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Tytuł:
Cotton Fibre-to-Yarn Engineering: A Simulated Annealing Approach
Przetwarzanie włókien bawełnianych na przędze – problem optymalizacji
Autorzy:
Das, S.
Ghosh, A.
Powiązania:
https://bibliotekanauki.pl/articles/233554.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
cotton fibre properties
Frydrych model
simulated annealing
yarn strength
yarn engineering
właściwości włókien bawełnianych
model Frydrych
metoda symulacji SA
wytrzymałość przędzy
inżynieria przędzy
Opis:
In this paper we undertake to engineer yarn of predefined strength by choosing suitable raw material and process parameters. In an attempt to achieve a yarn of optimal strength, the constrained optimisation problem is formulated with the relation between raw material and yarn properties. Frydrych’s theoretical model of yarn strength is used for formulation of the optimisation problem. The simulated annealing (SA) method has been used to solve the optimisation problem by researching the best combination of raw material and process parameters that can bring into reality a yarn with the strength desired. The results show that SA is capable of ascertaining a set of parameters that gives the yarn strength desired.
W pracy podjęto próbę otrzymywania przędzy o określonej wytrzymałości poprzez wybór odpowiedniego surowca i parametrów procesu przędzenia. W celu otrzymania przędzy o optymalnej wytrzymałości sformułowano problem optymalizacji zawierający zależności pomiędzy surowcem i właściwościami przędzy. Zastosowano przy tym teoretyczny model Frydrych wytrzymałości przędzy a także metodę symulacji SA. Udokumentowano, że za pomocą zastosowanej metody symulacji można sprecyzować zestaw parametrów, który umożliwia osiągniecie zakładanej wytrzymałości przędzy.
Źródło:
Fibres & Textiles in Eastern Europe; 2015, 3 (111); 51-53
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ocean acidification and marine microorganisms: responses and consequences
Autorzy:
Das, S.
Mangwani, N.
Powiązania:
https://bibliotekanauki.pl/articles/49020.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
acidification
ocean
water microorganism
climate change
ecosystem
marine environment
primary production
trace gas
nitrogen fixation
community composition
organic matter
enzyme activity
Źródło:
Oceanologia; 2015, 57, 4
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spatial Resolution Test of a Beam Profile Monitoring System for the Double Electrostatic Ion Storage Ring
Autorzy:
Das, S.
Källberg, A.
Powiązania:
https://bibliotekanauki.pl/articles/1195610.pdf
Data publikacji:
2014-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
07.05.Pj
07.77.Ka
07.05.Fb
Opis:
A beam profile monitoring system based on the imaging of low energy electrons created when the ion beam impinges on a metal plate was built to monitor the beam profile and to cover the wide range of beam intensities and energies for the DESIREE (Double ElectroStatic Ion Ring ExpEriment) beam line diagnostics. The spatial resolution of the system was tested with different beams of various energies and was found to be around 2 mm. A significant steering effect on the ion beam before hitting the metallic foil was observed at low energies.
Źródło:
Acta Physica Polonica A; 2014, 125, 1; 13-17
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Technique Based on Fuzzy Logic for Cotton Bale Lay-down Management
Nowa technika zarządzania składowaniem bel bawełny
Autorzy:
Das, S.
Ghosh, A.
Powiązania:
https://bibliotekanauki.pl/articles/232810.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
cotton bale
cluster analysis
fibre property
fuzzy logic
fuzzy c-means algorithm
składowanie bawełny
logika rozmyta
bela bawełny
Opis:
In this paper a new technique has been proposed for cotton bale management using fuzzy logic. The fuzzy c-means clustering algorithm has been applied for clustering cotton bales into 5 categories from 1200 randomly chosen bales of the J-34 variety. In order to cluster bales of different categories, eight fibre properties, viz., the strength, elongation, upper half mean length, length uniformity, short fibre content, micronaire, reflectance and yellowness of each bale have been considered. The fuzzy c-means clustering method is able to handle the haziness that may be present in the boundaries between adjacent classes of cotton bales as compared to the K-means clustering method. This method may be used as a convenient tool for the consistent picking of different bale mixes from any number of bales in a warehouse.
W artykule zaproponowano nową technikę zarządzania składowaniem bawełny opartą na logice rozmytej. Badaniu poddano 1200 losowo wybranych bel bawełny. W celu pogrupowania bel w 5 kategoriach zbadano właściwości, tj. wytrzymałość, wydłużenie, średnią długość, jednorodność długości, zawartość włókien krótkich, dojrzałość, współczynnik odbicia i zażółcenie każdej beli. Opracowana metoda może być stosowana jako wygodne narzędzie do sortowania różnych mieszanek z dowolnej liczby bel w magazynie.
Źródło:
Fibres & Textiles in Eastern Europe; 2017, 2 (122); 30-33
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Group decision making using interval-valued intuitionistic fuzzy soft matrix and confident weight of experts
Autorzy:
Das, S.
Kar, S.
Pal, T.
Powiązania:
https://bibliotekanauki.pl/articles/91665.pdf
Data publikacji:
2014
Wydawca:
Społeczna Akademia Nauk w Łodzi. Polskie Towarzystwo Sieci Neuronowych
Tematy:
multiple attribute group decision making
MAGDM
interval-valued intuitionistic fuzzy soft matrix
IVIFSM
interval-valued intuitionistic fuzzy soft sets
IVIFSSs
Opis:
This article proposes an algorithmic approach for multiple attribute group decision making (MAGDM) problems using interval-valued intuitionistic fuzzy soft matrix (IVIFSM) and confident weight of experts. We propose a novel concept for assigning confident weights to the experts based on cardinals of interval-valued intuitionistic fuzzy soft sets (IVIFSSs). The confident weight is assigned to each of the experts based on their preferred attributes and opinions, which reduces the chances of biasness. Instead of using medical knowledgebase, the proposed algorithm mainly relies on the set of attributes preferred by the group of experts. To make the set of preferred attributes more important, we use combined choice matrix, which is combined with the individual IVIFSM to produce the corresponding product IVIFSM. This article uses IVIFSMs for representing the experts’ opinions. IVIFSM is the matrix representation of IVIFSS and IVIFSS is a natural combination of interval-valued intuitionistic fuzzy set (IVIFS) and soft set. Finally, the performance of the proposed algorithm is validated using a case study from real life.
Źródło:
Journal of Artificial Intelligence and Soft Computing Research; 2014, 4, 1; 57-77
2083-2567
2449-6499
Pojawia się w:
Journal of Artificial Intelligence and Soft Computing Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
First report of twig blight of ban tulsi (Croton bonplandianus Bail.) caused by Choanephora cucurbitarum (Berk.and Ravenel) Thaxt. in India
Autorzy:
Das, S.
Dutta, S.
Ray, S.K.
Powiązania:
https://bibliotekanauki.pl/articles/65731.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
twig blight
ban tulsi
Croton bonplandianus
Euphorbiaceae
herb
perennial plant
folk medicine
Choanephora cucurbitarum
plant pathogen
sporangium
India
Opis:
In August 2015, twig blight disease of ban tulsi (Croton bonplandianus Bail.) caused by Choanephora cucurbitarum (Berk. & Ravenel) Thaxt. was observed for the first time, in the Gangetic alluvial region of West Bengal, India. A severe disease incidence (40–50%) showed twig blight symptoms starting with shoot apical meristem (SAM), leaf, and blossom blight symptoms. Typical symptoms were characterized by over-projecting black pin head like emerging sporangiola which formed mycelial cushion on the infected surface. The present report describes the identification of the causal pathogen as C. cucurbitarum based on its morphology and the internal transcribed spacer of its ribosomal DNA (rDNA – ITS) sequences with 100% identity of NCBI-GenBank published Choanephora database. Optimum temperatures, 28–30°C, coupled with high relative humidity (80–90%) during the monsoon season enhances the disease’s progress. To the best of our knowledge this is the first report of twig blight of C. bonplandianus, caused by C. cucurbitarum, in India as well as globally.
Źródło:
Journal of Plant Protection Research; 2017, 57, 4
1427-4345
Pojawia się w:
Journal of Plant Protection Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Green Function Estimation of Correction to Vegards Law for isovalent Substitutional Defects in Alkali Halide Crystals
Autorzy:
Datta Roy (Paul), S.
Das, S. K.
Powiązania:
https://bibliotekanauki.pl/articles/2013286.pdf
Data publikacji:
2000-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.72.Bb
61.82.Bg
Opis:
A Green function method is developed for estimation of lattice parameter r(χ) of an AX-BX solid solution over entire composition range (χ=0 to 1). The r(χ) obtained in the present method is different from the value r$\text{}_{V}$(χ) suggested by Vegard's law. We estimated the deviation from Vegard's law, r(χ)-r$\text{}_{V}$(χ), over entire composition range for isovalent substitutional defect in alkali halide crystals. When compared to X-ray diffraction measurements, we find that the deviation is in correct direction, variation of r(χ) with χ is consistent with experiment and the overall agreement is fairly good considering the accuracy of the experiment.
