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Tytuł:
A method for production of nanoMOF and prelimiary characterization by selected analytical techniques
Autorzy:
Starosta, W.
Sartowska, B.
Łyczko, K.
Maurin, J.
Pawlukojć, A.
Waliś, L.
Buczkowski, M.
Powiązania:
https://bibliotekanauki.pl/articles/146902.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
HKUST-1
metal-organic frameworks (MOFs)
solvothermal method
template synthesis
Opis:
Metal-organic frameworks (MOFs) are a class of porous hybrid materials comprising metal ion-based vertices and multitopic organic ligands (linkers). The possibility of combining a wide range of metals with similarly large number of available ligands opens ways to design the structures meeting specific purposes. At present, many potential applications of MOFs may require them to be constructed at the nanometer length scale (nanoMOFs). The possibility of filling the track-etched membrane pores with MOF HKUST-1 has been demonstrated in this work.
Źródło:
Nukleonika; 2012, 57, 4; 581-583
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Anion alkoksyallenowy w syntezie związków naturalnych i ich analogów
Alkoxyallene anion in the synthesis of natural products and their analogues
Autorzy:
Busiak, B.
Utecht, G.
Jasiński, M.
Powiązania:
https://bibliotekanauki.pl/articles/172377.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
alkoksyalleny
addycja nukleofilowa
synteza organiczna
związki naturalne
związki heterocykliczne
alkoxyallenes
nucleophilic addition
organic synthesis
natural products
heterocycles
Opis:
Among diverse systems containing multiple bonds, cumulenes are recognized as the most reactive derivatives towards both nucleophilic and electrophilic agents, and for this reason, they are considered as important class of substrates for organic synthesis. Over the last three decades alkoxyallenes have been demonstrated as highly useful C3-building blocks for the construction of numerous N-, O-, and S-containing heterocycles, including enantiomerically pure compounds. Special attention has been paid to lithiated alkoxyallenes as suitable nucleophiles for the reactions with alkyl halides, strained heterocycles, carbonyl compounds and their derivatives. The presence of the allene unit in the initially formed adducts opens up several possibilities in the preparation of more complex systems. In this review, selected applications of lithiated alkoxyallenes in the synthesis of natural products and their analogues are discussed.
Źródło:
Wiadomości Chemiczne; 2016, 70, 1-2; 3-23
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bezpośrednia synteza azydków i tioli organicznych pochodnych glikolu etylenowego w zmodyfikowanej reakcji Appela
Direct synthesis of organic azides and thiols derived from ethylene glycol via modified Appel reaction 1
Autorzy:
Stefaniak, M.
Jasiński, M.
Urbaniak, K.
Romański, J.
Seliger, P.
Gutowska, N
Powiązania:
https://bibliotekanauki.pl/articles/141899.pdf
Data publikacji:
2014
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
synteza organiczna
tiole
azydki
reakcja „click”
makrocykle
kompleksy metali
organic synthesis
thiols
azides
click reaction
macrocycles
metal complexes
Opis:
Klasyczną metodę konwersji alkoholi pierwszorzędowych w odpowiednie halogenki alkilowe z użyciem trifenylofosfiny oraz tetrahalogenometanu, tzw. reakcję Appela, zaadoptowano do bezpośredniej syntezy terminalnych tioli i azydków organicznych pochodnych glikolu etylenowego oraz jego siarkowego analogu. W kluczowym etapie opisanej procedury one-pot, otrzymane in situ, w reakcji z N-bromosukcynimidem (NBS), odpowiednie dibromopochodne zostały przekształcone w związki docelowe w reakcji z nukleofilem siarkowym lub azotowym. Wybrane diazydki wykorzystano w syntezie nowych układów makrocyklicznych, które przetestowano pod kątem ich właściwości kompleksotwórczych.
Classical method of conversion of primary alcohols into corresponding alkyl halides by usage of triphenylphosphine and tetrahalogenated methane, so-called Appel reaction, was adopted for the direct synthesis of terminal organic thiols and azides derived from ethylene glycol and its sulfurated analogue. In key step of the presented ‘one-pot’ protocol, corresponding dibromides, generated in situ via reaction with N-bromosuccinimide (NBS), were converted into desired products by treatment with appropriate sulfur or nitrogen nucleophile. A series of diazides and dithiols derived from (poly)ethylene glycols and their sulfur analogues were obtained. Selected diazides were utilized for the construction of novel macrocyclic systems, that were tested incontext of their complexing properties.
