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Tytuł:
Optimization of acid assisted extraction process of foxtail millet polysaccharides and its antioxidant activity
Autorzy:
Shi, Y.
Zhu, A.
Shen, L.
Powiązania:
https://bibliotekanauki.pl/articles/2082902.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
foxtail millet
polysaccharides
acid extraction
response surface methodology
antioxidant activity
Opis:
Experiments concerning hydrochloric acid assisted extraction of polysaccharides from foxtail millet were carried out. Various combinations of extraction conditions of hydrochloric acid concentration, liquid-solid ratio, extraction time and extraction temperature were investigated using the Response Surface Methodology at three levels and four variables of Box-Behnken designs to obtain the maximum yield of polysaccharides. The experimental data were fitted to a quadratic equation using multiple regression analysis and analysed. The antioxidant activity of the obtained polysaccharides was also investigated in vitro. The optimal conditions were an acid concentration of 2.4 mol L-1, a liquid- solid ratio of 19.3:1 mL g-1, an extraction time of 1.2 h, and an extraction temperature 80.6°C. Under these conditions, the experimental yield was 52.13 mg g-1, which was in close agreement with the value of 52.37 mg g-1 predicted by the model. The mathematical model had a high correlation with experimental data (p<0.05). The polysaccharides of foxtail millet display a high radical scavenging capacity against superoxide and hydroxyl radicals.
Źródło:
International Agrophysics; 2020, 34, 2; 141-149
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zmiany form chemicznych metali ciężkich w osadach ściekowych po procesie ekstrakcji roztworem kwasu cytrynowego
Changes of chemical forms of heavy metals in sewage sludge after extraction with citric acid solution
Autorzy:
Karwowska, Beata
Piekutin, Janina
Powiązania:
https://bibliotekanauki.pl/chapters/27315989.pdf
Data publikacji:
2023-07-19
Wydawca:
Politechnika Częstochowska. Wydawnictwo Politechniki Częstochowskiej
Tematy:
metale ciężkie
osady ściekowe
kwas cytrynowy
frakcjonowanie
heavy metals
sewage sludge
citric acid extraction
fractionation
Opis:
W pracy określono wpływ ekstrakcji 1 M roztworem kwasu cytrynowego na formy i mobilność wybranych metali (Zn, Cu, Cd, Ni i Pb) w osadach ściekowych. Osady przed i po ekstrakcji 1 M roztworem kwasu cytrynowego poddano analizie sekwencyjnej metodą BCR w celu oznaczenia zawartości metali we frakcjach osadów. Metale usuwane były ze wszystkich frakcji, jednak nie w takim samym stopniu. Zmiany udziału cynku, niklu i ołowiu największe były we frakcji I, miedź była ekstrahowana z frakcji II, kadm z IV, a ołów z frakcji III i IV. Zmiany mobilności największe były dla niklu, miedzi i cynku.
The aim of the study was to establish the influence of 1 M citric acid solution extraction on the forms and distribution of selected heavy metals (Zn, Cu, Ni, Pb, Cd) in sewage sludge. Sewage sludge before and after washing was examined for speciation of mentioned heavy metals using BCR sequential extraction procedure. Metals were removed from all fractions, but in different efficiency. Changes in zinc, nickel and lead fates were the highest in I fraction, copper was extracted mainly from II fraction, cadmium from IV and lead from I and III. Changes in mobility were the most significant in case nickel, copper and zinc.
Źródło:
Inżynieria środowiska i biotechnologia. Wyzwania i nowe technologie; 357-366
9788371939013
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bioługowanie metali ciężkich z odpadów pogalwanicznych przy neutralnym pH środowiska, w obecności bakterii produkujących biosurfaktanty
Bioleaching of heavy metals from galvanic wastes at neutral pH in the presence of biosurfactant producing bacteria
Autorzy:
Karwowska, E.
Andrzejewska-Morzuch, D
Powiązania:
https://bibliotekanauki.pl/articles/1819284.pdf
Data publikacji:
2012
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
microbial surfactants
sludge
extraction
acid
Opis:
Precipitates and sludges from the galvanic industry are one of the sources of the environment contamination with heavy metals. Therefore, the investigations are carried out in order to developer the effective method of metals elimination from these wastes. The promising results are obtained in case of the application of microbial leaching. Up to now results concerned mainly the metals bioleaching in acidic environment. In this research work the possibility of heavy metals removal from galvanic wastes using the culture of sulphur oxidizing bacteria (pH 2-4) and a mixed culture of both sulphur oxidizing bacteria and biosurfactant producing bacteria (pH 6.5-8) was examined. It allowed to compare the process effectiveness in acidic and neutral environment. The cultures were prepared based on the activated sludge from the municipal wastewater treatment plant. The presence of sulphur oxidizing bacteria Acidithiobacillus ferrooxidans was confirmed using the PCR method. Bacillus subtilis and B. cereus strains were applied as biosurfactant producers. Three galvanic wastes, different in grain size, water content and heavy metal concentration, were bioleached. The research revealed that the metal release from galvanic wastes was more effective in presence of biosurfactant, especially in case of copper, but also for cadmium and chromium. The process effectiveness in acidic condition was comparatively lower. Zinc was the only metal that was bioleached faster in acidic environment, with similar final metal removal after 25 days of the process. The maximum values of metals elimination in the presence of biosurfactant depended on the bioleached waste type and were: 7.1-100% for copper, 3.7-50.3% for zinc, 30-50.5% for chromium, 34.1-71.9% for cadmium. The effectiveness of the nickel and lead removal was lower than 5%. The prolongation of the bioleaching period up to 40 days in case of waste C (the less susceptible to the bioleaching) resulted in elimination of 67.9% of Cu, 34.7% of Zn, 100% of Cr and 39.1% of Pb, while the effectiveness of nickel removal was still very low.
Źródło:
Rocznik Ochrona Środowiska; 2012, Tom 14; 597-606
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction equilibria of hypophosphorous, phosphorous and phosphoric acids by toluene solution of tri-n-octylamine
Autorzy:
Sana, T.
Shiomori, K.
Kawano, Y.
Powiązania:
https://bibliotekanauki.pl/articles/347049.pdf
Data publikacji:
2003
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
hypophosphorous acid
phosphorous acid
phosphoric acid
tri-n-octylamine
extraction equilibrium
Opis:
The extraction equilibria of hypophosphorous, phosphorous and phosphoric acids with tri-n-octylamine as an extractant in toluene were measured at 303K. Under these conditions, undissociated acid (A’) reacts with the amine (B) to form various complexes in toluene. The complexes formed and equilibrium constants were estimated by a graphical analysis method. The complexes formed in these systems were found to be A’nB type species for hypophosphorous acid, A’nBm type species for phosphorous acid, (A'B)n type species for phosphoric acid, respectively. The experimental results could be explained by reaction models and equilibrium constants for each acid.
Źródło:
Ars Separatoria Acta; 2003, 2; 125-138
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Copper recovery from chalcopyrite concentrate acid leach solutions by Acorga M5397
Autorzy:
El Amari, K.
Jdid, E.-A.
Blazy, P.
Powiązania:
https://bibliotekanauki.pl/articles/110601.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
copper solvent extraction
solvent extraction selectivity
nitro-fluorosilic acid
AcorgaM5397
Opis:
Chalcopyrite concentrate from Hajar Mine, Morocco, was leached with nitro-fluosilicic acid leach solution. The pregnant leach solution obtained contained 19.3 g/dm3 Cu, 18.1 g/dm3 Fe, 4.5 g/dm3 Zn and 0.03 g/dm3 Pb. Copper recovery from this pregnant leach liquor was performed by solvent extrac-tion using Acorga M5397 diluted in Escaid 110. McCabe–Thiele distribution isotherms showed that at pH 1.7 complete and selective copper extraction can be achieved with φo/φa =1.5/1 in 3 stages of extraction. Stripping of the loaded copper by treating the organic phases by a fresh sulphuric acid solution was easily realized.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 1; 329-339
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zinc extraction from Ghazouat leach residues by using jarosite method
Autorzy:
Begar, Abdelhakim
Djeghlal, Mohamed El Amine
Ould Hamou, Malek
Powiązania:
https://bibliotekanauki.pl/articles/2016450.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Wydział Geoinżynierii, Górnictwa i Geologii. Instytut Górnictwa
Tematy:
sphalerite
Zn
zinc
acid leaching
leaching residue
extraction
Opis:
In this paper, it was aimed to select and propose a feasible as well as an applicable method, for the extraction of zinc that was present in the disposed GHAZOUAT leach residues having 17.82 wt. % Zn and 20.82 wt. % Fe. After the determination of the components of the residue, the acid leaching was performed to reclaim Zn sequentially. The acid leaching experiments were carried out for Zn extraction by controlling acid concentration, reaction duration and temperature. At the optimum conditions, 240 g/L H2SO4 at 90 °C for 210 min, 80% of initial iron content was removed, and the resultant overall zinc extraction was usually superior than 96%.
Źródło:
Mining Science; 2021, 28; 117-126
2300-9586
2353-5423
Pojawia się w:
Mining Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New approach for third phase investigation in solvent extraction system
Autorzy:
Borkowski, M.
Powiązania:
https://bibliotekanauki.pl/articles/346969.pdf
Data publikacji:
2008
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
third phase
TBP
nitric acid
dodecane
solvent extraction
Opis:
The phenomenon of third phase formation in different liquid extraction systems is well known for more than 50 years but until now a good mathematical model that could predict the third phase formation has not been developed. The third phase is unwanted in extraction systems because, for example, in nuclear fuel reprocessing it can cause criticality problems. However, the third phase may be a useful tool in other technologies. In this paper a new approach to third phase investigation is proposed. This new approach eliminates the aqueous phase, simplifies the system and gives new insight in the nature the third phase. It is a step forward in understanding of the mechanism governing the formation of third phase. This new approach could quickly provide sufficient data to develop a comprehensive model.
Źródło:
Ars Separatoria Acta; 2008, 6; 31-40
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Direct measurements of reaction time for extractive processes
Autorzy:
Gotfryd, L.
Becker, K.
Pietek, G.
Szołomicki, Z.
Piwowonska, J.
Powiązania:
https://bibliotekanauki.pl/articles/109772.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
reaction time
solvent extraction
viscosity
stripping rate
sulphuric acid
Opis:
Extraction times for selected metal cations (Mg2+, Al3+, Zn2+, Cd2+, Cu2+, Ni2+, Co2+, Mn2+, Fe2+ and Fe3+) have been measured using cation-exchanging extractants - Versatic 10 (neodecanoic acid), DEHPA (bis(2-ethylhexyl)phosphoric acid) and Cyanex 272 (bis(2,4,4-trimetylpentyl)phosphinic acid). Data was collected directly by measuring and recording pH of the two phase reaction mixture with maintaining continuity of the aqueous phase. Similarly, the stripping rate of selected cations (Mg2+, Al3+, Zn2+, Cu2+, Ni2+, Co2+) in a sulphuric acid solution was measured. Viscosities of organic phases, saturated with cations, were measured before their stripping. Additionally, the extraction dependence of Mg2+, Al3+, Fe2+ and Fe3+ on pH was measured using Versatic 10 at various concentrations (7.5, 15 and 30 %).
