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Tytuł:
Application of Spent Ion Exchange Sorbents for the Reclamation of Degraded Soils
Autorzy:
Chomczyńska, Mariola
Wasag, Henryk
Kujawska, Justyna
Powiązania:
https://bibliotekanauki.pl/articles/124227.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
degraded soils
ion exchange sorbents
cation exchange capacity
Opis:
The paper presents the possibility of applying spent synthetic ion exchangers and sorbents based on natural zeolites for the reclamation of degraded soils. The obtained research results confirmed the improvement of the soil sorption capacity (cation exchange capacity) caused by the addition of spent ion exchange sorbents. They also enabled to determine the magnitude of changes of the analyzed parameters depending on the amount of wastes introduced to the soil. The addition of 1% (w/w) spent cation exchanger enables to increase the cation exchange capacity twice, whereas in the case of zeolite, the observed increase reaches about 20%. Simultaneously, introduction of waste ion exchange sorbents increases the content of exchangeable calcium and magnesium while doubling in the content of these macroelements is observed for 5% (w/w) and 2% (w/w) of spent ion exchanger, respectively. In the case of the exchangeable potassium content, a satisfactory increase is observed with 1% (w/w) addition of spent zeolite.
Źródło:
Journal of Ecological Engineering; 2019, 20, 2; 239-244
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ammonium Adsorption Onto a Contaminated Soil-Water Environment Amended with Organic Matter
Autorzy:
Al-Saedi, Rasha
Hammood, Zaman Ageel
Chyad, Tasnim Fahim
Powiązania:
https://bibliotekanauki.pl/articles/1839546.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
ammonium
adsorption
calcareous soil
compost
cation exchange capacity
Opis:
In this research, the ability of calcareous soil to absorb ammonium was investigated and the effect of compost amendment as a natural organic source on ammonium adsorption was also studied. The pH, dissolved ammonium concentrations, ammonium adsorption capacity, and cation exchangeable capacity for the soil samples were analyzed in relation to an untreated control and treatment with compost under ambient temperature and different initial ammonium concentrations (10, 20, 30, 40, 50, 70, and 100 mg/L). The amounts of ammonium adsorbed increased along with initial concentrations of dissolved ammonium for control and treatment with compost. The models evaluated in this study included the Langmuir and Freundlich isotherms. Ammonium adsorption was found to conform to the Freundlich equation isotherm more than that with Langmuir. The highest adsorption capacity was exhibited by 100 mg/L added initial ammonium concentration. Adding compost as a source of organic matter enhanced the adsorption capacity of calcareous soil with an increase in the adsorption of 36%, which indicated that the organic matter is a key limiting parameter in the mechanism of ammonium adsorption. Ammonium adsorption by calcareous soils is an important process in identifying the ammonium nitrogen route in soil-water systems.
Źródło:
Journal of Ecological Engineering; 2021, 22, 1; 188-194
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mineralogical characteristics of the heterolithic formations from the Carpathian Foredeep Miocene sediments, south-eastern Poland
Autorzy:
Przelaskowska, Anna
Zagórska, Urszula
Urbaniec, Andrzej
Łykowska, Grażyna
Klaja, Jolanta
Grela, Jacek
Kędracka, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/2172901.pdf
Data publikacji:
2022
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
Carpathian Foredeep
heteroliths
lithotypes
mineralogical composition
cation exchange capacity (CEC)
Opis:
Heterolithic complexes from the Carpathian Foredeep are a subject of growing attention as many natural gas accumulations of industrial importance have been discovered in such formations during the last decades. The aim of the presented work was to determine lithotypes of different lithology and mineralogical composition in the heterolithic sequences. Individual lithotypes were distinguished of macroscopic observations of cores, X-ray diffraction analysis (XRD) and X-ray fluorescence method (XRF). Preliminary distinction between the lithotypes was based on macroscopic observations of the core samples. Correlation plots between the contents of particular minerals (XRD analyses) and corresponding elements (XRF analyses) were used for verification of the lithotypes distinguished based on macroscopic observations. Swelling properties of the investigated rocks were determined using the cation exchange capacity (CEC) values. The following lithotypes were identified: medium- to fine-grained sandstones, fine- to very fine-grained sandstones, clayey sandstones, sand-dominated heteroliths, heteroliths with approx. equal proportions of sandstones and mudstones, mud-dominated heteroliths, mudstones, clayey shales. Such division provides a basis for precise petrophysical characterization of the analyzed profiles, that is assignment of particular petrophysical parameters values to individual lithotypes. More reliable petrophysical parameters in the geophysical interpretation of heterolithic sequences allow for a more precise determination of zones characterized by good reservoir parameters.