Źródło:
Chemik; 2014, 68, 7; 592-599
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biokatalityczne metody otrzymywania nieracemicznych alkoholi aryloallilowych
Biocatalytic methods for preparation of nonracemic arylallylic alcohols
Autorzy:
Szymkuć, S.
Ostaszewski, R.
Powiązania:
https://bibliotekanauki.pl/articles/172469.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
biokataliza
nieracemiczne alkohole aryloallilowe
synteza organiczna
enzymy
mikroorganizmy
biocatalysis
nonracemic arylallylic alcohols
organic synthesis
enzymes
microorganisms
Opis:
Different methods for preparing nonracemic arylallylic alcohols are presented in this work. A key feature was an application the biocatalyst as a mean to obtain final products. These compounds play an important role in pharmaceutical industry, because they are substrates in the synthesis of various important therapeutics [1–3]. Methods presented in this work are divided into five main groups: 1. enantioselective hydroxylation, 2. microbiological deracemization, 3. enzymatic kinetic resolution, 4. enzymatic dynamic kinetic resolution, 5. enantioselective reduction. First two methods use only microorganisms like bacteria [4, 5, 10], fungi [6–8] or yeasts [11] as biocatalysts. Owing to the metabolic processes in the cells it was possible to obtain nonracemic arylallylic alcohol (results for method 2 are presented in Table 1). Unfortunately, the data were insufficient to create direct correlation between values of enantiomeric excess and types of applied microorganisms. Methods 3 and 4 used only isolated enzymes as biocatalysts. They belong to two classes: hydrolases and oxidoreductases. Oxidoreductases were used in the enzymatic kinetic resolution based on the enantioselective oxidation [28] of one enantiomer of the racemic arylallylic alcohol. Nevertheless, hydrolases [12–27], mainly lipases, isolated from microorganisms are enzymes of common use in enzymatic kinetic resolution. Owing to this method it was possible to obtain final products with excellent enantioselectivity (results are presented in Tables 2 and 3). Because kinetic resolution and dynamic kinetic resolution are related processes, in most cases similar enzymes are used. The choice of lipases as biocatalysts for method 4 was caused by the fact that they are able to catalyze enantioselective transesterification of arylallylic alcohols or their acetates. Furthermore, racemization is very important factor for efficacy of dynamic kinetic resolution processes. In most cases they are catalyzed by different types of complexes based on palladium [30, 31] and ruthenium [32, 34]. Final products prepared by this method had very high enantiomeric excesses and yields up to 93% (results are presented in Tables 4 and 5). The only method, presented in this work, that allowed to use both enzymes [39–41] and microorganisms [35–38] as biocatalysts, was enantioselective reduction. This method allows to obtain nonracemic arylallylic alcohols with excellent enantiomeric excess and yields up to 85% (results are presented in Table 6). In summary, all methods presented in this work show the advantages of biocatalysis as an alternative route to traditional chemical method
Źródło:
Wiadomości Chemiczne; 2012, 66, 1-2; 93-118
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bionics in architecture
Autorzy:
Zakharchuk, A.
Powiązania:
https://bibliotekanauki.pl/articles/115817.pdf
Data publikacji:
2012
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
architectural bionics
bionic style
forms of wildlife
organic architecture
synthesis of nature and technology
Opis:
The usage of forming principles of wild life got the new quality and received a name of architectural and bionic process and became one of the trends of architecture in the world architectural practice for the last 40 years. Bionics is an innovative architectural style that took all the best from nature: relief outlines and forms. It can be called architecture of future and its aim is synthesis of nature and modern technologies.
Źródło:
Challenges of Modern Technology; 2012, 3, 2; 50-53
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ditlenek węgla w syntezie organicznej
Carbon dioxide in organic synthesis
Autorzy:
Burczyk, B.
Powiązania:
https://bibliotekanauki.pl/articles/172758.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
wiązanie ditlenku węgla
surowce odnawialne
synteza organiczna
kataliza
kompleksy metali przejściowych
carbon dioxide fixation
renewable resources
organic synthesis
catalysis
transition metal complexes
Opis:
Carbon dioxide is an abundant, cheap, almost nontoxic, thermodynamically stable, inert electrophile. Exploitation of CO 2 as a chemical feedstock, although will almost certainly not reduce its atmospheric concentration significantly, aims to generate high-value products and more-efficient processes. In recent years efficient transition-metal complexes have been used to perform homogeneously catalyzed transformations of CO 2 . This paper presents an overview of available catalytic routes for the synthesis of carboxylic acids, lactones, urea and carbamates, linear and cyclic carbonates as well as polycarbonates. Reduction processes of CO 2 are shortly men - tioned as well. C arboxylic acids have been synthesized via : (i) carboxylation of organolithium, organomagnesium (Scheme 2 [35]), organoboron (Scheme 3 [40 -42]), organozinc (Scheme 4 [43, 44]) and organotin (Scheme 5 [45, 46]) compounds; (ii) oxidative cycloaddition of CO 2 to olefins and alkynes (Scheme 6 -10 [47 -50, 57]) catalyzed by Ni(0)-complexes; (iii) transition-metal catalyzed reductive hydrocarboxylation of unsaturated compounds (Scheme 11, 12 [64 -67]); (iv) carboxylation of C-H bond (Scheme 13 [69 -71]). Telomerization of dienes, for instance 1,3-butadiene, and CO 2 in the presence of Ni(II) and Pd(II) complexes leads to lactones and esters of carboxylic acids (Scheme 14, 15 [73 -79]). Nucleophilic ammonia, primary and secondary amines react with CO 2 to give, respectively, urea and carbamic acid esters - carbamates and isocyanates (Scheme 16 -18 [94, 95]), thus eliminating the use of phosgene in their synthesis. CO 2 reacts with alcohols, diols and epoxides in the presence of transition-metal complexes (Fig. 2) and the reaction products are: linear carbonates (Scheme 20, 21 [110 -118]), cyclic carbonates (Scheme 22 -24 [153 -170]) and polycarbonates (Scheme 25, 26, Fig. 3, Tab. 1 [179 -186]). Finally, hydrogenation of CO 2 , leading to the formation of CO, HCOOH, CH 3 OH, CH 4 , C 2 H 6 and C 2 H 4 (Scheme 27), as well as electrochemical and photochemical reductions in the pre - sence of homogeneous and heterogeneous catalysts have been shortly reviewed.
Źródło:
Wiadomości Chemiczne; 2013, 67, 1-2; 1-53
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Donorowo-akceptorowe struktury oligopirolowe : projektowanie, synteza i właściwości
Donor-acceptor oligopyrroles : design, synthesis, and properties
Autorzy:
Stępień, Marcin
Powiązania:
https://bibliotekanauki.pl/articles/1409858.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
pirol
układy donorowo-akceptorowe
chromofory
synteza
pyrrole
donor-acceptor systems
chromophores
organic synthesis
Opis:
The review summarizes one decade of research carried out in the Stępień Laboratory at the University of Wrocław. We focus on the group’s contributions to pyrrole chemistry, notably the development of donor-acceptor pyrrole hybrids and their use as building blocks in the synthesis of porphyrins, small-molecule dyes, and nanographene analogues.
Źródło:
Wiadomości Chemiczne; 2021, 75, 5-6; 593-602
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Generating Organic Compounds by Retrosynthetic Pathway via Typical Corey’s Synthesis
Autorzy:
Ononiwu, Chinonso Godwin
Enwereuzo, Onyekachi Oluchi
Akakuru, Obinna Chigoziem
Ejiogu, Chukwudima Benaiah
Onumah, Chinonso Uchenna
Achukee, Chinedu Kingsley
Umaefulam, Tobechukwu Nnamdi
Abaekwume, Nkechi Nancy
Akakuru, Ozioma Udochukwu
Powiązania:
https://bibliotekanauki.pl/articles/1031449.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Corey’s synthesis
aldehydes
alkanes
alkynes
ketones
organic compounds
organic reaction mechanism
Opis:
Several methods exist for the synthesis of alkanes including Corey’s synthesis, Wurtz reaction, reduction of alcohols and aldehydes, Kolbe’s electrolysis, hydrogenation of alkenes, and Grignard reaction. Among the available methods, the age-long Corey’s synthesis presents robust advantages of yielding symmetrical, unsymmetrical, straight chain and branched chain alkanes. Moreover, it allows of generating high yields of alkanes by utilizing primary alkyl halide and an array of lithium dialkyl copper ranging from primary, secondary to tertiary. Corey’s synthesis has also been implicated in the synthesis of various organic compounds such as (+)-taylorione, terminal alkynes, caribenol A, ketones, and aldehydes. In this work, an explanation of the general concept in the Corey’s synthesis is provided. Furthermore, specific examples of Corey’s reactions and modifications are discussed. Finally, an outlook into the benefits of the Corey’s synthesis in present-day organic synthesis is provided, which is expected to enhance the understanding of organic reaction mechanisms for the development of various organic compounds as drugs for treating diseases.
