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Tytuł:
Adsorption behavior of pharmaceutically active dexketoprofen as sustainable corrosion Inhibitor for API X80 carbon steel in acidic medium
Autorzy:
Nkem, B. Iroha
Abosede, O. James
Powiązania:
https://bibliotekanauki.pl/articles/1076601.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Adsorption
Carbon steel
Dexketoprofen
Inhibition
SEM
Opis:
The inhibition of X80 carbon steel corrosion in 1 M HCl solution by dexketoprofen (DKP) was studied using weight loss (WL), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP) and scanning electron microscopy (SEM) techniques. The results indicated that DKP acts by way of adsorption as an effective protective inhibitor in the aggressive acid medium. The inhibition efficiency of DKP increased with concentration but was lower at higher temperature. The results of potentiodynamic polarization showed that DKP molecule behaved as a mixed type inhibitor by reducing both the anodic and the cathodic electrochemical reactions. Dexketoprofen was adsorbed on the X80 steel surface in accordance with Langmuir adsorption isotherm. SEM analyses supported formation of protective film on the X80 steel in the presence of DKP.
Źródło:
World News of Natural Sciences; 2019, 27; 22-37
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence structure on the plasticity of carbon steel of the railway wheel rim in operation
Autorzy:
Vakulenko, Igor Alex
Vakulenko, Leonid
Bolotova, Dariy
Kurt, Bulent
Asgarov, Hangardash
Çölova, Ömer
Powiązania:
https://bibliotekanauki.pl/articles/2176495.pdf
Data publikacji:
2022
Wydawca:
Politechnika Śląska. Wydawnictwo Politechniki Śląskiej
Tematy:
carbon steel
strain
stal węglowa
naprężenie
Opis:
When simulating the operating conditions of the rim of a railway wheel, an analysis of change in the structural state from the possible degree of plastic deformation and the heating temperature of steel near the rolling surface was carried out. The development processes of spheroidization and coalescence of cementite during heating of the cold-worked steel change its ability to strain hardening. Substructure changes during heating to temperatures of 500-550°C deformed steel are accompanied by a simultaneous decrease in its ability to strain hardening and the level of plasticity. When heated above 500-550°C, the development of ferrite recrystallization processes provides a gradual transition of the metal from substructure hardening to hardening from grain boundaries with large angles of disorientation. It is shown that regardless of the nature of the main structural element, the ability of steel to strain hardening and the level of plasticity after heating are related by a proportional relationship.
Źródło:
Zeszyty Naukowe. Transport / Politechnika Śląska; 2022, 115; 183--192
0209-3324
2450-1549
Pojawia się w:
Zeszyty Naukowe. Transport / Politechnika Śląska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Influence of Deformation and Austenitization Temperature on the Kinetics of Phase Transformations During Cooling of High-Carbon Steel
Autorzy:
Kawulok, P.
Podolinský, P.
Kajzar, P.
Schindler, I.
Kawulok, R.
Ševčák, V.
Opěla, P.
Powiązania:
https://bibliotekanauki.pl/articles/350975.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high-carbon steel
cooling
transformation diagrams
microstructure
hardness
Opis:
The aim of the performed experiments was to determine the influence of deformation and of austenitization temperature on the kinetics of phase transformations during cooling of high-carbon steel (0.728 wt. % C). The CCT and DCCT diagrams for austenitization temperature 940°C and DCCT diagram for austenitization temperature 1000°C were constructed with the use of dilatometric tests. On the basis of obtained results, a featureless effect of austenitization temperature and deformation on the kinetics of phase transformations during cooling of investigated steel was observed. Critical cooling rates for the transformation of martensite in microstructure fluctuated from 5 to 7°C · s-1 (depending on the parameters of austenitization and deformation), but only at cooling rates higher than 8°C · s-1 a dominant share of martensite was observed in the investigated steel, which resulted in the significant increase of hardness.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 4; 1743-1748
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High Temperature Corrosion Performance of Carbon Steel Coated with Iron Aluminide in Mixture of O2 and SO2 Atmosphere
Autorzy:
Omranian-Mohammadi, P.
Raiszadeh, R.
Shahverdi, H. R.
Powiązania:
https://bibliotekanauki.pl/articles/352419.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
iron aluminide
high temperature corrosion
plain carbon steel
Opis:
In this investigation the surface of an aluminized sample of plain carbon steel was melted and alloyed using a tingsten inert gas (TIG) welding process to produce iron-aluminide intermetallic phases on the surface. The produced coating was then characterized by SEM and EDS and its high-temperature properties in O2 + 1%SO2 gas were examined. The results showed that the Fe3 Al coating produced could protect the substrate as it was subjected to the corroding gases at 700°C due to the formation of an alumina layer between the substrate and an outer layer of Fe2 O3 . At 900°C, the coating could only protect the substrate for 64 h. The lack of further protection at this temperature is attributed to the decrease in the protective properties of alumina with an increase in its temperature and the lack of presence of enough Al atoms in the coating for the repair of the defects formed in the alumina layer.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 529-538
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of die approach and bearing part of die on mechanical-technological properties of high carbon steel wires
Wpływ części roboczej i kalibrującej ciągadła na własności mechaniczno-technologiczne drutów ze stali wysokowęglowej
Autorzy:
Adamczyk, J.
Suliga, M.
Pilarczyk, J.W.
Burdek, M.
Powiązania:
https://bibliotekanauki.pl/articles/356185.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high carbon steel wires
mechanical properties
die geometry
Opis:
In this work the influence of the die approach and bearing part of die on mechanical-technological properties of high carbon steel wires has been assessed. The drawing process of φ5.5 mm wires to the final wire of φ2.9 mm was conducted in 6 passes, by means of a multi-die drawing machine Koch type. The drawing speeds in the last passes were: 7 m/s. For wires drawn according to four variants the investigation of mechanical-technological properties has been carried out, in which yield strength, tensile strength, uniform and total elongation, reduction of area, the number of twists and the number of bends were determined. On the basis of numerical analyses wire drawing process, the influence of geometry of die on redundant strain and effective strain has been determined. The investigations have shown the essential influence of geometry of die on mechanical-technological properties of high carbon steel wires. It has been shown that the increase of strength properties in wires drawn with high die angle is related to the occurrence in their bigger effective strain.
W pracy określono wpływ części roboczej i kalibrującej ciągadła na własności mechaniczno-technologiczne drutów ze stali wysokowęglowej. Proces ciągnienia drutów o średnicy 5,5 mm na średnice końcowa 2,9 mm zrealizowano w 6 ciągach na ciągarce wielostopniowej typu Koch. Prędkość ciągnienia na ostatnim ciągu wynosiła 7 m/s. Dla drutów ciągnionych według czterech wariantów ciągnienia, przeprowadzono badania własności mechaniczno-technologicznych, w których określono umowna granice plastyczności, wytrzymałość na rozciąganie, wydłużenie równomierne i całkowite, przewężenie, liczba skręceń i liczbę zgięć. Natomiast w oparciu o analizę teoretyczna procesu ciągnienia określono wpływ geometrii ciągadła na odkształcenia postaciowe i intensywność odkształcenia. Przeprowadzone badania wykazały istotny wpływ geometrii ciągadła na własności mechaniczno-technologiczne oraz nierównomierność odkształcenia drutów ze stali wysokowęglowych. Stwierdzono, ze wzrost własności wytrzymałościowych w drutach ciągnionych z dużymi wartościami kata ciągnienia związany jest z ich większa intensywnością odkształcenia.
Źródło:
Archives of Metallurgy and Materials; 2012, 57, 4; 1105-1110
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Process Parameters on Ceroxide Formation in Low-Carbon Steels
Autorzy:
Vaucheret, A.
Nicolini, C.
Carton, J.-F.
Jacquet, P.
Powiązania:
https://bibliotekanauki.pl/articles/106937.pdf
Data publikacji:
2017
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
ceroxide
low carbon steel
mold/metal reaction
deoxidation
Opis:
Ceroxides are surface defects caused by a mold-metal reaction during the casting process of steels. This type of defect may affect a large area, but it is located only on the skin of the parts. It does not affect the core of the parts nor its mechanical properties. Nevertheless, ceroxides induce a lack of material on the surface, forming a kind of crater and needing complementary surfacing. The defect is also composed by several non-metallic inclusions containing Al, Mg, Si and O. An EDX analysis by mapping show these elements involved in the mold-metal reaction. The presence of these oxides could confirm the hypothesis of the deoxidizer reoxidation found in the bibliography. To better understand the specific conditions of ceroxide formation, the first step was to find of way to generate systematically this defect at each casting. Two patterns with different filling rate were designed, simulated on Quikcast and tested. The pattern with turbulent filling rate allowed the formation of ceroxide at each casting and so was used during this study. This result shows that the filling rate of the mold could be considered as a first order parameter in ceroxide formation. Then, a specific experimental set up was designed to characterize this defect. The analysis of the defect was done for sizing it: surface and depth. Finally, some key parameters on defect formation were determined like the nature of deoxidizer or the amount of oxygen in the mould. Some laboratory tests were lead to show the influence of these parameters by characterization of the casted parts in comparison with a reference sample. This study allowed us to find process parameters responsive of ceroxide formation and to propose some way of improvement to reduce the size and the occurrence of ceroxides.
Źródło:
Journal of Casting & Materials Engineering; 2017, 1, 4; 90-96
2543-9901
Pojawia się w:
Journal of Casting & Materials Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on Inhibition of N80 Carbon Steel in 0.5M KCl Solution Saturated with CO2 by Gum Arabic
Autorzy:
Palumbo, G.
Banaś, J.
Powiązania:
https://bibliotekanauki.pl/articles/106989.pdf
Data publikacji:
2018
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
corrosion inhibition
gum arabic
carbon steel
electrochemical techniques
Opis:
The effect of Gum Arabic (GA) on the corrosion of an N80 carbon steel pipeline in a CO2 -saturated chloride (0.5M KCl) solution was investigated through AC impedance and polarization curves. Potentiodynamic measurements showed that the corrosion current density decreased in the presence of inhibitors and that the inhibitor acts like a mixed-type inhibitor, with anodic predominance. The Nyquist diagrams showed an increase in polarization resistance values in the presence of the inhibitor, thus increasing inhibition efficiency. At higher temperatures, the inhibition efficiency decreased, implying that the inhibition action of GA occurred via the physical adsorption process. The activation parameters of the corrosion process such as activation energies, Ea, and the heat of adsorption, Qads, were calculated, respectively, by the obtained corrosion rate and inhibition efficiency at different temperatures. At higher temperatures, the increase in activation energy combined with the negative levels of the heat of adsorption further supported the physical adsorption nature of the process.
Źródło:
Journal of Casting & Materials Engineering; 2018, 2, 1; 5-8
2543-9901
Pojawia się w:
Journal of Casting & Materials Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact assessment of effectiveness of thiourea and THAM for corrosion process on carbon steel in calcium chloride environment
Autorzy:
Malinowski, S.
Jaroszyńska-Wolińska, J.
Powiązania:
https://bibliotekanauki.pl/articles/390655.pdf
Data publikacji:
2016
Wydawca:
Politechnika Lubelska. Wydawnictwo Politechniki Lubelskiej
Tematy:
corrosion inhibitor
thiourea
THAM
carbon steel
anticorrosive properties
Opis:
The main objective of this paper is to present a comparison of the corrosion inhibiting effect of thiourea and THAM (tri(hydroxymethyl)aminomethane) on carbon steel samples immersed in calcium chloride solutions. The testing has shown that to inhibit the corrosive action of the calcium chloride solution, the thiourea solution can be successfully replaced by the THAM solution. The study was performed with the use of st3s, structural and reinforcing steel. In the case of st3s steel samples, the application of the 0.01% THAM solution causes a decrease of its weight loss by about 60%. The application of a 10-times stronger THAM solution causes an increase of the corrosion inhibition on the tested samples by about 20%. A combined protective action of the thiourea and THAM solutions brings about an increase of the corrosion process inhibition by about 70% both for the st3s and the structural samples. The 0.01% and 0.1% THAM solutions applied to inhibit the corrosion process on structural samples cause an increase of the corrosion protection by about 50% and 15% respectively.
