- Tytuł:
- Kinetic Study on the Preparation of Aluminum Fluoride Based on Fluosilicic Acid
- Autorzy:
-
Chen, Gaoxiang
Yang, Xingdong
Qu, Jiyan
Luo, Jianhong
Zhang, Zhiye
Sun, Lan - Powiązania:
- https://bibliotekanauki.pl/articles/1849322.pdf
- Data publikacji:
- 2021
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
kinetic study
fluosilicic acid
aluminum fluoride
uncreated-core model - Opis:
- Reasonable mathematical derivation and mechanism model in the process of producing aluminum fluoride by fluosilicic acid is the key to the industrial treatment of fluorine resources in the tail gas of phosphate ore. In this work, aluminum fluoride was generated directly by fluosilicic acid to extract fl uorine from the tail gas of phosphate rock. The uncreated-core model dominated by interfacial reaction and the uncreated-core model dominated by internal diffusion-reaction were then respectively utilized to describe the reaction kinetics of the generation of aluminum fluoride. The result showed that the uncreated-core model was dominated by interface reaction and internal diffusion, the apparent reaction order n = 1, and the activation energy Ea = 30.8632 kJ . mol–1. Product characterization and kinetic analysis were employed to deduce the reaction mechanism of preparing aluminum fluoride. The theoretical basis for the low-cost recycling of fluorine resources in the tail gas of industrial phosphate ore was provided in this work.
- Źródło:
-
Polish Journal of Chemical Technology; 2021, 23, 3; 10-16
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki