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Wyświetlanie 1-15 z 79
Tytuł:
A novel method to extract vanadium from vanadium-bearing steel slag using sodium carbonate solution
Autorzy:
Gao, M.
Xue, X.
Li, L.
Yang, H.
Bai, R.
Wang, H.
Powiązania:
https://bibliotekanauki.pl/articles/109859.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
leaching
kinetics
vanadium
vanadium-bearing steel slag
Opis:
A new method using sodium carbonate solution to treat a vanadium-bearing steel slag is proposed. The effects of the particle size, solid-to-liquid ratio, initial concentration of sodium carbonate solution, leaching temperature and stirring speed on the leaching rate of vanadium were investigated. The leaching kinetics of vanadium from the vanadium-bearing steel slag was studied, which indicated that the leaching rate was controlled by the step of diffusion through the solid layer around the unreacted core. The apparent activation energy for the process was 13.75 kJ/mol. By using this process, vanadium could be extracted effectively with the leaching rate of more than 80%.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 911-921
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oznaczanie wanadu(IV) i wanadu(V) w roztworach Benfielda
Autorzy:
Michalski, R.
Kondrat, A.
Syrek, M.
Łyko, A.
Powiązania:
https://bibliotekanauki.pl/articles/273963.pdf
Data publikacji:
2015
Wydawca:
Roble
Tematy:
wanad
specjacja wandu
oznaczanie wanadu
proces Benfielda
vanadium
vanadium speciation
vanadium determination
Benfield process
Opis:
W pracy opisano metody oznaczania jonów wanadu(IV) i wanadu(V) za pomocą chromatografii jonowej. Specjacja wanadu jest istotna miedzy innymi podczas usuwania CO 2 metodą Benfielda w procesie wytwarzania amoniaku, w której nieorganiczne jony wanadu pełnią istotną rolę inhibitora korozji.
Źródło:
LAB Laboratoria, Aparatura, Badania; 2015, 20, 4; 16-18
1427-5619
Pojawia się w:
LAB Laboratoria, Aparatura, Badania
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Leaching of vanadium(V) from the mixture after potassium metavanadate synthesis based on KCl and spent vanadium catalyst
Autorzy:
Kiełkowska, U.
Białowicz, K.
Drużyński, S.
Powiązania:
https://bibliotekanauki.pl/articles/780081.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
KVO3 synthesis
spent vanadium catalyst
leaching
recovery
iron
vanadium(V)
Opis:
The results of the leaching of vanadium(V) from the mixture after potassium metavanadate synthesis from KCl and spent vanadium catalyst in the presence of steam were presented. Spent vanadium catalyst was obtained from the waste storage of a chemical plant producing sulfuric acid(VI) by the contact method. The reaction mixture was leached using different solutions: 1 M Na2CO3, 20% CO(NH2)2, 15% NaOH, 15% KOH, 2 M H2SO4. The effect of time and temperature was studied. The results showed that for reaction mixture leached for 4 h at 303 K in the presence of 15% sodium hydroxide solution at a liquid:solid ratio of 10:1, the extent of leaching of vanadium(V) was 95.43%.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 4; 33-35
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Use of Ion Exchange in the Recovery of Vanadium from the Mass of a Spent Catalyst Used in the Oxidation of SO2 to SO3
Autorzy:
Drużyński, S.
Mazurek, K.
Białowicz, K.
Powiązania:
https://bibliotekanauki.pl/articles/778892.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
spent vanadium catalyst
recovery of vanadium
ion exchange
solid waste utilization
Opis:
In the studies on the recovery of vanadium from vanadium catalyst extracts, three types of polymer strongly acidic ion exchangers were used. The ion exchange resins differed in terms of granularity and their ion exchange capacity. As a result, breakthrough curves were made for three main components of the test extract, i.e.: ions of vanadium, iron and potassium. On this basis the optimum conditions for the removal of iron ions from the solution were defined and the technological concept of the process in the semi-technical scale was proposed.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 2; 69-73
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Anisotropic in Situ Metal Matrix Composite Reinforced with VC Carbide Fibres
Autorzy:
Kawalec, M.
Górny, M.
Sikora, G.
Powiązania:
https://bibliotekanauki.pl/articles/381579.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
cast composite
directional solidification
vanadium eutectic
vanadium carbide
microstructure
kompozyt odlewany
krzepnięcie kierunkowe
węglik wanadu
Opis:
A eutectic reaction is a basic liquid-solid transformation, which can be used in the fabrication of high-strength in situ composites. In this study an attempt was made to ensure directional solidification of Fe-C-V alloy with hypereutectic microstructure. In this alloy, the crystallisation of regular fibrous eutectic and primary carbides with the shape of non-faceted dendrites takes place. According to the data given in technical literature, this type of eutectic is suitable for the fabrication of in-situ composites, owing to the fact that a flat solidification front is formed accompanied by the presence of two phases, where one of the phases can crystallise in the form of elongated fibres. In the present study an attempt was also made to produce directionally solidifying vanadium eutectic using an apparatus with a very high temperature gradient amounting to 380 W/cm at a rate of 3 mm/h. Alloy microstructure was examined in both the initial state and after directional solidification. It was demonstrated that the resulting microstructure is of a non-homogeneous character, and the process of directional solidification leads to an oriented arrangement of both the eutectic fibres and primary carbides.
Źródło:
Archives of Foundry Engineering; 2015, 15, 1; 21-24
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of Pyrolox sorbent for vanadium(V) ions removal
Autorzy:
Wójcik, Grzegorz
Hubicki, Zbigniew
Powiązania:
https://bibliotekanauki.pl/articles/2146947.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium(V)
kinetics
removal
sorption
Pyrolox
Opis:
The sorption of vanadium(V) ions from acidic solutions using the Pyrolox sorbent was studied at varying ions concentrations, pH, contact time and temperature. The investigated ions were determined by means of graphite-furnace atomic absorption spectrometry (GF-AAS). The sorption capacity of vanadium(V) ions was examined in the pH range 2-10. The adsorption capacities of vanadium(V) ions depend on the pH values. Therefore, the initial pH 2 of vanadium(V) results in the highest adsorption capacities. The sorption vanadium(V) kinetics was investigated. The experimental data were analyzed using the pseudo-first-order, pseudo-second-order forms, Elovich, and intra-particle diffusion models. The kinetics of vanadium(V) sorption is described by the pseudo-first-order in the best way. The results indicate the endothermic process of V(V) ions sorption. The presented results of vanadium ions recovery from the solutions obtained as a result of spent catalysts leaching indicate the possibility of vanadium recovery.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 2; art. no. 147974
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Adding Niobium and Vanadium to Fe-Based Oxide Dispersion Strengthened Alloy
Autorzy:
Park, Chun Woong
Choi, Won June
Byun, Jong Min
Kim, Young Do
Powiązania:
https://bibliotekanauki.pl/articles/353024.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Fe-based ODS
vanadium
niobium
superalloy
hardness
Opis:
In this study, the effects of adding niobium and vanadium to Fe-based oxide dispersion strengthened alloys are confirmed. The composition of alloys are Fe-20Cr-1Al-0.5Ti-0.5Y2 O3 and Fe-20Cr-1Al-0.5Ti-0.3V-0.2Nb-0.5Y2 O3. The alloy powders are manufactured by using a planetary mill, and these powders are molded by using a magnetic pulsed compaction. Thereafter, the powders are sintered in a tube furnace to obtain sintered specimens. The added elements exist in the form of a solid solution in the Fe matrix and suppress the grain growth. These results are confirmed via X-ray diffraction and scanning electron microscopy analyses of the phase and microstructure of alloys. In addition, it was confirmed that the addition of elements, improved the hardness property of Fe-based oxide dispersion strengthened alloys.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 4; 1265-1268
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pre-concentration of vanadium-bearing mica from stone coal by roasting-flotation
Autorzy:
Tang, J.
Zhang, Y.
Bao, S.
Liu, C.
Powiązania:
https://bibliotekanauki.pl/articles/109373.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
roasting
flotation
vanadium bearing mica
stone coal
Opis:
In China, stone coal is an important source of vanadium. The use of roasting–floatation for the pre-concentration of vanadium bearing mica from vanadium bearing stone coal was investigated based on its mineralogical characteristics. The results showed that the vanadium occurred in mica minerals and the main gangue minerals were coal, calcite, and quartz. The pre-concentration process comprises three key steps: roasting, desliming, and flotation. The coal was completely removed by roasting at 700 °C for an hour. Slime was concentrated and the subsequent flotation pulp was improved by desliming. Calcite was removed by reverse flotation and mica was concentrated by positive floatation. During the process, the grade of V2O5 was increased from 0.71% to 1.14%, and 46.18% of the tailings were rejected. The leaching rate of vanadium was increased from 30.49% of raw ore to 69.15% of the concentrate which was an increase of about 40% at the same leaching process. This technique may promote the efficient utilization of stone coal resources.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 402-412
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigmen
Autorzy:
Kwolek, P.
Czubajewski, K.
Wojnicki, M.
Powiązania:
https://bibliotekanauki.pl/articles/351844.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
recovery
inorganic pigments
solubility
vanadium
bismuth
immobilisation
Opis:
It has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free from nickel impurity. The precipitate is insoluble in the solutions with pH ≥ 3. In more acidic media the solubility of precipitate increases with the decreasing pH. The solubility of the precipitate increases also with the increasing concentration of chloride ions.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 901-909
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The spheroidisation of VC carbides in high-vanadium cast iron
Autorzy:
Kawalec, M.
Powiązania:
https://bibliotekanauki.pl/articles/380290.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
mechanical properties
high-vanadium cast iron
eutectic alloy
vanadium carbide
właściwości mechaniczne
żeliwo wysokowanadowe
stop eutektyczny
węglik wanadu
Opis:
High-vanadium cast iron is a type of white cast iron, in which a regular fibrous γ + VC eutectic with about 20 vol.% of vanadium carbides crystallises. The paper presents the results of research during which the high-vanadium cast iron was subjected to spheroidisation treatment with magnesium Elmag 5800 master alloy. The purpose of this operation was to obtain the VC carbides of a spheroidal shape. The study also included metallographic examinations and testing of mechanical properties carried out on high-vanadium cast iron of a eutectic composition in as-cast condition and after the spheroidising treatment. The attempt to spheroidise the vanadium carbides has proved to be quite successful. The introduction of magnesium alloy has made nearly one half of the crystallised vanadium carbides acquire a spheroidal shape. The, obtained in this way, high-vanadium cast iron with vanadium carbides of a spheroidal shape showed very high mechanical and plastic properties. The tensile strength Rm increased by 60% compared to the as-cast alloy, while ductility increased more than twenty times. The presented results are based on the initial trials, but further studies of this new material are planned, mainly to check its resistance to abrasion, to impacts and corrosion. Tests are also planned to increase the fraction of spheroidal carbides and measure the effect of their content on the mechanical and tribological properties.
Źródło:
Archives of Foundry Engineering; 2011, 11, 3 spec.; 111-116
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biochemical and medical importance of vanadium compounds
Autorzy:
Korbecki, Jan
Baranowska-Bosiacka, Irena
Gutowska, Izabela
Chlubek, Dariusz
Powiązania:
https://bibliotekanauki.pl/articles/1039732.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
inflammation
cancer
vanadium
diabetes
insulin-mimetic action
pollution
Opis:
Vanadium belongs to the group of transition metals and is present in the air and soil contaminants in large urban agglomerations due to combustion of fossil fuels. It forms numerous inorganic compounds (vanadyl sulfate, sodium metavanadate, sodium orthovanadate, vanadium pentoxide) as well as complexes with organic compounds (BMOV, BEOV, METVAN). Depending on the research model, vanadium compounds exhibit antitumor or carcinogenic properties. Vanadium compounds generate ROS as a result of Fenton's reaction or of the reaction with atmospheric oxygen. They inactivate the Cdc25B2 phosphatase and lead to degradation of Cdc25C, which induces G2/M phase arrest. In cells, vanadium compounds activate numerous signaling pathways and transcription factors, including PI3K-PKB/Akt-mTOR, NF-κB, MEK1/2-ERK, that cause cell survival or increased expression and release of VEGF. Vanadium compounds inhibit p53-dependent apoptosis and promote entry into the S phase of cells containing functional p53 protein. In addition, vanadium compounds, in particular organic derivatives, have insulin-mimetic and antidiabetic properties. Vanadium compounds lower blood glucose levels in animals and in clinical trials. They also inhibit the activity of protein tyrosine phosphatase 1B. By activating the PI3K-PKB/Akt pathway, vanadium compaunds increase the cellular uptake of glucose by the GLUT4 transporter. The PKB/Akt pathway is also used to inactivate glycogen synthase kinase-3. The impact of vanadium compounds on inflammatory reactions has not been fully studied. Vanadium pentoxide causes expression of COX-2 and the release of proinflammatory cytokines in a human lung fibroblast model. Other vanadium compounds activate NF-κB in macrophages by activating IKKβ.
Źródło:
Acta Biochimica Polonica; 2012, 59, 2; 195-200
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Feasibility study on preparation of magnesium titanate in carbonthermic reduction of vanadium titanomagnetite concentrates
Autorzy:
Chen, Chao
Sun, Ti-Chang
Kou, Jue
Wang, Xiao-Ping
Zhao, Yong-Qiang
Powiązania:
https://bibliotekanauki.pl/articles/110181.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium titanomagnetite
carbonthermic reduction
magnesium titanate
formation mechanism
Opis:
Effect of temperature and Mg:Ti ratio on phase composition and microstructure of reduced pellets was investigated to verify the feasibility of preparation of magnesium titanate by adding MgO in carbonthermic reduction of the vanadium titanomagnetite concentrates (VTC). Thermodynamic analysis results showed that magnesium titanate is more easily generated than FeTi2O5 or TiO2 by the reaction of FeTiO3 and MgO under the reductive atmosphere, which was confirmed by the discovery of magnesium titanate at roast experiment. It was found that the optimum conditions for reduction of VTC pellets were temperature of 1250 ºC and Mg:Ti ratio of 2, and the main phases of reduction product were metallic Fe and magnesium titanate (Mg2TiO4). However, trace iron impurities in Mg2TiO4 particles were found by energy-dispersive spectroscopy (EDS), so further purification is required.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 417-425
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction of vanadium compounds from the used vanadium catalyst with the potassium hydroxide solution
Autorzy:
Mazurek, K.
Białowicz, K.
Trypuć, M.
Powiązania:
https://bibliotekanauki.pl/articles/778384.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
katalizator wanadowy
ługowanie
wanad
żelazo
kwas siarkowy
wodorotlenek potasu
vanadium catalyst
leaching
recovery
vanadium
iron
sulfuric acid
potassium hydroxide
Opis:
The paper presents the results of the research on the degree of the recovery of vanadium(V) from the used vanadium catalyst with the use of KOH solution. The extraction was performed at 293 - 323 K, for 0.5 to 4 h and the catalysts of the variable grain diameter. The concentration of the extracting solution was varied in the range 5 - 20%. The optimal ratio of solid to liquid phase S/L was determined. Additionally the degree of the recovery of total iron ions was presented.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 1; 23-28
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of the conditions and worktime on the waste vanadic catalyst amount
Autorzy:
Grzesiak, P.
Motała, R.
Grobela, M.
Trypuć, M.
Mazurek, K.
Powiązania:
https://bibliotekanauki.pl/articles/777887.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
katalizator wanadowy
odpady produkcyjne
vanadium catalyst
waste products
Opis:
This paper includes the research results of the vanadic catalyst study that was operated in PCC Rokita S.A. during a gaseous SO3 formation. The physical properties have been studied: mechanical strength, bulk density and grindability during the five-year cycle of the catalyst worktime. The studies presented underline the prediction of the amount of the formed vanadic waste material.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 3; 73-76
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 79

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