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 909-919
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solvent extraction of Terbium(III) from chloride solution using organophosphorus extractant, its mixture and ionic liquid in the presence of organic acids
Autorzy:
Tran, Thanh Tuan
Song, Si Jeong
Oh, Chang Geun
Lee, Man Seung
Powiązania:
https://bibliotekanauki.pl/articles/24085863.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
extraction
Terbium(III)
organic acid
ionic liquid
buffer effect
Opis:
Addition of organic acids to dilute hydrochloric acid solution can improve the extraction of rare earth elements by single cationic extractants. However, the correlation between the chemical structure of organic acids and the extraction of REEs as well as the variation in equilibrium pH has not been elucidated. In this study, we investigated the extraction of Tb(III) from dilute HCl solutions containing an organic acid like formic, lactic, fumaric, or maleic acid. As extractants, single Cyanex 272, a mixture of Cyanex 272 and Alamine 336 (Ala336-Cy272), and an ionic liquid (ALi-Cy272) synthesized by Cyanex 272 and Aliquat 336 were used. The speciation of Tb(III) in dilute HCl solutions containing organic acids was analyzed. In extraction of Tb(III), organic acids showed two roles as complexing and buffering agent, which depended on the chemical structure of the acids. There was some difference in the extraction of Tb(III) between single Cyanex 272 and ionic liquid, ALi-Cy272. During extraction with ALi-Cy272, formic and lactic acid negatively affected the extraction of Tb(III). The fact that the chemical structure of organic acids affected the extraction of Tb(III) from dilute HCl solution by the studied extractants can provide important information on the selection of suitable extraction systems.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 162714
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective extraction of vanadium from vanadium-titanium magnetite concentrates by non-salt roasting of pellets-H2SO4 leaching process
Autorzy:
Luo, Yi
Che, Xiaokui
Wang, Haixia
Zheng, Qi
Wang, Lei
Powiązania:
https://bibliotekanauki.pl/articles/1445902.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium-titanium magnetite
pellets
selective extraction
sulfuric acid leaching
Opis:
In this work, a novel process of pellet non-salt roasting and H2SO4 leaching was proposed for the selective extraction of vanadium from vanadium–titanium magnetite concentrate. Vanadium can be leached but the iron impurity was maintained in the pellets. Moreover, the leached pellets can meet the quality requirements of the iron-making process after secondary roasting, realizing comprehensive utilization. The maximal vanadium leaching efficiency was up to 60.3%, whereas 0.17% of the iron impurity was leached. The optimum conditions of pellet roasting and leaching were obtained by single-factor experiments. The X-ray diffraction and scanning electron microscopy–energy disperse X-ray spectrometry analyses showed that the vanadium iron spinel can be oxidized and decomposed into Fe2O3 and vanadate during the roasting process. Given that dilute sulfuric acid can react with vanadate without reacting with Fe2O3 in the leaching process, selective vanadium extraction was realized. This work provides new insights into the industrial production of vanadium–titanium magnetite concentrate involving the direct extraction of vanadium.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 36-47
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Neodecanoic acid as extractant of selected non-ferrous metals
Autorzy:
Gotfryd, L.
Pietek, G.
Szołomicki, Z.
Becker, K.
Piwowońska, J.
Powiązania:
https://bibliotekanauki.pl/articles/109507.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Versatic 10
neodecanoic acid
solvent extraction
non-ferrous metals
hydrometallurgy
Opis:
The paper presents results of studies on extracting properties of neodecanoic acid (Versatic 10) solutions. Neodecanoic acid was diluted in Exxsol D80 AZ to three concentrations: 7.5, 15, and 30 % (v/v). Tests were conducted using sulphate(VI) solutions of six ions: Zn(II), Ni(II), Cu(II), Co(II), Cd(II), Mn(II) and a nitrate(V) solution of Pb(II). All the aqueous solutions were prepared as 0.1 M concentration. For all combinations of the used solutions (organic and aqueous), direct methods of measuring and recording the pH of the biphasic mixture have been applied. The degrees of ions extraction, depending on equilibrium pH were also presented in the paper. Extraction and stripping isotherms of selected ions and organic phase were plotted for 7.5 and 30 % (v/v) of extractant solutions and Zn(II), Ni(II) and Cu(II) ions.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 435-445
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction mechanism of lead ion with p-allylcalix[4]arene tetracarboxylic acid
Autorzy:
Ohto, K.
Yokomoto, T.
Higuchi, H.
Oshima, T.
Inoue, K.
Jumina, -
Powiązania:
https://bibliotekanauki.pl/articles/1202500.pdf
Data publikacji:
2004
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
p-allylcalix[4]arene tetracarboxyic acid
extraction
selectivity
peak shift
Opis:
25,26,27,28-Tetrakis(carboxymethoxy)-5,11,17,23-tetraallylcalix[4]arene in a cone conformation has been synthesized for the selective extraction of divalent lead ions. The extraction of divalent metal ions, such as lead, copper, nickel and zinc with p-allycalix[4]arene tetracarboxylic acid was investigated. The extraction data and chemical shift of 1H-NMR for the extractant, caused by the complexation with lead, supports the conclusion that two lead ions are extracted stepwise. The complex structure was proposed.
Źródło:
Ars Separatoria Acta; 2004, 3; 62-71
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sample Preparation Followed by High Performance Liquid Chromatographic (HPLC) Analysis for Monitoring Muconic Acid as a Biomarker of Occupational Exposure to Benzene
Autorzy:
Shahtaheri, S. J.
Ghamari, F.
Golbabaei, F.
Rahimi-Froushani, A.
Abdollahi, M.
Powiązania:
https://bibliotekanauki.pl/articles/91059.pdf
Data publikacji:
2005
Wydawca:
Centralny Instytut Ochrony Pracy
Tematy:
benzene
muconic acid
sample preparation
solid-phase extraction
biological monitoring
chromatography
Opis:
Factors affecting solid phase extraction (SPE) of trans,trans-muconic acid (ttMA), as a benzene biomarker, including sample pH, sample concentration, sample volume, sample flow rate, washing solvent, elution solvent, and type of sorbent were evaluated. Extracted samples were determined by HPLC-UV (high performance liquid chromatography-ultraviolet). The analytical column was C18, UV wave length was 259 nm, and the mobile phase was H2O/methanol/acetic acid run at flow rate of 1 ml/min. A strong anion exchange silica cartridge was found successful in simplifying SPE. There was a significant difference between recoveries of ttMA when different factors were used (p < .001). An optimum recovery was obtained when sample pH was adjusted at 7. There was no significant difference when different sample concentrations were used (p > .05). The optimized method was then validated with 3 different pools of samples showing good reproducibility over 6 consecutive days and 6 within-day experiments.
Źródło:
International Journal of Occupational Safety and Ergonomics; 2005, 11, 4; 377-388
1080-3548
Pojawia się w:
International Journal of Occupational Safety and Ergonomics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Quantitative relations between the content of selected trace elements in soil extracted with 0.03 M CH3COOH or 1 M HCL and its total concentration in carrot storage roots
Relacje ilościowe między zawartością wybranych pierwiastków śladowych w glebie ekstrahowanych 0,03 M CH3COOH i 1 M HCL a zawartością ich form ogólnych w korzeniach spichrzowych marchwi
Autorzy:
Smoleń, S.
Sady, W.
Ledwożyw-Smoleń, I.
Powiązania:
https://bibliotekanauki.pl/articles/11541915.pdf
Data publikacji:
2010
Wydawca:
Uniwersytet Przyrodniczy w Lublinie. Wydawnictwo Uniwersytetu Przyrodniczego w Lublinie
Tematy:
soil
chemical composition
extraction
heavy metal
trace element
element concentration
carrot
root
storage
acetic acid
hydrochloric acid
Opis:
There is an existing need for the development of rapid and easy-to-perform methods for analyzing chemical composition of soil basing on simultaneous extraction of many elements in a single solution. Furthermore, it is desirable that mineral concentration determined in soil using these methods should be significantly correlated with its content in plants. Many researches indicated that soil concentration of heavy metals and trace elements after extraction using 0.01 M CaCl2 did not reflect its content in vegetable plants.. The aim of the research was to determine the relation between soil content of: Al, B, Ba, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, Pb, Sr, Ti, V and Zn extracted in 0.03 M CH3COOH as well as 1 M HCl and its content in carrot storage roots. In 2008–2009 studies were carried out on soil samples after carrot cultivation (from 0–30 cm, 30–60 cm and 60–90 cm layers) as well as on carrot storage roots grown on the same soil site. In total, analysis of chemical composition (with respect to the content of tested elements) comprised: 112 samples of carrot storage roots, 112 soil samples from 0–30 cm layer as well as 48 soil samples from 30–60 cm and 60–90 cm layers. Higher applicability of soil extraction with 0.03 M CH3COOH (commonly used for macro element chlorides and boron determination) in comparison to extraction with 1 M HCl was demonstrated in reference to the estimation of the relation between soil and carrot content of: Al, B, Ba, Cd, Cr, Cu, Li, Ni, Sr, Ti and Zn. Application of 1 M HCl gave relatively better results when compared to the extraction with 0.03 M CH3COOH with respect to calculated values of correlation coefficient for Co, Fe, Mn, Mo and Pb content in soil and carrot. Content of Co, Mo, Pb and V in soil after extraction using 0.03 M CH3COOH was below the limits of its detection using ICP-OES spectrometer. No relation was found between vanadium content in soil (analyzed after extraction with 1 M HCl) and its content in carrot storage roots.
Istnieje potrzeba poszukiwania szybkich i łatwych do wykonania metod analizy zawartości składników w glebach, opartych na wspólnej ekstrakcji wielu składników. Zawartość składników oznaczona w glebach za pomocą tych metod korelowała z ich zawartością w roślinach. Liczne badania wykazały, że zawartość mikroelementów, metali ciężkich oraz pierwiastków śladowych w glebie oznaczana za pomocą 0.01 M CaCl2 nie odzwierciedla zawartości tych składników w warzywach. Celem badań było określenie zależności pomiędzy zawartością w glebie Al, B, Ba, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, Pb, Sr, Ti, V i Zn ekstrahowanych za pomocą 0,03 M CH3COOH i 1 M HCl, a ich zawartością w korzeniach spichrzowych marchwi. W latach 2008–2009 badaniami objęto próby gleby (z warstw 0–30 cm, 30–60 cm i 60–90 cm) po uprawie marchwi oraz próby korzeni spichrzowych marchwi z uprawy polowej prowadzonej na tym samym stanowisku glebowym. Łącznie analizie składu chemicznego (pod względem zawartości badanych pierwiastków) poddano 112 prób korzeni spichrzowych marchwi i 112 prób gleby z warstwy 0–30 cm oraz po 48 prób gleby z warstw 30–60 cm i 60–90 cm. Badania wykazały większą przydatność ekstrakcji gleby 0,03 M CH3COOH (standardowo służącej do określania zawartości makroskładników chlorków i boru) niż ekstrakcji 1 M HCl do oceny związku pomiędzy zawartością Al, B, Ba, Cd, Cr, Cu, Li, Ni, Sr, Ti i Zn w glebie a zawartością tych pierwiastków w korzeniach spichrzowych marchwi. Zastosowanie ekstrakcji 1 M HCl dało stosunkowo lepsze rezultaty niż ekstrakcja 0,03 M CH3COOH w zakresie wielkości współczynników korelacji pomiędzy zawartością Co, Fe, Mn, Mo i Pb w glebie i marchwi. Zawartość Co, Mo, Pb i V w glebie po ekstrakcji 0,03 M CH3COOH była niższa od limitu detekcji spektrometru ICP-OES. Nie wykazano związku pomiędzy zawartością wanadu w glebie (oznaczanego w 1 M HCl) a zawartością V w korzeniach spichrzowych marchwi.
Źródło:
Acta Scientiarum Polonorum. Hortorum Cultus; 2010, 09, 4; 3-12
1644-0692
Pojawia się w:
Acta Scientiarum Polonorum. Hortorum Cultus
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Eco-Friendly Principles on the Extraction of Humic Acids Intensification from Biosubstrates
Autorzy:
Malyushevskaya, Antonina
Koszelnik, Piotr
Yushchishina, Anna
Mitryasova, Olena
Mats, Andrii
Gruca-Rokosz, Renata
Powiązania:
https://bibliotekanauki.pl/articles/2202369.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
eco-friendly technology
environmental security
extraction
electric discharge
humic acid
biosubstrate
peat
Opis:
It is necessary to find innovative ways to improve the environmental performance of production processes and products. The technology of extracting valuable components from raw materials of plant origin is often used in technological processes of the food, pharmaceutical, chemical and other industries. Extraction is the most energy intensive step. The factors contributing to the extraction of humic acids from plant substrates under the action of electric discharge were studied. The purpose of the work was to study the efficiency of humic acids extraction from the biosubstrate under the action of electric discharges. The physical experiment showed that the main factor influencing the intensity of extraction is the degree of grinding of the solid phase of the biosubstrate-water suspension. The efficiency of electric discharge grinding depends on the pressure amplitude at the distance of the inner radius of the chamber and the number of discharge pulses. It was established that the number of chemical reagents (alkalis), usually used in the process of extracting humic acids from peat, can be reduced many times due to the appearance of radicals and peroxide compounds in the peat-water suspension resulting from the action of an electric discharge. The prospects of the non-thermal electric discharge method of intensification of the extraction of humic acids from biosubstrates were determined.
Źródło:
Journal of Ecological Engineering; 2023, 24, 2; 317--327
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
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