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Tytuł:
Synthesis And Electrochemical Characteristics Of Mechanically Alloyed Anode Materials SnS2 For Li/SnS2 Cells
Synteza mechaniczna i charakterystyka elektrochemiczna materiałów anodowych SnS2 dla ogniw Li/SnS2
Autorzy:
Hong, J. H.
Liu, X. J.
Park, D. K.
Kim, K. W.
Ahn, H. J.
Ahn, I. S.
Powiązania:
https://bibliotekanauki.pl/articles/356903.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
MA
Li/SnS2 cell
PCA
wet milling process and electrochemical characteristics
ogniwa Li/SnS2
charakterystyka elektromechaniczna
Opis:
With the increasing demand for efficient and economic energy storage, tin disulfide (SnS2), as one of the most attractive anode candidates for the next generation high-energy rechargeable Li-ion battery, have been paid more and more attention because of its high theoretical energy density and cost effectiveness. In this study, a new, simple and effective process, mechanical alloying (MA), has been developed for preparing fine anode material tin disulfides, in which ammonium chloride (AC), referred to as process control agents (PCAs), were used to prevent excessive cold-welding and accelerate the synthesis rates to some extent. Meanwhile, in order to decrease the mean size of SnS2 powder particles and improve the contact areas between the active materials, wet milling process was also conducted with normal hexane (NH) as a solvent PCA. The prepared powders were both characterized by X-ray diffraction, Field emission-scanning electron microscopeand particle size analyzer. Finally, electrochemical measurements for Li/SnS2 cells were takenat room temperature, using a two-electrode cell assembled in an argon-filled glove box and the electrolyte of 1M LiPF6 in a mixture of ethylene carbonate(EC)/dimethylcarbonate (DMC)/ethylene methyl carbonate (EMC) (volume ratio of 1:1:1).
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1191-1194
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface Modification of Self-Consolidated Microporous Ti Implant Compacts Fabricated by Electro-Discharge-Sintering in Air
Autorzy:
Jo, Y. J.
Yoon, Y. H.
Kim, Y. H.
Chang, S. Y.
Kim, J. Y.
Lee, Y. K.
Van Tyne, C. J.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/356790.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium
implant
porous
sintering
X-ray photoelectron spectroscopy (XPS)
Opis:
A single pulse of 0.75-2.0 kJ/0.7g of atomized spherical Ti powders from 300 mF capacitor was applied to produce a microporous Ti implant compact by electro-discharge-sintering (EDS). A solid core in the middle of the compact surrounded by a microporous layer was found. X-ray photoelectron spectroscopy was employed to study the surface characteristics of the EDS Ti compact and it revealed that Ti, C and O were the main constituents on the surface with a smaller amount of N. The surface was lightly oxidized and was primarily in the form of TiO2 resulting from the air oxidation during EDS processing. The lightly oxidized surface of the EDS compact also exhibited Ti nitrides such as TiN and TiON, which revealed that the reaction between air constituents and the Ti powders even in times as short as 128 msec.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1287-1291
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study On The Electro-Refining Of Tin In Acid Solution From Electronic Waste
Badanie elektrorafinacji cyny w roztworze kwasu z e-odpadów
Autorzy:
Son, S. H.
Park, S. C.
Kim, J. H.
Kim, Y. H.
Lee, M. S.
Ahn, J.-W.
Powiązania:
https://bibliotekanauki.pl/articles/352665.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
electrorefining
tin
electronic waste
recycling
high purity
elektrorafinacja
cyna
odpady elektroniczne
recykling
Opis:
The tin metal could be retractable from wasted tin scrap, sludge, and wasted electroplated solution hydrometallurgical treatment, and purification process. In order to be used as resource of electronic devices, the retracted crude metal should be purified to the extent of higher than 99.9%. In this study, tin electro-refining process was performed to purify the casted tin crude metal at various experimental conditions: at the current density of 3, 5A/dm2, and in various electrolytes such as hydrochloric acid, sulfuric acid and methansulfonic acid. Additional experiment was conducted using Rotating Disk Electrode (RDE) in order to investigate the rate determining step of tin electro-refining process. The current efficiency, 65.6%, was achievable at the condition of current density, 5A/dm2, and in the electrolyte of Hydrochloric acid. During tin electro-refining process, impurity dissolved from tin crude metal into the electrolyte was analyzed using Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES), and the result showed the concentration of impurity metal gradually increased. Quantitative analysis on casted tin crude metal showed that it consists of tin with 93.9 wt.% and several impurity metals of Ag, Bi, Pb, Cu, and etc. After tin electro-refining process, the purity of tin increased up to 99.985 wt.%.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1217-1220
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on Crystal Structure and Magnetic Properties of Ba4Co2Fe36O60 by Sol-Gel Method
Autorzy:
Jeong, K.-P.
Yang, S.-W.
Kim, J.-G.
Powiązania:
https://bibliotekanauki.pl/articles/351655.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
U-type ferrite
sol-gel method
nano-powder
Opis:
U-type ferrite typified by Ba4Co2Fe36O60 is used as a RAM (Radar Absorbing Materials) in the X-band (8-12 GHz). Ba4Co2Fe36O60 is known to have a complex crystal structure, which makes it difficult to obtain single phase and have low reproducibility. Previously known U-type ferrites have been fabricated based on a ceramic process that mixing (by a ball mill), calcining, grinding, binder mixing, drying, sieving, pressing and sintering. In contrast, the process of preparing the powder by the sol-gel method and its heat-treating is advantageous in that it can reduce the process steps and the required time. In addition, the precise stoichiometric control by the sol-gel method can effectively evaluate the effect of added or substituted elements. In this study investigates the crystal structure of Ba4Co2Fe36O60 synthesized by the sol-gel method and the morphology of U-type ferrite nano-powders according to various heat treatment conditions. Analysis of the crystal structure is used for XRD. Morphology and size are observed by SEM. In addition, VSM is performed to confirm the change of magnetic properties according to various heat treatment conditions.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1449-1452
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spontaneous Formation of Titanium Nitride on the Surface of a Ti Rod Induced by Electro-Discharge-Heat-Treatment in an N2 Atmosphere
Autorzy:
Lee, W. H.
Yoon, Y. H.
Kim, Y. H.
Lee, Y. K.
Kim, J. Y.
Chang, S. Y.
Powiązania:
https://bibliotekanauki.pl/articles/352477.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium
surface modification
diffusion
heat treatment
XPS
Opis:
A single pulse of 2.0 to 3.5 kJ of input energy from a 450 mF capacitor was applied to a commercially pure Ti rod in a N2 atmosphere. The surface of the Ti rod transformed from TiO2 into titanium nitride in times as short as 159 msec, providing a bimodal morphology of the cross-section. A much higher value of hardness that was observed at the edge of the cross-section was attributed to nitrogen-induced solid-solution hardening that occurred during the electrical discharge process. The activation energy (Ea) for the diffusion process was estimated to be approximately 86.9 kJ/mol. Results show that the electrical discharge process is a possible potential method for the nitriding of Ti; advantages include a short processing time and control of the nitrided layer without dimensional changes.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1281-1285
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solvent Extraction of Co, Ni and Mn from NCM Sulfate Leaching Solution of Li(NCM)O2 Secondary Battery Scraps
Autorzy:
Hong, H. S.
Kim, D. W.
Choi, H. L.
Ryu, S.-S.
