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Tytuł:
Zastosowanie siatki dyfrakcyjnej do pomiaru zawartości biokomponentów w paliwach
Applied diffraction grating for determine the content of biocomponents of fuels
Autorzy:
Polińska, A.
Powiązania:
https://bibliotekanauki.pl/articles/157376.pdf
Data publikacji:
2006
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
biodiesel
absorption spectrophotometry
RME
Opis:
W artykule przedstawiono analizę wyników pomiarów zawartości biokomponentów w postaci estrów metylowych kwasów karboksylowych oleju rzepakowego (RME - Rapeseed oil Methyl Ester) w oleju napędowym. Zgodnie z obowiązującymi normami zastosowana została metoda spektrofotometrii w podczerwieni IR. Do oceny ilościowej wykorzystano prawo Lamberta-Beera. W torze pomiarowym do ustawienia analitycznej długości fali (5,73 žm) zastosowana została siatka dyfrakcyjna z regulowaną szerokością szczeliny. Przeanalizowany został wpływ szerokości szczeliny w siatce na dokładność wyników pomiaru.
The paper presents analysis of the measurement results of the content of biocomponents - rapeseed oil methyl esters (RME) in diesel oil. Up to mandatory standard as a method of analysis concentration RME of biodiesel infrared absorption spectroscopy IR was used. The quantitative determinations of the contents of biocomponents from the absorption spectra are based on the Lambert and Beer law. In slotted section to set analytical wavelength (5,73 žm) diffraction grating with regulate width gap was applied. Width gap effect was analysed.
Źródło:
Pomiary Automatyka Kontrola; 2006, R. 52, nr 7/8, 7/8; 13-15
0032-4140
Pojawia się w:
Pomiary Automatyka Kontrola
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oleje mineralne - metody oznaczania
Autorzy:
Kijeńska, D.
Powiązania:
https://bibliotekanauki.pl/articles/180126.pdf
Data publikacji:
2000
Wydawca:
Centralny Instytut Ochrony Pracy
Tematy:
oleje mineralne
spektrofotometria absorpcyjna
spektrofotometria w podczerwieni
mineral oils
absorption spectrophotometry
IR spectrophotometry
Źródło:
Bezpieczeństwo Pracy : nauka i praktyka; 2000, 11; 24-25
0137-7043
Pojawia się w:
Bezpieczeństwo Pracy : nauka i praktyka
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A green method for the removal of Zinc(II) ions from wastewater using modifed biopolymers
Autorzy:
Jeyaseelan, Christine
Jain, Antil
Jugade, Ravin
Powiązania:
https://bibliotekanauki.pl/articles/2131501.pdf
Data publikacji:
2021
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
Adsorption
modified chitosan
spectrophotometry
zinc(II)
Opis:
Zinc pollution in wastewater is a global problem because it is highly toxic. Zinc is commonly used in industries that transfer the water containing zinc directly into water sources, leading to pollution. Exposure to a high level of zinc causes major health problems. This study evaluated the adsorption of zinc ions from aqueous system using modified biopolymers of chitosan by crosslinking with sulphates using the batch adsorption method; the concentration was determined using atomic absorption spectrophotometry. The sulphate cross-linked chitosan (SCC) was characterised by several method. The effects of various experimental parameters such as pH, contact time, concentration, adsorbent dosage and temperature were investigated. Under the optimised conditions, the percentage efficiency for the removal of zinc(II) was up to 85%. Freundlich and Langmuir isotherms were used to analyse the equilibrium adsorption data along with kinetic studies. Various thermodynamic parameters have also been reported.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2021, 26; 101-111
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
2-(4-Diethylaminostyryl)-1,3,3-trimethyl-5-thiocyanato-3H-indolium chloride as a new reagent for indirect spectrophotometric red-ox determination of Osmium (VI)
Autorzy:
Kormosh, Z.
Korolchuk, S.
Powiązania:
https://bibliotekanauki.pl/articles/779698.pdf
Data publikacji:
2008
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
osm
oznaczanie
spektrofotometria
osmium
determination
spectrophotometry
Opis:
A highly sensitive indirect spectrophotometric redox method for the determination of osmium is reported on. The method is based on the oxidation of iodide by osmium (VI) and the spectrophotometric detection of the liberated iodine in the form of complex anion associate with 2-(4-diethylaminostyryl)-1,3,3-trimethyl-5-thiocyanato-3H-indolium chloride reagent. The appropriate reaction conditions have been established. The molar absorptivity is (0.2-1.2)ź10^5 dm3/molźcm at 589.5 nm wavelength. The absorbance of the coloured extracts obeys the Beer's law in the range to 7.6 mg/dm3 of Os(VI).
Źródło:
Polish Journal of Chemical Technology; 2008, 10, 2; 17-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanism of peroxynitrite interaction with cytochrome c.
Autorzy:
Gębicka, Lidia
Didik, Joanna
Powiązania:
https://bibliotekanauki.pl/articles/1043459.pdf
Data publikacji:
2003
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
cytochrome c
radiolysis
peroxynitrite
stopped-flow spectrophotometry
Opis:
Kinetics of the reaction of peroxynitrite with ferric cytochrome c in the absence and presence of bicarbonate was studied. It was found that the heme iron in ferric cytochrome c does not react directly with peroxynitrite. The rates of the absorbance changes in the Soret region of cytochrome c spectrum caused by peroxynitrite or peroxynitrite/bicarbonate were the same as the rate of spontaneous isomerization of peroxynitrite or as the rate of the reaction of peroxynitrite with bicarbonate, respectively. This means that intermediate products of peroxynitrite decomposition, ·OH/·NO2 or, in the presence of bicarbonate, CO3-·/·NO2, are the species responsible for the absorbance changes in the Soret band of cytochrome c. Modifications of the heme center of cytochrome c by radiolytically produced radicals, ·OH, ·NO2 or CO3-·, were also studied. The absorbance changes in the Soret band caused by radiolytically produced ·OH or CO3-· were much more significant that those observed after peroxynitrite treatment, compared under similar concentrations of radicals. ·NO2 produced radiolytically did not interact with the heme center of cytochrome c. Cytochrome c exhibited an increased peroxidase-like activity after reaction with peroxynitrite as well as with radiolytically produced ·OH, ·NO2 or CO3-· radicals. This means that modification of protein structure: oxidation of amino acids and/or tyrosine nitration, facilitates reaction of H2O2 with the heme iron of cytochrome c, followed by reaction with the second substrate.
Źródło:
Acta Biochimica Polonica; 2003, 50, 3; 815-823
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badanie przebiegu procesów deemulgacji za pomocą metod spektrofotometrycznych
Investigations on the course of de-emulsification processes using spectrophotometry methods
Autorzy:
Sęk, J.
Głębała, D.
Powiązania:
https://bibliotekanauki.pl/articles/2071861.pdf
Data publikacji:
2012
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
emulsja
deemulgacja
spektrofotometria
emulsion
de-emulsification
spectrophotometry
Opis:
W pracy przedstawiono badania dotyczące zagadnienia procesu rozwarstwiania się układów emulsyjnych. Dokonano porównania wpływu różnego stężenia deemulgatora dodanego do emulsji O/W na proces deemulgacji. Do rozważań wykorzystano emulsję olej w wodzie o stężeniu 6%, ponieważ takie emulsje mają praktyczne zastosowanie w przemyśle oraz występują w oczyszczalniach ścieków. Do obserwacji rozwarstwienia się faz w emulsji użyto metod spektrofotometrycznych.
The paper deals with the investigations into de-emulsification process. An influence of de-emulsifying agent amount was studied and changes in time of emulsion concentrations were recorded. Oil-in-water emulsions of 6% concentration were used as experimental media. Such emulsions have a practical application in industry and wastewater treatment plants. Separation of phases was observed using spectrophotometric methods.was
Źródło:
Inżynieria i Aparatura Chemiczna; 2012, 6; 381-382
0368-0827
Pojawia się w:
Inżynieria i Aparatura Chemiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ocena metod monitoringu stężeń siarkowodoru w powietrzu
Evaluation of methods for monitoring air concentrations of hydrogen sulfide
Autorzy:
Janoszka, Katarzyna
Wziątek, Agata
Gromiec, Jan P.
Powiązania:
https://bibliotekanauki.pl/articles/2166782.pdf
Data publikacji:
2014-11-03
Wydawca:
Instytut Medycyny Pracy im. prof. dra Jerzego Nofera w Łodzi
Tematy:
siarkowodór
spektrofotometria
powietrze
hydrogen sulfide
spectrophotometry
air
Opis:
Rozwój różnych gałęzi przemysłu oraz wydobywanie na coraz większą skalę kopalin powoduje wzrost stężenia produktów ubocznych w powietrzu atmosferycznym. Substancjami zanieczyszczającymi powietrze są m.in.: CO, CO₂, SO₂, SO₃, H₂S, tlenki azotu oraz związki pochodzenia organicznego. Celem niniejszej publikacji jest przegląd i ocena metod monitoringu stężeń siarkowodoru w powietrzu. Różne techniki instrumentalne, m.in. elektrochemiczne, chromatograficzne, spektrofotometryczne (mokre i suche), omówiono pod względem ich przydatności do monitorowania niskich stężeń siarkowodoru (H₂S), zbliżonych do jego progu zapachowego. Na podstawie przeprowadzonego przeglądu do badań H₂S w powietrzu wybrano metodę polegającą na pochłanianiu w wodnym roztworze octanu cynku oraz reakcji z N,N-dimetylo-p-fenylodiaminą i chlorkiem żelaza(III), przeprowadzono też wstępne badania walidacyjne. Zaadaptowana metoda umożliwia oznaczanie stężeń siarkowodoru w środowisku pracy i powietrzu atmosferycznym w stężeniach bliskich progowi zapachowemu. Med. Pr. 2013;64(3):449–454
The development of different branches of industry and a growing fossil fuels mining results in a considerable emission of by-products. Major air pollutants are: CO, CO₂, SO₂, SO₃, H₂S, nitrogen oxides, as well as compounds of an organic origin. The main aspects of this paper is to review and evaluate methods used for monitoring of hydrogen sulfide in the air. Different instrumental techniques were discussed, electrochemical, chromatographic and spectrophotometric (wet and dry), to select the method most suitable for monitoring low levels of hydrogen sulfide, close to its odor threshold. Based on the literature review the method for H₂S determination in the air, involving absorption in aqueous zinc acetate and reaction with N,N-dimethylo-p-phenylodiamine and FeCl₃, has been selected and preliminary verified. The adopted method allows for routine measurements of low concentration of hydrogen sulfide, close to its odor threshold in workplaces and ambient air. Med Pr 2013;64(3):449–454
Źródło:
Medycyna Pracy; 2013, 64, 3; 449-454
0465-5893
2353-1339
Pojawia się w:
Medycyna Pracy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Remarks on spectra-photometric monitoring of urea in dialysate
Autorzy:
Filutowicz, Z.
Łukaszewski, K.
Pieszyński, K.
Powiązania:
https://bibliotekanauki.pl/articles/333345.pdf
Data publikacji:
2004
Wydawca:
Uniwersytet Śląski. Wydział Informatyki i Nauki o Materiałach. Instytut Informatyki. Zakład Systemów Komputerowych
Tematy:
monitorowanie dializ
mocznik
spektrofotometria
dialysis monitoring
urea
spectrophotometry
Opis:
The authors try to explain why the direct, spectra-photometric examination of urea content in dialysate is practically ineffective (in UV-VIS range of spectrum) despite the fact that, in general, spectra-photometry is valuable and very sensitive method of chemical composition determination. An attempt was made to prove that spectra-photometric monitoring of urea dialysis, in chosen parts of UV-VIS spectrum, can be achieved only through indirect measurements.
Źródło:
Journal of Medical Informatics & Technologies; 2004, 8; MM105-110
1642-6037
Pojawia się w:
Journal of Medical Informatics & Technologies
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrophotometric Analysis of the Kinetic of Pd(II) Chloride Complex Ions Sorption Process from Diluted Aqua Solutions Using Commercially Available Activated Carbon
Autorzy:
Wojnicki, M.
Powiązania:
https://bibliotekanauki.pl/articles/354034.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
palladium
recovery
recycling
adsorption
sorption
chloride ions
spectrophotometry
Opis:
In this paper, results of adsorption kinetic studies of Pd(II) chloride complex ions on activated carbon Organosrob 10 CO are presented. Spectorphotometrical method was applied to investigate the process. Kinetic model was proposed, and fundamental thermodynamic parameters were determined. Proposed kinetic model describes well observed phenomenon in the studied range of concentration of Pd(II) chloride complex ions as well, as concentration of activated carbon.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 4; 2405-2411
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of molding conditions on the quality of geopolymer surfaces
Autorzy:
Jaglarz, Janusz
Wyszyński, Dominik
Lach, Michał
Mikuła, Janusz
Duraj, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/173702.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
surface topography
bidirectional reflectance distribution function
ellipsometry
spectrophotometry
Opis:
The presented work describes the method of measuring surface topography with application of BRDF (bidirectional reflectance distribution function), ellipsometry and spectrophotometry. This non-contact method enables measurement and analysis of large area surfaces, such as plasters and facades. A standard method of topography analysis does not describe sufficiently all of the interesting features. The visual aspect of the surface evaluation is very important from the functional and utilitarian point of view. The proposed methods of surface analysis enable not only the quantitative evaluation but also indirectly the qualitative properties (visual aspects).
Źródło:
Optica Applicata; 2020, 50, 1; 135-146
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sensitive and selective extraction-free spectrophotometric determination of quetiapine fumarate in pharmaceuticals using two sulphonthalein dyes
Autorzy:
Rajendraprasad, N.
Basavaiah, K.
Vinay, K.B.
Powiązania:
https://bibliotekanauki.pl/articles/3032.pdf
Data publikacji:
2010
Wydawca:
Instytut Medycyny Wsi
Tematy:
extraction
spectrophotometry
determination
quetiapine fumarate
drug
sulphonthalein dye
Źródło:
Journal of Pre-Clinical and Clinical Research; 2010, 04, 1
1898-2395
Pojawia się w:
Journal of Pre-Clinical and Clinical Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of magnetic nanoparticles for water treatment
Autorzy:
Marcinkowska, D.
Powiązania:
https://bibliotekanauki.pl/articles/134736.pdf
Data publikacji:
2016
Wydawca:
ADVSEO
Tematy:
magnetic nanoparticles
water treatment
cyclodextrins
maghemite
absorption spectrophotometry
Opis:
In this study magnetic nanoparticles were fabricated and used for water treatment. Nanoparticles were prepared in two ways. The first one involved NiZn ferrite nanoparticles synthesized by co-precipitation of metal cations with sodium hydroxide at high temperature. The second one featured maghemite nanoparticles was prepared by salt-assisted solid-state reaction. Modification and functionalization of nanoparticles surface was investigated. Nanoparticles were characterized by scanning electron microscopy (SEM). Modified nanoparticles were added to the solution of desired concentration of methylene green. Adsorption ability was examined trough ultraviolet-visible spectroscopy (UV-VIS). For NiZn ferrite and also for maghemite nanoparticles results were positive. Both of complexes can be used for water treatment with 51% success for maghemite and 72% for NiZn ferrite nanoparticles.
Źródło:
Technical Issues; 2016, 2; 33-38
2392-3954
Pojawia się w:
Technical Issues
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The attempts to identify the sources of the emission of phenol compounds in the Upper Dunajec catchment
Próby ustalenia źródeł emisji związków fenolowych w zlewni górnego Dunajca
Autorzy:
Michałowski, M.
Powiązania:
https://bibliotekanauki.pl/articles/385847.pdf
Data publikacji:
2011
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
Dunajec
fenole
zanieczyszczenie wody
spektrofotometria
phenols
water pollution
spectrophotometry
Opis:
Dunajec – a river in south Poland, together with the San River, is the most important right-bank tributary of the Vistula River. It flows into the Vistula River at its 160.6 km. The Upper Dunajec area starts at the spring and ends at the mouth of the Ochotnica stream (including the stream itself). The catchment of the upper Dunajec is placed in two districts: Tatrzański and Nowotarski. It is very important to keep the catchment as clean as possible due to the fact that it supplies both districts with drinkable water. The goal of my paper was to find out to what extent the upper Dunajec catchment was contaminated with phenols. All contaminants in water mostly come from chemical substances, bacteria and other microorganisms that are present in natural waters in huge amounts. These contaminants are permanent and resistant towards chemical or biochemical processes that are supposed to purify the water. Phenol and its derivatives are very toxic, ones of the most burdensome compounds for the environment. Sources of phenol compounds emission can be divided into two groups: of natural and of anthropogenic origin, i.e. resulting from human activity in industry, agriculture as well as in tourism. The most dangerous substances that cause contamination of water with phenols are wastewaters coming from plastics, paint pigments, varnish or glue factories and from pharmaceutical companies. Municipal wastewaters tend to contaminate water with phenols as well, however to smaller extent. Phenol and its derivatives are widely used in many branches of industry as well as in agriculture. In order to mark phenol concentrations, I applied the photometric method.
Dunajec, rzeka w południowej Polsce, jest obok Sanu najważniejszym prawobrzeżnym dopływem Wisły. Górny Dunajec rozciąga się od źródeł do ujścia potoku Ochotnica. Zlewnia górnego Dunajca znajduje się na terenie dwóch powiatów: tatrzańskiego oraz nowotarskiego. Bardzo ważne jest utrzymanie w jak największej czystości tej zlewni, gdyż dostarcza ona wody pitnej dla obu powiatów. Celem pracy było oznaczenie stopnia zanieczyszczenia związkami fenolowymi zlewni górnego Dunajca. Nieczystości te są trwałe i odporne na działanie procesów chemicznych czy też biochemicznych służących oczyszczeniu wód. Fenol i jego pochodne są związkami o dużej toksyczności, należą do substancji najbardziej uciążliwych dla otoczenia. Źródła emisji związków fenolowych dzielimy na dwie grupy: pochodzenia naturalnego oraz pochodzenia antropogenicznego, czyli będące wynikiem działalności człowieka w przemyśle, rolnictwie czy też turystyce. Najważniejszymi emitorami związków fenolowych do wód są ścieki z fabryk tworzyw sztucznych, barwników, farb, lakierów czy klejów oraz z zakładów farmaceutycznych. W mniejszym stopniu wprowadzane są do wód ze ściekami komunalnymi. Fenol oraz jego pochodne mają szerokie zastosowanie w bardzo wielu gałęziach przemysłu, a także w rolnictwie. Do oznaczenia stężeń fenoli wykorzystano metodę fotometryczną.
Źródło:
Geomatics and Environmental Engineering; 2011, 5, 1; 85-102
1898-1135
Pojawia się w:
Geomatics and Environmental Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New spectrophotometric methods for the determination of nifedipine in pharmaceutical formulations
Autorzy:
Rahman, Nafisur
Azmi, Syed
Powiązania:
https://bibliotekanauki.pl/articles/1041343.pdf
Data publikacji:
2005
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
pharmaceutical formulations
spectrophotometry
potassium hydroxide
validation
nifedipine
ammonium molybdate
Opis:
Two simple, sensitive and economical spectrophotometric methods were developed for the determination of nifedipine in pharmaceutical formulations. Method A is based on the reaction of the nitro group of the drug with potassium hydroxide in dimethyl sulphoxide (DMSO) medium to form a coloured product, which absorbs maximally at 430 nm. Method B uses oxidation of the drug with ammonium molybdate and subsequently reduced molybdenum blue is measured at 830 nm. Beer's law is obeyed in the concentration range of 5.0-50.0 and 2.5-45.0 µg ml-1 with methods A and B, respectively. Both methods have been successfully applied for the assay of the drug in pharmaceutical formulations. No interference was observed from common pharmaceutical adjuvants. The reliability and the performance of the proposed methods are established by point and interval hypothesis tests and through recovery studies.
Źródło:
Acta Biochimica Polonica; 2005, 52, 4; 915-922
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
DETERMINATION OF FLUOXETINE HYDROCHLORIDE VIA ION PAIR COMPLEXATION WITH ALIZARIN RED S
Autorzy:
Clementina, Constantinescu I.
Alexandra, Neagu F.
Valentina, Uivarosi
Powiązania:
https://bibliotekanauki.pl/articles/895425.pdf
Data publikacji:
2018-12-31
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
spectrophotometry
Alizarin Red S
fluoxetine hydrochloride
ion pair
fluorimetry
Opis:
Two UV-Vis spectrophotometric methods and one fluorimetric method have been developed for the quantitative determination of fluoxetine hydrochloride in bulk and pharmaceutical formulations. These methods are based on the ion pair complex formation between alizarin red S and fluoxetine hydrochloride. In the first method (method A), the yellow-coloured complex obtained in acidic medium was extracted with chloroform, and the absorbance of chloroformic solution was measured at 425 nm. Beer’s law limits (9.5 – 48 µg/mL), the molar absorptivity (5256 L · mol-1· cm-1), and the complex composition (1:1) were determined. In the second method (method B), the yellow complex fluoxetine – alizarin red S extracted in chloroform was broken in alkaline medium, and the absorbance of the resulting violet-coloured free dye was measured at 524 nm. A linear relationship was observed in the range 9.0 – 54 µg/mL. In the third method (method C) the fluorescence intensity of the fluoxetine – alizarin red S complex, obtained in the same manner as for method A, was measured at 594 nm after excitation at 425 nm. The fluorescence intensity was proportional to the drug concentration in the linear range of 2.7-10.2 µg/mL. The limits of detection and quantification have also been calculated. Furthermore, the proposed methods have been successfully applied for the assay of the drug in pharmaceutical dosage forms.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2018, 75, 6; 1293-1303
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extractive Spectrophotometric Determination of Pd(II) with Sodium salt of hexamethyleneiminecarbodithioate
Autorzy:
Dhanavate, S. D.
Garole, D. J.
Garole, V. J.
Tetgure, S. R.
Sawant, A. D.
Powiązania:
https://bibliotekanauki.pl/articles/412252.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
palladium
sodium hexamethyleneiminecarbodithioate
Extractive Spectrophotometry
synthetic mixture
Real Samples
Opis:
The reagent NaHMICdt•2H2O has found to be a good chelating agent for the spectrophotometric determination of various metal ions. The present investigation deals with spectrophotometric determination of Pd(II) by using NaHMICdt•2H2O. The reagent reacted with Pd(II) to give yellow complex extractable into toluene. Pd (II) was extracted quantitatively in the pH range 0.5-2.0. Pd(II)-HMICdt complex showed λmax at 435 nm. The extracted species has a 1:2 (M:L) stoicheometry. Beer’s law is obeyed in the range of 0.2-0.8 μg ml-1 of Pd (II). The molar absorptivity and the sandells sensitivity were found to be 0.754 x 104 lmol-1cm-1 and 0.0140 μg mol-1 cm-2 respectively. The effect of divers ion on the extraction of Pd(II) has been investigated. The proposed method is highly sensitive, selective, and simple and rapid has been applied for accurate determination of palladium in synthesis mixtures and real samples.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 4; 20-28
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Measurement data processing in spectrophotometric analysers of food. Review paper
Autorzy:
Morawski, R. Z.
Powiązania:
https://bibliotekanauki.pl/articles/221182.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spectrophotometry
chemometrics
spectral data processing
food analysis
wine analysis
Opis:
Spectrometry, especially spectrophotometry, is getting more and more often the method of choice not only in laboratory analysis of (bio)chemical substances, but also in the off-laboratory identification and testing of physical properties of various products, in particular - of various organic mixtures including food products and ingredients. Specialised spectrophotometers, called spectrophotometric analysers, are designed for such applications. This paper is on the state of the art in the domain of data processing in spectrophotometric analysers of food (including beverages). The following issues are covered: methodological background of food analysis, physical and metrological principles of spectrophotometry, the role of measurement data processing in spectrophotometry. General considerations are illustrated with examples, predominantly related to wine and olive oil analysis.
Źródło:
Metrology and Measurement Systems; 2012, 19, 4; 623-652
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biological Approach for the Synthesis and Characterization of Zinc Oxide Nanopaticles from Croton bonplandianum Baill. Extracts
Autorzy:
Manokari, M.
Shekhawat, Mahipal S.
Powiązania:
https://bibliotekanauki.pl/articles/1112329.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Croton bonplandianum
Plant extracts
UV-Visible spectrophotometry
Zinc oxide nanoparticles
Opis:
The biogenesis of nanoparticles recently gained more attention. Here, we report the biogenesis of zinc oxide (ZnO) nanoparticles using aqueous extracts of the leaves, stem, root, flowers and fruits of Croton bonplandianum Baill. at room temperature. Croton bonplandianum is an important medicinal plant used to cure many pathological conditions in the traditional systems of Indian medicines due to the presence of important and specific bioactive compounds in the plant parts of this plant. Aqueous solution of Zinc Nitrate hexahydrate [Zn(NO3)2·6H2O] was used as a precursor and the various plant extracts played as reducing agents. The formation of ZnO nanoparticles was monitored by UV-Visible spectrophotometric analysis. The leaf extract showed strong absorbance peak at 302 nm, stem and fruit at 293 nm, root at 290 nm and flowers at 305 nm.
Źródło:
World News of Natural Sciences; 2018, 19; 95-107
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of humic substances on results of the spectrophotometric (TPTZ) analysis of monosaccharides
Autorzy:
Grzybowski, W.
Dudzinska, M.
Powiązania:
https://bibliotekanauki.pl/articles/48161.pdf
Data publikacji:
2004
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
monosaccharide analysis
aquatic substance
humic substance
spectrophotometry
water
Gdansk Gulf
Opis:
A spectrophotometric method of monosaccharide analysis was assessed with regard to its non-selectivity towards humic substances. Analysis of model solutions showed that it responds positively to both marine and terrestrial humics. The systematic error in monosaccharide analysis (in glucose equivalents) was 0.18–0.20mg per 1 mg of Aldrich humic acid and 0.11–0.12 mg per 1 mg of humic substances isolated from Gulf of Gdańsk water.
Źródło:
Oceanologia; 2004, 46, 3
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of structure and properties of membrane active substance on analytical performance of ion-selective electrodes
Autorzy:
Wardak, Cecylia
Grabarczyk, Małgorzata
Lenik, Joanna
Powiązania:
https://bibliotekanauki.pl/articles/110902.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
ion-selective electrode
acidic chelating ionophore
PVC membrane
potentiometry
spectrophotometry
Opis:
The potential creating properties of a group of acidic chelating compounds are presented. The studies have been carried out by the constructing of new ion-selective electrodes based on PVC membranes doped with the studied compounds, and determining the basic analytical parameters of the electrodes. The usefulness of eight out of nine investigated compounds in the preparation of the membrane phase electrodes selective for cobalt, zinc and cadmium has been shown. It has been also found that the acidic properties of ionophore have an essential influence on the analytical parameters of the constructed electrodes. The response mechanism of the obtained electrodes has been investigated by simultaneous spectrophotometric-potentiometric measurement of membranes used in electrodes. It has been found that during the conditioning of electrode, a complex of active substance with primary ion is formed in the membrane phase, then the membrane composition is established and remains unchanged in the next measurements.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1413-1421
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Status Assessment of Heavy Metals in Water of the Lepenci River Basin, Kosova
Autorzy:
Bytyçi, P.
Fetoshi, O.
Durmishi, B. H.
Etemi, F. Z.
Çadraku, H.
Ismaili, M.
Abazi, A. S.
Powiązania:
https://bibliotekanauki.pl/articles/123080.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
atomic absorption spectrophotometry
river water
heavy metals
WQI
quality
correlation
Opis:
Water represents an essential element for life and living things on earth. Aquatic ecosystems play a decisive role in the socio-economic development in urban and rural areas. In recent decades, there has been concern at the global level with regard to the deterioration of aquatic ecosystems due to the pollution, which is a product of mainly anthropogenic activity. Heavy metals pollution is worrisome for the ecological balance of the aquatic environment, affecting a variety of organisms. Therefore, the objective of this paper was to characterize the quality of water in the Lepenci River basin, to express heavy metals concentration, and to determine the surface water quality index in this basin. In order to achieve such an objective, water samples were collected at eight stations for analyzing the concentrations for heavy metals. Heavy metals were determined by means of atomic absorption spectrophotometry. A good correlation was found between Pb and Zn (r = 0.84), whereas the average negative correlation coefficient was shown between Mn and Cr (r = -0.6513). The heavy metals concentrations varied from 0.0092 to 0.1135 mg/L.The mean concentrations of heavy metals found in the river water were in the order of: Mn > Fe > Pb > Ni > Cd > Zn > Cr > Cu. The Water Quality Index varied from 57 to 81, with the average value of WQI = 68.1250, which ranks the surface water of this basin as fair. From the results we have concluded that the Lepenci River waters during the monitoring period have had low pollution from heavy metals.
Źródło:
Journal of Ecological Engineering; 2018, 19, 5; 19-32
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of five SVD-based algorithms for calibration of spectrophotometric analyzers
Autorzy:
Wagner, J.
Morawski, R. Z.
Miękina, A.
Powiązania:
https://bibliotekanauki.pl/articles/220564.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spectrophotometry
chemometrics
singular value decomposition
regularisation
food analysis
edible oils analysis
Opis:
Spectrophotometry is an analytical technique of increasing importance for the food industry, applied i.a. in the quantitative assessment of the composition of mixtures. Since the absorbance data acquired by means of a spectrophotometer are highly correlated, the problem of calibration of a spectrophotometric analyzer is, as a rule, numerically ill-conditioned, and advanced data-processing methods must be frequently applied to attain an acceptable level of measurement uncertainty. This paper contains a description of four algorithms for calibration of spectrophotometric analyzers, based on the singular value decomposition (SVD) of matrices, as well as the results of their comparison - in terms of measurement uncertainty and computational complexity - with a reference algorithm based on the estimator of ordinary least squares. The comparison is carried out using an extensive collection of semi-synthetic data representative of trinary mixtures of edible oils. The results of that comparison show the superiority of an algorithm of calibration based on the truncated SVD combined with a signal-to-noise ratio used as a criterion for the selection of regularisation parameters - with respect to other SVD-based algorithms of calibration.
Źródło:
Metrology and Measurement Systems; 2014, 21, 2; 191-204
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Quantification of synthetic food dyes in beverages or pharmaceutical tablets by solid phase extraction (SPE) followed by UV/VIS spectrophotometry
Autorzy:
Sobańska, A. W.
Jakubczyk, P.
Pyzowski, J.
Brzezińska, E.
Powiązania:
https://bibliotekanauki.pl/articles/105606.pdf
Data publikacji:
2018
Wydawca:
Centrum Badań i Innowacji Pro-Akademia
Tematy:
food dyes
quantification
SPE
VIS spectrophotometry
barwniki spożywcze
kwantyfikacja
VIS
spektrofotometria
Opis:
Synthetic food dyes (E102, E104, E110, E122, E124, E132, E133) were concentrated by solid phase extraction on aminopropyl modified silica with aqueous sodium hydroxide or selected amines as eluents. Ponceau 4R (E124) was used as the model dye in the studies of the elution step. The recoveries of E124 differed depending on the eluent and ranged from 76% (AMP) to over 90% (TEA, imidazole, NaOH). Diluted aqueous triethanolamine (TEA) was found to be a suitable eluent for E124 but other dyes were eluted more effectively with NaOH. The solid extraction process was combined with UV/VIS spectroscopy to quantify synthetic dyes in drinks and OTC pharmaceutical tablets. The SPE-UV/VIS spectroscopic method was validated in terms of linearity, accuracy (recovery of dyes from spiked preparations), precision (repeatability, intermediate precision) and limits of detection/quantification. The method was found sufficiently fast, easy and reliable for the routine control of dyes in these types of products.
Źródło:
Acta Innovations; 2018, 27; 53-60
2300-5599
Pojawia się w:
Acta Innovations
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Mechanism of Redox Reaction between Palladium(II) Complex Ions and Potassium Formate in Acidic Aqueous Solution
Autorzy:
Wojnicki, M.
Podborska, A.
Powiązania:
https://bibliotekanauki.pl/articles/356614.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
analysis
spectrophotometry
palladium
chloride
speciation
TD-DFT
recycling
recovery
kinetics
formate
Opis:
The kinetics studies of redox reaction between palladium(II) chloride complex ions and potassium formate in acidic aqueous solutions was investigated. It was shown, that the reduction reaction of Pd(II) is selective in respect to Pd(II) complex structure. The kinetic of the process was monitored spectrophotometrically. The influence of chloride ions concentration, Pd(II) initial concentration, reductant concentration, ionic strength as well as the temperature were investigated in respect to the process dynamics. Arrhenius equation parameters were determined and are equal to 65.8 kJ/mol, and A = 1.12×1011 s-1.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2A; 737-745
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-25 z 78

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