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Tytuł:
Study of the characteristics about insulation damage based on the accelerated life tests
Badanie charakterystyk uszkodzeń izolacji w oparciu o testy przyspieszonego starzenia
Autorzy:
Yang, Y. H.
Wang, K.-S.
Powiązania:
https://bibliotekanauki.pl/articles/300857.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Polskie Naukowo-Techniczne Towarzystwo Eksploatacyjne PAN
Tematy:
accelerated life testing
competing failure mode
insulation degradation
Gompertz-type relation shape parameter
Opis:
In this study the Maximum Likelihood Estimator is taken to identify the characteristics of insulation failure about the class-H motors by considering the accelerated life testing data under censored situation from Nelson. Based on the Weibull survival modeling the failure is expressed as the series connection of three modes, namely the turn, phase, and ground, respectively, the so-called competing failure. The main concern in present investigation is about the variation of shape parameters, β with the temperature. The Gompertz-type relation of βi(T) is suggested with the reference temperature, Tri for the i-th failure mode. It is found that the Tri ’s not only distinguish the characteristics of cumulative damage process about the insulation, but also involve the estimation of mean-time-to-failure (MTTF). Physically Tri denotes the turning point of varied βi as the i-th failure mode becomes moderate in a sense of less capability about the accumulation of insulation damage at higher temperature where corresponds the thermal degradation process. The numerical results indicate that the insulation technique used is acceptable as the operation temperature kept in the use condition 363K. According to the predicted lifetime as the temperature rises up to 440K, which still within the allowed range in application, the turn structure needs to be rearranged primarily, then the phase next. The ground mode has only influence on the failure at much higher temperature.
Źródło:
Eksploatacja i Niezawodność; 2013, 15, 4; 325-331
1507-2711
Pojawia się w:
Eksploatacja i Niezawodność
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Piecewise reliability-dependent hazard rate for composites under fatigue loading adjustment
Konstrukcja funkcji ryzyka uszkodzeń kawałkami zależnej od niezawodności dla kompozytów poddanych różnym scenariuszom obciążenia zmęczeniowego
Autorzy:
Chen, C.-L.
Wang, K.-S.
Powiązania:
https://bibliotekanauki.pl/articles/281955.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
fatigue loading adjustment
hazard rate function
dynamical reliability
Monte Carlo simulation
linear damage sum
Opis:
Based on the derived transition period and reliability drop, this paper proposes a method of piecewise combination of the reliability-dependent hazard rate function named (eocp) model to describe the dynamical reliability in a two-stage fatigue loading process. First, the parameters eo, c, p are fitted through simulated failure data under various constant- amplitude cyclic stresses. The reliability of the high-low loading process is described piecewise with the corresponding values of (eo, c, p) for each respective stress level, and maintains Ra in the transition period while Ra denotes the reliability at which the stress level changes. The reliability of the low-high process is determined by subtracting the portion of reliability drop at Ra from the piecewise fitted curves. The proposed reliability behavior is verified successfully. The linear damage sum is found to be larger than unity for the high-low loading, and on the contrary for the low-high cases. A larger difference between the stress level changed results in larger deviation of damage sum from unity, especially when Ra near 0.9.
W oparciu o wyznaczony okres przejściowy i spadek niezawodności, artykuł prezentuje metodę określania funkcji ryzyka uszkodzenia kawałkami zależnej od poziomu niezawodności, zwanej (eocp) i służącej do modelowania dynamicznej niezawodności dla dwustanowych procesów obciążania zmęczeniowego. Na poczatku, parametry eo, c, i p dopasowano do danych otrzymanych w drodze symulacji uszkodzeń pod wpływem działania cyklicznych naprężeń o kilku stałych amplitudach. Niezawodność dla obciążeń przechodzących od dużej amplitudy do małej opisano kawałkami zależnymi od poziomu przykładanych naprężeń i odpowiadającymi im wartościami eo, c, i p. Wynosi ona Ra w okresie przejściowym, gdzie Ra jest niezawodnością, przy której poziom naprężeń jest zmieniany. Niezawodność przy obciążeniu rosnącym wyznaczono, odejmując część jej spadku przy Ra od kawałkami dopasowanych krzywych. Zaproponowany sposób opisu niezawodności sukcesywnie weryfikowano. Zaobserwowano, że liniowa suma uszkodzeń przekracza jedność dla scenariusza obciążeń stopniowo malejących i nie osiąga tej wartości w przypadku przeciwnym. Większe różnice w poziomach obciążeń skutkowały w większych odstępstwach liniowej sumy uszkodzeń od jedności. Szczególnie duże zauważono dla Ra = 0.9.