Powiązania:
https://bibliotekanauki.pl/articles/355577.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
waste recycling
NCM-system lithium ion battery
reduction
leaching
Opis:
As a part of the study on recycling Li(NCM)O2 lithium-ion battery scraps, solvent extraction experiments were performed using different extraction agents such as PC88A, Cyanex272 and D2EHPA to separate Co, Ni and Mn from the leaching solution. When the ratio of Mn to Ni was about 0.4 in the leaching solution, the separation factor for Co and Mn was found to be less than 10 so that the separation of Co and Ni was insufficient. When solvent extraction was done using the solution with the lower Mn/Ni ratio of 0.05 where Mn was removed by potassium permanganate and chlorine dioxide, more than 99% of Mn could be extracted through five courses of extraction using 30vol% D2EHPA while the extraction rates of Co and Ni were around 17% and 11%, respectively. In the case that Mn was removed from the solution, the extraction rate of Co was higher than 99% whereas less than 7% Ni was extracted using Cyanex272 suggesting that Co and Ni elements were effectively separated.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1011-1014
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sintering and Microstructures of SUS 316L Powder Produced by 3D Printing Process
Autorzy:
Kim, W. J.
Nguyen, H.-H.
Kim, H. Y.
Nguyen, M.-T.
Park, H. S.
Kim, J.-C.
Powiązania:
https://bibliotekanauki.pl/articles/356018.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
stainless steel
3D printing
selective laser sintering
SUS 316L
flake powder
Opis:
Selective laser sintering (SLS) is a type of laminating sintering technique, using CO2 laser with (metal, polymer, and ceramic) powders. In this result, the flake SUS 316L was used to achieve a high porous product, and compare to spherical type. After SLS, the porosity of flake-type sample with 34% was quite higher than that of the spherical-type one that had only 11%. The surface roughness of the flake SLS sample were also investigated in both inner and surface parts. The results show that the deviation of the roughness of the surface part is about 64.40μm, while that of the internal one was about 117.65μm, which presents the containing of high porosity in the uneven surfaces. With the process using spherical powder, the sample was quite dense, however, some initial particles still remained as a result of less energy received at the beneath of the processing layer.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1215-1218
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Similarity of chromosome structure among Populus tremula var. davidiana, Populus alba and their hybrids revealed by FISH karyotype analysis
Autorzy:
Kim, Y.G.
Kwon, S.H.
Kang, H.I.
Yoem, D.B.
Kim, K.W.
Kim, H.H.
Kang, K.S.
Powiązania:
https://bibliotekanauki.pl/articles/2077655.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
Karyotype analysis
Fluorescence in situ hybridization
Ribosomal DNA site
Poplar
Cytogenetics
Opis:
The genus Populus is one of the important tree species in Korean peninsula and many other coun- tries in the world. It represents the model species of forest genomics because it grows fast and reproduces rapidly. In this reason, their genetic characteristics have been well studied and the whole genome has been sequenced completely in some species. However, cytogenetic study of the genus Populus has been limited. In the present study, karyotypes of Korean aspen (P. tremula var. davidiana), Silver poplar (P. alba) and their two hybrids, Suwon aspen (P. tremula var. glandulosa) and Hyun aspen (P. alba × P. tremula var. glandulsa) were analyzed by means of the fluorescence in situ hybridization (FISH). Root samples were collected from mature trees in the demonstration forest, located at Suwon, Kyonggi province in South Korea. The fresh root cells were examined by DAPI (4’,6-diamidino-2-phenylindole) staining and FISH using 45S rDNA and 5S rDNA probes. As the results, the chromosome compositions of all species were the same as 2n = 38. The karyotype formulas of Korean aspen, Silver poplar, Suwon aspen and Hyun aspen were 28m + 6sm + 4st (2sat), 26m + 10sm (2sat) + 2st, 26m + 12sm (2sat) and 28m + 10sm (2sat), respectively. The four species had one pair of 45S rDNA site and one pair of 5S rDNA site in common with FISH karyotypes. The similarity of FISH karyotypes among four species indicated close genetic relationship and coexistence of their interspecific hybrids. This research will provide genetic information on cytogenetic research of Populus and genetic mapping that can be applied to the breeding program of Populus in the near future.
Źródło:
Dendrobiology; 2020, 83; 68-74
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation Mechanism of Ti5Si3 Compact Obtained by Electro-Discharge-Sintering Directly from Physically Blended Ti-37.5 At.% Si Powder Mixture
Autorzy:
Chang, S. Y.
