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Wyszukujesz frazę "synthesis" wg kryterium: Temat


Tytuł:
An Automatic Synthesis of Musical Phrases from Multi-Pitch Samples
Autorzy:
Pluta, M.
Spalek, L. J.
Delekta, R. J.
Powiązania:
https://bibliotekanauki.pl/articles/177577.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sound synthesis
synthesis methods
sampling
Concatenative Sound Synthesis
Opis:
Sound synthesizers are a natural element of a musician’s toolset. In music arrangement, samplers can often produce satisfactory results, but it requires a combination of manual and automatic methods that may be arduous at times. Concatenative Sound Synthesis reproduces many of natural performance- and expression-related nuances but at a cost of high demand for processing power. Here, another method of musical phrase synthesis aimed at music arrangement is presented that addresses these and other related issues. Contrary to common practice, we propose to record and utilize sound samples containing not one, but short sequences of pitches. In effect, natural pitch transitions are preserved and phrases appear to be much smoother, despite using very limited set of performance rules. The proof-of-concept implementation of the proposed method is discussed in detail along with attempts at optimizing the final sound effects, based on auditory tests. The limitations and future applications of the synthesizer are also discussed.
Źródło:
Archives of Acoustics; 2017, 42, 2; 235-247
0137-5075
Pojawia się w:
Archives of Acoustics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A parametric synthesizer of audio signals on FPGA
Autorzy:
Borko, J.
Dulnik, G.
Grzelka, A.
Łuczak, A.
Paszkowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/114575.pdf
Data publikacji:
2015
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
FPGA
sound synthesis
Opis:
The paper presents a sound synthesizer dedicated to parametric sound compression, but also able to generate any signal in the audible band. The synthesizer is realized on an FPGA platform, and it uses additive sound synthesis. The synthesizer is characterized by a high quality, faithful reproduction of sound and low power consumption.
Źródło:
Measurement Automation Monitoring; 2015, 61, 7; 367-369
2450-2855
Pojawia się w:
Measurement Automation Monitoring
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Methylation demand: a key determinant of homocysteine metabolism.
Autorzy:
Brosnan, John
Jacobs, Rene
Stead, Lori
Brosnan, Margaret
Powiązania:
https://bibliotekanauki.pl/articles/1043276.pdf
Data publikacji:
2004
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
total plasma homocysteine
liver
creatine synthesis
phospholipid synthesis
S-adenosylmethionine
Opis:
Elevated plasma homocysteine is a risk factor for cardiovascular disease and Alzheimer's disease. To understand the factors that determine the plasma homocysteine level it is necessary to appreciate the processes that produce homocysteine and those that remove it. Homocysteine is produced as a result of methylation reactions. Of the many methyltransferases, two are, normally, of the greatest quantitative importance. These are guanidinoacetate methyltransferase (that produces creatine) and phosphatidylethanolamine N-methyltransferase (that produces phosphatidylcholine). In addition, methylation of DOPA in patients with Parkinson's disease leads to increased homocysteine production. Homocysteine is removed either by its irreversible conversion to cysteine (transsulfuration) or by remethylation to methionine. There are two separate remethylation reactions, catalyzed by betaine:homocysteine methyltransferase and methionine synthase, respectively. The reactions that remove homocysteine are very sensitive to B vitamin status as both the transsulfuration enzymes contain pyridoxal phosphate, while methionine synthase contains cobalamin and receives its methyl group from the folic acid one-carbon pool. There are also important genetic influences on homocysteine metabolism.
Źródło:
Acta Biochimica Polonica; 2004, 51, 2; 405-413
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Methods of controller synthesis using linear matrix inequalities and model predictive control
Autorzy:
Miller, A.
Rybczak, M.
Powiązania:
https://bibliotekanauki.pl/articles/135474.pdf
Data publikacji:
2015
Wydawca:
Akademia Morska w Szczecinie. Wydawnictwo AMSz
Tematy:
controller synthesis
LMI
MPC
predictive controller
controller synthesis methods
optimization methods
Opis:
Controllers based on linear matrix inequalities (LMI) and model predictive control (MPC) both use optimization methods; there are however significant differences between them. In case of LMI controllers, optimization is carried out during controller synthesis, because LMI’s are an optimization tool that requires a linear programming problem being solved. With MPC controllers, however, optimization methods are not used as much in controller synthesis as in controller algorithm operation, to determine optimal control signal values based on the found minimum of the criteria function. A square function is used with boundaries from above and below, which requires a square programming problem, with boundaries for decision variables, being solved. In this paper controller synthesis methods using LMI and MPC are shown, with a focus on the steps that need to be performed, and a comparison of both methods.
Źródło:
Zeszyty Naukowe Akademii Morskiej w Szczecinie; 2015, 43 (115); 22-28
1733-8670
2392-0378
Pojawia się w:
Zeszyty Naukowe Akademii Morskiej w Szczecinie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sonochemical synthesis of drug molecules nanoparticles: towards controlled drug release
Autorzy:
Chytrosz, P.
Golda-Cepa, M.
Kotarba, A.
Powiązania:
https://bibliotekanauki.pl/articles/286014.pdf
Data publikacji:
2018
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
nanoparticles
drugs
sonochemical synthesis
Źródło:
Engineering of Biomaterials; 2018, 21, 148; 69
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Implementation of Reconfigurable PLC on FPGA Platform
Autorzy:
Milik, A.
Hrynkiewicz, E.
Powiązania:
https://bibliotekanauki.pl/articles/226640.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
PLC
LD
IL
FPGA
high level synthesis
logic synthesis
arithmetic circuits
reconfigurable hardware
Opis:
The paper presents a set of algorithms dedicated for synthesis of reconfigurable logic controllers implemented on FPGA platform and programmed according to IEC1131 and EN61131. The program is compiled to hardware structure with a massive parallel processing. The developed method automatically allocates resources and operations. It controls resource usage and operation timing. Using mixed concept of operation allocation that considers operation timing and forms combinatorial chains of operations number of execution cycles can be reduced. An example of logic functions, PID controller and mixed arithmetic and logic programming examples are considered. Introducing the automatic implementation method allows flexible implementing the control algorithms. The maximal possible parallelism (limited only by the algorithm dependencies and available resources) is introduced.
Źródło:
International Journal of Electronics and Telecommunications; 2012, 58, 1; 85-94
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
KIERKEGAARD AND THE CONCEPT OF NEGATIVE DIALECTICS OF THEODOR ADORNO
Autorzy:
Krawerenda-Wajda, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/647184.pdf
Data publikacji:
2012
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
Tematy:
Kierkegaard
Adorno
dialectic
synthesis
mind
Opis:
The main subject of this paper is the influence of Kierkegaard's philosophy on the concept of Adorno's dialectics. This article is focused on the analysis of Adorno's work published in 1966 titled Negative Dialec-tics. Adomo 's concept of dialectics, which is based on undefined experience, is broadly similar to the "negative" concept of existential philosophy of Kierkegaard. Although Adomo uses the Hegelian dialectics to expose the ways in which Kierkegaard’s thoughts fali into idealism. Finally, Adomo adopts Kierkegaard’s criticism of Hegelian identity of thinking. Adomo, in Negative Dialectics refers to Kant, Hegel Heidegger, but seldom to Kierkegaard. A careful analysis shows that a number of themes and concepts of its predecessor have been assimilated to his philosophy.
Źródło:
Studia Humanistyczne AGH; 2012, 11, 3
2084-3364
Pojawia się w:
Studia Humanistyczne AGH
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dialektyka i synteza. O Pascalowskiej filozofii człowieka
Autorzy:
Błaszczyk, Marek
Powiązania:
https://bibliotekanauki.pl/articles/631051.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet im. Adama Mickiewicza w Poznaniu
Tematy:
individual existence
paradox
dialectics
synthesis
Opis:
The study focuses on the characteristically Pascalian attempt at synthesizing of contradictory and intensely remote extremes of existence. Assuming the form of existential dialectics, the paradox of Pascalian vision refers in particular to the human, demonstrating the non-reducible tension between the intuitive (irrational) and the rational (panlogical); between the heart and the mind, between faith and knowledge. The conviction of human misery or the worldly vanity is fused here with the simultaneous sense of human greatness (the power of thought). The tension which therefore spans those dichotomous ontological-ontic dimensions is the determining factor of the constitution of individual existence.
Źródło:
Studia Europaea Gnesnensia; 2015, 11; 83-96
2082-5951
Pojawia się w:
Studia Europaea Gnesnensia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New Synthetic Methods for 4,4’,5,5’-Tetranitro-2,2’-bi- 1H-imidazole (TNBI)
Autorzy:
Szala, M.
Lewczuk, R.
Powiązania:
https://bibliotekanauki.pl/articles/358154.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
tetranitrobiimidazole
nitration
synthesis
explosive properties
Opis:
Four new nitration methods for the synthesis of 4,4’,5,5’-tetranitro-2,2’- bi-1H-imidazole (TNBI) were examined. TNBI was synthesized by nitration of 2,2’-bi-imidazole (BI) with the following mixtures: (CH3CO)2O/HNO3, (CF3CO)2O/ HNO3, P4O10/HNO3 and H3PO4/P4O10/HNO3. Nitration of BI with a mixture of nitric acid and acetic anhydride leads to 4,4’-dinitro-bi-imidazole. The other nitrating conditions investigated gave TNBI in lower yields (6.0-22.4%). Crystallization of crude TNBI from wet ethanol/acetone gave TNBI as its dihydrate. The structures of BI and TNBI were characterized by 1H, 13C and 15N NMR spectroscopy and elemental analysis. Friction and impact sensitivity, detonability and detonation velocity were determined for pure TNBI dihydrate.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 261-270
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
In silico screening, synthesis, in vitro evaluations antibacterial and DPPH scavenging activity of some 1,3,5-trisubstituted 2-pyrazoline derivatives as dihydrofolate reductase inhibitors
Autorzy:
Suriya, S.
Mala, V.
Powiązania:
https://bibliotekanauki.pl/articles/1112558.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Synthesis
antibacterial
antioxidant
chalcone
pyrazoline
Opis:
In this work, synthesis of three pyrazoline derivatives (6-8) is described. (E)-1,3-(phenylsubstituted)-prop-2-en-1-one (3-5) is prepared by the reaction of substituted benzaldehyde with 4-methylacetophenone, whereas condensation cyclization of the same chalcones (3-5) with phenylhydrazine hydrate in ethanol yielded 6-8. The structures of the title compounds (6-8) were characterized by chemical reactions, elemental analysis, and spectral methods such as IR spectra. The synthesized chalcone and pyrazolines were evaluated for in-vitro antibacterial and antioxidant activities against standard. The zone of inhibition for some of the newly synthesized compounds showed notable antibacterial activity against selected bacterial strains when compared with ampicillin. Significant antioxidant activities were also shown by chalcone and pyrazolines.
Źródło:
World News of Natural Sciences; 2018, 18, 2; 180-186
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of Indexed Partition Calculus in Logic Synthesis of Boolean Functions for FPGAs
Autorzy:
Rawski, M.
Powiązania:
https://bibliotekanauki.pl/articles/226483.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
indexed partition
logic synthesis
FPGA
Opis:
Functional decomposition of Boolean functions specified by cubes proved to be very efficient. Most popular decomposition methods are based on blanket calculus. However computation complexity of blanket manipulations strongly depends on number of function's variables, which prevents them from being used for large functions of many input and output variables. In this paper a new concept of indexed partition is proposed and basic operations on indexed partitions are defined. Application of this concept to logic synthesis based on functional decomposition is also discussed. The experimental results show that algorithms based on new concept are able to deliver good quality solutions even for large functions and does it many times faster than the algorithms based on blanket calculus.
Źródło:
International Journal of Electronics and Telecommunications; 2011, 57, 2; 209-216
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chitosan derivatives - synthesis and characterization
Autorzy:
Szulc, Marta
Lewandowska, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1844946.pdf
Data publikacji:
2020
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
chitosan
synthesis
characterization
synteza
charakterystyka
Źródło:
Engineering of Biomaterials; 2020, 23, 158 spec. iss.; 11
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of PVA Polymer Type and Calcination Temperature on Synthesis of Nanocrystalline Yttria Powder by Polymer Solution Route
Autorzy:
Yang, Y.-K.
Lee, S.-J.
Powiązania:
https://bibliotekanauki.pl/articles/356024.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
yttria
PVA
nanocrystalline
synthesis
nanowire
Opis:
Nano-sized yttria (Y2O3) powders were synthesized by a polymer solution route using polyvinyl alcohol (PVA) as an organic carrier. The PVA polymer affected the dispersion of yttrium ions in precursor sol. In this study, three kinds of PVA polymer (different molecular weight) were applied for synthesis of yttria powder. The PVA type as well as calcination temperature had a strongly influence on the particle morphology. Single crystal nano wire particles were observed at the temperature of polymer burn out range and the size was dependent on the PVA type. The stable, fully crystallized yttria powder was obtained through the calcination at 800°C for 1 h. The yttria powder prepared with the high weight PVA (MW: 153,000) revealed a particle size of 30 nm with a surface area of 18.8 m2/g.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1473-1476
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Review of Nano-thermites: a Pathway to Enhanced Energetic Materials
Autorzy:
Zaky, Mohamed Gaber
Elbeih, Ahmed
Elshenawy, Tamer
Powiązania:
https://bibliotekanauki.pl/articles/27787860.pdf
Data publikacji:
2021
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
nanothermite
synthesis
applications
Opis:
Nano-thermites or metastable intermolecular composites (MICs) have been implemented into modern research on energetic materials as they offer much higher energy densities, higher rates of energy release, stability, and safety (lower sensitivity). This paper reviews several synthetic methods for MICs that have been well thought-out for energetic applications, advantages and disadvantages, as well as the characteristics of each manufacturing technique. The techniques presented include powder mixing, sol-gel, synthesis of MICs based on nano-porous silicon (Psi), sputtering, multilayer nano-foils and electrolytically plated carbon nano-materials for nano-thermite applications. These techniques offer enormously different characteristics and, through the variation of various chemical techniques and conditions, a wide range of chemical and energetic properties may be attained. This may give the opportunity for the safe use of MICs as replacements for some conventional energetic materials in various applications, and may also enable us to study the effects when incorporating these MICs into energetic matrixes, as a promising and feasible research field.
Źródło:
Central European Journal of Energetic Materials; 2021, 18, 1; 63--85
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biosynthesis of antibacterial silver nano-particles from Aspergillus terreus
Autorzy:
Singh, P. Shivakumar
Vidyasagar, G. M.
Powiązania:
https://bibliotekanauki.pl/articles/1112999.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Bio-synthesis
Silvernanoparticles
TEM
UV
Opis:
This paper deals with the bio-synthesis of silver nano-particles using a soil fungi. In this work, FTIR examinations indicated that the encountered soil particles actually contained Silver particles, while XRD analysis confirmed the silver was in the nano-crystalline phase. Moreover, the hurried decline of silver (Ag+) ions monitored using UV-visible spectrophotometer, demonstrated that these silver nano-particles formed within 19 minutes. In addition, transmission electron microscopy (TEM) revealed that the synthesized silver nano-particles come in a size ranging between 16-57 nm and have a variety of shapes, including round, rod and uneven. The present study thus concludes that silver nano-particles were actually produced and that these have admirable antibacterial activity. The current study also indicates that increasing concentration increases the rate of reduction and decreases the particle size.
Źródło:
World News of Natural Sciences; 2018, 16; 109-116
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chitosan-based nanocomposites modified with reduced graphene oxide prepared via green synthesis
Autorzy:
Kosowska, K.
Domalik-Pyzik, P.
Jagiełło, J.
Lipińska, L.
Chłopek, J.
Powiązania:
https://bibliotekanauki.pl/articles/284680.pdf
Data publikacji:
2017
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
nanocomposites
graphene oxide
green synthesis
Źródło:
Engineering of Biomaterials; 2017, 20, no. 143 spec. iss.; 59
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evolutionary Algorithm that Designs the DNA Synthesis Procedure
Autorzy:
Michalak, M.
Nowak, R.
Powiązania:
https://bibliotekanauki.pl/articles/308431.pdf
Data publikacji:
2011
Wydawca:
Instytut Łączności - Państwowy Instytut Badawczy
Tematy:
bioinformatics
gene synthesis
optimum searching
Opis:
Chemical synthesis of nucleotide chains is very erroneous for long sequences. Often a gene is constructed from short fragments joined with the use of complementary helper chains. The number of possible potential solutions for a long gene synthesis is very large, therefore a fast automated search is required. In the presented approach a modified method of long DNA construction is proposed. A computer program that searches for an optimal solution in the space of potential synthesis methods has been developed. This software uses an evolutionary algorithm for global optimization and a hillclimbing algorithm for local optimization. The long DNA construction method was tested on random sequences. The results are very promising. The next step is to perform experiments in a biotechnological wet laboratory involving DNA strand synthesis using the method designed by the presented software.
Źródło:
Journal of Telecommunications and Information Technology; 2011, 4; 50-54
1509-4553
1899-8852
Pojawia się w:
Journal of Telecommunications and Information Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Robot modelling, perception, and motion synthesis
Autorzy:
Tchoń, K.
Zieliński, C.
Powiązania:
https://bibliotekanauki.pl/articles/384804.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Przemysłowy Instytut Automatyki i Pomiarów
Tematy:
robot modelling
perception
motion synthesis
Źródło:
Journal of Automation Mobile Robotics and Intelligent Systems; 2017, 11, 2; 3-4
1897-8649
2080-2145
Pojawia się w:
Journal of Automation Mobile Robotics and Intelligent Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Homogenization and Micro/Nano Source of Starting Powders on Format Ion of the Single YAP Phase
Autorzy:
Michalik, D.
Pawlik, T.
Plewa, J.
Sopicka-Lizer, M.
Powiązania:
https://bibliotekanauki.pl/articles/351720.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
YAP
scintillators
synthesis
polycrystalline ceramics
Opis:
Manufacturing high purity polycrystalline YAlO3 (YAP) ceramics could replace monocrystalline YAP thus recently it is an interesting task for low cost producers of scintillators. The paper presents influence of different source of initial oxide powders (micro/nano powders of Y2O3 and Al2O3) and the method of their homogenization on the formation of a YAP phase. The solid state reaction method was used to prepare YAP powder or ceramic pellets. After preheating, all samples in the form of powders and pellets were heat-treated in the temperature range of 1050-1650 °C. DTA method was applied for examination of the phase crystallization in the tested system. X-ray diffraction method (XRD) was used for characterization of the phase composition. X-ray microanalysis (EDS) was used to control homogeneity in the small areas. Morphology of the resultant samples are presented on SEM pictures. The results show a significant influence of the starting powders on the homogeneity, purity and temperature of formation of the main phase.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 4; 1753-1760
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Przykłady otrzymywania nanocząstek z wykorzystaniem mikrofalowej solwotermalnej syntezy MSS
Examples of the Nanoparticles Produced by Microwave Solvothermal Synthesis (MSS) Route
Autorzy:
Wojnarowicz, J.
Chudoba, T.
Smoleń, D.
Łojkowski, W.
Majcher, A.
Mazurkiewicz, A.
Powiązania:
https://bibliotekanauki.pl/articles/167882.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Ceramiki i Materiałów Budowlanych
Tematy:
nanocząstki
synteza hydrotermalna
synteza solwotermalna
reaktor mikrofalowy
nanoparticles
hydrothermal synthesis
solvothermal synthesis
microwave reactor
Opis:
Proces mikrofalowej syntezy solwotermalnej (Microwave Solvothermal Synthesis, MSS) jest przykładem zastosowania wspomagającego reakcje chemiczne promieniowania mikrofalowego. Grzanie mikrofalowe umożliwia precyzyjne programowanie czasu syntezy. Dzięki temu możliwe jest uzyskiwanie cząstek charakteryzujących się wąskim rozkładem wielkości oraz wysokim stopniem krystaliczności (tzn. niskim udziałem faz amorficznych). Dodatkową zaletą procesu jest znacznie niższa temperatura w porównaniu z technologiami: plazmowymi, zol żel, syntezy z fazy gazowej. W artykule przedstawiono nowe reaktory do realizacji procesów MSS. Podano przykłady syntez hydroksyapatytu, tlenku cynku i tlenku cyrkonu. Wykazano możliwość sterowania właściwościami uzyskiwanych materiałów. Reaktory typu MSS-1 i MSS-2 stwarzają możliwość przemysłowej produkcji nanocząstek.
Microwave solvothermal synthesis (MSS) is an example of microwave assisted wet chemical synthesis process. Microwave heating enables a precise control of the reaction time, fast heating and reducing the thermal gradients. This results in a better crystallinity of the nanoparticles comparing to the precipitation process, and a narrow size distribution. An additional advantage is a reduced synthesis temperature, since no calcination is need. In the paper we presented two new reactors used for the MSS process. We have shown their applications in the synthesis of nanohydroksyapatite ZnO and ZrO2, as well as the enhanced control of their properties possible due to the use of microwaves. The MSS-1 and MSS-2 reactors enable industrial scale production of nanoparticles.
Źródło:
Szkło i Ceramika; 2014, R. 65, nr 6, 6; 8-11
0039-8144
Pojawia się w:
Szkło i Ceramika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ostatnie postępy w syntezie alkaloidów tropanowych i pochodnych tropanu
Recent advances in the synthesis of tropane alkaloids and other tropane derivatives
Autorzy:
Sidorowicz, K.
Kropiwnicki, K.
Łaźny, R.
Powiązania:
https://bibliotekanauki.pl/articles/171941.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
synteza
alkaloidy tropanowe
pochodne tropanów
synteza stereoselektywna
synthesis
tropane alkaloids
tropane derivatives
stereoselective synthesis
Opis:
Tropane alkaloids are a long-known class of compounds possessing an 8-azabicyclo[ 3.2.1]octane skeleton. Many tropane alkaloids posses biological activity (anticholinergic, anti-Parkinsonian, hypotensive), and as such had a significant influence on medicine and played a notable role in the development of organic chemistry [1]. The most known representatives of biologically active tropane alkaloids are: cocaine, atropine, scopolamine, ecgonine, and Bao Gong Teng A. A number of natural tropane alkaloids are chiral compounds, whose preparation in optically active forms is still a big challeng [2]. The biological activity of enantiomers often differs depending on their configurations. Alkaloids are a subject of an intensive research: scopus database contains nearly 200 thousand publications with the word „alkaloid”, and almost 4,500 publications with the phrase „tropane alkaloids” (about half of them have appeared in the last ten years). About 55 papers are devoted to stereoselective synthesis of tropane derivatives in 2000-2015. About half of this concernes stereoselective methods. The organic synthesis of alkaloids has a long history and numerous synthetic approaches to the tropane skeleton have been developed, from the classical synthesis of tropinone by Willstätter at the beginning of the XX century, to more recent developments dealing with asymmetric deprotonation of tropinone with chiral lithium amide bases for the enantioselective synthesis of a range of tropanes [3, 4]. Owing to extensiveness of the field, the current review presents the most interesting, from a synthetic point of view, approaches to tropane derivatives and tropane analogues. Most of the methods of synthesis are long (often several steps), time- and recourses-intensive, and often required elaborate and hardly available starting materials. But there are also notable exceptions, based on the asymmetric deprotonation approach; e.g., from the syntheses of cocaine described in this article, the most efficient one was reported by Lee in 2000 [5]. The concise synthesis (6 steps) gave the unnatural enantiomer of cocaine starting from commercially available tropinone in 78% overall yield. This approach allows to obtain both enantiomers and racemate, by changing type of one reactant only. However, most strategies provide only one enantiomer or racemic mixture of an alkaloid. As can be seen, despite of advances in chemicall science, there is no general way to synthesize majority of the representatives of this group of structurally related compounds.
Źródło:
Wiadomości Chemiczne; 2015, 69, 11-12; 1019-1045
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of multiple-valued logic networks for FPGA implementation using developmental genetic programming
Autorzy:
Deniziak, S.
Wiśniewski, M.
Wieczorek, K.
Powiązania:
https://bibliotekanauki.pl/articles/114577.pdf
Data publikacji:
2016
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
multiple-valued functions
FPGA
symbolic synthesis
Opis:
This paper presents a method of FPGA-oriented synthesis of multiple-valued logical networks. A multiple-valued network consists of modules connected by multivalued signals. During synthesis the modules are decomposed into smaller ones. For this purpose the symbolic decomposition is applied. Since the decomposition of modules strongly depends on the encoding of multiple-valued inputs and outputs, the result of synthesis depends on the order, in which the consecutive modules are implemented. Experimental results showed that our approach significantly reduces the cost of implementation.
Źródło:
Measurement Automation Monitoring; 2016, 62, 8; 278-281
2450-2855
Pojawia się w:
Measurement Automation Monitoring
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
1-fenylo-2,6-bis(etoksykarbonylometylo)imidazo[1,5-c]-chinazolino-3,5-dion : półprodukt w syntezie poliuretanów
1-phenyl-2,6-bis(ethoxycarbonylmethyl)imidazo[1,5-c]-quinazoline-3,5-dione : an intermediate product in synthesis of polyurethanes
Autorzy:
Hęclik, K.
Szyszkowska, A.
Zarzyka, I.
Powiązania:
https://bibliotekanauki.pl/articles/278346.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Inżynierii Materiałów Polimerowych i Barwników
Tematy:
poliuretany
synteza
imidazochinazolin
polyurethanes
synthesis
imidazoqinazolin
Opis:
W niniejszej pracy podjęto badania w celu wyjaśnienia struktury krystalograficznej 2,6-bis(etoksykarbonylometylo)-1-fenyloimidazo[1,5-c]chinazolino-3,5-dionu (BEFIC). Związek ten jest półproduktem w syntezie poliuretanów liniowych z pierścieniem imidazochinazolinowym. Monokryształ BEFIC tworzy tylko jedna para enancjomerów z pośród 32 możliwych konformerów. Obliczenia kwantowo-mechaniczne cząsteczki BEFIC przeprowadzone w oparciu o Teorię Funkcjonału Gęstości (DFT) z użyciem programu Gaussian wykazały możliwość wzajemnej przemiany konformerów tego związku. Transformacja konformerów BEFIC prowadzi ostatecznie do występowania tylko jednej, najbardziej stabilnej pary enancjomerów, pozwalającej na najlepsze upakowanie cząsteczek w komórce elementarnej.
In the present work, we have undertaken research in order to clarify the crystal structure of 2,6-bis(ethoxycarbonylmethyl)-1-phenylimidazo[1,5-c]quinazoline-3,5-dione. This compound is an intermediate in the synthesis of the linear polyurethanes with imidazoquinazoline ring. Single crystal of 2,6-bis(ethoxycarbonylmethyl)-1-phenylimidazo[1,5-c]quinazoline-3,5-dione is formed by only one pair of enantiomers from among 32 possible conformers. Quantummechanical calculations 2,6-bis(ethoxycarbonylmethyl)-1-phenylimidazo[1,5-c]quinazoline-3,5-dione carried out based on the density functional theory (DFT) using the program Gaussian demonstrated the possibility of the mutual transformations of the conformers. Transformation of 2,6-bis(ethoxycarbonylmethyl)-1-phenylimidazo[1,5-c]quinazoline-3,5-dione conformers ultimately leads to the presence of only one pair of enantiomers. This pair is the most stable and allows the best packing of molecules in the unit cell.
Źródło:
Przetwórstwo Tworzyw; 2017, T. 23, Nr 1 (175), 1 (175); 24-32
1429-0472
Pojawia się w:
Przetwórstwo Tworzyw
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Characterization and Compatibility Studies of Poly(DFAMO/NIMMO) with Propellant and PBX Ingredients
Autorzy:
Li, H.
Yang, Y.
Pan, J.
Wang, W.
Pan, R.
Zhu, W.
Powiązania:
https://bibliotekanauki.pl/articles/358094.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic binder
synthesis
characterization
compatibility
PDN
Opis:
Oxetane-based polymers substituted with difluoroamino groups can be used as energetic binders in propellants and polymer-bonded explosives (PBXs). As a novel candidate, poly(3-difluoroaminomethyl-3-methyloxetane/3-nitratomethyl-3-methyloxetane) (PDN) was synthesized and its structure was established. Thermogravimetry (TG) and differential scanning calorimetry (DSC) were employed to investigate its thermal decomposition behaviour. The compatibility between PDN and some common ingredients of propellants and PBXs was evaluated by the DSC method. PDN with good thermal stability was synthesized via a cationic solution polymerization process. Additionally, it has improved compatibility with cyclotetramethylenetetranitramine (HMX), carbon black (C.B.) and lead carbonate (PbCO3) compared with homopoly(3-difluoroaminomethyl-3-methyloxetane) (PDFAMO). PDN could be used as a promising difluoroamino energetic binder in the future.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 85-99
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modelling of the Synthesis of 1,1-Diamino-2,2-dinitroethene (DADNE)
Autorzy:
Trzciński, W. A.
Chyłek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/358345.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
DADNE
modelling of the synthesis
kinetics
Opis:
In this work the conditions and kinetics of nitration of 2-methylpyrimidine- 4,6-dione (MPD), which leads to the formation of 1,1-diamino-2,2-dinitroethene (DADNE), are presented. An analysis of literature data enabled us to propose a model and a mathematical formulation of the synthesis of DADNE. The model was verified on the basis of literature data and our own experimental data. The influence of the addition time of nitric acid into a model reactor on temperature and composition of the reaction mixture was investigated. The proposed synthesis model could be useful in a study of the MPD nitration process on a large, laboratory scale.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 2; 101-117
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, COX-1/2 inhibition and antioxidant activities of new oxicam analogues designed as potential chemopreventive agents
Autorzy:
Szczęśniak-Sięga, Berenika
Gębczak, Katarzyna
Gębarowski, Tomasz
Maniewska, Jadwiga
Powiązania:
https://bibliotekanauki.pl/articles/1038390.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
synthesis
chemoprevention
antioxidant
COX
NSAIDs
oxicams
Opis:
Oxicams (e.g. piroxicam, meloxicam) are widely used nonsteroidal anti-inflammatory drugs (NSAIDs). A large body of evidence from epidemiological and preclinical studies has shown that NSAIDs have a chemopreventive effect on different types of cancer, especially in colorectal cancer. Moreover, mounting evidence from preclinical and clinical studies suggests that persistent inflammation functions as a driving force in the journey to cancer. What is more, inflammation induces reactive oxygen and nitrogen species, which cause damage to important cellular components (e.g., DNA, proteins and lipids), which can directly or indirectly contribute to malignant cell transformation. In this study, we discuss the synthesis and the resultant newly synthesized oxicam derivatives which are potentially chemopreventive, and at the same time antioxidant. Compound 9c, with the highest therapeutic index in the LoVo cancer cell line, was found to be the most efficient in ROS scavenging activity under conditions of oxidative stress.
Źródło:
Acta Biochimica Polonica; 2018, 65, 2; 199-207
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
On Transformation of a Logical Circuit to a Circuit with NAND and NOR Gates Only
Autorzy:
Baranov, S.
Karatkevich, A.
Powiązania:
https://bibliotekanauki.pl/articles/963932.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
logic synthesis
logic devices
VLSI
minimization
Opis:
In the paper we consider fast transformation of a multilevel and multioutput circuit with AND, OR and NOT gates into a functionally equivalent circuit with NAND and NOR gates. The task can be solved by replacing AND and OR gates by NAND or NOR gates, which requires in some cases introducing the additional inverters or splitting the gates. In the paper the quick approximation algorithms of the circuit transformation are proposed, minimizing number of the inverters. The presented algorithms allow transformation of any multilevel circuit into a circuit being a combination of NOR gates, NAND gates or both types of universal gates.
Źródło:
International Journal of Electronics and Telecommunications; 2018, 64, 3; 373-378
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of Macro Petri Nets into FPGA with Distributed Memories
Autorzy:
Bukowiec, A.
Adamski, M.
Powiązania:
https://bibliotekanauki.pl/articles/226342.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
decomposition
FGPAs
logic synthesis
Petri nets
Opis:
In this paper a new method of Petri net array-based synthesis is proposed. The method is based on decomposition of colored interpreted macro Petri net into state machine subnets. Each state machine subnet is determined by one color. During the decomposition process macroplaces are expanded or replaced by doublers of macroplace. Such decomposition leads to parallel implementation of a digital system. The structured encoding of places is done by using minimal numbers of bits. Colored microoperations, which are assigned to places, are written into distributed and flexible memories. It leads to realization of a logic circuit in a two-level concurrent structure, where the combinational circuit of the first level is responsible for firing transitions, and the second level memories are used for generation of microoperations. Such an approach allows balanced usage of different kinds of resources available in modern FPGAs.
Źródło:
International Journal of Electronics and Telecommunications; 2012, 58, 4; 403-410
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chitosan derivatives - synthesis and characterization
Autorzy:
Szulc, Marta
Lewandowska, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1844877.pdf
Data publikacji:
2020
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
chitosan
synthesis
characterization
chitozan
synteza
charakterystyka
Źródło:
Engineering of Biomaterials; 2020, 23, 158 spec. iss.; 11
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of saccharides on pullulan synthesis by Aureobasidium pullulans A.p.-3
Autorzy:
Gniewosz, M.
Sobczak, E.
Powiązania:
https://bibliotekanauki.pl/articles/1371461.pdf
Data publikacji:
1992
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
pullulan
Aureobasidium pullulans
saccharide
synthesis
biosynthesis
Źródło:
Polish Journal of Food and Nutrition Sciences; 1992, 01, 4; 37-43
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The activity of fused-iron catalyst doped with lithium oxide for ammonia synthesis
Autorzy:
Jedrzejewski, R.
Lendzion-Bieluń, Z.
Arabczyk, W.
Powiązania:
https://bibliotekanauki.pl/articles/779518.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
iron catalyst
ammonia synthesis
lithium oxide
Opis:
The iron catalyst precursor promoted with Al2O3, CaO, and Li2O was obtained applying the fusing method. Lithium oxide forms two phases in this iron catalyst: a chemical compound with iron oxide (Li2Fe3O4) and a solid solution with magnetite. The catalyst promoted with lithium oxide was not fully reduced at 773 K, while the catalyst containing potassium was easily reducible at the same conditions. After reduction at 873 K the activity of the catalyst promoted with lithium oxide was 41% higher per surface than the activity of the catalyst promoted with potassium oxide. The concentration of free active sites on the surface of the catalyst containing lithium oxide after full reduction was greater than the concentration of free active sites on the surface of the catalyst promoted with potassium oxide.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 2; 78-83
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Technology mapping oriented to adaptive logic modules
Autorzy:
Kubica, M.
Kania, D.
Powiązania:
https://bibliotekanauki.pl/articles/200466.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
decomposition
logic synthesis
technology mapping
ALM
Opis:
This paper presents an innovative method of technology mapping of the circuits in ALM appearing in FPGA devices by Intel. The essence of the idea is based on using triangle tables that are connected with different configurations of blocks. The innovation of the proposed method focuses on the possibility of choosing an appropriate configuration of an ALM block, which is connected with choosing an appropriate decomposition path. The effectiveness of the proposed technique of technology mapping is proved by experiments conducted on combinational and sequential circuits.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2019, 67, 5; 947-956
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pisanie „pomiędzy”. O prozie Anny Kańtoch
Writing “In-Between”. On Anna Kańtoch’s Prose
Autorzy:
Czaja, Kamila
Powiązania:
https://bibliotekanauki.pl/articles/534821.pdf
Data publikacji:
2019
Wydawca:
Wydawnictwo Uniwersytetu Śląskiego
Tematy:
Anna Kańtoch
fantasy writing
genre
synthesis
Opis:
The article endeavours to present the most significant features of Anna Kańtoch’s prose works. Not only is the author in question capable of utilizing various conventions of popular literature, such as: fantasy, science-fiction, and detective stories, but also to mingle them and come up with “hybrid-genres” that are difficult to pigeonhole (Czarne, Niepełnia). Spatial and temporal changeability characterize the novels and short stories of the Katowice-based writer, making the world depicted therein a place existing “in-between,” and moreover, involving both – brutality of rules that world is governed by as well as palpable desire of a proper moral order, which does not always eventually gains the upper hand.
Źródło:
Śląskie Studia Polonistyczne; 2019, 13, 1; 139-154
2084-0772
2353-0928
Pojawia się w:
Śląskie Studia Polonistyczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Green chemistry for the preparation of silver nanoparticles using mint leaf leaves extracts and evaluation of their antimicrobial potential
Autorzy:
Aziz, Wisam J.
Jassim, Haneen A.
Powiązania:
https://bibliotekanauki.pl/articles/1112556.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Green synthesis
Mentha (Mint)
Silver Nanoparticles
Opis:
The aim of this study was to develop a green synthesis of silver nanoparticles using mint plant leaves extracts. The fresh suspension of plant extracts was yellowish-green in color. However, after the addition of AgNO3 within 15min, the suspension showed a change in color to dark brown after 5 hours of incubation at room temperature. The formation of silver nanoparticles was confirmed using UV-Vis spectral analysis and revealed silver surface plasmon resonance band to be in a range around 200-500 nm. The XRD pattern showed the characteristic bragg peaks of (111), (200) and (220) planes of the face center cubic (FCC) silver nanoparticles AgNPS. Under scanning electron microscope (SEM), silver nanoparticles with a mean particle size of 26 nm and a spherical shape were most frequently observed. In testing, the synthesized AgNPs colloidal solution showed better antibacterial activity against both Gram-positive and Gram-negative bacterial strains. The diameter of the inhibition zones of AgNPs at 50 µg/ml concentration against bacterial strains such as Bacillus subtilis and Escherichia coli were 25 mm and 20 mm, respectively.
Źródło:
World News of Natural Sciences; 2018, 18, 2; 163-170
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Design, Synthesis, Characterization and Biological evaluation of (4-(7-chloroquinolin-4-yl)piperazin-1-yl)(substitutedphenyl)methanones as antimicrobial agents
Autorzy:
Parmar, Nilesh D.
Hadiyal, Sanjay D.
Kapupara, Vimal H.
Kalavadiya, Prakash L.
Gojiya, Dinesh G.
Bhatt, Tejal
Vekariya, Mitesh B.
Chovatiya, Pankaj J.
Joshi, Hitendra S.
Powiązania:
https://bibliotekanauki.pl/articles/1075589.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Chloroquinoline
antimicrobial agents
multistep synthesis
piperazine
Opis:
A series of (4-(7-chloroquinolin-4-yl)piperazin-1-yl)(substitutedphenyl)methanones were prepared via multistep synthesis which involved acrylation without base, cyclisation, hydrolysis, decarboxylation, electrophilic chlorination reactions and subsequent chloro-amine coupling with various substituted benzoyl chloride derivatives. The structure of the synthesized compounds was established by using elemental analysis, FT-IR, 1H NMR, 13C NMR and Mass spectroscopy. All the novel compounds have been tested on thin layer chromatographic plate for purity and evaluated for their antimicrobial activity against gram positive and gram negative bacteria which demonstrated moderate to good antimicrobial activity.
Źródło:
World Scientific News; 2019, 122; 193-205
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microbiological processes in folacin synthesis in kefir
Mikrobiologiczne procesy syntezy folacyny w kefirze
Autorzy:
Drewek, Z.
Czarnocka-Roczniakowa, B.
Powiązania:
https://bibliotekanauki.pl/articles/1398631.pdf
Data publikacji:
1986
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
folacin synthesis
kefir microflora
yeast influence
Opis:
It was found that folacin is produced by microflora of kefir grains. The folacin content in kefir increases threefold as a result of fermentation and cold storage. Experiments with modified kefir grains in which the ratio of bacteria number to yeast was changed, indicates the dominant role of yeast in folacin synthesis. However, the kefir grains with increased yeast number bad an adverse effect on the organoleptic qualities of kefir.
Badania zmierzały do ustalenia zmian zawartości folacyny w toku produkcji i przechowywania kefiru, ze szczególnym uwzględnieniem roli mikroflory grzybków kefirowych w kształtowaniu poziomu tej witaminy. W wyniku biosyntezy, zachodzącej przy udziale mikroflory ziarn kefirowych, wyrównywane zostają podczas fermentacji straty folacyny spowodowane pasteryzacją mleka (średnio 20%), a następnie kefir zostaje wzbogacony w tę witaminę o 115% w stosunku do mleka pasteryzowanego. W badaniach wpływu poszczególnych ugrupowań mikroflory ziarn kefirowych na biosyntezę folacyny, stwierdzono, że same ziarna są bogatym źródłem tej witaminy (70-77 μg/100 g) oraz ustalono, że biosynteza ta w kefirze zachodzi głównie przy udziale drożdży. Jednakże produkcja kefiru przy użyciu ziarn kefirowych o zwiększonej liczbie komórek drożdży prowadzi do niekorzystnych zmian cech organoleptycznych napoju. Praktyczne znaczenie mają natomiast obserwacje zmian zawartości folacyny w kefirze produkowanym sposobem tradycyjnym. W badaniach tych na uwagę zasługuje znaczne zwiększenie poziomu folacyny podczas przetrzymywania napojów Przez 24-48 h w temperaturze chłodniczej ( +4°C), tym bardziej, że warunki te wpływają także korzystnie na wartość dietetyczną i cechy smakowe kefiru. Mikroflora ziarn kefirowych syntetyzuje związki grupy kwasu foliowego, których zawartość Wzrasta trzykrotnie podczas fermentacji, dojrzewania i chłodniczego przechowywania napojów.
Źródło:
Acta Alimentaria Polonica; 1986, 12, 1; 39-45
0137-1495
Pojawia się w:
Acta Alimentaria Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation and characterization of ultra-fine silver bromide suspension
Autorzy:
Król-Gracz, A.
Michalak, E.
Nowak, P.
Dyonizy, A.
Powiązania:
https://bibliotekanauki.pl/articles/115949.pdf
Data publikacji:
2011
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
nanoparticles
silver bromide
synthesis method
gelatine
Opis:
This paper present the results of studies on ultra fine-crystalline silver bromide suspensions, which were stabilized by gelatin and excess of bromide ions. Relation between dosing rate of reactants to size of obtained silver bromide crystals was investigated. Granulometric properties obtained nanocrystals were studied by turbidity method and by technique of Dynamic Light Scattering (DLS). Additionally, a photomicrograph of suspension using Scanning Electron Microscopy (SEM) was performed.
Źródło:
Challenges of Modern Technology; 2011, 2, 2; 38-42
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Opracowanie warunków syntezy poliuretanów z pierścieniami imidazochinazolinowymi
Study on the synthesisconditions of polyurethanes with imidazoquinazoline rings
Autorzy:
Szyszkowska, A.
Hęclik, K.
Kisała, J.
Iłowska, J.
Mościpan, M.
Bereska, B.
Zarzyka, I.
Powiązania:
https://bibliotekanauki.pl/articles/279164.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Inżynierii Materiałów Polimerowych i Barwników
Tematy:
poliuretany
synteza
imidazochinazolin
polyurethanes
synthesis
imidazoqinazolin
Opis:
W celu otrzymania poliuretanów linowych z pierścieniami imidazochinazolinowymi przeprowadzono reakcję 1,6-diizocyjanianu heksametylenu z 1-fenylo-2,6-bis(2-hydroksyetylo)imidazo[1,5-c]chinazolino-3,5-dionem (BEFIC). Początkowo reakcję prowadzono w środowisku acetonu w obecności dilaurynianudibutylocyny(IV) jako katalizatora, w temperaturze wrzenia mieszaniny reakcyjnej (54°C). Reakcja przebiegała na granicy faz, co spowodowało niewielkie przereagowanie substratów. Wprowadzenie do układu dodatkowego rozpuszczalnika – sulfotlenku dimetylu i zwiększenie ilości katalizatora również nie zapewniło całkowitego przereagowania diolu. Dopiero zmiana rozpuszczalnika na N,N’-dimetyloformamid pozwoliła prowadzić reakcję w wyższej temperaturze (90°C), co doprowadziło do uzyskania poliuretanu liniowego z dobrą wydajnością (90%). Otrzymany poliuretan scharakteryzowano metodami instrumentalnymi (spektroskopia IR, ¹H-NMR, analiza elementarna i chromatografia żelowa).
In order to obtain linear polyurethanes with imidazoquinazoline rings, the reaction of hexame-thylene 1,6-diisocyanate with 1-phenyl-2,6-bis(2-hydroxyethyl)imidazo[1,5-c]quinazoline-3,5-dione was carried out. Initially, the reaction was carried out in acetone in the presence of dibutyltin(IV)dilaurate as a catalyst, at the boiling point of the reaction mixture. Unfortunately, the conversion degree of substrates was not very high. Therefore, the amount of catalyst was increased. Nevertheless, a significant improvement in the conversion degree of substrates was still not achieved. Only changing the solvent into N,N-dimethylformamide allowed to conduct the reaction at a higher temperature (90°C). It resulted in the obtaining of the linear polyurethane with good yield (90%). The polyurethane was characterized by instrumental methods (IR and ¹H-NMR spectroscopy, elemental analysis and gel permeation chromatography).
