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Wyświetlanie 1-12 z 12
Tytuł:
Ag+/S2O8 2– system for the degradation of aqueous flutriafol
Autorzy:
Yang, H.
Zhou, W.
Yang, L.
Deng, J.
Hu, Q.
Wei, H.
Au, C.
Yi, B.
Powiązania:
https://bibliotekanauki.pl/articles/207760.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chemical analysis
degradation
free radicals
metal ions
molecular orbital
transition metals
analiza chemiczna
degradacja
wolne rodniki
jony metali
orbital molekularny
metale przejściowe
Opis:
The degradation of flutriafol in aqueous persulfate (S2O82–) system in the presence of selected transition metal ions was investigated. In the presence of Ag+ or Fe2+, flutriafol degradation occurs, whereas in the presence of Mn2+, Co2+, Ni2+, Cu2+, Zn2+ and Bi3+ ions, the degradation is less than 15%. The Ag+/ S2O82– aqueous system being the most effective was adopted for experimental and theoretical investigations. It was confirmed that pH of 3.0 is the most suitable, and that both · SO4and ·OH– radicals are the main active species to afford flutriafol degradation, with the former contributes more than the latter. To elucidate degradation mechanism, molecular orbital calculations were performed and reaction intermediates identified by GC/MS and HPLC/MS/MS analyses. Three degradation pathways are proposed that involve the cleavage of C–N and C–C bonds as a result of ·SO4 attack, as well as the formation of hydroxylated products due to · OH radicals.
Źródło:
Environment Protection Engineering; 2018, 44, 2; 57-72
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of polyacrylic acid on the surface properties of calcite and fluorite aiming at their selective flotation
Autorzy:
Zhang, C.
Gao, Z.
Hu, Y.
Sun, W.
Tang, H.
Yin, Z.
He, J.
Guan, Q.
Zhu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/110577.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
calcite
fluorite
selective flotation
polyacrylic acid
Opis:
In this study, the polyacrylic acid (PAA) was studied as a selective depressant for calcite in the selective flotation of fluorite and calcite, and the implications of this process for the separation of fluorite ore were studied using micro-flotation tests, and the results were analyzed with Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) analyses. The flotation tests indicated that the preferential adsorption of PAA onto calcite rather than sodium oleate (NaOl) could selectively depress the flotation of calcite, allowing its separation from fluorite at pH 7. The zeta potential of calcite became more negative with the addition of PAA rather than with NaOl. However, the characteristic features of PAA adsorption were not observed for fluorite, suggesting that NaOl preferentially adsorbed on the surface of fluorite, or that PAA could be replaced by NaOl on the fluorite surface. FT-IR and XPS analysis were utilized to obtain a better understanding of the mechanism by which PAA was more strongly adsorbed on the calcite surface than NaOl. This was revealed to occur through chemical bonding between the carboxyl group of PAA and the hydroxyl groups of the Ca species on the calcite surface, modifying the structure of the adsorbed layer. A possible adsorption mechanism, along with a postulated adsorption mode for the surface interaction between PAA and calcite, is proposed.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 868-877
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inversion of side scan sonar motion and posture in seabed geomorphology
Autorzy:
Tao, W.
Liu, Y.
Hu, H.
Powiązania:
https://bibliotekanauki.pl/articles/258774.pdf
Data publikacji:
2017
Wydawca:
Politechnika Gdańska. Wydział Inżynierii Mechanicznej i Okrętownictwa
Tematy:
side scan sonar
image matching
image fusion
neutral network
motion inversion
Opis:
Side scan sonar measurement platform, affected by underwater environment and its own motion precision, inevitably has posture and motion disturbance, which greatly affects accuracy of geomorphic image formation. It is difficult to sensitively and accurately capture these underwater disturbances by relying on auxiliary navigation devices. In this paper, we propose a method to invert motion and posture information of the measurement platform by using the matching relation between the strip images. The inversion algorithm is the key link in the image mosaic frame of side scan sonar, and the acquired motion posture information can effectively improve seabed topography and plotting accuracy and stability. In this paper, we first analyze influence of platform motion and posture on side scan sonar mapping, and establish the correlation model between motion, posture information and strip image matching information. Then, based on the model, a reverse neural network is established. Based on input, output of neural network, design of and test data set, a motion posture inversion mechanism based on strip image matching information is established. Accuracy and validity of the algorithm are verified by the experimental results.
Źródło:
Polish Maritime Research; 2017, S 2; 81-88
1233-2585
Pojawia się w:
Polish Maritime Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Research on Characterization of Crushability for Foundry Sand Particles
Autorzy:
Dai, Y.
Ma, Q. Y.
Li, X. H.
Zhang, X.
Hu, F. P.
Zhang, Y.
Xie, W. D.
Powiązania:
https://bibliotekanauki.pl/articles/379689.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
foundry sand particle
mechanical load
AFS grain fineness
crushability
piasek odlewniczy
obciążenie mechaniczne
rozdrobnienie ziarna
Opis:
In this paper, crushability of foundry sand particles was studied. Three kinds of in-service silica sands in foundry enterprises selected as the study object, and foundry sand particles were subjected to mechanical load and thermal load during service were analyzed. A set of methods for simulating mechanical load and thermal load by milling and thermal-cold cycling were designed and researched, which were used to characterize the crushability for silica sand particles, the microstructure was observed by SEM. According to the user’s experience in actual application, the crushability of Sand C was the best and then Sand B, the last Sand A. The results indicated that mechanical load, thermal load and thermal-mechanical load can all be used to characterize the crushability of foundry sand particles. Microscopic appearances can qualitatively characterize the crushability of foundry sand particles to a certain extent, combining with the additions and cracks which are observed on the surface.
Źródło:
Archives of Foundry Engineering; 2017, 17, 4; 231-235
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorptive performance of MCM-41 towards hg(II) in water. Adsorption and desorption studies
Autorzy:
Zhai, Q. Z.
Hu, W.-H.
Guo, X.-Y.
Powiązania:
https://bibliotekanauki.pl/articles/208154.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
electron microscopy
mesoporous silicates
cetyltrimethylammonium bromide
adsorption conditions
mikroskopia elektronowa
krzemiany mezoporowate
bromek cetyltrimethylammonium
warunki adsorpcyjne
Opis:
MCM-41 mesoporous material was prepared under a standard conditions by using cetyltrime-thylammonium bromide as a structure-directing agent and tetraethyl orthosilicate as silica source from the liquid phase at 80 °C. Powder X-ray diffraction and scanning electron microscopy used to characterize the product, showed that the MCM-41material had an average particle size of 110 nm. The synthesized material was used to investigate the effects of acidity, adsorption time, the concentration of Hg2+, adsorbent dosage and temperature on the adsorption of Hg2+. The results showed that the optimal adsorptive conditions were: pH 5.0, m(MCM-41):mHg2+ 6.67, temperature 20 °C and contact adsorption time 60 min, for the initial Hg2+concentration of 1.0 mg/cm3. The maximum adsorptive amount of Hg2+ was 56.48 mg Hg2+/g MCM-41. The results of the desorptive effect of three desorption agents such as HCl, HNO3 and HAc showed that the best desorbent was HCl at the concentration of 0.10 mol/dm3. The highest desorption efficiency was 77.21% for the desorption time 2 h.
Źródło:
Environment Protection Engineering; 2016, 42, 1; 5-15
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Acid alpha-galactosidase is involved in D-chiro-inositol accumulation during tartary buckwheat germination
Autorzy:
Jia, C.-F.
Hu, W.-H.
Chang, Z.
Gao, H.-L.
Powiązania:
https://bibliotekanauki.pl/articles/59199.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Botaniczne
Tematy:
alpha-galactosidase
D-chiro-inositol
accumulation
tartary buckwheat
Fagopyrum tataricum
duckwheat zob.tartary buckwheat
India buckwheat zob.tartary buckwheat
India wheat zob.tartary buckwheat
green buckwheat zob.tartary buckwheat
germination
gene expression
Opis:
Tartary buckwheat seed and especially its sprouts are rich in D-chiroinositol (DCI). The research was to evaluate when DCI was most accumulated in tartary buckwheat sprouts. In addition, we explored the activity and expression pattern of α-galactosidase during tartary buckwheat seed germination. The results showed that DCI contents steadily increased at early stage of germination and reached the highest level of 33.42 μg/seed at 24 h during the 72 h trail. However, the total fagopyritol contents sharply decreased from 214.6 μg/seed to 46 μg/seed at the end of the germination. The activity of acid α-galactosidase increased gradually to the peak of 0.36 nkat/seed at 24 h after the primed seed imbibition. We cloned the gene fragment of α-galactosidase in tartary buckwheat for the first time. The deduced amino acid sequence is 93% identical to that of P. vulgaris. The quantitative PCR result of gene expression pattern was consistent with its enzyme activity during seed germination.
