- Tytuł:
- Chemical Shift of X-Ray K-Absorption Edge of Ni in Some of its Compounds and its Correlation with Partial Charge
- Autorzy:
-
Singh, V. K.
Chetal, A. R.
Sarode, P. R. - Powiązania:
- https://bibliotekanauki.pl/articles/1933455.pdf
- Data publikacji:
- 1995-06
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
- 78.70.Dm
- Opis:
- X-ray absorption Ni K-edge spectra are recorded for the following systems: Ni metal, Ni(NO$\text{}_{3}$)$\text{}_{2}$ • 6H$\text{}_{2}$0, Ni$\text{}_{3}$(PO$\text{}_{4}$)$\text{}_{2}$ • 6H$\text{}_{2}$0, NiSO$\text{}_{4}$ • 6H$\text{}_{2}$0, NiCO$\text{}_{3}$, NiO and La$\text{}_{2}$NiO$\text{}_{4}$ using a Cauchois-type bent crystal spectrograph. The chemical shift of these systems is correlated with the partial charge determined using Sanderson's method. On the basis of regression analysis a relation ΔE = A$\text{}_{0}$ + A$\text{}_{1}$q + A$\text{}_{2}$q$\text{}^{2}$ -A$\text{}_{3}$q$\text{}^{3}$ + A$\text{}_{4}$q$\text{}^{4}$ between the chemical shift, ΔE, and the partial charge, q, has been suggested. The discrepancy in the shift of NiO and La$\text{}_{2}$NiO$\text{}_{4}$ has also been discussed.
- Źródło:
-
Acta Physica Polonica A; 1995, 87, 6; 1003-1008
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł