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Tytuł:
Dual Application of Al-Kheriat of Removal of Arsenic from Aqueous Solution and Acting as Rodenticide
Autorzy:
Al-Jendeel, Haider Abdulkareem
Rasheed, Hala Abdulkareem
Ahmedzeki, Nada Sadoon
Alhassani, Maha Hadi
Powiązania:
https://bibliotekanauki.pl/articles/24201659.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
arsenic
biosorbent
rodenticide
green process
Al-Kheriat
liver enzyme
Opis:
Arsenic is a prevalent and pervasive environmental contaminant with varied amounts in drinking water. Arsenic exposure causes cancer, cardiovascular, liver, nerve, and ophthalmic diseases. The current study aimed to find the best conditions for eliminating arsenic from simulated wastewater and their effect on biomarkers of hepatic in mice. Adsorption tests including pH, contact duration, Al-kheriat dosage, and arsenic concentrations were evaluated. Seventy-two healthy albino mice (male) were accidentally allocated into nine groups (n = 8), the first group was considered as healthy control, the second group (AL-Kheriat), and other groups received AL-Kheriat and arsenic 25, 50, 75, 100, 125, 150 and 175 mg/kg, respectively. Next 10 days, the following were examined: LD50 level, ALP (alkaline phosphatase), ALT (alanine aminotransferase), and AST (aspartate aminotransferase), besides the histological condition of the liver. The results showed that the best time for arsenic removal was 4 hours, pH 8, Alkheriat dose 1 gram, and 50 ppm of pollutants. The level of alkaline phosphatase ALP, alanine transaminase ALT, and aspartate transaminase AST was increased to 150.96 (U/L), 143.1(U/L), and 32.8(U/L), respectively, in Al-Khriet and arsenic exposed population than the healthy control group, When the appropriate dose of Al-Khriet and arsenic mixture is used, it can aid in the selection of a safe way of disposing of the adsorbed residue. Additionally, it can serve as a low-cost rodent pesticide, increasing the commercial viability of this removal strategy.
Źródło:
Journal of Ecological Engineering; 2023, 24, 4; 16--26
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Statistical Analysis of Selected Coal Charateristics and Toxic Compounds for FGX Air-Vibrating Separation
Analiza statystyczna wybranych charakterystyk i składników toksycznych węgla dla procesu separacji w separatorze powietrznym FGX
Autorzy:
Mijał, Waldemar
Niedoba, Tomasz
Polek, Daria
Baic, Ireneusz
Blaschke, Wiesław
Powiązania:
https://bibliotekanauki.pl/articles/27323297.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
dry separation
FGX dry separator
deshaling
statistical analysis
correlation
mercury
arsenic
thallium
calorific value
ash content
separacja sucha
suchy separator FGX
odkamienianie
analiza statystyczna
korelacja
rtęć
arsen
tal
wartość opałowa
zawartość popiołu
Opis:
Dry beneficiation methods were popular in the first part of the 20th century. In the 1930s, before World War II, dry separators were used more commonly in the United States. Currently, this method is very popular in China, the United States, India, Russia and other places where its implementation is possible. In Poland, by contrast, dry separation still remains uncommon. However, during the last 30 years, dry separators have started to be more commonly used in coal beneficiation. One example of this type of separator might be the FGX air-vibrating separator. This type of separator uses air suspension to separate heavier particles (tailings) from lighter coal grains. The process of dry separation may depend on various parameters, e.g. particle size fraction, air supply, feed parameters, etc.. This paper describes the mathematical model which shows the scope for using this separation method for coal beneficiation. Mathematical models are based on dependencies between calorific value and ash content in the samples tested as well as relations between arsenic, thallium, mercury, lead and other coal characteristics. The latter parameters are of vital importance as Polish emission standards do not have any limits for the elements mentioned above (arsenic, thallium, mercury and lead).
Suche metody wzbogacania były popularne w pierwszej połowie XX wieku. Separatory suche były używane zwłaszcza przed II Wojną Światową w latach 30-ych w USA. Obecnie, metoda ta jest bardzo popularna w Chinach, USA, Indiach, Rosji oraz w innych miejscach, gdzie możliwe jest jej zastosowanie. W Polsce proces ten jest wciąż bardzo mało popularny. Podczas ostatnich 30 lat systemy wzbogacania węgla zaczęły szerzej korzystać z separatorów suchych a przykładem bardzo popularnego urządzenia tego typu jest FGX – wibracyjny stół powietrzny. Ten typ separatora korzysta z zawiesiny powietrznej w celu wydzielenia cięższych ziaren (odpadów) od lżejszych ziaren węgla. Sucha separacja może zależeć od różnych parametrów, tj. klasa ziarnowa, zasoby powietrza, parametry nadawy itp. Artykuł ten opisuje model matematyczny, który pokazuje możliwości zastosowania tej metody separacji przy wzbogacaniu węgla. Modele matematyczne oparte były na zależnościach pomiędzy wartością opałową oraz zawartością popiołu w testowanych próbkach, jak również na relacjach pomiędzy zawartościami arsenu, talu, rtęci, ołowiu i innych charakterystyk węgla. Ostatnie parametry są bardzo ważne ponieważ polskie standardy emisji nie zawierają limitów dla pierwiastków wymienionych powyżej, a więc arsenu, talu, rtęci oraz ołowiu.
Źródło:
Inżynieria Mineralna; 2023, 2; 377--387
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ dawnego górnictwa rud polimetalicznych w Czarnowie na wybrane elementy środowiska przyrodniczego w świetle badań geochemicznych
The impact of former mining of polymetallic ore in Czarnów on selected elements of the natural environment in the light of geochemical studies
Autorzy:
Januszewska, Anna
Siuda, Rafał
Dembicz, Iwona
Powiązania:
https://bibliotekanauki.pl/articles/20239682.pdf
Data publikacji:
2023
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
arsen
zanieczyszczenie gleby
metale ciężkie
dawne górnictwo
arsenic
soil contamination
heavy metals
former mining
Opis:
The exploitation of mineral resources can lead to the migration of potentially harmful substances into the natural environment, resulting in environmental degradation and pollution. The mining of polymetallic ores can have severe consequences due to the release of toxic elements such as arsenic (As) and heavy metals. Among the areas contaminated with toxic elements is the village of Czarnów in the Rudawy Janowickie mountains, where mining activities related to copper, arsenic, and gold extraction were likely initiated in the Middle Ages. This study aimed to investigate the geochemical anomalies of arsenic and heavy metals in the soil and their uptake by plants in this region. Portable XRF spectrometry was used to perform geochemical soil analyses in the former mining sites. The results showed clear geochemical anomalies in the arsenic and heavy metal content of soils, with concentrations exceeding permissible standards. The highest concentrations of As were found in the mining dumps, exceeding 100 000 ppm. Phytogeochemical analyses were conducted on raspberry leaves (Rubus idaeus) to determine the content of arsenic, lead, zinc, and copper using the ICP-MS method. The findings indicated that the high levels of individual elements found may pose a risk to the environment. The study demonstrates that even abandoned mining sites can be a source of pollution, and long-term monitoring of these areas is essential to mitigate their potential environmental impact.
Źródło:
Przegląd Geologiczny; 2023, 71, 4; 179-183
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption behaviour of As(III) onto synthetic iron-based minerals: a comparative study of akaganeite, goethite and magnetite
Autorzy:
Ulatowska, Justyna.
Powiązania:
https://bibliotekanauki.pl/articles/2146953.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
iron-based minerals
arsenic
adsorption
FTIR analysis
kinetic study
Opis:
The present study compares the adsorption capacity of iron-based minerals in removing As(III) from aqueous solutions. The work contains the results of studies carried out on a laboratory scale. The synthetic material was used in three forms as akaganeite, goethite and magnetite. To characterise the minerals before and after adsorption of As(III), specific surface area, particle size distribution, density, and zeta potential were determined. Additionally, digital and optical micrographs, SEM, and FTIR analyses were performed. In the experimental part, the influence of the main parameters on the adsorption efficiency was investigated (pH, initial concentration, contact time, and amount of adsorbent). Adsorption isotherms were fitted by Freundlich, Langmuir, and DubininRadushkevich models. Pseudo-first-order (PFO), pseudo-second-order (PSO), and intraparticle diffusion (IPD) models were used to fit the kinetics data. Linear regression was used to estimate the parameters of isotherm and kinetic models. FTIR measurements gave helpful information on the synthesised minerals and the As(III) removal process. Results show that As(III) adsorption is related to the iron-based adsorbents, and adsorption efficiency increases in the following order: goethite < magnetite < akaganeite.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 2; art. no. 144818
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Arsenate removal on the ion exchanger modified with cerium(III) ions
Autorzy:
Dudek, Sebastian
Kołodyńska, Dorota
Powiązania:
https://bibliotekanauki.pl/articles/2146888.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
arsenic
adsorption
cerium
iron oxides
Ferrix A33E
Opis:
The iron oxide ion exchanger Ferrix A33E was successfully modified with cerium(III) ions to obtain Ferrix A33E-Ce(III) providing much better sorption properties in relation to the As(V) species. The new material has been characterized using a number of techniques including scanning electron microscopy SEM, nitrogen adsorption/desorption isotherms, Fourier transform infrared spectroscopy FTIR and X-ray photoelectron spectroscopy XPS. At optimal pH 6 the main mechanism of arsenate adsorption on A33E-Ce(III) was electrostatic attraction and formation of monodentate and bidentate surface complexes. The process was exothermic and spontaneous. Unlike the unmodified ion exchanger, A33E-Ce(III) could completely remove arsenic from the arsenate solution at a concentration of 50 mg/dm3 in 60 minutes. Furthermore, the maximum sorption capacity for As(V) was determined to be 60.41 mg/g which almost doubled after modification with cerium(III) ions. It is also worth noting that even after three cycles of sorption/desorption A33E-Ce(III) exhibited a higher sorption capacity than unmodified A33E before the arsenate adsorption. It can be concluded that modifying the sorbent with a small amount of cerium(III) ions boosts its sorption properties significantly, improves effectiveness of water purification and reduces the overall operation cost
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 2 (Special issue - selected papers conference: Physicochemistry of interfaces - instrumental methods); art. no. 147412
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation of antimony ores with high arsenic content
Autorzy:
Özer, Mustafa
Powiązania:
https://bibliotekanauki.pl/articles/2146881.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
antimony
arsenic
flotation
rougher
clearing
Opis:
Efficient evaluation of antimony ores, which are on the critical raw materials list due to the supply risk by the European Union, is an important necessity. In this context, ore preparation and enrichment processes are very important during the process from ore to metal. Especially for sulfide antimony ores, the most common beneficiation method is flotation. Therefore, antimony ore consisting of stibnite mineral obtained from Tokat-Turkey region was used in this study. Due to the low antimony (5.06%Sb) and the high Arsenic (1.38%As) content, it is an important requirement to increase the Sb content of this ore by flotation, as well as to reduce the As content to certain levels. Stibnite as an antimony mineral and arsenopyrite as arsenic mineral, are minerals that have a sulphurous structure in mineralization and their flotation properties are quite close to each other. Therefore, in this study, it is aimed to selectively separate the bulk concentrate taken from rougher flotation by cleaning steps. A bulk sulfur concentrate with 24.54% Sb and 3.69% As content obtained as a result of the rougher flotation was obtained with a recovery of 98.9%. This product was subjected to 6 stages of cleaning flotation and a concentrate with a content of 63.8% Sb and 0.31% As was produced with an antimony recovery of 83% Sb.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 152865
