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Tytuł:
Antibacterial activity of iron oxide nanoparticles synthesized by co-precipitation technology against Bacillus cereus and Klebsiella pneumoniae
Autorzy:
Ansari, S. A.
Oves, M.
Satar, R.
Khan, A.
Ahmad, S. I.
Jafri, M. A.
Zaidi, S. K.
Algahtani, M. H.
Powiązania:
https://bibliotekanauki.pl/articles/778380.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
antibacterial activity
co-precipitation
iron oxide nanoparticles
Klebsiella pneumoniae
physico-chemical characterization
Opis:
The present study investigates the synthesis and characterization of iron oxide nanoparticles (Fe3 O4 -NPs) for their antibacterial potential against Bacillus cereus and Klebsiella pneumonia by modified disc diffusion and broth agar dilution methods. DLS and XRD results revealed the average size of synthesized Fe3 O4 -NPs as 24 nm while XPS measurement exhibited the spin-orbit peak of Fe 2p3/2 binding energy at 511 eV. Fe3 O4 -NPs inhibited the growth of K. pneumoniae and B. cereus in both liquid and soild agar media, and displayed 26 mm and 22 mm zone of inhibitions, respectively. MIC of Fe3 O4 -NPs was found to be 5 μg/mL against these strains. However, MBC for these strains was observed at 40 μg/mL concentration of Fe3 O4 -NPs for exhibiting 40–50% loss in viable bacterial cells and 80 μg/mL concentration of Fe3 O4 -NPs acted as bactericidal for causing 90–99% loss in viability. Hence, these nanoparticles can be explored for their additional antimicrobial and biomedical applications.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 4; 110-115
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of magnetite nanoparticles synthesis conditions on their ability to separate heavy metal ions
Wpływ warunków syntezy nanocząstek magnetytu na ich zdolność do separacji jonów metali ciężkich
Autorzy:
Bobik, M.
Korus, I.
Dudek, L.
Powiązania:
https://bibliotekanauki.pl/articles/205007.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
iron oxide nanoparticles
co-precipitation
heavy metals separation
adsorption
nanocząstki tlenku żelaza
chemiczne współstrącanie
metale ciężkie
separacja metali ciężkich
adsorpcja
Opis:
Magnetite nanoparticles have become a promising material for scientific research. Among numerous technologies of their synthesis, co-precipitation seems to be the most convenient, less time-consuming and cheap method which produces fine and pure iron oxide particles applicable to environmental issues. The aim of the work was to investigate how the co-precipitation synthesis parameters, such as temperature and base volume, influence the magnetite nanoparticles ability to separate heavy metal ions. The synthesis were conducted at nine combinations of different ammonia volumes - 8 cm3, 10 cm3, 15 cm3 and temperatures - 30°C, 60°C, 90°C for each ammonia volume. Iron oxides synthesized at each combination were examined as an adsorbent of seven heavy metals: Cr(VI), Pb(II), Cr(III), Cu(II), Zn(II), Ni(II) and Cd(II). The representative sample of magnetite was characterized using XRD, SEM and BET methods. It was observed that more effective sorbent for majority of ions was produced at 30°C using 10 cm3 of ammonia. The characterization of the sample produced at these reaction conditions indicate that pure magnetite with an average crystallite size of 23.2 nm was obtained (XRD), the nanosized crystallites in the sample were agglomerated (SEM) and the specific surface area of the aggregates was estimated to be 55.64 m2·g-1 (BET). The general conclusion of the work is the evidence that magnetite nanoparticles have the ability to adsorb heavy metal ions from the aqueous solutions. The effectiveness of the process depends on many factors such as kind of heavy metal ion or the synthesis parameters of the sorbent.
Nanocząstki magnetytu stanowią obiecujący materiał badań ze względu na możliwość ich praktycznego zastosowania w różnorodnych dziedzinach. Wśród wielu metod ich syntezy, jako jedną z najwygodniejszych, najmniej pracochłonnych oraz ekonomicznych, wyróżnić można chemiczne współstrącanie. Efektem metody chemicznego współstrącania są drobne nanocząstki tlenku żelaza o dużej czystości, odpowiednie do zastosowań w zagadnieniach środowiskowych. Celem pracy było badanie w jaki sposób warunki syntezy chemicznego współstrącania, takie jak temperatura reakcji czy też ilość użytej zasady wpływają na zdolności separacyjne nanocząstek magnetytu względem jonów kilku metali ciężkich. Syntezy prowadzone były w dziewięciu kombinacjach przy różnej objętości dodawanego amoniaku – 8 cm3, 10 cm3, 15 cm3 oraz temperaturze – 30°C, 60°C, 90°C. Powstałe podczas każdej z syntez tlenki żelaza były badane jako adsorbenty jonów siedmiu metali ciężkich: Cr(VI), Pb(II), Cr(III), Cu(II), Zn(II), Ni(II) and Cd(II). Ponadto próbka magnetytu zsyntezowanego w wybranych warunkach była badana przy użyciu metod XRD, SEM oraz BET. Analizując wyniki procesu sorpcji stwierdzono, iż najbardziej efektywny materiał, dla większości metali ciężkich, powstał w temperaturze 30°C przy użyciu 10 cm3 amoniaku. Dodatkowa charakterystyka powstałego w tych warunkach sorbentu wykazała, iż stanowił on czysty magnetyt o średniej wielkości ziarna 23,2 nm (XRD). Ponadto wykazano, iż pojedyncze ziarna w badanej próbce są zaglomerowane (SEM) a powierzchnia właściwa agregatów wynosi 55,64 m2/g (BET). Ogólnym wnioskiem z pracy jest dowód, iż warunki syntezy badanego adsorbentu mają wpływ na jego zdolność separacyjne względem niektórych jonów metali ciężkich.
Źródło:
Archives of Environmental Protection; 2017, 43, 2; 3-9
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies of the Influence of Nano Iron(III) Oxide on Selected Properties of Solid Heterogeneous Propellants Based on HTPB
Autorzy:
Bogusz, R.
Magnuszewska, P.
Florczak, B.
Maranda, A.
Drożdżewska, K.
Powiązania:
https://bibliotekanauki.pl/articles/358189.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
combustion rate modifier
nano iron(III) oxide
solid heterogeneous rocket propellant
HTPB
LRM
Opis:
This paper presents the results of investigations into the use of 56 nm nano iron(III) oxide as a combustion rate modifier in a solid heterogeneous rocket propellant (SHRP). A series of solid heterogeneous rocket propellants based on HTPB and ammonium perchlorate with different nano iron(III) oxide contents in the propellant composition were prepared and investigated. The ballistic parameters of the examined propellants were determined by combustion in a laboratory rocket motor (LRM). The ballistic properties were evaluated in the pressure range 5-10 MPa. It was found that the linear burning rate at 7 MPa was increased by 15% for 1% nano iron(III) oxide content in comparison to 0.2% content. Determination of the sensitivity to friction and impact, the calorific value, hardness and decomposition temperature of the derived propellants were also investigated.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 1051-1063
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of neutron activation for investigation of Fe3O4 nanoparticles accumulation by plants
Autorzy:
Bystrzejewska-Piotrowska, G.
Asztemborska, M
Stęborowski, R.
Polkowska-Motrenko, H.
Danko, B.
Ryniewicz, J.
Powiązania:
https://bibliotekanauki.pl/articles/146840.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron (II,III) oxide
nanoparticles
neutron activation
plants
Opis:
As a result of the rapid development of nanotechnology and increasing application of nanoproducts in many areas of everyday life, there is a growing risk of production of nanowastes potentially dangerous for the environment. This makes it necessary to investigate the accumulation and toxicity of nanoparticles (NPs) at different trophic levels. In the studies neutron activation was applied for the investigation of iron (II,III) oxide nanoparticle (Fe3O4-NPs) accumulation by Lepidium sativum and Pisum sativum L. Plants were cultivated on growth medium contaminated with different concentrations (0.01-10 mmolźL-1) of Fe3O4-NPs. For the identification of the presence of Fe3O4-NPs in plant tissues gamma spectrometry following iron oxide (II,III) nanoparticles irradiation was applied. Both plant species were found to accumulate iron (II,III) oxide nanoparticles. The highest content of NPs was found in plant roots, reaching 40 g/kg for Pisum sativum L. More than 90% of accumulated NPs were found in roots. Accumulation of Fe3O4-NPs was found to depend on the concentration of nanostructures in the growth medium. The transfer factor for Lepidium sativum roots and shoots and Pisum sativum L. shoots decreased with increasing NP concentration in the medium; for Pisum sativum L. roots the tendency was reversed. Neutron activation of nanoparticles was shown to be a powerful tool for tracing the environmental fate of NPs and their uptake and accumulation in organisms.
Źródło:
Nukleonika; 2012, 57, 3; 427-430
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cation exchange capacity of clay rich soils in relation to mineralogical composition and organic matter content
Autorzy:
Dabkowska-Naskret, H
Jaworska, H.
Kobierski, M.
Powiązania:
https://bibliotekanauki.pl/articles/1450278.pdf
Data publikacji:
2001
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
organic matter
capacity
clay rich soil
mineralogical composition
aluminium oxide
soil component
clay fraction
manganese oxide
soil
cation exchange
whole soil
free iron
terrestrial ecosystem
Opis:
Contribution of clay mineral phase (<2 um) and organic matter to the cation exchange capacity (CEC) of two clayey soils (gleyic black earths from Gniew) was investigated. The XRD analysis showed dominance of illite and mixed laver illite/smectite as well as the presence of smectite, chlorite and trace of kaolinite in the clay fraction of studied soils. CEC of the soils ranged between 22.08-32.64 cmol(+)/kg. After removal of organic matter with 30% H2O2, CEC the above values decreased significantly. However, the CEC of organic and inorganic components is not an additive. This may be explained by the formation of organo-mineral complexes, which might lower the CEC of the soil as a whole.
Źródło:
Acta Agrophysica; 2001, 50; 113-118
1234-4125
Pojawia się w:
Acta Agrophysica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The role of free iron oxides in the association of lead and cadmium in gleyic phaeozems [black earths]
Autorzy:
Dabkowska-Naskret, H
Powiązania:
https://bibliotekanauki.pl/articles/1450860.pdf
Data publikacji:
2001
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
organic matter
iron oxide
soil component
lead
adsorption
association
soil
cadmium
clay mineral
terrestrial ecosystem
black earth
toxic metal
heavy metal
Opis:
Twelve samples, collected from four pedons of cultivated soils (black earths) were analyzed by sequential extraction to characterize the role of free iron oxides in the association of lead and cadmium. Amounts of lead and cadmium retained varied from 11 to 89.3% of the total Pb and from 4.8 to 48.7% of the total Cd. Metals associated with amorphous Fe oxides are at least ten times higher than with crystalline Fe forms. Under the existing soil conditions (high pH and CaCO3 content) free iron oxides are components of great importance in the Pb and Cd binding process. However, the results may indicate a stronger association of Pb than Cd with iron oxides in the studied black earths.
Źródło:
Acta Agrophysica; 2001, 50; 105-111
1234-4125
Pojawia się w:
Acta Agrophysica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ uproszczenia technologii oczyszczania biogazu na efektywność procesu
Influence of simplifying the technology of purifying biogas on the effectiveness of this process
Autorzy:
Dworecki, Z
Adamski, M
Powiązania:
https://bibliotekanauki.pl/articles/312561.pdf
Data publikacji:
2012
Wydawca:
Instytut Naukowo-Wydawniczy "SPATIUM"
Tematy:
odsiarczanie
tlenek żelaza
biogaz
filtry
desulphurising
iron oxide
biogas
filters
Opis:
Siarkowodór mimo że występuje w biogazie w niewielkich stężeniach powoduje m.in. korozje armatury stalowej, starzenie substancji smarnych i niszczenie komór spalania jednostek CHP. Celem pracy było określenie parametrów efektywności procesu odsiarczania biogazu przy wykorzystaniu złoża zawierającego głównie wodorotlenek żelaza (III). Uproszczenie polegało na zastosowaniu metody odsiarczania suchej bez regeneracji złoża tlenem. W wyniku przeprowadzonych badań określono efektywny zakres pracy złoża filtracyjnego przy przepływie już od 0,3 NL/min biogazu.
