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Tytuł:
Lycopene as a guardian of redox signalling
Autorzy:
Palozza, Paola
Catalano, Assunta
Simone, Rossella
Cittadini, Achille
Powiązania:
https://bibliotekanauki.pl/articles/1039763.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
ROS
intracellular redox status
redox signal
antioxidant
lycopene
Opis:
It has been suggested that lycopene, the major carotenoid found in tomato, exhibits health-beneficial effects by virtue of its antioxidant activity. However, recent literature suggests that lycopene can actually "perform" roles independent of such capacity and involving a direct modulation of redox signalling. Reactive oxygen species are known to act as second messengers in the modulation of cellular signalling leading to gene expression changes and pharmacological responses. Lycopene may control redox-sensitive molecular targets, affecting enzyme activities and expressions and modulating the activation of MAPKs and transcription factors, such as NF-κB and AP-1, Nrf2.
Źródło:
Acta Biochimica Polonica; 2012, 59, 1; 21-25
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Developmental changes in the levels and redox potentials of main hemolymph thiols/disulfides in the Jamaican field cricket Gryllus assimilis
Autorzy:
Sadowska-Bartosz, Izabela
Furmaniak, Paulina
Bieszczad-Bedrejczuk, Edyta
Bartosz, Grzegorz
Głowacki, Rafał
Powiązania:
https://bibliotekanauki.pl/articles/1038598.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
insect
Gryllus assimilis
hemolymph
glutathione
cysteine
homocysteine
redox potential
redox environment
Opis:
Main thiols and disulfides were determined in the hemolymph of the Jamaican field cricket Gryllus assimilis at various developmental stages. On the basis of these data, redox potentials of the glutathione, cysteine and homocysteine redox systems were calculated. The concentrations of all thiols studied decreased during development (at a stage of 6 molts) with respect to young crickets, and increased again in adult insects. Redox potentials of the glutathione and cysteine systems increased from values of -131.0±5.6 mV and -86.9±17.1 mV, respectively in young crickets to -58.0±3.6 mV and -36.1±4.2 mV, respectively, at the stage of 6 molts and decreased to values of -110.4±24.8 mV and -66.3±12.2 mV, respectively, in adult insects. Redox potentials of the glutathione and cysteine systems in the hemolymph of young and adult insects were similar to those reported for human plasma.
Źródło:
Acta Biochimica Polonica; 2017, 64, 3; 503-506
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Redox changes affect growth and gene expression in maize
Autorzy:
Gulyas, Z.
Boldizsar, A.
Szalai, G.
Kocsy, G.
Galiba, G.
Powiązania:
https://bibliotekanauki.pl/articles/81154.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
redox change
gene expression
maize
root
glutathione level
redox potential
thioredoxin
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
In vitro inhibition of topoisomerase IIα by reduced glutathione
Autorzy:
Delwar, Zahid
Vita, Marina
Siden, Åke
Cruz, Mabel
Yakisich, Juan
Powiązania:
https://bibliotekanauki.pl/articles/1039933.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
DNA topoisomerases
glutathione
redox regulation
Opis:
In most cells, the major intracellular redox buffer is glutathione (GSH) and its disulfide-oxidized (GSSG) form. The GSH/GSSG system maintains the intracellular redox balance and the essential thiol status of proteins by thiol disulfide exchange. Topoisomerases are thiol proteins and are a target of thiol-reactive substances. In this study, the inhibitory effect of physiological concentration of GSH and GSSG on topoisomerase IIα activity in vitro was investigated. GSH (0-10 mM) inhibited topoisomerase IIα in a concentration-dependent manner while GSSG (1-100 µM) had no significant effect. These findings suggest that the GSH/GSSG system could have a potential in vivo role in regulating topoisomerase IIα activity.
Źródło:
Acta Biochimica Polonica; 2011, 58, 2; 265-267
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Elektryczny kalibrator elektrod redox
Electrical calibrator of redox electrodes
Autorzy:
Suchocki, K.
Powiązania:
https://bibliotekanauki.pl/articles/152779.pdf
Data publikacji:
2010
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
pomiar potencjału redox
kalibracja
dokładność pomiaru
measurements of redox potential
calibration
accuracy of measurement
Opis:
Pomiar wartości potencjału redox jest wykorzystywany do oceny stanu środowiska naturalnego, dlatego bardzo istotna jest dokład-ność z jaką jest on wykonywany. Duży wpływ ma na nią między innymi kalibracja elektrod redox wraz z dołączonymi do nich urządzeniami pomiarowymi. Do chwili obecnej kalibrację elektrod redox wykonuje się przy pomocy roztworów redox, co niestety nie gwarantuje jej dużej dokładności. W celu jej poprawy opracowano koncepcję elektrycznego kalibratora redox. Urządzenie to charakteryzuje się prostą konstrukcją i pozwala na szybką i dokładną kalibrację elektrod redox napięciem bipolarnym w bardzo szerokim zakresie. W artykule omówiono budowę elektrycznego kalibratora redox, a także przeanalizowano czynniki wpływające na rozkład potencjału pola elektrycznego w jego elektrodzie kalibracyjnej. Omówiono także wpływ konstrukcji kalibratora na szybkość ustalania się rozkładu potencjału pola elektrycznego i dokładność przeprowadzanej kalibracji elektrod redox.
Measurements of the redox potential value are used in estimation of the natural environment condition, for this reason it is important to take the measurements accurately. The redox electrodes calibration together with measuring devices connected to the electrodes influ-ence the measurement accuracy significantly. Nowadays the cali-bration of the redox electrodes is performed with use of redox solutions which, unfortunately does not always provide the adequate accuracy. Therefore, an electrical redox calibrator has been devel-oped. This device has a simple construction and allows fast and accurate calibration of the redox electrodes in a broad range with use of bipolar voltage. In the paper the electrical structure of the redox calibrator is presented. The factors influencing the decomposition of the electric field potential are analysed. Additionally, the influence of the calibrator construction on the speed of the electric potential field decomposition settlement as well as the accuracy of the performed redox electrodes calibration are discussed.
Źródło:
Pomiary Automatyka Kontrola; 2010, R. 56, nr 8, 8; 848-850
0032-4140
Pojawia się w:
Pomiary Automatyka Kontrola
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Why are variations in bromine isotope compositions in the Earths history larger than chlorine isotope compositions?
Autorzy:
Eggenkamp, Hans
Powiązania:
https://bibliotekanauki.pl/articles/763372.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
chlorine isotopes
bromine isotopes
Phanerozoic
redox
Opis:
In this paper we discuss the marked discrepancy in global chlorine and bromine isotope variations. While, based on experimentally and theoretically determined fractionation factors, it is expected that bromine isotope variations should be, depending on the process, 2 to 7 times less than chlorine isotope variations it is observed that in formation brines the isotope variations of bromine are at least of the same size as chlorine isotope variations, and regularly even larger. In this paper we argue that this is caused by the fact that oxidation-reduction processes play a more important role in bromine isotope geochemistry than in chlorine isotope geochemistry. Due to the fact that the bromide ion is more easily to oxidise than the chloride ion Rayleigh effects can cause the observed larger variations in bromine isotope geochemistry. In this paper we propose that biochemical reactions (oxidation of bromide ions to methyl bromide) may be the major cause for this effect. Although we do not yet understand the full processes that take place we show that oxidation-reduction processes must be the main effect to explain the differences between the two isotope systems and propose that more research is developed to understand how the processes cause the observed variations.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AAA – Physica; 2015, 70
0137-6861
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AAA – Physica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Monitoring the Evolution of Redox Changes in Sediments made Possible by Electrochemical Multilayer Probes
Autorzy:
Popa, Radu
Moga, Ioana Corina
Nealson, Kenneth H.
Cimpoiasu, V.M.
Powiązania:
https://bibliotekanauki.pl/articles/2134093.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sensor
sediments
SPEAR
multielectrode
redox interface
Opis:
Marine sediments with rapid oxic/anoxic transitions are difficult to monitor in real time. Organic overload that may lead to anoxia and buildup of hydrogen sulfide can be caused by a variety of factors such as sewage spills, harbor water stagnation, algal blooms and the vicinity of aquaculture operations. We have tested a novel multiprobe technology (named SPEAR) on marine sediments to evaluate its performance in monitoring sediments and overlaying water. Our results show the ability of the SPEAR probes to distinguish electrochemical changes at 2-3 mm scale and at hourly cycles. SPEAR probes have the ability to identify redox interfaces and redox transition zones in sediments, but do not use micromanipulators (which are cumbersome in field and underwater applications). We propose that the best target habitats for SPEAR-type monitoring are rapidly evolving muddy deposits and sediments near aquaculture operations where pollution with organics stresses the ecosystem.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 3; 1037--1041
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of ovalbumin on pyrite flotation in the absence and presence of metal ions
Autorzy:
Guler, T.
Sahbudak, K.
Akdemir, U.
Cetinkaya, S.
Powiązania:
https://bibliotekanauki.pl/articles/110499.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
ovalbumin
metal ion
flotation
redox potential
Opis:
Recovery of gangue pyrite and its accidental activation are vital issues in flotation of complex sulfide ores. This work was performed by cyclic voltammetry (CV) and flotation tests to elucidate applicability of ovalbumin (OVA) as depressant for pyrite. The synergetic effect of metal ions in addition to its possible use in case of accidental activation by metal ions. CV tests stated that OVA adsorbed irreversibly on pyrite, and restricted electron transfer up to moderately oxidizing potentials due to electrostatic interaction together with weak hydrophobic interactions. At highly oxidizing potentials, adsorption occurred through electrochemical mechanisms through formation of metal-OVA chelates. Rate of pyrite depression with OVA was found to be potential dependent reaching its peak point around moderately oxidizing potentials both in absence and presence of metal ions. Electrochemically active metals display synergetic effect with OVA on pyrite depression, whereas noble metals activate pyrite and reduced depressing potency of OVA.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 31-40
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Soil Redox Potential and its Impact on Microorganisms and Plants of Wetlands
Autorzy:
Tokarz, E.
Urban, D.
Powiązania:
https://bibliotekanauki.pl/articles/125438.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
redox potential
peatland
microbial communities
enzymatic activity
Opis:
Although peatlands cover only 3% of the Earth’s surface, they constitute a huge reservoir of carbon. It is estimated that they accumulate one third of carbon contained in all types of soils worldwide. Therefore, knowledge of the physical, chemical, and biological properties of peat is important for prevention of peat degradation and release of carbon stored as CO2 into the atmosphere. In organic soils, water plays a very important role as a protective factor against mineralisation of organic matter. Therefore, organic soils are characterised by high specificity and dissimilarity from mineral soils. The hydrological factor induces a variety of changes in the physical and chemical properties, e.g. low redox potential or low oxygen content in soil pores. Many soil processes are determined by the soil oxygenation status, which can be measured with various indicators as well as direct and indirect measurements. One of the indirect methods is measurement of the redox potential. The oxidation-reduction potential (redox potential or Eh) is a measure of the ratio of oxidised to reduced forms in a solution. This parameter is inextricably linked to oxygen supply and the processes of consumption thereof by microorganisms and plant roots. Therefore, the redox potential is used as an indicator of the oxygenation status and the content of biogenic forms and toxins in the soil environment and sediments. In the case of submerged soils, penetration of atmospheric oxygen into the soil is limited due to low rates of oxygen diffusion and, hence, low redox potential, which inhibits plant growth through inhibition of respiration and production of toxins in reducing conditions. The aim of this article is (1) to the show soil-plant-soil microorganism interactions taking place on peatbogs in the context of redox potential, (2) to investigate the responses of plants and soil microorganisms to the changing redox potential, and (3) to demonstrate the mechanisms of plant adaptation to the reducing conditions prevailing in peatbogs.
Źródło:
Journal of Ecological Engineering; 2015, 16, 3; 20-30
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metabolic parameters in young turkeys fed diets with different inclusion levels of copper nanoparticles
Autorzy:
Kozłowski, K.
Jankowski, J.
Otowski, K.
Zduńczyk, Z.
Ognik, K.
Powiązania:
https://bibliotekanauki.pl/articles/2087738.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
nano-copper
turkey
blood
liver
redox status
Źródło:
Polish Journal of Veterinary Sciences; 2018, 21, 2; 245-253
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of citrus flavanones on the redox homeostasis in cells exposed to oxidative stress – studies in vitro
Wpływ flawanonów cytrusowych na homeostazę redoks komórek narażonych na stres oksydacyjny – badania in vitro
Autorzy:
Kurzeja, Ewa
Synowiec-Wojtarowicz, Agnieszka
Spiołek, Katarzyna
Derewniuk, Małgorzata
Pawłowska-Góral, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1035565.pdf
Data publikacji:
2016
Wydawca:
Instytut Medycyny Wsi
Tematy:
"cell culture"
"flavanones"
"oxidative stress"
"redox homeostasis"
Opis:
Introduction: Flavanones (an important group of antioxidants in citrus fruits) are beneficial for health, which is connected with their anti-inflammatory, anti-atherogenic and anti-carcinogenic properties. The present study was undertaken to investigate whether – and in what way – the presence of flavanones influences the redox homeostasis of fibroblasts and alleviates the effects of oxidative stress. Material and methods: The study was conducted on murine fibroblast cell cultures with the addition of flavanones (hesperidin, hesperetin, naringin, naringenin), exposed to oxidative stress (Fe/Asc). In cell homogenates, the activity of superoxide dismutase (SOD) and glutathione peroxidase (GPx) was measured; in the medium, the concentration of nitric oxide was measured. Results and conclusion: Our results demonstrate that the addition of naringenin, hesperetin, naringin and hesperidin has a protective effect on cells subjected to oxidative stress The changes observed are particularly visible in the case of aglycone forms of both compounds. Despite the protective properties against oxidative stress which flavanones display, we determined distrubances in redox homeostasis in comparison to the control culture.
Wstęp: Flawanony, będące głównymi związkami bioaktywnymi cytrusów, wykazują działanie prozdrowotne, co wynika z ich właściwości przeciwzapalnych, przeciwmiażdżycowych i przeciwnowotworowych. Celem badania była ocena wpływu flawanonów na homeostazę redoks fibroblastów oraz czy ich obecność łagodzi skutki stresu oksydacyjnego. Materiały i metody: Badanie przeprowadzono na hodowlach mysich fibroblastów z dodatkiem flawanonów (hesperydyna, hesperetyna, naringina, naringenina) poddanych stresowi oksydacyjnemu (Fe/Asc). W homogenatach komórkowych oznaczono aktywność dysmutazy ponadtlenkowej (SOD) i peroksydazy glutationowej (GPx), a bezpośrednio w pożywce stężenie tlenku azotu. Wyniki i wnioski: Wyniki naszej pracy wskazują, że dodatek naringeniny, hesperetyny, naringiny i hesperydyny działa ochronnie na komórki poddane stresowi oksydacyjnemu. Pomimo stwierdzonego ochronnego działania flawanonów zaobserwowaliśmy również zaburzenie homeostazy redoks w odniesieniu do hodowli kontrolnej.
Źródło:
Medycyna Środowiskowa - Environmental Medicine; 2016, 19, 2; 32-39
1505-7054
2084-6312
Pojawia się w:
Medycyna Środowiskowa - Environmental Medicine
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical Reduction of Gold(III) Bromide Complexes Using Sodium Nitrite - Kinetic Aspects
Autorzy:
Pacławski, K.
Powiązania:
https://bibliotekanauki.pl/articles/354755.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
kinetics
mechanism
redox
gold complexes
sodium nitrite
Opis:
In this work, the spectrophotometric studies on the kinetics of redox reaction between gold(III) bromide complexes and sodium nitrite, were carried out. From the kinetic curves collected under different conditions of reactants concentration, addition of bromide ions, temperature, pH and ionic strength, corresponding rate constants have been determined. The obtained results suggest the complex path of the [AuBr4]- reduction consisting of two parallel, bimolecular reactions where different reductant species (HNO2 and NO2-) take place and consecutive step with the metallic gold production. The second-order rate constants at 20°C are equal to 2.948 and 0.191 M-1·s-1, respectively. The values of activation enthalpy and activation entropy for the first and the second parallel step of the reaction were found to be ΔH‡ = 29.18 kJ·mol-1 and ΔS‡ = –13.95 J·mol-1·K, and ΔH‡ = 40.75 kJ·mol-1 and ΔS‡ = –31.06 J·mol-1·K, respectively. It was found that the reaction accelerates significantly with the increase of pH and is inhibited with the increase of Br- concentration. The substitutive, inner-sphere mechanism of electron transfer in the studied system was also suggested.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 667-675
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metody określania potencjału redox zestawu surowcowego i masy szklanej
The methods of determination redox potential of the glass batch and glass melt
Autorzy:
Zawiła, J.
Powiązania:
https://bibliotekanauki.pl/articles/392454.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Ceramiki i Materiałów Budowlanych
Tematy:
przemysł szklarski
szkło przemysłowe
wsad surowcowy
stop szklany
potencjał redox
glass industry
commercial glass
batch
glass melt
redox potential
Opis:
Omówiono zagadnienia związane z rolą stanu redox w procesie topienia szkieł przemysłowych oraz z oznaczaniem i kontrolą potencjału utleniająco-redukującego (potencjału redox) - jednego z najbardziej istotnych parametrów tego procesu. Szczególną uwagę zwrócono na metody określania potencjału redox szkieł przemysłowych. Omówiono i porównano ze sobą metody empiryczne, metodę spektrometryczną oraz metodę online pomiaru ciśnieniowej aktywności tlenu w masie szklanej.
There have been described problems connected with function of the redox-state in the melting process of the commercial glasses and with determination and control of redox potential - one of the most important parameters of this process. Especially, attention has been devoted to the methods of determination redox potential of the commercial glasses. This article describes and compares the empirical method, spectrometric method and method of measurement online of the chemical activity of oxygen dissolved in the glass melt.
Źródło:
Prace Instytutu Szkła, Ceramiki, Materiałów Ogniotrwałych i Budowlanych; 2008, R. 1, nr 2, 2; 105-117
1899-3230
Pojawia się w:
Prace Instytutu Szkła, Ceramiki, Materiałów Ogniotrwałych i Budowlanych
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Constraints of the MAX4781 CMOS Solution for Electrode Switching in Multilayer Electrochemical Probes
Autorzy:
Cimpoiasu, V.M.
Radulescu, F.
Nealson, K.H.
Moga, Ioana Corina
Popa, R.
Powiązania:
https://bibliotekanauki.pl/articles/2106598.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sensor
SPEAR
multielectrode
redox interface
sediments
electrochemical gradients
Opis:
The most common means to analyze redox gradients in sediments is by push/pulling electrochemical probes through sediment’ strata while repeating measurements. Yet, as electrodes move up and down they disrupt the texture of the sediment layers thus biasing subsequent measurements. This makes it difficult to obtain reproducible measurements or to study the evolution of electrochemical gradients. One solution for solving this problem is to eliminate actuators and electrode movements altogether, while instead deploying probes with numerous electrodes positioned at various depths in the sediment. This mode of operation requires electrode switching. We discuss an electrode-switching solution for multi-electrode probes, based on Complementary Metal-Oxide-Semiconductor (CMOS) multiplexors. In this solution, electrodes can be individually activated in any order, sequence or time frame through digital software commands. We discuss constraints of CMOS-based multilayer electrochemical probes during cyclic voltammetry.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 2; 691--694
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Interactions of dietary carotenoids with singlet oxygen (1O2) and free radicals: potential effects for human health
Autorzy:
Böhm, Fritz
Edge, Ruth
Truscott, T
Powiązania:
https://bibliotekanauki.pl/articles/1039764.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
dietary carotenoids
singlet oxygen
free radicals
redox potentials
Opis:
The dietary carotenoids provide photoprotection to photosynthetic organisms, the eye and the skin. The protection mechanisms involve both quenching of singlet oxygen and of damaging free radicals. The mechanisms for singlet oxygen quenching and protection against free radicals are quite different - indeed, under some conditions, quenching of free radicals can lead to a switch from a beneficial anti-oxidant process to damaging pro-oxidative situation. Furthermore, while skin protection involves β-carotene or lycopene from a tomato-rich diet, protection of the macula involves the hydroxyl-carotenoids (xanthophylls) zeaxanthin and lutein. Time resolved studies of singlet oxygen and free radicals and their interaction with carotenoids via pulsed laser and fast electron spectroscopy (pulse radiolysis) and the possible involvement of amino acids are discussed and used to (1) speculate on the anti- and pro-oxidative mechanisms, (2) determine the most efficient singlet oxygen quencher and (3) demonstrate the benefits to photoprotection of the eye from the xanthophylls rather than from hydrocarbon carotenoids such as β-carotene.
Źródło:
Acta Biochimica Polonica; 2012, 59, 1; 27-30
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The key role of the redox status in regulation of metabolism in photosynthesizing organisms
Autorzy:
Kornas, Andrzej
Kuźniak, Elżbieta
Ślesak, Ireneusz
Miszalski, Zbigniew
Powiązania:
https://bibliotekanauki.pl/articles/1040395.pdf
Data publikacji:
2010
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
evolution
chloroplast
ROS
redox status
photosynthesis
hydrogen peroxide
Opis:
The redox status of the cell is described by the ratio of reduced to non-reduced compounds. Redox reactions which determine the redox state are an essential feature of all living beings on Earth. However, the first life forms evolved under strongly anoxic conditions of the young Earth, and the redox status probably was based on iron and sulphur compounds. Nowadays, redox reactions in cells have developed in strict connection to molecular oxygen and its derivatives i.e. reactive oxygen species (ROS). Oxygen has started to accumulate on the Earth due to oxygenic photosynthesis. All aspects of aerobic life involve ROS, reactive nitrogen species (RNS), antioxidants and redox regulation. Many different redox-active compounds are involved in the complex of redox processes, including pyridine nucleotides, thioredoxins, glutaredoxins and other thiol/disulphide-containing proteins. Redox regulation is integrated with the redox-reactions in photosynthesis and respiration to achieve an overall energy balance and to maintain a reduced state necessary for the biosynthetic pathways that are reductive in nature. It underlies the physiological and developmental flexibility in plant response to environmental signals.
Źródło:
Acta Biochimica Polonica; 2010, 57, 2; 143-151
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
XAFS in the tracking of reactions in aqueous solution: a case of redox reaction between [AuCl4]- complex ions and ethanol
Metoda XAFS w badaniach reakcji zachodzących w roztworach wodnych: przykład reakcji redoks pomiędzy jonami kompleksowymi [AuCl4]- i alkoholem etylowym
Autorzy:
Pacławski, K.
Sikora, M.
