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Wyświetlanie 1-15 z 35
Tytuł:
Alanine dosimetry of 60 MeV proton beam - preliminary results
Autorzy:
Michalec, B.
Mierzwińska, G.
Sowa, U.
Ptaszkiewicz, M.
Nowak, T.
Swakoń, J.
Powiązania:
https://bibliotekanauki.pl/articles/146730.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
alanine
dosimetry
electron paramagnetic resonance (EPR)
proton beam
Opis:
Electron paramagnetic resonance (EPR) spectrometry (X-band) was used to determine the dose absorbed in alanine detectors, of different shapes and different alanine content, irradiated with Co-60 gamma rays and in a 60 MeV proton beam. The goal of our study was to confirm applicability of alanine as a passive detector in therapeutic proton beam. In the paper dose response characteristic and relative efficiency of alanine are shown. The study confirmed that alanine detectors with a high alanine content (ca. 95%) may be a useful and convenient tool for dose measurements in proton beams, used for eye cancer treatment.
Źródło:
Nukleonika; 2012, 57, 4; 503-506
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Attaching a spin to a protein - site-directed spin labeling in structural biology
Autorzy:
Czogalla, Aleksander
Pieciul, Aldona
Jezierski, Adam
Sikorski, Aleksander
Powiązania:
https://bibliotekanauki.pl/articles/1041067.pdf
Data publikacji:
2007
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
protein structure
site-directed spin labeling
electron paramagnetic resonance (EPR) spectroscopy
Opis:
Site-directed spin labeling and electron paramagnetic resonance spectroscopy have recently experienced an outburst of multiple applications in protein science. Numerous interesting strategies have been introduced for determining the structure of proteins and its conformational changes at the level of the backbone fold. Moreover, considerable technical development in the field makes the technique an attractive approach for the study of structure and dynamics of membrane proteins and large biological complexes at physiological conditions. This review focuses on a brief description of site-directed spin labeling-derived techniques in the context of their recent applications.
Źródło:
Acta Biochimica Polonica; 2007, 54, 2; 235-244
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bloch - Siegert shift in the Rabi oscillations on the “dressed” electron spin states
Autorzy:
Fedaruk, R.
Kolasa, A.
Saiko, A. P.
Powiązania:
https://bibliotekanauki.pl/articles/146386.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
electron paramagnetic resonance (EPR)
Bloch-Siegert shift
Rabi oscillation
bichromatic field
dressed state
spin qubit
Opis:
Using electron paramagnetic resonance (EPR) at Rabi frequencies, we study the Bloch-Siegert effect in the coherent dynamics of electron spin states driven by a bichromatic radiation consisting of a transverse microwave (MW) and longitudinal radio frequency (RF) fields. The Rabi oscillations on the electron spin states “dressed” by the MW field are observed at the double resonance, when the MW frequency equals the Larmor frequency of the spin system and the frequency ωrf of the RF field is close to the Rabi frequency ω1 in the MW field. The dispersive (|ωrf – ω1| ~ ωrf, ω1) and near-resonant (ωrf ≈ ω1) regimes are investigated. We demonstrate that the Bloch-Siegert shift increases with increasing RF amplitude and at the fixed RF amplitude it has the largest values in the “low-frequency” (ωrf < ω1) range of the dispersive regime. Experimental results were obtained in the time-resolved EPR for E’1 centres in quartz.
Źródło:
Nukleonika; 2013, 58, 3; 375-378
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparatwe EPR analysis of oxygen interactions with plants carbonized at different temperatures
Autorzy:
Bartłomiejczyk, S.
Pilawa, B.
Krzesińska, M.
Pusz, S.
Zachariasz, J.
Wałach, W.
Powiązania:
https://bibliotekanauki.pl/articles/284848.pdf
Data publikacji:
2008
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
karbonizacja roślin
centra paramagnetyczne
paramagnetyczne utlenianie cząsteczek
elektroniczny rezonans paramagnetyczny
widma EPR
oksymetria
carbonized plants
paramagnetic centers
paramagnetic oxygen molecules
electron paramagnetic resonance
EPR spectra
oximetry
Opis:
Carbon materials, bamboo (Bambusa vulagris) and yucca (Yucca flaccida) pyrolysed at 550°C, 750°C and 950°C, were tested as oximetric probes by electron paramagnetic resonance spectroscopy at X-band (9.3 GHz). The following parameters of the spectra: amplitude, linewidth and g-factor, were determined. Influence of oxygen molecules 02 on EPR spectra of the individual carbon materials was compared. Strong EPR spectra were recorded for samples carbonized at 550°C and weak signals were obtained for plants carbonized at higher temperatures: 750°C and 950°C. It was stated that amplitudes of EPR lines of all the carbonized plants decrease in the air environment compared to amplitudes of spectra measured in vacuum. This effect increases with degree of vacuum. Changes in the EPR spectra of samples studied in the air environment may be applied in medicine to determination of oxygen content in different cells. Because of strong resonance signals as oximetric probes we proposed bamboo and yucca carbonized at 550°C, and we rejected plants carbonized at 750°C and 950°C with Iow EPR signals.
Źródło:
Engineering of Biomaterials; 2008, 11, 73; 3-5
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Concentration of free radicals in faba bean seeds after the pre-sowing treatment of the seeds with laser light
Autorzy:
Podlesny, J.
Misiak, L.
Koper, R.
Powiązania:
https://bibliotekanauki.pl/articles/25440.pdf
Data publikacji:
2001
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
concentration
laser light
pre-sowing treatment
electron paramagnetic resonance
faba bean
free radical
plant cultivation
seed
Źródło:
International Agrophysics; 2001, 15, 3
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Copper-manganese-zinc spinels in zeolites : study of EMR spectra
Autorzy:
Decyk, P.
Więckowski, A. B.
Najder-Kozdrowska, L.
Bilkova, I.
Powiązania:
https://bibliotekanauki.pl/articles/146776.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Cu-Mn-Zn spinels
electron magnetic resonance
paramagnetic complexes
Y zeolites
Opis:
The aim of this study is the application of electron magnetic resonance (EMR) spectroscopy to determine the interactions between NaY and HY zeolites and Cu-Mn-Zn spinels loaded onto the zeolite surfaces. The materials were characterized using XRD and IR spectroscopies. Four types of EMR lines were observed for Cu-Mn-Zn/NaY, Cu-Mn-Zn/HY samples. The difference between the EMR spectra recorded at 77 and 293 K has been shown. The spectra recorded at 77 K allowed us to distinguish between the species formed on NaY and HY zeolites. The EMR spectrum of Cu-Mn-Zn/NaY recorded at 77 K showed only one line attributed to antiferromagnetic spinels Cu1.4Mn1.6O4 and ZnMn2O4 or/and Cu0.5Zn0.5Mn2O4. The spinels appeared to be more stable (more strongly attached) on HY zeolite than on NaY one. It was proved that different strength of interactions between the zeolites and Cu-Mn-Zn spinels was caused by differences in the acidity of NaY and HY zeolites.
Źródło:
Nukleonika; 2015, 60, No. 3, part 1; 423-428
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of the fraction of paramagnetic centers not-fulfilling the Curie law in coal macerals by the two-temperature EPR measurement method
Autorzy:
Słowik, G. P.
Więckowski, A. B.
Powiązania:
https://bibliotekanauki.pl/articles/146892.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
electron paramagnetic resonance (EPR)
macerals
two-temperature EPR measurement
Opis:
Two-temperature electron paramagnetic resonance (EPR) measurements, applied to determine the relative contributions of paramagnetic centers – fulfilling and not-fulfilling the Curie law, were carried out. The measurements were made on the macerals – exinite and vitrinite, separated from clarain of the Polish medium- -rank coal (85.6 wt% C). The two-temperature EPR measurements, presented in this work, were performed respectively, at temperatures: T1 = 293 K and T2 = 173 K for exinite, and T1 = 293 K and T2 = 153 K for vitrinite. The relative contributions X of spins not-fulfilling the Curie law present in the studied macerals were calculated. A comparison of different methods of calculating the relative contributions of paramagnetic centers – fulfilling and not-fulfilling the Curie law, present in exinite and vitrinite studied by EPR was made.
Źródło:
Nukleonika; 2015, 60, No. 3, part 1; 389-393
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of microwave power on EPR spectra of DOPA-melanin-netilmicin complexes with different drug concentrations : a study at temperatures in the range of 125-275 K
Autorzy:
Zdybel, M.
Pilawa, B.
Buszman, E.
Wrześniok, D.
Krzyminiewski, R.
Kruczyński, Z.
Powiązania:
https://bibliotekanauki.pl/articles/146482.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
DOPA-melanin
electron paramagnetic resonance (EPR) spectroscopy
free radicals
netilmicin
Opis:
Electron paramagnetic resonance (EPR) spectra of the model eumelanin – DOPA-melanin complexes with netilmicin measured with a microwave power in the range 0.3–200 mW were examined. The influence of microwave power on amplitudes (A) and linewidths (ΔBpp) of the spectra was determined. The EPR spectra were recorded by a BRUKER spectrometer at temperatures 125, 175, 225 and 275 K. Continuous microwave saturation of EPR lines was used to compare the acceleration of spin-lattice relaxation processes in melanin samples. Changes of the parameters of the EPR spectra of DOPA-melanin-netilmicin complexes, with the microwave power for the samples differing in netilmicin concentrations, were observed. The effect of temperature on the changes of the EPR spectra of the analyzed melanin complexes with the microwave power was determined. The spin-lattice relaxation is faster at higher temperatures for all the tested melanin complexes.
