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Wyświetlanie 1-10 z 84
Tytuł:
Analysis of Double Base Propellant Infuence on Detonation Process of Ammonals
Autorzy:
Maranda, A.
Lipińska, K.
Lipiński, M.
Powiązania:
https://bibliotekanauki.pl/articles/358689.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium nitrate based explosives
detonation parameters
Opis:
Aluminum powder has been applied to various types of mining and military explosives for over a hundred years. A known solution is its application as an additive to ammonium nitrate that enhances detonation ability and detonation parameters. Besides aluminum powders, organic fuels are used as ammonals components. In the present work reuse of double base propellants as components of ammonals was proposed. The results of detonation velocity and performance measurements of double base propellants and ammonals mixtures are presented.
Źródło:
Central European Journal of Energetic Materials; 2010, 7, 2; 145-159
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Tetraamminecopper(II) Nitrate and Its Effects on Ammonium Nitrate(V)
Autorzy:
Künzel, M.
Vodochodský, O.
Matyáš, R.
Jalový, Z.
Pachman, J.
Maixner, J.
Powiązania:
https://bibliotekanauki.pl/articles/357988.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium nitrate
complex salt
copper
detonation
initiation
Opis:
Tetraamminecopper(II) nitrate(V) (TACN) is a complex copper salt which is easily formed when ammonium nitrate (AN) comes into contact with copper. It is considered to be an unwanted contaminant of AN because of its sensitivity to mechanical stimuli and significant explosive properties. The formation of TACN by the reaction of copper with molten ammonium nitrate(V) was demonstrated by powder diffraction. Friction and impact sensitivity testing was performed and field experiments were then conducted to reveal the detonation parameters of TACN and its initiation capability towards ammonium nitrate. The dependence of the detonation velocity on charge diameter was revealed and the ideal detonation velocity of 3500 m·s−1 at 0.87 g·cm−3 was measured. AN with the addition of 16 wt.% of TACN was found to detonate when initiated with a small booster charge. Moreover, TACN was able to initiate detonation in fertilizer grade ammonium nitrate(V) under massive steel confinement. TACN should be therefore considered as a possible contributory initiation source in some large scale accidents. In this article, some properties of TACN are revealed which could be useful for the investigation of accidents.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 169-183
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonability of Ammonium Nitrate and Mixtures on Its Base
Autorzy:
Kuzmin, V.
Kozak, G.
Mikheev, D.
Powiązania:
https://bibliotekanauki.pl/articles/357972.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
improvised explosive
ammonium nitrate
detonability
failure detonation diameter
Opis:
Quantities of improvised explosive devices on a base of industrial explosives that were applied at criminal incidents or were withdrawn from illegal circulation were reduced on average on 9% during last decade. This tendency is explained in particular by toughening of control under circulation of commercial explosive devices. The most commonly used improvised explosives according to returns of The Forensic Science Center of Ministry of Internal Affairs are mixtures on a base of ammonium nitrate with organic fuels and aluminum powder. Quantitative and qualitative compositions of such improvised mixtures can be various. The most essential question for a criminal case investigator is argument that excepted substance is explosive one. In this connection detonability of the mixtures on base fne (particle size was near 20 microns) and granulated ammonium nitrate with some organic fuels and aluminum powder was experimentally investigated. Failure detonation diameters of systems were measured experimentally.
Źródło:
Central European Journal of Energetic Materials; 2010, 7, 4; 335-343
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of thermal analysis and calorimetry for assessment of safety and quality of nitrogen fertilizers
Autorzy:
Poplawski, D.
Kaniewski, M.
Hoffmann, J.
Hoffmann, K.