Źródło:
World News of Natural Sciences; 2021, 36; 88-98
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kwas winowy i jego pochodne we współczesnej chemii organicznej
Tartaric acid and its derivatives in current organic chemistry
Autorzy:
Grajewski, J.
Powiązania:
https://bibliotekanauki.pl/articles/171622.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
kwas winowy
winiany
stereochemia
synteza organiczna
kataliza
tartaric acid
tartrates
stereochemistry
organic synthesis
catalysis
Opis:
The tartaric acid and its salts have been present in chemistry for almost 350 years, since Pierre Seignette isolated Rochelle salt in 1675. Since that time tartaric acid and its derivatives have been often used in chemistry due to their accessibility, enantiopurity, relatively low cost and presence of different functional groups which easily allow to modify the molecule. Many tartaric acid derivatives serve as catalysts in important stereoselective transformations such as Sharpless asymmetric epoxidation or asymmetric Rousch aryloboronation. In many others reactions tartaric acid have been employed as a chiral building block for natural products synthesis, highly functionalized molecules or ligand design such as well known TADDOL or its analogues. Its polar functional groups allow to form crystals with amines and aminoalcohols what is widely used for their enantiopurification and resolution. The relatively new subdiscipline is the use of tartaric acid in chiral recognition and chiral discrimination in nanochemistry and enantioselective chromatography. The other, recent applications of tartaric acid include functionalization of metal layers, antibacterial and antifungal activity among many others. The significance of tartaric acid is evident – since 2000, words “tartaric acid” or “tartrates” can be found in databases over four thousand times. Taking that into account this short review is concentrated on selected applications of tartaric acid and its derivatives in organic chemistry in recent several years.
Źródło:
Wiadomości Chemiczne; 2013, 67, 5-6; 495-519
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Materiały MOF, nowa rodzina sit molekularnych o niezwykłych właściwościach i możliwościach zastosowań
MOF materials, the new family of the molecular sieves with exceptional properties and possible applications
Autorzy:
Florczak, P.
Janiszewska, E.
Kędzierska, K.
Kowalak, S.
Powiązania:
https://bibliotekanauki.pl/articles/171820.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
organiczno-nieorganiczne sita molekularne
związki metaloorganiczne MOF
synteza
zastosowanie
właściwości
organic-inorganic molecular sieves
MOF
structure
synthesis
properties
applications
Opis:
The metal organic frameworks (MOFs) are a novel group of molecular sieves discovered in the last decade of the twentieth century. Most of conventional molecular sieves such as microporous zeolites and zeolite-like materials, ordered mesoporous materials (M41S) are typical inorganic compounds. Although their synthesis often involves an assistance of organic compounds acting as structure directing agents and organic solvents are sometimes applied during their crystallization, the organics are always removed from resulted products (mainly by calcinations). The MOFs are crystalline materials build of metal ions or ion clusters coordinatively bonded with organic segments (linkers) that form porous (one-, two-, or threedimensional) structures. The various coordination number of selected metal and the nature of organic linkers allow to prepare a great variety of structures with different properties. The inorganic components comprise a great variety of transition (e.g. Zn Cu, Fe, rare earths) and base metal (e.g. Al) cations of different valence. The organic linkers are functionalized compounds containing O, N, P, S atoms (i.e. carboxylates, phosphonates, sulfonates, cyanides, amines, imidazoles) enable to chelate the inorganic cations. The organic subunits can be additionally modified by substitution of other functional groups (halogens, hydroxyls, aminogroups). The MOF materials are mostly prepared similarly as zeolitic materials by crystallization in solvothermal conditions. The solvents (water or organic compounds) can play a role of templates, although sometimes additional structure directing agents are admitted into the initial mixtures. The crystallization is always conducted in moderate temperatures (20–200°C). After removal of solvents well ordered pore systems are available for selective adsorption and for other applications. The thermal stability of this family of molecular sieves is obviously lower than that of inorganic materials, but most of them can withstand heating at 350–400°C, which still makes them suitable for variety of potential applications. The adsorption properties of MOFs makes them very appealing for practical application. The recorded surface areas of some types are overwhelming and they surpass 5000 m2/g. The high adsorption capacity is very promising for storage of fuels (natural gas, hydrogen) or waste gases (CO2, SO2) as well as for their separation. The great and very fast growing variety of structures and chemical compositions brings also a hope to use them as efficient catalysts. The metal segments, functional groups in organic blocks as well as occluded or encapsulated species can play a role of catalytically active sites. The MOF materials can be also applied as matrices for sensors, pigments, and microelectronic or optical devices.