Hydrogen sulphide even though is found in biogas in little concentrations causes corrosions of steel fittings among others, grow old of spreadable substances and destroying of combustion chambers of CHP units. The aim of the study was to determine effectiveness parameters of biogas desulphurising process utilising a deposit containing primarily iron oxide (III). With simplification it is an application of the desulphurizing dry method without the regeneration of the deposit with oxygen. The performed experiments allowed determination of the effective range of work of the filtration deposit at the biogas flow of 0.3 NL/min.
Źródło:
Autobusy : technika, eksploatacja, systemy transportowe; 2012, 13, 10; 98-101
1509-5878
2450-7725
Pojawia się w:
Autobusy : technika, eksploatacja, systemy transportowe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oxide Inclusions in Ductile Cast Iron as Starting Materials for Production SiMo Iron Castings
Autorzy:
Dyrlaga, Ł.
Kopyciński, D.
Guzik, E.
Powiązania:
https://bibliotekanauki.pl/articles/2079828.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
oxide inclusions
slag defects
ductile cast iron
structure
wtrącenia tlenkowe
wady żużlu
żeliwo sferoidalne
struktura
Opis:
This paper presents the study about defects found in industrial high silicon ductile iron. The microstructures were analysed using an optical microscope. Afterwards, a scanning electron microscope was used to analyse the chemical composition. The study also examined the origin of oxygen and what is the amount of oxygen in the cast iron. The amount of active oxygen was measured at two production processes. Firstly, at the end of melting process, and secondly, after the nodularization treatment. The research was carried out with different proportions of the raw materials. The focus was on determining the mechanism of the formation of slag defects to eliminate them in order to obtain ductile iron with increased silicon content of the highest possible quality. The research presented in this publication is a part of an implementation doctorate carried out in the METALPOL Foundry in Węgierska Górka (Poland). The presented research concerns the elaboration of initial parameters of liquid metal intended for processing into high-silicon ductile cast iron SiMo1000 type with aluminum and chromium additives.
Źródło:
Archives of Foundry Engineering; 2021, 21, 3; 43-47
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Do changes in iron metabolism contribute to the acceleration of the atherosclerosis process?
Autorzy:
Formanowicz, D.
Powiązania:
https://bibliotekanauki.pl/articles/80735.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
acceleration
atherosclerosis
cholesterol
chronic disease
coronary heart disease
inflammation
iron metabolism
lipid peroxidation
nitric oxide
oxidative stress
proinflammatory cytokine
risk factor
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2011, 92, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
3D block modelling of the Sin Quyen IOCG deposit, North Vietnam
Autorzy:
Hao, Duong Van
Nguyen, Dinh Chau
Klityński, Wojciech
Zygo, Władysław
Nowak, Jakub
Powiązania:
https://bibliotekanauki.pl/articles/27310153.pdf
Data publikacji:
2023
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
North Vietnam
iron oxide copper deposits
3D model
resources
deposit development
Opis:
The IOCG Sin Quyen deposit is located in the Red River shear zone of North Vietnam. The ore bodies are known as hydrothermal veins and are hosted in Proterozoic metapelite. A block modelling approach was used to build a 3D model of the ore bodies. An analysis was carried out on Surfer 11 computer software using the archival data recorded from several dozen boreholes distributed within the study area, as well as data obtained from the mineral and chemical analysis of 50 samples collected recently in the deposit. The ore bodies generally trend in a NW-SE direction with an average azimuth of 107° and dip of around 70°.The Cu content in the ore bodies is inhomogeneous. In the bed extension direction, the exponential correlation of Cu concentration in ore bodies is recognized within 2,500 m, while in the direction perpendicular to the bed strike, the exponential dependence is observed on 500 m of distance. The high-grade mineralisation of copper within the ore bodies is often at the altitude interval from ∼100 m to ∼150 m above sea level (asl). These bodies are also rich in uranium and gold bearing minerals. The total resources of Cu, U and Ag were estimated and amount to 361,000; 12.7 and 11.87 tonnes respectively. The model indicates the downward extension of some ore bodies to below 300 m beneath the ground surface.
Źródło:
Geology, Geophysics and Environment; 2023, 49, 2; 175--195
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental Insight into the Catalytic Mechanism of MFe2O4 (M = Ni, Zn and Co) on the Thermal Decomposition of TKX-50
Autorzy:
Hou, Xiaoting
Zhang, Ming
Zhao, Fengqi
Yang, Yanjing
An, Ting
Li, Hui
Pan, Qing
Wang, Xiaohong
Zhang, Kun
Powiązania:
https://bibliotekanauki.pl/articles/27788010.pdf
Data publikacji:
2021
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
bimetallic iron oxide
thermal decomposition
TKX-50
catalysis
mechanism
Opis:
Synthesized dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate (TKX-50) owes its outstanding application prospects in the field of insensitive solid propellants not only to its high energetic performance but also to its low mechanical sensitivity. Based on the excellent catalytic activity of bimetallic iron oxides for the thermal decomposition of TKX-50, the catalytic mechanism of bimetallic iron oxides (NiFe2O4, ZnFe2O4 and CoFe2O4) for TKX-50 pyrolysis has been explored. For this study, the decomposition process of TKX-50, before and after mixing with the bimetallic iron oxides NiFe2O4, ZnFe2O4 and CoFe2O4 was monitored by in-situ FTIR and gas-phase MS-FTIR instruments. Of the different catalysts, ZnFe2O4 gave the best result for reducing the initial decomposition temperature of TKX-50. Additionally, the activation energy of functional group cleavage of TKX-50, before and after mixing with ZnFe2O4, was also calculated for mechanism analysis from the results of the in-situ FTIR measurements. The results showed that the condensate and the gas-phase decomposition products of TKX-50 remained unchanged after mixing with different catalysts, while the activation energy of tetrazole ring cleavage was significantly reduced. The results of this study will be helpful for the rational design of insensitive solid propellant formulations containing TKX-50, and for understanding the pyrolysis mechanisms of TKX-50 before and after mixing with the efficient catalyst ZnFe2O4.
Źródło:
Central European Journal of Energetic Materials; 2021, 18, 2; 223--244
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of uniform test design in optimizing the flotation reagents of iron anionic reverse flotation circuit
Autorzy:
Hou, Ying
Sobhy, Ahmed
Powiązania:
https://bibliotekanauki.pl/articles/2146945.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
iron oxide
quartz
uniform test design
reverse flotation
optimization
flotation reagents
Opis:
Most iron reserves are low in grade with quartz as the main gangue mineral, and anionic reverse flotation has become the most crucial separation method in the processing plants of iron ore. Thus, a flotation feed sample that is a mixture of low-intensity and high-gradient magnetic separators concentrates was acquired from a processing plant. The sample characterizations with X-ray diffraction (XRD), X-ray fluorescence (XRF), laser particle size analyzer, and mineral liberation analysis (MLA) confirmed that the sample consists of iron oxide as a valuable mineral and quartz as a gangue mineral with adequate liberation degree. In the anionic reverse flotation, the interaction of the flotation reagents with the constituents of the feed makes the flotation a complex system. Thus, the selection and optimization of regent dosages were performed using a uniform experimental design to estimate the optimum separation efficiency. The optimum reagent system was 1.6 kg/Mg starch depressant, 1.0 kg/Mg calcium oxide (lime) activator, and 0.8 kg/Mg TD-II anionic collector. At the optimum, 68.90% iron grade with 92.62% recovery was produced.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 1; 37--49
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Significance of reagents addition sequence on iron anionic reverse flotation and their adsorption characteristics using QCM-D
Autorzy:
Hou, Ying
Sobhy, Ahmed
Wang, Yue
Powiązania:
https://bibliotekanauki.pl/articles/1448929.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
iron oxide
adsorption
pH modifier
starch
reverse flotation
QCM-D
Opis:
To explore the influence of reagents addition sequence of the pH regulator and the starch depressant on the anionic reverse flotation of iron oxide, flotation conditional experiments were performed on mixed low-intensity and high-gradient magnetic concentrates which is the flotation feed acquired from the iron processing plant. Besides, quartz crystal micro-balance with dissipative (QCM-D) was conducted to detect the adsorption phenomena of the flotation reagent on iron oxide sensors at different addition orders. The outcomes showed that the flotation performance using the pH regulator prior to the depressant was the best. For example, at 1.6 kg/Mg starch dosage, the recovery and separation efficiencies were improved by 18.3% and 21.2%, respectively, with keeping the concentrate Fe grade as high as 69.5%. Also, QCM-D frequency shifted by -41 Hz from 17 Hz to -24 Hz with increased dissipation from -2.6 x 10-6 to 8.2 x 10-6, indicating an increase in the mass of slightly-rigid starch adsorption layer on the surface of iron oxide under a strong alkaline condition with adsorption density of about 0.46 mg/cm2. On the other hand, under weak alkaline conditions, starch was adsorbed, and then the starch was desorbed upon the addition of the strong alkaline solution. Whereas, adding the pH modifier to create a strong alkaline condition enhanced the starch adsorption significantly with coordination and hydrogen bonds, and prevented the following adsorption of the anionic collector for more efficient reverse flotation of iron oxide minerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 284-293
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of Zn2+, Cd2+ and Cu2+ on zeolites coated by manganese and iron oxides
Autorzy:
Irannajad, M.
Hhaghighi, H. K.
Soleimanipour, M.
Powiązania:
https://bibliotekanauki.pl/articles/110138.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption
wastewater
manganese oxide
iron oxide
zeolite
Opis:
Adsorption of copper, cadmium and zinc on manganese and iron oxide coated zeolite from aqueous solution was investigated in a batch mode. Experiments were conducted to investigate the effects of the initial concentration of metals, initial pH, contact time and temperature on the adsorption of ions. According to the results, adsorption of ions on manganese and iron oxide coated zeolite increased with the enhancement of initial Cu2+, Zn2+ and Cd2+ concentrations and contact time and also with increase of temperature. The results showed that at the beginning, the adsorption rate of Cu2+ and Cd2+ was more than 90 %. This rate continued to be slower for Zn2+ in both zeolites. Furthermore, the amount of Cu2+, Zn2+, and Cd2+ adsorption on the manganese oxide coated zeolite (qe) was equal to 14 mg/g, 9 mg/g and 16 mg/g and on the iron oxide coated zeolite it was 11 mg/g, 7 mg/g and 13mg/g, respectively. It was shown that at the concentrations below 100 mg/dm3 adsorption was rapid and almost all heavy metals were adsorbed. As a result, the significant factor affecting qe is the proportion of weight to liquid and pH in the solutions. Finally, the results showed that the adsorption of Zn2+, Cu2+ and Cd2+ onto the manganese oxide coated zeolite followed both the Langmuir and Freundlich isotherm models.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 894-908
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The activity of fused-iron catalyst doped with lithium oxide for ammonia synthesis
Autorzy:
Jedrzejewski, R.
Lendzion-Bieluń, Z.
Arabczyk, W.
Powiązania:
https://bibliotekanauki.pl/articles/779518.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
iron catalyst
ammonia synthesis
lithium oxide
Opis:
The iron catalyst precursor promoted with Al2O3, CaO, and Li2O was obtained applying the fusing method. Lithium oxide forms two phases in this iron catalyst: a chemical compound with iron oxide (Li2Fe3O4) and a solid solution with magnetite. The catalyst promoted with lithium oxide was not fully reduced at 773 K, while the catalyst containing potassium was easily reducible at the same conditions. After reduction at 873 K the activity of the catalyst promoted with lithium oxide was 41% higher per surface than the activity of the catalyst promoted with potassium oxide. The concentration of free active sites on the surface of the catalyst containing lithium oxide after full reduction was greater than the concentration of free active sites on the surface of the catalyst promoted with potassium oxide.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 2; 78-83
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 38

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