- Tytuł:
- $[FeCl_{4}]¯$ Ionic Liquid Based Ferrofluids
- Autorzy:
-
Parnica, J.
Kesa, P.
Kovac, J.
Timko, M.
Antalik, M. - Powiązania:
- https://bibliotekanauki.pl/articles/1368745.pdf
- Data publikacji:
- 2014-07
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
87.64.kp
75.50.Bb
47.65.Cb
75.50.Mm - Opis:
- Magnetic ionic liquids derived from hydrochloride methyl ester alanine amino acids (AA) and $FeCl_{3}$ were synthesized in ethanol and their magnetic properties were investigated. Iron (III) chloride forms ionic liquid in ethanol at saturated concentrations by the transfer of Cl¯ anion from one molecule of $FeCl_{3}$ to the other molecule with the creation of tetrachloro ferrate anion $[FeCl_{4}]$¯ as well as dimer $[Fe_{2}Cl_{7}]$¯. Raman scattering indicates that after addition of hydrochloride methyl ester alanine to ethanol solutions of $FeCl_{3}$ increase the intensities of signal at the frequencies at 318 $cm^{-1}$ and 380 $cm^{-1}$ as markers for the presence of $[FeCl_{4}]$¯ and $[Fe_{2}Cl_{7}]$¯ complexes. The magnetization at room temperature showed in both samples a linear dependence on the applied magnetic field. On the other hand, in the Raman scattering experiments the magnetization is smaller for $FeCl_{3}$ sample in the presence of methyl ester alanine.
- Źródło:
-
Acta Physica Polonica A; 2014, 126, 1; 276-277
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł