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Tytuł:
New Approach to Non-Volatile Metal Ion Production Using Plasma Ion Source with Internal Evaporator
Autorzy:
Turek, Marcin
Droździel, Andrzej
Pyszniak, Krzysztof
Filiks, Janusz
Węgierek, Paweł
Powiązania:
https://bibliotekanauki.pl/articles/2206283.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
ion sources
ion implantation
ion beams
Opis:
A new approach to application the internal evaporator in an arc discharge ion source is presented, namely a crucible with a plug made of feeding substance. This solution is suitable especially for high-melting point metallic feeding substances. The ion source was tested using Ni and Cr. Basic ion source characteristics, i.e. dependences of ion current and discharge voltage on discharge and filament currents as well as on the external magnetic field flux density are shown and discussed in order to find optimal working conditions. The maximal ion currents were 18 μA for Ni+ and 38μA for Cr+. The stability of the ion current was also tested. It was proven that ion source is able to provide intense ion beam current long enough to perform irradiations with the fluence of ~5×1015 cm-2 confirming the usefulness of the design for ion implantation purposes.
Źródło:
Advances in Science and Technology. Research Journal; 2022, 16, 5; 20--27
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Post acceleration of ions emitted from laser and spark - generated plasmas
Autorzy:
Torrisi, L.
Cavallaro, S.
Rosiński, M.
Nassisi, V.
Paperny, V.
Romanov, I.
Powiązania:
https://bibliotekanauki.pl/articles/146658.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
post ion acceleration
laser plasma
ion beam
ion implantation
Opis:
Pulsed lasers at intensities of the order of 1010 W/cm2 interacting with solid matter in vacuum, produce hot plasmas at high temperatures and densities. The charge state distributions of the plasma generate a high electric field, which induces high ion acceleration along the normal to the target surface. The high yield of the emitted ions can generate a near constant current by using repetitive pulses irradiating thick targets. In order to increase ion energy, a post-acceleration system can be employed by using acceleration voltages above 10 kV. Special ion extraction methods can be employed to generate the final ion beam, which is multi-ionic and multi-energetic, due to the presence of different ion species and of different charge states. In this article four different methods of post ion acceleration, employed at the INFN-LNS of Catania, at the IPPLM of Warsaw, at the INFN of Lecce and at the LPI of Moscow, are presented, discussed and compared. All methods are able to implant ions in different substrates at different depth and at different dose-rates.
Źródło:
Nukleonika; 2012, 57, 3; 323-332
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The modifications of the JYFL 6.4 GHz ECR ion source
Autorzy:
Koivisto, H.
Liukkonen, E.
Moisio, M.
Nieminen, V.
Suominen, P.
Powiązania:
https://bibliotekanauki.pl/articles/148664.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
ECR ion source
ion beams
Opis:
A new JYFL 14 GHz ECRIS was completed in spring 2000 for the nuclear physics program at the Department of Physics, University of Jyväskylä (JYFL). The old JYFL 6.4 GHz ECRIS (built in 1990-1991) is now also available for the material physics experiments and for the research and development work of the ECR ion sources. During the last year remarkable modifications to the structure of the source have been undertaken. In the first phase, which was completed in fall 2001, the axial magnetic field was optimized using the old power supplies and the coils. The radial magnetic field was improved in spring 2002 by installing an iron cylinder around the hexapole permanent magnets. According to the measurements the improvement of about 25% to the radial magnetic field was achieved. The research work to improve the ion beam quality has been started.
Źródło:
Nukleonika; 2003, 48,suppl.2; 81-84
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An algorithm for the calculation of heavy ion ranges in SiO2
Autorzy:
Kabadayi, Ö.
Gümüs, H.
Powiązania:
https://bibliotekanauki.pl/articles/148433.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
ion implantation
ion range
SiO2
Opis:
The heavy ion ranges in amorphous SiO2 have been calculated by using a technique based on solution of first order ODE’s. Br, Au, Hg, Bi, projectiles have been chosen as incident ion. Since the target is assumed to be amorphous, Bragg’s rule can be used to calculate electronic and nuclear stopping powers in the compound. Numerical solutions have been performed by using Fehlberg fourth-fifth order Runge-Kutta method. The results are compared with experimental data, as well as with the result of the Monte Carlo program SRIM and other standard procedures such as PRAL and WS [19]. It is found that the agreement between our method and the experiment is good and within 10%.
Źródło:
Nukleonika; 2003, 48, 3; 145-149
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recent ion measurements within the modified DPF-1000U facility
Autorzy:
Kwiatkowski, R.
Czaus, K.
Skladnik-Sadowska, E.
Sadowski, M. J.
Zaloga, D. R.
Paduch, M.
Zielinska, E.
Powiązania:
https://bibliotekanauki.pl/articles/148249.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
DPF-1000U facility
ion beams
ion energy spectra
ion pinhole images
Opis:
In this note we describe measurements of ion beams emitted along the z-axis of the DPF-1000U facility operated at 23 kV, 334 kJ, and with the initial deuterium pressure of 1.6–2 hPa. The DPF-1000U device was recently renewed and equipped with a dynamic gas-puff valve placed inside the inner electrode. The investigated ions were recorded by means of ion pinhole cameras equipped with solid state nuclear track detectors of the PM-355® (PADC) type. The energy spectra of ions were determined using a Thomson spectrometer placed on the symmetry axis at a distance of 160 cm from the electrodes outlets. The ion images recorded during discharges performed under different experimental conditions show that the ion beams have a complex structure, usually in the form of a central bunch and an annular stream composed of many micro-beams. Energies of the registered deuterons have been in the range of 30–700 keV, while the fast protons (which originated from the hydrogen remnants) had energies in the range of 300–850 keV.
Źródło:
Nukleonika; 2015, 60, 2; 297-302
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on spatial and energetic characteristics of the ion beams emitted in the PF - 360 discharges
Autorzy:
Kwiatkowski, R.
Skladnik-Sadowska, E.
Malinowski, K.
Sadowski, M. J.
Czaus, K.
Zebrowski, J.
Garkusha, I. E.
Powiązania:
https://bibliotekanauki.pl/articles/147918.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
ion beams
PF-360 facility
ion pinhole images
Opis:
Experimental results are presented on the spatial structure and energetic characteristics of the fast ion beams produced by high-current discharges in a PF-360 device operated at the National Centre for Nuclear Research (NCBJ, Otwock/Świerk, Poland). The 105 kJ discharges were initiated at the initial deuterium pressure around p0 = 6 hPa and were powered from a 234 miF capacitor bank charged up to 30 kV. The spatial structure of the ion beams was recorded using pinhole cameras equipped with the solid-state nuclear track detectors of the PM-355 type, placed at two different angles (0 centigrade, 45 centigrade) relative to the discharge axis. The detectors were shielded by thin absorption filters made of pure Al foils of various thickness, which made it possible to record only ions with energies exceeding a chosen threshold value. Similarly as in other plasma focus (PF) experiments, energies of the emitted ions ranged from about 30 keV to about 3 MeV, i.e. they were much higher than the voltage applied to the electrodes. The recorded ion images showed a complex spatial structure of the fast ion beams, which consisted of many micro-beams of different energies. It is possible that these beams were emitted by various local micro-sources (e.g. plasma micro-diodes) the were formed inside the PF pinch column.
Źródło:
Nukleonika; 2012, 57, 1; 67-74
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inhibiting effect of citric acid on the floatability of serpentine activated by Cu(II) and Ni(II) ions
Autorzy:
Huang, Jun-wei
Zhang, Cheng-qiang
Powiązania:
https://bibliotekanauki.pl/articles/110224.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
copper ion
nickel ion
serpentine
floatation
activation
inhibiting
Opis:
The laboratory researches about the inhibiting effect of citric acid on the flotation performance of serpentine activated by Cu2+ and Ni2+ were carried out through micro flotation tests, zeta potential measurements, collector adsorption capacity measurements and solution chemistry analysis. The flotation results showed that Cu2+ and Ni2+ could remarkably activate the flotation of serpentine when the pH value was more than 6, however, this activation could be effectively weakened by adding citric acid. Zeta potential measurement and adsorption capacity measurement indicated that the presence of citric acid could prevent the adsorption of Cu2+ and Ni2+, and therefore reduce the adsorption amount of potassium butyl xanthate on serpentine surface. Furthermore, solution chemical analysis of the flotation system showed that copper hydroxide Cu(OH)2(s) and the nickel hydroxide Ni(OH)2(s) were the main component in the pH range of 9 to 10, which adsorbed onto serpentine surface and made it activated; while the citric acid could effectively prohibit the formation of these metal hydroxide in slurry so as to inhibit the activation impact.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 4; 960-968
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Progress in theoretical models of the ICRF mode conversion
Autorzy:
Kazakov, Y. O.
Powiązania:
https://bibliotekanauki.pl/articles/147690.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
ICRF heating
ion-ion hybrid resonance
mode conversion
tokamak
Opis:
The technique of heating the plasma with the electromagnetic waves in the ion cyclotron range of frequencies (ICRF) has many important applications that may lead to improved performance of tokamaks. Recently the heating efficiency of the ICRF mode conversion scenarios characterized by a narrow power deposition profiles received much attention. This paper highlights progress in the theoretical models of the ICRF mode conversion that allowed to achieve a successful experimental realisation of these scenarios in present-day tokamaks.
Źródło:
Nukleonika; 2012, 57, 1; 31-35
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Accelerators in materials research
Autorzy:
Turos, A.
Powiązania:
https://bibliotekanauki.pl/articles/147928.pdf
Data publikacji:
2005
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
materials research
accelerators
ion beam modification
ion beam analysis
Opis:
Abstract Since at least forty years accelerators of charged particles no longer belong to nuclear physics exclusively. This is especially true for accelerators at energies below 1 GeV. The vast majority of accelerators in this energy range is used for materials research and medicine. In materials research the applications are principally twofold: modifications of solids and surface layer microanalysis. Two most important challenges for materials research at the beginning of XXI century as determined by the Materials Research Society are: development of materials able to repair human body and development of materials for new electronic devices able to cope with the enormous amount of information to be stored and transmitted. The role of accelerators with regard to the challenges of modern technology will be discussed.
Źródło:
Nukleonika; 2005, 50,suppl.3; 11-15
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Development of New Water Deoxidization Systems for Heat and Power Plants
Autorzy:
Shabliy, Tetyana
Gomelya, Mykola
Pohrebennyk, Volodymyr
Ivanenko, Olena
Nosachova, Yuliia
Powiązania:
https://bibliotekanauki.pl/articles/2025740.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
redoxite
deoxidation
ion exchange resin
ion exchange resin modification
Opis:
The analysis of water conditioning methods for closed water supply systems was carried out in the work. The expediency of using redoxites based on ion exchange materials to combat the corrosion processes in water recirculation systems by preliminary deoxidation of water was shown. Modified KU-2–8, Dowex Mac-3, AB-17–8, Dowex Marathon WBA, AMBERLITE IRA 96 ion exchange resins were used as deoxidizing materials.
Źródło:
Journal of Ecological Engineering; 2022, 23, 1; 193-205
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improvement of metal separation process from synthetic hydrochloric acid leaching solution of spent lithium ion batteries by solvent extraction and ion exchange
Autorzy:
Nguyen, Viet Nhan Hoa
Lee, Man Seung
Powiązania:
https://bibliotekanauki.pl/articles/1446393.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
spent lithium-ion batteries
solvent extraction
ion exchange
separation
Opis:
Spent lithium-ion batteries (LIBs) are good secondary resources for recycle and reuse. To develop a process for the separation of Cu(II), Co(II), Mn(II), Ni(II) and Li(I) with high purity from spent LIBs and circumvent some drawbacks of the previous work, solvent extraction and ion exchange experiments were done in this work. The synthetic hydrochloric acid leaching solution of 3 M was employed. Compared to Aliquat 336 (N-Methyl- N, N, N-trioctyl ammonium chloride), extraction with Cyanex 301 (bis(2,4,4-trimethylpentyl) dithiophosphinic acid) led to selective extraction of Cu(II) over other metal ions. Employing ion exchange with TEVA-SCN resin can completely separate Co(II) over Mn(II). After adjusting the pH of Co(II) free raffinate to 3, Mn(II) was quantitatively extracted by the mixture of Alamine 336 (mixture of tri-octyl/decyl amine) and PC 88A (2-ethylhexyl hydrogen-2-ethylhexylphosphonate) with two stage cross-current extraction. The synthesized ionic liquid (ALi-CY) was used for complete extraction of Ni(II), whereas Li(I) remained in final raffinate. The metal ions in the loaded organic phase were completely stripped with the proper agents (5% aqua regia for Cu(II), 5% $NH_3$ for Co(II), weak $H_2SO_4$ solution for Mn(II) and Ni(II) stripping, respectively). The experimental results revealed that purity of the metal ions in stripping solution was higher than 99.9%. A flowsheet was suggested to separate metal ions from the HCl leaching solutions of spent LIBs.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 1-17
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
R&D of ECR ion sources: news and perspectives
Autorzy:
Gammino, S.
Powiązania:
https://bibliotekanauki.pl/articles/148656.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
ion source
plasma
Opis:
The future accelerators need ion beams with higher charge state and higher current. This demand will be met by the “third generation Electron Cyclotron Resonance Ion Sources” (ECRIS) which will make use of improved plasma confinement by means of higher magnetic field and of higher microwave frequency, thus boosting the performance of nowadays ECRIS operating at the frequency of 14 and 18 GHz. The possibility to obtain confining fields exceeding 4 tesla, by means of special design of NbTi superconducting magnets, open the way to a new operational domain, at the typical frequencies of gyrotrons, above 28 GHz, with plasma densities never achieved before in ECRIS (1013 cm–3 and higher). The test of SERSE at 28 GHz, confirming the theoretical frame on which the third generation ECR sources design is based, will be presented; a synthetic review of the new generation ECRIS is carried out, with a particular emphasis on the design of the GyroSERSE source. Finally, the scheme of an innovative hybrid source will be outlined and a short description of the ECLISSE (Electron Cyclotron Resonance ion source Coupled to a Laser Ion Source for charge State Enhancement) experiment is hereinafter presented.
Źródło:
Nukleonika; 2003, 48,suppl.2; 73-79
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inorganic constituents in surface runoff from urbanised areas in winter: the case study of the city of Brest, Belarus
Autorzy:
Bulskaya, I.
Volchek, A.
Powiązania:
https://bibliotekanauki.pl/articles/48193.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
snowmelt
surface run-off
inorganic compound
pollution
phosphate ion
nitrate ion
ammonium ion
chloride ion
urbanized area
winter
Brest region
Belorussia
Źródło:
Oceanologia; 2014, 56, 2
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biochemistry of magnesium
Biochemia magnezu
Autorzy:
Pasternak, K
Kocot, J.
Horecka, A.
Powiązania:
https://bibliotekanauki.pl/articles/14627.pdf
Data publikacji:
2010
Wydawca:
Uniwersytet Warmińsko-Mazurski w Olsztynie / Polskie Towarzystwo Magnezologiczne im. Prof. Juliana Aleksandrowicza
Tematy:
magnesium
DNA repair process
enzyme
metabolic cycle
cellular respiration
calcium ion
ion transport
potassium ion
biochemistry
Opis:
Magnesium is essential for biochemical functions of cells. Since Mg2+ has a relatively low ionic radius in proportion to the size of the nucleus (0.86 versus 1.14 f A for Ca2+), it shows exceptional biochemical activity. Due to its physicochemical properties, intracellular magnesium can bind to the nucleus, ribosomes, cell membranes or macromolecules occurring in the cell’s cytosol. It is indispensable for the nucleus to function as a whole and for the maintenance of physical stability as well as aggregation of rybosomes into polysomes able to initiate protein synthesis. Mg2+ can also act as a cofactor for ribonucleic acid enzymes (ribozymes) capable of specifically recognizing and cleaving the target mRNA. As an essential cofactor in NER, BER, MMR processes, Mg2+ is required for the removal of DNA damage. An activator of over 300 different enzymes, magnesium participates in many metabolic processes, such as glycolysis, Krebs cycle, β-oxidation or ion transport across cell membranes. Mg2+ plays a key role in the regulation of functions of mitochondria, including the control of their volume, composition of ions and ATP production.
