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    Wyświetlanie 1-27 z 27
    Tytuł:
    A successful operational initiative in copper oxide flotation: Sequential sulphidisation-flotation technique
    Autorzy:
    Asadi, Moharram
    Soltani, Faraz
    Mohammadi, Mohammad Reza Tavakoli
    Khodadadi, Darban Ahmad
    Abdollahy, Mahmoud
    Powiązania:
    https://bibliotekanauki.pl/articles/110770.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    copper oxide
    sulphidisation
    flotation
    Opis:
    One of the main challenges in the copper oxide processing industry is implementation of a flotation method to reduce operating costs. Sulphidising flotation is the most common used technique in which a sulphidisation agent is used to sulphidise the surface of the oxide minerals. In this research, the mentioned technique was used sequentially for the concentration of silicate-carbonate ore containing 3.1% Cu (malachite). The presence of 39% Cu in -38 μm size fraction (fine particles) of feed led to poor grades and recoveries in the initial tests. The addition of sodium sulfide and subsequent flotation at three sequential stages was identified as a successful operational initiative to solve this problem in the following tests. The dosages of 1500, 1567 and 100 g/Mg of sodium silicate, sodium sulfide and potassium amyl xanthate, respectively, the conditioning time of 5 min for sulphidisation and pH=9.72 were chosen as optimum operational conditions using central composite design (CCD) method of experiments design. The rougher concentrate with 9.28% grade and 81.15% recovery was obtained under these conditions. The grade of obtained concentrate was reached to 24% in the cleaner step. The total recovery of both steps was over 74%.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 2; 356-369
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Analysis of chemical and phase composition of copper oxide prepared by direct current sputtering for photovoltaic applications
    Autorzy:
    Sawicka-Chudy, P.
    Wielgosz, M.
    Wal, A.
    Cieniek, B.
    Wisz, G.
    Głowa, Ł.
    Cholewa, M.
    Sawicka, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/101735.pdf
    Data publikacji:
    2018
    Wydawca:
    Instytut Polityki Energetycznej im. Ignacego Łukasiewicza
    Tematy:
    XRF
    XRD
    copper oxide
    photovoltaics
    Opis:
    This paper presents the application of X-ray fluorescence and X-ray diffraction methods for the study of copper oxide structures as an absorber layer in thin-film solar cells. The layers of copper oxide were applied by direct current magnetron sputtering. Quantitative and qualitative analysis of oxide layers were performed using XRF (X-ray fluorescence). The studies showed a high copper content in both samples, amounting to 98% and 96%, as well as trace amounts of other elements (nickel, lead). The XRD (X-ray diffraction) study showed Cu20 and Cu8O phases, amorphism ranging from 24% to 44%, and crystallinity from 55% to 75%. Crystallites of 30 nm were also determined. The aim of the study was to determine the chemical and phase composition of the layers obtained and to determine the degree of their contamination depending on the parameters of the manufacturing technology in terms of their application in photovoltaics. One of the samples showed an advantage both in terms of material and structural composition.
    Źródło:
    Energy Policy Studies; 2018, 1 (2); 3-11
    2545-0859
    Pojawia się w:
    Energy Policy Studies
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Evaluation of the quality of titanium oxide and copper oxide layers by means of optical microscopy
    Autorzy:
    Głuszek, A.
    Sawicka-Chudy, P.
    Wisz, G.
    Sibiński, M.
    Cholewa, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/101772.pdf
    Data publikacji:
    2018
    Wydawca:
    Instytut Polityki Energetycznej im. Ignacego Łukasiewicza
    Tematy:
    titanium oxide
    copper oxide
    optical microscopy
    histograms
    Opis:
    The aim of this paper is to analyse high-resolution optical images of the surface layers of titanium oxide and copper oxide. The materials were produced using the PREVAC Modular Platform for layer deposition located at the University of Rzeszów. Images with a magnification of 50x were obtained using an optical microscope. On the basis of the results obtained, the quality of the layers was evaluated based on the image analysis. The quantitative method of analysis was applied, as a result of which the conditions of the manufacturing process for which the obtained layers had the highest homogeneity were indicated. The minimum range of grey shade counting was from 65 to 150 and the maximum range from 135 to 220. The standard deviation was from 8 to 40%.
    Źródło:
    Energy Policy Studies; 2018, 1 (2); 39-51
    2545-0859
    Pojawia się w:
    Energy Policy Studies
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Solar cells based on copper oxide and titanium dioxide prepared by reactive direct-current magnetron sputtering
    Autorzy:
    Wisz, Grzegorz
    Sawicka-Chudy, Paulina
    Sibiński, Maciej
    Starowicz, Zbigniew
    Płoch, Dariusz
    Góral, A.
    Bester, Mariusz
    Cholewa, M.
    Woźny, Janusz
    Sosna-Głębska, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/1818195.pdf
    Data publikacji:
    2021
    Wydawca:
    Polska Akademia Nauk. Stowarzyszenie Elektryków Polskich
    Tematy:
    solar cells
    copper oxide
    titanium dioxide
    reactive magnetron sputtering
    Opis:
    In this study, solar cells based on copper oxide and titanium dioxide were successfully manufactured using the reactive direct-current magnetron sputtering (DC-MS) technique with similar process parameters. TiO₂/CuO, TiO₂/Cu₂O/CuO/Cu₂O, and TiO₂/Cu₂O solar cells were manufactured via this process. Values of short-circuit current efficiencies, short-circuit current density, open-circuit voltage, and maximum power of PV devices were investigated in the range of 0.02÷0.9%, 75÷350 µA, 75÷350 µA/cm², 16÷550 mV, and 0.6÷27 µW, respectively. The authors compare solar cells reaching the best and the worst conversion efficiency results. Thus, only the two selected solar cells were fully characterized using I-V characteristics, scanning electron microscopy, X-ray diffraction, ellipsometry, Hall effect measurements, and quantum efficiency. The best conversion efficiency of a solar cell presented in this work is about three times higher in comparison with the authors’ previous PV devices.
    Źródło:
    Opto-Electronics Review; 2021, 29, 3; 97--104
    1230-3402
    Pojawia się w:
    Opto-Electronics Review
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    aaSolar cells based on copper oxide and titanium dioxide prepared by reactive direct-current magnetron sputtering
    Autorzy:
    Wisz, G.
    Sawicka-Chudy, P.
    Sibiński, M.
    Starowicz, Z.
    Płoch, D.
    Góral, A.
    Bester, M.
    Cholewa, M.
    Woźny, J.
    Sosna-Głębska, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/1818199.pdf
    Data publikacji:
    2021
    Wydawca:
    Polska Akademia Nauk. Stowarzyszenie Elektryków Polskich
    Tematy:
    solar cells
    copper oxide
    titanium dioxide
    reactive magnetron sputtering
    Opis:
    In this study, solar cells based on copper oxide and titanium dioxide were successfully manufactured using the reactive direct-current magnetron sputtering (DC-MS) technique with similar process parameters. TiO₂/CuO, TiO₂/Cu₂O/CuO/Cu₂O, and TiO₂/Cu₂O solar cells were manufactured via this process. Values of short-circuit current efficiencies, short-circuit current density, open-circuit voltage, and maximum power of PV devices were investigated in the range of 0.02÷0.9%, 75÷350 µA, 75÷350 µA/cm², 16÷550 mV, and 0.6÷27 µW, respectively. The authors compare solar cells reaching the best and the worst conversion efficiency results. Thus, only the two selected solar cells were fully characterized using I-V characteristics, scanning electron microscopy, X-ray diffraction, ellipsometry, Hall effect measurements, and quantum efficiency. The best conversion efficiency of a solar cell presented in this work is about three times higher in comparison with the authors’ previous PV devices.
    Źródło:
    Opto-Electronics Review; 2021, 29, 3; 97--104
    1230-3402
    Pojawia się w:
    Opto-Electronics Review
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Investigation of Metal Oxides as Catalysts for the Thermal Decomposition of Potassium Chlorate(VII)
    Autorzy:
    Wojewódka, A.
    Zakusylo, R.
    Kravets, V.
    Romanchenko, A.
    Jarosz, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/358236.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    metal oxide catalysts
    thermal decomposition
    potassium perchlorate
    manganese oxide
    copper oxide
    differential thermal analysis
    Opis:
    The results of studies on the thermal decomposition of potassium chlorate(VII) (PP) and the catalytic effects of copper, iron, nickel, titanium, magnesium, chromium and manganese oxides on the process are presented in this paper. The investigated oxides are ranked according to the magnitude of their catalytic effect; of these, CuO and МnО2 show the best catalytic performance. These oxides reduce the PP decomposition temperature from 919.3 K down to even 825.2 K. The share of the catalytic additive in the composition, required to achieve a desirable thermal decomposition profile, was found to be no more than 0.5 wt.%. The activation energy of the decomposition process was determined, using the modified Freeman and Carroll method for both neat PP and PP supplemented with MnO2; the addition of the catalyst produced a 48.8% decrease in the activation energy of thermal decomposition.
    Źródło:
    Central European Journal of Energetic Materials; 2018, 15, 2; 327-338
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Some Physical Properties of Copper Oxide Thin Films Prepared by Electrolysis Method
    Autorzy:
    Oudah, Mustafa H.
    Mazin, H. Hasan
    Abd, Ahmed N.
    Powiązania:
    https://bibliotekanauki.pl/articles/1065248.pdf
    Data publikacji:
    2019
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    copper oxide
    drop-casting method
    electrolysis
    quantum size effect
    thin films
    Opis:
    The aim of this paper is to study the properties of copper oxide thin films prepared by electrolysis method and deposited on glass substrates by drop-casting method at different annealing temperatures. Copper oxide colloidal was successfully prepared by electrolysis method. The X-ray diffraction confirms the polycrystalline structure of the films. Atomic force microscopy shows that the increase in the annealing temperature improves the surface morphology, increases the grain size and removes the cracks. The best optical transmittance was for the film annealed at 200 ºC. The bandgap decreases from 3.35 eV to 3.15 eV as a result of increasing the annealing temperature. The wide bandgap that obtained in this study is due to quantum size effect.
    Źródło:
    World Scientific News; 2019, 135; 59-70
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and Characterization of CuO Nanoparticles by the Chemical Liquid Deposition Method and Investigation of Its Catalytic Effect on the Thermal Decomposition of Ammonium Perchlorate
    Autorzy:
    Eslami, A.
    Juibari, N. M.
    Hosseini, S. G.
    Abbasi, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/358128.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    copper oxide nanoparticles
    ex-situ growth
    ammonium perchlorate
    thermal decomposition
    chemical liquid deposition
    Opis:
    Copper oxide nanoparticles have been synthesized by the chemical liquid deposition method and characterized by means of X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The XRD and SEM results showed that the particle size was between 50 nm and 70 nm. Ammonium perchlorate (AP)-CuO nanostructures have been prepared by ex-situ mixing of AP and CuO nanoparticles, while AP/CuO nanocomposites have been obtained by in-situ growth of nano CuO on the surface of AP. The effect of the nanoparticles on the thermal decomposition of AP has been examined by differential scanning calorimetery (DSC) and thermogravimetric analysis (TGA) methods. The results showed that the ex-situ prepared nanoparticles had better catalytic activity than the in-situ prepared ones. The effect of the synthesized nanoparticles on the thermal decomposition of AP in experiments with a AP to CuO ratio of 98:2 was as follows: with the ex-situ prepared experiments, the decomposition temperature decreased from 428 °C to 348 °C and the heat released increased from 344 J·g−1 to 1432 J·g−1, while those with the in-situ prepared samples exhibited 341 °C and 1317 J·g−1, respectively.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 1; 152-168
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Copper (II) Oxide particles as Adsorbent for Removal of Alkali Blue; Isotherm and Kinetic Studies
    Autorzy:
    Ibrahim, M. A.
    Ibrahim, M. B.
    Powiązania:
    https://bibliotekanauki.pl/articles/1158766.pdf
    Data publikacji:
    2018
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Adsorption
    Copper (II) Oxide particles
    FTIR
    Isotherm
    Kinetics
    Opis:
    Adsorption behaviour of copper (II) oxide particles (CuO-Ps) for the removal of Alkali Blue (AB) was studied. Different adsorption variables such as contact time, initial concentration and pH for the adsorption process were investigated by batch adsorption studies. FTIR was carried out to determine the functional groups present at the surface of the particle with functional groups such as –OH, C=C, C-H, C≡C detected. The percentage removal and optimum contact time for the removal of AB was 84.8% at 10 min. The experimental isotherms data were analyzed using Langmuir, Temkin, Freundlich and Dubinin-Radushkevich (D-R) isotherms and it was observed that AB fits closely to Langmuir with R2 value of 0.884. Kinetics studies shows that the adsorption process fits better to pseudo-second order with the experimental values of qe 4.242 been closer to the calculated values of the qe 4.108. Effect of pH shows that it adsorb better at the initial pH of 5.30. Lower value of mean square energy of 0.707 kJ/mol indicates that the adsorption process is physical. The results indicated that copper (II) oxide particle can be used as a low-cost adsorbent for the removal of AB from aqueous solutions.
    Źródło:
    World Scientific News; 2018, 114; 208-217
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Use of synthetic zeolite materials from fly ash to remove copper(II) ions from aqueous solutions
    Autorzy:
    Ulatowska, Justyna
    Stala, Łukasz
    Nowakowska, Alicja
    Polowczyk, Izabela
    Powiązania:
    https://bibliotekanauki.pl/articles/1450167.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fly ash
    copper oxide (II)
    Cu(II)
    modification of fly ashes
    zeolite materials
    adsorption
    Opis:
    Water quality and waste management are two chief problems that the modern world is struggling with. Intensified development of the industry not only leads to the production of large amounts of solid waste that must be stored in landfills but can also result in contaminant emissions into the environment. Enormous quantities of ash produced from coal combustion have been a long-term problem of the industry. Literature studies show that fly ash can be used as a material to produce cheap and efficient zeolite-type adsorbents due to abundance of alumina-silicates in their composition. Fly ashes which were processed into zeolites as a result of alkaline hydrothermal treatment were obtained from two power plants in Poland (in Turów and Zgierz). The obtained zeolite materials and raw fly ash samples were characterised in terms of specific surface area, particle size distribution and density. The structure was also investigated using Fourier transform infrared spectroscopy (FTIR) in the mid- infrared wavenumber range. Two raw fly ashes and two zeolite materials were examined for their ability to remove Cu(II) ions from aqueous solutions. The results showed that the amount of adsorbed copper ions by alkaline-modified fly ash was higher than for unmodified fly ash. The ion removal efficiency is high and exceeds 95%.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 6; 114-124
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Symulacja komputerowa procesu redukcji ciekłego żużla
    Computer simulation of process in molten oxide slag reduction
    Autorzy:
    Kalisz, D.
    Rzadkosz, S.
    Piękoś, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/381577.pdf
    Data publikacji:
    2012
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    symulacja komputerowa
    ciekły żużel
    tlenek miedzi
    równowaga termodynamiczna
    computer simulation
    liquid slag
    copper oxide
    thermodynamic equilibrium
    Opis:
    Praca zajmuje się termodynamiczną analizą elementarnych procesów chemicznych zachodzących podczas redukcji żużla zawierającego tlenek miedzi. Redukcja żużla zachodzi przez zastosowanie reduktora w postaci stałej - węgla, gazowej - tlenek węgla lub węgla rozpuszczonego w ciekłym żużlu. Obecna praca rozpatruje dwa procesy chemiczne: reakcję ciekłego żużla z węglem oraz z tlenkiem węgla. Korzystając z komercyjnego oprogramowania FATSage obliczono w warunkach równowagi termodynamicznej składy faz dla układów: stały węgiel – ciekły żużel - stop Cu–Fe–Pb – faza gzowa oraz gazowy CO – ciekły żużel – stop Cu–Fe–Pb – faza gazowa. Symulację prowadzono dla temperatury procesu 1500, 1600, 1700 K. Gazowe produkty reakcji redukcji i stop Cu–Fe–Pb były usuwane z układu w każdym kroku obliczeniowym. Uzyskane wyniki obliczeń wykazały, że redukcja za pomocą węgla odgrywa zasadniczą rolę w procesie odzysku miedzi.
    The present work deals with thermodynamic analysis of process of the reduction of molten slag containing copper oxide. Reduction of liquid slag is possible with solid carbon, gaseous carbon oxide. and carbon dissolved in liquid slag. This work studied two chemical reactions of liquid slag containing copper oxide: with solid carbon and gaseous CO. Thermodynamic equilibrium in the system: solid carbon – liquid slag – metallic alloy Cu–Fe–Pb – gas and gaseous CO – liquid slag – metallic Cu–Fe–Pb – gas were calculated by means of FACTSage software. The simulation of the progress of reduction process at 1500, 1600, 1700K was obtained under assumption that the gaseous reduction products and metallic alloy Cu–Fe–Pb were removed from consideration after each simulation step. The calculation revealed that consumption of reducing agent is much higher in the case of CO reduction. The effect of simulation suggested, that reduction with solid carbon is the predominant mode of industrial process.
    Źródło:
    Archives of Foundry Engineering; 2012, 12, 1s; 91-96
    1897-3310
    2299-2944
    Pojawia się w:
    Archives of Foundry Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Anodic growth of copper oxide nanostructures in glow discharge
    Autorzy:
    Breus, A.
    Abashin, S.
    Lukashov, I.
    Serdiuk, O.
    Powiązania:
    https://bibliotekanauki.pl/articles/2201134.pdf
    Data publikacji:
    2022
    Wydawca:
    Stowarzyszenie Komputerowej Nauki o Materiałach i Inżynierii Powierzchni w Gliwicach
    Tematy:
    nanotechnology
    plasma synthesis
    copper oxide nanostructure
    glow discharge
    nanotechnologia
    synteza plazmowa
    nanostruktura tlenku miedzi
    wyładowanie jarzeniowe
    Opis:
    Purpose: Application of plasma glow discharge to copper oxide nanostructure growth is studied. The simplicity of the proposed technique may be beneficial for the development of new plasma reactors for large-scale production of diverse metal oxide nanostructures. Design/methodology/approach: Copper sample was placed on anode of a setup designed to ignite plasma glow discharge. The proposed approach allows eliminating the negative effects of ion bombardment, like sputtering and generation of defects on a surface of the growing nanostructures, but preserves the advantages of thermal growth. The growth process was explained in terms of thermal processes interaction occurring on a surface of the anode with the glow discharge plasma. Findings: Plasma treatment resulted in generation of reach and diverse nanostructures that was confirmed by SEM images. Nanowire-like, flower-like, anemone-like nanostructures and nanodisks composed into the nanoassemblies are observed; the nanostructures are associated with microbabbles on CuO layer. These findings allow concluding about the possible implementation of the proposed method in industry. Research limitations/implications: The main limitation is conditioned by the lack of heat supplied to the anode, and absence of independent control of the heat and ion fluxes; thus, the additional heater should be installed under the anode in order to expand the nomenclature of the nanospecies in the future studies. Practical implications: High-productivity plasma process in copper oxide nanostructures synthesis was confirmed in this research. It may be applied for field emitter and supercapacitor manufacturing. Originality/value: Oxide nanostructure synthesis is conducted by use of a simple and well-known glow discharge technique in order to expand the production yield and diversity of nanostructure obtained in the processes of thermal growth.
    Źródło:
    Archives of Materials Science and Engineering; 2022, 113, 3; 24--33
    1897-2764
    Pojawia się w:
    Archives of Materials Science and Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Próba zwiększenia własności przeciwzatarciowych Smaru Maszynowego 2
    Attempt at enhancing anti-seizing properties of Machine Grease 2
    Autorzy:
    Czupryk, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/189143.pdf
    Data publikacji:
    2012
    Wydawca:
    Stowarzyszenie Inżynierów i Techników Mechaników Polskich
    Tematy:
    Smar Maszynowy 2
    tlenki miedzi
    redukacja tlenku
    Auger Electron Spectroscopy (AES)
    Machine Grease 2
    copper oxide
    oxide reduction
    Auger electron spectroscopy (AES)
    Opis:
    Smar Maszynowy 2 charakteryzuje się zbyt niskimi własnościami przeciwzatarciowymi w zastosowaniu do smarowania łożysk tocznych. Cechę tę potwierdzają dane literaturowe i wyniki badań własnych wykonanych na aparacie czterokulowym. W celu zwiększenia własności przeciwzatarciowych Smaru Maszynowego 2 wprowadzono do jego objętości mieszankę tlenku miedzi i gliceryny z alkoholem etylowym. Badania miały na celu dać odpowiedź na pytanie, czy w warunkach dużych nacisków, zmiennych naprężeń i wysokich krótkotrwałych temperatur w obszarze kontaktu tlenek miedzi będzie redukowany do miedzi metalicznej, która będzie spełniała rolę smaru stałego. Badania wykonano na aparacie czterokulowym w trzech następujących po sobie seriach. Każda z nich trwała 60 sekund. Nacisk był stały i wynosił 1472 N. Po wykonaniu badań obliczono graniczne obciążenie zatarcia G0Z. Stwierdzono znaczny wzrost wskaźnika G0Z dla smarów z wymienionymi wcześniej dodatkami: G0Z dla Smaru Maszynowego 2 wynosił 529 [N/mm2], a dla innych składów dodatków wprowadzonych do smaru zawierał się w przedziale 900–1736 [N/mm2]. W celu potwierdzenia zjawiska redukcji tlenku miedzi do miedzi metalicznej wykonano badania powierzchniowe i wgłębne z użyciem spektrometrii AES. Wyniki analiz potwierdziły występowanie w warstwie powierzchniowej i warstwach głębiej zlokalizowanych miedzi metalicznej. Obecność warstewki metalicznej miedzi na ścieżce kontaktu spełniającej rolę smaru stałego skutkowała zwiększeniem odporności na zatarcie Ft trzy-, a nawet czterokrotnie w stosunku do tego samego wskaźnika dla Smaru Maszynowego 2.
    The anti-seizing properties of Machine Grease 2 are too poor to ensure the proper lubrication of rolling bearings. This is confirmed by research publications and the results of the author's tests carried out using the four-ball EP tester. In order to enhance the anti-seizing properties of Machine Grease 2, a mixture of copper oxide, glycerine, and ethyl alcohol was introduced into its volume. The aim of the tests was to find out if, under high pressures, variable stresses and short-duration temperatures in the contact region cause the copper oxide to be reduced to metallic copper functioning as grease. The tests in the four-ball EP tester were carried out in three consecutive series, each lasting 60 seconds. The pressure remained constant and amounted to 1472 N. After the tests, the limit of the seizure load G0Z was calculated. Index G0Z was found to be considerably higher for lubricants containing the above additives, amounting to 529 [N/mm2] and 900–1736 [N/mm2] for Machine Grease 2 and lubricating compositions containing the mixture of copper oxide, glycerine and ethyl alcohol, respectively. Due to the presence a metallic copper film on the contact path, seizure resistance Pt increased three to even four times in comparison with this index for Machine Grease 2.
    Źródło:
    Tribologia; 2012, 3; 35-44
    0208-7774
    Pojawia się w:
    Tribologia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Antiviral Activities of Cu2+ Ions in Viral Prevention, Replication, RNA Degradation, and for Antiviral Efficacies of Lytic Virus, ROS-Mediated Virus, Copper Chelation
    Autorzy:
    Ishida, Tsuneo
    Powiązania:
    https://bibliotekanauki.pl/articles/1177808.pdf
    Data publikacji:
    2018
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Capsid protein
    Copper chelation
    Copper homeostasis
    Copper oxide nanoparticles
    Cu2+ and Cu1+ ions
    DNA/RNA virus
    HSV
    ROS
    Viral replication
    mRNA degradation or decay
    Opis:
    Copper has been known for decades that marked changes of micronutrient homeostasis in the host are accompanied by infection or inflammation. Copper levels in the serum are significantly elevated in response to inflammation that copper accumulates at sites of inflammation. Easily oxidized copper oxide nanoparticles (CuONPs) are widely used as catalysts that the ability of CuONPs to reduce bacterial population and virus application is enhanced. The mechanism of copper-mediated inactivation of herpes simplex virus (HSV) is by which cupric ions oxidatively damage biomolecules. Virus-mediated subjugation and modulation of host lipids during infection that the life cycle of most viruses proceeds through a series of basic steps: binding and internalization, fusion, uncoating, of the viral genome, its replication, assembly of new particles, and budding or release of the newly made viruses. The HIV-1 protein Vpu is an 81-amino-acid (16-kDa) type I which the presence of Vpu leads to the degradation of BST-2 via an endosome-lysosome degradation pathway. Oxidative degradation by a Cu-metalloenzyme, and ubiquitin-mediated degradation of cellular proteins were exploited. Copper can disrupt the lytic cycle of the Coccolithovirus. Lysins represent a novel class of anti-infectives derived from bacteriophage which lysins are bacterial cell wall hydrolytic enzymes that selectively and rapidly kill specific bacteria. Regarding copper induced cellular toxicity, several mechanisms have been proposed based on the formations of ROS by free Cu ions as cupric and cuprous ions can participate in redox reactions. ROS (O2ˉ,･OH, OHˉ), Cu+ and H2O2 play the important roles for viral inactivations. Thujaplicin-copper chelates inhibit influenza virus-induced apoptosis. Pyrrolidine dithiocarbamate as a metal ion binding agent inhibits the activity of the viral proteases of polyprotein processing and RNA replication of HRV. Chelation enables metals are capable of ligand scavenging via complexation, since reverse transcriptase enzyme inhibits the growth and replication of RNA tumor viruses. Thus, copper complex and copper chelation enhance antiviral efficacy.
    Źródło:
    World Scientific News; 2018, 99; 148-168
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    3D block modelling of the Sin Quyen IOCG deposit, North Vietnam
    Autorzy:
    Hao, Duong Van
    Nguyen, Dinh Chau
    Klityński, Wojciech
    Zygo, Władysław
    Nowak, Jakub
    Powiązania:
    https://bibliotekanauki.pl/articles/27310153.pdf
    Data publikacji:
    2023
    Wydawca:
    Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
    Tematy:
    North Vietnam
    iron oxide copper deposits
    3D model
    resources
    deposit development
    Opis:
    The IOCG Sin Quyen deposit is located in the Red River shear zone of North Vietnam. The ore bodies are known as hydrothermal veins and are hosted in Proterozoic metapelite. A block modelling approach was used to build a 3D model of the ore bodies. An analysis was carried out on Surfer 11 computer software using the archival data recorded from several dozen boreholes distributed within the study area, as well as data obtained from the mineral and chemical analysis of 50 samples collected recently in the deposit. The ore bodies generally trend in a NW-SE direction with an average azimuth of 107° and dip of around 70°.The Cu content in the ore bodies is inhomogeneous. In the bed extension direction, the exponential correlation of Cu concentration in ore bodies is recognized within 2,500 m, while in the direction perpendicular to the bed strike, the exponential dependence is observed on 500 m of distance. The high-grade mineralisation of copper within the ore bodies is often at the altitude interval from ∼100 m to ∼150 m above sea level (asl). These bodies are also rich in uranium and gold bearing minerals. The total resources of Cu, U and Ag were estimated and amount to 361,000; 12.7 and 11.87 tonnes respectively. The model indicates the downward extension of some ore bodies to below 300 m beneath the ground surface.
    Źródło:
    Geology, Geophysics and Environment; 2023, 49, 2; 175--195
    2299-8004
    2353-0790
    Pojawia się w:
    Geology, Geophysics and Environment
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Morphology and properties of the graphene layer on the copper substrate
    Autorzy:
    Pietrzak, K.
    Olesińska, W.
    Strąk, C.
    Siedlec, R.
    Gładki, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/778091.pdf
    Data publikacji:
    2015
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    copper
    graphene
    graphene oxide
    reduced graphene oxide
    Opis:
    The aim of the work presented in the article was to clarify controversial comments about anti-corrosion and mechanical properties of graphene coatings, deposited on copper substrates. It was designed special experimental cycle comprising: preparation of graphene forms and copper, the observation of layers Cu / GO (rGO) after the thermal reduction processes and oxidative test in air at 150°C temperature and 350 h in time. The resulting coatings and graphene layers were subjected to tribological test for hardness. The observed differences in the continuity of the coverage copper surface by graphene forms, allowed to understand the macroscopic effect of increased hardness and wear resistance layers rGO/Cu.
    Źródło:
    Polish Journal of Chemical Technology; 2015, 17, 4; 104-108
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis of Copper-based Multi-walled Carbon Nanotube Composites
    Autorzy:
    Domagała, K.
    Borlaf, M.
    Kata, D.
    Graule, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/355954.pdf
    Data publikacji:
    2020
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    MWCNT
    water treatment
    copper
    cuprous oxide
    cupric oxide
    Opis:
    In this study, the synthesis of copper-based multi-walled carbon nanotube compositesis described. Over the last years, carbon nanotubes (CNTs) have been widely used in many scientific research fields and have found applications in several sectors, e.g. for water treatment. This work focuses on combining the exceptional characteristics of CNTs, such as high specific surface areaand antibacterial properties, with the antimicrobial / antivirus features of copper oxides. The influence of synthesis parameters and thermal treatment on the final product was studied. Copper leakage was evaluated at both pH 5 and pH 7, confirming the possibility of applying Cu-based MWCNT composites in water filtration systems.
    Źródło:
    Archives of Metallurgy and Materials; 2020, 65, 1; 157-162
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    THE INFLUENCE OF KETOPROFEN AND ZINC OXIDE NANOPARTICLES ON SERUM COPPER LEVEL IN RATS
    Autorzy:
    Olbert, Magdalena
    Krośniak, Mirosław
    Gdula-Argasińska, Joanna
    Librowski, Tadeusz
    Zygmunt, Małgorzata
    Powiązania:
    https://bibliotekanauki.pl/articles/956850.pdf
    Data publikacji:
    2018
    Wydawca:
    Zakład Opieki Zdrowotnej Ośrodek Umea Shinoda-Kuracejo
    Tematy:
    inflammation
    ketoprofen
    serum copper level
    zinc oxide nanoparticles
    zinc-copper antagonism
    Opis:
    The role of copper in anti-inflammatory response includes several mechanisms. Antagonism between zinc (Zn) and copper (Cu) and proper balance between the two elements in the organism may affect the course of inflammatory diseases. Copper is a component of Zn/Cu superoxide dismutase (Zn/Cu SOD) and other enzymes involved in the anti-inflammatory response of the organism. To investigate the serum copper level during inflammation and diseases, numerous researches were conducted. Copper deficiency or copper intoxication may lead to biological consequences. Copper deficiency may be caused by various factors, one of them is excessive zinc supplementation. The aim of the study was to investigate the alterations in the serum copper level after 2-week zinc oxide nanoparticles (NPs-ZnO) administration. The second aim was to investigate serum copper level alterations after 2-week NPs-ZnO and single ketoprofen administration. The inflammatory state was induced in each group by the carrageenan injection at the 15th day of the experiment. The results indicate for the decrease in serum copper level in group receiving NPs-ZnO compared to control. Moreover, in groups receiving NPs-ZnO as well as ketoprofen, a decrease in serum copper level was observed. We may conclude that NPs-ZnO administration and also ketoprofen administration acts as anti-inflammatory agents and may induce a decrease in serum copper level.
    Źródło:
    Medicina Internacia Revuo; 2018, 28, 110; 11-22
    0465-5435
    Pojawia się w:
    Medicina Internacia Revuo
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Mechanical Properties of Graphene Oxide–Copper Composites
    Autorzy:
    Duda, P.
    Muzyka, R.
    Robak, Z.
    Kaptacz, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/351676.pdf
    Data publikacji:
    2016
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    composites of copper
    graphene oxide
    surface microgeomety
    tribological properties
    Opis:
    Due to their characteristics, sintered Cu-C composites are materials used in electrical equipment. These characteristics include high electrical conductivity, thermal conductivity and excellent resistance to abrasion. Currently, graphite nanopowder is used successfully as a carbon material. Metal-graphite, which is created on its basis, exists in different proportions of graphite to metal. A larger graphite content has a positive effect on smaller wear of commutators and rings. In contrast, a material with a higher copper content is used at high current densities. An example of such machines is a DC motor starter characterized by low voltage and large current. Tribological properties of Cu-C composites depend on the form of carbon they include. Owing to the capability to manufacture graphene, it has become possible to produce composites with its content. The present study tested the effect of a graphene oxide content on tribological properties in contact with steel. Tests were conducted on a ball-on-disk apparatus in conditions of dry friction. Microscopic observation was performed on the Hitachi SU70 field emission electron microscope. EDS analyses were performed using the Thermo Scientific X-ray Microanalysis system. Disk wear and surface geometrical structure parameters (SGP) of the samples after tribological tests were determined on the basis of measurements made on the Talysurf 3D contact profilometer from Taylor Hobson.
    Źródło:
    Archives of Metallurgy and Materials; 2016, 61, 2A; 863-868
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Properties of Copper Doped Neodymium Nickelate Oxide as Cathode Material for Solid Oxide Fuel Cells
    Autorzy:
    Lee, K. J.
    Choe, Y-J.
    Hwang, H-J.
    Powiązania:
    https://bibliotekanauki.pl/articles/351292.pdf
    Data publikacji:
    2016
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    solid oxide fuel cells
    copper
    electrical conductivity
    excess oxygen
    Opis:
    Mixed ionic and electronic conducting K2NiF4-type oxide, Nd2Ni1-xCuxO4+δ (x=0~1) powders were synthesized by solid state reaction technique and solid oxide fuel cells consisting of a Nd2Ni1-xCuxO4+δ cathode, a Ni-YSZ anode and ScSZ as an electrolyte were fabricated. The effect of copper substitution for nickel on the electrical and electrochemical properties was examined. Small amount of copper doping (x=0.2) resulted in the increased electrical conductivity and decreased polarization resistance. It appears that this phenomenon was associated with the high mean valence of nickel and copper and the resulting excess oxygen (δ). It was found that power densities of the cell with the Nd2Ni1-xCuxO4+δ (x=0.1 and 0.2) cathode were higher than that of the cell with theNd2NiO4+δ cathode.
    Źródło:
    Archives of Metallurgy and Materials; 2016, 61, 2A; 625-628
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ozone decomposition on ZnO catalysts obtained from different precursors
    Autorzy:
    Milenova, Katya I.
    Nikolov, Penko M.
    Kasabova, Nikoleta A.
    Avramova, Ivalina A.
    Powiązania:
    https://bibliotekanauki.pl/articles/778353.pdf
    Data publikacji:
    2014
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    ozone decomposition
    zinc oxide catalyst
    manganese doping
    copper doping
    nanosize
    Opis:
    Kinetic investigations for ozone conversion on three different series of zinc oxide catalysts, containing pure ZnO and doped with Mn or Cu one with dopant content less than 1 wt.% were carried out. The different samples were obtained from carbonate, nitrate and acetate precursors. The as prepared catalysts were characterized by AAS, XRD, IR, EPR and BET methods. The mean size of the crystallites determined by XRD data is in the range 27÷68 nm. The presence of Mn2+ and Cu2+ ions into the ZnO matrix was established by EPR. The ozone decomposition was investigated for 30÷75°C temperature range. The zinc carbonate precursor samples show highest activity, while the nitrate precursor ones show lowest activity toward reaction decomposition of ozone in the whole temperature range. At 75°C two of the catalyst, obtained from carbonate precursor - ZnO and CuZnO show 100% conversion.
    Źródło:
    Polish Journal of Chemical Technology; 2014, 16, 4; 55-59
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and evaluation of radiolabeled, folic acid-PEG conjugated, amino silane coated magnetic nanoparticles in tumor bearing Balb/C mice
    Autorzy:
    Razjouyan, J.
    Zolata, H.
    Khayat, O.
    Nowshiravan, F.
    Shadanpour, N.
    Mohammadnia, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/147452.pdf
    Data publikacji:
    2015
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    superparamagnetic iron oxide nanoparticles (SPIONs)
    (3-aminopropyl) triethoxysilane (APTES)
    poly(ethylene glycol) (PEG)
    folic acid
    KB cells
    copper-64
    Opis:
    To design a potent agent for positron emission tomography/magnetic resonance imaging (PET/MRI) imaging and targeted magnetic hyperthermia-radioisotope cancer therapy radiolabeled surface modified superparamagnetic iron oxide nanoparticles (SPIONs) were used as nanocarriers. Folic acid was conjugated for increasing selective cellular binding and internalization through receptor-mediated endocytosis. SPIONs were synthesized by the thermal decomposition of tris (acetylacetonato) iron (III) to achieve narrow and uniform nanoparticles. To increase the biocompatibility of SPIONs, they were coated with (3-aminopropyl) triethoxysilane (APTES), and then conjugated with synthesized folic acid-polyethylene glycol (FA-PEG) through amine group of (3-aminopropyl) triethoxysilane. Finally, the particles were labeled with 64Cu (t1/2 = 12.7 h) using 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid mono (N-hydroxy succinimide ester) DOTA-NHS chelator. After the characterization of SPIONs, their cellular internalization was evaluated in folate receptor (FR) overexpressing KB (established from a HeLa cell contamination) and mouse fibroblast cell (MFB) lines. Eventually, active and passive targeting effects of complex were assessed in KB tumor-bearing Balb/C mice through biodistribution studies. Synthesized bare SPIONs had low toxicity effect on healthy cells, but surface modification increased their biocompatibility. Moreover, KB cells viability was reduced when using folate conjugated SPIONs due to FR-mediated endocytosis, while having little effect on healthy cells (MFB). Moreover, this radiotracer had tolerable in vivo characteristics and tumor uptake. In the receptor blocked case, tumor uptake was decreased, indicating FR-specifi c uptake in tumor tissue while enhanced permeability and retention effect was major mechanism for tumor uptake.
    Źródło:
    Nukleonika; 2015, 60, No. 3, part 1; 497-502
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Badanie zawartości miedzi w strumieniach technologicznych procesu wytwarzania poli(tlenku fenylenu)
    Analysis of copper content in the poly(phenylene oxide) production process streams
    Autorzy:
    Kolasa, D.
    Ratajczak, W.
    Talma-Piwowar, M.
    Krakowiak, J.
    Majewska, E.
    Polarczyk, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/947148.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
    Tematy:
    poli(tlenek fenylenu)
    skład strumieni technologicznych
    oznaczanie miedzi
    mineralizacja próbek
    poly(phenylene oxide)
    process streams composition
    determination of copper
    sample digestion
    Opis:
    Przedstawiono wyniki oznaczania zawartości miedzi w strumieniach technologicznych pochodzących z procesu otrzymywania poli(tlenku fenylenu) (PPO) metodą polimeryzacji strąceniowej 2,6-dimetylofenolu z użyciem soli miedzi(II) jako kokatalizatora. Techniką FAAS (płomieniowa absorpcyjna spektrometria atomowa) badano mineralizaty próbek pochodzących z węzła odzysku rozpuszczalników (metanol lub etanol, toluen) i z węzła odzysku składników układu katalitycznego [jony miedzi(II), morfolina]. Zaproponowano procedurę analityczną obejmującą, na etapie przygotowania roztworów do badań, mineralizację próbek za pomocą nowoczesnego systemu do roztwarzania mikrofalowego Ultra WAVE (Milestone). Metoda ta (w połączeniu z techniką FAAS) pozwala na szybkie i sprawne oznaczanie zawartości miedzi w ciekłych próbkach z matrycą organiczną (metanol/etanol – toluen, morfolina) i wodno-organiczną.
    Results of copper determination in process streams coming from the poly(phenylene oxide) (PPO) production by precipitation polymerization of 2,6-dimethylphenol using the copper(II) salt as a co-catalyst have been presented. A microwave-assisted sample preparation analytical procedure for the determination of copper in stream samples from the organic solvents (methanol or ethanol, toluene) and the catalyst components [copper(II) ions, morpholine] recovery nodes using a modern Milestone Ultra WAVE digestion system combined with the FAAS technique has been proposed. The method is useful for quick and efficient determination of copper in liquid samples with organic (methanol/ethanol – toluene, morpholine) mixtures and aqueous-organic matrix.
    Źródło:
    Polimery; 2018, 63, 4; 290-296
    0032-2725
    Pojawia się w:
    Polimery
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Tribological properties of Cu based composite materials strengthened with Al2O3 particles
    Autorzy:
    Kaczmar, J.
    Granat, K.
    Grodzka, E.
    Kurzawa, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/381312.pdf
    Data publikacji:
    2012
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    metal matrix composite
    copper
    aluminium oxide particles
    tribological properties
    wear resistance
    friction coefficient
    Pin-on-disc tester
    kompozyt metalowy
    miedź
    tlenek aluminium
    właściwości tribologiczne
    odporność na ścieranie
    współczynnik tarcia
    Opis:
    In the present work copper was strenghtened with 20 and 30 vol. % of alumina particles characterized by diameter of 3-6μm. The copper based composite materials were manufactured by the squeeze casting method. Preheated preforms made from Al2O3 particles were placed in the desired place in the heated cast die and the squeeze casting process with liquid copper was performed applying the infiltration pressure of 90MPa and pressure was kept for 10-15s until solidification was complete. The microstructure and physical properties: Brinell hardness (HBW) and density were characterized. Metallografic examinations showed that alumina particles were uniformly distributed in the copper matrix. Hardness of 208 HBW for composite materials containing 30 vol.% of particles was achieved. Wear investigations were performed applying the tribological pin-on-disc tester. Friction forces between copper based composite materials containing 20 and 30 vol. % of Al2O3 particles and cast iron were registered and wear was determined on the base of the specimen mass loss after 1.0, 3.5 and 8.5 km friction distance.
    Źródło:
    Archives of Foundry Engineering; 2012, 12, 2s; 33-36
    1897-3310
    2299-2944
    Pojawia się w:
    Archives of Foundry Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Extraction of vanadium and potassium compounds from the spent vanadium catalyst from the metallurgical plant
    Autorzy:
    Mazurek, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/779744.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    kwas siarkowy
    tlenek siarki
    katalizatory wanadu
    ługowanie
    wanad
    potas
    miedź
    cynk
    arsen
    ołów
    XRF
    sulfuric acid
    sulfur oxide
    spend vanadium catalysts
    leaching
    recovery
    vanadium
    potassium
    copper
    zinc
    arsenic
    lead
    Opis:
    A spent vanadium catalyst, from the plant of metallurgical type, was leached in a sulfuric acid solution to recover vanadium and potassium compounds. The effect of time, temperature, concentration of acid, catalyst particle size and phase ratio was studied. Additionally the concentration of iron, copper, zinc, arsenic and lead compounds was determined. The flow sheet for the proposed process of spent vanadium catalyst leaching is presented.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 2; 49-53
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis of inorganic oxide composites with the use of postgalvanic waste solutions of copper(II) sulfate
    Autorzy:
    Modrzejewska-Sikorska, A.
    Ciesielczyk, F.
    Jesionowski, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/779557.pdf
    Data publikacji:
    2010
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    powierzchnia
    tlenek złożonych CuO.SiO2
    rozkład wielkości cząsteczek
    powierzchnia właściwa
    właściwości kalorymetryczne
    opady
    oxide composite CuO.SiO2
    waste solution of copper(II) sulfate
    precipitation
    particle size distribution
    surface area
    colorimetric characteristics
    Opis:
    The study was undertaken to obtain an oxide composite (inorganic colourful pigment) in the method based on the use of postgalvanic waste solution of copper(II) sulfate. The conditions of the process of precipitation of synthetic CuOźSiO 2 were optimised by checking the effect of the concentration and the volume ratio of the reagents and the temperature on the physico-chemical parameters of the final product. The oxide composite obtained in the optimum conditions was characterised by high refinement of particles and large specific surface area BET of 326 m2/g.
    Źródło:
    Polish Journal of Chemical Technology; 2010, 12, 2; 46-51
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Mineralizacja polimetaliczna z kopalni Beiyi w okręgu rud żelaza Shilu na wyspie Hajnan w południowych Chinach
    The polymetallic mineralization from the Beiyi mine, Shilu iron ores district, Hainan Island (Southern China)
    Autorzy:
    Mikulski, S.Z.
    Bakun-Czubarow, N.
    Xu, D.
    Wang, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/2062063.pdf
    Data publikacji:
    2012
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    kruszce
    rudy siarczkowe miedzi i kobaltu
    rudy żelaza
    amalgamat Ag-Hg
    analizy w mikroobszarze
    kopalnia Beiyi
    złoże Shilu
    Wyspa Hajnan
    Chiny
    ore mineralogy
    ores
    copper-cobalt sulfides
    iron oxide
    Ag-Hg amalgamate
    microprobe analyses
    Beiyi mine
    Shilu deposit
    Hainan Island
    China
    Opis:
    W regionie górniczym Shilu posiadającym olbrzymie zasoby rud żelaza typu BIF (Banded Iron Formation), oprócz mineralizacji tlenkami Fe (głównie hematyt), występuje lokalnie w spągu 6 poziomu stratygraficznego grupy Shilu, bogata polimetaliczna mineralizacja siarczkowa Cu–Co. W regionie górniczym Shilu występują słabo zmetamorfizowane skały wulkanoklastyczne i węglanowe zaliczane do mezo- i neoproterozoiku, w które intrudowały różnego wieku granitoidy. Przedmiotem badań mikroskopowych w świetle odbitym i w mikroskopie elektronowym CAMECA SX 100, wyposażonym w przystawkę EDS i WDS, była polimetaliczna mineralizacja kruszcowa z kopalni Beiyi i jej okolic. Mineralizacja kruszcowa, głównie pirotynowo-chalkopirytowa oraz kobaltonośny piryt (do ok. 11% wag. Co), występuje w zmienionych skałach węglanowo-krzemianowych i silnie okwarcowanych skałach diopsydowo-tremolitowych w postaci impregnacji, żyłek i masywnych agregatów ziarnistych. Pirotyn i chalkopiryt zawierają liczne wrostki oraz tworzą przerosty z innymi minerałami (sfaleryt, galena, glaukodot, costibit, kobaltyn, arsenopiryt, ullmannit, siegenit, tytanit, Co-bravoit i kasyteryt). Niewielkie kryształy (10–20 μm średnicy) tworzą minerały Bi (matyldyt i cosalit) i argentyt. W paragenezie z barytem, kalcytem i chlorytem pojawiają się amalgamaty Ag–Hg oraz cynober. Wyniki prac pozwoliły rozpoznać nowe, dotychczas nieopisywane ze złoża minerały. Rezultaty badań wskazują na krystalizację minerałów kruszcowych podczas 4–5 oddzielnych etapów precypitacji kruszców z roztworów hydrotermalnych, w zakresie od temperatur średnich do niskich. Wstępne wyniki oznaczeń wieku izotopowego metodą Re–Os młodszej generacji pirytów (pozbawionych domieszek kobaltu) wskazują na ich precypitację w interwale 240–260 mln lat.
    The famous Shilu iron-polymetallic ore mining district located in western Hainan Island, South China, occurs within Meso- and Neoproterozoic low-grade metamorphosed volcanoclastics and carbonates, that belong to the 6th sequence of the Shilu Group. Granitoid intrusions of different ages occur in the surroundings of the mining area. The Shilu deposit is considered to be a structurally reworked as well as hydrothermally altered and enriched ore deposit of a Banded Iron Formation type. The deposit is a very important iron producer from hematite (and minor magnetite) ores. Our work focused on the polymetallic sulfide mineralization that underlies the iron oxide ores. We selected several samples of sulfide ores from the Shilu deposit of the Beiyi mine and its close vicinity. We performed detailed ore microscopic studies as well as electron microprobe analyses using the CAMECA SX 100 equipped with EDS and WDS systems. Pyrrhotite, chalcopyrite and Co-bearing pyrite (up to 11 wt% Co) dominated among ore sulfides in the studied samples. These ore minerals occur in calc-silicate rocks and strongly silicified diopside, tremolite-bearing rocks, either as disseminated grains, sometimes in veinlets, or in aggregates that may form massive ores. Pyrrhotite and chalcopyrite may contain numerous solid inclusions, overgrowths and intergrowths of subordinate sulfides (sphalerite, galena), sulfosalts (glaucodot, costibite, cobaltite, arsenopyrite, ullmannite), sulfospinels (siegenite) and cassiterite that belong to the minerals crystallizing at medium to low temperatures. Among these minerals, siegenite and Co-bravoite dominate. Tiny crystals (10–20 μm in size) of Bi-minerals (matildite, cosalite) and argentite are also present. Moreover, in association with barite, calcite and chlorite, Ag-Hg amalgamate and cinnabar can occur. The results of our study point to the multistage medium- to low-temperature hydrothermal precipitation of ore sulfides during 4–5 separate stages. Preliminary results of Re-Os isotope datings indicate that pyrites of younger generation (lack of significant Co admixture) crystallized during 240–260 Ma.
    Źródło:
    Biuletyn Państwowego Instytutu Geologicznego; 2012, 452; 181--197
    0867-6143
    Pojawia się w:
    Biuletyn Państwowego Instytutu Geologicznego
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-27 z 27

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