Źródło:
Przetwórstwo Tworzyw; 2017, T. 23, Nr 1 (175), 1 (175); 64-72
1429-0472
Pojawia się w:
Przetwórstwo Tworzyw
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
m-Synthesis control of flexible modes of AMB rotor
Autorzy:
Mystkowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/386538.pdf
Data publikacji:
2010
Wydawca:
Politechnika Białostocka. Oficyna Wydawnicza Politechniki Białostockiej
Tematy:
wirnik
synthesis
elastyczność
rotor
synteza
flexibility
Opis:
In the paper the optimal robust vibration control of flexible rotor supported by the active magnetic bearings (AMBs) is investigated. The purpose of the control system is stabilization of the high speed rotor and effective control of the rotor vibration due to noncollocation, gyroscopic effects and model uncertainties. The noncollocation effect is considered and frequency modal analysis of the noncollocated AMBs system with gyroscopic effects is presented. The ž-Synthesis control is applied to stabilize the rigid and flexible critical frequency modes of the rotor, with emphasis structural and parametric uncer-tainty. The input and output signals in AMBs system are limited by the weighting functions. The singular value analysis is used to obtain therobust performances of the closed-loop system. The stable operation and good stiffness of the high speed rotor supported magnetically is reached. The dynamical behaviour of the AMBs rotor is evaluated in the range up to 21 000 rpm. The experimental tests show the effectiveness of the robust control system as well as good vibrations reduction and robustness of the designed controllers.
Źródło:
Acta Mechanica et Automatica; 2010, 4, 4; 83-90
1898-4088
2300-5319
Pojawia się w:
Acta Mechanica et Automatica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Robot Grasp Synthesis Under Object Pose Uncertainty
Autorzy:
Szynkiewicz, W.
Powiązania:
https://bibliotekanauki.pl/articles/950999.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Przemysłowy Instytut Automatyki i Pomiarów
Tematy:
grasp synthesis
pose uncertainty
grasp quality
Opis:
This paper addresses the problem of grasp synthesis for grasping objects considering both object pose uncertainty and object dynamics. These two factors greatly affect success or failure in a real-world robotic grasping and should be considered simultaneously. The proposed approach is based on simulation of grasping process assuming that the 3D model of the object is known. Object geometry is modelled using superquadrics. To evaluate grasp quality three different measures are utilised. The proposed grasp synthesis approach will be implemented and tested on a real robot with multi-fingered hand.
Źródło:
Journal of Automation Mobile Robotics and Intelligent Systems; 2015, 9, 1; 53-61
1897-8649
2080-2145
Pojawia się w:
Journal of Automation Mobile Robotics and Intelligent Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Easy, Simplistic and Green Synthesis of Various Benzimidazole and Benzoxazole Derivatives Using PEG400 as a Green Solvent
Autorzy:
Khunt, M. D.
Kotadiya, V. C.
Viradiya, D. J.
Baria, B. H.
Bhoya, U. C.
Powiązania:
https://bibliotekanauki.pl/articles/411999.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
PEG-400
Benzimidazole
Benzoxazole
Green synthesis
Opis:
An improved environmentally benign procedure for the synthesis of various benzimidazole and benzoxazole derivatives using green solvent PEG400. We have optimized the reaction condition and it was found that PEG400 was believed to be best as compared to PEG200, PEG600 and PEG800 at 80 to 85 °C. This method provides a novel route for the synthesis of benzimidazole and benzoxazole derivatives. The main attractive features of this process are a mild reaction conditions, easy workup procedure and good to excellent yield. The structures of all the synthesized compounds were confirmed by 1H NMR, IR, MASS and Elemental Analysis.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 6; 61-68
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characterization of substituted bisbenzoxazine as potent antimicrobial agent
Autorzy:
Lalcheta, K.R.
Dhaduk, D.D.
Mendapara, J.P.
Powiązania:
https://bibliotekanauki.pl/articles/412174.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Benzoxazines
synthesis
microbial activity
Spectral techniques
Opis:
Bisbenoxazines derivatives were synthesized by refluxing substituted bisphenol-C, substituted aniline and formaldehyde in presence of 1,4-dioxane with good yields. All the synthesized compounds were characterized by mass, NMR and IR and also evaluated for antimicrobial activity against four different bacterial and two fungal strains. The compounds 1c, 1h, 1j and 1l has found comparatively good active against all the bacterial strains.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2015, 40; 73-80
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
UVB Radiation Impact on Activity of DNA and Cellular Protein Synthesis of Water Environment Bacteria
Wpływ UVB na aktywność syntezy DNA i białek komórkowych przez bakterie środowiska wodnego
Autorzy:
Walczak, M.
Burkowska, A.
Powiązania:
https://bibliotekanauki.pl/articles/389411.pdf
Data publikacji:
2011
Wydawca:
Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:
UV
synteza DNA
synteza białek
substancje humusowe
mikrowarstwa powierzchniowa
DNA synthesis
protein synthesis
humic substances
surface microlayer
Opis:
The studies were carried out in 2007 based on water samples collected from SM and SW of pelagic zone of Brzezno lake. For the purpose of further research, representative collection of bacterial strains was isolated from collected samples. The progress of the research included estimation of the DNA and cellular protein synthesis activity of the bacteria subjected to UVB radiation. The survey was conducted in two experimental layouts: with and without humic substances (HS) playing role of compounds potentially protective from UV radiation. Conducted research demonstrated that under influence of UVB radiation the SM and SW bacteria activity of DNA and cellular protein synthesis were strongly inhibited. On the other hand, presence of HS have another impact on DNA and cellular protein synthesis.
Badania prowadzono w 2007 r., pobierając próbki wody z MP i WPP w strefie pelagialu jeziora Brzeźno. Z pobranych próbkach wody izolowano reprezentatywną kolekcję szczepów, na których wykonywano dalsze badania. W toku badań oznaczano aktywność syntezy DNA i białek komórkowych bakterii poddanych promieniowaniu UVB. Badania prowadzono w dwóch układach doświadczalnych: bez substancji humusowych (SH) i w obecności tych substancji jako związków o działaniu potencjalnie ochronnych przed UV. Przeprowadzone badania wykazały, że pod wpływem promieniowania UVB aktywność syntezy DNA i białek komórkowych ulegały silnej inhibicji. Natomiast obecność SH inaczej wpływa na syntezę DNA i białek.
Źródło:
Ecological Chemistry and Engineering. A; 2011, 18, 3; 469-475
1898-6188
2084-4530
Pojawia się w:
Ecological Chemistry and Engineering. A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on template-synthesized polypyrrole nanostructures
Autorzy:
Starosta, W.
Buczkowski, M.
Sartowska, B.
Wawszczak, D.
Powiązania:
https://bibliotekanauki.pl/articles/146221.pdf
Data publikacji:
2006
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
template synthesis
track-etched membranes
polypyrrole nanotubules
Opis:
The paper presents a short review of recent achievements in the rapidly growing field of the template synthesis of nanostructures together with their possible application. The results of our own work, concerning the polypyrrole nanotubules synthesis inside pores of track-etched membranes, have been presented as well. Finally, the kinetics of nanotubule growth process using the SEM method and permeability for air of the resulting structures has been also determined.
Źródło:
Nukleonika; 2006, 51,suppl.1; 35-39
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Information aspects of optimization synthesis of functional-modular structure of technological equipment
Autorzy:
Palchevskyi, B.
Powiązania:
https://bibliotekanauki.pl/articles/118005.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Promocji Wiedzy
Tematy:
information technology
technological equipment
design
synthesis
structure
Opis:
The paper presents the information approach to the design of equipment with functional-modular structure. The advantages and drawbacks of various technologies of synthesis are shown.
Źródło:
Applied Computer Science; 2013, 9, 1; 17-33
1895-3735
Pojawia się w:
Applied Computer Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reduced number of design parameters in optimum path synthesis with timing of four-bar linkage
Autorzy:
Buśkiewicz, J.
Powiązania:
https://bibliotekanauki.pl/articles/279257.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
path synthesis
evolutionary algorithm
four-bar linkage
Opis:
The paper presents the method for the optimal synthesis of four-link mechanism generating open/closed paths with time prescription. Although the method is suitable for both closed and open paths, it enables decreasing the number of design parameters describing dimensions, orientation and position of a path generator. Compared to the methods presented in the references, this is a one-phase synthesis method; although the number of design parameters is reduced, the method does not require affine transformations to be performed on the synthesised mechanism. The effectiveness of the method is discussed based on examples of three paths, with two taken from the literature.
Źródło:
Journal of Theoretical and Applied Mechanics; 2018, 56, 1; 43-55
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on a New Synthesis of LLM-105 Using N-Nitroso-bis(cyanomethyl)amine
Autorzy:
Jing, S.
Liu, Y.
Liu, D.
Guo, J.
Powiązania:
https://bibliotekanauki.pl/articles/358371.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
LLM-105
energetic materials
synthesis
characterization
properties
Opis:
A new three-step synthetic method was designed to prepare 2,6-diamino- 3,5-dinitropyrazine 1-oxide (LLM-105) with an overall yield of 43.5%, using iminodiacetonitrile, triethylamine and hydroxylamine hydrochloride as the starting materials, and involved nitrosylation, cyclization and nitration. The structure of LLM-105 was characterized by FTIR, 1H NMR spectroscopy and elemental analysis. The crucial factors and mechanism of the cyclization were explored. Thermal decomposition, mechanical sensitivity and the purity of the LLM-105 were determined by TG-DTA, an impact sensitivity instrument and high performance liquid chromatography (HPLC) respectively. The results showed that LLM-105 synthesised via 2,6-diamino-3,5-dinitropyrazine (ANPZ) was less sensitive to impact, but the LLM-105 synthesized by the new method had some obvious advantages in terms of purity, security and production costs. Moreover, the LLM-105 synthesized by this new method can be initiated reliably without recrystallization.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 1; 21-32
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Combustion Synthesis of Titanium Carbonitrides
Autorzy:
Dyjak, S.
Wasilewska, M.
Cudziło, S.
Powiązania:
https://bibliotekanauki.pl/articles/358421.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
combustion synthesis
titanium carbonitride
ceramics
refractory materials
Opis:
Titanium carbonitride (TiC0.5N0.5) micron powders were synthesized in reactions of titanium with zinc dicyanide: Zn(CN)2 + 4Ti → 4TiC0.5N0.5 + Zn. The reactions are sufficiently exothermic to propagate in the reactant mixture to form a self-sustaining, high-temperature synthesis (SHS). The final product was separated and the only byproduct (zinc) was removed by dissolution in dilute hydrochloric acid. The use of zinc dicyanide as the source of carbon and nitrogen causes the titanium carbonitride to contain only these elements in an atomic ratio of one. The reaction temperature can be easily reduced by the addition of zinc powder to the green mixture. Synthesis in the presence of zinc yields TiC0.5N0.5 powders consisting of round-shaped and unagglomerated particles.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 249-259
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Demonstration of Wet Chemical Synthesis of Nanomaterials for High School Students
Autorzy:
Acharyya, Swarnali
Acharyya, Sarani
Samanta, Pijus Kanti
Powiązania:
https://bibliotekanauki.pl/articles/1031206.pdf
Data publikacji:
2020
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Chemical Synthesis
Electronics
Nanomaterials
Nanotechnology
School-education
Opis:
Nanotechnology is the most emerging branch of science and technology leading to the development of devices starting from electronics to biomedical devices. It is thus desired that the students should have basic idea of this new emerging technology during their school education. Experimental demonstration of simple experiments of synthesizing nanomaterials and demonstration of its properties are very much important in motivating the students to learn this new technology. Wet chemical synthesis method is a simple and cost-effective method that can be adopted in the chemistry laboratory of higher secondary level school education in India. This hands-on experience will encourage the students to enter more into this nanotechnology.
Źródło:
World Scientific News; 2020, 148; 15-26
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Terapia słowem – „opowiedziane malarstwo” Alfreda Kubina
Verbal Therapy – “Painting Told” by Alfred Kubin
Autorzy:
Bajer, Ewelina
Powiązania:
https://bibliotekanauki.pl/articles/951556.pdf
Data publikacji:
2016
Wydawca:
Uniwersytet w Białymstoku. Wydawnictwo Uniwersytetu w Białymstoku
Tematy:
art synthesis
grotesque
literature
painting
Alfred Kubin
Opis:
The Other Side (1909) is the only novel by an Austrian painter and illustrator, Alfred Kubin. His work epitomizes the modernist concept of art synthesis. Kubin, drawing from the aesthetics of grotesque, creates an amalgam of apparently detached forms of representation, literature and painting. The Other Side uses surrealist humour and nightmarish motifs of onirism to convey the existential anxiety of fin de si`ecle.
Źródło:
Białostockie Studia Literaturoznawcze; 2016, 8
2082-9701
2720-0078
Pojawia się w:
Białostockie Studia Literaturoznawcze
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Genomics and the evolution of aminoacyl-tRNA synthesis.
Autorzy:
Ruan, Benfang
Ahel, Ivan
Ambrogelly, Alex
Becker, Hubert
Bunjun, Shipra
Feng, Liang
Tumbula-Hansen, Debra
Ibba, Michael
Korencic, Dragana
Kobayashi, Hiroyuki
Jacquin-Becker, Clarisse
Mejlhede, Nina
Min, Bokkee
Raczniak, Gregory
Rinehart, Jesse
Stathopoulos, Constantinos
Li, Tong
Söll, Dieter
Powiązania:
https://bibliotekanauki.pl/articles/1044116.pdf
Data publikacji:
2001
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
evolution
tRNA
aminoacyl-tRNA
translation
protein synthesis
Opis:
Translation is the process by which ribosomes direct protein synthesis using the genetic information contained in messenger RNA (mRNA). Transfer RNAs (tRNAs) are charged with an amino acid and brought to the ribosome, where they are paired with the corresponding trinucleotide codon in mRNA. The amino acid is attached to the nascent polypeptide and the ribosome moves on to the next codon. Thus, the sequential pairing of codons in mRNA with tRNA anticodons determines the order of amino acids in a protein. It is therefore imperative for accurate translation that tRNAs are only coupled to amino acids corresponding to the RNA anticodon. This is mostly, but not exclusively, achieved by the direct attachment of the appropriate amino acid to the 3'-end of the corresponding tRNA by the aminoacyl-tRNA synthetases. To ensure the accurate translation of genetic information, the aminoacyl-tRNA synthetases must display an extremely high level of substrate specificity. Despite this highly conserved function, recent studies arising from the analysis of whole genomes have shown a significant degree of evolutionary diversity in aminoacyl-tRNA synthesis. For example, non-canonical routes have been identified for the synthesis of Asn-tRNA, Cys-tRNA, Gln-tRNA and Lys-tRNA. Characterization of non-canonical aminoacyl-tRNA synthesis has revealed an unexpected level of evolutionary divergence and has also provided new insights into the possible precursors of contemporary aminoacyl-tRNA synthetases.