Źródło:
Journal of Theoretical and Applied Mechanics; 2012, 50, 1; 231-250
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application study on cooperative drainage technology for mining-affected pressure relief gas in overlaying adjacent seams
Badanie zastosowania połączonej technologii odprowadzania gazu dla gazu rozprężonego w przyległych pokładach złożowych
Autorzy:
Wang, K.
Zang, J.
Zhou, A.
Gao, H.
Powiązania:
https://bibliotekanauki.pl/articles/348651.pdf
Data publikacji:
2012
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
przyległe pokłady węgla
odmetanowanie
wzbogacenie strefy
technologia łączonego odprowadzania gazu
overlaying adjacent seams
mining-affected pressure relief gas
zoning enrichment
cooperative drainage technology
Opis:
During the mining process of 12# coal seam in Yangquan mine area, gas quantity emitting from overlaying adjacent seams was high and gas concentration in upper corners and return airways of mining faces often exceeded limitation. To solve these problems, through the combination of theoretical study, numerical simulation and on-site observation, the high-low zoning enrichment law of the mining-affected pressure relief gas in overlaying adjacent seams of 12# coal seam was formulated. According to this law, the cooperative drainage technology was proposed, namely arranging the high-located and low-located boreholes to drain the gas respective in high and low enrichment zones. By applying the cooperative drainage technology, the safety production status of mining faces of 12# coal seam in Nanzhuang mine has been significantly ameliorated, advance efficiency, drainage rate and drainage quantity have been improved greatly, carbon emission has been reduced and the environment has been protected, resource utilization has been improved, the service life of the mine will be extended. In a word, good economic, social and environmental benefits have been achieved, meanwhile, a safe, efficient, and sustainable exploitation of the mine has been realized.
Podczas eksploatacji ściany nr 12 w Yangquan zanotowano dużą ilość gazu wydobywającego się z przyległych pokładów węgla. Koncentracja metanu w chodniku nadścianowym bardzo często przekraczała wartości dopuszczalne. Aby rozwiązać te problemy, sformułowano zasadę wysokiego/niskiego odmetanowania dla dekompresji metanu w przyległych do ściany nr 12 pokładach węgla na podstawie symulacji numerycznych oraz obserwacji. W odniesieniu do tej zasady zaproponowano technologię łączonego odprowadzania gazu poprzez otwory wiertnicze zlokalizowane odpowiednio na niższym i wyższym poziomie odpowiednich stref metanowości. Zastosowanie technologii odprowadzania łączonego przyczyniło się do znacznej poprawy bezpieczeństwa produkcji na przodku nr 12 kopalni Nanzhuang, zwiększenia wydajności, prędkości odprowadzania i ilości odprowadzanego gazu, obniżenia emisji dwutlenku węgla oraz lepszej ochrony środowiska, a także lepszego wykorzystania zasobów i wydłużenia okresu eksploatacji kopalni. Krótko mówiąc, uzyskano znaczne korzyści ekonomiczne, społeczne i środowiskowe, przy jednoczesnym zapewnieniu bezpiecznej, wydajnej i zrównoważonej eksploatacji kopalni.
Źródło:
AGH Journal of Mining and Geoengineering; 2012, 36, 3; 385-393
1732-6702
Pojawia się w:
AGH Journal of Mining and Geoengineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Focusing properties of partially coherent dark hollow Gaussian beams through a thin lens system
Autorzy:
Dong, Y
Zhao, C
Wang, K
Cai, Y
Powiązania:
https://bibliotekanauki.pl/articles/175075.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
focusing properties
partially coherent
dark hollow beam
focal shift
Opis:
This paper investigated the focal shift of partially coherent dark hollow Gaussian beams through a thin lens system. An analytic expression of the irradiance distribution of the focusing partially coherent dark hollow Gaussian beams in the back focal plane has been given by using the Collins formula. The focus shift of focused partially coherent dark hollow Gaussian beams in different parameters is studied in detail by numerical calculations. It is found that the absolute value of the focal shift of partially coherent dark hollow Gaussian beams decreases as the transverse coherence width or the order of the dark hollow Gaussian beams or a parameter of the dark hollow Gaussian beams increases.
Źródło:
Optica Applicata; 2015, 45, 2; 151-161
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An Enhanced Run-Length Encoding Compression Method for Telemetry Data
Autorzy:
Shan, Y.
Ren, Y.
Zhen, G.
Wang, K.
Powiązania:
https://bibliotekanauki.pl/articles/221755.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
multichannel acquisition system
high compression performance
run-length encoding with error parameter
oversampling
hardware implementation
Opis:
The telemetry data are essential in evaluating the performance of aircraft and diagnosing its failures. This work combines the oversampling technology with the run-length encoding compression algorithm with an error factor to further enhance the compression performance of telemetry data in a multichannel acquisition system. Compression of telemetry data is carried out with the use of FPGAs. In the experiments there are used pulse signals and vibration signals. The proposed method is compared with two existing methods. The experimental results indicate that the compression ratio, precision, and distortion degree of the telemetry data are improved significantly compared with those obtained by the existing methods. The implementation and measurement of the proposed telemetry data compression method show its effectiveness when used in a high-precision high-capacity multichannel acquisition system.
Źródło:
Metrology and Measurement Systems; 2017, 24, 3; 551-562
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dual reference beam digital off-axis holography for exact suppression of zero-order term and twin image without spectrum loss
Autorzy:
Wang, M.
Wang, K.
Zheng, M.
Li, F.
Wu, J.
Powiązania:
https://bibliotekanauki.pl/articles/174894.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
noise suppression
pixel-by-pixel multiplication
digital off-axis holography
Opis:
In this paper, we describe an effective approach to suppressing zero-order term and twin image by using pixel-by-pixel multiplication of double holograms in digital off-axis holography. This method records two holograms, respectively, by using the reference waves in different directions. It shows not only a simpler algorithm and easier implementation in experiment, but also exact and complete suppression of the zero-order term and twin image without any spectrum loss of the object in the image reconstruction, particularly when the image and the zero-order term are fairly close to each other. The experimental result approves of the theoretical prediction very well. This approach provides an effective solution to suppressing undesired noises in the digital off-axis holography.
Źródło:
Optica Applicata; 2017, 47, 3; 435-443
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phytoremediation of phenol using Polygonum orientale and its antioxidative response
Autorzy:
Wang, K.
Cai, J.
Xie, S.
Feng, J.
Wang, T.
Powiązania:
https://bibliotekanauki.pl/articles/205372.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Polygonum orientale
phenol
phytoremediation
antioxidant enzyme
osmotic regulator
Opis:
Polygonum orientale with beautiful red flowers can be found as one dominant species in the vicinity of most water bodies and wetlands in China. However, its phytoremediation potential has not been sufficiently explored because little is known about its resistance to inorganic or organic pollutants. We investigated P. orientale response to low and moderate levels of phenol stress (≤ 80 mg L-1). Endpoints included phenol tolerance of P. orientale and the removal of the pollutant, antioxidant enzyme activities, damage to the cell membrane, osmotic regulators and photosynthetic pigments. In plant leaves, phenol stress significantly increased the activities of peroxidase (POD) and catalase (CAT), as well as the contents of proline, soluble sugars and carotenoids, whereas superoxide dismutase (SOD), H2O2 and electrolyte leakage (EL) levels remained unaltered. On the other hand, there were significant decreases of soluble protein and chlorophyll contents. We demonstrated that, in combination with phenol tolerance and its removal, P. orientale has efficient protection mechanisms against phenol-induced oxidative damage (≤ 80 mg L-1). We propose that P. orientale could be used as an alternative and interesting material in the phytoremediation of phenol.
Źródło:
Archives of Environmental Protection; 2015, 41, 3; 39-46
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
PIV measurement of tube-side in a shell and tube heat exchanger
Autorzy:
Wang, K.
Zhang, Z.
Liu, Q.
Tu, X.
Hyoung-Bum, K.
Powiązania:
https://bibliotekanauki.pl/articles/778192.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
shell and tube heat exchanger
tube-side
PIV
unsteady flow
Opis:
In order to improve the performance of the shell and tube heat exchanger, a porous baffle and a splitter bar are employed in this research. Through the arrangement of the porous baffle in the tube-side inlet and the splitter bar in the tube, the flow distribution of liquid in the heat exchanger is improved. PIV technology is used to investigate the unsteady flow in the tube-side inlet and the outlet of different models. The porous baffle significantly improves the flow of fluid in the shell and tube heat exchanger, especially by eliminating/minimizing the maldistribution of fluid flow in the tube-side inlet. The performance of the arc baffle is better than that of the straight baffle. The splitter bar has a minimal effect on the flow field of the tube-side inlet, but it effectively improves the flow in the tube bundle and restrains the vortex generation in the tube-side outlet.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 1; 60-66
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative Theoretical Investigation on Energetic Substituted Furazanyl Ethers
Autorzy:
Liu, N.
Wang, K.
Shu, Y.
Zeman, S.
Wang, B.
Wang, W.
Powiązania:
https://bibliotekanauki.pl/articles/358622.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
furazanyl ethers
heats of formation
bond dissociation energy
detonation performance
melting point
Opis:
Furazanyl ether has great potential to be an important candidate as a casting explosive and energetic plasticizer. The density functional theory (DFT) method was used to investigate the heats of formation (HOFs), molecular stability, detonation performance and melting point of a series of substituted furazanyl ethers at B3LYP/6-311G(d,p) level. The results show that the introduction of –N3 or –N(O)=N– groups significantly improves the HOFs values of the derivatives. The bond dissociation energies (BDEs) were analyzed, showing that the N–O bond in the furazan ring is the weakest for most compounds and the ring is vulnerable to cleavage in thermal decomposition. The calculation of density, detonation velocities and detonation pressures suggests that the substitution of –NF2, –CF(NO2)2, furoxan or –N(O)=N– group is an effective method for enhancing their detonation performance. The melting points were determined according to the variation of specific heat capacity, and good estimates were obtained in comparison with the available experimental data. Taking into account the detonation performance and melting point, four compounds are favoured for application in melt cast explosive or energetic plasticizers.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 47-71
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational Investigation on the Structure and Performance of Novel 4,7-dinitro-furazano-[3,4-d]-pyridazine Derivatives
Autorzy:
Wang, K.
Shu, Y.
Liu, N.
Ding, X.
Wu, Z.
Lu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358090.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
4,7-dinitro-furazano-[3,4-d]-pyridazine
heat of formation
density
detonation performance
bond dissociation energy
Opis:
Seven novel energetic 4,7-dinitro-furazano-[3,4-d]-pyridazine derivatives were designed, and their optimized structures and performances were studied by density functional theory (DFT) at B3LYP/6-311g(d,p) level. The detonation performances were estimated by the Kamlet-Jacobs equations. The results show that these compounds have high crystal densities (1.818-1.925 g·cm−3), detonation velocities (8.51-9.56 km·s−1) and detonation pressures (32.28-41.70 GPa). The bond dissociation energies (BDEs) of the weakest bond (N–O bond) vary from 70.889 kJ·mol−1 to 173.283 kJ·mol−1, and some of them exhibit higher BDEs than that of RDX (N–NO2 bond, 149.654 kJ·mol−1) and HMX (N–NO2 bond, 154.905 kJ·mol−1). M4 and M5 exhibit similar and higher detonation performance than RDX (8.81 km·s−1, 34.47 GPa). The detonation performance of M7 (9.56 km·s−1, 41.70 GPa) even surpasses that of HMX (9.10 km·s−1, 39.00 GPa). Otherwise, the specific impulse values of M1-M7 (266-279 s) outperform HMX (266 s) by 0-13 s, which indicates that M1-M7 may show better performance as monopropellants. It is concluded that density, heat of formation, stability, detonation performance and specific impulse of the designed compounds depend on the position and number of the N→O oxidation bonds.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 26-46
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Serological surveillance of avian influenza virus and canine distemper virus in captive Siberian Tigers in Northeastern China
Autorzy:
Wang, K.
Wang, H.
Feng, N.
Zhao, Y.
Gao, Y.
Hu, G.
Xia, X.
Powiązania:
https://bibliotekanauki.pl/articles/2087698.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
influenza A virus
canine distemper virus
serological
Siberian Tiger
Źródło:
Polish Journal of Veterinary Sciences; 2018, 21, 3; 491-495
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical Studies of High-nitrogen-containing Energetic Compounds Based on the s-Tetrazine Unit
Autorzy:
Man, T. T.
Wang, K.
Zhang, J.G.
Niu, X. Q.
Zhang, T. L.