Źródło:
Geology, Geophysics and Environment; 2022, 48, 3; 219--242
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improving the Quality of Clay Powders by Mechanoactivation
Autorzy:
Bogoslavets, Volodymyr
Voloshyn, Yurii
Hrytsulyak, Halyna
Yurych, Lidiia
Powiązania:
https://bibliotekanauki.pl/articles/2202297.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
clay
bentonite
swelling index
cation exchange capacity
drilling fluid
rheology
Opis:
The ability to effectively use mineral resources is the key to the sustainable development of industry in modern conditions of environmental protection. High-quality bentonites are rarely found in nature, so technologies for improving the quality of clay powders are quite relevant today. The article considers the possibility of improving the quality of clays obtained from candidate quarries for the purpose of further use as components of drilling fluids. The filtration and rheological characteristics of drilling fluids obtained on the basis of activated clay powder were also investigated by Benta Limited Liability Company.
Źródło:
Journal of Ecological Engineering; 2022, 23, 12; 145--154
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Different Doses of N Fertilization on the Parameters of Soil Organic Matter and Soil Sorption Complex
Autorzy:
Šimanský, V.
Kováčik, P.
Jonczak, J.
Powiązania:
https://bibliotekanauki.pl/articles/124019.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
nitrogen
fertilization
Luvisol
soil organic matter
hydrolytic acidity
cation exchange capacity
Opis:
Mineral N fertilizer application may have an effect on soil organic matter and other soil parameters. Therefore, we studied the effects of different doses of N fertilization on soil organic matter and chemical properties of Haplic Luvisol in the locality of Dolná Malanta (Slovakia) during 2014–2016. Soil samples were collected from the plots exposed to the following treatments: 1. N0 – no N fertilization as control during 2014–2016, 2. N40 – N fertilizer at the rate of 40 kg N ha–1 in 2014 and 2016, 3. N80 – N fertilizer at the rate of 80 kg N ha–1 in 2014 and 2016, 4. N160 – N fertilizer at the rate of 160 kg N ha–1 in 2015, and 5. N240 – N fertilizer at the rate of 240 kg N ha–1 in 2015. The results showed that in N80 the soil organic carbon (SOC) content increased by 32% in comparison to N0. The addition of 80 kg ha-1 of N significantly decreased the humic substances (HS) content in the soil by 16% compared to N0. The higher doses of N fertilization 80 rather than 40 kg ha-1 as well as 240 rather than 160 kg ha-1 significantly decreased humus stability. The addition of N fertilization decreased the average values of soil pH. Values of hydrolytic acidity (Ha) increased by 41% and 46% in N40 and N80, respectively than N0, but on the other hand, this one decreased by 36% and 27% in N160 and N240, respectively in comparison to N0. Positive statistically significant correlations were determined between soil pH and SOC in N40 and N80 treatments. The increase of soil pH was connected with higher humus quality in N160 and N240. Negative correlations between humic acids (HA) and sum of basic cations (SBC) and cation exchange capacity (CEC) were observed in N80 < N160 < N240 treatments. Higher values of fulvic acids corresponded with lesser CEC in N80 and N160 treatments. In N160, with increased humus quality, CEC significantly decreased. The same effect was observed in N240. In addition, in N240, we also observed that with increased HA:FA ratio SBC and base saturation significantly decreased.