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Speciation Analysis of Arsenic in Copper Electrolyte Baths Using Liquid-liquid Extraction and ICP-OES Method Detection
Autorzy:
Stefanov, Eduard
Georgieva, Stela
Powiązania:
https://bibliotekanauki.pl/articles/2106573.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
arsenic
speciation analysis
copper electrolyte
iCP-OES method
extraction
Opis:
The present study describes a method for the determination of As (III) and As (V) in copper electrolytes. The method is based on the separation of As (III) from a copper electrolyte by triple liquid-liquid extraction using a non-polar organic solvent in a medium of 10-12 mol L–1 HCl. The extract contains As (III) and the raffinate-As (V), respectively. As(III) specie can be re-extracted from the organic solvent through the water. Analyzes of the concentration of As in the re-extract and raffinate were performed by ICP-OES spectroscopic method. The average recovery of arsenic by the proposed method is about 99%. Repeatability was estimated with RSD (n = 6). Selectivity and accuracy were proven by the standard addition method. The relative error for restoring the standard addition of As (III) is about 0.3%. The speciation method analysis could be applied for determination of the arsenic species in the analytical quality control of refined copper in copper tanks in the production of copper cathodes.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 2; 607--613
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Arsenic in Agricultural Soils of Slovakia
Autorzy:
Kobza, Jozef
Powiązania:
https://bibliotekanauki.pl/articles/2088178.pdf
Data publikacji:
2021
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
arsenic
soil contamination
soil monitoring system
agricultural soils
Slovakia
Opis:
The article presents the current distribution of arsenic in agricultural soils of Slovakia. The current concentration of arsenic (extracted with aqua regia) was measured and evaluated based on 318 monitoring sites of national soil monitoring system in Slovakia. Based on the obtained results, one can state that the average content of arsenic is lower than the valid hygienic limit for arsenic (25 mg.kg-1) for predominated sandy-loamy and loamy soils in Slovakia. Increased values of arsenic were determined only for the Horná – Upper Nitra region (anthropogenic impact) – 24.5 mg.kg-1 and for the Stredný – Central Spiš region (mixed anthrophogenic and geogenic impact) – 129.5 mg.kg-1. These regions belong to the most arsenic-affected regions in Slovakia, where the content of bioavailable forms of arsenic is also increased in the range of 0.013–0.997 mg.kg-1. The hygienic limit for bioavailable arsenic in soils of Slovakia is 0.4 mg.kg-1. Finally, there is a serious risk of arsenic transport from soil into the plants and food chain especially in case of acid soils. A higher risk of As presence seems to be in anthropogenically affected soils.
Źródło:
Polish Journal of Soil Science; 2021, 54, 1; 89-101
0079-2985
Pojawia się w:
Polish Journal of Soil Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Arsenic removal through bio sand filter using different bio-adsorbents
Autorzy:
Keerio, Ghulam S.
Keerio, Hareef A.
Ibuphoto, Khalil A.
Laghari, Mahmood
Panhwar, Sallahuddin
Talpur, Mashooque A.
Powiązania:
https://bibliotekanauki.pl/articles/1844385.pdf
Data publikacji:
2021
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
arsenic
banana peel
bio-adsorbent
bio-sand filter
biochar
rice-husk
water treatment
Opis:
Arsenic is one of the most harmful pollutants in groundwater. In this paper, the Nepali bio sand filter (BSF) was modified with different bio-adsorbents, and proved to be an efficient method for arsenic removal from groundwater. Three different bio-adsorbents were used to modify the Nepali BSF. Iron nails and biochar BSF, ~96% and ~93% arsenic removal was achieved, within the range of WHO guidelines. In iron nails, BSF and biochar BSF ~15 dm3∙h–1 arsenic content water was treated. In the other two BSFs, rice-husk and banana peel were used, the arsenic removal efficiency was ~83% of both BSFs. Furthermore, the efficiency of rice-husk and banana peel BSFs can be increased by increasing the surface area of the adsorbent or by reducing the flow rate.
Źródło:
Journal of Water and Land Development; 2021, 48; 11-15
1429-7426
2083-4535
Pojawia się w:
Journal of Water and Land Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heavy Metals and Arsenic in Soil and Cereal Grains and Potential Human Risk in the Central Region of Peru
Autorzy:
Custodio, María
Peñaloza, Richard
Orellana, Edith
Aguilar-Cáceres, Manuel A.
Maldonado-Oré, Edith M.
Powiązania:
https://bibliotekanauki.pl/articles/1839545.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
soil
cereal
heavy metals
arsenic
human risk
Opis:
The objective of this study was to analyze the content of heavy metals and arsenic in soil and cereal grains as well as to evaluate the possible human risk in the central region of Peru. The soil samples of corn and barley grains were collected from seven agricultural zones and the concentrations of Cu, Fe, Pb, Zn and As were determined with the method of atomic absorption flame spectrophotometry. PERMANOVA showed that the effect of the type of crop and the sampling zone significantly influence the concentrations of heavy metals and As in soil and corn and barley grains (p < 0.05). PCA for heavy metals and As in soil and grain samples of the cereals studied showed that the first two main components represented 81.03% and 94.77% of the total variance, respectively. Hazard Quotient (HQ) for ingestion was the most significant. The HQ values of Pb and As in crop soils indicated that detrimental health effects are unlikely (HQ < 1). The soil hazard index (HI) values of both crops did not exceed the threshold value of 1 (HI < 1). The carcinogenic risk level (CR) of As from ingestion of corn and barley crop soils contaminated by As was higher in children than in farmers and adults. The bioconcentration factor (BCF) of As was higher in barley grains than in corn grains. The THQ of As exceeded the target value of 1 in 100% of the barley and corn sampling sites. The RC of As in grains exceeded the acceptable risk level of 10–6 in all sampling zones.
Źródło:
Journal of Ecological Engineering; 2021, 22, 1; 206-220
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heavy Metals and Arsenic in Water, Sediment and the Muscle of Oncorhynchus Mykiss from the Tishgo River in the Central Andes of Peru
Autorzy:
Condor, Andrés
Custodio, María
Chanamé, Fernán
Cuadrado, Walter
Peñaloza, Richard
Powiązania:
https://bibliotekanauki.pl/articles/1839590.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metals
arsenic
water
sediment
Oncorhynchus mykiss
Tishgo river
Opis:
The concentration of Cu, Pb, Zn and As in water, sediment and muscle of Oncorhynchus mykiss from the Tishgo river in the central Andes of Peru were analyzed. The water, sediment and fish samples were collected from 36 sites in three sampling sectors. The analytical determination was performed by flame atomic absorption spectrophotometry. The mean Pb concentrations in the water from the three sampling sectors showed significant differences (p < 0.05) which exceeded the values of the Peruvian standard and the WHO. The mean concentrations of Cu, Pb and As in sediment did not present significant differences (p > 0.05) in the three sectors evaluated. The redundancy analysis (RDA) revealed that the concentrations of As and Pb in water, and Cu, As and Zn in sediment significantly influence the concentration of these elements in the O. mykiss muscle. The mean concentrations of Cu, Pb, Zn and As in the O. mykiss muscle were lower than those established by international regulations. Therefore, the concentrations of heavy metals and As recorded in this study do not represent a threat to the consumption of O. mykiss from the Tishgo river.
Źródło:
Journal of Ecological Engineering; 2021, 22, 4; 156-166
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Occurrence of Arsenic in Food as a Current Health Concern®
Występowanie arsenu w żywności jako aktualny problem zdrowotny®
Autorzy:
Wierzbicka, Elżbieta
Powiązania:
https://bibliotekanauki.pl/articles/2051144.pdf
Data publikacji:
2021
Wydawca:
Wyższa Szkoła Menedżerska w Warszawie
Tematy:
arsenic
inorganic arsenic
dietary exposure
risk assessment
rice
rice based products
arsen
arsen nieorganiczny
pobranie z dietą
ocena ryzyka
ryż
produkty na bazie ryżu
Opis:
The health-related food quality is determined by, among others, the content of undesirable elements such as arsenic (As). It is a widespread environmental pollutant, naturally occurring in the earth’s crust and as a result of anthropogenic human activities. As is a metalloid that occurs as inorganic (iAs) and organic arsenic species. The inorganic forms of As are more toxic as compared to the organic arsenic. Most As compounds are water soluble, therefore there is also a high possibility of arsenic penetrating from rocks and soil into the hydrosphere, which to some extent also causes its inclusion in the food chain. Contaminated groundwater used for irrigation of crops, in particular rice, is a major source of exposure to iAs. This is especially important for consumers for whom rice is a staple food in their diet. In contrast, fish and other seafood contain the most of less toxic organic arsenic. Diet is the major route of As exposure, and rice and rice-based products are food groups with relatively high iAs levels. Dietary iAs exposure may have long-term effects on health. It is of particular importance to apply the requirements of EU legislation on maximum levels of iAs in rice and ricebased products, as well as to define these requirements in products for infants and young children. Inorganic arsenic contamination levels in food have decreased significantly in European countries over the past years. Current European exposures according to the EFSA Opinion of 2021 show no or little the margin of exposure (MoE) in relation to the lower confidence limit of the benchmark dose (BMDL). Based on this data, the potential health risk by iAs for certain infants and toddlers by the consumption of rice and rice-based products cannot be excluded. Therefore, it is necessary to control iAs levels in certain products, especially in infants and children, and individuals with celiac disease and/or gluten intolerance. As a result, this article presents potential health risks of exposure to arsenic as well as the occurrence and consumption of arsenic in rice and rice-based products, fish, fish products and seafood. Dietary exposure to iAs in light of the scientific opinion of EFSA and regulatory policies concerning As in food is also covered. Additionally, the effect of technological treatment on the reduction of iAs levels in rice is also presented.
O jakości zdrowotnej żywności decyduje między innymi zawartość pierwiastków niepożądanych, takich jak arsen (As). Jest on szeroko rozpowszechnionym zanieczyszczeniem środowiskowym obecnym naturalnie w skorupie ziemskiej oraz na skutek antropogenicznej działalności człowieka. Arsen jest metaloidem występującym zarówno w formie nieorganicznych (iAs), jak i organicznych związków, przy czym formy iAs są bardziej toksyczne dla organizmu niż związki organiczne. Większość związków arsenu jest łatwo rozpuszczalna w wodzie, dlatego też istnieje duża możliwość przenikania arsenu ze skał i gleby do hydrosfery, co w pewnym stopniu powoduje również jego włączenie w łańcuch żywnościowy. Zanieczyszczone wody gruntowe wykorzystywane do nawadniania upraw, w szczególności ryżu, są głównych źródłem narażenia na iAs. Szczególnie ważne jest to w przypadku konsumentów, u których ryż w diecie jest podstawnym produktem. Ryby i inne owoce morza zawierają najwięcej mniej toksycznej formy arsenu. Dieta jest główną drogą narażenia na As, a ryż i produkty ryżowe stanowią grupę żywności o stosunkowo wysokim poziomie i As. Pobranie z dietą iAs może mieć wpływ na zdrowie w dłuższej perspektywie. Szczególne znaczenie ma objęcie wymaganiami w ustawodawstwie UE w zakresie najwyższych dopuszczalnych poziomów iAs w ryżu i produktach na bazie ryżu, jak również określenie tych wymagań w produktach dla niemowląt i małych dzieci. Poziomy za- nieczyszczenia iAs w żywności znacznie się zmniejszyły w krajach eu- ropejskich. Obecne narażenia w Europie według Opinii EFSA z 2021 roku wykazują brak lub niewielkie marginesy w stosunku do dolnej granicy ufności dawki referencyjnej (BMDL). Odnosząc się do tych danych margines narażenia (MoE) jest niewielki lub żaden, w związku z tym nie można wykluczyć możliwości wystąpienia ryzyka zdrowotnego spowodowanego przez iA w przypadku niektórych małych dzieci w wyniku spożycia produktów na bazie ryżu. Dlatego konieczne jest kontrolowanie poziomów iAs w żywności, szczególnie dla niemowląt i małych dzieci oraz osób z celiakią i/lub nietolerancją glutenu. W związku powyższym w niniejszym artykule przedstawiono potencjalne zagrożenia zdrowotne związane z narażeniem organizmu na As, jak również omówiono zawartość i pobranie As głównie z ryżem i produktami na bazie ryżu, rybami, przetworami rybnymi i owocami morza. Przedstawiono również wyniki oszacowania pobrania i As z żywnością w świetle opinii naukowej EFSA oraz regulacje prawne w zakresie maksymalnych dopuszczalnych limitów. Ponadto omówiono wpływ obróbki technologicznej na obniżenie w ryżu poziomu i As
Źródło:
Postępy Techniki Przetwórstwa Spożywczego; 2021, 2; 194-206
0867-793X
2719-3691
Pojawia się w:
Postępy Techniki Przetwórstwa Spożywczego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The content of lead, cadmium, arsenic, mercury and tin in fruit and their products based on monitoring studies – exposure assessment
Autorzy:
Mania, M.
Rebeniak, M.
Chabros, E.
Orshulyak, O.
Postupolski, J.
Powiązania:
https://bibliotekanauki.pl/articles/2082840.pdf
Data publikacji:
2021
Wydawca:
Narodowy Instytut Zdrowia Publicznego. Państwowy Zakład Higieny
Tematy:
food
fruit
monitoring
lead
cadmium
mercury
arsenic
tin
exposure assessment
Opis:
Background. Fruit and fruit products are important part of our daily diet. In addition to the ingredients necessary for the proper functioning of the body, these products can also be a source of intake elements harmful to human health. Objective. Analysis of the results of monitoring studies conducted in Poland in 2015 concerning contamination of lead (Pb), cadmium (Cd), arsenic (As), mercury (Hg) and tin (Sn) in fruit and fruit products and exposure assessment. Material and methods. Approximately 600 samples of fresh, frozen, dried fruits, fruit preserves and canned fruits were tested. The laboratories of State Sanitary Inspection were involved in testing. Accredited and validated analytical methods were used. The test samples were prepared in accordance with the standard PN-EN 13804:2013. The contents of lead, cadmium and tin were determined by using flame atomic absorption spectrometry (FAAS) or flameless with electrothermal atomization spectrometry (GFAAS); arsenic by using hydride generation atomic absorption spectrometry method (HGAAS) and mercury the "cold vapor" atomic absorption spectrometry (CVAAS) method. Results. Contamination of investigated samples with elements harmful to human health (Pb, Ca, As, Hg and Sn does not rise concern to human health and was in most cases comparable with contamination reported in other European Union countries. The estimated average exposure of adults and children to lead intake with fruit and fruit products ranged from 0.5% to 14.6% of the respective Benchmark Dose Lower Confidence Limit (BMDL) established by the European Food Safety Authority (EFSA). The mean intake of cadmium with these groups of foodstuffs was in the range 0.3 - 8.5% of the TWI value (Tolerable Weekly Intake) established by EFSA for adults and children (0.1 - 3.6% of the PTMI (Provisional Tolerable Monthly Intake) established by JECFA. In case of arsenic mean intake was in the range 0.5 - 1.6% BMDL whilst for mercury (inorganic form) intake represented 0.5 - 1.4% of TWI value established by JECFA and then confirmed by EFSA. Conclusions. Based on the obtained results, it was found that content of Pb, Cd, As, Hg and Sn in the tested samples of fruit and their products does not pose a risk to consumer health. Estimated exposure of consumers does not exceed tolerable doses established by EFSA and JECFA for these elements.
Źródło:
Roczniki Państwowego Zakładu Higieny; 2021, 72, 4; 353-360
0035-7715
Pojawia się w:
Roczniki Państwowego Zakładu Higieny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
« Il faut prescrire l’usage de la viande en petite quantité, comme on prescrit l’arsenic » Josephine Joteyko et Varia Kipiani: la recherche médicale pionnière en faveur du végétarisme en 1906
„Meat Should Be Prescribed in Very Small Doses, Arsenic-like”. How Josephine Joteyko and Varia Kipiani Pioneered Medical Research to Improve Vegetarianism in 1906
Autorzy:
Joteyko, Josephine
Kipiani, Varia
Nowak, Ewa
Löwy, Ilana
Powiązania:
https://bibliotekanauki.pl/articles/1067924.pdf
Data publikacji:
2020-12-30
Wydawca:
Uniwersytet im. Adama Mickiewicza w Poznaniu
Tematy:
Josephine Joteyko
Varia Kipiani
physiology of vegetarianism
experimental questionnaire with 43 vegetarians
pioneering medical research on vegetarian diet
meat on prescription to be consumed arsenic-like
Brussels 1906
history of medicine
the modernist utopias of labor and efficiency
Opis:
This compilation is based on the original report on a clinical survey conducted in Brussels (1905-1906) by Josephine Joteyko and Varia Kipiani with 43 vegetarians. Having advanced expertise in physiology and experimentalism, Joteyko (with Lithuanian and Polish origins) and Kipiani (with Georgian origins) discussed their findings at the Congress of the Belgian Society for Vegetarianism in 1906. For both children and adults, females and males, regardless of age, the findings demonstrated vegetarian dietary habits to be beneficiary for human development, the subjects’ physical and mental health, welfare, and physical and intellectual efficiency. Surprisingly, Joteyko and Kipiani confirmed C. Darwin’s observation across various nutritional cultures that vegetarian food would increase the energetic balance of the human body. Additionally, their focus on the moteur humain shows affinities with Taylorism, the modernist utopias of labor, the enhancement of human faculties, the protection of workers and their rights from automation, and applied social science represented by Joteyko and Kipiani as multidisciplinary investigators. The compilation was made on: J. Joteyko & V. Kipiani, Enquête scientifique sur les Végétariens de Bruxelles, Conférence donnée à la Société végétarienne de Belgique, le 4 décembre 1906, pp. 1–77, with no further correction.
Źródło:
Ethics in Progress; 2020, 11, 2; 80-87
2084-9257
Pojawia się w:
Ethics in Progress
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Aktywność mikrobiologiczna i biochemiczna pod sadzonkami klonu zwyczajnego oraz lipy drobnolistnej rosnącymi na osadzie pogórniczym silnie zanieczyszczonym pierwiastkami śladowymi
Microbiological and biochemical activity under Norway maple and small-leaved lime seedlings growing on post-mining sediment with high trace elements contamination
Autorzy:
Mocek-Płóciniak, A.
Mleczek, M.
Skowrońska, M.
Powiązania:
https://bibliotekanauki.pl/articles/979207.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Leśne
Tematy:
lesnictwo
klon pospolity
Acer platanoides
lipa drobnolistna
Tilia cordata
badania wazonowe
zanieczyszczenia gleb
arsen
mikroorganizmy glebowe
aktywnosc enzymatyczna
leśnictwo
tereny pogrónicze
rekultywacja leśna
osady pogórnicze
pierwiastki składowe
aktywność mikrobiologiczna
aktywność biochemiczna
arsenic
heavy metals
post−mining sediment
microorganisms
enzymatic activity
Opis:
The aim of the study was to determine the abundance of soil microbiome and enzymatic activity in a control soil sample and in samples with post−mining sediment containing high concentrations of arsenic and some trace elements. The samples were collected under two−year−old seedlings of Norway maple (Acer plantanoides L.) and small−leaved lime (Tilia cordata Mill.), which came from the Pniewy Forest District (western Poland). Optical emission spectrometry with excitation in plasma induced by the Agilent 5110 ICP−OES spectrometer was applied to analyse the concentration of arsenic and other heavy metals in the substrates and plant material. Before analysis the samples were mineralised with concentrated (65%) nitric acid (V). The count of selected groups of soil microorganisms was measured with the serial dilution method by Koch. The microbiome was measured on selective media. The activity of dehydrogenases as well as acid and alkaline phosphatase was measured spectrophotometrically. The soil and sediment on which the seedlings grew were characterised by the following physicochemical parameters: soil texture (control – loamy sand, sediment – silt), pH (control – 5.85−5.92, sediment – 7.13−7.43), the content of phosphorus (control – 117−121 mg/kg, sediment – 38−46 mg/kg), potassium (control – 6.97−7.03 mg/kg, sediment – 57−61 mg/kg), nitrogen (control – 0.53−0.65 mg/kg, sediment – 1.7−2.1 mg/kg) and total carbon (control – 9.4−10.2 g/kg, sediment – 54.2−57.2 g/kg). The samples contained: control – 0.24 mg/kg, sediment – 282 mg/kg of Astotal, control – below the detection limit, sediment – 1,766 and 16,220 mg/kg of As(III) and (V) respectively. The counts of the microorganisms were lower (103−105) than in typical arable soils (105−109). The counts of bacteria and actinobacteria under the lime seedlings in the control were greater than in the sediment, whereas the counts of moulds were roughly identical. The counts of bacteria and moulds in the sediments under the maple seedlings were greater than in the control, whereas the counts of actinobacteria were roughly identical. The sediments under both species exhibited higher alkaline and acid phosphatase activity than the control soil sample. Only dehydrogenases exhibited higher activity in the control soil under both tree seedlings.
Źródło:
Sylwan; 2020, 164, 02; 127-132
0039-7660
Pojawia się w:
Sylwan
Dostawca treści:
Biblioteka Nauki
Artykuł
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