Powiązania:
https://bibliotekanauki.pl/articles/358527.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
high-energy-density materials (HEDMs)
substituted s-tetrazine
compounds
electronic properties
thermodynamic properties
detonation
properties
Opis:
In order to develop new high-energy-density materials (HEDMs), we have investigated 12 substituted s-tetrazine (TZ) compounds, where s-tetrazine was substituted by amino, amido and related groups. Density functional theory (DFT) was used to predict the optimized geometries, electronic structures, total energy, heats of formation (HOFs) and densities. In addition the detonation properties were evaluated by using the VLW equation of state (EOS). The standard enthalpy of formation, the Gibbs free energy, entropy and equilibrium constants were used to estimate the success of the synthetic substitution reactions, which provided theoretical support for practical work. The bond dissociation energy (BDE) of bond C-R was calculated at each stage of the substitution reaction. The calculated results showed that substitution of amino, amido and their derivatives in the TZ ring enhances the HOF values and is favorable for increasing the thermal stability. The calculated detonation properties indicated that incorporating the above groups into the TZ ring is benefcial for improving the explosive performance. Considering the detonation properties and thermal stability, the 12 derivatives may be regarded as promising candidates as high-energy-density materials (HEDMs).
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 2; 171-189
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of Four Energetic Transition Metal Complexes of 3,4-Diamino-1,2,4-triazole
Autorzy:
Yin, X.
Jin, X.
Xu, C.-X.
He, P.
Wang, K.
Zhang, J.-G.
Powiązania:
https://bibliotekanauki.pl/articles/358716.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
3,4-diamino-1,2,4-triazole
theoretic study
crystal structure
thermal stability
sensitivity
Opis:
Four complexes with the formula of [M5(DATr)12~14(H2O)6](ClO4)10 (M = Mn (1), Co (2), Ni (3), Zn (4)) about their synthesis, structures and some energetic properties (such as sensitivities tests) have been described, where the DATr here denotes 3,4-diamino-1,2,4-triazole. These four compounds are all light metallic complexes with good thermal stability. The structures of 2-4 were determined by single-crystal X-ray diffraction, and the crystal structures mainly consist of penta-nuclear units. All the structures have a common interesting property in which DATr plays a role of bi-dentate ligand. Besides, it is observed from the crystal structure of 4 that DATr can be also act as a mono-dentate ligand. Thermodynamic studies of their decomposition properties and kinetic parameters show that the four complexes have high thermal stabilities. Furthermore, tests of their impact and friction sensitivities show that complexes (2) and (3) can be potential candidates as primary explosives to replace toxic lead azide.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 2; 301-320
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Development of an indirect ELISA based on glycoprotein B gene for detecting of Feline herpesvirus type 1
Autorzy:
Tan, Y.
Dong, G.
Niu, J.
Guo, Y.
Yi, S.
Sun, M.
Wang, K.
Hu, G.
Powiązania:
https://bibliotekanauki.pl/articles/2087468.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
feline herpesvirus type 1
gB protein
indirect ELISA
prokaryotic expression
Źródło:
Polish Journal of Veterinary Sciences; 2019, 3; 631-633
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Decomposition Kinetics of Hexanitrohexaazaisowurtzitane/Ammonium Perchlorate
Autorzy:
Zhu, Y.-L.
Wang, K.-K.
Shan, M.-X.
Zheng, X.-D.
Jiao, Q.-J.
Wang, J.-S.
Powiązania:
https://bibliotekanauki.pl/articles/358067.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
hexanitrohexaazaisowurtzitane
ammonium perchlorate
thermal analysis
thermal decomposition kinetics
Opis:
The thermal decomposition kinetics of hexanitrohexaazaisowurtzitane/ ammonium perchlorate (HNIW/AP) have been investigated by thermogravimetrydifferential scanning calorimetry-mass spectrometry (TG-DSC-MS) simultaneous analysis. TG showed that there were three weight loss processes for the thermal decomposition of the HNIW/AP mixture. The first was ascribed mainly to the thermal decomposition of HNIW, while the second and third were assigned to that of AP. The presence of AP has little effect on the thermal decomposition process of the HNIW component. The apparent activation energy of the thermal decomposition of the HNIW component, calculated by the Kissinger method, was little changed compared to that of neat HNIW. The addition of HNIW to AP caused the onset and end temperatures of the thermal decomposition to be decreased and the decomposition process to be shortened. The high-temperature and lowtemperature decomposition processes of AP became blurred in the presence of HNIW, and this was supported by the MS results.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 1; 149-159
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł

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