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Tytuł:
Implication and collecting mechanism of emulsified sodium vegetable oleate on fluorite flotation
Autorzy:
Sun, L.
Liu, J.
Liao, Y.
Powiązania:
https://bibliotekanauki.pl/articles/109761.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
emulsified sodium vegetable oleate
collector
fluorite flotation
sodium oleate
Opis:
The emulsified sodium vegetable oleate (ESVO) was prepared with low-cost vegetable oleate. Using ESVO as a collector, the flotation performance of fluorite had been investigated comparing with sodium oleate at a temperature of 20 ± 2 °C. The results of flotation showed that ESVO had better collecting performance than the sodium oleate. The interaction mechanism of these two collectors with fluorite was studied by the zeta potential, FTIR spectra and laser grain-size tests. Both ESVO and sodium oleate changed fluorite zeta potential by electrostatic attraction and chemical adsorption, and generated calcium carboxylate on the fluorite surface. Moreover, it was concluded that higher fluorite recovery was a consequence of ESVO smaller surface tension comparing to sodium oleate.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 211-219
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation behaviour and surface characteristic of anosovite in a sodium oleate solution
Autorzy:
Wang, Y.
Wen, S.
Zhang, J.
Wu, D.
Xian, Y.
Shen, H.
Powiązania:
https://bibliotekanauki.pl/articles/110766.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
anosovite
sodium oleate
flotation
adsorption
Opis:
Properties of anosovite in titanium slag, anosovite flotation response in a collector solution of sodium oleate, and adsorption behaviour of sodium oleate on the mineral surface were studied in the present work using XRD, Raman spectra, flotation tests, zeta potential analysis, FTIR and XPS. The results show that the anosovite crystal contains magnesium, and its chemical composition is Mg0.09Ti2.91O5. The chemical bonds on the anosovite surface mainly comprise Ti-O bonds. Micro-flotation tests indicate that anosovite has better floatability at a wide pH range and the recovery reaches 88% at pH=6, when the dosage of sodium oleate is only 4·10−6 mol/dm3. The point of zero charge of anosovite was determined near pH 3.2 by the zeta potential measurement. In the flotation process, chemical adsorption occurs between the carboxyl of sodium oleate and the titanium sites on the anosovite surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 714-723
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular Interactions in Binary Organic Liquid Mixtures Containing Ethyl Oleate and Ethanol at 2MHz Frequency
Autorzy:
Manukonda, S.
Kumar, G. P.
Babu, C. P.
Powiązania:
https://bibliotekanauki.pl/articles/412193.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Ethyl Oleate
Ethanol
molecular interactions
adiabatic compressibility
Opis:
Molecular interactions of binary mixtures of Ethanol with a new organic compound Ethyl Oleate are investigated at a constant ultrasonic frequency of 2MHz under the temperature range of 303.15K-318.15K. The effect of mole fraction of Ethyl Oleate on velocity of sound wave and the density and viscosity of binary mixtures at various temperatures were studied. The effects on density (ρ), viscosity (η), adiabatic compressibility (βad), inter molecular free length (Lf) and internal pressure (Пi) also was studied.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2015, 40; 17-23
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Interaction of sulfuric acid with dolomite (104) surface and its impact on the adsorption of oleate anion: a DFT study
Autorzy:
Cao, Qinbo
Zou, Heng
Chen, Xiumin
Yu, Xingcai
Powiązania:
https://bibliotekanauki.pl/articles/1449558.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
dolomite
adsorption
oleate
depressor
density functional theory
Opis:
Sulfuric acid $(H_2SO_4)$ is a specific depressor for apatite rather than for dolomite. The $H_2SO_4$ treated dolomite can still be floated effectively by oleate. However, the role of $H_2SO_4$ in the adsorption of oleate onto dolomite surface remains unclear. In this work, density functional theory calculations were conducted to probe the interactions among sulfate anion ($SO_4^{2−}$), oleate anion and the dolomite surface. The adsorption behaviors of $SO_4^{2−}$ anion onto the perfect and $CO_3$-defect dolomite surfaces were compared. Such results show that $SO_4^{2−}$ anion could only adsorb onto the defective dolomite surface, where it bonded with a $Ca$ atom. The remaining $Ca$ and $Mg$ atoms at the defect site could further react with the oleate anion, generating new $Ca$/$Mg–O$ ionic bond. In this regard, oleate and $SO_4^{2−}$ anions may both present on the dolomite surface. This phenomenon accounts for the flotation of $H_2SO_{4-}$treated dolomite.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 1; 34-42
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An atomic scale investigation of the adsorption of sodium oleate on Ca2+ activated quartz surface
Autorzy:
Gong, Guichen
Liu, Jie
Han, Yuexin
Zhu, Yimin
Powiązania:
https://bibliotekanauki.pl/articles/949736.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quartz
sodium oleate
Ca(OH)+
density functional theory
Opis:
In this study, the surface properties and flotation behavior of quartz with NaOl as a collector in the presence of Ca2+ ions were investigated using density functional theory (DFT) calculations in conjunction with flotation tests, adsorption experiments, zeta potential measurements, and solution chemistry calculations. The results of the flotation and adsorption tests proved that Ca2+ promoted the flotation recovery and the adsorption density of sodium oleate on quartz at pH > 8. Zeta potential analyses and solution chemistry calculations demonstrated that Ca(OH)+ was the functional species which activated quartz. DFT calculations indicated that O atoms dominated the quartz (101) surface, and great electrostatic repulsion and space resistance existed between the surface and oleate anion.The spontaneous adsorption of H2O and OH- on the (101) surface made quartz surfaces hydrated and hydroxylated, and resulted in the hydrophilicity of quartz. The adsorption of Ca(OH)+ on quartz (101) surface was more favorable and able to repulse the water film, which decreased the electrostatic repulsion and space resistance, and further facilitated the adsorption of oleate anion. During the activating and collecting adsorption processes, electron transition occurred along the O1—Ca—O2 path, implying Ca(OH)+ acted as an intermediary and electron donator in the activation process.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 426-436
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation separation of cassiterite and chlorite using carboxymethyl cellulose as a depressant
Autorzy:
Hu, Yang
Ying, Luo Hong
Zhang, Ying
Wei, Lu Kuan
Hao, Guan Zhen
Powiązania:
https://bibliotekanauki.pl/articles/2175422.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cassiterite
chlorite
sodium oleate
carboxymethyl cellulose
selective inhibition
Opis:
The nature and mechanism of interaction between carboxymethyl cellulose (CMC) with cassiterite (and chlorite surfaces) and their effects on the flotation separation process of cassiterite (from chlorite) were investigated by micro-flotation tests, surface adsorption experiments, zeta potential measurements, solution chemical calculation, infrared spectroscopy, and X-ray photo-electron spectroscopy (XPS). The results from single mineral tests revealed that CMC exhibited good selective inhibition effects with cassiterites and chlorites. When the dosage was 12.5 mg/L at pH 8, cassiterite and chlorite recovery was 92.2% and 6.3%, respectively. The artificial mixed ore test revealed that the flotation separation effect was the best when the dosage of CMC was 6.5 mg/L. Cassiterite used during the studies was 75.1% pure. The recovery was 82.8%. The interaction between CMC and the cassiterite surface led to a shift in the zeta potential toward the negative direction. CMC was weakly adsorbed on the cassiterite surface. There was no significant impact on the subsequent collection of sodium oleate. The concentration of C atom increased post interaction, and the potential shifted toward the negative direction. Characteristic CMC peaks were observed at this point. Hydrogen bonds and weak chemisorption interactions between CMC and chlorite affected the interaction between sodium oleate and the chlorite surface. It also affected the flotation results. The cassiterite and chlorite were separated effectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 155141
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Relationship between flotation and Fe/Mn ratio of wolframite with benzohydroxamic acid and sodium oleate as collectors
Autorzy:
Yang, S.
Feng, Q.
Qiu, X.
Gao, Y.
Xie, Z.
Powiązania:
https://bibliotekanauki.pl/articles/109666.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
wolframite
flotation
collector mixture
benzohydroxamic acid
sodium oleate
Opis:
Several studies revealed that flotation of wolframite changes with different Fe/Mn ratios, but they did not reach a consensus. This relationship in the presence of benzohydroxamic acid (BHA) and sodium oleate (NaOl) as collectors was studied in this paper through comparison of probability distribution curve of wolframite with different Fe/Mn ratios between the raw ore and the flotation concentrate, the pure mineral flotation and solution chemistry of flotation. The results showed that wolframite with high Fe/Mn ratio showed higher flotation with BHA as a collector while the flotation behavior of wolframite was completely opposite with NaOl as a collector. Besides, the calculations of chemical equilibrium in the solution were plotted as ΔG°-pH graphs. The results revealed that the flotation of wolframite may be determined by the interaction between BHA and ferric(II) ion or between NaOl and manganous ion. From the perspective of collector mixture, the results also explain the high collecting capability of the BHA/NaOl collector mixture, which can be defined as “functional complementation”.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 2; 747-758
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective flotation of witherite from calcite using potassium chromate as a depressant
Autorzy:
Qiu, Yangshuai
Zhang, Lingyan
Jiao, Xuan
Guan, Junfang
Li, Ye
Qian, Yupeng
Powiązania:
https://bibliotekanauki.pl/articles/110784.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
witherite
calcite
selective flotation
sodium oleate
potassium chromate
Opis:
Witherite has been widely used as an industrial and environmental source of barium, with calcite being the primary associated carbonate mineral. However, few studies have been conducted to effectively concentrate witherite from barium ores. In this work, with the treatment of potassium chromate (K2CrO4) and sodium oleate (NaOL), witherite was selectively separated from calcite through selective flotation at different pH conditions. In addition, contact angle, Zeta potential, adsorption and X-ray photoelectron spectroscopy measurements were performed to characterize the separation mechanisms. The results demonstrated that NaOL had a strong collecting ability for both witherite and calcite; nevertheless, witherite could be effectively selected from calcite with the highest recovery at pH 9 in the presence of K2CrO4. From the XPS measurements, NaOL and K2CrO4 were found to be primarily attached to the surfaces of witherite and calcite through chemisorption. The presence of K2CrO4 on the surface of calcite adversely influenced the NaOL adsorption, which could make the flotation separation efficient and successful.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 565-574
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dispersion of sodium phytate on muscovite and the implications for arsenopyrite flotation
Autorzy:
Zou, Dan
Wang, Zhen
Zhao, Kaile
Xu, Ying
Powiązania:
https://bibliotekanauki.pl/articles/2175449.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cassiterite
chlorite
sodium oleate
carboxymethyl cellulose
selective inhibition
Opis:
The effective flotation separation of sulfides and sliming silicate minerals is always a difficult problem. In this paper, the selective flotation of arsenopyrite from muscovite was studied by using sodium phytate (SP) as dispersant, and the mechanism was investigated through SEM/EDS, zeta potential, FTIR and XPS measurements. Single mineral flotation results showed that with the increasing isoamyl xanthate (IAX) dosage the recovery of arsenopyrite increased, until 8×10−5 mol/L IAX (79.40% recovery, pH=7), after that it decreased slightly. While muscovite floated poorly at any IAX concentration. For the mixed minerals, arsenopyrite recovery was only 54.63% while that of muscovite was 42.70%, which was attributed to the coverage of muscovite on arsenopyrite surface. When 6×10−5 mol/L SP was added into the mixed minerals system, the recovery of arsenopyrite recovered to 68.26% while that of muscovite was 8.48% (approximate the value of the single mineral). SEM/EDS results showed that SP could disperse muscovite and prevented its coverage on arsenopyrite surface. Zeta potential results showed that the electrokinetic potential of muscovite and arsenopyrite decrease from -26.60mV to -39.01 mV and from -26.90 mV to -27.84 mV at pH=7, respectively. It was obvious that the negatively charged phytate ions selectively adsorbed on the surface of muscovite. FTIR and XPS resulted co-proved the chemisorption of SP with active sites on muscovite while arsenopyrite spectrum did not change significantly, which was consistent with flotation and zeta potential results. The selective adsorption of SP on muscovite compared to arsenopyrite was responsible for the effective separation of them.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 154951
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on separation of fine-particle ilmenite and mechanism using flocculation flotation with sodium oleate and polyacrylamide
Autorzy:
Peng, Yang
Xiao, Junhui
