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Tytuł:
$TiO_2$ Nanotube Array as Efficient Transparent Photoanode in Dye-Sensitized Solar Cell with High Electron Lifetime
Autorzy:
Lamberti, A.
Sacco, A.
Hidalgo, D.
Bianco, S.
Manfredi, D.
Quaglio, M.
Tresso, E.
Pirri, C.
Powiązania:
https://bibliotekanauki.pl/articles/1399940.pdf
Data publikacji:
2013-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
73.63.Bd
72.20.Jv
72.40.+w
73.40.Mr
88.40.H-
81.07.De
Opis:
In the present work, the fabrication and characterization of non-curling, free-standing $TiO_2$ nanotube membranes and their integration in front-side illuminated dye-sensitized solar cells are reported. Vertically oriented $TiO_2$ nanotube arrays were fabricated by anodic oxidation of a titanium foil. Nanotube membranes were detached from the metallic foil, transferred and bonded on transparent fluorine-doped tin oxide/glass substrates employing a $TiO_2$ sol as a binder. Crystalline phase and morphology of the film were investigated, evidencing the formation of a highly ordered 1D nanotubes carpet, with a pure anatase crystalline structure. $TiO_2$ nanotube-based DSCs were fabricated using reversible microfluidic architecture. The cell performances were studied by I-V electrical characterization, incident-photon-to-electron conversion efficiency, electrochemical impedance spectroscopy and open circuit voltage decay measurements, showing an increase in electron lifetime compared to nanoparticle-based dye-sensitized solar cells.
Źródło:
Acta Physica Polonica A; 2013, 123, 2; 376-379
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Lattice Dynamical Investigation of the Raman and the Infrared Wave Numbers of $MnWO_4$
Autorzy:
Gupta, H.
Ruby, -
Sinha, M.
Powiązania:
https://bibliotekanauki.pl/articles/1419784.pdf
Data publikacji:
2012-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.50.Ah
63.22.Dc
63.70.+h
75.10.Pq
78.30.-j
Opis:
A short-range force constant model has been applied using normal coordinate analysis to investigate the Raman and the infrared modes in multiferroic $MnWO_4$ having space group P2/c. The calculation of zone centre phonons has been made with eight stretching and seven bending force constants. The calculated Raman and infrared wave numbers are in good agreement with the observed ones. The potential energy distribution has also been investigated for determining the significance of contribution from each force constant toward the Raman and the infrared wave numbers.
Źródło:
Acta Physica Polonica A; 2012, 122, 1; 142-145
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Asymmetry Driven Phase Transformations
Autorzy:
Damczyk, J.
Ostasiewicz, K.
Radosiński, Ł.
Radosz, A.
Powiązania:
https://bibliotekanauki.pl/articles/1535592.pdf
Data publikacji:
2010-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
05.70.-a
64.60.-i
63.70.+h
Opis:
Motivated by the properties of one-dimensional lattice systems with asymmetric on-site potential, one can formulate a hypothesis of an asymmetry driven phase transformation. Characteristic feature of one-dimensional systems exhibiting asymmetry driven phase transformation is a sequence of the two phase conversions. In particular class of such systems with a triple-well potential, phase conversions of one-dimensional systems would evolve into a sequence of two phase transitions in three-dimensional models. We propose here a model of three-dimensional system exhibiting a sequence of two first order asymmetry driven phase transitions.
Źródło:
Acta Physica Polonica A; 2010, 118, 4; 527-530
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Debye-Waller Factor in an Isotopically Disordered Semiconductor Crystal
Autorzy:
Gairola, S.
Powiązania:
https://bibliotekanauki.pl/articles/1398919.pdf
Data publikacji:
2016-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.70.+h
87.64.Bx
63.20.-e
63.20.Pw
64.70.kg
Opis:
The diagonal and non-diagonal parts for the Debye-Waller factor have been established using equation of motion technique of quantum dynamics and the Dyson equation approach. The double time temperature dependent phonon Green function has been taken to find the phonon linewidth and phonon shift. Renormalized mode frequency has been investigated in terms of electron-phonon coupling constant and temperature. The effect of electron-phonon interaction on the Debye-Waller factor has been studied in low temperature limit in low impurity concentration in semiconductor crystals.
Źródło:
Acta Physica Polonica A; 2016, 129, 6; 1141-1146
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Displacive Phase Transformations and Generalized Stacking Faults
Autorzy:
Paidar, V.
Ostapovets, A.
Hardouin Duparc, O.
Khalfallah, O.
Powiązania:
https://bibliotekanauki.pl/articles/1418492.pdf
Data publikacji:
2012-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.70.+h
Opis:
The displacive phase transformations can be considered as composed of two processes, namely, pure displacements, shuffling or shearing of atomic planes, and supplementary homogeneous lattice deformation changing also the dimensions of the moving planes. Such deformation causes shape memory effect when the structural transformation is reversed. General displacements of atomic planes will be examined, i.e. γ-surface type calculations will be reported for single plane shuffling, alternate shuffling of every other bcc atomic plane and successive displacements of parallel atomic planes producing in combination with homogeneous deformation the close packed structures. The results of calculations using the many-body potentials of the Finnis-Sinclair type will be compared with ab initio calculations that indicate in which way the phase transformation can be initiated.
Źródło:
Acta Physica Polonica A; 2012, 122, 3; 490-492
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrical Behaviour of Nanostructured Porous Silicon
Autorzy:
Azim-Araghi, M.
Ashrafabadi, S.
Kanjuri, F.
Powiązania:
https://bibliotekanauki.pl/articles/1419847.pdf
Data publikacji:
2012-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
73.30.+y
73.40.Sx
73.50.-h
73.90.+f
73.63.Rt
68.37.Hk
Opis:
The electrical behaviour of porous silicon layers has been investigated on one side of p-type silicon with various anodization currents, electrolytes, and times. Electron microscopy reveals the evolution of porous silicon layer morphology with variation in anodization time. In this work electrical conductivity of bulk silicon and porous layer which is formed by electrochemical etching is compared due to I-V measurements and calculation of activation energy. We have also studied the dependence of porous silicon conductivity on fabrication conditions. Also the effect of the temperature on conduction of porous silicon at different frequencies is investigated. At last dependence of capacitance on the temperature was probed at $10^2 - 10^5$ Hz frequency range.
Źródło:
Acta Physica Polonica A; 2012, 122, 1; 170-173
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrical Resistivity of the Monoatomic Metallic Layer
Autorzy:
Paja, A.
Działo, A.
Powiązania:
https://bibliotekanauki.pl/articles/1400157.pdf
Data publikacji:
2013-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
73.50.-h
73.50.Bk
73.63.-b
73.63.Hs
Opis:
We present new formula which describes the change of electrical resistivity of a monoatomic metallic layer with temperature. The results are compared with those given by the Bloch-Grüneisen formula for bulk metals. Our calculated values compared with those for bulk materials are significantly higher at low temperatures (T<0.1θ) and apparently lower at the remaining range of temperatures. Both effects can be explained by the low dimensionality of the sample.
Źródło:
Acta Physica Polonica A; 2013, 123, 4; 770-772
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron Transport and Spin Scattering in Very Thin Disordered Metallic Films
Autorzy:
Paja, A.
Spisak, B.
Powiązania:
https://bibliotekanauki.pl/articles/1814037.pdf
Data publikacji:
2007-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
72.15.Cz
72.25.Ba
73.50.-h
73.63.-b
Opis:
We consider the electron transport through a very thin disordered metallic film doped with magnetic impurities. We treat the film as a quasi-two-Łinebreak -dimensional system with structural disorder where some ions have spins and other are spinless. The interaction of conduction electrons with localized spins is described by means of the exchange term of the Hamiltonian. The scattering is treated in the first Born approximation and the potential is assumed to be the Coulomb screened one. The total effective cross-section is calculated as a sum of the part responsible for the potential scattering and the second part which comes from the spin-spin scattering. The Fermi sphere splits into separate sheets due to the finite size of the system in the z direction, therefore, the cross-section and the relaxation time are calculated for each sheet independently. The total transport relaxation time and the conductivity are obtained as functions of the thickness of the system and the contents of magnetic impurities. Some model calculations have been made for a thin disordered film of copper doped with manganese.
Źródło:
Acta Physica Polonica A; 2007, 112, 6; 1289-1295
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electronic Structure and X-Ray Photoelectron Spectra of YNi$\text{}_{4}$B Compound
Autorzy:
Pugaczowa-Michalska, M.
Chełkowska, G.
Kowalczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/2036993.pdf
Data publikacji:
2003-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.Eh
82.80.Pv
71.20.-b
63.70.+h
Opis:
The electronic structure of the ternary YNi$\text{}_{4}$B compound, crystallizing in the hexagonal CeCo$\text{}_{4}$B structure (P6/ mmm space group), was studied by X-ray photoelectron spectroscopy and ab initio calculations. Core levels and the valence band were investigated. The X-ray photoelectron spectroscopy valence band is compared with that obtained from ab initio calculations. The valence band spectrum at the Fermi level exhibits the domination of the Ni(3d) states, which are hybridized with 4d states of Y and 2p states of B. The theoretical electronic specific heat coefficientγ derived from N(E$\text{}_{F}$) is about 11.33 mJ/(mol K$\text{}^{2}$) for experimental lattice parameters. The calculated bulk modulus is B$\text{}_{0}$=1.61632 Mbar.
Źródło:
Acta Physica Polonica A; 2003, 104, 5; 487-494
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geometry of the $\text{}^4T_{2g}$ Excited State in $Cs_2SiF_6:Mn^{4+}$
Autorzy:
Reisz, A.
Avram, C.
Powiązania:
https://bibliotekanauki.pl/articles/1815472.pdf
Data publikacji:
2007-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.70.Ej
63.20.Kr
63.70.+h
Opis:
The aim of this paper is to calculate the equilibrium displacements of the $\text{}^4T_{2g}$ potential surface minimum from the ground state along the $a_{1g}$ and $e_g$ Jahn-Teller active modes for the octahedral $[MnF_6]^{2-}$ cluster obtained by doping $Mn^{4+}$ ions in $Cs_2SiF_6$ host crystal. The equilibrium displacements in normal and Cartesian coordinates were estimated from force constants of $[MnF_6]^{2-}$ cluster and Huang-Rhys factors associated with the Jahn-Teller stabilization energy. A net equatorial expansion and an axial stretching of the geometry of the $[MnF_6]_{2-}$ cluster in first $\text{}^4T_{2g}$ excited state, as combined effect of the $a_{1g}$ and $e_g$ displacements, were demonstrated.
Źródło:
Acta Physica Polonica A; 2007, 112, 5; 829-833
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inelastic X-Ray Scattering Studies of Phonon Dispersion in PbTe and (Pb,Cd)Te Solid Solution
Autorzy:
Kuna, R.
Minikayev, R.
Trzyna, M.
Gas, K.
Bosak, A.
Szczerbakow, A.
Petit, S.
Łażewski, J.
Szuszkiewicz, W.
Powiązania:
https://bibliotekanauki.pl/articles/1398584.pdf
Data publikacji:
2016-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.20.D-
68.43.-h
68.49.Sf
Opis:
PbTe and its solid solution (Pb,Cd)Te containing 2% of CdTe and PbTe grown by self-selecting vapour growth technique were investigated by inelastic X-ray scattering using synchrotron radiation. The ID28 beamline at ESRF with the incident photon energy of 17794 eV and the energy resolution of 3 meV was applied for that purpose. The measurements were performed at room temperature along [001]-type high symmetry direction in the Brillouin zone. In spite of a very low energy of phonon branches they can be determined by inelastic X-ray scattering with a high accuracy. The transversal acoustic phonon dispersion obtained by inelastic X-ray scattering corresponds well to those resulting from inelastic neutron scattering measurements and ab initio calculations. Apart from expected structures corresponding to the bulk phonons an additional scattering related to the crystal surface properties was observed in the inelastic X-ray scattering spectra. The analysis performed with the use of secondary ion mass spectroscopy technique demonstrated a presence of a thin oxide layer at sample surfaces.
Źródło:
Acta Physica Polonica A; 2016, 130, 5; 1251-1254
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the hydrogen adsorption to the optical properties of boron nitride nanotubes
Autorzy:
Bayani, A.
Powiązania:
https://bibliotekanauki.pl/articles/1070608.pdf
Data publikacji:
2016-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.67.Ch
85.35.-p
68.43.-h
67.63.Cd
67.80.ff
Opis:
In this research we have studied physisorption of hydrogen molecules on armchair (3,3) boron-nitride nanotube using density functional methods. Optical properties of the boron-nitride nanotube, with and without adsorbed H₂ molecules, were investigated under parallel and perpendicular polarized electric fields. The results indicate that the nanotube optical gap slightly changes due to H₂ physisorption and increasing H₂ physisorption suppresses the boron-nitride nanotube optical spectrum. Also, the nanotube gets more transparent as the H₂ concentration increases, in other words boron-nitride nanotube dielectric function decreases. Anisotropic dielectric function is another result which is determined by random phase approximation method.
Źródło:
Acta Physica Polonica A; 2016, 129, 3; 348-351
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Low Temperature Crystal Structure Behaviour of Complex Yttrium Aluminium Oxides YAlO_3 and Y_3Al_5O_{12}
Autorzy:
Senyshyn, A.
Vasylechko, L.
Powiązania:
https://bibliotekanauki.pl/articles/1399474.pdf
Data publikacji:
2013-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
61.05.F-
65.40.De
65.60.+a
63.70.+h
Opis:
Crystal structures of two yttrium aluminium oxides, namely $YAlO_3$ and $Y_3Al_5O_{12}$, were investigated in the temperature range 3.4-300 K by high-resolution neutron powder diffraction. Neither traces of phase transformations nor discontinuous changes of physical properties were observed. Thermal expansion of yttrium aluminium oxides was evaluated in terms of 1st order Grüneisen approximation, where the Debye temperatures and the Grüneisen parameters have been estimated for both compositions. Anomalies in the thermal expansion of yttrium aluminium perovskite have been observed and modelled using the Einstein oscillator with negative Grüneisen parameter. Extended bond length analysis revealed significant thermally-driven modifications of the aluminium-oxygen framework.
Źródło:
Acta Physica Polonica A; 2013, 124, 2; 329-335
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetite Fe$\text{}_{3}$O$\text{}_{4}$: the Correlated Electron-Phonon System
Autorzy:
Kozłowski, A.
Kąkol, Z.
Tarnawski, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2047312.pdf
Data publikacji:
2007-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
64.70.Kb
75.40.-s
63.20.Kr
71.30.+h
75.30.Cr
Opis:
In the paper the influence of magnetic as well as electron-lattice interactions on the Verwey transition in magnetite related compounds is discussed based on the authors' experimental activity and available literature. While magnetism was proved to only reflect the transition, the results of nuclear inelastic scattering show that lattice dynamics actively participates in it. The studies of diffuse neutron scattering and heat capacity suggest also that the low temperature lattice properties of slightly doped magnetite are distinct from those with higher dopant concentration. Finally, recent theoretical results strongly suggest that the Verwey transition in magnetite cannot be understood and described without strong involvement of electron-lattice interactions.
Źródło:
Acta Physica Polonica A; 2007, 111, 4; 537-547
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular Electronics: A Review of Experimental Results
Autorzy:
Erbe, A.
Verleger, S.
Powiązania:
https://bibliotekanauki.pl/articles/1808307.pdf
Data publikacji:
2009-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
85.65.+h
73.63.-b
85.35.-p
Opis:
Molecular electronics aims for scaling down electronics to its ultimate limits by choosing single molecules as the building blocks of active devices. The advantages of this approach are the high reproducibility of molecular synthesis on the nanometer scale, the ability of molecules to form large structures by self-assembly, and the huge versatility of molecular complexes. On the other hand, conventional contacting techniques cannot form contacts on the single molecule scale and imaging techniques nowadays cannot provide a detailed image of such junctions. Therefore, the fabrication has to rely to some degree on self-organization of the constituents. The proof that a molecule has been contacted successfully can only be given by indirect methods, for example by measuring the current transport through the junctions. Here we give an overview of various techniques that were used successfully to contact molecules and to characterize them electrically. The techniques range from methods to contact single molecules to such which can be used to characterize ensembles of molecules. Especially, the comparison between such different techniques shows that a single measurement is always prone to artefacts originating from the unknown microscopic details of the junctions. It is therefore necessary to perform a statistically relevant number of measurements in order to resolve molecular properties. Various properties of the molecules can be studied. Special examples are the influence of conformational changes of the molecules, differences between various coupling endgroups of the molecules and effects of light-irradiation onto the molecular junctions.
Źródło:
Acta Physica Polonica A; 2009, 115, 2; 455-461
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł

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