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Tytuł:
Potassium chloride recovery from mechanically activated microcline through the chlorination roasting and leaching route
Autorzy:
Alyosif, Bahaa
Uysal, Turan
Erdemoğlu, Murat
Powiązania:
https://bibliotekanauki.pl/articles/24148588.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
KCl
K-feldspar
chlorination roasting
mechanical activation
energy efficiency
Opis:
In this study, effects of mechanical activation in the chlorination roasting and water leaching route known as CaCl2 process and developed for the production of potassium chloride (KCl) from potassium feldspar ores were studied. A microcline containing K-feldspar ore with 10.89% K2O was first intensively dry milled by a planetary ball mill and mixed with calcium chloride (CaCl2) and then roasted at temperatures up to 1000 °C to obtain KCl that will be finally dissolved by the water leaching. Potassium recovery by water leaching increased rapidly up to 800 °C. At higher temperatures, the recovery decreased fast due to the evaporation of KCl. According to the K recovery values per unit energy consumed, the optimum roasting temperature was determined as 750 °C and the milling time was 15 min. It was concluded that intensive milling causes mechanical activation of the microcline to reduce the chlorination roasting temperature, which triggers a rise in the K recovery by the water leaching.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 5; art. no. 167500
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Roasting conditions and quality coffee: the empirically optimised process
Autorzy:
Vakaryk, Nadiia
Sachko, Anastasiia
Sema, Oksana
Kobasa, Igor
Gubsky, Sergey
Powiązania:
https://bibliotekanauki.pl/articles/27323586.pdf
Data publikacji:
2023
Wydawca:
Centrum Badań i Innowacji Pro-Akademia
Tematy:
sensory characteristics
Arabica coffee
Robusta coffee
coffee beans
roasting process
temperature
kawa Arabika
kawa Robusta
ziarna kawy
proces palenia
temperatura
cechy sensoryczne
Opis:
The degree of roast, temperature and duration of the roasting phases of the coffee bean directly affect the sensory characteristics of the coffee cup. Therefore, to achieve the best roasting result, it is important to combine the human factor with special software products. To automate the roasting process, the Artisan roasting recording software was used. Automation of roasting allows better reproduction of the process conditions for different coffee samples. However, roasting is a rather complex and multi-stage process, and its automation does not guarantee the full reproduction and disclosure of the taste and aroma properties of the "perfect cup". Therefore, the qualifications, skills and experience of the roaster play a significant role in achieving and further reproducing the desired flavour profile.
Źródło:
Acta Innovations; 2023, 49; 31--38
2300-5599
Pojawia się w:
Acta Innovations
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization and treatment of clayey waste using a sulfuric acid roasting-water leaching process for the extraction of lithium
Autorzy:
Obut, Abdullah
Aktosun, Zeynep
Girgin, İsmail
Deveci, Hacı
Yörükoğlu, Abdulkerim
Powiązania:
https://bibliotekanauki.pl/articles/2146902.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Kırka boron plant
lithium
smectite
sulfuric acid roasting
water leaching
Opis:
In this study, a detailed characterization of the clayey waste of the Kırka boron plant was undertaken before the development of a sulfuric acid roasting-water leaching process for the extraction of lithium from this waste. The effects of roasting temperature (650-800°C) and sulfuric acid/waste ratio (90-260 kg H2SO4/1000 kg waste on a dry basis) on the extraction of lithium were investigated. By roasting the waste sample, which contained 0.37% Li2O with dolomite, smectite and borax as the main phases, at temperatures between 650°C and 800°C in the absence of sulfuric acid as the additive, CaMgSiO4 was found to form as the dominant phase after the decomposition of dolomite and smectite present in the sample. On the other hand, the X-ray diffraction analyses of the waste sample subjected to sulfuric acid treatment without roasting showed the in-situ formation of various hydrated calcium sulfate phases for all sulfuric acid/waste ratios tested. Besides, at the highest acid/waste ratio of 260, a hydrated magnesium sulfate phase was also identified in the sample. The application of the sulfuric acid roasting-water leaching process under the optimum roasting temperature of 750°C and the acid/waste ratio of 180 was found to lead to a lithium extraction of 85.7%. The applied sulfuric acid roasting-water leaching process appeared to be an attractive process with its attributes including low roasting temperature, high extraction percentage and no requirement for gypsum as the external sulfation agent.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149635
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of recycling blast furnace dust by magnetization roasting with straw charcoal as reductant
Autorzy:
Ju, Jinrong
Feng, Yali
Li, Haoran
Zhang, Qian
Powiązania:
https://bibliotekanauki.pl/articles/2146900.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
blast furnace dust
straw charcoal
magnetization roasting
hematite
zinc ferrite
Opis:
Blast furnace dust generated in the iron-making process not only contains a large amount of iron but also the widely used non-ferrous metal zinc, which is classified as hazardous waste. In this study, the process of recycling blast furnace dust by magnetization roasting with straw charcoal as the reductant is proposed, and the mechanism of magnetization roasting was explored through thermodynamic analysis, X-ray diffraction analysis, and thermogravimetric analysis. The results for the thermodynamic analysis showed that the reduction of blast furnace dust by the straw charcoal was feasible theoretically. The increase in the roasting temperature not only promoted the reduction of hematite (Fe2O3) but also reduced zinc ferrite (ZnFe2O4) to Fe3O4 and ZnO. The results showed that almost all Fe2O3 and ZnFe2O4 in the blast furnace dust were reduced to Fe3O4 and ZnO under the conditions of straw charcoal amount of 6%, the roasting temperature of 750℃, and the roasting time of 60 min. Then, the iron concentrate with the iron recovery of 85.61% and an iron grade of 63.50% was obtained by the magnetic separation. Meanwhile, the grade of zinc in the iron concentrate was 0.19%. Finally, the flowsheet of simultaneously recovering iron and zinc from the blast furnace dust was put forward, which could realize that 85.61% of iron was recovered and 92.57% of zinc was extracted into the solution.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 149265
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on fluoride fixation effect of Bayan Obo rare earth iron ore and three sodium agents under microwave irradiation
Autorzy:
Guo, Jing
Wen, Ming
Li, Jie
Hong, Xunhai
Zhang, Wenhao
Wang, Yonglun
Powiązania:
https://bibliotekanauki.pl/articles/2146846.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Bayan Obo rare earth iron ore
microwave roasting
sodium agent fluoride fixation
Opis:
To investigate the fluorine fixation of Bayan Obo rare-earth iron ores in beneficiation and metallurgy processes, the effect of three sodium agents, namely, sodium hydroxide, sodium carbonate, and sodium bicarbonate, on fluorine fixation under the action of microwaves was investigated using Xray diffraction, chemical detection, and orthogonal experiments. The effects of different types of sodium, roasting temperatures, sodium ratios, and roasting times on the fluorine fixation rate were evaluated. Results show that compared with conventional roasting, the fluorine fixation efficiency of Bayan Obo rare-earth iron ore under the action of microwave is superior after the formulation of the sodium agent, which is crucial for the study. Among the three sodium agents, the fluorine fixation effect of NaHCO3 can be used as the preferred sodium agent. Orthogonal experiments showed that the factors influencing the magnitude of the fluorine fixation rate are the roasting temperature, sodium agent ratio, and roasting constant temperature time in the order of priority. The optimal conditions for the fluorine fixation process are the microwave roasting temperature of 973.15 K, sodium bicarbonate ratio of 40%, and roasting time of 60 min. The highest fluorine fixation rate of 86.72% can be obtained. The findings of this study can provide a reference for the development of green and economic recovery processes for Bayan Obo rare-earth iron ores.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 1; 63--76
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The investigation of lithium extraction by roasting with sulfating agent and water leaching from nepheline syenite rocks
Autorzy:
Üçerler, Zeynep
Güney, Ali
Powiązania:
https://bibliotekanauki.pl/articles/2146905.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
zinnwaldite
water leaching
roasting
lithium extraction
Opis:
In this study, the extraction of lithium from zinnwaldite concentrate containing 0.25% Li was investigated. The run-of-mine ore originated from nepheline syenite rocks in Kırşehir, Turkey, and contained 216.3 ppm Li. Firstly, the ore was beneficiated by a flotation process to increase the lithium content. Then, it was subjected to roasting and water leaching processes, respectively. In the roasting process, calcite and gypsum were used as additives to form dissoluble lithium sulfate for the next process. Additionally, the effect of roasting temperatures (750, 850, 950, and 1000°C) and times (30, 60, 90, 120, and 240 min) was examined along with different ratios of additives to concentrate to find the optimal conditions. Accordingly, the calcined product from the roasting process was dissolved in water by determining the optimal leaching temperature, time, and water/solid ratio. Consequently, a lithium product was obtained from the concentrate with 93.3% extraction efficiency. Finally, the mother liquor contained 30 mg/dm3 Li, the production of Li2CO3 from mother liquor will be investigated in case of production of the sample at the optimal conditions of roasting and leaching in further studies.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 146154