Powiązania:
https://bibliotekanauki.pl/articles/355830.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
XAFS
XANES
redox reaction
gold complex ions
ethanol
Opis:
In this work the potential application of synchrotron radiation in the studies of reaction kinetics in aqueous phase were presented. After short introduction describing principles of technique and potential application of XAFS for the structural studies of reacting species, the experimental results of kinetic measurements of reaction between gold(III) chloride complex ions and ethanol were presented. Analyzing the changes of absorption intensity in the XANES spectra registered at Au-L &sub3; edge during the reaction, the change of the valence state of Au central atom (form 3+to 0) of reacting complex ion was determined. Moreover, empirical XANES data gave the chance to register the kinetic curve and to determine the rate constant of the studied reaction. It was found that reaction is relatively slow (second-order rate constant k = 3.66 · 10 &sup-5; M ;sup-1;s) and lead to the gold metallic phase formation in the system. Applying the continuous-flow method, within the first 600 ms of reaction the changes in XANES spectra were registered. From the obtained results, supported with numerical calculations, two intermediate forms of adducts appearing prior the electron transfer were suggested. It was concluded that when the classic methods, e.g. UV-Vis spectrophotometry, cannot be applied to studies of kinetics of reactions in aqueous solution, the XAFS technique can be a valuable and substitutive (or supplementary) tool for such measurements.
W pracy przedstawiono potencjalne możliwości zastosowania promieniowania synchrotronowego w badaniach nad kinetyka reakcji przebiegających w roztworach wodnych. We wstępie, omówiono podstawy techniki rentgenowskiej analizy struktury nadsubtelnej (XAFS) i jej możliwości zastosowania w badaniach strukturalnych związków chemicznych w fazie ciekłej. Zaprezentowano również dane eksperymentalne z pomiarów XAFS dotyczące kinetyki reakcji pomiędzy chlorkowymi kompleksami złota(III) i alkoholem etylowym. Z analizy zmian intensywności absorpcji widm XANES rejestrowanych przy krawędzi L &sub3; złota określono zmianę stopnia utlenienia atomu centralnego Au (z 3+ do 0) reagującego kompleksu. Ponadto, dane empiryczne pozwoliły na wyznaczenie krzywej kinetycznej oraz określenie drugorzędowej wartości stałej szybkości reakcji (k = 3.66 ·10 &sup-5; M &sup-1;s). W wyniku analizy widm XANES potwierdzono powstawanie faza metalicznej złota w układzie. Stosując metodę ciągłego przepływu reagentów, zarejestrowano zmiany w widmie XANES w ciągu 600 ms od rozpoczęcia reakcji.Na podstawie zarejestrowanych widm oraz przeprowadzonych obliczeń numerycznych zasugerowano dwie możliwe struktury adduktu tworzącego się przed właściwym transferem elektronu w reakcji redoks. Z przeprowadzonych eksperymentów wynika, ze w układach, w których nie jest możliwe stosowanie spektrofotometrii UV-Vis, metoda XAFS może być zastępczym i obiecującym narzędziem do badań kinetyki reakcji.
Źródło:
Archives of Metallurgy and Materials; 2012, 57, 4; 1011-1020
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ czynników technologicznych na potencjał redox stopu szklanego
Influence of some technological factors on the redox potential values of the glass melt
Autorzy:
Zawiła, J.
Powiązania:
https://bibliotekanauki.pl/articles/392516.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Ceramiki i Materiałów Budowlanych
Tematy:
stop szklany
skład chemiczny
potencjał redox
czynnik technologiczny
pierwiastek wielowartościowy
glass melt
chemical composition
redox potential
technological factor
polivalent element
Opis:
Omówiono zagadnienia związane z rolą, jaką odgrywa stan redox w procesie topienia szkieł użytkowych. Przedstawiono pojęcie i najważniejsze reakcje redox zachodzące w trakcie topienia składników zestawu, omówiono także wpływ niektórych czynników na wartość potencjału redox. Szczególny nacisk położono na: wpływ składu chemicznego zestawu, skład atmosfery nad lustrem szkła, dodatek stłuczki szklanej oraz zanieczyszczeń organicznych w niej zawartych.
There have been described problems connected with function of the redox-state in the melting process of the commercial glasses. Definition and the most important redox-reactions occurring during melting process of glass batch components have been presented as well as influence of some essential factors on the redox-potential values. Especially, attention has been devoted the problems connected with influence of such factors as chemical composition of glass batch, composition of gas atmosphere above the surface of the melt, application and organic contaminations of the cullet.
Źródło:
Prace Instytutu Szkła, Ceramiki, Materiałów Ogniotrwałych i Budowlanych; 2008, R. 1, nr 1, 1; 45-57
1899-3230
Pojawia się w:
Prace Instytutu Szkła, Ceramiki, Materiałów Ogniotrwałych i Budowlanych
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Potential immune modulating properties and antioxidant activity of supplementing commercially available lactoferrin and/orLactobacillus sp. in healthy Ossimi lambs
Autorzy:
El-Ashker, M.
Risha, E.
Abdelhamid, F.
Ateya, A.
Powiązania:
https://bibliotekanauki.pl/articles/2087639.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
immunity
lactoferrin
lambs
redox status
probiotic
RT-PCR
sheep
Źródło:
Polish Journal of Veterinary Sciences; 2018, 21, 4; 705-713
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Gwałtowne reakcje redoksowe - okiełznane
Taming the dramatic redox reactions
Autorzy:
Grochala, Wojciech
Powiązania:
https://bibliotekanauki.pl/articles/1409905.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
reakcje redoksowe
układy domieszkowane chemicznie
redox reactions
chemically doped systems
Opis:
This popular-scientific account is focused on electron-transfer (redox) reactions, and on systems exhibiting mixed- or intermediate valence, in particular on chemically doped systems. Selected applications of such systems were presented together with the associated scientific and technological breakthroughts of the XX and XXI century. The novel theoretical concept of continuous doping (charge injection) was described based on spatial separation of oxidzers and reductor in the nanoscale. These novel systems were described in comparison with related electrochemical batteries, capacitors and n/p junctions.
Źródło:
Wiadomości Chemiczne; 2021, 75, 5-6; 755-769
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geochemistry of Middle Jurassic mudstones (Kraków-Częstochowa area, southern Poland): interpretation of the depositional redox conditions
Autorzy:
Szczepanik, P.
Witkowska, M.
Sawłowicz, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2059479.pdf
Data publikacji:
2007
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Middle Jurassic
Częstochowa Clay Formation
palaeoenvironment
geochemical parameters
redox conditions
Opis:
Middle Bathonian iron-bearing dark grey mdstones and claystones from the Kraków-Czestochowa Upland (southern Poland) were subjected to geochemical and mineralogical study in order to evaluate palaeo-redox conditions of their deposition and diagenesis. They are mainly composed of kaolinite, with smaller amounts of other clay minerals and detrital quartz. Organic matter is composed of type III and/or IV kerogen and its d13C is between -23 and -24‰, suggesting a mainly terrigenous source, with a possible admixture of marine input. Most geochemical parameters: (total organic carbon) TOC/S, U/Th, Ni/Co, V/Cr, (Cu+Mo)/Zn ratios, authigenic uranium content, and Fe-TOC-S relationship, indicate deposition under oxygenated bottom water conditions. By contrast, DOP (degree of pyritization) and V/V+Ni indices suggest a dysoxic environment. However, DOP probably reflects redox conditions in the sediment during diagenesis rather than in the over laying water column. The composition of the organic matter and the domination of pyrite euhedra over framboids indicates that the V/V+Ni ratio may not be reliable for determination of redox conditions in the rocks studied. There is no significant difference between the geochemical indices of host rocks with nodules and those with out them.
Źródło:
Geological Quarterly; 2007, 51, 1; 57-66
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geochemical and faunal proxies in the Westphalian A (Langsettian) marine horizon of the Lublin Coal Basin
Autorzy:
Krzeszowska, E.
Powiązania:
https://bibliotekanauki.pl/articles/2060565.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
inorganic geochemistry
palaeo-redox conditions
Dunbarella horizon
Lublin Coal Basin
Opis:
The uppermost Westphalian marine horizon (Dunbarella horizon) is especially important for correlation of Carboniferous deposits in the Lublin Coal Basin and in other basins of the Northwest European Carboniferous Basin. The Dunbarella horizon is characterized by cyclic sedimentation and consequent faunal spectrum variability, typical for Westphalian marine horizons of northwestern Europe. Palaeontological study of the Dunbarella horizon showed the presence of macrofauna representing different palaeoenvironments, from marine to brackish (non-marine) and freshwater conditions. The vertical sea level fluctuations and changes in seawater salinity resulting in palaeontological record changes do not link with geochemical proxies. TOC, redox-sensitive trace element concentrations, and V/Cr, Ni/Co and V/(V + Ni) ratios generally suggest that the Dunbarella horizon sediments were deposited under predominantly oxic conditions (with local exceptions during the initial phase of the Dunbarella ingression; Kopina 1 borehole).
Źródło:
Geological Quarterly; 2017, 61, 4; 751--764
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reliability evaluation of renewable energy-based power system containing energy storage
Autorzy:
Ghaeedi, A.
Noroozi, E.
Powiązania:
https://bibliotekanauki.pl/articles/103047.pdf
Data publikacji:
2016
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
reliability evaluation
renewable resources
vanadium redox batteries
fuzzy clustering method
Opis:
In recent years, renewable energy based power plants, especially wind and solar farms are increasingly installed and operated for electric power generation. Uncertainty nature associated to the generated power of these power plants, arisen from variability of wind speed or solar radiation, effects on different aspects of power system such as reliability, operation, dynamic and so on. Energy storages in connection with renewable power plants can reduce the variability and uncertainty nature of these renewable resources. In recent years the flow batteries such as vanadium redox (VR) with large capacities are developed and so in this paper effect of this largecapacity energy storages on the reliability performance of power system containing large-scale wind and photovoltaic (PV) farms are investigated. The renewable energy-based power plants and also energy storages are different from conventional units, so, for study of power system containing these resources new methods and techniques must be developed. To this end in this paper for reliability evaluation of renewable-energy based power system containing energy storage, an analytical approach is proposed. This approach can be employed both in planning and also operation studies of the power system when large scale wind and photovoltaic farms with energy storages exist. Data associated to wind speed of Manjil and solar radiation of Jask regions both in Iran are utilized for studying the reliability evaluation of RBTS and also IEEERTS in planning phase.
Źródło:
Advances in Science and Technology. Research Journal; 2016, 10, 32; 198-205
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Redox-regulation of S-nitrosoglutathione reductase
Autorzy:
Holzmeister, C.
Kovacs, I.
Romling, G.
Wirtz, M.
Durner, J.
Lindermayr, C.
Powiązania:
https://bibliotekanauki.pl/articles/80722.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
nitric oxide
signalling molecule
S-nitrosoglutathione
protein
glutathione level
redox signalling
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
N2O emission and sorption in relation to soil dehydrogenase activity and redox potential
Autorzy:
Wlodarczyk, T.
Stepniewski, W.
Brzezinska, M.
Kotowska, U.
Powiązania:
https://bibliotekanauki.pl/articles/26185.pdf
Data publikacji:
2002
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
emission
sorption
soil
nitrous oxide
redox potential
brown sandy soil
dehydrogenase activity
Źródło:
International Agrophysics; 2002, 16, 3
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trace element variations as a proxy for reconstruction of palaeoenvironmental changes during the Late Aeronian faunal and carbon isotope perturbations: new data from the peri-Gondwanan region
Autorzy:
Pašava, J.
Frýda, J.
Štorch, P.
Powiązania:
https://bibliotekanauki.pl/articles/2060353.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Aeronian
graptolite mass extinction
redox-sensitive trace elements
Barrandian area
Bohemian Massif
Opis:
Trace element variations in the Upper Aeronian (Llandovery, Lower Silurian), deep-water, black shale succession of the Barrandian area (Perunica) were studied across an interval associated with a graptolite mass extinction and global, positive carbon isotope anomaly. The main aim of the paper is to test whether distinct changes in graptolite diversity during Late Aeronian were linked with changes in deep sea water oxygenation. Using multiple geochemical proxies we documented high-frequency changes in oxygenation of sea water from sediments of the convolutus to linnaei (guerichi) biozones. Detailed comparison of graptolite diversity with those high-frequency oxygenation changes suggests that the long-term and step-wise Late Aeronian graptolite crisis was not significantly influenced by changes in oxygen level and thus it probably resulted by another causes. The collapse of global carbon cycle during the Late Aeronian probably only temporarily increased extinction rate of the long-term graptolite crisis and considerably decreased evenness of the uppermost Aeronian graptolite communities. The Aeronian graptolite mass extinction was thus primarily driven by other biotic and/or abiotic causes
Źródło:
Geological Quarterly; 2017, 61, 1; 91--98
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ordovician Jeleniów Claystone Formation of the Holy Cross Mountains, Poland - Reconstruction of redox conditions using pyrite framboid study
Autorzy:
Smolarek, J.
Marynowski, L.
Trela, W.
Powiązania:
https://bibliotekanauki.pl/articles/100786.pdf
Data publikacji:
2014
Wydawca:
Uniwersytet Śląski. Wydział Nauk o Ziemi
Tematy:
ordowik
piryt
Jeleniów
Góry Świętokrzyskie
ordovician
pyrite framboids
redox conditions
Jeleniów Formation
Opis:
The aim of this research is to reconstruct palaeoredox conditions during sedimentation of the Jeleniów Claystone Formation deposits, using framboid pyrite diameter measurements. Analysis of pyrite framboids diameter distribution is an effective method in the palaeoenvironmental interpretation which allow for a more detailed insight into the redox conditions, and thus the distinction between euxinic, dysoxic and anoxic conditions. Most of the samples is characterized by framboid indicators typical for anoxic/euxinic conditions in the water column, with average (mean) values ranging from 5.29 to 6.02 µm and quite low standard deviation (SD) values ranging from 1.49 to 3.0. The remaining samples have shown slightly higher values of framboid diameter typical for upper dysoxic conditions, with average values (6.37 to 7.20 µm) and low standard deviation (SD) values (1.88 to 2.88). From the depth of 75.5 m till the shallowest part of the Jeleniów Claystone Formation, two samples have been examined and no framboids has been detected. Because secondary weathering should be excluded, the lack of framboids possibly indicates oxic conditions in the water column. Oxic conditions continue within the Wólka Formation based on the lack of framboids in the ZB 51.6 sample.