Źródło:
Acta Societatis Botanicorum Poloniae; 2015, 84, 1
0001-6977
2083-9480
Pojawia się w:
Acta Societatis Botanicorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Argon Plasma in a New Process for Improving the Physical and Anti-bacterial Properties of Crosslinked Cotton Cellulose with Dimethyloldihydroxyethyleneurea-Maleic Acid
Zastosowanie plazmy niskotemperaturowej w środowisku argonu w procesie obróbki tkanin bawełnianych sieciowanych za pomocą kwasu dimetylodihydroxyetylenourylomaleinowego dla polepszenia właściwosci fizycznych oraz antybakteryjnych
Autorzy:
Tsou, C H
Suen, M C
Tsou, C Y
Chen, J C
Yeh, J T
Lin, S M
Lai, Y C
Hwang, J Z
Huang, S H
Hung, W S
Hu, C C
Lee, K R
Lai, J Y
Powiązania:
https://bibliotekanauki.pl/articles/232331.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
cotton
plasma
antibacterial
crosslinking
crosslink length
crosslinks number per anhydroglucose
surface distribution
odour absorption
bawełna
plazma
właściwości antybakteryjne
sieciowanie tkanin bawełnianych
kwas dimetylodihydroxyetylenourylomaleinowy
odporności na zagniecenia
pochłanianie zapachów
żywica termoutwardzalna
Opis:
This study reports the findings of an argon (Ar) plasma treatment added to the traditional pad-dry-cure process between dry and cure treatments. This new process is called the "paddry-plasma-cure process". The crosslinking agent was a mixture of dimethyloldihydroxyethyleneurea (DMDHEU) and maleic acid (MA). Results show that Ar plasma treatment can increase the bonded crosslinking agent (i.e., the nitrogen content). The dry crease recovery angle (DCRA), wet crease recovery angle (WCRA), and tensile strength retention (TSR) of the pad-dry-plasma-cure finished fabrics were higher than those of traditional pad-dry-cure finished fabrics at a given nitrogen content. Additionally it was found that the number of crosslinks per anhydroglucose unit (CL/AGU) and the length of crosslinks of pad-dry-plasma-cure-finished fabrics were higher than that of traditional pad-dry-cure finished fabrics at the same resin concentration in the pad bath. DCRA, WCRA and TSR values of pad-dry-plasma-cure-finished fabrics were higher than those of pad-dry-curefinished fabrics at the same CL/AGU value. However, activation energies for the pad-dryplasma-cure process were higher than those for the pad-dry-cure process. The anti-bacterial ability and odour absorption of the pad-dry-plasma-cure and pad-dry-plasma-cure finished fabrics were higher than those for the pad-dry-cure finished fabrics. The surface distribution of crosslinking agents for the pad-dry-plasma-cure process was higher than that of the pad-dry-cure process. Thus the pad-dry-plasma-cure process is excellent for improving the physical properties, bacterial inhibition, and odour absorption of finished cotton fabrics and for decreasing their formaldehyde release.
Artykułu odnosi się do problematyki możliwości i celowości wprowadzenia modyfikacji plazmowej w warunkach niskociśnieniowych i w środowisku argonu do konwencjonalnego procesu wykończenia przeciw mnącego z zastosowaniem reaktywnych żywic termoutwardzalnych. Badano kąt odprężenia na sucho i na mokro, i stwierdzono polepszenie właściwości odporności na zagniecenia w wyniku dodatkowego zastosowania plazmy. Badano również właściwości antybakteryjne i pochłanianie zapachów, które okazały się korzystniejsze dla dodatkowej obróbki plazmowej. W wyniku zmodyfikowanej obróbki uzyskano mniejsze wydzielanie formaldehydu z gotowej tkaniny.
Źródło:
Fibres & Textiles in Eastern Europe; 2015, 1 (109); 49-56
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Free chlorine loss during spraying of membraneless acidic electrolyzed water and its antimicrobial effect on airborne bacteria from poultry house
Autorzy:
Zhao, Y.
Xin, H.
Zhao, D.
Zheng, W.
Tian, W.
Ma, H.
Liu, K.
Hu, H.
Wang, T.
Soupir, M.
Powiązania:
https://bibliotekanauki.pl/articles/49243.pdf
Data publikacji:
2014
Wydawca:
Instytut Medycyny Wsi
Źródło:
Annals of Agricultural and Environmental Medicine; 2014, 21, 2
1232-1966
Pojawia się w:
Annals of Agricultural and Environmental Medicine
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure and Improvement of Properties of Floss Silk via Scouring and Finishing Treatment
Struktura i możliwość poprawy właściwości jedwabiu naturalnego poprzez procesy wykończenia
Autorzy:
Lin, H.
Ma, P.
Ning, W.
Huang, J.
Jiang, F.
Hu, Z.
Xiao, H.
Powiązania:
https://bibliotekanauki.pl/articles/233484.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
floss silk
finishing treatment
structure
silk fibre properties
nici jedwabne
obróbka wykańczająca
struktura
właściwości włókien jedwabiu
Opis:
In the present study, floss silk was treated by scouring and finishing, respectively. The micro structure was observed with scanning electron microscopy (SEM), the mechanical property tested by an Instron 5566 tensile tester, and the crystal structure was analysed with Fourier transform attenuated total reflection infrared spectroscopy (FTIR) and X-ray diffraction (XRD), respectively. The results show that the properties of floss silk treated with the refining method are better than with the alkali method.
Badania dotyczyły obróbki wykańczalniczej jedwabiu naturalnego. Mikrostruktura jedwabiu była badana za pomocą skaningowej mikroroskopii elektronowej, a właściwości mechaniczne testowane były klasyczną zrywarką firmy Instron, podczas gdy strukturę krystaliczną analizowano za pomocą spektroskopii w podczerwieni (FTIR) oraz rozproszenia promieniowania rentgenowskiego. Wyniki pozwoliły wytypować najlepszą w danych warunkach metodę obróbki.
Źródło:
Fibres & Textiles in Eastern Europe; 2013, 3 (99); 18-21
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Circulation and winter deep-water formation in the Northern Red Sea
Autorzy:
Manasrah, R.
Badran, M.
Lass, H.U.
Fennel, W.
Powiązania:
https://bibliotekanauki.pl/articles/49153.pdf
Data publikacji:
2004
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
Aqaba Gulf
eddy
deep-water formation
winter
circulation
Red Sea
Opis:
Water mass characteristics and circulation patterns in the Gulf of Aqaba and northern Red Sea were studied for the first time during the r/v ‘Meteor’ cruise leg 44/2 from February 21st to March 7th 1999 using temperature-salinity profiles and current observations. The deep water in the northern Red Sea had similar characteristics to the well-mixed upper 450 m of water in the Gulf of Aqaba. This indicates that the winter mixed waters of the Gulf of Aqaba contribute significantly to deep-water in the northern Red Sea. Mixing in the Gulf of Aqaba is an annually repeated event that starts with the cooling of the surface water during November–December and reaches a maximum, which in most years extends down the entire water column in March–April. Waters deeper than the mixed layer in the Gulf seems to be rather passive and play no specific role in water mass formation in the northern Red Sea. In contrast to the Gulf of Aqaba, the upper 200 m of the northern Red Sea were stratified (21.5–23.5◦C, and 40.0–40.3 PSU). Stratification at the Strait of Tiran was weak (21.6–22.0◦C, and 40.3–40.5 PSU) and disappeared abruptly in the Gulf of Aqaba (21.4–21.6◦C, and 40.6–40.7 PSU). A well-developed cyclonic gyre with a diameter of about 50–60 km and maximum velocity of about 0.4 m s−1 was observed in the stratified upper 200 m of the northern Red Sea waters. The gyre may contribute to the preconditioning for intermediate water formation in the northern Red Sea.
Źródło:
Oceanologia; 2004, 46, 1
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical Reactions and Electronic Functions of Carbon Cluster Arrays Studied by Scanning Tunneling Spectroscopy and High-resolution Electron Energy Loss Spectroscopy
Autorzy:
Kasuya, A.
Hu, C.-W.
Suto, S.
Tohji, K.
Takahashi, H.
Czajka, R.
Wawro, A.
Nishina, Y.
Powiązania:
https://bibliotekanauki.pl/articles/1968721.pdf
Data publikacji:
1998-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.16.Ch
61.14.Rq
73.61.Wp
Opis:
Novel nanometer scale structures have been produced by thermal heating or laser irradiation on the surface of single- and multi-layers of C$\text{}_{60}$ and C$\text{}_{84}$ on Si. These structures were examined by combined measurements of scanning tunneling spectroscopy and high resolution electron energy loss spectroscopy. The results show specific chemical reactions of substrate with carbon clusters having single- and double-bonded network. Covalent bonds are formed in some of these chemical reactions.
Źródło:
Acta Physica Polonica A; 1998, 93, 2; 317-322
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-12 z 12

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