Źródło:
Budownictwo i Architektura; 2016, 15, 2; 65-72
1899-0665
Pojawia się w:
Budownictwo i Architektura
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Production of Chromium Boride Layers on Carbon Steel with Conversion Treatment: Chromium Deposition + Diffusion Annealing
Autorzy:
Boubaaya, R.
Benarioua, Y.
Allaoui, O.
Djendel, M.
Powiązania:
https://bibliotekanauki.pl/articles/1031720.pdf
Data publikacji:
2017-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
carbon steel
boriding
chromium plating
diffusion annealing
chromium boride
Opis:
The present study has been conducted in order to obtaining chromium boride layers on carbon steel using a conversion processing comprising the following steps: boriding treatment in order to increase the amount of boron atoms in the steel surface, deposition of a thin layer of pure chromium using electrolytic method, and finally an annealing treatment for boron diffusion and formation of boride layer until complete transformation of chromium layer. Depending on the method used (chromium deposition followed by boriding or boriding followed by chromium deposition) and the holding time, the partial or complete conversion is obtained as a result of the diffusion process. The role of the annealing temperature on transformation rates of chromium into chromium boride films was investigated. It is shown that for 1 h at 900°C, the chromium layer is totally transformed. The scanning electron microscopy analysis and X-ray diffraction showed the presence of CrB and CrB₂ chromium borides in addition of FeB and Fe₂B iron borides.
Źródło:
Acta Physica Polonica A; 2017, 132, 3; 541-543
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Adhesive Compound Viscosity on the Strength Properties of 1.0503 Steel Sheets Adhesive Joints
Autorzy:
Miturska-Barańska, Izabela
Rudawska, Anna
Powiązania:
https://bibliotekanauki.pl/articles/2180221.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
adhesive joints
carbon steel
shear strength
epoxy adhesives
viscosity
Opis:
The presented study concerned the comparison of the adhesive joints strengths of 1.0503 carbon steel sheets of higher quality, which were made using adhesive compounds characterized by different viscosity index of the components. Three types of commercial epoxy resins were used: Epidian 5, Epidian 53 and Epidian 57, as well as two types of curing agents: polyamide (PAC) and amine (Z-1). The surfaces of the test specimens were subjected to a pre-treatment operation in the process of a mechanical machining with an abrasive coated tool of P320 gradation. The surface roughness measurements were carried out as a control. The single-lap adhesive joints were the subject of the strength testing. The strength tests carried out on a Zwick/Roell Z150 testing machine concerned the comparison of the strength of the adhesive joints loaded in shear. Statistical analysis was performed on the results obtained. It was observed, among others, that the adhesive joints prepared with the epoxy adhesive compounds containing the polyamide curing agent showed much higher the shear strength than the adhesive joints made with the epoxy adhesive compounds containing the amine curing agent. Moreover, the use of the polyamide curing agent in the adhesive compounds with the epoxy resins resulted in formation of a more elastic adhesive layer, for which higher elongation was observed than in the case of the epoxy compound with the amine curing agent.
Źródło:
Advances in Science and Technology. Research Journal; 2022, 16, 2; 196-205
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Acoustic emission analysis of the plastic deformation stages of degraded low-carbon steel after long-term operation in the oil refining and petrochemical processing
Autorzy:
Lyasota, I.
Sarniak, Ł.
Kustra, P.
Powiązania:
https://bibliotekanauki.pl/articles/351029.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
monitoring
low carbon steel
plastic deformation
acoustic emission
refinery industry
Opis:
This paper presents results obtained from a laboratory investigation conducted on material from a pressure vessel after longterm operation in the oil refinery industry. The tested material contained structural defects which arose from improper heat treatment during steel plate manufacturing. Complex tensile tests with acoustic emission signal recording were conducted on both notched and unnotched specimens. The detailed analysis of different acoustic emission criteria allowed as to detect each stage of plastic deformation and microstructural damage processes after a long-term operation, and unused carbon steels during quasi-static axial tension testing. The acoustic emission activity, generated in the typical stages of material deformation, was correlated by microscopy observations during the tensile test. The results are to be used as the basis for new algorithms for the assessment of the structural condition of in-service pressure equipment.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 1; 143-151
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Shot Peening With Glass Microspheres on the Fatigue Behavior of a Low Carbon Steel
Autorzy:
de Lacerda, J. C.
Pereira, I. R.
Costa, J. M. G.
Pinto, J. S.
Souza, H. F. M.
Fonseca, M. A.
Powiązania:
https://bibliotekanauki.pl/articles/352156.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
fatigue
shot peening
Wöhler curve
low carbon steel
glass microspheres
Opis:
The present work has the objective of studying the effect of shot peening with glass microspheres on SAE 1020 steel in its resistance to fatigue. Fatigue tests were carried out by rotary bending with load control and loading on balance in specimens with and without shot peening. A rotation speed of approximately 750 rpm (12.5 Hz) was employed in the fatigue tests. Vickers microhardness tests were performed in order to verify the surface hardening produced by shot peening with glass microspheres. Analysis of the steel surface and fatigue fractures was performed using scanning electron microscopy (SEM). Fatigue tests were performed in order to obtain S-N curves (Wöhler curves). It was observed that shot peening with glass microspheres improved the fatigue strength of the steel at high cycle.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 4; 1513-1518
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enhancement in bath mixing and plume area in a new degassing process - a computational fluid dynamic study
Zwiększenie mieszania kąpieli i obszaru mieszania w nowym procesie odgazowania - badania obliczeniowej dynamiki płynów
Autorzy:
Mondal, M. K.
Maruoka, N.
Kitamura, S.
Gupta, G. S.
Powiązania:
https://bibliotekanauki.pl/articles/353329.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
REDA
stal niskowęglowa
CFD
odwęglanie
decarburization
ultra low carbon steel
Opis:
Reaction between the various species in slag and metal phase is usually mass transfer controlled. There have been continuous efforts to increase the reaction efficiency in slag-metal system, especially during decarburization of steel to produce the ultra low carbon steel (ULCS) in secondary steelmaking. It has been found that the surface reaction is a dominant factor in the final stage of decarburization. In the initial stage, the inner site reaction is major factor in the refining process. The mixing of bath affects the later reaction. However, the former reaction (surface reaction) is affected by the plume size area at the top of the metal surface. Therefore, a computational study has been made to understand the fluid dynamics of a new secondary steelmaking process called Revolutionary Degasser Activator (REDA) to study the bath mixing and plume area. REDA process has been considered as it is claimed that this process can reduce the carbon content in steel below 10ppm in a less time than the other existing processes such as RH and Tank degasser. This study shows that both bath mixing and plume area are increased in REDA process facilitating it to give the desired carbon content in less time. Qualitative comments are made on slag-metal reaction system based on this finding.