Źródło:
Contemporary Trends in Geoscience; 2014, 3, 1; 59-67
2299-8179
Pojawia się w:
Contemporary Trends in Geoscience
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Możliwość wykorzystania owoców suszonych jako źródła składników bioaktywnych do stabilizacji tłuszczu w produktach mięsnych typu pasztetowa
Dried fruits as a source of ingredients with antioxidant potential and the possibility of their use to stabilize fat in meat products such as liver pâté
Autorzy:
Bilska, Agnieszka
Kobus-Cisowska, Joanna
Kasieńczar, Karolina
Kluczyńska, Loretta
Neumann, Małgorzata
Powiązania:
https://bibliotekanauki.pl/articles/2159201.pdf
Data publikacji:
2022-12-22
Wydawca:
Centrum Doradztwa Rolniczego w Brwinowie. Oddział w Poznaniu
Tematy:
suszone owoce z aronii
aceroli
borówki i dzikiej róży
pasztetowa
liczba nadtlenkowa
TBARS
potencjał redox
chokeberry
acerola
blueberry and wild rose extracts
liver pâté
peroxide
value
redox potential
Opis:
Celem pracy była ocena wpływu owoców suszonych z aronii, aceroli, borówki i dzikiej róży na zmiany zawartości pierwotnych i wtórnych produktów utleniania tłuszczu oraz wartości pH, aw, potencjału redox w przechowywanych wędlinach podrobowych typu pasztetowa, otrzymanych z częściową wymianą tłuszczu zwierzęcego tłuszczem roślinnym. Dodatek suszonych owoców pozytywnie wpłynął na spowolnienie procesu powstawania produktów utleniania tłuszczu. Stwierdzono, że wybrane dodatki wpłynęły istotnie na badane parametry i spowodowały m.in. podwyższenie potencjału oksydacyjno-redukcyjnego w analizowanych produktach. Dodatkami, które wywarły największy wpływ na parametry fizyczne badanych produktów mięsnych były acerola (Malpighia emarginata) oraz dzika róża (Rosa canina L.).
The aim of the study was to evaluate the effect of dried fruits from chokeberry, acerola, blueberry and rosehip on storage changes of primary and secondary products of fat oxidation as well as the pH value, aw, redox potential in of liver pâté, obtained with partial replacement of animal fat with vegetable fat. The addition of dried fruit had a positive effect on slowing down the formation of fat oxidation products. It was found that the selected additives had a significant effect on the tested parameters and caused, among others, increasing the oxidation-reduction potential in the analyzed products. Acerola (Malpighia emarginata) and wild rose (Rosa canina L.) turned out to be the additive that had the greatest impact on the physical parameters of the meat products tested.
Źródło:
Zagadnienia Doradztwa Rolniczego; 2022, 109, 3; 33-47
1232-3578
2719-8901
Pojawia się w:
Zagadnienia Doradztwa Rolniczego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Action mechanisms of antioxidant and prooxidants properties of flavonoids as model for understanding the oxygen metabolism
Autorzy:
Espindola, C.
Powiązania:
https://bibliotekanauki.pl/articles/81104.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
redox potential
flavonoids
free radical
antioxidant
prooxidant
oxygen metabolism
lipid peroxidation
hydrophobicity
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Energy storage systems
Autorzy:
Arrebola Haro, José Carlos
Powiązania:
https://bibliotekanauki.pl/chapters/4138978.pdf
Data publikacji:
2019
Wydawca:
Politechnika Białostocka. Oficyna Wydawnicza Politechniki Białostockiej
Tematy:
battery
acid-lead battery
lithium ion battery
UPS
anodic materials
redox flow batteries
Opis:
This chapter attempts to shed some light on energy storage systems with stationary and building applications. Among these, we must highlight the batteries, from the oldest ones which were employed for these purposes, to those of lead-acid, or those that harbour a very promising future, the redox flow batteries, RFB; finally, we cannot forget the lithium-ion batteries, widely used today.
Źródło:
Buildings 2020+. Energy sources; 255-271
9788365596727
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
DYn-2 is an excellent chemical reporter for the Arabidopsis sulfenome
Autorzy:
Akter, M.
Wahni, K.
Martinez-Acedo, P.
Carroll, K.
van Breusegem, F.
Messens, J.
Powiązania:
https://bibliotekanauki.pl/articles/80760.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
oxidative stress
redox signal
Arabidopsis thaliana
DYn-2 reporter
purification
sulphenome
stress tolerance
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Redox control of photosynthetic acclimation in plants
Autorzy:
Pfannschmidt, T.
Powiązania:
https://bibliotekanauki.pl/articles/81175.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
redox control
photosynthesis
acclimation
plant
dynamic process
stoichiometry
nuclear gene
stress-resistant crop
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Methane and carbon dioxide emissions from a loess soil treated with municipal waste water after second step of purification
Autorzy:
Stepniewska, Z.
Nosalewicz, M.
Ostrowska, A.
Powiązania:
https://bibliotekanauki.pl/articles/24681.pdf
Data publikacji:
2003
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
loess soil
emission
carbon dioxide
waste water
municipal waste water
purification
methane
redox potential
Źródło:
International Agrophysics; 2003, 17, 1
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sensitivity and response to hydrogen peroxide of nuclei of sunflower seeds
Autorzy:
Kalemba, E.
Meimoun, P.
Bailly, C.
Powiązania:
https://bibliotekanauki.pl/articles/81166.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
reactive oxygen species
signalling molecule
redox signalling
germination
sunflower seed
nucleus
hydrogen peroxide
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical and experimental ground of the fuel energy efficiency improvement by an activation of the burning reaction molecules - reagents
Autorzy:
Kovalyshyn, B.
Powiązania:
https://bibliotekanauki.pl/articles/410674.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Oddział w Lublinie PAN
Tematy:
wysokie napięcia
pole elektryczne
wydajność energetyczna
high voltage
electric field
activation
energy efficiency
redox
Opis:
In theory and experimentally a method of fuel options energy efficiency rise due to an activation of burning reaction molecules-reagents under high voltage electric field action is grounded. A variant of the technical realization of the offered method is described.
Źródło:
ECONTECHMOD : An International Quarterly Journal on Economics of Technology and Modelling Processes; 2012, 1, 1; 63-66
2084-5715
Pojawia się w:
ECONTECHMOD : An International Quarterly Journal on Economics of Technology and Modelling Processes
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Glutathione-dependent regulation of cell proliferation and root meristem development
Autorzy:
Schnaubelt, D.
Queval, G.
Dong, Y.
Diaz-Vivancos, P.
Hannah, M.
Foyer, C.
Powiązania:
https://bibliotekanauki.pl/articles/79874.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
cell proliferation
root meristem
Arabidopsis thaliana
green fluorescent protein
nucleus
cytoplasm
glutathione redox potential
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selected chemical and physicochemical properties of sediments in Moszne Lake and mire (Polesie National Park)
Autorzy:
Tokarz, E.
Urban, D.
Szafranek-Nakonieczna, A.
Stepniewska, Z.
Powiązania:
https://bibliotekanauki.pl/articles/961605.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Warmińsko-Mazurski w Olsztynie / Polskie Towarzystwo Magnezologiczne im. Prof. Juliana Aleksandrowicza
Tematy:
lake
sediment
chemical property
physicochemical property
Lake Moszne
mire
pH
redox potential
Polesie National Park
Opis:
Properties of peat reflect the peat-forming environment, peat development processes and the types of peat-forming plant. They also enable peat classification and quality evalution. Investigation of the physicochemical properties of organic matter is the key to understanding the history, evolution and geology of bogs. The purpose of this study was to determine some physicochemical properties, such as pH, Eh, electrolytic conductivity, carbon forms in water extracts and dry peat samples (TOC, IC, TC), degree of decomposition, macrofossil plant analysis and ash content, in a whole stratigraphic profile of bog sediment located near Lake Moszne. The research comprised a 17.5 ha lake, which was described in the 1990s as a dystrophic one, and the adjacent mires. The open water surface of the lake is surrounded by a 30–150 m wide belt of floating mat, composed of peatmosses and sedges with the dominant Sphagno-Caricetum rostratae association, all representing vegetation typical for transitional mires. These communities are most often found in the Polesie Lubelskie Region, in old lakes, and usually on their floating mat. The research material was collected from such a site. The analysis demonstrated acidic pH (4.17 in profile I and 4.08 in profile II, respectively) in the layer of 0-0.65 m, whilst from the 1.50 m depth to the mineral bottom the pH increased to nearly neutral (pH = 6.62 ± 0.18 in profile I and pH = 6.45 ± 0.12 in profile II). Redox potential in the surface layer corresponds to good oxygenation of mineral soils: 577 mV and 490 mV for profile I and II, respectively. A nearly linear decrease of Eh was observed to about 118 mV at the depth of 2.50 m. Lower than that, down to the depth of 3.50 m, the Eh value was stabilized. The graphical presentation of the Eh-pH relationship shows that in both cases (profiles I and II) aerobiosis prevails to the depth of 0.45-0.65 m, confirming that oxygen continues to be the final electron acceptor.