Powiązania:
https://bibliotekanauki.pl/articles/30147054.pdf
Data publikacji:
2018
Wydawca:
Akademia Wojsk Lądowych imienia generała Tadeusza Kościuszki
Tematy:
ammonium nitrate
fertilizers
safety
quality
calorimetry
thermal analysis
Opis:
The paper presents the results of studies carried out using differential thermal analysis (DTA) and differential scanning calorimetry (DSC), conjugated with thermogravimetry (TG). Measurements were made for samples with differentiated compositions, mainly consisting of ammonium nitrate with fertilizer purity and compounds that may be present in nitrogen fertilizers as potential additives or contaminants. The possibilities of applied techniques and recommendations concerning proper selection of measurement conditions are described. Furthermore, the method of interpretation of the obtained results is presented, which allows evaluating the thermal stability of the tested mixtures for the safety and quality of nitrogen fertilizers.
Źródło:
Scientific Journal of the Military University of Land Forces; 2018, 50, 3(189); 206-217
2544-7122
2545-0719
Pojawia się w:
Scientific Journal of the Military University of Land Forces
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Erythritol tetranitrate as a sensitizer in ammonium nitrate based explosives
Autorzy:
Künzel, M.
Němec, O.
Matyáš, R.
Powiązania:
https://bibliotekanauki.pl/articles/358427.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
erythritol tetranitrate
improvised explosive
ammonium nitrate
slurry
emulsion
Opis:
This paper focuses on ammonium nitrate based explosives sensitized with erythritol tetranitrate. Erythritol tetranitrate (ETN) is an ester of nitric acid and erythritol. It is a low melting crystalline solid with explosive properties similar to those of pentaerythritol tetranitrate. Experiments were conducted in order to determine any sensitizing effect this compound might have on three basic types of ammonium nitrate based mixtures – powdered, slurry and emulsion explosives. According to the results obtained, erythritol tetranitrate acts as a sensitizer giving detonator sensitivity to ammonium nitrate based explosives when incorporated therein in quantities from 10 to 20 percent.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 3; 351-358
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ammonium nitrate phase state stabilization with small amounts of some organic compounds
Autorzy:
Golovina, N.
Nechiporenko, G.
Nemtsev, G.
Zyuzin, I.
Manelis, G. B.
Lempert, D.
Powiązania:
https://bibliotekanauki.pl/articles/358906.pdf
Data publikacji:
2009
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium nitrate
phase transitions
phase stabilization
intermolecular interactions
Opis:
The investigation considers phase stabilization of ammonium nitrate for considerable extension of its application area including new generation of gas-generating compositions for airbag inflators. It was shown that alloys of ammonium nitrate with small amounts (2-10%) of some organic compounds can have no phase transitions or at least have only one instead of three ones in initial ammonium nitrate. The mostly effective as stabilizers are the compounds that have rather close crystallographic parameters. A strong donor-acceptor interaction between nitrate-anion and organic molecules are found. Using quantum-chemical calculations, X-ray analysis, X-ray phase analysis, UV- and IR-spectroscopy it was found a new ammonium nitrate phase state in its alloy with some organic additives. This state is stable in temperature range between -50 and +100 C.
Źródło:
Central European Journal of Energetic Materials; 2009, 6, 1; 45-56
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cast Porous Charges on a Base of Ammonium Nitrate-Urea Eutectic
Autorzy:
Litovka, O. B.
Kozak, G. D.
Chugreeva, E. Y.
Starshinov, A. V.
Powiązania:
https://bibliotekanauki.pl/articles/358034.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
eutectic
ammonium nitrate
urea
fusion diagram
detonability
detonation velocity
Opis:
There are great number tasks of explosive technique, requiring the charges with low pressure and detonation velocity. Powerful tool of regulation of these parameters is lowering of charge density. The main goal of this work is elaboration of technology of manufacture and investigation of explosive properties of charges on a base of eutectic ammonium nitrate-urea mixtures (AN/UR) that have melting point T[m] < 100 C. The physicochemical properties of these mixtures were investigated by means of DSC method and fusion diagram of them was plotted. The composition AN/UR 80/20, that has Tm= 80-90 C was chosen for subsequent investigation. The molten composition was mixed with fine aluminum powder, portion of it was placed into paper tube. The level of a liquid was less than length of the tube. Crystallization of melted mixtures was carried out in vacuum chamber, the level of liquid increased at pumping because of expansion of air bubbles introduced with aluminum particles and reached the upper cork of tube. In such a way porous charges were formed. The dependence of charge density vs. population of tubes by melted mixtures was plotted. Calculated heat explosion of mixtures at content of aluminum Al = 10-15% is Qv = 4.5-5.3 MJ/kg, calculated detonation velocity at density ρ = 0.5-1 g/cm3 changes from D = 3.2 to 5.2 km/s. Detonability of charges was investigated experimentally. Failure diameter (df) of detonation was measured, it was df = 22 mm (ρ = 0.6-0.7 g/cm3) for charges without confinement at initiation by means of booster or blasting cap.
Źródło:
Central European Journal of Energetic Materials; 2008, 5, 2; 57-66
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonation Properties of Mixtures of Ammonium Nitrate Based Fertilizers and Fuels
Autorzy:
Buczkowski, D.
Zygmunt, B.
Powiązania:
https://bibliotekanauki.pl/articles/358466.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium nitrate based fertilizers
detonation properties
illicit use explosives
Opis:
Detonation properties of mixtures of milled ammonium nitrate based fertilizers and fuels - aluminium or mineral oil - have been determined. The fertilizers used were ammonium nitrate and its compositions with mineral meal; for some compositions additional amount of mineral meal was mixed with the fertilizer. Detonation velocity, Guerney's energy and limits of detonability of such mixtures have been measured. It was examined that mixtures of mineral oil and fertilizers containing over 20% of mineral meal detonated during the tests. Mixtures of aluminium and fertilizers detonated even if concentration of mineral meal in the fertilizers was 40%.
Źródło:
Central European Journal of Energetic Materials; 2011, 8, 2; 99-106
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Explosive Properties of Mixtures of Ammonium Nitrate(V) and Materials of Plant Origin – Danger of Unintended Explosion
Autorzy:
Buczkowski, D.
Powiązania:
https://bibliotekanauki.pl/articles/358069.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium nitrate(V)
materials plant origin
decomposition
detonation properties
Opis:
The addition of many organic substances decreases the thermal stability and increases the explosive properties of ammonium nitrate(V). In order to determine how very material of plant origin would increase the risk of decomposition and explosion of ammonium nitrate(V), tests using the DTA method and the detonation properties were performed. The materials tested were milled ammonium nitrate(V) mixed with wheat flour, hard coal, rape seeds or wood dust. It was found that all of the mixtures tested decompose at significantly lower temperatures than ammonium nitrate(V) and ANFO explosive. Some of them decompose close to the melting temperature of ammonium nitrate(V) and their decomposition is violent. All of the mixtures tested are cap sensitive and some of them have smaller critical diameters than ANFO. The detonation velocities of the mixtures are lower than the detonation velocity of ANFO, but significantly higher than that of ammonium nitrate(V).
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 1; 115-127
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonation parameters of mixtures containing ammonium nitrate and aluminium
Autorzy:
Zygmunt, B.
Powiązania:
https://bibliotekanauki.pl/articles/358910.pdf
Data publikacji:
2009
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium nitrate based mixtures
detonation parameters
Dremin’s method
Opis:
Ammonium nitrate (AN) is the most popular ingredient of commercial explosives. Pure AN is not treated as an explosive compound but a slight organic or inorganic addition makes the mixture capable of explosion. In the paper the experimental tests were focused on aluminium (Al) as the most effective sensitizer. Mixture of AN or water solution AN with aluminium (ammonals and hydro-ammonals) were studied. Using electromagnetic method of measuring of the mass velocity behind the detonation wave front (Dremin’s method), detonation parameters as well the shape of detonation waves in explosive mixtures were determined. The essential factor influencing the detonation parameters of the studied explosives is their physical structure.
Źródło:
Central European Journal of Energetic Materials; 2009, 6, 1; 57-66
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 84

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