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Wyświetlanie 1-3 z 3
Tytuł:
State of water in citrate crosslinked chitosan membrane
Autorzy:
Ostrowska-Czubenko, Jadwiga
Pieróg, Milena
Powiązania:
https://bibliotekanauki.pl/articles/1035556.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
DSC method
chitosan membrane
state of water
trisodium citrate
Opis:
The ionically crosslinked membranes were prepared of chitosan (Ch) and trisodium citrate (Ch/CIT). The characteristics of the state of water in crosslinked and uncrosslinked chitosan membranes with different water content was performed by differential scanning calorimetry (DSC). The kinetics of water swelling in Ch and Ch/CIT membranes were also studied. Conclusions concerning effect of ionic crosslinking on the state of water in chitosan hydrogel membranes were drawn out. Results shows that freezable and non-freezable water exist in analysed Ch and Ch/CIT membranes, while there are variations in the amount of non-freezing bound water in these polymers.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2010, 15; 33-40
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal degradation of double crosslinked hydrogel chitosan membranes
Autorzy:
Pieróg, Milena
Ostrowska-Czubenko, Jadwiga
Gierszewska-Drużyńska, Magdalena
Powiązania:
https://bibliotekanauki.pl/articles/1035381.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
DSC
FTIR
chitosan membrane
thermal degradation
thermogravimetry
Opis:
The thermal degradation behaviour of uncrosslinked and crosslinked chitosan membranes were studied by means of dynamic thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) over the temperature range 25-500ºC in nitrogen atmosphere. Modified chitosan membranes were prepared using a crosslinking method based on covalent crosslinking of chitosan with glutaraldehyde and subsequent ionic crosslinking with sodium citrate, sulfuric acid, sulfosuccinic acid and tripolyphosphate, respectively. Chemical structure of modified chitosan membranes before and after their thermal degradation was characterized by FTIR spectroscopy. Both TGA and DSC experiments as well as spectral results (FTIR spectra of thermal degradation residues) indicated some differences in the mechanism of thermal degradation of uncrosslinked and crosslinked chitosan membranes.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2012, 17; 71-78
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
State of water in noncrosslinked and crosslinked hydrogel chitosan membranes – dsc studies
Autorzy:
Ostrowska-Czubenko, Jadwiga
Pieróg, Milena
Gierszewska-Drużyńska, Magdalena
Powiązania:
https://bibliotekanauki.pl/articles/1035477.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
DSC
chitosan membranes
crosslinking
glutaraldehyde
states of water
trisodium citrate.
Opis:
Modified chitosan hydrogel membranes were prepared using glutaraldehyde (GA) and sodium citrate (NaCIT) as crosslinking agents. Molecular and supermolecular structure analyses of unmodified and modified chitosan membranes have been conducted by FTIR and X-ray spectroscopy. FTIR results showed covalent and ionic crosslinks formation between chitosan (Ch) and GA or simultaneously Ch, GA and NaCIT. The state of water in noncrosslinked and crosslinked chitosan membranes were analysed by differential scanning spectroscopy (DSC). Three types of water in hydrogel membranes were found: non-freezing bound water, freezing bound water and freezing free water, while there were variations in the amount of non-freezing bound water in these polymers. The effect of ionic crosslinking on water state, mainly on the nonfreezing water content, was discussed.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2011, 16; 147-156
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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