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanism and kinetics of pyrite transformation at elevated temperatures
Autorzy:
Aracena, Alvaro
Jerez, Oscar
Powiązania:
https://bibliotekanauki.pl/articles/2146885.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
pyrrhotite
roasting
kinetics
Opis:
Pyrite (FeS2) is known as a sulfide that provides energy for various pyrometallurgical processes (fusion and conversion). There are several studies related to the evaluation of pyrite oxidation mechanisms at high temperatures, obtaining discrepancies in the products generated. In our work, the novelty of our research would be to obtain the thermochemical oxidation mechanism of FeS2 by using conventional thermogravimetric methods. The oxidative roasting of pyrite from 550 to 800°C was analyzed for an oxygen concentration of 5.07 to 28.06 kPa of oxygen and particle size between 12.3 to 33.8 microns. The results showed that the pyrite proceeded by sequential roasting: first, it produced an intermediate compound, pyrrhotite (Fe7S8), which was later oxidized to generate hematite (Fe2O3), both stages validated by weight loss of the sample as well as by analysis by DRX. Each stage had a different roasting speed as it was also influenced differently by different parameters. The temperature and particle size favored the rate of pyrrhotite generation, and the oxygen concentration favored the rate of hematite formation. The first-order kinetic equation ln (1-XPy) represented the roasting of the first stage (FeS2 → Fe7S8), with a calculated activation energy of 70.1 kJ/mol. The order of reaction was 0.5 concerning the partial pressure of oxygen and inversely proportional to the initial particle radius.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 6; 127--139
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A novel process for extraction of iron from a refractory red mud
Autorzy:
Ding, Wei
Xiao, Junhui
Peng, Yang
Shen, Siyue
Chen, Tao
Zou, Kai
Wang, Zhen
Powiązania:
https://bibliotekanauki.pl/articles/1450194.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
red mud
sodium sulfate
segregation roasting
magnetic separation
iron recovery
Opis:
Red mud is a kind of solid waste produced during alumina extraction from bauxite. To extraction valuable iron from red mud, the technology of adding sodium sulfate-segregation roasting-magnetic separation to treat red mud was developed. During the paper, the effects of various process parameters on the extraction of iron by segregation roasting-magnetic separation were studied, and the phase transformation behavior and microstructure of iron are explored. Repeated test results showed that magnetic concentrate (mass percent), TFe of 80.29 % and overall iron recovery of 92.08 %was obtained. The X-ray diffraction (XRD) and scanning electron microscopy (SEM) results indicated that after the segregation roasting, the hematite was transformed into a new metal phase consisting mainly of metallic iron and magnetite. The addition of sodium sulfate during the segregation roasting can obviously improve the efficiency of segregation roasting-magnetic separation for iron extraction.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 125-136
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of microwave treatment on quality parameters of snacks food. Impact issues
Autorzy:
Goszkiewicz, Anna
Kochańska, Ewa
Korczak, Katarzyna
Potapov, Volodymyr О.
Prasol, Svitlana
Powiązania:
https://bibliotekanauki.pl/articles/1430017.pdf
Data publikacji:
2020
Wydawca:
Centrum Badań i Innowacji Pro-Akademia
Tematy:
roasting
microwave
convection
nuts
sensory quality
LCA
economy
prażenie
kuchenka mikrofalowa
orzechy
jakość sensoryczna
gospodarka
Opis:
The following publication presents results of the research on a new, innovative, mild technology of food processing with microwaves technology in order to develop novel food in the form of “on the go” healthy snacks. Different aspects of microwave treatment technologies within the context of physical model of electromagnetic field interaction with a food product, marketing and energy aspects were considered. Furthermore, comparison of sensory quality of conventionally and microwave treated nuts was shown, which is a key feature of nuts, seeds and dried fruits for most consumers. A comparative LCA analysis of convectional and microwave roasting was performed as well.
Źródło:
Acta Innovations; 2020, 36; 64-80
2300-5599
Pojawia się w:
Acta Innovations
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Manufacture of Low Sulphur Pig Iron from Copper Slag
Autorzy:
Erdenebold, Urtnasan
Sung, Choi Moo
Wang, Jei-Pil
Powiązania:
https://bibliotekanauki.pl/articles/354242.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
copper slag
desulphurization
roasting
sulphur
basicity
Opis:
Copper slag differs by chemical composition and structure, depending on the type of processing. Copper slag typically contains about 1 wt.% copper and 40 wt.% iron depending upon the initial ore quality and type of furnace used. The aim is to produce a typical foundry pig iron with the chemical composition of C > 3.40 wt.%, Si 1.40 to 1.80 wt.%, Mn 0.30 to 0.90 wt.%, P < 0.03 wt.% and S < 0.03 wt.% from copper slag. But foundry pig iron manufactured from copper slag contains a high sulphur content. Therefore, this study examines how to conduct desulphurization. Desulphurization roasting and reduction smelting with desulphurization additives used to remove sulphur from the copper slag. The results showed that desulphurization effect of desulphurization roasting is poor but when combined with reduction smelting with CaO addition is possible to manufacture low sulphur pig iron from copper smelting slag.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 1; 349-355
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of fluidized magnetizing roasting on iron recovery and transformation of weakly magnetic iron mineral phasein iron tailings
Autorzy:
Li, Wenbo
Han, Yuexin
Liu, Xiao
Shan, Yan
Li, Yanjun
Powiązania:
https://bibliotekanauki.pl/articles/110633.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
iron tailings
fluidized magnetizing roasting
hematite
limonite
iron phase transformation
low intensity magnetic separation
Opis:
The eastern tailings of the Anshan mining area are generally categorized as high silicon-bearing iron tailings, and the iron mainly exists in the form of hematite–limonite with an iron grade of 10.60%. In order to recover iron minerals and reduce the influence of the tailings on the environment, a method for pre-enrichment through the combination of low intensity magnetic separation and high intensity magnetic separation with fluidized magnetizing roasting and subsequent low intensity magnetic separation was developed to treat the eastern tailings of the Anshan mining area. The effects of gas-flow rate, H2 concentration, roasting temperature, and roasting time on the quality of the final iron concentrate were discussed. Moreover, the iron phase transformation and change in magnetism of the sample were studied. The results indicated that an iron concentrate with an iron grade of 65.30% and a recovery of 85.85% could be obtained under the conditions of gas-flow rate of 8 m3/h, H2 concentration of 50%, and fluidized magnetizing roasting at 600 ℃ for 20 s. X-ray diffraction analysis, phase analysis, and magnetism analysis on the roasted materials indicated that the hematite–limonite could be transformed into magnetite during the fluidized magnetizing roasting process, and effective separation of iron and gangues could be easily achieved by the weak magnetic separation.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 4; 906-916
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of the fixed carbon and ash in blast furnace dust on its co-reduction with seaside titanomagnetite
Autorzy:
Wang, Xiaoping
Hu, Tianyang
Chen, Chuanzhong
Sun, Tichang
Powiązania:
https://bibliotekanauki.pl/articles/109936.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
seaside titanomagnetite
blast furnace dust
co-reduction roasting
fixed carbon
ash
Opis:
Previous research has found that the fixed carbon in blast furnace dust (BFD) could be used as the reductant of co-reduction roasting of the iron oxides in seaside titanomagnetite and BFD to replace coals. This research studied the influence mechanism of the fixed carbon and ash in BFD on coreduction.Results showed that both fixed carbon and ash in BFD promoted the reduction of iron, while ash had adverse effect on separation of titanium and iron. The main mechanism was as follows: The ash in BFD accelerated melting. In addition, the iron oxide in the ash of BFD could be reduced to metallic iron cores more easily in the initial stage, providing the site of inhomogeneous core and promoting the aggregation and growth of metallic iron. Furthermore, the fixed carbon mainly reacted with iron ore by solid-solid reaction, leading to a rapid reduction rate and a high utilization rate of fixed carbon.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1323-1337
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A novel method to extract vanadium from high-grade vanadium slag: non-salt roasting and alkaline leaching
Autorzy:
Liu, B.
Meng, L.
Zheng, S.
Li, M.
Wang, S.
Powiązania:
https://bibliotekanauki.pl/articles/110480.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
high-grade vanadium slag
cleaner production
non-salt roasting
alkaline leaching
mechanisms
Opis:
A new method using non-salt roasting-alkaline leaching to treat vanadium slag was proposed in this study. The V(III) in vanadium slag is oxidized to V(V) by roasting and the latter can be effectively leached out as vanadate by alkaline leaching. This method possesses distinct advantage of being able to treat high-grade vanadium slag. For the South Africa high-grade vanadium slag, the maximum vanadium recovery of 98% was achieved when the reaction conditions were roasting temperature of 850 °C, roasting time of 2 h, alkali concentration of 30 wt.%, leaching temperature of 210 °C, and leaching time of 2 h. The roasting and leaching mechanisms have been well elucidated based on the XRD and SEM analysis results. The phases transitions of vanadium slag were clearly presented. This work has laid the foundation for the industrial application of non-salt roasting-alkaline leaching and provided new insights into effective extraction of high-grade vanadium slag.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 657-667
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An innovative methodology for recycling iron from magnetic preconcentrate of an iron ore tailing
Autorzy:
Yu, J.
Han, Y.
Gao, P.
Li, Y.
Yuan, S.
Li, W.
Powiązania:
https://bibliotekanauki.pl/articles/110888.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
magnetic preconcentrate
iron ore tailing
iron recycling
fluidized magnetization roasting
magnetic separation
Opis:
Iron ore tailing is a kind of hazardous solid waste produced by iron and steel industry. In order to separate and recycle iron from the magnetic preconcentrate of an iron ore tailing, an innovative technological route of fluidized magnetization roasting followed by low-intensity magnetic separation was proposed in this paper. The effects of roasting temperature, dosages of reducing gas CO and fluidizing gas N2 on recovery rate of iron were carried out and optimized. The results showed that the hematite was almost reduced to magnetite by a gas mixture of 4 m3/h CO and 1 m3/h N2 at roasting temperature of 540 °C. Under the optimized conditions, a magnetic concentrate assaying 61.4 wt% Fe with a recovery rate of 81.8% was obtained from the magnetic preconcentrate of an iron ore tailing. The iron chemical phase, X-ray diffraction (XRD), and optical metallographic microscope analyses revealed that siderite was converted to magnetite successfully after roasting, and some coarse magnetite-hematite interlocking particles were formed due to insufficient reaction time, which could also be recovered by magnetic separation after liberating from gangue minerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 668-676
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Efficient sulfidization of lead oxide at high temperature using pyrite as vulcanizing reagent
Autorzy:
Zheng, Y.-X.
Lv, J.-F.
Wang, H.
Wen, S.-M.
Huang, L.
Powiązania:
https://bibliotekanauki.pl/articles/110351.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
lead oxide
sulfidization roasting
pyrite
reaction mechanism
TG
Opis:
A sulfidization roasting-flotation process was usually viewed to be effective in treating the refractory oxide ore. In this paper, pyrite was proposed to be applied as a potential vulcanizing reagent to transform PbO or its surface to PbS based on feasibilities of technology and economy. The evolution process, phase and characteristics of crystal growth were investigated by TG, XRD and SEM-EDS, respectively, to interpret the interaction mechanism of lead oxide and pyrite at high temperature. It was found that the decomposition process of pyrite under argon atmosphere was a slow process of sulfur released from FeS2 to FexS, which made the process easier to be controlled. When PbO was introduced into the system, the initial solid-solid (PbO-FeS2) reaction and prevailing solid-gas (PbO-S2(g)) reaction occurred at about 500 °C and 700 °C, respectively. Combined with the SEM-EDS analyses results, the optimal temperature for the sulfidization of PbO should be in the range of 700-750 °C.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 270-277
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł

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