Źródło:
Acta Biochimica Polonica; 2001, 48, 2; 313-321
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The use of the linear form of dynamical equations of the satellite attitude control system for its analysis and synthesis
Autorzy:
Moldabekov, Meirbek
Sukhenko, Anna
Shapovalova, Darya
Yelubayev, Suleimen
Powiązania:
https://bibliotekanauki.pl/articles/1839688.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
synthesis
stability analysis
attitude control system
satellite
Opis:
At present, the methods based on using linearized dynamical equations are applied for syn- thesis of an attitude control system of a satellite with nonlinear dynamics. Linearized equa- tions describe the satellite dynamics approximately, which is the main their disadvantage. This article shows that basing on the angular momentum theorem, the nonlinear dynamical equations of the satellite attitude control system can be represented in the form of linear differential equations with variable coefficients, which makes it possible to use engineering methods of stability analysis and analysis of transient quality in the process of synthesis of the satellite attitude control system.
Źródło:
Journal of Theoretical and Applied Mechanics; 2021, 59, 1; 109-120
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characterisation of alginate micro- and nanospheres loaded with bovine serum albumin
Autorzy:
Wirecka, R.
Arruebo, M.
Sebastian, V.
Kyzioł, A.
Powiązania:
https://bibliotekanauki.pl/articles/284154.pdf
Data publikacji:
2017
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
drug delivery systems
bovine serum albumin
synthesis
Źródło:
Engineering of Biomaterials; 2017, 20, no. 143 spec. iss.; 35
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Factors influencing the occurrence of Fusarium mycotoxins in the grain of winter wheat
Autorzy:
Aleksandrowicz, Edyta
Powiązania:
https://bibliotekanauki.pl/articles/2148079.pdf
Data publikacji:
2020-12-30
Wydawca:
Instytut Uprawy Nawożenia i Gleboznawstwa – Państwowy Instytut Badawczy
Tematy:
fungal diseases
synthesis of mycotoxins
cereal protection
Opis:
Fusarium mycotoxins are secondary metabolites, bio-synthesized by filamentous fungi of the genus Fusarium, which, due to their diverse toxicity and difficulty in their removal from food and animal feeds, are the subject of research by scientists around the world. The most important mycotoxins found in wheat are: deoxynivalenol (DON), zearalenone (ZEN), and the T-2 and HT-2 toxins. Bearing consumer safety in mind, the levels of these substances in grain, food and animal feeds are regulated by law. In order to meet the health safety requirements imposed on grain, it is important to minimise the risk of fungal infection at individ-ual production stages. Weather conditions are the most important factor influencing the development of fungi and the accumula-tion of mycotoxins in grain. High temperature, combined with rainfall, are factors favouring the spread of fungal spores. Apart from weather conditions, individual elements of the production technology, such as appropriate variety selection, soil cultivation method, preceding crop, use of fungicides, and fertilization may reduce the quantity of mycotoxins in grain. In the conditions of the emerging climatic changes, favouring the development of fun-gal diseases, creating wheat varieties resistant to fungal diseases is a considerable challenge. Acquiring more in-depth knowledge on the relationship between the phenotypic features of a wheat variety and mycotoxin content would be helpful. This work is of review character and aims to indicate the basic factors influenc-ing the production of fusarium mycotoxins in winter wheat grain. The focus was placed on factors independent of human activity (weather conditions) and on individual elements of cultivation technology.
Źródło:
Polish Journal of Agronomy; 2020, 43; 103-112
2081-2787
Pojawia się w:
Polish Journal of Agronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
SCMNPs@Uridine/Zn: An efficient and reusable heterogeneous nanocatalyst for the rapid one-pot synthesis of tricyclic fused pyrazolopyranopyrimidine and 3-methyl carboxylate substituted pyrano[2,3-c]pyrazole derivatives under solvent-free conditions
Autorzy:
Wei, Jia
Gui, Wenjun
Cui, Yanjun
Zhang, Zhifang
Yousif, Qahtan A.
Powiązania:
https://bibliotekanauki.pl/articles/778587.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
nanocatalyst
synthesis of tricyclic
carboxylate
efficient heterogeneous
Opis:
SCMNPs@Uridine/Zn is utilized as an environmental-friendly and efficient heterogeneous nanocatalyst for two one-pot four-component condensation reactions, containing hydrazine hydrate, arylaldehyde, ethyl acetoacetate, and barbituric acid to yield tricyclic fused pyrazolopyranopyrimidine derivatives (5a-q), and hydrazine hydrate, arylaldehyde, malononitrile, and dimethyl acetylenedicarboxylate/diethyl acetylenedicarboxylate to yield 3-methyl carboxylate substituted pyrano[2,3-c]pyrazole derivatives (8a-y) under solvent-free conditions with high to excellent yields. The main advantages of this process are easy work-up, short reaction times, no chromatographic purifications, and recyclability of the catalyst for a minimum of six runs without any signifcant decrease in yields of the products. Also, the prepared catalyst SCMNPs@Uridine/Zn was synthesized and fully characterized by various techniques including Fourier transform infrared spectroscopy (FT-IR), energy dispersive X-ray (EDX), thermogravimetric analysis (TGA), X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and Raman spectroscopy.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 2; 20-33
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of a novel environmental friendly plasticizer based on tung oil fatty acid for poly (vinyl chloride) blends
Autorzy:
Tong, H.
Hai, J.
Powiązania:
https://bibliotekanauki.pl/articles/778643.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Synthesis
plasticizer
migration resistance
poly (vinyl chloride)
Opis:
A novel environmental friendly plasticizer (TPE) derived from tung oil fatty acid with long fatty acid chain and high degree of branching was synthesized. Chemical structure of the obtained TPE was characterized with Fourier transform infrared spectroscopy (FT-IR) and  1H NMR. TPE was used to prepare plasticized PVC blends as main plasticizer. Thermal stability, mechanical properties and migration resistance of poly (vinyl chloride) plasticized with TPE were investigated. The results showed that torque data of plasticized PVC blends reached 12.4 N·m when the mass of the TPE was 50 wt.%. TPE improved the thermal stability of PVC blends obviously than dioctyl phthalate (DOP). The leaching tests showed that PVC plasticized with TPE were with higher migration resistance than that of DOP. The excellent thermal stability and high migration resistance of PVC blends showed high application value for TPE.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 2; 92-97
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties and activity of the cobalt catalysts for NH3 &enspsynthesis obtained by co-precipitation – the effect of lanthanum addition
Autorzy:
Zybert, M.
Karasińska, M.
Truszkiewicz, E.
Mierzwa, B.
Raróg-Pilecka, W.
Powiązania:
https://bibliotekanauki.pl/articles/778653.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ammonia synthesis
cobalt catalyst
promoter
lanthanum
coprecipitation
Opis:
In modern research on catalysts for NH3&enspsynthesis a lot of attention is paid to cobalt. In this work the new catalytic systems based on cobalt are presented. Unsupported cobalt catalysts singly promoted (La or Ba) and doubly promoted (La and Ba) were prepared and tested in NH3&enspsynthesis reaction under commercial synthesis conditions. Characterization studies revealed that lanthanum plays a role of a structural promoter, which improves the surface of catalyst precursors and prevents from sintering during calcination. However, lanthanum has a negative effect on the reduction of cobalt oxide, but the addition of barium promoter (Co/La/Ba catalyst) diminishes the negative impact of La. The co-promotion of cobalt with lanthanum and barium results in the increasing of the active phase surface and improvement of its activity in NH3&enspsynthesis.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 138-143
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solid State Synthesis of Europium Zirconate Based Material
Autorzy:
Mikuśkiewicz, M.
Moskal, G.
Powiązania:
https://bibliotekanauki.pl/articles/353816.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
europium zirconates
solid-state synthesis
pyrochlores
TBC
Opis:
In the article, the characterization of the microstructure, phase composition and distribution of elements in the Eu2 O3 -ZrO2 sintered materials obtained by four different ways of powders’ homogenization (mixing) process and different temperature of sintering process is shown. The feedstock powders with an average mole ratio of ZrO2 to Eu2 O3 equal 74% to 26% were used as an initial material. The principal aim of the investigation was characterization of differences in the microstructure of the same type of ceramics, however, prepared via different mixing and manufacturing processes. The range of the investigation covered a characterization of these materials via phase identification of all samples by XRD (X-ray diffraction) and characterization of internal morphology of the specimens with detailed analysis of elements distributions by SEM (scanning electron microscopy) and EDS (energy dispersive spectrometry). The aim of the following investigation is to characterize the possibilities of the solid state synthesis of the europium zirconate based materials, dedicated for TBC applications.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 4; 1343-1352
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of quercetin-functionalized silver nanoparticles by rapid one-pot approach
Autorzy:
Pandian, S.R.K.
Kunjiappan, S.
Ravishankar, V.
Sundarapandian, V.
Powiązania:
https://bibliotekanauki.pl/articles/2096369.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
quercetin
bioflavonoid
one-pot synthesis
AgNPs
antioxidant
Opis:
Nanotechnology plays a pivotal role in all areas of science, and the synthesis and surface modification of nanoparticles are crucial in this field. Metal nanoparticles synthesized using plant extracts or phytocompounds are highly significant in the development of various therapeutics and diagnostics. In the present study, we report the one-pot and rapid synthesis of silver nanoparticles (AgNPs) by quercetin, a flavonoid found in various edible plants. The nanoparticles were then characterized using UV-VIS spectrophotometry, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The role of quercetin in the synthesis of silver nanoparticles was demonstrated. The nanomaterial was 20–30 nm in size and spherical in shape. The silver nanoparticles were also confirmed to show antioxidant activity at 80 μg/ml concentration in vitro by DPPH, FRAP, and power reduction methods.
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2021, 102, 1; 75-84
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of yttrium citrate by the reaction of yttrium hydroxide with sodium citrate
Autorzy:
Janusz, Władysław
Skwarek, Ewa
Sternik, Dariusz
Powiązania:
https://bibliotekanauki.pl/articles/1450116.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
yttrium citrate synthesis
CHN
TGA
particle size
Opis:
A method of obtaining yttrium citrate by transformation of freshly precipitated yttrium hydroxide in the solutions of sodium citrate under hydrothermal conditions has been proposed. To determine the synthesis time, transformation kinetics consisted in by taking the solid samples for the C and H contents analysis after 6, 12, 24, 48 and 72 hours of synthesis. Simultaneously these samples were subjected to the thermogravimetric analysis. As follows from the thermogravimetric analysis adsorption of citrate dihydrate on yttrium hydroxide is observed in the initial period up to 24 hours. Later the yttrium citrate dihydrate is formed. The thermogravimetric analysis of the final product i.e. amorphous yttrium citrate showed that the decomposition/oxidation of the sample occurs in six stages the particle size analysis method of static light scattering showed that 45% of the particles had a diameter of 0.1-0.9 µm and 55% of particles with sizes from 0.9 to 5 µm.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 51--59
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Silver(I) recovery on sulfur-containing polymeric sorbents from chloride solutions
Autorzy:
Pilśniak-Rabiega, Magdalena
Wolska, Joanna
Powiązania:
https://bibliotekanauki.pl/articles/1450545.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
functional polymers
synthesis
silver(I)
sorption
selectivity
Opis:
This work describes the preparation of functional polymers containing 2-mercapto-1-methylimidazole and guanylthiourea ligands from chemically modified vinylbenzyl chloride/divinylbenzene copolymer (VBC/DVB). The resins were used for the removal of Ag(I) from synthetic and real chloride solutions. The 2-mercapto-1-methylimidazole resin was highly selective towards Ag(I) in relation to Pb(II) from real chloride leaching solution. The resins were selective for Ag(I) from real chloride solution and they did not sorb chloride complexes of Co(II), Ni(II) and Zn(II). The sorption kinetic data were well fitted to the pseudo-first-order kinetic model. The degree of Ag(I) desorption was about 80% using 1% potassium cyanide solution in 0.5% hydrogen peroxide solution. Resins retain their capacity towards Ag(I) in five consecutive sorption/desorption cycles.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 290-310
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nanostrukturalne materiały wybuchowe otrzymywane metodą zol-żel : synteza i właściwości
Nanostructured energetic materials with sol-gel chemistry : preparation and properties
Autorzy:
Kiciński, W.
Powiązania:
https://bibliotekanauki.pl/articles/209673.pdf
Data publikacji:
2007
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Tematy:
energetic nanocomosities
sol-gel synthesis
oxygen balance
Opis:
Nową formą materiałów wysokoenergetycznych, która w ostatnich latach wzbudza duże zainteresowanie, są nanostrukturalne materiały wybuchowe (NanoMW). Materiały takie łączą zalety jednoskładnikowych MW (duża moc) i mieszanin pirotechnicznych (duża gęstość energii). W artykule opisano syntezę i wstępną charakterystykę nanokompozytów wybuchowych złożonych z żeli organicznych, pełniących rolę paliwa, i soli nieorganicznych pełniących rolę utleniacza. Wykorzystując znaną od wielu lat technikę zol-żel, otrzymano dwa typy wodnych zoli organicznych: zol rezorcynowo-formaldehydowy (RF) i rezorcynowo-furfuralowy (RFur), które mieszano następnie z roztworem soli nieorganicznych NH₄ClO₄, LiClO₄, Mg(ClO₄)₂ i NH₄NO₃. Mieszaniny takie poddawano procesowi żelatynizacji i powolnego suszenia, w wyniku którego otrzymywano hybrydowy, organiczno-nieorganiczny kompozyt zwany kserożelem, posiadający cechy materiału wybuchowego. Stężenie soli oraz dodatek drugiego, obok wody rozpuszczalnika (np. metanolu) do wodnego zolu ma zasadnicze znaczenie w procesie transformacji zolu w żel. Wybrane kompozyty badano przy wykorzystaniu wielu technik; SEM, HR, TEM, AFM, XRD i TG/DTA. Głównym celem tych badań było oszacowanie wielkości kryształów utleniacza nieorganicznego i jednorodności jego rozproszenia w matrycy polimerowej. Obserwacje SEM potwierdziły nanostrukturalny charakter kompozytów żel organiczny/sól nieorganiczna, w których kryształy soli (w zależności od rodzaju badanego materiału) mają wielkość 100-1000 nm i są równomiernie rozproszone w polimerze. Badania XRD wskazały, że poprzez zmianę składu żelu i sposobu jego suszenia możliwe jest otrzymanie znacznie mniejszych kryształów utleniacza. W przypadku kompozytu RFur/Mg(ClO₄)₂ utleniacz krystalizuje w polimerze rezorcynowo-furfuralowym w postaci nanokryształów o wielkości ok. 20 nm. Dodatkowo analiza HR TEM tego kompozytu wykazała obecność porów o wielkości 10 nm. Analizy TG/DTA potwierdziły wysokoenergetyczny charakter kompozytów kserożel/utleniacz nieorganiczny. Po ogrzaniu w płomieniu materały RF/LiClO₄ = 63/37, RFur/Mg(ClO₄)₂ = 60/40, spalają się wybuchowo, czemu towarzyszy efekt dźwiękowy i błysk.
Sol-gel synthesis and characterization of organic gel-based energetic materials are presented. Two types of polymetric sols: resorcinol-formaldehyde (RF), and resorcinol-furfural (RFur) sols were mixed in water-containg medium with water solution of inorganic salts NH₄ClO₄, LiClO₄, Mg(ClO₄)₂ and NH₄NO₃. After gelation and drying, the hybrid nanocomposities with the properties of energetic materials were obtained. It was stated that salt concentration and addition of second solvent (e.g. methanol) to the mixture of reagents has crucial meaning for gel formation. In the case when only water was used, a mixture of organic sol/inorganic salt-did not transfer from sol to gel and precipitates were formed. Conventional drying of wet gelled composites leads to rigid material called xerogels. The microstructure, morphology, and some other properties of chosen composities were studied by means of HR SEM, HR TEM, AFM, XRD, DTA/TG, and elemental analysis. SEM observation revelated that sizes of the oxidizer particles vary from less than 100 nm to c.a. 1000 nm.XRD patterns suggest that in some-cases, the crystal particles are of 20-30 nm in size. HR TEM images revelated that xerogels are porous materials with cavities, c.a. 10 nm. TG/DTA analyses showed that the tested composites decompose as typical energetic materials. If pre-heated and exposed to flame, some of them (especially RF/LiClO₄ = 63/37, RFur/Mg(ClO₄)₂ = 60/40 composites) undergo violent deflagration with loud sound and flash effect.
Źródło:
Biuletyn Wojskowej Akademii Technicznej; 2007, 56, 3; 131-143
1234-5865
Pojawia się w:
Biuletyn Wojskowej Akademii Technicznej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microwave synthesis of sulfanilic acid
Synteza mikrofalowa kwasu sulfanilowego
Autorzy:
Havlíček, J.
Myška, K.
Tejchman, W.
Karásková, N.
Doležal, R.
Maltsevskaya, N. V.
Kolář, K.
Powiązania:
https://bibliotekanauki.pl/articles/106593.pdf
Data publikacji:
2017
Wydawca:
Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:
synthesis of sulfanilic acid
microwave assisted synthesis
solvent-free synthesis
school experiment
organic chemistry education
synteza kwasu sulfanilowego
synteza mikrofalowa
synteza bez rozpuszczalnika
eksperyment szkolny
edukacja chemii organicznej
Opis:
Sulfanilic acid represents an important substance, which is frequently utilized in the industry of azo dyes as well as in drug development of antimicrobials (e.g. of sulfonamides). Students can also meet with such type of compounds in chemistry labs, for example, when they estimate pH by methyl orange indicator or prepare Orange II for textile colouring. Both of these dyes are products of azo coupling of sulfanilic acid as diazonium salt with N,N-dimethylaniline or 2-naphthol, respectively. In the article, we focus on the synthesis of sulfanilic acid as a well-known experiment in the organic chemistry education. The synthesis was modified as the solvent free and microwave assisted experiment under semimicroscale conditions. That experiment is very convenient for the organic chemistry courses in the university or the high school teaching.
Kwas sulfanilowy stanowi ważną substancję, często stosowaną w przemyśle barwników azowych, jak również w produkcji leków przeciwdrobnoustrojowych (np. sulfonamidów). Studenci mogą również spotykać się z takimi związkami w laboratoriach chemicznych, na przykład przy oznaczaniu pH z wykorzystaniem oranżu metylowego lub przy przygotowywaniu Oranżu II dla przemysłu tekstylnego. Oba te barwniki są produktami sprzężenia soli diazoniowych kwasu sulfanilowego odpowiednio z N,N-dimetyloaniliną lub 2-naftolem. W artykule przedstawiono syntezę kwasu sulfanilowego jako przykład dobrze znanego eksperymentu w edukacji chemii organicznej. Syntezę zmodyfikowano jako reakcję bez rozpuszczalników i wspomagano mikrofalowo w warunkach półmikropreparacji. Eksperyment ten powinien być przedstawiany podczas kursów chemii organicznej na uniwersytecie lub w szkole średniej.
Źródło:
Chemistry-Didactics-Ecology-Metrology; 2017, 22, 1-2; 93-98
2084-4506
Pojawia się w:
Chemistry-Didactics-Ecology-Metrology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimal SAT Solver Synthesis of Quantum Circuits Representing Cryptographic Nonlinear Functions
Autorzy:
Jagielski, Adam
Powiązania:
https://bibliotekanauki.pl/articles/27311913.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
quantum computing
circuit synthesis
cryptography
satisfiability problem
Opis:
In this article we present a procedure that allows to synthesize optimal circuit representing any reversible function within reasonable size limits. The procedure allows to choose either the NCT or the MCT gate set and specify any number of ancillary qubits to be used in the circuit. We will explore efficacy of this procedure by synthesizing various sources of nonlinearity used in contemporary symmetric ciphers and draw conclusions about properties of those transformations in quantum setting. In particular we will try to synthesize optimal circuit representing ASCON cipher SBOX which recently won NIST competition for Lightweight Cryptography standard.
Źródło:
International Journal of Electronics and Telecommunications; 2023, 69, 2; 261--267
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on sintering process of synthetic hydroxyapatite
Autorzy:
Malina, Dagmara
Biernat, Kamila
Sobczak-Kupiec, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/1039506.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
calcium phosphates
hydroxyapatite
sintering process
wet synthesis
Opis:
In this study the effect of sintering process in different temperatures on microstructure and morphological properties of sintered hydroxyapatite (HAp) was investigated. HAp powder was prepared by wet precipitation method from following reagents: Ca(OH)2 + H3PO4 in an alkaline conditions. Thermal analysis (TA), X-Ray diffraction method (XRD), FT-IR spectrometry (FT-IR) and scanning electron microscopy (SEM) were used to elaborate the phase composition and properties of sintered HAp samples and raw HAp powder as well. The total and apparent density and total porosity of sintered compacts, shrinkage and weight loss during the sintering were also measured. The results show that there is a difference in sintering behavior of synthetic hydroxyapatites depending on sintering temperature. The main differences refer to the loss of mass, shrinkage, changes in porosity and density of the investigated materials.
Źródło:
Acta Biochimica Polonica; 2013, 60, 4; 851-855
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure, catalytic activity and evolutionary relationships of 1-aminocyclopropane-1-carboxylate synthase, the key enzyme of ethylene synthesis in higher plants.
Autorzy:
Jakubowicz, Małgorzata
Powiązania:
https://bibliotekanauki.pl/articles/1043746.pdf
Data publikacji:
2002
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
ethylene synthesis
1-aminocyclopropane-1-carboxylate synthase
Opis:
Both ethylene and the enzymes of ethylene synthesis are subjects of intensive scientific investigation. The present review discusses structure, catalytic activity and evolutionary relationships of 1-aminocyclopropane-1-carboxylate synthase, identified for the first time in ripening tomato in 1979. This enzyme is responsible for the conversion of S-adenosyl-L-methionine to 1-aminocyclopropane-1-carboxylic acid, which is the key step of ethylene synthesis in higher plants. The role of this enzyme (especially in the fruit ripening) was demonstrated in 1991 in transgenic tomato plants, expressing 1-aminocyclopropane-1-carboxylate synthase antisense RNA. On the basis of mutagenesis and crystallization of the enzyme, new data were provided on the three-dimensional structure and amino-acid residues which are critical for catalysis. The control of ethylene production is of great interest for plant biotechnology because it can delay senescence and overmaturation. These processes are responsible for large loss of vegetables and fruit on storage. Detailed structural and biochemical data are necessary to help design 1-aminocyclopropane-1-carboxylate synthase inhibitors, whose application is expected to have immense agricultural effects.
Źródło:
Acta Biochimica Polonica; 2002, 49, 3; 757-774
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and LFER study of some substituted hydrazones
Autorzy:
Vijayakumar, R.
Rajarajan, M.
Senbagam, R.
Balaji, S.
Manikandan, V.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1182767.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Hydrazones and substituent effect
LFER study
Synthesis
Opis:
A series containing ten substituted hydrazones have been synthesized by condensation between semicarbazide and various substituted benzaldehydes. The hydrazones were confirmed by their physical constants and UV, IR, 1H NMR and 13C NMR spectral data. This UV, IR, 1H NMR and 13C NMR spectral data have been used for LFER studied with Hammett constants and Swain-Lupton’s parameters.
Źródło:
World Scientific News; 2017, 66; 263-280
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, characterization and docking studies of some novel xanthene derivatives
Autorzy:
Bhatt, Aditya H.
Shah, Viral R.
Rawal, Rakesh M.
Powiązania:
https://bibliotekanauki.pl/articles/1075739.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Antimicrobial activity
Docking studies
Hantzsch synthesis
Xanthene
Opis:
The synthesis of a novel xanthene derivatives bearing dimedone as an excellent precursor has been achieved by applying one pot three component Hantzsch type condensation. The newly synthesized compounds were characterized by spectral and elemental analyses. All synthesized compounds undergo docking studies and biological screening for antimicrobial activity against Gram-positive bacteria, Gram-negative bacteria and fungal species. Among all the tested compounds, it was found that compound 3c, 3d, 3g and 3h revealed better activities against the Gram-positive rather than the Gram-negative bacteria whereas results of docking studies revealed that compounds 3b, 3g and 3i showed best binding affinity towards ATP binding pocket of Human PIM1 kinase receptor through steric favorable and H-bond interactions.
Źródło:
World Scientific News; 2019, 118; 100-114
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Characterization, In-Vitro Antimicrobial Evaluation and Antioxidant Studies of Some Isoxazoline Derivatives
Autorzy:
Vishnupriya, P.
Rubala mary, M.
Powiązania:
https://bibliotekanauki.pl/articles/1112444.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Chalcone
antibacterial
antifungal
antioxidant activity
isoxazole
synthesis
Opis:
The tremendous rise in development of resistance to antimicrobials has created an alarming situation for researchers and clinicians. In this regard, an attempt has been made to develop a series of azole-based derivatives. The presented study consists of the design and synthesis of some newer derivatives by incorporating the isoxazole nucleus in the pharmacophore. These are also characterized physicochemically and by spectral means (IR and microanalysis). Moreover, the antioxidant activity of these derivatives was assessed using DPPH radical scavenging methods Finally, all of the newly isolated compounds were tested for their antimicrobial activities. Herein, antimicrobial screening using the agar disc diffusion method revealed that the majority of the derivatives are most active.
Źródło:
World News of Natural Sciences; 2018, 18, 2; 72-78
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Time constraints on experimental studies of lead apatites
Autorzy:
Topolska, Justyna
Bajda, Tomasz
Puzio, Bartosz
Manecki, Maciej
Kozub-Budzyń, Gabriela
Powiązania:
https://bibliotekanauki.pl/articles/2058621.pdf
Data publikacji:
2019
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
pyromorphite
vanadinite
experimental mineralogy
dissolution
solubility synthesis
Opis:
The paper presents the results of experimental studies on the synthesis and thermodynamic stability of selected Pb-apatites in terms of criteria determining termination of the experiments. Based on the case study, we indicate difficulties in analysing the obtained experimental data. Time-resolved sampling of precipitate formed during a dropwise synthesis of pyromorphite was performed and the results were compared to the literature data. It has been concluded that the Ostwald ripening time for synthesized solids depends primarily on the chemical composition of the intended Pb-apatite phase. We presented that heterogeneity of precipitate affects its dissolution in terms of repeatability of the results and equilibrating time. A unique 9-year-long experiment on vanadinite stability at a pH range from 2.0-6.0 revealed that among all tested dissolution conditions only the reactions at the pH = 3.5 can perform as the basis for some thermodynamic calculations. It has been concluded that the rate of phase transitions in the Pb-apatites group can be misleading in terms of determining the equilibrium of the system, and the experimental setup designed particularly to provide reliable controls in this aspect should be involved. Means in this respect have been proposed.
Źródło:
Geological Quarterly; 2019, 63, 4; 721--728
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Energetic Nitrogen-rich Salts
Autorzy:
Wu, J.-W.
Zhang, J.-G.
Zhang, T.-L.
Yang, L.
Powiązania:
https://bibliotekanauki.pl/articles/358479.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic salts
synthesis
characterization
crystal structure
review
Opis:
Energetic salts as a unique class of energetic materials have recently been investigated widely, since they possess advantages over their atomically similar nonionic analogues – they tend to exhibit lower vapor pressures, higher densities and better thermal stabilities. Furthermore, these salts are readily improved upon by the appropriate combination of different cations and anions. Over the last twenty years, our group has continued to synthesize and study novel ionic energetic materials. Here, we have summarized all of the series of nitrogen-rich energetic salts. This review gives an overview of the various studies dealing with synthetic aspects and some of the physicochemical properties of ionic compounds that are based on ammonia, guanidine, semicarbazide, carbohydrazide, tetrazine, tetrazole, triazole and imidazole. In addition, their potential applications in the fields of explosives and propellants are discussed. We hope these investigations will be helpful in providing a wider insight for future research in the area of energetic salts.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 3; 417-437
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Syntetyzer mowy uwzględniający prozodię wypowiedzi
Text-to-speech synthesizer employing automatic prosodic modification
Autorzy:
Łopatka, K.
Czyżewski, A.
Powiązania:
https://bibliotekanauki.pl/articles/266714.pdf
Data publikacji:
2010
Wydawca:
Politechnika Gdańska. Wydział Elektrotechniki i Automatyki
Tematy:
synteza mowy
prozodia
PSOLA
speech synthesis
prosody
Opis:
Przedstawiono system syntezy mowy polskiej uwzględniający w sposób automatyczny prozodię, tj. profil intonacyjny, tempo i akcenty wypowiedzi. Zastosowano syntezę konkatenacyjną z wykorzystaniem jednostek mowy zawierających przejścia między dwoma głoskami – difonów. Opisano poszczególne moduły wchodzące w skład syntetyzera: przetwarzanie tekstu, bazę jednostek mowy oraz algorytmy związane z tworzeniem syntetyzowanego sygnału. Przeprowadzono testy subiektywne potwierdzające wysoką zrozumiałość generowanej mowy i skuteczność modyfikacji prozodycznych. Przedstawiono możliwość zastosowania opisanego systemu w aplikacjach edukacyjnych lub terapeutycznych oraz interfejsach multimodalnych przeznaczonych dla osób niepełnosprawnych.
The paper presents a Text-To-Speech synthesizer of Polish language employing automatic prosodic modification. The method used for synthesizing the speech signal is concatenative synthesis using constant-length segments – diphones. The subsequent modules of the synthesizer are introduced. Employed language analysis and signal processing techniques are described. The synthesized speech yields high intelligibility and naturalness, which is proved by auditory tests. The proposed system can be used in educational and therapeutic applications or multimodal interfaces for disabled people.
Źródło:
Zeszyty Naukowe Wydziału Elektrotechniki i Automatyki Politechniki Gdańskiej; 2010, 28; 105-108
1425-5766
2353-1290
Pojawia się w:
Zeszyty Naukowe Wydziału Elektrotechniki i Automatyki Politechniki Gdańskiej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Implementation of Algorithm of Petri Nets Distributed Synthesis into FPGA
Autorzy:
Bukowiec, A.
Tkacz, J.
Gratkowski, T.
Gidlewicz, T.
Powiązania:
https://bibliotekanauki.pl/articles/226156.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
C#
decomposition
FGPA
logic synthesis
Petri net
Opis:
In the paper an implementation of algorithm of Petri net array-based synthesis is presented. The method is based on decomposition of colored interpreted macro Petri net into subnets. The structured encoding of places in subnets is done of using minimal numbers of bits. Microoperations, which are assigned to places, are written into distributed and flexible memories. It leads to realization of a logic circuit in a twolevel concurrent structure, where the combinational circuit of the first level is responsible for firing transitions, and the second level memories are used for generation of microoperations. This algorithm is implemented in C# and delivered as a stand alone library.
Źródło:
International Journal of Electronics and Telecommunications; 2013, 59, 4; 317-324
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of Generalised Threshold Gates and Multi Threshold Threshold Gates
Autorzy:
Nikodem, M.
Bawiec, M. A.
Biernat, J.
Powiązania:
https://bibliotekanauki.pl/articles/227258.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
threshold gates
synthesis
Boolean functions
MTTG
GTG
Opis:
This paper presents synthesis algorithms for Generalised and Multi Threshold Threshold Gates. Both algorithms can be applied to generate circuit structures for arbitrary Boolean functions. We present gate's formal models, synthesis algorithms and complexity estimations of the resulting structures.
Źródło:
International Journal of Electronics and Telecommunications; 2012, 58, 1; 49-54
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A New Thermally-stable Insensitive High Explosive:N,N′-Bis(1,2,3,4-tetrazol-5-yl)-4,4′-diamino-2,2′,3,3′,5,5′,6,6′-octanitroazobenzene (BTeDAONAB)
Autorzy:
Mousavi, S.
Esmaeilpour, K.
Keshavarz, M. H.
Powiązania:
https://bibliotekanauki.pl/articles/951499.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
synthesis
BTeDAONAB
sensitivity
thermal stability
high explosive
Opis:
A novel high performance explosive compound, N,N′-bis(1,2,3,4-tetrazol5-yl)-4,4′-diamino-2,2′,3,3′,5,5′,6,6′-octanitroazobenzene( BTeDAONAB), is introduced which is a thermally stable, insensitive high explosive. The presence of −NH2, −N=N− groups and the tetrazole ring simultaneously in the BTeDAONAB unit surprisingly increases its thermal stability. For the identification and characterization of BTeDAONAB, different analytical techniques have been used, including melting point, IR, 1H NMR, 13C NMR spectroscopy, elemental analysis, differential thermal analysis (DTA), thermogravimetry (TG), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The sensitivity and detonation properties of BTeDAONAB were compared with 2,4,6-triamino1,3,5-trinitrobenzene (TATB) and N,N′-bis(1,2,4-triazol-3-yl-)-4,4′-diamino2,2′,3,3′,5,5′,6,6′-octanitroazobenzene (BTDAONAB), two well-known, thermally stable, insensitive high explosives, as well as hexanitrostilbene (HNS). These studies show that BTeDAONAB has favorable thermal stability with high performance.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 4; 455-465
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Towards automated synthesis of concurrent control programs
Autorzy:
Bocewicz, G.
Bzdyra, K.
Banaszak, Z.
Powiązania:
https://bibliotekanauki.pl/articles/117806.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Promocji Wiedzy
Tematy:
automated synthesis
automatic modeling
concurrent control programs
Opis:
One of the key problems in the area of automatic synthesis of real-time concurrent control programs is a problem of automated modeling of systems comprising multiple activities or processes that proceed concurrently. In that context, the discrete-event systems framework enabling to predict the modeled objects performance and then to design of assumed quality control program on the basis of the given specification of the processes controlled, plays a crucial role. From that point of view, the Petri nets can be seen as a most widely recognized tool aimed at modeling system’s concurrency. So, the main objective of our contribution is to illustrate the Petri nets based approach from both: IF…THEN… rules system’s behavior specification and its Turing machine like representation points of view.
Źródło:
Applied Computer Science; 2011, 7, 2; 7-20
1895-3735
Pojawia się w:
Applied Computer Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inverse Model for the Solute Micro-Field Formation during Self-Propagating High Temperature Reaction
Autorzy:
Wołczyński, W.
Powiązania:
https://bibliotekanauki.pl/articles/351234.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
diffusion equation
diffusion barrier
self-propagating synthesis
Opis:
A new thermodynamic description for the self-propagating high temperature synthesis (SHS - reaction) is presented in the “inverse” version. This description is worked out for the diffusion barrier, thickness of which is at the limit, i.e. its value is infinitesimally small. The solution to the diffusion equation delivered in the description can be easily extended for the diffusion barrier of a greater thickness. The Ni/Al multi-layers system is treated as a virtual eutectic alloy solidifying with the rate equal to that involved by the self-propagating reaction. It is suggested to inverse the curves obtained for solidification in order to characterize the melting completed by the formation of the AlNi - intermetallic phase required in the self-propagating synthesis.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 141-147
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kwasy nukleinowe jako katalizatory reakcji chemicznych
Nucleic acids as catalysts in chemical reactions
Autorzy:
Bukowiecka-Matusiak, M.
Sobczak, M.
Powiązania:
https://bibliotekanauki.pl/articles/172466.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
DNA
kataliza
synteza asymetryczna
catalysis
asymmetric synthesis
Opis:
Nucleic acids, due to their specific structure, are effective and durable carriers of genetic information. They have also been used as catalysts in chemical reactions. The right-handed DNA double helix structure has become one of the icons of modern science, and its share in asymmetric catalysis is undeniable. In these reactions, DNA is a source of chirality and proximity between oligonucleotides and complexes of copper during catalysis, what allows a direct transfer of chirality from DNA to the reaction product. Almost complete regioselectivity and excellent enantioselectivity of the aforementioned reactions in water are the evidence of the potential of asymmetry based on DNA. Asymmetric catalysis used in organic synthesis, allows achieving high enantioselectivity. This strategy has been successfully used to create new C-C bonds in Diels- Alder cycloaddition, Friedel-Crafts alkylation and Michael addition using copper complexes with oligonucleotides as catalysts. The important factor to optimize the reaction of asymmetric catalysis in the presence of DNA constitutes its sequence. It has been shown that the use of the double helix DNA can provide the product with higher enantiomeric excess than using the single strand of DNA. In addition, the results of the study suggest that Friedel-Crafts alkylation is accelerated by DNA almost 30-fold. The same correlation is observed in Diels-Alder cycloaddition. Due to promising results, further testing directed at the possibility of using catalytic DNA is being conducted.
Źródło:
Wiadomości Chemiczne; 2012, 66, 1-2; 119-137
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of the Content of Promoters in Magnetite and Wustite Phases in the Fused Iron Catalyst
Autorzy:
Lendzion-Bieluń, Z.
Jędrzejewski, R.
Powiązania:
https://bibliotekanauki.pl/articles/779352.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
iron catalyst
promoters
ammonia synthesis
selective etching
Opis:
Taking advantage of differences in etching rates of crystallographic phases, forming an oxidized form of the fused iron catalyst, a content of promoters in main phases, magnetite and wustite, was determined. A calcium oxide content in magnetite and wustite was 0.54 wt% and 3.59 wt%, respectively. Aluminum oxide was found in the magnetite phase, and its content was 4.5 wt%. The third promoter, potassium oxide, was almost completely located outside these phases. XRD and ICP-OES instrumental methods were used in the investigations.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 27-29
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microwave assistant synthesis of calcium phosphate minerals using hen’s eggshells as a calcium source
Autorzy:
Kalbarczyk, Marta
Szcześ, Aleksandra
Powiązania:
https://bibliotekanauki.pl/articles/1450409.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hydroxyapatite
brushite
β-TCP
microwave assisted synthesis
Opis:
In this study raw hen’s eggshells were used as a calcium source for calcium phosphate mineral synthesis. The materials composed of brushite and different amounts of HA (hydroxyapatite) and β-TCP (β-tricalcium phosphate) with the needle-like, sheet-like and hexagonal structures were synthesized in the presence of the microwave. It was found that the time of microwave action, temperature and initial pH are parameters affecting the morphology and composition of the obtained materials, i.e. the increasing duration of MW exposure increases the amount of HA increases, whereas the temperature increase causes an increase in the contents of brushite and β-TCP. The lowering of initial pH leads to an increase in the brushite content.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 167-177
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Some applications of barium titanate prepared by different methods
Autorzy:
Sydorchuk, Volodymyr
Khalameida, Svitlana
Skwarek, Ewa
Biedrzycka, Adrianna
Powiązania:
https://bibliotekanauki.pl/articles/2146894.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
barium titanate
synthesis
physicochemical properties
photocatalytic properties
Opis:
The paper presents some application of barium titanate synthesized by different methods. Barium titanate samples were prepared by four procedures: solid state, mechanochemical as direct synthesis and modification as well as hydrothermal and microwave. The obtained samples were systematically studied using X-ray diffraction, nitrogen adsorption, Fourier transform infrared spectroscopy (FTIR), potentiometric titration, and quasi-elastic light scattering and zeta potential measurements. The values of pHpzc (point of zero charge) and pHIEP (isoelectric point) characteristic of the electrical double layer were determined. The prepared samples were tested as photocatalysts under visible light. As a result, relationship between the conditions of barium titanate synthesis, its physicochemical and electrokinetic parameters, as well as photocatalytic activity under visible light was first established.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 2 (Special issue - selected papers conference: Physicochemistry of interfaces - instrumental methods); art. no. 147192
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Silver(I) recovery on thiomorpholine - modified functional polymer
Autorzy:
Pilśniak-Rabiega, Magdalena
Wolska, Joanna
Powiązania:
https://bibliotekanauki.pl/articles/2175444.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
synthesis
microwave modification
sorption
chloride solutions
selectivity
Opis:
The functional polymer containing heterocyclic ligands was synthesized by microwave modification of a crosslinked poly(vinylbenzyl chloride–divinylbenzene) matrix with thiomorpholine. The modification yield was 89.3%. The sorbent was used to recover Ag(I) from the synthetic and real chloride solutions. The maximum sorption capacity of Ag(I) was approximately 180 mg Ag/g. The sorption kinetic data were well-fitted to the pseudo-first-order kinetic model. The degree of silver desorption was approximately 50.0% using a 1.0% potassium cyanide solution in a 0.50% hydrogen peroxide solution. The resin retained its capacity toward Ag(I) in five consecutive sorption/desorption cycles. The thiomorpholine modified resin was highly selective toward Ag(I) in relation to Cu(II), Pb(II), Co(II), Ni(II), and Zn(II) from the real chloride leaching solution.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 156609
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Practical highly enantioselective synthesis of (R)- and (S)-(E)-4-hydroxynon-2-enal
Autorzy:
Komisarski, Marek
Kaczmarska, Zuzanna
Kuśmierek, Jarosław
Powiązania:
https://bibliotekanauki.pl/articles/1040657.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
asymmetric synthesis
4-HNE enantiomers
(E)-4-hydroxynon-2-enal (4-HNE) synthesis
lipid peroxidation
Candida antarctica lipase
Opis:
Oxidative stress enhances lipid peroxidation (LPO) implicated in cancer promotion and progression. (E)-4-Hydroxynon-2-enal 1 (trans-4-hydroxy-2-nonenal, HNE) is one of the most abundant products of LPO. Reactions of HNE with DNA and proteins are responsible for its mutagenic and toxic effects. On the other hand, HNE is regarded as a key molecule in stress mediated cell cycle signaling. LPO generates racemic HNE (rac-1); however, it is expected that the individual enantiomers will behave differently in their interactions with cell components. The study of HNE stereochemistry in its chemical and biochemical interactions is hindered by the lack of expedient methods for preparation of pure enantiomers. This study presents one step synthesis of HNE in a cross-metathesis reaction between the commercially available oct-1-en-3-ol and acrolein in the presence of 2nd generation Grubbs catalyst. The use in the metathesis reaction of enantiomers of oct-1-en-3-ol obtained via Candida antarctica lipase resolution of the racemate allowed us to prepare of 4-(R)- and 4-(S)-enantiomers of HNE (R-1 and S-1, respectively) with excellent optical purity (97.5 and 98.4% ee, respectively) and good chemical yields (70%).
Źródło:
Acta Biochimica Polonica; 2009, 56, 1; 189-193
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Manipulation of vanillin synthesis genes in flax
Autorzy:
Pastor, M.
Boba, A.
Zuk, M.
Szopa-Skorkowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/951296.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
vanillin synthesis
flax
secondary metabolite
antifungal property
antibacterial property
antiinflammatory property
antioxidant property
oligonucleotide synthesis
DNA fragment
homologous gene
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2015, 96, 1
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reakcje i procesy katalityczne. Cz. XV a. Proces Fischera-Tropscha
Autorzy:
Sarbak, Z.
Powiązania:
https://bibliotekanauki.pl/articles/273930.pdf
Data publikacji:
2014
Wydawca:
Roble
Tematy:
reakcja katalityczna
procesy katalityczne
gaz syntezowy
synteza Fischera-Tropscha
catalytic reaction
catalytic processes
syngas
synthesis gas
Fisher-Tropsch synthesis
Źródło:
LAB Laboratoria, Aparatura, Badania; 2014, 19, 2; 16-22
1427-5619
Pojawia się w:
LAB Laboratoria, Aparatura, Badania
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Praca ważna i doniosła
A significant work
Autorzy:
Moczkodan, Rafał
Powiązania:
https://bibliotekanauki.pl/articles/451194.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Rzeszowski. Wydawnictwo Uniwersytetu Rzeszowskiego
Tematy:
emigration
Lithuania
art
synthesis
emigracja
Litwa
sztuka
synteza
Opis:
‘To save the home country from migrational distance… Lithuanian art and Lithuanian artists on emigration (1940-1990)’ (Moscow 2012) focuses on stressing the importance of the work under discussion. First and foremost, it should be pointed out that it is the first synthesis encompassing such an extensive subject, which has not thus far been examined. It is also emphasized in the review that the composition of the work as well as its abundance in content are worth noting (230 profiles of Lithuanian painters and graphic artists are presented). Additionally, we should appreciate the methodological values and the diligence of the author in research. On the other hand, the lack of illustrative material seems to be a drawback of the work. All in all, the work is highly assessed.
Źródło:
Tematy i Konteksty; 2015, 10, 5; 408-413
2299-8365
Pojawia się w:
Tematy i Konteksty
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
On implementation of FFT processor in XILINX FPGA using high-level synthesis
Autorzy:
Smyk, Robert
Czyżak, Maciej
Powiązania:
https://bibliotekanauki.pl/articles/377926.pdf
Data publikacji:
2020
Wydawca:
Politechnika Poznańska. Wydawnictwo Politechniki Poznańskiej
Tematy:
Fast Fourier Transform Processor
FPGA
high-level synthesis
Opis:
The paper presents results of the high level synthesis of an 1024-point radix-2 FFT processors in Xilinx Vivado FPGA environment. The use of various directives controlling the synthesis process is examined. The results indicate that using the proper set of directives the latency of the processor can be reduced by 95% from about 35k for the default parameters to 1.5k cycles after optimizations.
Źródło:
Poznan University of Technology Academic Journals. Electrical Engineering; 2020, 104; 17-33
1897-0737
Pojawia się w:
Poznan University of Technology Academic Journals. Electrical Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synteza układów kombinacyjnych na jednym uniwersalnym układzie PAL z wykorzystaniem montażowego łączenia wyjść
Synthesis of combinatorial logic on single PAL device using wired-or method of PAL outputs joining
Autorzy:
Solov'ev, V.
Klimowicz, A.
Powiązania:
https://bibliotekanauki.pl/articles/341115.pdf
Data publikacji:
2002
Wydawca:
Politechnika Białostocka. Oficyna Wydawnicza Politechniki Białostockiej
Tematy:
synteza logiczna
układy kombinacyjne
logic synthesis
combinatorial logic
Opis:
W artykule został opisany algorytm syntezy układów kombinacyjnych z łączeniem montażowym wyjść, dopuszczający użycie tylko jednego uniwersalnego układu PAL, a także jego modyfikacje pozwalające zastosować ten algorytm do syntezy na jednym "klasycznym" układzie PAL oraz do syntezy na jednym bloku funkcjonalnym złożonego układu programowalnego. Algorytm wykorzystuje właściwości architektury współczesnych uniwersalnych układów PAL, takie jak różna liczba linii iloczynów podłączona do jednej makrokomórki i możliwość wyboru polaryzacji sygnału wyjściowego. Określono też warunki realizacji systemu funkcji boolowskich przy pomocy tego algorytmu. Wyniki działania algorytmu porównano z innymi znanymi metodami oraz z wynikami uzyskanymi za pomocą systemu MAX+Plus II.
This article contains a description of an algorithm of synthesis of combinatorial logic schemes, which uses wired-OR method of joining outputs, limited to use only one universal PAL device and some modifications, which allow to use this algorithm to synthesis on single "classic" PAL device and one functional block of complex programmable device. This algorithm uses features of modern universal PAL devices, such as different number of terms connected to single macrocell and possibility of selection of output signal polarity. Conditions allowing to realize boolean function system using this algorithm are described. Work results are compared
Źródło:
Zeszyty Naukowe Politechniki Białostockiej. Informatyka; 2002, Z.1; 219-233
1644-0331
Pojawia się w:
Zeszyty Naukowe Politechniki Białostockiej. Informatyka
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Safety of Ammonium Dinitramide Synthesis vs. Size of a Commercial Production Scale
Autorzy:
Gołofit, T.
Maksimowski, P.
Kotlewski, A.
Powiązania:
https://bibliotekanauki.pl/articles/358124.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ADN synthesis
safety
explosion potential
increased production scale
Opis:
Ammonium dinitramide (ADN) is an ecological oxidizer suggested as a substitute for ammonium chlorate(VII) in solid rocket fuels. Three ADN synthetic methods were studied in order to estimate process safety under increased production scale, viz.: from ammonia (Method I), from urea (Method II), or from potassium sulfamate (Method III). The intermediates formed in these processes were identified and their thermal stability was examined. DSC analysis showed that the intermediates in Method II are unstable, they readily decompose and pose an explosion hazard. The intermediate in Method III is more thermally stable and less hazardous than its counterparts in Method II. The most suitable methods for large-scale processes are Methods I and III. The preferred method for commercial ADN production, in terms of safety, is Method III.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 4; 817-830
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of Iron Aluminates and a New Modification of Alumina at Impact of Explosive
Autorzy:
Apolenis, A. V.
Tsvigunov, A. N.
Annikov, V. E.
Raikova, V. M.
Powiązania:
https://bibliotekanauki.pl/articles/358543.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
alumina oxides
iron aluminates
synthesis
explosive
impact structure
Opis:
Synthesis of new high-strength superdispersed materials by use of detonation and shock waves is a developing branch of manufacture. Diamond, metal oxides, nitrides, and many other substances are produced and find industrial application. The objective of current work was the method of synthesis of iron aluminates and a new modification of alumina. For the synthesis initiation of explosion of aluminized composite explosive by impact was firstly used.
Źródło:
Central European Journal of Energetic Materials; 2008, 5, 3-4; 37-44
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization of the Synthesis Parameters and Analysis of the Impact Sensitivity for Tetrazene Explosive
Autorzy:
Li, Jin-Shuh
Chang, Chun-Chieh
Lu, Kai-Tai
Powiązania:
https://bibliotekanauki.pl/articles/358591.pdf
Data publikacji:
2020
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
tetrazene
yield
optimal synthesis parameters
Taguchi design method
Opis:
Tetrazene [1-(5-tetrazolyl)-4-guanyltetrazene hydrate] is widely used in ordnance systems as a sensitizer of primer compositions, for use in both percussion and stab applications. It can be synthesized by reacting aminoguanidinium bicarbonate (AGB) with sodium nitrite (NaNO2) in the presence of acetic acid. However, little is known about its optimal synthesis parameters in the manufacturing process. In this study, Taguchi's experimental design method was used to further improve the yield of tetrazene. Under the condition that the molar ratio of AGB to NaNO2 was fixed at 1.0:1.2, a L9(33) orthogonal array with three control factors and three levels for each control factor was used to design nine experimental conditions. The experimental data were transformed into a signal-to-noise (S/N) ratio to analyze and evaluate the experimental conditions of the optimal parameter combination for the maximum yield of tetrazene. Verification of the results indicated that the optimal synthesis parameters were as follows: pH value of AGB solution was 5.0, reaction temperature was 35 °C and reaction time was 6 h; the maximum yield of tetrazene could reach 83.7%. Furthermore, the synthesized tetrazene was identified and characterized by elemental analysis (EA), nuclear magnetic resonance spectroscopy (NMR), Fourier transform infrared spectroscopy (FTIR), optical microscopy (OM),particle size distribution analysis (PSDA), X-ray diffraction (XRD) and differential scanning calorimetry (DSC), and its impact sensitivity was determined using a BAM Fallhammer apparatus and the Bruceton analysis method.
Źródło:
Central European Journal of Energetic Materials; 2020, 17, 1; 5-19
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bio synthesis and characterization of silver nanoparticles using Lagenaria siceraria leaf extract and their antibacterial activity
Autorzy:
Anandh, B.
Muthuvel, A.
Emayavaramban, M.
Powiązania:
https://bibliotekanauki.pl/articles/412277.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
green synthesis
silver nanoparticles
Lagenaria siceraria
antibacteriala activity
Opis:
The present investigation demonstrates the formation of silver nanoparticles by the reduction of the aqueous silver metal ions during exposure to the Lagenaria siceraria leaf extract. The synthesized AgNPs have characterized by UV-visible spectroscopy, X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) techniques. AgNPs formation has screened by UV-visible spectroscopy through colour conversion due to surface plasma resonance band at 427 nm. X-ray diffraction (XRD) confirmed that the resulting AgNPs are highly crystalline and the structure is face centered cubic (fcc). FT-IR spectrum indicates the presence of different functional groups present in the biomolecules capping the nanoparticles. Further, inhibitory activity of AgNPs and leaf extract were tested against human pathogens like gram-pastive (Staphylococcus aureus, Bacillus subtilis), gram-negative (Escherichia coli and Pseudomonas aeruginosa). The results indicated that the AgNPs showed moderate inhibitory actions against human pathogens than Lagenaria siceraria leaf extract, demonstrating its antimicrobial value against pathogenic diseases.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 19, 1; 35-45
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinematic synthesis of spatial linkages with spherical pairs
Autorzy:
Kosbolov, S.
Zhauyt, A.
Powiązania:
https://bibliotekanauki.pl/articles/949116.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
mechanism
four-link
kinematic pairs
kinematic chains
synthesis
Opis:
A solution to the problem of synthesizing an initial three-dimensional kinematic chain with spherical and rotary kinematic pairs is presented. It is shown that this chain can be used as a structural module for structural-kinematic synthesis of motion of a three-dimensional four-link generating lever mechanisms by preset positions of the input and output links.
Źródło:
Journal of Theoretical and Applied Mechanics; 2016, 54, 1; 75-85
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and application of chiral triazine condensing reagents prepared from esters of amino acids.
Autorzy:
Kamiński, Zbigniew
Zając, Krzysztof
Jastrząbek, Konrad
Powiązania:
https://bibliotekanauki.pl/articles/1044064.pdf
Data publikacji:
2001
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
enantioselective reagent
coupling reagent
chiral triazines
peptide synthesis
Opis:
Treatment of cyanuric chloride with chiral amines or esters of chiral amino acids gave chiral 2,4-dichloro-6-alkylamino-1,3,5-triazines (2-5) in 49-69% yield, which were found useful as coupling reagents. Enantioselective activation and enantioselective aminolysis in the presence of 2-5 was observed.
Źródło:
Acta Biochimica Polonica; 2001, 48, 4; 1143-1146
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inhibitory effects of pentamidine analogues on protein biosynthesis in vitro.
Autorzy:
Bielawski, Krzysztof
Galicka, Anna
Bielawska, Anna
Średzińska, Krystyna
Powiązania:
https://bibliotekanauki.pl/articles/1044401.pdf
Data publikacji:
2000
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
amidine
elongation factors
protein synthesis in vitro
DAPI
Opis:
Pentamidine despite its rather high toxicity, is currently in clinical use. For development of new drugs of this type it is important to know the mechanism of their action. Two new amidines (I and II) and 4',6-diamidino-2-phenylindole (DAPI) were found in preliminary experiments to inhibit protein synthesis in vitro in the cell-free rat liver system. The three compounds differed in the precise mode of action. The inhibitory effect of I on the activity of the eukaryotic elongation factor eEF-2 and ribosomes seems to suggest that the binding site of eEF-2 on the ribosome was blocked by this compound. eEF-2 has been identified as the primary target of II and eEF-1 as the primary target of DAPI in the system studied.
Źródło:
Acta Biochimica Polonica; 2000, 47, 1; 113-120
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of kaempferide Mannich base derivatives and their antiproliferative activity on three human cancer cell lines
Autorzy:
Nguyen, Van-Son
Shi, Ling
Luan, Fang-Qian
Wang, Qiu-An
Powiązania:
https://bibliotekanauki.pl/articles/1039003.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
kaempferide
flavonoids
Mannich base derivatives
synthesis
antiproliferative activity
Opis:
Kaempferide (3,5,7-trihydroxy-4'-methoxyflavone, 1), a naturally occurring flavonoid with potent anticancer activity in a number of human tumour cell lines, was first semisynthesized from naringin. Based on Mannich reaction of kaempferide with various secondary amines and formaldehyde, nine novel kaempferide Mannich base derivatives 2-10 were synthesized. The aminomethylation occurred preferentially in the position at C-6 and C-8 of the A-ring of kaempferide. All the synthetic compounds were tested for antiproliferative activity against three human cancer cell lines (Hela, HCC1954, SK-OV-3) by the standard MTT method. The results showed that compounds 1, 2 and 5-10 were more potent against Hela cells with IC50 values of 12.47-28.24 μM than the positive control cis-platin (IC50 41.25 μM), compounds 5, 6, 8 and 10 were more potent against HCC1954 cells with IC50 values of 8.82-14.97 μM than the positive control cis-platin (IC50 29.68 μM), and compounds 2, 3, 5, 6 and 10 were more potent against SK-OV-3 cells with IC50 values of 7.67-18.50 μM than the positive control cis-platin (IC50 21.27 μM).
Źródło:
Acta Biochimica Polonica; 2015, 62, 3; 547-552
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fe-Al based composite reinforced with ultra-fine Al2O3 oxides for high temperature applications
Autorzy:
Kopec, Mateusz
Jóźwiak, Stanisław
Kowalewski, Zbigniew
Powiązania:
https://bibliotekanauki.pl/articles/2055052.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
cermet composites
reaction synthesis
powder method
electron microscopy
Opis:
In this paper, an Fe-Al based composite reinforced with ultra-fine Al2O3 oxides was obtained through sintering of aluminium, iron and mullite ceramic powders using self-propagated high temperature synthesis (SHS). The powder mixture with a 50%wt. content of the ceramic reinforcement was cold pressed and subsequently subjected to the sintering process in vacuum at 1200◦C for 25 minutes under external loading of 25 kN. The complex microstructure of the Fe-Al matrix reinforced with ultra-fine Al2O3 oxides was found to be desired in high temperature applications since only 3% of the relative weight gain was observed after 100 hours of annealing at 900◦C.
Źródło:
Journal of Theoretical and Applied Mechanics; 2021, 59, 3; 509--513
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optyczna metoda diagnostyki gazu syntezowego z biomasy
Optical Method for Biomass Syngas Monitoring
Autorzy:
Komada, P.
Cięszczyk, S.
Zhirnova, O.
Askarova, N.
Powiązania:
https://bibliotekanauki.pl/articles/1818001.pdf
Data publikacji:
2016
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
spektroskopia
gaz syntezowy
diagnostyka
spectroscopy
synthesis gas
diagnostics
Opis:
One of the methods of increasing the overall biomass share in the electricity and heat production is its gasification and subsequent co-combustion of the obtained syngas in conventional power boilers. The process of biomass gasification is relatively well controlled and understood. It does not change the fact that the syngas composition depends on many process factors, as well as the composition of the charge batch. Unfortunately, it means that the obtained product is not homogeneous in time. Consequently, the use of such fuel for electricity production may present a number of problems from the control point of view. Therefore, both during the syngas production and the co-firing process, it is advisable to use information on the composition of produced syngas, or at least its main components. It is possible to use optical methods, which are an interesting alternative to classical methods, even despite unfavorable measurement conditions. The article presents selected optical method for the synthesis gas monitoring. The results of simulation studies are presented, confirming the possibility of determining the concentration of interesting components in the syngas mixture.
Źródło:
Rocznik Ochrona Środowiska; 2016, Tom 18, cz. 2; 271-283
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A set of connection network synthesis based on the linear Diophantine constraints solution in area {0,1}
Autorzy:
Bolanowski, M.
Paszkiewicz, A.
Powiązania:
https://bibliotekanauki.pl/articles/106266.pdf
Data publikacji:
2013
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
network synthesis
linear Diophantine constraints
TSS
MTSS algorithm
Opis:
In the paper we present a method for synthesis of a set of connection networks, which fulfill the designer’s assumption. In order to do that, the designed network is presented as a system of Diophantine constraints in a special form. A method to resolve those systems is proposed, which is characterized by lower computational complexity, especially in the case of rare topologies design.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska. Sectio AI, Informatica; 2013, 13, 1; 11-21
1732-1360
2083-3628
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska. Sectio AI, Informatica
Dostawca treści:
Biblioteka Nauki
Artykuł

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