Źródło:
Journal of Elementology; 2015, 20, 4
1644-2296
Pojawia się w:
Journal of Elementology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
GGT-assisted glutathione degradation is functional to apoplastic redox control and seed storage proteins accumulation
Autorzy:
Trentin, A.
Pivato, M.
Giaretta, S.
Fabrega-Prats, M.
Arrigoni, G.
Prasad, D.
Masi, A.
Powiązania:
https://bibliotekanauki.pl/articles/80200.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
gamma-glutamyl cycle
redox control
seed storage
abiotic stress
biotic stress
carbohydrate metabolism
photosynthesis
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Implication of early nitric oxide and reactive oxygen species generation in potato resistance to Phytophthora infestans
Autorzy:
Abramowski, D.
Arasimowicz-Jelonek, M.
Floryszak-Wieczorek, J.
Powiązania:
https://bibliotekanauki.pl/articles/80727.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
nitric oxide
reactive oxygen species
potato resistance
Phytophthora infestans
reactive nitrogen species
redox signalling
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High temperature inhibition of potato tuberisation is associated with altered redox status and associated transcript profiles
Autorzy:
Hancock, R.
Morris, W.
Ducreux, L.
Morris, J.
Usman, M.
Verrall, S.
Hedley, P.
Taylor, M.
Powiązania:
https://bibliotekanauki.pl/articles/81094.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
abiotic stress
biotic stress
potato crop
temperature stress
tuberization
redox state
thioredoxin
glutaredoxin
peroxiredoxin
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Redox control of gene expression during the vegetative-generative transition in wheat
Autorzy:
Koscy, G.
Boldizsar, A.
Carrera, D.
Gulyas, Z.
Szalai, G.
Galiba, G.
Powiązania:
https://bibliotekanauki.pl/articles/81211.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
redox control
gene expression
winter cereal
wheat
vernalization
vegetative-generative transition
glutathione
hydrogen peroxide
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badania potencjału redoks na przykładzie sudeckich wód leczniczych
Research of redox potential on the example of curativewaters in the Sudetes Mts., Poland
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2074741.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
chemizm wód podziemnych
ptencjał redoks
wody lecznicze
Sudety
groundwater chemistry
redox potential
curative water
Sudetes
Opis:
In Poland, the redox potential (EH) is seldomly measured in groundwater. Since the year 2006 determination of redox potential is required for documenting properties of curative mineral waters. Investigations of redox conditions in groundwater need both proper measurement and interpretation. In the paper, crucial questions of: 1) redox equilibrium in groundwater, 2) field measurement, 3) correction methods, and 4) EH interpretation are presented. Some aspects of applying the redox potential for interpreting groundwater chemistry and using geochemical modelling are illustrated by hydrochemical data of curative waters from spas in the Sudetes Mts., SW Poland. Main reasons of the common redox non-equilibrium found in groundwater are co-existence of numerous aqueous redox pairs and usually non-equilibrium in particular redox pairs. Redox determinations have to be done in the field, and require extreme cleanness and precision, e.g., measuring without contact with the atmospheric air. Field measurements must be corrected to the standard hydrogen electrode, considering: type of reference electrode, concentration of electrode filling solution, type of standard redox solution, and water temperature. The redox potential has been measured in water at first from all the Sudetic spas, totally in 33 water intakes. In curative waters from the Sudetes corrected EH ranges between –159 mV and +343 mV. Usually, thermal waters show lower EH values than cold, CO2-rich waters. The lowest redox potential was found in the hottest thermal waters, i.e., in water from Zdzisław intake (in Lądek Zdrój) and C-2 intake (in Cieplice Śląskie Zdrój). Generally, the higher the pH, the lower the EH in groundwater. Methods of geochemical modelling, which are often and often applied in groundwater research, also require the EH determination. Information about EH are used in the calculation of speciation models of water, and affect the results of whole geochemical modelling as well as evaluations of the saturation state. The speciation-solubility modelling for the Sudetic curative waters, presented in the paper, shows that the proper correction of field EH measurement determines the quality of calculations. Improperly corrected EH values might lead to species activity errors, even up to several order of magnitudes, and erroneous interpretation of the mineral phases stability in the hydrogeochemical system.
Źródło:
Przegląd Geologiczny; 2010, 58, 1; 46-53
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fenomen kambryjskich łupków z Burgess w Górach Skalistych (Kanada) : przegląd fauny, środowiska sedymentacji i zjawisk tafonomicznych
The Cambrian Burgess Shale phenomenon of the Rocky Mountains (Canada) : an overview of the fauna, sedimentary and taphonomic conditions
Autorzy:
Śliwiński, M. G.
Żylińska, A.
Powiązania:
https://bibliotekanauki.pl/articles/2075033.pdf
Data publikacji:
2013
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Cambrian
Burgess Shale
Rocky Mountains
Lagerstätten
redox
kambr
łupki z Burgess
Góry Skaliste
natlenienie wód
Opis:
The Burgess Shale of the Canadian Rocky Mts is one of the most well-known occurrences of Cambrian strata exhibiting exceptional preservation of a soft-bodied fauna. While Lagerstätten of the Burgess Shale-type fauna have been recognized in almost all parts of the world and in all Cambrian series, the circumstances and mechanisms allowing for such a unique mode of preservation have remained enigmatic. Of particular debate has been the reconstruction of prevailing redox conditions. This brief contribution overviews the fauna and recent advances towards understanding the sedimentary and taphonomic conditions prevailing during deposition.
Źródło:
Przegląd Geologiczny; 2013, 61, 12; 746--754
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
PCBs in phytoplankton in the Odra Estuary
Autorzy:
Konat-Stepowicz, J.
Kowalewska, G.
Powiązania:
https://bibliotekanauki.pl/articles/48775.pdf
Data publikacji:
2003
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
polychlorinated biphenyl
turbidity
temperature
Odra estuary
pigment content
salinity
Baltic Sea
phytoplankton
redox potential
oxygen
Opis:
Eleven PCB congeners were determined in phytoplankton samples collected from the Odra Estuary at 9 stations in 2001–2002. The PCB concentrations were related to the temperature, turbidity, salinity, oxygen and redox potential of the water as well as to the pigment content in the samples. The results indicate that phytoplankton and the detritus derived from it play a crucial role in the distribution of PCBs, their transfer from the water column to sediments and from the Estuary to the sea. The species composition of the phytoplankton occurring in this area could also be very important as regards the sorption of PCBs.
Źródło:
Oceanologia; 2003, 45, 3
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chromium and its forms in soils in the proximity of the old tannery waste lagoon
Autorzy:
Stepniewska, Z.
Bucior, K.
De Boodt, M.