Źródło:
Journal of Ecological Engineering; 2017, 18, 3; 104-111
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Variability of cation-exchange capacity (cec) of fenpeats in vertical profiles from eastern and central poland in relation to function of peat lands as natural geological barriers
Autorzy:
Rydelek, Paweł
Bąkowska, Anna
Zawrzykraj, Piotr
Powiązania:
https://bibliotekanauki.pl/articles/2025307.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
natural geological barrier
peat
fen
cation-exchange capacity
Nauki o Ziemi
Opis:
An anal y sis of cat ion-ex change ca pac ity (CEC) vari abil ity of peats is pre sented in ver ti cal pro files from east ern and cen tral Po land. CEC val ues were com pared with ash con tent (Ac), pH and CaCO3 con tent. Eight peatlands were selected for re search in the fol low ing ar eas: War saw Pla teau (2 ob jects), Siedlce Pla teau (2 ob jects), Lubartów Pla teau (2 ob jects), Na³êczów Ta ble land (1 ob ject) and Dobrohusk De pres sion (1 ob ject). The peatlands rep re sented a fen peat type of sim i lar bo tanic com po si tions of sed i ments, but they dif fered in the area, peat thick ness and drain age con ditions. Char ac ter is tic reg u lar i ties in CEC vari abil ity were noted in the peatlands and there were three types of CEC vari abil ity in ver ti cal pro files. Car bon ate peats (types 1 and 2) had the high est pH and def i nitely the high est val ues of CEC. In ver ti cal pro files, there was also a zonation, but the reg u lar i ties sim i lar to non-car bon ate peats were not observed. Dif fer ent dis tri bu tion of phys i cal and chem i cal pa ram e ters were es tab lished in ver ti cal pro files in partly drained peatlands (with a muck layer on top) with non-car bon ate peats (type 3) and there were three dis tinct zones in ver tical pro files, with dif fer ent Ac and CEC. De ter mi na tion of the ver ti cal CEC vari abil ity and other phys i cal and chem i calpa ram e ters in peatlands made it pos si ble to dis tin guish zones with po ten tially most ben e fi cial iso la tion con di tions.
Źródło:
Studia Quaternaria; 2016, 33; 111-116
1641-5558
2300-0384
Pojawia się w:
Studia Quaternaria
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zeolitic adsorbent synthesized from powdered waste porcelain, and its capacity for heavy metal removal
Autorzy:
Wajima, T.
Ikegami, Y.
Powiązania:
https://bibliotekanauki.pl/articles/346935.pdf
Data publikacji:
2006
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
zeolite synthesis
waste porcelain
heavy metal removal
cation exchange capacity
neutralization
Opis:
A zeolitic adsorbent was synthesized from powdered waste porcelain kept at 80 °C for 24 h. The product contained the zeolite phases Na-P1 and hydroxysodalite. The product with the highest cation exchange capacity (CEC) was synthesized using 4 M NaOH and the sample weight / volume of alkali solution ratio was 1/4. The highest CEC obtained for the product was almost 1900 mmol/kg, which is the same as that of natural zeolite. The product with the highest CEC was tested for its ability to remove heavy metals (Fe, Cu, Ni, Zn, Pb, Cd, Mn, Cr, Al, B, Mo) from an acidic solution (pH 2). The product can neutralize the acidic solution to almost pH 7, and the capacity of the product for the removal of heavy metals is higher than that of the natural zeolite, except for Mo and B.
Źródło:
Ars Separatoria Acta; 2006, 4; 86-95
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Quantitative analysis of physical and chemical attribute of soil around power-line dumpsite at Boji-Boji Owa, Delta State, Nigeria
Autorzy:
Ulakpa, Ruth Oghenerukevwe Eyankware
Ulakpa, Wisdom Chukwuemeke
Eyankware, Moses Oghenenyoreme
Powiązania:
https://bibliotekanauki.pl/articles/1031480.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Boji-Boji Owa
Cation exchange capacity
Delta State
Exchangeable cation
Nigeria
Solid waste
dumpsite
Opis:
The study ascertains some physiochemical properties of soils around Power-line dumpsite at Boji-Boji Owa, Delta State, Nigeria. In order to evaluate the effects of municipal solid waste dumpsites on soils, soil samples were collected with the aid of a graduated soil auger at depths of 0 – 10 cm, 15 – 25 cm and 25 – 40 cm, representing top to sub and bottom soil sand also 500 m away from dumpsites which serves as control site (R). Samples were taken for laboratory analyses to determine the level of physiochemical properties such as: pH, grain size distribution, Electrical Conductivity (Ec), Organic Carbon (OC), Organic Matter (OM), Available Phosphorous (Av. P), Overall Nitrogen (ON), Basic Cations and Cation Exchange Capacity (CEC) in soils. Results obtained from the study, revealed that values between waste dumpsite and control site were significantly different. Findings showed that the pH value in sampled soils from studied dumpsites ranged from 6.22±0.06 and 7.97±0.04 while the mean pH value for controlled site was 39.8±0.08. The increase in the pH value of the sampled soil indicated an increase in CEC mean value of soil which ranged from 4.73±0.30 and 10.28±0.46 mEq/100 g while a low pH indicated low CEC mean value of 1.50±0.22 mEq/100 g. This is because there exists a positively significant relationship between pH, OC, OM, Av.P, ON, basic cations and CEC. As Ec varied between 692±4.50 to 918±4.03 μScm-1, OC varied between 0.05±0.00 to 0.64±0.03%, OM varied between 0.10±0.06 to 0.57±0.07%, Av.P varied between 8.98±0.06 to 25.36±0.22 mg/kg and ON varied between 0.44±0.01 to 0.93±0.03% across all studied dumpsites.
Źródło:
World News of Natural Sciences; 2021, 35; 118-134
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sezonowość zmian składu kompleksu wymiennego kationów i jego wpływ na wyniki modelowania odwrotnego
Seasonality changes in the composition of the exchangeable cations of the complex and its impact on the results of the inverse modelling
Autorzy:
Jóźwiak, K.
Solovey, T.
Powiązania:
https://bibliotekanauki.pl/articles/2062052.pdf
Data publikacji:
2013
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
modelowanie geochemiczne
wymiana jonowa
pojemność wymiany jonowej
geochemical modelling
ion exchange
cation exchange capacity
Opis:
Wymiana jonowa jest zaliczana do podstawowych procesów kształtujących skład chemiczny wód podziemnych. W praktyce ilościowym jej wymiarem jest pojemność wymiany kationów (PWK), która może służyć jako podstawa do obliczania liczby miejsc jonowymiennych przy modelowaniu odwrotnym. W pracy zaprezentowano wyniki oznaczeń kompleksu wymiennego kationów na obszarze pojedynczej wydmy w Kampinoskim Parku Narodowym. Wyniki oznaczeń posłużyły jako podstawa do wykonania modeli odwrotnych w obrębie strefy aeracji i wpływu na te modele oznaczonych statystycznie i empirycznie wartości PWK.
Ion exchange is considered to be a fundamental process that form the chemical composition of groundwater. In practice, its quantitative aspect is the cation exchange capacity (PWK), which can be used as a basis for calculating the amount of ion exchange sites for reverse modeling. The results of the cation exchange complex determination in a single dune located in the Kampinos National Park were presented in this paper. These results were used as a basis for the implementation of the inverse models within the vadose zone as well as assessment of the impact of statistically and empirically evaluated values of the cation exchange capacity on these models.
Źródło:
Biuletyn Państwowego Instytutu Geologicznego; 2013, 456 Hydrogeologia z. 14/1; 243--248
0867-6143
Pojawia się w:
Biuletyn Państwowego Instytutu Geologicznego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of the sorption properties of different soils using water vapour adsorption and potentiometric titration methods
Autorzy:
Skic, K.
Boguta, P.
Sokolowska, Z.
Powiązania:
https://bibliotekanauki.pl/articles/25797.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
sorption property
soil
water vapour adsorption
potentiometric titration
cation exchange capacity
surface area
physicochemical characteristics
Źródło:
International Agrophysics; 2016, 30, 3
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Morphological analysis of organo-montmorillonites via MD simulations
Autorzy:
Karataş, Deniz
Tekin, Adem
Can, Muhammed F.
Xu, Zhenghe
Çelik, Mehmet S.
Powiązania:
https://bibliotekanauki.pl/articles/2146936.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
organo-montmorillonite
tetradecyl dimethyl ethyl benzyl ammonium chloride
molecular dynamics simulation
cation exchange capacity
binding energy
Opis:
Adsorption on clay surfaces has been studied intensively in recent years. The most curious subject of these studies, which are generally experimental, is how the surfactants are adsorbed at the atomic level to the surface. In this study, the adsorption of quaternary amine salt (tetradecyl dimethyl ethyl benzyl ammonium chloride–TDEBAC) to sodium montmorillonite (Na-MMT) with various cation exchange capacities (CEC) was investigated by using Molecular Dynamics (MD) simulation. In the simulations, as in the experimental studies, it was revealed that the surfactants were both adsorbed on to basal surfaces and settled between the layers. From the morphological analysis obtained from MD simulations, it was calculated that the inter-molecular interaction between the layers was higher than on the basal surface. For example, for the model with 118 CEC motif, the binding energy of all three surfactants in the models with the hydrophilic heads facing the same direction was calculated as -678.18 kcal/mol at the basal surface, while this value was found to be -688.90 kcal/mol in the interlayer. The more striking result is that in the simulations made by turning the head of the middle one of the three surfactants towards the tails of the right and left ones, only -34.86 kcal/mol binding energy was calculated on the basal surface, while this value was -525.63 kcal/mol in the interlayer. As compared middle reversed surfactant models with the same direction ones, despite increased CEC the intermolecular interaction decreased for the basal surface, but the interaction increased between the layers.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 152499
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prediction of CEC using fractal parameters by artificial neural networks
Autorzy:
Bayat, H.
