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Wyświetlanie 1-15 z 93
Tytuł:
Process simulation of dimethyl ether synthesis via methanol vapor phase dehydration
Autorzy:
Bai, Z.
Ma, H.
Zhang, H.
Ying, W.
Fang, D.
Powiązania:
https://bibliotekanauki.pl/articles/779378.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
dimethyl ether
methanol dehydration to DME
process simulation
Opis:
The production processes included catalytic dehydration of methanol in an adiabatic fixed-bed reactor and two columns product separations. In this study, the technological process for dimethyl ether (DME) synthesis is built on PRO/II platform based on the combined parameters of the reaction dynamic model for methanol dehydration reaction, the improved NRTL model of the liquid phase, the PR model of vapor phase. In order to validate the proposed model, the simulation results have been compared with the available data from a set of industrial production equipment with a production capacity of 200 000 tonnes per annum. A comparison between the calculated and measured results has proved that these results are satisfactory. The bed height and the volume of the catalytic bed are calculated aim at one million t/a DME yields and while taking account of high-purity DME production. After discussing the influence of feed stage location and reflux ratio for DME product purity, the suitable unit operation conditions are chosen. Accordingly, accurate process simulation results provide the basis and guidance for an improvement and development of the similar industrial device.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 2; 122-127
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Focusing of linearly polarized helico-conical Lorentz beam with sine-azimuthal variation wavefront
Autorzy:
Bao, Y.
Lan, J.
Miao, Y.
Zhang, D.
Gao, X.
Powiązania:
https://bibliotekanauki.pl/articles/174305.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Lorentz beam
focusing properties
optical vortex
Opis:
In this article a theoretical research is described into focusing of a linearly polarized helico-conical Lorentz beam with a sine-azimuthal variation wavefront. The simulation results show the vortex charge on the axis, which has an obvious modulation effect on the focal modes of the Lorenz beam under certain beam parameters and phase parameters. Both the phase parameter and the vortex charge are zero, the focal spot appears round. The focal spot is symmetric about y axis when the charge is 0 and the phase parameter is adjusted. And the focal evolution patterns vary remarkably under different beam parameters and the phase parameters. In the process of focus evolution, there appears some novel focal patterns, such as a circle, a “T”, a butterfly, a small running humanoid, a whale tail, a flower of four leaves, a serpentine, a goldfish, a Chinese knot and an octopus, which indicates that the focus mode of the optical vortex Lorentz beam can be altered by changing the phase parameters and vortex charge.
Źródło:
Optica Applicata; 2018, 48, 3; 373-387
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Image compression-encryption algorithm combining compressive sensing with log operation
Autorzy:
Chen, R.-L.
Zhou, Y.
Luo, M.
Zhang, A.-D.
Gong, L.-H.
Powiązania:
https://bibliotekanauki.pl/articles/174009.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
image encryption
image compression
compressive sensing
log operation
Opis:
Based on compressive sensing and log operation, a new image compression-encryption algorithm is proposed, which accomplishes encryption and compression simultaneously. The proposed image compression-encryption algorithm takes advantage of not only the physical realizability of partial Hadamard matrix, but also the resistance of the chosen-plaintext attack since all the elements in the partial Hadamard matrix are 1, –1 or log 1 = 0. The proposed algorithm is sensitive to the key and it can resist various common attacks. The simulation results verify the validity and reliability of the proposed image compression-encryption algorithm.
Źródło:
Optica Applicata; 2018, 48, 4; 563-573
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dynamic response of a base-isolated concrete rectangular liquid-storage structure under large amplitude sloshing
Dynamiczna odpowiedź prostokątnej struktury magazynowania substancji ciekłych z wykorzystaniem betonu izolacyjnego
Autorzy:
Cheng, X.
Li, D.
Li, P.
Zhang, X.
Li, G.
Powiązania:
https://bibliotekanauki.pl/articles/230249.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
chlupotanie cieczy
amplituda duża
trzęsienie ziemi
struktura prostokątna
substancja ciekła
magazynowanie
nieliniowość
odpowiedź dynamiczna
liquid sloshing
large amplitude
earthquake
rectangular structure
liquid substance
storage
nonlinearity
dynamic response
Opis:
Considering concrete nonlinearity, the wave height limit between small and large amplitude sloshing is defined based on the Bernoulli equation. Based on Navier-Stokes equations, the mathematical model of large amplitude sloshing is established for a Concrete Rectangle Liquid-Storage Structure (CRLSS). The results show that the seismic response of a CRLSS increases with the increase of seismic intensity. Under different seismic fortification intensities, the change in trend of wave height, wallboard displacement, and stress are the same, but the amplitudes are not. The areas of stress concentration appear mainly at the connections between the wallboards, and the connections between the wallboard and the bottom.
Gdy amplituda chlupotania cieczy jest zbliżona do częstotliwości drgań struktury magazynowania substancji ciekłych (CRLSS), wówczas osiągamy rezonans i możemy zaobserwować silne zjawisko nieliniowe. Szkoda jest znacznie większa niż chlupotanie o małej amplitudzie. Obecnie brak jest odpowiedniego raportu na temat badań dynamicznej odpowiedzi struktury magazynowania substancji ciekłych z wykorzystaniem betonu izolacyjnego (CRLSS) z chlupotaniem o dużej amplitudzie, a wpływ materiałów betonowych nie jest brany pod uwagę. W związku z tym, w niniejszej pracy, w oparciu o równanie Bernoulliego, otrzymano ograniczone wysokości fali o dużej amplitudzie chlupotania oraz małej amplitudzie chlupotania. Na podstawie równań Naviera-Stokesa ustanowiono matematyczny model chlupotania o dużej amplitudzie i zbadano odpowiedź sejsmiczną CRLSS podczas chlupotania o dużej amplitudzie. Rozważając równanie Bernoulliego i zadowalający stan, chlupotanie substancji ciekłej jest liniowe, a nieliniowy kwadratowy człon jest lekceważony. W stałym i płynnym interfejsie, struktura magazynowania substancji ciekłych spełnia warunki ciągłości przemieszczania i równowagi siły oddziaływań. Właściwość mechaniczna gumowego zabezpieczenia izolacyjnego została opisana w oparciu o konstytutywną relacje modelu Mooney-Rivlin.
Źródło:
Archives of Civil Engineering; 2017, 63, 1; 33-45
1230-2945
Pojawia się w:
Archives of Civil Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Identification of a linear epitope in the capsid protein of goose astrovirus with monoclonal antibody
Autorzy:
Dai, G.
Huang, X.
Liu, Q.
Li, Y.
Zhang, L.
Han, K.
Yang, J.
Liu, Y.
Xue, F.
Zhao, D.
Powiązania:
https://bibliotekanauki.pl/articles/16647377.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
epitope
goose astrovirus
capsid protein
monoclonal antibody
Opis:
Goose astrovirus (GoAstV) is a novel avastrovirus that typically causes gosling gout and results in 2 to 20% mortality. GoAstV capsid protein is the sole structural protein, which is responsible for viral attachment, assembly, maturation as well as eliciting host antibodies. However, the epitopes within capsid protein have not been well studied. In this study, a monoclonal antibody, named 1D7, was generated against GoAstV capsid protein by hybridoma technology. Western blot results showed that this MAb could react with recombinant capsid protein expressed in E. coli. Also, it recognized the precursor of capsid protein, VP90 and VP70, in GoAstV-infected cells. Besides, excellent specificity of MAb 1D7 was further demonstrated in indirect immunofluorescence assay and immunohistochemical analysis. Epitope mapping results revealed that MAb 1D7 recognized the epitope 33QKVY 36 within Cap protein. Sequence alignment indicated that 33QKVY 36 is a conserved epitope among the isolates of goose astrovirus type 2 (GoAstV-2), suggesting the potential for its use in GoAstV-2 specific diagnostic assay. These findings may provide some insight into a function of the GoAstV capsid protein and further contribute to the development of diagnostic methods for GoAstV infection.
Źródło:
Polish Journal of Veterinary Sciences; 2022, 25, 4; 579-587
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Research on Characterization of Crushability for Foundry Sand Particles
Autorzy:
Dai, Y.
Ma, Q. Y.
Li, X. H.
Zhang, X.
Hu, F. P.
Zhang, Y.
Xie, W. D.
Powiązania:
https://bibliotekanauki.pl/articles/379689.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
foundry sand particle
mechanical load
AFS grain fineness
crushability
piasek odlewniczy
obciążenie mechaniczne
rozdrobnienie ziarna
Opis:
In this paper, crushability of foundry sand particles was studied. Three kinds of in-service silica sands in foundry enterprises selected as the study object, and foundry sand particles were subjected to mechanical load and thermal load during service were analyzed. A set of methods for simulating mechanical load and thermal load by milling and thermal-cold cycling were designed and researched, which were used to characterize the crushability for silica sand particles, the microstructure was observed by SEM. According to the user’s experience in actual application, the crushability of Sand C was the best and then Sand B, the last Sand A. The results indicated that mechanical load, thermal load and thermal-mechanical load can all be used to characterize the crushability of foundry sand particles. Microscopic appearances can qualitatively characterize the crushability of foundry sand particles to a certain extent, combining with the additions and cracks which are observed on the surface.
Źródło:
Archives of Foundry Engineering; 2017, 17, 4; 231-235
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Numerical Simulation of Dynamic Pressure and Displacement for the Top Part of Men’s Socks Using the Finite Element Method
Numeryczna symulacja ciśnienia dynamicznego i przesunięć w górnej części skarpet męskich
Autorzy:
Dan, R.
Dan, M. H.
Fan, X. R.
Chen, D. S.
Shi, Z.
Zhang, M.
Xu, L. B.
Powiązania:
https://bibliotekanauki.pl/articles/234002.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
top part of socks
pressure
displacement
finite element
dynamic
górna część skarpetki
ciśnienie
przemieszczenie
elementy skończone
dynamika
Opis:
Numerical simulation of elastic human body deformation and dynamic pressure and displacement distribution are critical for pressure comfort and optimal design of apparel products. This paper demonstrates an analytical method for simulating dynamic pressure and displacement at the top part of men’s socks using the finite element method (FEM). The dynamic pressure is divided into two parts: the first is pressure with time, and the second is pressure with walking. Pressure with time is set at six periods (maximum 12 h). After measuring pressure values in different periods of time and simulating pressure and displacement distribution using ANSYS software, the tendency of pressure and displacement changes with time at the top part of men’s socks can be obtained. We divided the walking process into four phases to analyse the variation rule of pressure and displacement changes with movement in this research work. Meanwhile the lower leg cross section is divided into four equal regions according to the angle, and dynamic changes in the area shrinkage mass of each region can be calculated, respectively. All these solutions provide a theoretical reference for the optimal design of the top part of men’s socks.
Numeryczna symulacja elastycznej deformacji ciała ludzkiego, dynamicznego ciśnienia i rozkładu przesunięć są krytycznymi czynnikami komfortu i optymalnych rozwiązań ciśnieniowych wyrobów odzieżowych. Przedstawiono analityczną metodę symulacji ciśnień dynamicznych i przesunięć w górnej części męskich skarpet stosując metodę elementów skończonych. Analizę ciśnień dynamicznych przeprowadzono rozpatrując dwa stadia: zmiany ciśnienia w czasie i zmiany przy ruchu związane z chodzeniem. Na podstawie pomiarów ciśnienia i odkształcenia w określonych przedziałach czasowych określono rozkład odkształceń stosując program ANSYS. Proces chodzenia podzielono na cztery fazy. Wszystkie przeprowadzone badania i rozwiązania dostarczyły informacji dla przedstawienia optymalnego sposobu projektowania męskich skarpet.
Źródło:
Fibres & Textiles in Eastern Europe; 2013, 4 (100); 112-117
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preliminary results on direct photon-photon HBT measurements in square root sNN = 62.4 GeV and 200 GeV Au+Au collisions at RHIC
Autorzy:
Das, D.
Lin, G.
Chattopadhyay, S.
Chikanian, A.
Finch, E.
Nayak, T.
Panitkin, S.
Sandweiss, J.
Suaide, A.
Zhang, H.
Powiązania:
https://bibliotekanauki.pl/articles/148364.pdf
Data publikacji:
2006
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
RHIC
HBT
interferometry
TPC
BEMC
photon
Opis:
We present the preliminary results on direct photon interferometry measurements in Au+Au collisions at square root sNN = 62.4 GeV and 200 GeV using the STAR (solenoidal tracker at RHIC) detector. Photons are reconstructed via e+/e- conversions in STAR Time Projection Chamber (TPC) and energy deposited by photons in STAR Barrel Electromagnetic Calorimeter (BEMC). The two-photon correlations are measured using (1) both photons measured with BEMC; (2) one photon from conversions and the other measured with BEMC. Both the methodologies and the possible constraints in the correlation function measurements are discussed.
Źródło:
Nukleonika; 2006, 51,suppl.3; 55-58
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An improved resonant thermal converter based on micro-bridge resonator
Autorzy:
Dong, L.
Han, J.
Zhang, P.
Zhao, Z.
Cheng, B.
Han, D.
Powiązania:
https://bibliotekanauki.pl/articles/220878.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
thermoelectric transfer difference
micro-bridge resonator
thermal converter
bifilar heater
Opis:
This paper presents the design, fabrication and testing of an improved thin-film thermal converter based on an electro-thermally excited and piezo-resistively detected micro-bridge resonator. The resonant thermal converter comprises a bifilar heater and an opposing micro-bridge resonator. When the micro-bridge resonator absorbs the radiant heat from the heater, its axial strain changes, then its resonant frequency follows. Therefore the alternating voltage or current can be transferred to the equivalent DC quantity. A non-contact temperature sensing mechanism eliminates heat loss from thermopiles and reduces coupling capacitance between the temperature sensor and the heater compared with traditional thin-film thermal converters based on thermopiles. In addition, the quasi-digital output of the resonant thin-film thermal converter eliminates such problems as intensity fluctuations associated with analogue signals output by traditional thin-film thermal converters. Using the fast-reversed DC (FRDC) method, the thermoelectric transfer difference, which determines the frequency-independent part of the ac-dc transfer difference, is evaluated to be as low as 1.1 · 10-6. It indicates that the non-contact temperature sensing mechanism is a feasible method to develop a high-performance thermal converter.
Źródło:
Metrology and Measurement Systems; 2018, 25, 4; 715-725
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Morphology and developmental traits of the trilobite Changaspis elongata from the Cambrian Series 2 of Guizhou, South China
Autorzy:
Du, G.-Y.
Peng, J.
Wang, D.-Z.
Wang, Q.-J.
Wang, Y.-F.
Zhang, H.
Powiązania:
https://bibliotekanauki.pl/articles/22906.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Opis:
The morphology and ontogeny of the trilobite Changaspis elongata based on 216 specimens collected from the Lazizhai section of the Balang Formation (Stage 4, Series 2 of the Cambrian) in Guizhou Province, South China are described. The relatively continuous ontogenetic series reveals morphological changes, and shows that the species has seventeen thoracic segments in the holaspid period, instead of the sixteen as previously suggested. The development of the pygidial segments shows that their number gradually decreases during ontogeny. A new dataset of well-preserved specimens offers a unique opportunity to investigate developmental traits after segment addition is completed. The ontogenetic size progressions for the lengths of cephalon and trunk show overall compliance with Dyar’s rule. As a result of different average growth rates for the lengths of cephalon, trunk and pygidium, the length of the thorax relative to the body shows a gradually increasing trend; however, the cephalon and pygidium follow the opposite trend. Morphometric analysis across fourteen post-embryonic stages reveals growth gradients with increasing values for each thoracic segment from anterior to posterior. The reconstruction of the development traits shows visualization of the changes in relative growth and segmentation for the different body parts. The new dataset and growth gradient of the trunk suggest that the thoracic segment growth dynamics of early Cambrian to Silurian trilobites follow the same general continuous, steady-state growth gradient decreasing from posterior to anterior.
Źródło:
Acta Palaeontologica Polonica; 2019, 64, 4
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A New Potential Superhard Phase of $OsN_2$
Autorzy:
Fan, Q.
Wei, Q.
Yan, H.
Zhang, M.
Zhang, D.
Zhang, J.
Powiązania:
https://bibliotekanauki.pl/articles/1205218.pdf
Data publikacji:
2014-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
62.20.de
65.40.-b
62.20.dq
Opis:
A new phase of C2/m $OsN_2$ is proposed in this paper. The crystal structure, elasticity and electronic properties of C2/m $OsN_2$ were studied by first-principles calculations. The elastic constants, the elastic moduli (B, G, and E) and Poisson's ratio v of $OsN_2$ have been investigated. From the first-principles calculations, we find that C2/m $OsN_2$ is metallic and mechanically stable. The quasi-harmonic Debye model, using a set of total energy versus molar volume obtained from the first-principles calculations, is applied to the study of the thermal and vibrational effects. The dependence of structural parameters, thermal expansions, heat capacities, Grüneisen parameters and Debye temperatures on the temperature and pressure are obtained in the whole pressure range from 0 to 80 GPa and temperature range from 0 to 800 K as well as compared with available data.
Źródło:
Acta Physica Polonica A; 2014, 126, 3; 740-746
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Soft anatomy of the Early Cambrian arthropod Isoxys curvirostratus from the Chengjiang biota of South China with a discussion on the origination of great appendages
Autorzy:
Fu, D.-J.
Zhang, X.-L.
Shu, D.-G.