Powiązania:
https://bibliotekanauki.pl/articles/26530.pdf
Data publikacji:
2001
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
chromium
natural environment
soil
atmosphere
tannery waste
water
redox potential
hazard
pH condition
heavy metal
Źródło:
International Agrophysics; 2001, 15, 2
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of multiple-area renewable integrated hydro-thermal system considering artificial rabbit optimized PI (FOPD) cascade controller and redox flow battery
Autorzy:
Saha, Arindita
Chiranjeevi, Tirumalasetty
Devarapalli, Ramesh
Babu, Naladi Ram
Dash, Puja
Garcìa Màrquez, Fausto Pedro
Powiązania:
https://bibliotekanauki.pl/articles/27324511.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
solar thermal
automatic generation control
geothermal
artificial rabbit optimization
redox flow battery
PI(FOPD) controller
Opis:
The current task explores automatic generation control knowledge under old-style circumstances for a triple-arena scheme. Sources in area-1 are thermal-solar thermal (ST); thermalgeothermal power plant (GPP) in area-2 and thermal-hydro in area-3. An original endeavour has been set out to execute a new performance index named hybrid peak area integral squared error (HPA-ISE) and two-stage controller with amalgamation of proportional-integral and fractional order proportional-derivative, hence named as PI(FOPD). The performance of PI(FOPD) has been compared with varied controllers like proportional-integral (PI), proportional-integralderivative (PID). Various investigation express excellency of PI(FOPD) controller over other controller from outlook regarding lessened level of peak anomalies and time duration for settling. Thus, PI(FOPD) controller’s excellent performance is stated when comparison is undergone for a three-area basic thermal system. The above said controller’s gains and related parameters are developed by the aid of Artificial Rabbit Optimization (ARO). Also, studies with HPA-ISE enhances system dynamics over ISE. Moreover, a study on various area capacity ratios (ACR) suggests that high ACR shows better dynamics. The basic thermal system is united with renewable sources ST in area-1 also GPP in area-2. Also, hydro unit is installed in area-3. The performance of this new combination of system is compared with the basic thermal system using PI(FOPD) controller. It is detected that dynamic presentation of new system is improved. Action in existence of redox flow battery is also examined which provides with noteworthy outcome. PI(FOPD) parameters values at nominal condition are appropriate for higher value of disturbance without need for optimization.
Źródło:
Archives of Control Sciences; 2023, 33, 4; 861--884
1230-2384
Pojawia się w:
Archives of Control Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wplyw form w podlozu na potencjal redoks i wzrost biomasy Azolla filiculoides Lam
Influence of nitrogen forms on redox potential of the nutrient solution and biomass of Azolla filiculoides Lam
Autorzy:
Bennicelli, R P
Powiązania:
https://bibliotekanauki.pl/articles/1401762.pdf
Data publikacji:
2000
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
paprotka wodna
Azolla filiculoides
sinice
Anabaena
biomasa
wzrost roslin
potencjal wzrostu
wykorzystanie
nawozy zielone
azot
azot azotanowy
potencjal redox
water fern
Cyanoprokaryota
biomass
plant growth
plant use
nitrogen
green fertilizer
nitrate nitrogen
redox potential
Opis:
Azolla filiculoides Lam. jest paprotką wodną współżyjącą z azot-wiążącą sinicą Anabaena, która budzi zainteresowania ze względu na możliwość jej wykorzystania w postaci nawozu zielonego. Azolla stała się obiektem badań na całym świecie. Wiedza na temat fizjologicznych i ekologicznych czynników wpływających na wzrost paproci jest istotna w badaniach przyrodniczych ukierunkowanych na jej praktyczne stosowania. Celem tej pracy było zbadanie w warunkach kontrolowanych wpływu różnych form azotu na jego właściwości oksydoredukcyjne (Eh) i przyrost biomasy Azolli, Stwierdzono, że optymalny zakres potencjału redoks wzrostu Azolli zawiera się w przedziale 550-600 mV, a pobór formy azotu azotanowego w podłożu wydaje się być preferowany przez paprotkę w stosunku do azotu wiązanego z atmosfery prze sinicę Anabaenę.
Azolla filiculoides Lam is a floating water fern. It has the ability to fix atmospheric nitrogen through symbiosis willi blue green algae Anabaena, therefore, il is considered an important potential source of nitrogen as green manure. Azolla stimulated many studies in all over the world. Knowledge of the physiological and ecological factors influencing the growth of the fern is therefore essential in order to enhance the azolla practical application. The greenhouse study described in this paper aimed (o evaluate and quantify the influence of different forms of nitrogen on redox potential (Eh) of the solution and Azolla biomass. An optimal redox potential range for growth of Azolla (550-600 mV) was found, and a privileged uptake of nitrate from nutrient solution versus atmosphere fixed nitrogen was observed.
Źródło:
Acta Agrophysica; 2000, 38; 7-14
1234-4125
Pojawia się w:
Acta Agrophysica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rola wolnych rodników w regulacji procesów fizjologicznych
Role of free radicals in physiological processes
Autorzy:
Gdula- Argasińska, Joanna
Tyszka- Czochara, Małgorzata
Paśko, Paweł
Opoka, Włodzimierz
Powiązania:
https://bibliotekanauki.pl/articles/1033782.pdf
Data publikacji:
2012
Wydawca:
Zakład Opieki Zdrowotnej Ośrodek Umea Shinoda-Kuracejo
Tematy:
hormeza
reaktywne formy azotu RFN
reaktywne formy tlenu RFT
regulacja procesów fizjologicznych
równowaga redox
wolne rodniki
Opis:
Free radicals containing one or more unpaired electrons have considerable reactivity. Those radicals derived from oxygen represent the most important class of such species. Free radicals generated in organism are reactive oxygen species (ROS) and reactive nitrogen species (RNS) well recognised for playing a dual role as both deleterious and beneficial species. The cumulative production of ROS/RNS is termed oxidative stress and were discovered in pathomechanism of many of diseases. It was observed that in medium concentration ROS and RNS are play a role in inflammation, apoptosis and as secondary messengers in intracellular signalling cascades.
Źródło:
Medicina Internacia Revuo; 2012, 25, 99; 41-46
0465-5435
Pojawia się w:
Medicina Internacia Revuo
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Plant contribution to methane emission after irrigation of peat soil with municipal waste water
Autorzy:
Przywara, G.
Stepniewska, Z.
Powiązania:
https://bibliotekanauki.pl/articles/24761.pdf
Data publikacji:
2002
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
peat soil
waste water
methane emission
soil
plant contribution
municipal waste water
grass
redox potential
irrigation
Źródło:
International Agrophysics; 2002, 16, 3
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dehydrogenase and catalase activity in Eutric Histosol as affected by soil temperature and water content
Autorzy:
Brzezinska, M
Stepniewska, Z.
Stepniewski, W.
Pasztelan, M.
Powiązania:
https://bibliotekanauki.pl/articles/1401863.pdf
Data publikacji:
2000
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
catalase activity
soil water
Eutric Histosol
redox potential
soil temperature
dehydrogenase activity
soil enzyme
water content
Opis:
Soil enzyme activity indicates potential of the soil to sustain biochemical processes, which are essential for the maintenance of soil fertility. Dehydrogenase activity reflects total oxidative activity of soil microflora, catalase activity is responsible for the decomposition of H2O2. Redox potential (Eh) is an index of the soil aeration status. Effects of soil temperature and water content on Eh, soil dehydrogenase activity and catalasc activity in an Eutric Histosol at three different fields planted with Papulus nigra, Salix amencana, and grasses (with Alopecurits pratensis, Phalaris arundinacea, Festuca pratensis is as dominating species) were studied at the depths of 10, 30, 50, 70 cm. Enzyme activity and redox potential showed seasonal fluctuations following natural changes of soil water content and temperature. Dehydrogenase activity was significantly correlated with soil temperature and water content (r=0.37** and r=0.27***, respectively). Redox potential showed a significant correlation with soil water content (r=-0.32*** ). Catalase activity did not exhibit any correlation with the tested parameters. The type of plantation influenced enzyme activities; tree cover was characterised by higher dehydrogenase and catalase activities than meadow soils.
Źródło:
Acta Agrophysica; 2000, 35; 31-40
1234-4125
Pojawia się w:
Acta Agrophysica
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-50 z 88

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