Źródło:
Acta Physica Polonica A; 2000, 97, 4; 671-679
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Earth observation and geospatial techniques for soil salinity and land capability assessment over Sundarban Bay of Bengal Coast, India
Autorzy:
Das, S.
Choudhury, M. R
Nagarajan, M.
Powiązania:
https://bibliotekanauki.pl/articles/145537.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
właściwości gleby
teledetekcja
dane satelitarne
Landsat
GIS and Remote Sensing
kriging
soil properties
land capability
Opis:
To guarantee food security and job creation of small scale farmers to commercial farmers, unproductive farms in the South 24 PGS, West Bengal need land reform program to be restructured and evaluated for agricultural productivity. This study established a potential role of remote sensing and GIS for identification and mapping of salinity zone and spatial planning of agricultural land over the Basanti and Gosaba Islands(808.314sq. km) of South 24 PGS. District of West Bengal. The primary data i.e. soil pH, Electrical Conductivity (EC) and Sodium Absorption ratio (SAR) were obtained from soil samples of various GCP (Ground Control Points) locations collected at 50 mts. intervals by handheld GPS from 0–100 cm depths. The secondary information is acquired from the remotely sensed satellite data (LANDSAT ETM+) in different time scale and digital elevation model. The collected field samples were tested in the laboratory and were validated with Remote Sensing based digital indices analysisover the temporal satellite data to assess the potential changes due to over salinization. Soil physical properties such as texture, structure, depth and drainage condition is stored as attributes in a geographical soil database and linked with the soil map units. The thematic maps are integrated with climatic and terrain conditions of the area to produce land capability maps for paddy. Finally, The weighted overlay analysis was performed to assign theweights according to the importance of parameters taken into account for salineareaidentification and mapping to segregate higher, moderate, lower salinity zonesover the study area.
Źródło:
Geodesy and Cartography; 2016, 65, 2; 163-192
2080-6736
2300-2581
Pojawia się w:
Geodesy and Cartography
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heuristic Procedure for the Assembly Line Balancing Problem With Postural Load Smoothness
Autorzy:
Jaturanonda, C.
Nanthavanij, S.
Das, S. K.
Powiązania:
https://bibliotekanauki.pl/articles/90459.pdf
Data publikacji:
2013
Wydawca:
Centralny Instytut Ochrony Pracy
Tematy:
assembly line balancing
postural load smoothness
upper extremities disorders
RULA
linia montażowa
obciążenie
kończyny górne
Opis:
This paper presents a heuristic procedure for assigning assembly tasks to workstations where both productivity and ergonomics issues are considered concurrently. The procedure uses Kilbridge and Wester’s algorithm to obtain an initial task–workstation assignment solution which minimizes the balance delay of an assembly line. A task reassignment algorithm was applied to improve the initial solution by exchanging assembly tasks, which smooth postural load among workers, between workstations. A composite index of variation was used to measure the effectiveness of the task–workstation assignment solution. On the basis of clothes assembling, it was found that the task–workstation assignment solution with a minimum composite index of variation can be obtained with relatively equal weights in balance delay and postural load.
Źródło:
International Journal of Occupational Safety and Ergonomics; 2013, 19, 4; 531-541
1080-3548
Pojawia się w:
International Journal of Occupational Safety and Ergonomics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calculation of Lattice Relaxation in Some Substitutional Alloys Using a Green Function
Autorzy:
Das, S. K.
Datta Roy (Paul), S.
Powiązania:
https://bibliotekanauki.pl/articles/1995663.pdf
Data publikacji:
1999-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.72.Bb
61.82.Bg
Opis:
In this paper we calculate nearest neighbour relaxation in some dilute substitutional alloys using a lattice static Green function and the Morse potential function. Distant neighbour relaxation is calculated by invoking a continuum approximation. The potential parameters for the unlike interactions are calculated using simple interpolation formulae. Using the above relaxation, we calculate volume changes in the above alloys. It is observed that the simple model predicts values which are in reasonably good agreement with the experimental values in all cases. The calculated values are also compared with those obtained from the Vegard law. For Au-Ag alloy, our model reproduces both the correct sign and the magnitude of the volume change, whereas the Vegard law cannot even give the sign of the volume change. This shows the inherent strength of the present model.