Reakcja pomiędzy różnymi składnikami w fazie żużlowej i metalowej jest zwykle kontrolowana przez transport masy. Ciągle dążono do zwiększenia wydajności reakcji w układzie metal-żużel, zwłaszcza podczas procesu odwęglania, przy produkcji stali o ultra niskiej zawartości węgla (ULCS) podczas obróbki pozapieciowej. Stwierdzono, że reakcja na powierzchni jest czynnikiem dominującym w końcowej fazie odwęglenia. W początkowym etapie, reakcja wewnątrz jest głównym czynnikiem w procesie rafinacji. Mieszanie kąpieli wpływa na późniejszą reakcję. Jednakże na poprzednią reakcję (reakcja na powierzchni) ma wpływ wielkość obszaru mieszania na powierzchni metalu. W związku z tym dokonano obliczeń, w celu zrozumienia dynamiki płynów nowego procesu metalurgii pozapiecowej, nazwanego Rewolucyjny Aktywator Odgazowania (REDA), do badania mieszania kąpieli i obszaru mieszania. Twierdzi się że proces REDA może zmniejszyć zawartość węgla w stali poniżej 10 ppm w krótszym czasie, niż inne istniejące procesy takie jak RH i odgazowanie w kadzi. Z niniejszych badań wynika, że zarówno mieszanie kąpieli i obszar mieszania zwiększa się w procesie REDA, ułatwiając uzyskanie żądanej zawartość węgla w krótszym czasie. Poczynione są jakościowe uwagi na temat reakcji w układzie żużel-metal, oparte na tych wynikach.
Źródło:
Archives of Metallurgy and Materials; 2010, 55, 4; 1131-1135
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Corrosion Inhibition of API 5L X52 Carbon Steel by 1-Ethyl-3-methylimidazolium-methanesulphonate and 1-Ethyl-3-methylimidazolium Acetate Ionic Liquids in Hydrochloric Acid
Autorzy:
Ikpi, Magdalene Edet
Obono, Okama Ebri
Powiązania:
https://bibliotekanauki.pl/articles/354447.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
corrosion inhibition
carbon steel
ionic liquids
potentiodynamic polarization
electrochemical impedance
Opis:
The corrosion inhibition behaviour of 1-Ethyl-3-methylimidazolium-methanesulphonate (EMIM[MS]) and 1-Ethyl-3-methylimidazolium acetate (EMIM[Ac]) on API 5LX-52 carbon steel in 2 M HCl was investigated using weight loss, potentiodynamic polarization and electrochemical impedance methods. The corrosion rates of carbon steel decreased in the presence of these ionic liquids. The inhibition efficiencies of the compounds increased with concentration and showed a marginal decrease with a 10°C increase in temperature. Polarization studies showed the compounds to be mixed type inhibitors with stronger anodic character. The adsorption mechanism of both compounds on the metal surface was via physical adsorption and the process obeyed the El-Awardy kinetic-thermodynamic model. The associated activation energy of corrosion and other thermodynamic parameters were calculated to elaborate on the thermodynamics and mechanism of the corrosion inhibition process. EMIM[MS] was found to inhibit the corrosion of carbon steel better than EMIM[Ac] and is attributed to the presence of the highly electronegative sulphur atom in its structure and its larger molecular size.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 1; 295-304
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrochemical and Quantum Chemical Investigation on Adsorption of Nifedipine as Corrosion Inhibitor at API 5L X-52 Steel / HCl Acid Interface
Autorzy:
Ikpi, M. E.
Abeng, F. E.
Powiązania:
https://bibliotekanauki.pl/articles/356191.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
nifedipine
corrosion inhibition
electrochemical impedance
carbon steel
quantum chemical study
Opis:
Nifedipine, a pyridine derivative was investigated as corrosion inhibitor for API 5L X-52 steel in 2 M HCl solution by potentiodynamic polarization, electrochemical impedance spectroscopy and quantum chemical calculations. Statistical tools were used to compare results of the experimental methods. The results showed that nifedipine is capable of inhibiting the corrosion of API 5L X-52 steel in 2 M HCl solution. Potentiodynamic polarization results reveal that nifedipine functions as a mixed-type inhibitor and presents an inhibition efficiency of about 78% at 500 ppm. Impedance data reveal an increasing charge transfer resistance with increasing inhibitor concentration and also shows comparable inhibition efficiency of about 89-94% at 500 ppm. Thermodynamic parameters imply that nifedipine is adsorbed on the steel surface by a physiochemical process and obeys Langmuir adsorption isotherm. The calculated molecular properties namely the highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy, chemical hardness, energy gap, dipole moment, electronegativity and global nucleophilicity index all show a positive relationship to the observed corrosion inhibition efficiency.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 1; 125-131
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 75

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