Cheon, Y. W.
Yoon, Y. H.
Kim, Y. H.
Kim, J. Y.
Lee, Y. K.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/353022.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sintering
mechanical alloying
powder consolidation
intermetallic compounds
titanium silicide
Opis:
Characteristics of electro-discharge-sintering of the Ti-37.5at.% Si powder mixture was investigated as a function of the input energy, capacitance, and discharge time without applying any external pressure. A solid bulk of Ti5Si3 was obtained only after in less than 129 μsec by the EDS process. During a discharge, the heat is generated to liquefy and alloy the particles, and which enhances the pinch pressure can condensate them without allowing a formation of pores. Three step processes for the self-consolidation mechanism during EDS are proposed; (a) a physical breakdown of oxide film on elemental as-received powder particles, (b) alloying and densifying the consolidation of powder particles by the pinch pressure, and (c) diffusion of impurities into the consolidated surface.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1299-1302
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation Mechanism Of Porous Ti-6Al-4V Implant Prototypes Produced By Electro-Discharge-Sintering Of Spherical Ti-6Al-4V Powders
Mechanizm autokonsolidacji prototypów porowatych implantów wytworzonych przez spiekanie sferycznych proszków Ti-6Al-4V
Autorzy:
Lee, W. H.
Jo, Y. J.
Kim, Y. H.
Jo, Y. H.
Seong, J. G.
Van Tyne, C. J.
Chang, S. Y.
Powiązania:
https://bibliotekanauki.pl/articles/356277.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Ti-6Al-4V
implant
porous
sintering
electrodischarge
porowatość
spiekanie
proszki spiekane
Opis:
Electro-Discharge-Sintering (EDS) was employed to fabricate Ti-6Al-4V porous implant prototypes from atomized powders (100 – 150 μm), that were subjected to discharges of 0.75 to 2.0 kJ/0.7g-powder from 150, 300, and 450 μF capacitors. Both fully porous and porous-surfaced Ti-6Al-4V compacts with various solid core sizes were self-consolidated in less than 86 – 155 μsec. It is known that EDS can simultaneously produce the pinch pressure to squeeze and deform powder particles and the heat to weld them together. The formation of a solid core in these prototypes depends on the amounts of both the pinch pressure and heat generated during a discharge. The size of the solid core and the thickness of the porous layer can be successfully controlled by manipulating the discharge conditions such as input energy and capacitance.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1185-1189
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation and Surface Modification of Mechanical Alloyed Ti-25.0 at.% Al Powder Mixture by Using an Electro-Discharge Technique
Autorzy:
Chang, S. Y.
Jang, H. S.
Yoon, Y. H.
Kim, Y. H.
Kim, J. Y.
Lee, Y. K.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/354212.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sintering
mechanical alloying
powder consolidation
intermetallic compounds
titanium aluminides
Opis:
Electrical discharges using a capacitance of 450 μF at 0.5, 1.0, and 1.5 kJ input energies were applied in a N2 atmosphere to obtain the mechanical alloyed Ti3Al powder without applying any external pressure. A solid bulk of nanostructured Ti3Al was obtained as short as 160 μsec by the Electrical discharge. At the same time, the surface has been modified into the form of Ti and Al nitrides due to the diffusion process of nitrogen to the surface. The input energy was found to be the most important parameter to affect the formation of a solid core and surface chemistry of the compact.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1293-1297
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reaction Kinetics and Morphological Study of TiNb2O7 Synthesized by Solid-State Reaction
Autorzy:
Choi, S. H.
Ali, B.
Choi, K. S.
Hyun, S. K.
Sim, J. J.
Choi, W. J.
Joo, W.
Lim, J. H.
Lee, T. H.
Kim, T. S.
