściwości mechaniczne, ale również na typ ząbkowania na krzywych rozciągania.
Źródło:
Archives of Metallurgy and Materials; 2012, 57, 3; 869-876
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Magnetic Entropy Changes in Pb Doped Ni-Mn-Cu-Ga Alloys
Autorzy:
Sielicki, K.
Zygmuntowicz, J.
Wróblewski, R.
Leonowicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/354050.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
magnetocaloric effect
magnetic entropy change
Curie temperature
Heusler alloys
Opis:
Effect of Pb addition on magnetocaloric properties of Ni50 Mn18,75 Cu6,25-aPbaGa25 (a = 1, 2, 3, 4, 5) alloys was investigated experimentally. The magnetic measurements conducted at low field of 4 kA/m showed that addition of Pb led to separation of the both transformation temperatures and significantly shifted the structural transition effect towards lower temperatures as well as increased the Curie temperature. The analysis of isothermal magnetic curves allowed for the calculation of magnetic entropychange (ΔSM). Although the peak values of |ΔSM| for alloys containing 4 and 5 at.% Pb, ~3 J/(kg*K) and ~1.5 J/(kg*K) respectively, are low they stretch over the structural transformation and Curie temperature, and are at least 30 K wide at half maximum height.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 823-825
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Incorporation of the Pore Size Variation to Modeling of the Elastic Behavior of Metallic Open-Cell Foams
Autorzy:
Ćwieka, K.
Wejrzanowski, T.
Kurzydłowski, K. J.
Powiązania:
https://bibliotekanauki.pl/articles/354721.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
open-cell metallic foams
Laguerre-Voronoi tessellations
pore size variation
Young's modulus
Opis:
In the present paper we present the approach for modeling of the elastic behavior of open-cell metallic foams concerning non-uniform pore size distribution. This approach combines design of foam structures and numerical simulations of compression tests using finite element method (FEM). In the design stage, Laguerre-Voronoi tessellations (LVT) were performed on several sets of packed spheres with defined variation of radii, bringing about a set of foam structures with porosity ranging from 74 to 98% and different pore size variation quantified by the coefficient of pore volume variation, CV(V), from 0.5 to 2.1. Each structure was numerically subjected to uni-axial compression test along three directions within the elastic region. Basing on the numerical response, the effective Young’s modulus, Eeff, was calculated for each structure. It is shown that the Eeff is not only dependent on the porosity but also on the pore size variation.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 259-262
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Compositional Dependence of Hardness of Ge-Sb-Se Glass for Molded Lens Applications
Zależność stężeniowa twardości szkła Ge-Sb-Se do zastosowań na formowane soczewki
Autorzy:
Park, J. K.
Lee, J. H.
Shin, S. Y.
Yi, J. H.
Lee, W. H.
Park, B. J.
Choi, J. H.
Kim, N. Y.
Choi, Y. G.
Powiązania:
https://bibliotekanauki.pl/articles/352228.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
chalcogenide glasses
Ge-Sb-Se glass
infrared lens
molded lens
infrared camera
szkło
Ge-Sb-Se
soczewki formowane
twardość szkła
kamera termowizyjna
Opis:
Chalcogenide glass in the ternary Ge-Sb-Se system is inherently moldable, thus being considered as a strong candidate material for use in infrared-transmitting lens applications from the viewpoint of thermal and mechanical stability. In an effort to experimentally determine compositional region suitable for the molded lens applications, we evaluate its compositional dependence of hardness. Among the constituent atoms, Ge content turns out to exert a most conspicuous correlation with hardness. This phenomenological behavior is then explained in connection with the structural evolution that Ge brings about.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1205-1208
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties of Copper Doped Neodymium Nickelate Oxide as Cathode Material for Solid Oxide Fuel Cells
Autorzy:
Lee, K. J.
Choe, Y-J.
Hwang, H-J.
Powiązania:
https://bibliotekanauki.pl/articles/351292.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
solid oxide fuel cells
copper
electrical conductivity
excess oxygen
Opis:
Mixed ionic and electronic conducting K2NiF4-type oxide, Nd2Ni1-xCuxO4+δ (x=0~1) powders were synthesized by solid state reaction technique and solid oxide fuel cells consisting of a Nd2Ni1-xCuxO4+δ cathode, a Ni-YSZ anode and ScSZ as an electrolyte were fabricated. The effect of copper substitution for nickel on the electrical and electrochemical properties was examined. Small amount of copper doping (x=0.2) resulted in the increased electrical conductivity and decreased polarization resistance. It appears that this phenomenon was associated with the high mean valence of nickel and copper and the resulting excess oxygen (δ). It was found that power densities of the cell with the Nd2Ni1-xCuxO4+δ (x=0.1 and 0.2) cathode were higher than that of the cell with theNd2NiO4+δ cathode.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 625-628
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The characteristic of deformability and quantitative description of the microstructure of hot-deformed Ni-Fe superalloy
Autorzy:
Ducki, K. J.
Rodak, K.
Mendala, J.
Wojtynek, L.
Powiązania:
https://bibliotekanauki.pl/articles/351819.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Incolloy 718
hot deformation
recrystallization
quantitative metallography
Zener-Hollomon parameter
Opis:
The paper presents the results of research concerning the influence of hot plastic working parameters on the deformability and microstructure of a Ni-Fe superalloy. The research was performed on a torsion plastometer in the range of temperatures of 900-1150°C, at a strain rates 0.1 and 1.0 s-1. Plastic properties of the alloy were characterized by the worked out flow curves and the temperature relationships of flow stress and strain limit. The structural inspections were performed on microsections taken from plastometric samples after so-called “freezing”. The stereological parameters as the recrystallized grain size, inhomogenity and grain shape have been determined. Functional relations between the Zener-Hollomon parameter and the maximum yield stress and the average grain area have been developed and the activation energy for hot working has been estimated.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 297-302
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł

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