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Wyszukujesz frazę "synchronous fluorescence spectroscopy" wg kryterium: Temat


Wyświetlanie 1-5 z 5
Tytuł:
Synchronous fluorescence spectra of water contaminated by dispersed crude oil
Autorzy:
Baszanowska, Emilia
Otremba, Zbigniew
Powiązania:
https://bibliotekanauki.pl/articles/174431.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
petroleum
dispersed oil
synchronous fluorescence spectroscopy
marine environment
Opis:
The development of petroleum extraction and transport technology does not ensure complete isolation of these substances from the natural environment. This problem is exacerbated by the location of mining equipment on the sea shelf and the fact that numerous submarine pipelines, tankers and handling terminals can also emit oil pollution. Therefore, the possibility of detecting oil dispersed in the water is particularly important. This paper reports the efforts to identify methods of characterization of the water containing the crude oil emulsion in a very low concentration (a few to several tens of ppm). Due to this, the effect of emulsion concentration on the possibility of its objective characterization using synchronous fluorescence spectra was studied. The similarity of spectra at various oil concentrations was analysed. It has been shown that the stabilization of the shape of synchronous fluorescence spectra occurs at relatively low oil concentrations.
Źródło:
Optica Applicata; 2020, 50, 1; 161-169
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Description of diesel fuel based on synchronous fluorescence spectroscopy
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/242632.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
synchronous fluorescence spectroscopy
total synchronous spectra
diesel fuel
wavelength-interval
offset
fluorescencyjna spektroskopia synchroniczna
widmo synchroniczne
olej napędowy
długość fali
Opis:
The purpose of the study is spectrally characterise fuel Diesel used in diesel ship engine. For description of Diesel fuel the techniques of total synchronous fluorescence spectroscopy was applied. To characterise the oil, the spectrofluorometer ‘Aqualog Horiba’, which allows performing precise measurement in a short time, was applied to measure the excitation-emission spectra. Total synchronous fluorescence spectra of oil were obtained using various wavelength intervals basing on the measured excitation-emission spectra of Diesel fuel. Total synchronous spectra of Diesel oil are considered for several oil concentration. Synchronous fluorescence spectra were used to describe the detected maxima of Diesel fuel fluorescence by the wavelength-interval fluorescence maximum, containing information about the excitation wavelength and the wavelength-interval describing the characteristic fluorescence peak position for each considered fuel sample. That approach is discussed in relation to find a universal indicator – the wavelength-interval – as a possible tool proposed to Diesel fuel description independent from the fuel concentration. Therefore, we discuss the changes of the total synchronous fluorescence spectra for different oil concentration. Obtained results indicate that the best indicator for this kind of oil characterisation seems to be the wavelength-interval for 60 nm due to the independence of the synchronous spectra from the oil concentration.
Źródło:
Journal of KONES; 2017, 24, 1; 39-45
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zastosowanie fluorescencyjnej spektroskopii synchronicznej do oceny jakości próbek ziarna pszenicy i nasion rzepaku
Application of synchronous scanning fluorescence spectroscopy to analysis quality of wheat grain and rapeseed samples
Autorzy:
Tańska, M.
Konopka, I.
Smyk, B.
Konopka, S.
Powiązania:
https://bibliotekanauki.pl/articles/271121.pdf
Data publikacji:
2013
Wydawca:
Centralny Ośrodek Badawczo-Rozwojowy Aparatury Badawczej i Dydaktycznej, COBRABiD
Tematy:
pszenica
rzepak
fluorescencyjna spektroskopia synchroniczna
analiza składowych głównych
wheat
rapeseed
synchronous scanning fluorescence spectroscopy
principal component analysis
Opis:
Celem prezentowanych badań było określenie możliwości zastosowania synchronicznej fluorescencji do odróżniania próbek ziarna pszenicy oraz nasion rzepaku różniących się jakością. Ocenie poddano próbki ziarna/nasion „zdrowych" oraz eksperymentalnie uszkodzonych termicznie (przesuszenie) i hydrolityczno-mikrobiologicznie (przechowywanie w warunkach podwyższonej wilgotności). Jakość kontrolnych próbek ziarna pszenicy i nasion rzepaku oceniono za pomocą standardowych wyróżników technologicznych oraz za pomocą analizy zawartości wybranych związków bioaktywnych (kwasy fenolowe, toko- chromanole, chlorofile). Wszystkie próbki poddano analizie spektralnej wykorzystując rejestrację synchroniczną widm fluorescencji. Zastosowanie analizy składowych głównych (PCA) pozwoliło na wskazanie głównych obszarów spektralnych wskazujących na różne typy (jakość) analizowanych próbek. Zastosowane warianty uszkodzenia ziaren/nasion bardziej wpłynęły na próbki nasion rzepaku.
The aim of this study was to determine the possibility of using synchronous fluorescence to distinguish the wheat grain and rapeseed samples of different quality. We compared "healthy" grain/seed samples and experimentally damaged by heat (drying) and moisture-microbial deteriorated by storing at high moisture content. Quality of control samples was evaluated using standard methods according to Polish Standards. Additionally some selected bioactive compounds (phenolic acids, tocochromanols and chlorophylls) were also analyzed. All samples were subjected to spectral analyses using synchronous fluorescence spectroscopy. Application of principal component analysis (PCA) allowed us to identify the main areas indicating different spectral types (quality) of the analyzed samples. Utilized variants of the grains/seeds deterioration affected more significantly the rapeseed samples quality.
Źródło:
Aparatura Badawcza i Dydaktyczna; 2013, 18, 4; 355-363
2392-1765
Pojawia się w:
Aparatura Badawcza i Dydaktyczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Testing of the synchronous fluorescence in application to used lubricate oil characterisation
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/243560.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine fleet exploitation
lubricate oil
fluorescence spectroscopy
synchronous fluorescence spectra
Opis:
Reliability of the ship propulsion system depends, inter alia, on the quality of lubricate oils. Research indicates that exploitive features of oil are reduced with it runtime in the ship engine circuit. At the present the basic parameters representing exploitive features of oil are: water content, total acid number and total base number or viscosity vs. temperature, anti-wear performance, further: content of additives and their concentrations, reaction products, and other contaminating substances, also magnetically separated large ferromagnetic particles, the size, the shape, the composition and concentration of the abnormal wear particles. Additional properties of oil are described based on atomic emission spectroscopy, granulometry of separated from the lubricant sample by magnets and gravity, permeability changes, as well as rheometric and tribometric characteristics. Complexity of composition of lubricate oil raises the idea to use changes of relative content of any compounds for characterization of oil exploitive features. Fluorescence method is possible to use for oil properties characterisation due to the presence mono and polycyclic compounds in oil that induces fluorescence phenomenon. Therefore identification the fluorescence spectra when exploitation time of oil increases could be novel indicator to monitor of lubricate oil exploitive quality. In this study we present changes of oil fluorescence expressed by synchronous spectra, taking into account working time of exemplary lubricate oil in the ship engine.
Źródło:
Journal of KONES; 2016, 23, 2; 39-44
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oil identification based on total synchronous spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246342.pdf
Data publikacji:
2014
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fluorescence spectroscopy
total synchronous spectra
lubricate oil
vessel engine room
marine environment
Opis:
Contribution of marine carriage in the global transport is in permanent developing. It leads to increase the unintentional oil spills, which may induce serious disturbances in functioning of the natural marine ecosystem, especially when it interferes with other technical activities in the marine space. That fact contributes to increase the interest in searching of new research techniques to protect the natural ecosystem. Therefore, the main task of marine international organisations concentrates on the effective and rapid detection of oil spill and on the possibility of identifying oil pollutants as well as on origin of pollution. The purpose of the study is to characterise the oil belonging to the vessel engine lubricate oils. We analyse the stage results of investigations based on one of types of fluorescence spectroscopy, namely: synchronous spectra. To characterise the oil, the Aqualog Horiba spectrofluorometer was applied, which allows performing precise measurement in a short time. Based on the measured excitation-emission spectra, total synchronous fluorescence spectra for oil were obtained using various wavelength intervals. Total synchronous fluorescence spectra of petroleum substances allow finding wavelength interval typical for particular type of oil. This approach could allow obtaining of complex mixtures, such as oils, more efficient description. We discuss the total synchronous fluorescence spectra for engine oil (Marinol type) dissolved in n-hexane in various concentrations of oil as a possible tool proposed to oil type identification. We present changes and variation of the total synchronous fluorescence spectra for oil with various oil concentrations.
Źródło:
Journal of KONES; 2014, 21, 2; 15-20
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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