Deng, Bing
Wang, Zhen
Liu, Nengyun
Yang, Daoguang
Ding, Wei
Chen, Tao
Wu, Qiang
Powiązania:
https://bibliotekanauki.pl/articles/1450088.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
sodium oleate
polyacrylamide
synergistic effect
ilmenite
flocculation flotation
Opis:
In this paper, sodium oleate, polyacrylamide, soluble starch and sodium carboxymethyl cellulose were used as flocculants to study the flocculation and sedimentation behavior of microfine ilmenite. Sedimentation test shows that sodium oleate and polyacrylamide have good flocculation effect on ultrafine ilmenite. The flocculation rate of ilmenite can be further improved by the combination of sodium oleate and polyacrylamide. It was found that both flocculants could generate chemical adsorption with ilmenite surface, and they all react with $Fe^{3+}$ on ilmenite surface. However, sodium oleate reacts with $Fe^{3+}$ to form a water-insoluble iron oleate precipitate which coats the surface of the ilmenite and hinders the action of polyacrylamide and the remaining $Fe^{3+}$. This problem can be avoided by adding polyacrylamide followed by sodium oleate, and the flotation recovery can be increased significantly.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 1; 161-172
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Pluronics and surfactant adsorption onto dolomite suspension zeta potential and stability
Autorzy:
Kozak, Anna
Sadowski, Zygmunt
Powiązania:
https://bibliotekanauki.pl/articles/764075.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
Pluronic
adsorption
synergism
zeta potential
dolomite
surfactant
sodium oleate
Opis:
Two kinds of Pluronics (PEO-PPO-PEO triblock copolymers) were used in these studies. They have mixed with anionic surfactant (sodium oleate). The adsorption isotherms of surfactant and copolymer-surfactant mixture onto dolomite have been determined.The adsorbed amount of the Pluronics increases with increasing concentration and reaches plateau. An increase of adsorbed amounts of anionic surfactant onto the mineral surfaces (dolomite) has been observed at the presence of Pluronic copolymers. The adsorption effect of triblock copolymers has been investigated on the zeta potential of dolomite at the water suspension. The interaction of anionic surfactant with copolymers causes a decrease of zeta potential to small amount due to the deformation of double electrical layer. The adsorbed non-ionic Pluronic layer partially screens the surface charge of mineral particles, and thus, reduces the zeta potential. On the other hand, the adsorption of anionic surfactant and copolymer caused a decrease of negative value of zeta potential both investigated minerals. The stability of dolomite suspension depends on the both copolymer and sodium oleate concentrations.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2015, 70, 1
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Concentration of chromite by means of magnetic carrier using sodium oleate and other reagents
Autorzy:
Ucbas, Y.
Bozkurt, V.
Bilir, K.
Ipek, H.
Powiązania:
https://bibliotekanauki.pl/articles/109814.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chromite
serpentine
magnetite
magnetic carrier
sodium oleate
zeta potential
FTIR
Opis:
Chromite recovery was studied using a magnetic carrier technology. Heavy media grade magnetite was used as the magnetic carrier. The effect of various reagents such as sodium oleate (NaOl) as a collector and carboxymethyl cellulose (CMC) as well as quebracho tannin as depressants on chromite removal was investigated. The effects of pH and reagent dosages were also determined. First, the zeta potential measurements were performed for different minerals in the absence and presence of NaOl, and then magnetic carrier tests were carried out under conditions based on zeta potential measurements. The magnetic carrier tests performed in the case of individual minerals (i.e. single minerals) showed that chromite (recovery of 95.1%) could be separated from serpentine (recovery of 3.2%) whereas it could not be separated from olivine. The best chromite concentrates containing 42.1% Cr2O3 were obtained with a 76% recovery from a synthetic mixtures of chromite and serpentine under optimum test conditions, that is at pH 10.5, 5.10–5 M NaOl, 20 g/Mg CMC, 0.5 g magnetite and 500 g/Mg kerosene (the feed contained 27% Cr2O3). Slime tailings of Turkish Maadin Company, Kavak Chrome Concentrating Plant in Eskisehir, which contain fine chromite, serpentine and olivine, were also investigated. It was found that chromite could not be satisfactorily recovered from the original slime sample in the presence and absence of NaOl by using the magnetic carrier technology. Additional FTIR studies performed with the investigated minerals showed that NaOl adsorption on chromite was greater than that on serpentine and magnetite minerals. It was also found that NaOl adsorption on serpentine is significantly reduced in the presence of magnetite while it increases only slightly on chromite.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 2; 767-782
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface characterization and froth flotation of fergusonite from Abu Dob pegmatite using a combination of anionic and nonionic collectors
Autorzy:
Fawzy, M. M.