Magnez jest składnikiem niezbędnym dla zasadniczych funkcji biochemicznych komórki. Ponieważ Mg2+ ma relatywnie mały promień w stosunku do wymiarów jądra (0.86 i 1.14 A odpowiednio dla Mg2+ i Ca2+), wykazuje dużą aktywność biochemiczną. Dzięki właściwościom fizykochemicznym śródkomórkowy Mg2+ może wiązać się z jądrem komórkowym, rybosomami, błonami komórkowymi oraz makromolekułami cytosolu komórki. Magnez jest niezbędny dla funkcjonowania jądra komórkowego jako całości oraz utrzymania fizycznej stabilności i agregacji rybosomów do polisomów zdolnych do biosyntezy białka. Odgrywa on również rolą kofaktora katalitycznych cząsteczek RNA (rybozymów), odpowiedzialnych za specyficzne rozpoznawanie i fragmentację docelowego mRNA. Jako kofaktor w procesach: NER, BER, MMR, przyczynia się do usuwania uszkodzeń DNA. Magnez, będąc aktywatorem ponad 300 różnych enzymów, uczestniczy w przebiegu wielu szlaków metabolicznych, takich jak glikoliza, cykl Krebsa, β-oksydacja czy transport jonów poprzez błony komórkowe. Odgrywa on ponadto bardzo ważną rolę w regulowaniu funkcji mitochondriów, łącznie z regulacją ich wielkości, kompozycją jonów, a także bioenergetyką i regulacją produkcji ATP.
Źródło:
Journal of Elementology; 2010, 15, 3; 601-616
1644-2296
Pojawia się w:
Journal of Elementology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of pH and ionic Al3 plus and Cu2 plus on the concentration of magnesium in Trifolium pratense L.
Wpływ pH oraz jonów Al3 plus i Cu2 plus na zawartość magnezu w Trifolium pratense L.
Autorzy:
Szerement, J.
Szatanik-Kloc, A.
Powiązania:
https://bibliotekanauki.pl/articles/35184.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
pH
aluminium ion
copper ion
magnesium concentration
Trifolium pratense
Opis:
The objective of the work was to determine the content of magnesium in plants of Trifolium pratense L. which grew in an environment contaminated with aluminium or copper. The growth and development of the plants was carried out in hydroponics, with strictly controlled composition and pH of the growth medium. Copper was added to the medium (as an additional application) in a solution of CuSO4·5H2O, and aluminium in the form of a solution of AlCl3, at concentrations of Al+3 and Cu+2 of 20 and 100 mg dm-3. The concentration of magnesium, aluminium and cooper was determined by means of a ICP sequential emission spectrometer D-820 Hilger Analytical (UK) in extracts from the roots and aboveground parts. Decreasing pH of the medium did not cause any statistically significant changes in the concentration of the metals studied. There was a significant increase in the concentration of aluminium and copper in roots and aboveground parts of Trifolium pratense L. and lower magnesium concentration for plants that were grown in an environment contaminated with Al+3/ Cu+2 at a concentration of 100 mg dm-3. In the lower concentrations of both stressors (20 mg dm-3) a decrease was noted in the level of magnesium in the whole plant, and a statistically significant increase in the concentration of aluminium and copper in the roots of Trifolium pretense L. In the aboveground parts of the plants that grew in me-dium supplemented with 20 mg dm-3 of Al+3/Cu+2, the increase of the concentration of these metals was not statistically significant.
Celem pracy było określenie zawartości magnezu w roślinach Trifolium praten-se L., które rosły w środowisku skażonym glinem lub miedzią. Wzrost i rozwój roślin prowadzono w hydroponice, przy ściśle kontrolowanym składzie i pH pożywki. Do pożywki dodano miedź, (jako dodatkową aplikację) w formie CuSO4·5H2O lub glin w formie AlCl3 w stężeniach 20 i 100 mg·dm-3. .Zawartość glinu , magnezu i miedzi w ekstraktach z korzeni i części nadziemnych oznaczono Emisyjnym Sekwencyjnym Spektrometrem ICP D-820 Hilger Analytical. Obniżenie pH pożywki nie wpłynę-ło istotnie na zmiany zawartości badanych metali. W badanych roślinach Trifolium pratense L, które rosły w środowisku skażonym Al+3/Cu+2 w stężeniu 100 mg·dm-3 stwierdzono istotny wzrost zawartości glinu i miedzi zarówno w korzeniach, jak i częściach nadziemnych oraz obniżenie zawartości magnezu. Przy niższym stężeniu obu stresorów (20 mg·dm-3), odnotowano spadek zawartości magnezu w całej roślinie i istotne zwiększenie zawartości glinu i miedzi w korzeniach Trifolium pratense L. Wczęściach nadziemnych roślin, które rosły w pożywce dodatkiem 20 mg·dm-3 jonów Al+3/Cu+2 , wzrost zawartości tych metali nie był statystycznie istotny.
Źródło:
Acta Agrophysica; 2013, 20, 3
1234-4125
Pojawia się w:
Acta Agrophysica
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 628

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