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Wyświetlanie 1-10 z 14
Tytuł:
Electrochemical impedance spectroscopy as a mean of measuring film thickness of calcium sulfate precipitate on an XC70 carbon steel
Autorzy:
Lanez, T.
Chaabia, N.
Belaid, A.
Powiązania:
https://bibliotekanauki.pl/articles/412077.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
EIS
calcium sulphate
thickness
Opis:
In this paper we present the use of electrochemical impedance spectroscopy measurement as a tool to measure the thickness of calcium sulphate film formed on an XC70 carbon steel. The solution used is a mixture of sodium sulphate and calcium chloride solution at different concentrations. The film thickness of calcium sulphate is estimated, after an immersion time of 4 days. The results indicate reciprocal relationship between measured capacitance and thickness of calcium sulphate film.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 13, 1; 54-61
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biodegradable cement type bone implant materials based on calcium phosphates and calcium sulphate
Autorzy:
Siek, D.
Czechowska, J.
Zima, A.
Ślósarczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/283901.pdf
Data publikacji:
2015
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
calcium phosphate cements
hydroxyapatite
calcium sulphate
α-tricalcium phosphate
biomaterials
Opis:
Calcium phosphates (CaPs) are widely used in hard tissue replacement because of their excellent biocompatibility. Calcium phosphate cements (CPCs) are an interesting alternative for sintered calcium phosphate ceramics due to their mouldability and self-setting properties which allow them to conform to even the most complex bone defects. However, one of the major limitations of CPCs is their relatively low resorption rate, not optimal for bone regeneration. The aim of our studies was to combine a stable hydroxyapatite with more soluble α-tricalcium phosphate (α-TCP) or calcium sulphate (CS) (resorbability: CS>>α-TCP>HA) to develop biomaterial with gradual degradation. Promising materials for use in minimally invasive surgery for bone defects repair were obtained. It was found that the degradation rate of hydroxyapatite based bone substitutes can be controlled by the addition of an appropriate kind and amount of more soluble constituent. The impact of the setting component (α-TCP or CS) on the physicochemical properties of the final products was confirmed. Furthermore the influence of organic additives (chitosan, methylcellulose, alginate) on the final materials characteristic was proven. Solutions of organic additives, applied as the liquid phases, significantly improved the workability of cement pastes. It has been demonstrated that implant materials based on calcium sulphate and α-TCP differed in their setting times, mechanical strength, dissolution rate and morphologies of apatite layers on their surfaces after soaking in simulated body fluid. The reason of observed differences is a higher susceptibility of calcium sulphate to both disintegration and degradation.
Źródło:
Engineering of Biomaterials; 2015, 18, 133; 2-6
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Equilibrium and kinetic studies of sorption of 2.4-dichlorophenol onto 2 mixtures: bamboo biochar plus calcium sulphate (BC) and hydroxyapatite plus bamboo biochar plus calcium sulphate (HBC), in a fluidized bed circulation column
Autorzy:
Alamin, A.H.
Kaewsichan, L.
Powiązania:
https://bibliotekanauki.pl/articles/780072.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
2.4-dichlorophenol
bamboo biochar
hydroxyapatite
calcium sulphate
adsorption
Opis:
Sorption studies were carried out to investigate removal of 2.4-dichlorophenol (2.4-DCP) from aqueous solution in a fluidized bed by two types of adsorbent mixtures: BC (Bamboo char plus Calcium sulphate), and HBC (Hydroxyapatite plus Bamboo char plus Calcium sulphate); both manufactured in ball shape. The main material bamboo char was characterized by FTIR, DTA and SEM. The adsorption experiments were conducted in a fluidized bed circulation column. Adsorption, isotherms and kinetic studies were established under 180 min operating process time, at differentinitial 2.4-DCP solution concentrations ranging from 5–10 mg/L, and at different flow rates ranging from 0.25–0.75 L/min. The data obtained fitted well for both the Langmuir and Freundlich isotherm models; indicating favorable condition of monolayer adsorption. The kinetics of both adsorbents complies with the pseudo second-order kinetic model. BC was proven a new effective composite and low cost adsorbent which can be applied in the field of wastewater treatment, and it can also play an important role in industry water treatment.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 2; 59-67
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Postharvest calcium salt treatment of fresh jujube fruit and its effects on biochemical characteristics and quality after cold storage
Autorzy:
Moradinezhad, F.
Ghesmati, M.
Khayyat, M.
Powiązania:
https://bibliotekanauki.pl/articles/2161.pdf
Data publikacji:
2019
Wydawca:
Instytut Ogrodnictwa
Tematy:
jujube fruit
Ziziphus jujuba
cold storage
calcium chloride
calcium nitrate
calcium sulphate
antioxidant
biochemical characteristics
Źródło:
Journal of Horticultural Research; 2019, 27, 2
2300-5009
Pojawia się w:
Journal of Horticultural Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Transformations of calcium sulphates in solidified carbonated volatile fluidized ashes
Autorzy:
Łączny, M. J.
Bzowski, Z.
Powiązania:
https://bibliotekanauki.pl/articles/92109.pdf
Data publikacji:
2017
Wydawca:
Główny Instytut Górnictwa
Tematy:
volatile fluidized ashes
carbonation
calcium sulphate
lotny popiół fluidalny
karbonatyzacja
siarczan wapnia
Opis:
Carbonation of volatile fluidized ashes with the use of carbon dioxide can be a means to their transformation into a product with a possible application as an additive to cement and concrete. Currently, due to its physical-chemical characteristics and particularly because of the high concentration of free calcium oxide, the possible applications of this product are highly limited, perhaps even none existent. A significant reduction or even the complete elimination of CaO can be achieved by its transformation into calcium carbonate. In carbonated volatile fluidized ashes, two components relevant to the binding time of mortar, as well as its durability, can be found: calcium carbonates and calcium sulphates. During the investigation it was assumed that calcium carbonate, being poorly water-soluble, would not react with the remaining components of the porous water of the volatile fluidized ash. Crystalline phases of calcium sulphates, anhydrite, gypsum and bassanite occurring in bound volatile fluidized ashes after carbonation demonstrate the possibility of crystallization in the presence of calcium carbonate. In particular, a change in the concentration of bassanite indicates that this phase, as a precursor to the crystallization of gypsum, may play a significant role in the process of binding carbonated volatile ashes.
Źródło:
Journal of Sustainable Mining; 2017, 16, 4; 151-155
2300-1364
2300-3960
Pojawia się w:
Journal of Sustainable Mining
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation methods of calcium sulphate and urea adduct
Autorzy:
Malinowski, P.
Biskupski, A.
Głowiński, J.
Powiązania:
https://bibliotekanauki.pl/articles/778701.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
addukt
siarczan wapnia
nawóz
gips
fosfogips
mocznik
adduct
calcium sulphate
fertilizer
gypsum
phosphogypsum
urea
Opis:
The paper presents the results of laboratory studies on the preparation of calcium sulphate and urea adduct by: grinding, compacting and mixing in the presence of physical water. A method for the measurement of urea conversion into the adduct form, which is based on the difference in solubility of free urea and the adduct bound urea CaSO4ź4CO(NH2)2 in n-butanol, was developed. Mixing the reagents in the presence of physical water produced the best results. High urea conversion into the adduct form, over 85%, in the prepared samples indicates that this method can be successfully used to get CaSO4ź4CO(NH2)2 adduct.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 4; 111-114
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative study on physicochemical properties of alpha-TCP / calcium sulphate dihydrate biomicroconcretes containing chitosan, sodium alginate or methylcellulose
Autorzy:
Czechowska, Joanna
Zima, Aneta
Ślósarczyk, Anna
Powiązania:
https://bibliotekanauki.pl/articles/307328.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alpha-tricalcium phosphate
calcium sulphate
chitosan
sodium alginate
methylcellulose
biomicroconcrete
siarczan wapnia
chitozan
alginian sodu
metyloceluloza
Opis:
Recently, the attention has been drawn to complex systems – biomicroconcretes composed of a bone cement matrix and resorbable granules or microspheres. This paper presents novel bone substitutes composed of α-tricalcium phosphate (α-TCP; cement matrix), calcium sulphate dihydrate granules (GCSD; aggregates in biomicroconcrete) and various polymers (chitosan, sodium alginate, methylcellulose) used for the improvement of material properties. The aim of this work was to study α-TCP-GCSD-polymer interactions and to compare the impact of organic additives on the physicochemical properties of biomicroconcretes. Methods: Scanning electron microscopy (SEM), mercury intrusion porosimetry (MIP), X-ray diffractometry (XRD) as well as universal testing machine (INSTRON), Gilmore apparatus and pH/ conduct-meter were used. Results: The chemical bonding between α-TCP matrix and CSD granules resulted in a compressive strength appropriate for low-load bearing applications (7–12 MPa) and clinically relevant setting times (8–33 min). Biomicroconcretes consisting of sodium alginate possessed the highest mechanical strength (12 ± 2 MPa). It has also been found that the dissolution-precipitation reactions of the α-TCP were retarded with the addition of chitosan and acetic acid. This effect was not observed in the case of methylcellulose and sodium alginate. Chemical stability and bioactivity of materials were demonstrated during in vitro studies in simulated body fluid. Conclusions: Materials containing calcium sulphate-based granules were surgically handy, possessed promising physicochemical properties and are supposed to ensure desired macroporosity as well as gradual resorption in vivo. It has been demonstrated that the presence of CSD granules and polymers influenced the physicochemical properties of composites.