Źródło:
Wiadomości Chemiczne; 2011, 65, 5-6; 427-460
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metal-organic frameworks for efficient drug adsorption and delivery
Autorzy:
Hyjek, Kornelia
Jodłowski, Przemysław
Powiązania:
https://bibliotekanauki.pl/articles/35134841.pdf
Data publikacji:
2023
Wydawca:
Radomskie Towarzystwo Naukowe
Tematy:
drug delivery systems
metal-organic frameworks
synthesis
characterization
drug loading
biocompatibility
systemy dostarczania leków
sieć metalo-organiczna
synteza
charakterystyka
akumulacja leku
biokompatybilność
Opis:
In recent years, the number of materials used as drug delivery systems (DDS) has increased dramatically. The widespread use of DDSs has improved both the safety and efficacy of therapy. The systems currently in use pose numerous drawbacks and require proper improvements. Although many modern materials are being developed, metal-organic frameworks (MOFs) deserve special attention. Thermal and chemical stability, high specific surface area, low toxicity, high biocompatibility, and great potential for modification are the main features enabling MOFs to be used as DDS. In this review, we describe MOFs, their structure, synthesis, and characterization, as well as drug loading, drug release kinetics, and bioassays. A critical approach is to outline the disadvantages as well as the limitations of MOFs and to identify areas that need to be studied more thoroughly. Nonetheless, the prospective nature of MOFs as DDS and potential adsorbents in overdose or poisoning is presented and highlighted.
Źródło:
Scientiae Radices; 2023, 2, 2; 115-189
2956-4808
Pojawia się w:
Scientiae Radices
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microwave synthesis of sulfanilic acid
Synteza mikrofalowa kwasu sulfanilowego
Autorzy:
Havlíček, J.
Myška, K.
Tejchman, W.
Karásková, N.
Doležal, R.
Maltsevskaya, N. V.
Kolář, K.
Powiązania:
https://bibliotekanauki.pl/articles/106593.pdf
Data publikacji:
2017
Wydawca:
Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:
synthesis of sulfanilic acid
microwave assisted synthesis
solvent-free synthesis
school experiment
organic chemistry education
synteza kwasu sulfanilowego
synteza mikrofalowa
synteza bez rozpuszczalnika
eksperyment szkolny
edukacja chemii organicznej
Opis:
Sulfanilic acid represents an important substance, which is frequently utilized in the industry of azo dyes as well as in drug development of antimicrobials (e.g. of sulfonamides). Students can also meet with such type of compounds in chemistry labs, for example, when they estimate pH by methyl orange indicator or prepare Orange II for textile colouring. Both of these dyes are products of azo coupling of sulfanilic acid as diazonium salt with N,N-dimethylaniline or 2-naphthol, respectively. In the article, we focus on the synthesis of sulfanilic acid as a well-known experiment in the organic chemistry education. The synthesis was modified as the solvent free and microwave assisted experiment under semimicroscale conditions. That experiment is very convenient for the organic chemistry courses in the university or the high school teaching.
Kwas sulfanilowy stanowi ważną substancję, często stosowaną w przemyśle barwników azowych, jak również w produkcji leków przeciwdrobnoustrojowych (np. sulfonamidów). Studenci mogą również spotykać się z takimi związkami w laboratoriach chemicznych, na przykład przy oznaczaniu pH z wykorzystaniem oranżu metylowego lub przy przygotowywaniu Oranżu II dla przemysłu tekstylnego. Oba te barwniki są produktami sprzężenia soli diazoniowych kwasu sulfanilowego odpowiednio z N,N-dimetyloaniliną lub 2-naftolem. W artykule przedstawiono syntezę kwasu sulfanilowego jako przykład dobrze znanego eksperymentu w edukacji chemii organicznej. Syntezę zmodyfikowano jako reakcję bez rozpuszczalników i wspomagano mikrofalowo w warunkach półmikropreparacji. Eksperyment ten powinien być przedstawiany podczas kursów chemii organicznej na uniwersytecie lub w szkole średniej.