Powiązania:
https://bibliotekanauki.pl/articles/110637.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fergusonite
sodium oleate
sorbitan monooleate
flotation
zeta-potential
FT-IR
Opis:
The performance of the mixed anionic (sodium oleate) / nonionic (sorbitan monooleate) collectors on fergusonite flotation and separation from silicate gangue minerals was investigated using the flotation tests. The surface characterization of fergusonite before and after the treatment with the mixed collectors was determined using the zeta-potential measurements and FT-IR analyses. The results obtained from this study showed that the flotation recovery of fergusonite using sodium oleate enhanced in the presence of sorbitan monooleate, and the optimum floatability was achieved at pH 5 using 1 Kg/Mg blended collectors of sodium oleate and sorbitan monooleate as by a ratio 1:1 and methyl isobutyl carbinol (MIBC) as a frother. It was also found that the addition of sodium metasilicate to citric acid as a depressant showed a high affinity for silicate gangue minerals and weak affinity for fergusonite. The zeta-potential and FT-IR measurements of fergusonite after the treatment with the mixed collectors indicated a strong adsorption of these molecules on the particle surface due to chemisorptions. Additionally, The SEM analysis of high grade froth and its corresponding tailing product showed that the fergusonite mineral mostly concentrated in the froth, while the gangue silicate minerals relatively concentrated in the tailing. Finally, synergistic interaction between the anionic and nonionic surfactants was observed during adsorption on fergusonite and was succeeded for separation from its gangue silicate minerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 677-687
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption mechanism of sodium oleate on titanium dioxide coated sensor surface using quartz crystal microbalance with dissipation
Autorzy:
Fan, G.
Liu, J.
Cao, Y.
Feng, L.
Xu, H.
Powiązania:
https://bibliotekanauki.pl/articles/110014.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
QCM-D
TiO2 coated sensor surface
sodium oleate
adsorption mechanism
Opis:
Quartz Crystal Microbalance with Dissipation (QCM-D) was firstly applied to investigate the adsorption mechanism of sodium oleate on TiO2 coated sensor surface. The effects of pH value, sodium oleate concentration, and temperature on TiO2 coated sensor surface were evaluated systematically using the QCM-D technique. Zeta potential, surface tension, adsorption isotherms, and adsorption thermodynamics were employed to characterize the adsorption process. The results showed the advantages of QCM-D on the investigation of the adsorption process. Additionally, the electrostatic equilibrium adsorption data was well matched to the Langmuir isotherm. Based on the thermodynamic analysis, adsorption was a spontaneous and endothermic physisorption process.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 597-608
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Separation of fine beryl from quartz via magnetic carriers by the aiding of non-ionic surfactant
Autorzy:
Fawzy, Mona M.
Powiązania:
https://bibliotekanauki.pl/articles/1447589.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
beryl
magnetic carrier
sorbitan monooleate
oleate-coated magnetite
zeta potential
FTIR
Opis:
This study demonstrated the possibility of separating fine beryl from quartz by using magnetic carrier technology with the presence of non-ionic surfactant (Sorbitan monooleate). Oleatecoated magnetite was used as a magnetic carrier for enhancing the magnetic properties of fine beryl to be separated and get rid of the most common associated gangue mineral "quartz". This study proved that the most important factors affecting this separation process is the pH, as the study showed that the efficiency of the separation process is the maximum possible when pH at the isoelectric point (IEP) of beryl. Where at IEP, beryl is ready to adsorb oleate-coated maginetite onto its surface and the presence of sorbitan monooleate helps this adsorption and strengthens. To demonstrate the separation process, physico-chemical surface characterization for beryl, quartz, magnetite and oleate-coated magnetite was studied before and after treatment with sorbitan monooleate using zeta potential measurements and Fourier Transform Infrared (FTIR). Mineralogical characterization was take place for separated minerals of beryl, quartz and magnetite using x-ray diffraction (XRD) analyses and scanning electron microscope (SEM) with energy-dispersive spectrometer (EDS) unit. The magnetic carrier separation tests were performed in this study in the case of separate minerals investigated that fine beryl (94% recovery) could be recovered under optimum test conditions of 2.5 pH, 4.29 g/L sorbitan monooleate and 1:0.5 beryl to oleate-coated magnetite ratio, while quartz under the same conditions was recovered by 9.8%. FTIR measurements for the investigated minerals before and after treatment with sorbitan monooleate confirmed that the adsorption of sorbitan monooleate on the surface of beryl far exceeds that of the surface of quartz at beryl IEP.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 2; 14-23
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł

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