Źródło:
Acta of Bioengineering and Biomechanics; 2020, 22, 1; 47-56
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of granular fertilisers produced from industrial and municipal wastes on the crop yield and their content of macroelements
Autorzy:
Krzywy, E.
Możdżer, E.
Bakenowa, Ż.
Powiązania:
https://bibliotekanauki.pl/articles/778051.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
iron(II) sulphate(VI) heptahydrate
calcium sulphate(VI) heptahydrate
municipal and industrial sewage sludge
yields and chemical composition of test plants
Opis:
Four granular fertilisers were produced from industrial waste products, such as CaSO4 2H2O and FeSO4 7H2O, coniferous and deciduous sawdust mixture and municipal sewage sludge with addition of mineral fertilisers. Based on the content of organic matter, nitrogen, phosphorus and potassium and heavy metals, these granular fertilisers can be included into the group of organic-mineral fertilisers. In order to determine their manurial value, a vegetation experiment was carried out with these granular fertilisers in which spring rape and spring triticale were the test plants. The study results show that granular fertilisers increased signifi cantly the yields of test plants and their content of macroelements. The granular fertilisers containing FeSO4 7H2O increased signifi cantly the yields of test plants and the contents of macroelements when compared to those with CaSO4 2H2O. As affected by the granular fertilisers containing CaSO4 2H2O, there was more phosphorus, calcium and sulphur in the test plants. The granular fertilisers composed of the waste products mentioned above can be a cheap source of organic matter and nutrients for plants and may reduce possibility of environmental contamination.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 2; 11-16
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of $Ca{2+}$ and $SO_4^{2-}$ ions on fluorite flotation
Autorzy:
Xun, Luobing
Hu, Jiacheng
Shi, Qing
Zhang, Guofan
Powiązania:
https://bibliotekanauki.pl/articles/1448205.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fluorite
flotation
calcium cation
sulphate anion
Opis:
The effects of $Ca^{2+}$ and $SO_4^{2-}$ on the flotation behaviour of fluorite with sodium oleate as a collector and the underlying mechanism by which these effects were investigated via micro-flotation experiments, solution chemistry calculations, and X-ray photoelectron spectroscopy. The results indicated that the addition of $SO_4^{2-}$ and $Ca^{2+}$ inhibited fluorite flotation and the inhibition effect was increased by the addition of pH. This was mainly due to the increase of the sulphate-containing components in the solution and the adsorption of $SO_4^{2-}$ on the surface of fluorite. With the increase of pH, the alkalinity of the solution increases, OH- and more $SO_4^{2-}$ are further adsorbed on the fluorite surface, thereby reducing the recovery of fluorite flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 2; 95-104
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Possibility of using a mixture of calcium salts to decrease sulphate concentration and total mineralisation of surface and mine waters
Możliwość zastosowania mieszanki soli wapnia w celu zmniejszenia stężenia siarczanów oraz ogólnej mineralizacji wód powierzchniowych i kopalnianych
Autorzy:
Trach, Y.
Trach, R.
Powiązania:
https://bibliotekanauki.pl/articles/28765727.pdf
Data publikacji:
2022
Wydawca:
Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Tematy:
limestone
surface water
mine water
mineralization
sulphate
sulphate concentration
calcium salt
sulphate ion
calcium acetate
pollutant removal
laboratory research
Źródło:
Acta Scientiarum Polonorum. Architectura; 2022, 21, 4; 63-68
1644-0633
Pojawia się w:
Acta Scientiarum Polonorum. Architectura
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 14

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