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Wyświetlanie 1-8 z 8
Tytuł:
Electrochemical Method of Copper Powder Synthesis on Rotating Electrode in the Presence of Surfactants
Autorzy:
Wojtaszek, K.
Cebula, F.
Partyka, B.
Deszcz, P.
Włoch, G.
Socha, R. P.
Woźny, K.
Żabiński, Piotr
Wojnicki, Marek
Powiązania:
https://bibliotekanauki.pl/articles/2203711.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
copper powder
electrochemical synthesis
rotating electrode
ethylene glycol
Opis:
This paper presents a method of synthesizing copper powders by electrochemical method with the use of a rotating working electrode. The influence of the rotation speed of the working electrode, the current density, the concentration of copper ions, and the addition of ethylene glycol on the shape, size, and size distribution of the obtained powders were investigated. Properties of the synthesized powders were characterized by scanning electron microscopy (SEM) and X-ray powder diffractometry (XRD). It has been shown that it is possible to obtain copper powders with a size of 1 µm by an electrochemical method using the rotary cathode, in sulphate bath with addition of ethylene glycol as a surfactant. Increasing current density causes a decrease in the average size of the obtained powder particles. The addition of 2.5% of ethylene glycol prevents the formation of dendritic powders. The change in the concentration of copper ions in the range from 0.01 to 0.15 mol/dm3 in the electrolyte did not show any significant effect on the size of obtained particles. However, higher concentrations of copper limiting the presence of dendritic-shape particles. Changing the speed of rotation of the electrode affects both the size and the shape of synthesized copper powder. For the rotational speed of the electrode of 115 rpm, the obtained powders have a size distribution in the range of 0-3 µm and an average particle size of 1 µm. The particles had a polygonal shape with an agglomeration tendency.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 1; 375--386
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preliminary Investigation on Leaching Behavior of Zinc ash
Autorzy:
Rudnik, E.
Włoch, G.
Szatan, L.
Powiązania:
https://bibliotekanauki.pl/articles/353814.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
zinc ash
hydrometallurgy
leaching
recovery
Opis:
Oxide fraction of industrial zinc ash from hot dip galvanizing was characterized in terms of composition and leaching behaviour in 10% sulfuric acid solution. Waste product contained about 68% Zn, 6% Cl, 3% Al, 1% Fe, 0.7% Si, 0.5% Pb and minor percentages of other metals (Mn, Cu, Ti etc.). It consisted mainly of zinc oxide contaminated with metallic zinc, zinc hydroxide chloride and silica. Dissolution of the metals from the material was determined as a function of solid to liquid ratio (50-150 kg/m3), temperature (20°C and 35°C) and agitation rate (300 and 900 rpm). The best results (50 g/dm3 Zn(II) at 78% zinc recovery) were obtained for 100 kg/m3 and the temperature of 20°C. Increase in the agitation rate had weak effect on the zinc yield. The final solutions were contaminated mainly by Fe(II, III) ions. Leaching of the material was an exothermic process with the reaction heat of about 800 kJ/kg.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 801-807
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Silver Matrix Composite Reinforced by Aluminium-Silver Intermetallic Phases
Autorzy:
Wloch, G.
Skrzekut, T.
Sobota, J.
Woznicki, A.
Błaż, L.
Powiązania:
https://bibliotekanauki.pl/articles/352667.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
silver-aluminum composite
plastic consolidation
powder metallurgy
Ag-Al intermetallics
Opis:
Silver and aluminum powders (82 mass % Ag and 18 mass % Al) were mixed and hot extruded at 673 K with extrusion ratio λ = 25. Performed X-ray diffraction analysis of as extruded rod revealed the development of Ag3Al and Ag2Al-type intermetallic phases. Structural observations and both chemical and diffraction analysis of structural components confirmed the growth of mentioned phases in the vicinity of elementary Al and Ag granules. No pores or voids were observed in the material. Mechanical properties of the composite, UTS = 490MPa, YS = 440 MPa, HV2 = 136, were relatively high if compared to commercial Ag and Cu products. Hot compression tests pointed to the good hot workability of the composite at deformation temperature range 473 K - 773 K. The differential scanning calorimetry tests were performed in order to estimate structural processes during heating of Ag/Al composite that lead to thermodynamically stable liquid state. It was found that characteristic temperature of three endothermic peaks correspond to (1) peritectoid transformation μ-Ag3Al → ζ-Ag2Al + (Ag), (2) the eutectic melting ζ-Ag2Al + (Al) → L, (3) melting of the ζ-Ag2Al phase. The Vickers hardness of the samples annealed at 673 K, for the time range up to 6900 minutes, was also determined. It was concluded that mutual diffusion of elements between Ag and Al granules and the growth of μ-Ag3Al and ζ-Ag2Al grains during annealing at 673 K result in a slight hardening of the composite.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 427-434
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron work function as a direct parameter for bacterial infection risk of implant surfaces
Autorzy:
Gołda-Cępa, M.
Syrek, K.
Brzychczy-Włoch, M.
Sulka, G. D.
Kotarba, A.
Powiązania:
https://bibliotekanauki.pl/articles/284984.pdf
Data publikacji:
2016
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
bacterial infections
implants
nanoporous materials
Źródło:
Engineering of Biomaterials; 2016, 19, 138; 58
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Precipitation Processes during Non-Isothermal Ageing of Fine-Grained 2024 Alloy
Autorzy:
Kozieł, J.
Błaż, L.
Włoch, G.
Sobota, J.
Lobry, P.
Powiązania:
https://bibliotekanauki.pl/articles/352499.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
AA2024 alloy
scrap metal milling
structure refining
powder metallurgy
precipitation hardening
Opis:
Mechanical alloying and powder metallurgy procedures were used to manufacture very fine-grained bulk material made from chips of the 2024 aluminum alloy. Studies of solution treatment and precipitation hardening of as-received material were based on differential scanning calorimetry (DSC) tests and TEM/STEM/EDX structural observations. Structural observations complemented by literature data lead to the conclusion that in the case of highly refined structure of commercial 2024 alloys prepared by severe plastic deformation, typical multi-step G-P-B →θ” →θ’ →θ precipitation mechanism accompanied with G-P-B →S” →S’ →S precipitation sequences result in skipping the formation of metastable phases and direct growth of the stable phases. Exothermic effects on DSC characteristics, which are reported for precipitation sequences in commercial materials, were found to be reduced with increased milling time. Moreover, prolonged milling of 2024 chips was found to shift the exothermic peak to lower temperature with respect to the material produced by means of common metallurgy methods. This effect was concluded to result from preferred heterogeneous nucleation of particles at subboundaries and grain boundaries, enhanced by the boundary diffusion in highly refined structures. Transmission electron microscopy and diffraction pattern analysis revealed the development of very fine Al4C3 particles that grow due to the chemical reaction between the Al matrix and graphite flakes introduced as a process control agent during the preliminary milling of chips. Al4C3 nano-particles are formed at high temperatures, i.e. during hot extrusion and the subsequent solution treatment of the samples. Highly refined insoluble particles such as aluminum carbide particles and aluminum oxides were found to retard recrystallization and reduce recovery processes during solution treatment of preliminarily milled materials. Therefore, the as-extruded material composed of a milled part and chip residuals retained its initial bimodal structure in spite of solution heat treatment procedures. This points to a high structural stability of the investigated materials, which is commonly required for new technologies of high-strength Al-based materials production.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 169-176
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Cooling Rate after Homogenization on the Microstructure and Properties of 2017a Alloy Billets for Extrusion with Solution Heat Treatment on the Press
Autorzy:
Woźnicki, A.
Leśniak, D.
Włoch, G.
Pałka, P.
Leszczyńska-Madej, B.
Wojtyna, A.
Powiązania:
https://bibliotekanauki.pl/articles/355500.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
2017A alloy
cooling rate after homogenization
θ (Al2Cu) phase particles precipitation
Opis:
The influence of cooling rate after homogenization on the 2017A alloy microstructure was analysed. The capability of the θ (Al2Cu) particles, precipitated during various homogenization coolings, for rapid dissolution was estimated. For this purpose, the DSC test was used to determine the effect of the cooling rate after homogenization on the course of melting during a rapid heating. Moreover, the samples after solution heat treatment (with short time annealing) and ageing, were subjected to the microstructure investigations and the microhardness of grains interiors measurements. It was found that cooling after homogenization at 160 °C/h is sufficient for precipitation of fine θ phase particles, which dissolve during the subsequent rapid heating. The cooling at 40 °C/h, causes the precipitation of θ phase in the form of large particles, incapable of further fast dissolution.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 3; 1663-1670
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Homogenization Conditions on the Structure and Properties of 6082 Alloy Billets
Wpływ warunków homogenizacji na strukturę i własności wlewków ze stopu 6082
Autorzy:
Woźnicki, A.
Leśniak, D.
Włoch, G.
Leszczyńska-Madej, B.
Wojtyna, A.
Powiązania:
https://bibliotekanauki.pl/articles/351632.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
6082 alloy
homogenization temperature
cooling rate after homogenization
stop 6082
temperatura homogenizacji
szybkość chłodzenia po homogenizacji
Opis:
The paper presents the results of laboratory homogenization investigations of the 6082 grade alloys, differing in Mg and Si content. At the first stage, the microstructure of alloys was analysed after homogenization finished with water quenching. SEM/EDS investigations and DSC tests were applied to evaluate the dissolution of the Mg2Si particles and concentration of the main alloying additions in the grains interiors, depending on soaking conditions. In the case of alloy with lower Mg and Si content, homogenization the temperature of 535ºC for 8h is sufficient for significant Mg2Si particles dissolution. For the alloy with higher Mg and Si content, after homogenization the temperature of 550ºC for 8h, the amount of undissolved Mg2Si particles decreases visibly, compared to homogenization at 535ºC for 8h. However, an unfavourable tendency of dispersoids growth is observed and these soaking conditions are not found to be recommended. At the second research stage, the influence of homogenization cooling rate on the size and distribution of the Mg2Si particles observed in the alloys microstructure was analysed. The ability of the Mg2Si particles, precipitated during various homogenization coolings, to rapid dissolution was estimated. For this purpose, the hardness after solution heat treatment with short annealing and ageing was determined and the DSC tests were performed. It was found, that cooling after homogenization at 315ºC/h is sufficient for precipitation of fine Mg2Si particles, which dissolve during subsequent rapid heating. Cooling at 40ºC/h, causes precipitation of Mg2Si phase in the form of large particles, unable for further fast dissolution.
