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Wyszukujesz frazę "solid crystal" wg kryterium: Temat


Wyświetlanie 1-5 z 5
Tytuł:
Nonlinear and linear pressure determination in a two-layer structure: solid crystal - water at GHz frequencies
Autorzy:
Filipczyński, L.
Wójcik, J.
Kujawska, T.
Powiązania:
https://bibliotekanauki.pl/articles/332574.pdf
Data publikacji:
2003
Wydawca:
Polskie Towarzystwo Akustyczne
Tematy:
pressure determination
solid crystal
water
GHz frequencies
Opis:
Determination of acoustic pressures at the frequency of 1 GHz by means of PVDF hydrophones is not possible due to their limited frequency response. Moreover, the size of their active electrodes is by about 3 orders of magnitude greater than the resolution in the acoustic microscopes at such a high frequency. Therefore the authors solved this problem at first in a microscope with the working frequency of 34 MHz using both the numerical and experimental methods. A numerical procedure of nonlinear propagation and transducer power measurements were applied giving in effect the same quantitative results. Therefore the identical numerical procedure was used for the l GHz microscope working in the reflection mode. Many pressure field quantities of the microscope were shown, e.g. the pressure values, distributions of the first, second, third and fourth pressure harmonics in and outside of the focus, pulse distortions and their spectra, the resolutions achieved etc. The obtained information on nonlinear propagation effects in microscopy was previously lacking.
Źródło:
Hydroacoustics; 2003, 6; 143-150
1642-1817
Pojawia się w:
Hydroacoustics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Crystal structure and Mössbauer effect in multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution
Autorzy:
Stoch, A.
Maurin, J.
Stoch, P.
Kulawik, J.
Szwagierczak, D.
Powiązania:
https://bibliotekanauki.pl/articles/146870.pdf
Data publikacji:
2017
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
BiFeO3
crystal structure
hyperfine interactions
multiferroics
solid solution
Opis:
Multiferroic 0.5BiFeO3-0.5Pb(Fe0.5Ta0.5)O3 solid solution is a material that exhibits ferroelectric and antiferromagnetic orderings in ambient temperature. The solid solution was obtained as a result of a conventional reaction in a solid state. The obtained material is a dense, fine-grained sinter whose surface was observed by scanning electron microscopy (SEM) and stoichiometry was confirmed by energy dispersive X-ray spectroscopic (EDS) analysis. According to the X-ray powder diffraction (XRD) measurements, the main phase is R3c space group with admixture of Pm-3m regular phase. Small contribution of pyrochlore-like phase was also observed. Mössbauer spectroscopy suggested random distribution of Fe3+/Ta5+ cations in the B sites of ABO3 compound. Reduction of the magnetic hyperfine field with an increase in the substitution of Ta5+ in Fe3+ neighbourhood was also observed.
Źródło:
Nukleonika; 2017, 62, 2; 177-181
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Formation of Transition Phases on Interface between Monocrystalline Fe and Cu Due to Mutual Solid-State Diffusion
Autorzy:
Perek-Nowak, M.
Boczkal, G.
Powiązania:
https://bibliotekanauki.pl/articles/351905.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
copper single crystals
iron single crystal
transition phase
solid-state diffusion
Opis:
Interdiffusion between Fe (Armco) and Cu single crystals of similar orientation (around [110]) annealed at temperatures of 873 and 973K in air for 0.5 up to 4 h is studied. Formation of three phases different in their chemical composition has been observed: 1) oxide layer on Cu border (porous), 2) a layer rich in copper, iron and oxygen, 3) a layer of iron and oxygen with only small addition of Cu. All reactions of interface formation occurred in solid state. It was noted that oxygen plays an important role in development of new phases. Strong Kirkendall effect is observed due to large difference in diffusion coefficients of copper atoms to iron, DCu→Fe=300exp(-67800/RT) and iron atoms to copper DCu→Fe=0.091exp(-46140/RT).
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 581-586
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Struktura a nieelastyczne rozpraszanie neutronów przez kryształy molekularne z wiązaniami wodorowymi
Structure and inelastic neutron scattering by the molecular crystals with the hydrogen bonds
Autorzy:
Rok, M.
Bator, G.
Sobczyk, L.
Powiązania:
https://bibliotekanauki.pl/articles/171492.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
kompleksy molekularne
wiązanie wodorowe
struktura krystaliczna
rozpraszanie neutronów
dynamika cząsteczek w fazie stałej
molecular complexes
hydrogen bonds
crystal structure
neutron scattering
molecular dynamics in the solid state
Opis:
The molecular crystals, which are built of organic or organic-inorganic molecules, are characterized by the weak intermolecular interactions. From the viewpoint of the potential applications in electronics or optoelectronics the electric properties of the crystals are essential. In turn these properties are related to their crystal structure as well as the dynamics of the molecules in the solid state. The existence of the hydrogen bonds in the crystal structures, conventional and unconventional, is crucial from the viewpoint of the electric properties of the crystals. The dynamics of methyl groups present in the structure can be a measure of the molecular interactions in the crystals. In this work the dynamical properties, first of all taking into account the research results concerning the neutron scattering, will be discussed. The neutron technique is very effective as regards the methyl group dynamics investigations. The relationship between a formation of the conventional and unconventional hydrogen bonds and a tunneling of the methyl groups at low temperature will be discussed. The method of the interpretation of the INS spectra will be described taking into account the theoretical model, the parameters of which are fitted to the experimental data. The examples will regard the following molecular crystals: p-N,N’-1,10-tetraacethyldiaminodurene (TADD) (Figs. 2 and 4), 2,3,5,6-tetramethylpyrazine with chloranilic acid (TMP·CLA) (Figs. 5, 6 and 7), 2,3,5,6- tetramethylpyrazine with bromanilic acid (TMP·BRA) (Figs. 5 and 6) and the crystal of 3,4,7,8-tetramethylphenantroline (Me4phen) and its complex with picric acid (Me4phen·PIC) (Figs. 8 and 9). In this paper we have shown that the surrounding of the methyl group and its interactions with the adjacent molecules has a stronger effect than the changes in the electronic charge density in the molecule.
Źródło:
Wiadomości Chemiczne; 2017, 71, 7-8; 533-557
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Crystal structure and spectroscopic properties of 4-acetaminopyridine and its protonated form
Autorzy:
Koleva, B.B.
Nikolova, R.
Tchapkanov, A.
Kolev, T.
Mayer-Figge, H.
Spiteller, M.
Sheldrick, W.S.
Powiązania:
https://bibliotekanauki.pl/articles/778733.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
4-acetyloaminopirydyna
struktura kryształów
spektroskopia IR
spektroskopia UV
4-acetaminopyridine
protonated form
crystal structure
solid-state linear polarized IR spectroscopy
UV spectroscopy
quantum chemical calculations
1H and 13C NMR
ESI-MS
TGA and DSC
Opis:
4-Acetaminopyridine dihydrate and its protonated form, stabilized as the hydrochloride salt have been synthesized and spectroscopic elucidated in solution and in the solid-state by means of the inear-polarized solid state IR-spectroscopy (IR-LD), UV-spectroscopy, TGA, DSC, and the positive and negative ESI MS. Quantum chemical calculations were used to obtain the electronic structure, vibrational data and the electronic spectra. The spectroscopic and theoretical data are compared with the structure of the first compound obtained by single crystal X-ray diffraction. The effect of Npy protonation on the optical and magnetic properties of a 4-acetaminopyridine is discussed.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 3; 35-40
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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