Źródło:
Chemistry-Didactics-Ecology-Metrology; 2017, 22, 1-2; 93-98
2084-4506
Pojawia się w:
Chemistry-Didactics-Ecology-Metrology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mikrofale w syntezie organicznej: historia i perspektywy
Autorzy:
Lipińska, T. M
Powiązania:
https://bibliotekanauki.pl/articles/273516.pdf
Data publikacji:
2013
Wydawca:
Roble
Tematy:
mikrofale
promieniowanie mikrofalowe
technika mikrofalowa
synteza organiczna
microwaves
microwave radiation
microwave techniques
organic synthesis
Źródło:
LAB Laboratoria, Aparatura, Badania; 2013, 18, 4; 6-10
1427-5619
Pojawia się w:
LAB Laboratoria, Aparatura, Badania
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Otrzymywanie i właściwości adsorpcyjne sieci metaloorganicznych
Synthesis and adsorption properties of metal-organic frameworks
Autorzy:
Szeligowska, S.
Choma, J.
Jaroniec, M.
Powiązania:
https://bibliotekanauki.pl/articles/171540.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
sieci metaloorganicze
MOF
synteza materiałów MOF
adsorpcja
CO2
adsorpcja H2
metal-organic frameworks
synthesis of MOF materials
adsorption
H2 adsorption
Opis:
MOF materials or metal-organic frameworks are compounds consisting of metal ions or clusters (metal junctions) and organic ligands (bridging groups) connected via coordination bonds. Since a variety of organic ligands and metal junctions is available, metal-organic frameworks of desired composition and structures can be synthesized. These compounds are relatively new, intensively studied, their number is continuously growing from year to year. Metalorganic frameworks may also possess elastic properties due to the presence of coordination bonds in their structure. A distinct feature of MOF materials, which differentiates them from other sorbents, is the possibility of changing their pore structure under influence of external stimuli and the ability of adjusting their pore size to the dimensions of the adsorbed molecules. An interesting phenomenon observed in these materials is the so-called “breathing” effect that is manifested by drastic changes in the pore volume upon external stimuli such as temperature, pressure, type of adsorbate, presence of solvent. There are numerous methods for the preparation of MOF materials: solvothermal, electrochemical, mechanochemical, sonochemical and microwave-assisted syntheses. An additional activation of these materials is often required to remove the remaining solvents from pores and consequently, increase their adsorption capacity. The latter can be also increased by additional modifications that can be used to tune their physicochemical properties, and especially porosity. Due to the excellent adsorption properties of MOF, especially very high BET specific surface area (up to 6200 m2/g) and large pore volume, these materials have been intensively studied for capture or storage of various gases such as CO2, H2 and CH4. Applications of metal-organic frameworks are continuously growing and range from gas storage, chemical sensors and phosphors to medicine, where they are used as drug carriers.
Źródło:
Wiadomości Chemiczne; 2017, 71, 5-6; 299-322
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of conjugated nitroalkenes: short review
Autorzy:
Zawadzińska, Karolina
Gaurav, Gajendra Kumar
Jasiński, Radomir
Powiązania:
https://bibliotekanauki.pl/articles/35110314.pdf
Data publikacji:
2022
Wydawca:
Radomskie Towarzystwo Naukowe
Tematy:
nitroalkenes
organic synthesis
nitrocompounds
nitroalkeny
synteza organiczna
nitrozwiązki
Opis:
Key protocols of the preparation of conjugated nitroalkenes were reviewed and critically discussed. It was established, that optimal strategy for the obtaining of target compounds are small molecules extrusion processes from saturated nitro-compounds. Among them, the most universal methodologies based on carboxylic acids elimination have been discussed, which provide for smooth applications.
Źródło:
Scientiae Radices; 2022, 1, 1; 69-83
2956-4808
Pojawia się w:
Scientiae Radices
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 20

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