Davatgar, N.
Jalali, M.
Powiązania:
https://bibliotekanauki.pl/articles/25675.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
cation exchange capacity
prediction
fractal structure
fractal theory
particle size distribution
artificial neural network
pedotransfer function
Opis:
The prediction of cation exchange capacity from readily available soil properties remains a challenge. In this study, firstly, we extended the entire particle size distribution curve from limited soil texture data and, at the second step, calculated the fractal parameters from the particle size distribution curve. Three pedotransfer functions were developed based on soil properties, parameters of particle size distribution curve model and fractal parameters of particle size distribution curve fractal model using the artificial neural networks technique. 1 662 soil samples were collected and separated into eight groups. Particle size distribution curve model parameters were estimated from limited soil texture data by the Skaggs method and fractal parameters were calculated by Bird model. Using particle size distribution curve model parameters and fractal parameters in the pedotransfer functions resulted in improvements of cation exchange capacity predictions. The pedotransfer functions that used fractal parameters as predictors performed better than the those which used particle size distribution curve model parameters. This can be related to the non-linear relationship between cation exchange capacity and fractal parameters. Partitioning the soil samples significantly increased the accuracy and reliability of the pedotransfer functions. Substantial improvement was achieved by utilising fractal parameters in the clusters.
Źródło:
International Agrophysics; 2014, 28, 2
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pojemność wymiany kationów osadów plejstocenu i wpływ wymiany jonowej na skład chemiczny wód podziemnych w dolinie kopalnej w rejonie Raciborza
Cation exchange capacity and the influence of ion exchange on chemical composition of groundwater in the buried valley in the Racibórz area
Autorzy:
Potoczny, K.
Miotliński, K.
Kowalczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/2062840.pdf
Data publikacji:
2009
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
wymiana jonowa
pojemność wymiany kationów
eksperyment statyczny
eksperyment dynamiczny
Racibórz
ion exchange
cation exchange capacity
batch experiment
column experiment
Opis:
Wymiana jonowa jest jednym z głównych procesów geochemicznych kształtujących skład chemiczny użytkowych wód podziemnych. Pojemność wymiany kationów (PWK) jest ważnym parametrem wymaganym przez programy do modelowania transportu reaktywnego, chociaż rzadko oznaczanym w badaniach hydrogeochemicznych. Jednak wzrost znaczenia modeli transportu reaktywnego wymaga zastosowania bardziej dokładnych wielkości PKW, co wiąże się z zastosowaniem optymalnych i precyzyjnych metod oznaczeń tego parametru. Niniejszy artykuł prezentuje wartości PWK próbek osadów pobranych z doliny kopalnej w rejonie Raciborza. W zbiorniku tym występowanie wielu kationów jest kontrolowane przez proces wymiany jonowej. Pomiary PWK były wykonywane przy użyciu trzech metod (wzór empiryczny, metoda statyczna, eksperyment kolumnowy). Następnie przedyskutowano różnice pomiędzy uzyskanymi wynikami.
Ion exchange is one of the major geochemical processes affecting chemical composition of potable groundwater. Cation exchange capacity (CEC) is a major parameter required by reactive transport models. Nevertheless, the said parameter is rarely quantitatively evaluated in hydrogeochemical studies. Since the role of reactive transport models increases, the choice of the most accurate method of CEC evaluation is of major significance in groundwater studies. The paper presents the values of CEC of sediments sampled in the buried valley aquifer in the Racibórz area. In that aquifer, the distribution of many cations is controlled by ion exchange process. The measurements of CEC were performed with the use of three conventional methods (empirical formula, batch test and column experiment). Subsequently, the differences among the results are discussed.
Źródło:
Biuletyn Państwowego Instytutu Geologicznego; 2009, 436, z. 9/2; 387-395
0867-6143
Pojawia się w:
Biuletyn Państwowego Instytutu Geologicznego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on the activation of calcium montmorillonite (Ca-MMT) by sodium cations
Badania nad procesem aktywacji montmorylonitu wapniowego Ca-MMT kationami sodu
Autorzy:
Kurleto-Kozioł, Ż.
Grabowska, B.
Powiązania:
https://bibliotekanauki.pl/articles/263798.pdf
Data publikacji:
2016
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
montmorillonite
activation of montmorillonite
cation exchange capacity
UV-Vis
IR
montmorylonit
aktywacja montmorylonitu
zdolność do wymiany jonowej
Opis:
The results of spectral research (IR, UV-Vis) on the activation process of calcium montmorillonite Ca-MMT by sodium cations are presented in this article. The modifications of Ca-MMT were carried out by a modifier in the form of sodium carbonate by keeping different times of activations. On the basis of received sodium modifiers MMT (Na-MMT) analytical cycle of research was done, including structural (IR) and spectrophotometric (UV-Vis) research, in order for the designation of ion exchange ability (CEC). There was observed that the method of processing modification (changing activation time) does not affect on ion exchange ability Na-MMT. Application of modified MMT used as a binding material in greensand will be described in the next part of our planned research.
W artykule przedstawiono wyniki badań spektralnych (IR, UV-Vis) procesu aktywacji montmorylonitu wapniowego Ca-MMT kationami sodu. Modyfikację Ca-MMT prowadzono z udziałem modyfikatora w postaci węglanu sodu przy zachowaniu różnych czasów aktywacji. Dla otrzymanych modyfikatów sodowych MMT (Na-MMT) przeprowadzono cykl badań analitycznych, w tym strukturalnych (IR) oraz spektrofotometrycznych (UV-Vis), w celu oznaczenia ich zdolności wymiany jonowej (CEC). Stwierdzono, że sposób prowadzenia modyfikacji (zmiana czasu aktywacji) nie wpływa istotnie na zdolność do wymiany jonowej Na-MMT. Zastosowanie zmodyfikowanego MMT jako materiału wiążącego w masach klasycznych zostanie określone w następnej części zaplanowanych prac badawczych.
Źródło:
Metallurgy and Foundry Engineering; 2016, 42, 3; 171-178
1230-2325
2300-8377
Pojawia się w:
Metallurgy and Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Long-term effects of tillage and fertilization on pH and sorption parameters of haplic Luvisol
Autorzy:
Simansky, V.
Kovacik, P.
Powiązania:
https://bibliotekanauki.pl/articles/13803.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Warmińsko-Mazurski w Olsztynie / Polskie Towarzystwo Magnezologiczne im. Prof. Juliana Aleksandrowicza
Tematy:
soil management system
long-term effect
tillage
fertilization
pH
sorption parameter
haplic Luvisol
hydrolytic acidity
cation exchange capacity
Opis:
The influence of different tillage and fertilization practices on changes in soil pH and sorptive parameters of loamy haplic Luvisol was evaluated in a long-term field experiment (established in 1994, in the locality of Dolná Malanta, at the experimental station of the Slovak University of Agriculture in Nitra). The field experiment included two types of soil tillage (conventional tillage – CT and reduced tillage – RT) and also three treatments of fertilization (1. Co – control, 2. PR+NPK – crop residues together with added NPK fertilizers, and 3. NPK – with added NPK fertilizers). The soil was sampled from all treatment sites throughout 1994-2011. The results showed a statistically significant influence of tillage and fertilization on pH and sorptive complex of haplic Luvisol. The values of pH were higher (by 4%) in RT than in CT. The sum of basic cations (SBC), cation exchangeable capacity (CEC) and base saturation (BS) were all higher in RT, by 11%, 8% and 3% respectively, than in CT. In NPK (by 16%) and in PR+NPK (by 20%) the values of hydrolytic acidity (Ha) were decreased in comparison to the control. On the other hand, SBC was elevated. This led to the increase of CEC and BS. Conventional tillage and application of crop residues together with NPK fertilizers increased pH by 0.06 and 0.03 units per year, respectively, which means that the pH in the soil increased by14% and 8%, correspondingly, between 1994 and 2011. In CT and in PR+NPK, an increase of SBC occurred at an average rate of 3.17 and 1.93 mmol kg-1 year-1, respectively. A positive correlation between the content of soil organic carbon (TOC) and Ha (r = 0.334, P ≤ 0.01, n = 54), as well as a negative correlation between TOC and BS (r = -0.307, P ≤ 0.05, n = 54) were determined only in CT.
Źródło:
Journal of Elementology; 2015, 20, 4
1644-2296
Pojawia się w:
Journal of Elementology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 21

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