Źródło:
Nukleonika; 2013, 58, 3; 407-411
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron paramagnetic resonance [EPR] investigations of laser induced free radicals in spring wheat grains
Autorzy:
Drozd, D.
Szajner, H.
Jezierski, A.
Powiązania:
https://bibliotekanauki.pl/articles/25812.pdf
Data publikacji:
1999
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
spring wheat
wheat grain
laser
electron paramagnetic resonance
free radical
Źródło:
International Agrophysics; 1999, 13, 3
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron paramagnetic resonance (EPR) study of the short - living radicals generated thermally in phosphorylated maize starch with different amounts of amylose
Autorzy:
Bidzińska, E.
Dyrek, K.
Kruczała, K.
Szczygieł, J.
Wenda, E.
Błaszczak, W.
Fornal, J.
Powiązania:
https://bibliotekanauki.pl/articles/147482.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
carbon centred radicals
electron paramagnetic resonance (EPR) spectroscopy
PBN spin trap
starch phosphates
thermal treatment
Opis:
Quantitative electron paramagnetic resonance (EPR) spectroscopy was used for the determination of a number and properties of short-living radicals generated thermally in maize starch with various amounts of amylose. The EPR spectra of radical adducts with N-tert-butyl-α-phenylnitrone (PBN) spin trap reveal the presence of three types of radicals of mobility related with their localization in the zones of various degree of crystallinity. Hylon VII, which represents a matrix with a high content of amylose, offers better conditions for free rotation of radical species, whereas waxy maize, containing almost exclusively amylopectin, exhibits more restricted dynamics.
Źródło:
Nukleonika; 2013, 58, 3; 429-433
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron paramagnetic resonance studies of manganese and cobalt ions in YAlO3 crystals
Autorzy:
Stefaniuk, I.
Rogalska, I
Suchocki, A
Berkowski, M.
Cieniek, B.
Potera, P.
Powiązania:
https://bibliotekanauki.pl/articles/174068.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
electron paramagnetic resonance (EPR)
spin Hamiltonian
Mn2+
Mn4+
Co2+
Fe3+
Cr3+
Nd3+ and Er3+ ions
YAlO3 (YAP) crystals
Opis:
The results of X-band electron paramagnetic resonance measurements of Mn2+ and Mn4+ ions in YAlO3 (YAP) crystals in the temperature range 100–300 K are presented. Additionally, we observe electron paramagnetic resonance spectra of unintentional impurities Fe3+ and Cr3+ in YAP crystals. The angular dependence for Mn ions in YAP crystals can be presented. We aim at obtaining a better insight into the spectroscopic properties of paramagnetic Mn centers and structural information about their nearest environment in YAP host and at determining the valence of manganese ion. In this paper we compare electron paramagnetic resonance spectra for Co and Mn ions in YAP crystals.
Źródło:
Optica Applicata; 2014, 44, 1; 113-121
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR measurements of ceramic cores used in the aircraft industry
Autorzy:
Stefaniuk, I.
Rogalska, I..
Potera, P.
Wróbel, D.
Powiązania:
https://bibliotekanauki.pl/articles/148814.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Al2O3
electron paramagnetic resonance (EPR)
mullite
nanopowders
Opis:
In this work the electron paramagnetic resonance (EPR) spectra of Al2O3 and ZrO2 powders were measured for different size of grains (0.074, 0.044 mm) as well as the mullites (0.07 and 0.12 mm). Also were investigated the ceramic cores. The measurements were performed at room temperature and in the temperature range from 140 up to 380 K. The main purpose of this work was to investigate the possible relationships between the EPR spectra and the size of powder grains as well as the identification of EPR spectra in view of the potential application of EPR technique as a fingerprinting method.
Źródło:
Nukleonika; 2013, 58, 3; 391-395
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR spectroscopy of Cu2+ and Mn2+ in borate glasses
Autorzy:
Drzewiecki, A.
Padlyak, B.
Adamiv, V.
Burak, Y.
Teslyuk, I.
Powiązania:
https://bibliotekanauki.pl/articles/147654.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
borate glasses
Cu2+ paramagnetic centre
electron paramagnetic resonance (EPR) spectroscopy
hyperfine structure
Mn2+ paramagnetic centre
Opis:
Electron paramagnetic resonance (EPR) spectra of the CaB4O7 and LiCaBO3 glasses containing 0.5 and 1.0 mol.% CuO and MnO2 impurity compounds were investigated at room temperature. The glasses with CaB4O7:Cu, LiCaBO3:Cu, CaB4O7:Mn and LiCaBO3:Mn compositions were produced from the corresponding polycrystalline compounds using standard glass synthesis and technological conditions developed by the authors. The EPR spectral parameters of the Cu2+ and Mn2+ centres in both glasses containing 0.5 and 1.0 mol.% CuO and MnO2 doping oxides were determined. Analysis of EPR spectral parameters shows that Cu impurity is incorporated into the CaB4O7 and LiCaBO3 glass network as isolated Cu2+ (3d9, 2D5/2) paramagnetic ions. The Cu2+ ions occupy Ca(Li) sites of the borate glass network coordinated by six O2− anions with geometry of elongated octahedron (D4h symmetry) due to the Jahn- -Teller effect. The EPR spectra of the Mn-doped CaB4O7 and LiCaBO3 glasses are virtually identical and typical of all oxide glasses activated with Mn2+ (3d5, 6S5/2) ions. Observed EPR spectra in the Mn-doped glasses were attributed to isolated Mn2+ (1) centres (geff ≅ 4.3) in octahedral Ca(Li) sites with a strong (fully) rhombic distortion, isolated Mn2+ (2) centres (geff ≅ 2.0) in octahedral Ca(Li) sites with nearly cubic local symmetry as well as pairs and small clusters of the Mn2+ ions, coupled by magnetic dipolar and exchange interactions. On the basis of the obtained results and analysis of referenced data, the local structure of the Cu2+ and Mn2+ centres in the borate glasses have been proposed.
Źródło:
Nukleonika; 2013, 58, 3; 379-385
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR studies of Cladosporium cladosporioides complexes with amphotericin B
Autorzy:
Zdybel, M.
Pilawa, B.
Buszman, E.
Witoszyńska, T.
Powiązania:
https://bibliotekanauki.pl/articles/147790.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
amphotericin B
Cladosporium cladosporioides
electron paramagnetic resonance (EPR) spectroscopy
free radicals
melanin
Opis:
Free radicals in Cladosporium cladosporioides cultured with amphotericin B were spectroscopically studied. The effect of drug concentrations on free radicals in the fungal melanin biopolymer was examined. It was pointed out that the concentrations of free radicals in the complexes of Cladosporium cladosporioides mycelium with amphotericin B depend on the drug concentrations. Eumelanin dominates in the fungal studied samples. The slow spin-lattice relaxation processes exist in the tested samples. Free radicals take a part in the formation of Cladosporium cladosporioides mycelium complexes with amphotericin B.
Źródło:
Nukleonika; 2013, 58, 3; 401-405
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
EPR studies of free radicals in thermally sterilized famotidine
Autorzy:
Ramos, P.
Pilawa, B.
Stroka, E.
Powiązania:
https://bibliotekanauki.pl/articles/148414.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
free radicals
thermal sterilization
famotidine
electron paramagnetic resonance (EPR) spectroscopy
Opis:
Free radicals formation in thermally sterilized famotidine was studied by the use of an X-band (9.3 GHz) electron paramagnetic resonance (EPR) spectroscopy. The influence of temperature and time of sterilization on free radicals generated in famotidine was determined. The best sterilization conditions for the tested drug were found. Sterilization was done according to the pharmaceutical norms at temperatures 160°C (120 min), 170°C (60 min), and 180°C (30 min). It was pointed out that the optimal temperature of thermal sterilization for famotidine was 170°C and time of heating 60 min in this conditions the lowest free radicals concentration was found. The highest free radicals concentration was measured in famotidine heated at 160°C during 120 min, the long time of sterilization is responsible for this effect. Free radicals concentration changes during storage of famotidine after thermal sterilization. Its value increased with storage time for the drug sterilized at both temperatures of 170°C and 180°C. Free radicals concentration decreases from 7 days after sterilization. Complex system of free radicals with the shape of EPR lines, dependent on microwave power exist in thermally sterilized famotidine. Slow spin-lattice relaxation processes, strong dipolar interactions characterize thermally sterilized famotidine. Microwave saturation indicates that EPR lines of famotidine are homogeneously broadened. The usefulness of EPR spectroscopy to examine of the sterilized drugs was evaluated.
Źródło:
Nukleonika; 2013, 58, 3; 413-418
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 35

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