W artykule przedstawiono wyniki laboratoryjnych badań homogenizacji dwóch stopów w gatunku 6082, różniących się zawartością Mg i Si. W pierwszym etapie analizowana była struktura stopów po homogenizacji z chłodzeniem w wodzie. Szczególną uwagę zwrócono na rozpuszczanie cząstek fazy Mg2Si podczas wygrzewania oraz zawartość głównych składników stopowych we wnętrzach ziarn. Oceny parametrów wygrzewania dokonano w oparciu o badania SEM/EDS oraz testy DSC. W przypadku stopu z niższą zawartością Mg i Si, homogenizacja w temperaturze 535ºC przez 8 h jest wystarczająca dla znaczącego rozpuszczenia cząstek fazy Mg2Si. W przypadku stopu z wyższą zawartością Mg i Si, po homogenizacji w temperaturze 550ºC przez 8h, udział nierozpuszczonych cząstek Mg2Si spada wyraźnie, w porównaniu z homogenizacją w temperaturze 535ºC przez 8h. Jednakże, stwierdzono niekorzystną tendencję do rozrostu dyspersoidów, zatem tych warunków wyżarzania nie uznano za rekomendowane. W drugim etapie analizowano wpływ szybkości chłodzenia z temperatury homogenizacji na wielkość i dystrybucję cząstek Mg2Si obserwowanych w strukturze stopów. Wykonano badania SEM oraz dokonano oceny możliwości szybkiego rozpuszczania cząstek Mg2Si wydzielonych podczas chłodzenia z temperatury homogenizacji z różnymi szybkościami. W tym celu wykonano badania twardości stopów po przesycaniu z krótkim wygrzewaniem oraz starzeniu, jak również badania DSC. Stwierdzono, że studzenie z temperatury homogenizacji z szybkością 315ºC/h jest wystarczające dla wydzielenia drobnych cząstek Mg2Si, które ulegają rozpuszczeniu podczas późniejszego gwałtownego nagrzewania. Chłodzenie z temperatury homogenizacji z szybkością 40ºC/h powoduje wydzielanie fazy Mg2Si w postaci dużych cząstek, które nie ulegają pełnemu rozpuszczeniu podczas późniejszego szybkiego nagrzewania.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 3A; 1764-71
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Influence of Potential-Current Conditions on the Electrodeposition of Ni-Sn Alloys from Acidic Chloride-Sulphate Solution
Wpływ warunków potencjałowo-prądowych na współosadzanie stopów Ni-Sn z kwaśnego roztworu chlorkowo-siarczanowego
Autorzy:
Rudnik, E.
Włoch, G.
Czarnecka, A.
Powiązania:
https://bibliotekanauki.pl/articles/352011.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
electrodeposition
nickel
tin
alloy
speciation
elektroliza
nikiel
cyna
stop
specjacja
Opis:
Ni - Sn alloys were electrodeposited from acidic chloride-sulphate solution in potentiostatic and galvanostatic conditions. Cyclic voltammetry and Hull cell were used for the selection of the appropriate deposition potentials and cathodic current densities, respectively. In the potentiostatic conditions (-1.0 - -1.2 V vs. Ag/AgCl) porous deposits (~7-10 wt% Ni) were obtained, while dense coatings (~15-34 wt% Ni) were produced in the galvanostatic conditions (0.5-1.5 A/dm2). In both cases, deposits consisted of β - Sn and Ni3Sn4 phases. Speciation of the bath was also calculated.
Stopy Ni - Sn osadzano katodowo z kwaśnego roztworu chlorkowo-siarczanowego w warunkach potencjostatycznych i galwanostatycznych. Warunki elektrolizy wytypowano na podstawie pomiarów chronowoltamperometrycznych i testów w komórce Hulla. W warunkach potenjostatycznych (-1.0- -1.2 V wzgl. Ag/AgCl) otrzymano warstwy porowate (7-10%mas Ni), natomiast w warunkach galwanostatycznych (0.5-1.5 A/dm2) tworzyły się warstewki zwarte (15-34%mas Ni). We wszystkich przypadkach uzyskano dwufazowe osady katodowe zawierające (β-Sn i Ni3Sn4. Obliczono także rozkład form jonowych w stosowanej kąpieli.
Źródło:
Archives of Metallurgy and Materials; 2014, 59, 1; 195-198
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-8 z 8

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