Źródło:
Acta Physica Polonica A; 1999, 95, 3; 359-366
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Breeding and agronomic approaches for the biofortification of zinc in wheat (Triticum aestivum L.) to combat zinc deficiency in millions of a population: a Bangladesh perspective
Biofortyfikacja pszenicy (Triticum aestivum L.) cynkiem w celu ograniczenia niedoboru cynku w populacji: perspektywa Bangladeszu
Autorzy:
Das, S.
Chaki, A.K.
Hossain, A.
Powiązania:
https://bibliotekanauki.pl/articles/27742.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Botaniczne
Opis:
The World Health Organization (WHO) has estimated that around 2 billion people across the globe are suffering from “hidden hunger”, where 815 million are under malnutrition. The major essential elements for humans are Fe, Zn, I, Se, Ca, F, and also vitamins. Among them, Zn is considered in the fifth place leading to causes of several deficiency diseases. At least one-third of the population in the world is facing Zn deficiency including around 450,000 children under the age of five. Vitamin A, Fe, and Zn deficiencies can be overcome through the biofortification of staple foodstuffs. This review emphasizes various breeding and agronomic approaches for the biofortification of Zn in wheat grains, which is an encouraging and cost-effective method to enhance the Zn contents of cereal grains. Recently, the Bangladesh Wheat and Maize Research Institute (BWMRI), with technical support from CIMMYT, Mexico, released a promising new Zn-biofortified wheat cultivar, ‘BARI Gom 33’, a result from a conventional breeding program. It has 32 and 50–55 mg kg−1 Zn without and with soil application of ZnSO4, respectively. This cultivar could be a savior for a million people in South Asia, including Bangladesh.
WHO (Światowa Organizacja Zdrowia) oceniła, że około 2 miliardy ludzi na całym świecie cierpi z powodu „ukrytego głodu”, podczas gdy 815 milionów cierpi z powodu niedożywienia. Głównymi pierwiastkami niezbędnymi w diecie dla człowieka są Fe, Zn, J, Se, Ca, F oraz witaminy. Cynk zajmuje 5 miejsce pod względem deficytu w pożywieniu, a jego niedobory prowadzą do wielu groźnych chorób. Co najmniej jedna trzecia populacji na świecie wykazuje objawy niedoboru Zn, w tym około 450000 dzieci poniżej piątego roku życia. Niedobory witaminy A, Fe i Zn można niwelować poprzez biofortyfikację podstawowych artykułów spożywczych. Niniejsza praca przeglądowa podkreśla różne podejścia hodowlane i agronomiczne do biofortyfikacji Zn w ziarniakach pszenicy, co może stanowić zachęcające i opłacalne narzędzie służące zwiększaniu zawartości Zn. Niedawno Bangladeski Instytut Badań Pszenicy i Kukurydzy (BWMRI), przy wsparciu technicznym Międzynarodowego Centrum Ulepszania Kukurydzy i Pszenicy (CIM-MYT) w Meksyku, przekazał nową, wzbogaconą w Zn odmianę biofortyfikowanej pszenicy ‘BARI Gom 33’ uzyskaną w ramach konwencjonalnego programu hodowlanego. Zawartość Zn w ziarniakach wynosi odpowiednio 32,09 i 50–55 μg L−1 Zn bez nawożenia i po doglebowym nawożeniu ZnSO4. Ta odmiana może uratować przed niedożywieniem milion ludzi w Azji Południowej, w tym w Bangladeszu.
Źródło:
Acta Agrobotanica; 2019, 72, 2
0065-0951
2300-357X
Pojawia się w:
Acta Agrobotanica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanical Properties of a Bainitic Steel Producible by Hot Rolling
Autorzy:
Rana, R.
Chen, S.
Haldar, A.
Das, S.
Powiązania:
https://bibliotekanauki.pl/articles/352494.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
carbide-free bainite
retained austenite
hot rolling
mechanical properties
Opis:
A carbide-free bainitic microstructure is suitable for achieving a combination of ultra high strength and high ductility. In this work, a steel containing nominally 0.34C-2Mn-1.5Si-1Cr (wt.%) was produced via industrial hot rolling and laboratory heat treatments. The austenitization (900°C, 30 min.) and austempering (300-400°C, 3 h) treatments were done in salt bath furnaces. The austempering treatments were designed to approximately simulate the coiling step, following hot rolling and run-out-table cooling, when the bainitic transformation would take place and certain amount of austenite would be stabilized due to suppression of carbide precipitation. The microstructures and various mechanical properties (tensile properties, bendability, flangeability, and room and subzero temperature impact toughness) relevant for applications were characterized. It was found that the mechanical properties were highly dependent on the stability of the retained austenite, presence of martensite in the microstructure and the size of the microstructural constituents. The highest amount of retained austenite (~ 27 wt.%) was obtained in the sample austempered at 375°C but due to lower austenite stability and coarser overall microstructure, the sample exhibited lower tensile ductility, bendability, flangeability and impact toughness. The sample austempered at 400°C also showed poor properties due to the presence of initial martensite and coarse microstructure. The best combination of mechanical properties was achieved for the samples austempered at 325-350°C with a lower amount of retained austenite but with the highest mechanical stability.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 4; 2331-2338
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
MIPS sequences: a promising molecular consideration in angiosperm phylogeny and systematics
Autorzy:
Hazra, A.
Nandy, P.
Sengupta, C.
Das, S.
Powiązania:
https://bibliotekanauki.pl/articles/80785.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
myo-inositol-1-phosphate synthase
protein sequence
angiosperm
phylogenesis
maximum likelihood method
multiple sequence alignment
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2018, 99, 1
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessment of antimutagenic avenue and wild plant diversity on roadside near Nature Park, Kolkata, India
Autorzy:
Das, S.
Benerjee, K.
Nandy, A.
Nath Talapatra, S.
Powiązania:
https://bibliotekanauki.pl/articles/11170.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Opis:
The study of diversity of plants in an urban area is a suitable measure of the terrestrial ecosystem. The study of avenue and wild plants diversity is an important research work, which provides knowledge about naturally occurring chemicals in plants, to protect against mutation, cancer and other diseases. These are commonly called as phytochemicals and the natural chemical ingredients are potent to use in antimutagenicity. The present study aims to understand the occurrence and population nos. of different avenue and wild plants planted or natural on roadside near Nature Park, Kolkata, India. The results clearly indicate that a total population of these plant species are having 282 nos. in the study area. Various literatures clearly revealed that these plants and/or their parts have potent antimutagenic properties by the presence of several phytochemicals. In conclusion, present preliminary research emphasizes an occurrence of antimutagenic avenue and wild plants on roadsides, containing natural chemical ingredients. Previous research works confirmed that toxins or mutagens or carcinogens may cause mutation that leads to cancer. The present study is a preliminary assessment of antimutagenic avenue and wild plant species diversity that have not yet been studied in that particular geographical area. The present study also suggested that avenue and wild plants are suitable for antimutagenic potential along with aesthetical view of human as well as ecosystem support. Therefore, biodiversity study, phytochemicals estimation and conservation of these particular plant species and/or different antimutagenic species in other local area viz. roadsides, parks, forests etc. might be relevant because the plant species can be used for herbal medicine in human healthcare as well as to prevent mutation and cancer.
Źródło:
International Letters of Natural Sciences; 2015, 02
2300-9675
Pojawia się w:
International Letters of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetics and mechanism of electron transfer to pyridinium chlorochromate (VI) from sulfur containing amino acid, L-cysteine in aqueous and micellar media
Autorzy:
Senapati, S.
Das, S.
Mohanty, P.
Patnaik, A.K.
Powiązania:
https://bibliotekanauki.pl/articles/779166.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
kinetyka
przeniesienie elektronu
chlorochromian pirydyny
cysteina
kinetics mechanism
electron transfer
pyridinium chlorochromate
cysteine
micellar media
Opis:
The electron transfer reaction of L-cysteine (RSH) with pyridinium chlorochromate (PCC) has been studied spectrophotometrically over the range 2.0 ≤ 10^3 [RSH] ≤ 6.0; 0.01 ≤ [H+] ≤ 0.2; 298 ≤ T ≤ 318 K and I = 0.3 mol dm-3 (NaClO4). The electron transfer reaction has also been carried out in the presence of anionic, cationic and neutral micelle. The reaction in acid medium is strongly catalyzed by changing [SDS]T (sodium dodecyl sulfate) up to 3 × 10-2 mol dm-3, beyond this concentration of SDS, the rate is retarded. The cationic and neutral micelle has a small effect on the rate. ΔH≠ (kJ mol-1) and ΔS≠ (JK-1 mol-1) values for the k1 and k2 paths are 30.20 ± 0.25, -159.65 ± 0.83 and 29.60 ± 0.62, -127.09 ± 2.17, respectively. The negative activation entropy is indicative of the ordered transition state for the electron transfer reaction. Formation of 2-amino-3-(2-amino-2-carboxy-ethyl) disulfanyl-propanoic acid as product is strongly supported by IR spectra.
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 2; 6-10
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
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