Park, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/355326.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
solid state reaction
kinetic analysis
quantitative phase analysis
TiNb2O7 synthesis
Opis:
Although TiNb2O7 is regarded as a material with high application potential in lithium-ion batteries (LIBs) and solid-oxide fuel cells (SOFCs), it has been difficult to find suitable cost-effective conditions for synthesizing it on a commercial scale. In this study, TiNb2O7 compounds were synthesized by a solid state synthesis process. For stoichiometrically precise synthesis of the TiNb2O7 phase, the starting materials, TiO2 and Nb2O5 were taken in a 1:1 molar ratio. Activation energy and reaction kinetics of the system were investigated at various synthesis temperatures (800,1000,1200, and 1400°C) and for various holding durations (1,5,10, and 20 h). Furthermore, change in the product morphology and particle size distribution were also evaluated as a function of synthesis temperature and duration. Additionally, quantitative phase analysis was conducted using the Rietveld refinement method. It was found that increases in the synthesis temperature and holding time lead to increase in the mean particle size from 1 to 4.5 μm. The reaction rate constant for the synthesis reaction was also calculated.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1051-1056
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation Of Fine Grained SiC At Reduced Temperature By Two-Step Sintering
Wytwarzanie drobnoziarnistego SiC w obniżonej temperaturze przez dwuetapowe spiekanie
Autorzy:
Kim, K.-W.
Oh, K.-S.
Lee, H.
Kim, B. S.
Chung, T.-J.
Powiązania:
https://bibliotekanauki.pl/articles/353772.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
SiC
liquid phase
two step sintering
coarsening
hardness
faza ciekła
spiekanie dwuetapowe
odporność
twardość
Opis:
Two-step sintering route was applied for the densification SiC by promoting the role of liquid phase. The specimen contained 8 vol% of liquid phase composed of Al2O3 and Y2O3. The heating schedule consisted with initial rapid heating to 2000°C and immediate quenching to 1700 or 1750°C. By heating at elevated temperature, even distribution of the liquid phase was intended. The heat treatment at reduced temperature was to suppress the evaporative loss of the liquid and to secure the time for densification. The two-step sintering effectively suppressed loss of mass and coarsening. The resultant SiC was thus dense and was composed of fine grains exhibiting hardness of 2321 kgf/mm2.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1539-1542
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photodynamic therapy of red and blue lights on Malassezia pachydermatis: an in vitro study
Autorzy:
Kim, W.R.
Bae, S.G.
Oh, T.H.
Powiązania:
https://bibliotekanauki.pl/articles/2087782.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
dog
LEDs
PDT
Malassezia infection
Źródło:
Polish Journal of Veterinary Sciences; 2018, 21, 1; 185-191
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oxidation Behavior of Steel with Cr Content and Water Flow Rate
Autorzy:
Kim, D.-J.
Kim, K. M.
Shin, J. H.
Cheong, Y. M.
Lee, E. H.
Lee, G. G.
Kim, S. W.
Kim, H. P.
Choi, M. J.
Lim, Y. S.
Hwang, S. S.
Powiązania:
https://bibliotekanauki.pl/articles/351548.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
steel
flow accelerated corrosion
Cr content
flow rate
surface oxides
Opis:
Fast water flow facilitates ferrous ion transport leading to flow accelerated corrosion (FAC) of carbon steel and the possibility of a large accident through a failure of a secondary pipe in a nuclear power plant. Ion transport is directly linked to oxide properties such as the thickness, chemical composition and porosity. This work deals with a precise observation of the cross section of the corroded specimen focusing on an oxide passivity and its thickness using SEM (scanning electron microscope) and TEM (transmission electron microscope) as well as an apparent weight loss and a surface observation for the specimens corroded using a rotating cylindrical electrode autoclave system in pure water of pH 7 at 150°C having dissolved oxygen below 1 ppb within a flow rate range of 0 to 10 m/s. The Cr content in steel was changed from 0.02 to 2.4 wt%. Increasing the Cr content in the alloy, the FAC rate and oxide thickness decreased. The oxide porosity tends to decrease with the Cr content and immersion time owing to the development of Cr containing oxide. The oxidation behavior is not changed with the immersion time.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1383-1387
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł

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