Powiązania:
https://bibliotekanauki.pl/articles/22449.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Opis:
An updated reconstruction of the body plan, functional morphology and lifestyle of the arthropod Isoxys curvirostratusis proposed, based on new fossil specimens with preserved soft anatomy found in several localities of the Lower Cambrian Chengjiang Lagerstätte. The animal was 2–4 cm long and mostly encased in a single carapace which is folded dorsally without an articulated hinge. The attachment of the body to the exoskeleton was probably cephalic and apparently lacked any well−developed adductor muscle system. Large stalked eyes with the eye sphere consisting of two layers (as corneal and rhabdomeric structures) protrude beyond the anterior margin of the carapace. This feature, together with a pair of frontal appendages with five podomeres that each bear a stout spiny outgrowth, suggests it was raptorial. The following 14 pairs of limbs are biramous and uniform in shape. The slim endopod is composed of more than 7 podomeres without terminal claw and the paddle shaped exopod is fringed with at least 17 imbricated gill lamellae along its posterior margin. The design of exopod in association with the inner vascular (respiratory) surface of the carapace indicates I. curvirostratus was an active swimmer. Morphological comparisons demonstrate that species of Isoxys were diverse in feeding habits and occupied a very broad morphospace, i.e., carapace bivalved or a single shield, the pre−oral limbs antenniform or modified into great appendages, the succeeding endopods slim or stout. This casts doubt on the current taxonomy that assigns all species to a single genus, and on any presumed lifestyle of Isoxys extrapolated to the generic level. Finally, since I. curvirostratus and I. acutangulus carry a pair of great appendages, Isoxys has recently been placed into the great appendage arthropods. Such placement might be inadequate because the homology of the great appendages can not be established.
Źródło:
Acta Palaeontologica Polonica; 2011, 56, 4
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Focus shaping of the radially polarized Bessel–Gauss beam with a sine-azimuthal variation wavefront
Autorzy:
Gao, X
Zhang, D.
Mei, T.
Fu, R.
Zhuang, S.
Powiązania:
https://bibliotekanauki.pl/articles/174283.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Bessel-Gauss beam
wavefront modulation
vector diffraction theory
Opis:
Focusing properties of the radially polarized Bessel–Gauss beam with a sine-azimuthal variation wavefront was investigated by the vector diffraction theory. The wavefront distribution is the sine function of the azimuthal angle with one phase parameter that indicates the phase change frequency. Results show that the focal pattern can be altered by the phase parameter, and many novel focal patterns may occur, such as multiple dark-foci focal pattern, crescent shape, and wheel shape. For case of a higher phase beam, the whole focal pattern turns on a symmetric wheel shape with multiple reduplicate intensity elements. When the phase parameter is an odd number, the number of reduplicate elements equals the phase parameter, while when the phase parameter is an even number, the number of reduplicate elements is two times the phase parameter. In addition, the effect of the phase parameter on the focal pattern is more considerable than that of the beam parameter under low numerical aperture. Under higher numerical aperture, the effect of the beam parameter on the focal pattern gets stronger.
Źródło:
Optica Applicata; 2013, 43, 3; 567-582
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
UV-Vis spectroscopic detection coupled with chemometrics for the measurement of mixed organic acids in water samples enriched by radial electric focusing solid phase extraction
Autorzy:
Guo, Y.
Liu, X.
Liu, J.
Bian, X.
Zhang, Q.
Pan, J.
Wan, D.
Powiązania:
https://bibliotekanauki.pl/articles/221808.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
chemometrics
UV-Vis spectrophotometer
radial electric focusing solid phase extraction
mixed organic acids
Opis:
Due to the difficulty of detecting traces of organic acid mixture in an aqueous sample and the complexity of resolving UV-Vis spectra effectively, a combinatory method based on a self-made radical electric focusing solid phase extraction (REFSPE) device, UV-Vis detection and partial least squares (PLS) calculation is proposed here. In this study, REFSPE was used to enhance the extraction process of analytes between the aqueous phase and the membrane phase to enrich the trace of mixed organic acid efficiently. Then, the analytes, which were eluted from the adsorption film by ethanol with the assistance of an ultrasonic cleaning machine, were detected with UV-Vis spectrophotometry. After that, the PLS method was introduced to solve the problem of overlapping peaks in UV-Vis spectra of mixed substances and to quantify each compound. The linearly dependent coefficients between the predicted value of the model and the actual concentration of the sample were all higher than 0.99. The limit values of detection for benzoic acid, phthalic acid and p-toluene sulfonic acid were found at 9.9 μg/L, 12.2 μg/L and 13.8 μg/L with the relative recovery values between 84.8% and 117.9%. The RSD (n = 20) values of each component are 1.17%, 1.11% and 0.86%, respectively. Therefore, the proposed combined method can determine traces of complex materials in an aqueous sample efficiently and has wonderful potential applications.
Źródło:
Metrology and Measurement Systems; 2018, 25, 2; 317-329
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
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