Autor: Baszanowska, E. - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Oil identification based on total synchronous spectra
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/246342.pdf
Data publikacji:: 2014
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: fluorescence spectroscopy
total synchronous spectra
lubricate oil
vessel engine room
marine environment
Opis:: Contribution of marine carriage in the global transport is in permanent developing. It leads to increase the unintentional oil spills, which may induce serious disturbances in functioning of the natural marine ecosystem, especially when it interferes with other technical activities in the marine space. That fact contributes to increase the interest in searching of new research techniques to protect the natural ecosystem. Therefore, the main task of marine international organisations concentrates on the effective and rapid detection of oil spill and on the possibility of identifying oil pollutants as well as on origin of pollution. The purpose of the study is to characterise the oil belonging to the vessel engine lubricate oils. We analyse the stage results of investigations based on one of types of fluorescence spectroscopy, namely: synchronous spectra. To characterise the oil, the Aqualog Horiba spectrofluorometer was applied, which allows performing precise measurement in a short time. Based on the measured excitation-emission spectra, total synchronous fluorescence spectra for oil were obtained using various wavelength intervals. Total synchronous fluorescence spectra of petroleum substances allow finding wavelength interval typical for particular type of oil. This approach could allow obtaining of complex mixtures, such as oils, more efficient description. We discuss the total synchronous fluorescence spectra for engine oil (Marinol type) dissolved in n-hexane in various concentrations of oil as a possible tool proposed to oil type identification. We present changes and variation of the total synchronous fluorescence spectra for oil with various oil concentrations.
Źródło:: Journal of KONES; 2014, 21, 2; 15-20
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 2.

Tytuł:: Properties of the Baltic crude oil in the oil-in-water emulsion form : excitation-emission spectra
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/246400.pdf
Data publikacji:: 2018
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: crude oil
excitation-emission spectra
fluorescence
seawater
ropa naftowa
fluorescencja
woda morska
Opis:: Due to the fact that marine environment contamination by oil substances are not uncommon, it is necessary to improve the ability of determine their origin. Therefore, research on the possibility of recognizing the type of oil using its individual characteristic manifested in the processes of fluorescence excitation has been undertaken. Oil pollutants present in seawater mainly coming from ship drives, tankers, pipelines or sea bottom seeps, moreover oil leaks from offshore extraction equipment also are possible. For this reason, the crude oil extracted from the Baltic Sea deposit in the Polish Maritime Areas has been chosen for tests. Fluorescence properties of water containing small amounts of oil (concentrations from 5.59 to 55.4 ppm) in the form of oil-in-water emulsion were tested. Individual samples were assigned matrices of fluorescent values for different wavelengths, while excited by monochromatic light also for different wavelengths. The obtained matrices were visualized as a contour maps and 3D charts. For considered concentrations of crude oil dispersed in water, the wavelength-independent fluorescence maximum was determined. Obtained result indicates that in the studied wavelength range, the total fluorescence intensity is proportional to the oil concentration only for the lowest oil concentrations. The analysis of the objective parameter of the difference between the shapes of spectra indicates the similarity of the spectral shape for the lowest oil concentrations. These results are the methodological suggestion, that for the purpose of identifying the type of oil dispersed in water, spectra should be determined for sequences of different dilutions, until the excitation-emission spectra shapes become independent from the oil concentration.
Źródło:: Journal of KONES; 2018, 25, 1; 7-14
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 3.

Tytuł:: Light absorption properties of ‘Petrobaltic’ oil-in-water emulsion present in seawater
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/246640.pdf
Data publikacji:: 2018
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: crude oil, absorbance
absorption spectra of dispersed oil
absorption coefficient
oil-in-water emulsion
Opis:: In the article, the characteristic of crude oil ‘Petrobaltic’ potentially present in the Baltic Sea water masses is considered in relation to the protection of marine environment. The main spectroscopic method to characterize various oils (crudes and refinery products like fuels and lubricating oils) is fluorescence. However, the absorbance measurements of oils are necessary due to the partial overlapping the spectra of natural seawater components and oil substances. Therefore, properties of crude oil are considered to expand the basis of spectroscopic properties of oils – typical marine organic pollutants – based on absorption measurements. Oils potentially found in the marine environment are, in addition to surface forms, also in-depth ones as oil-in-water emulsion. Therefore, in the article crude oil as oil-in-water emulsion form is considered. As a solvent demineralised water with salinity, corresponding to Baltic Sea salinity was used. Several concentrations of dispersed crude oil were prepared. The absorbance spectra in the UV and visual range of the light in the range from 240 to 600 nm, for each prepared samples are discussed. Based on the Lambert-Beer law for each wavelength of excitation, in the range 240-600 nm, the specific parameter absorption coefficient was determined. Obtained results indicate the rapid decreasing of the absorbance for this kind of oil in the wavelength range from 240 nm to 420 nm. However, in the shape of absorbance spectra is observed the characteristic wide and flat peak located at 260 nm for excitation wavelength, which could be a specific point for this kind of oil.
Źródło:: Journal of KONES; 2018, 25, 3; 59-64
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 4.

Tytuł:: Testing of the synchronous fluorescence in application to used lubricate oil characterisation
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/243560.pdf
Data publikacji:: 2016
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: marine fleet exploitation
lubricate oil
fluorescence spectroscopy
synchronous fluorescence spectra
Opis:: Reliability of the ship propulsion system depends, inter alia, on the quality of lubricate oils. Research indicates that exploitive features of oil are reduced with it runtime in the ship engine circuit. At the present the basic parameters representing exploitive features of oil are: water content, total acid number and total base number or viscosity vs. temperature, anti-wear performance, further: content of additives and their concentrations, reaction products, and other contaminating substances, also magnetically separated large ferromagnetic particles, the size, the shape, the composition and concentration of the abnormal wear particles. Additional properties of oil are described based on atomic emission spectroscopy, granulometry of separated from the lubricant sample by magnets and gravity, permeability changes, as well as rheometric and tribometric characteristics. Complexity of composition of lubricate oil raises the idea to use changes of relative content of any compounds for characterization of oil exploitive features. Fluorescence method is possible to use for oil properties characterisation due to the presence mono and polycyclic compounds in oil that induces fluorescence phenomenon. Therefore identification the fluorescence spectra when exploitation time of oil increases could be novel indicator to monitor of lubricate oil exploitive quality. In this study we present changes of oil fluorescence expressed by synchronous spectra, taking into account working time of exemplary lubricate oil in the ship engine.
Źródło:: Journal of KONES; 2016, 23, 2; 39-44
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 5.

Tytuł:: Light absorption spectra for lubricate oil quality tracking in the combustion engine
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/243648.pdf
Data publikacji:: 2016
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: lubricate oil
dissolved oil
absorption spectroscopy
absorption coefficient
engine system
Opis:: The important role in the proper functioning of combustion engines plays the quality of lubricates oil. However, the quality of oil changes with the time of exploitation. Therefore, several parameters for examination of oil quality were determined; however, the indicator for quick and efficient tracking of evolution of oil with exploitation time is still searched. Taking into account the complex composition of oils, the ability of oils components to absorb light in various wavelengths is considered. In the article absorption properties of oils is discussed in relation to the time of circulation of oil in the engine lubricate system. For this study, two lubricate oils designated to lubricate the cylinder of vessel engines with different brightness and transparency were used. Oil samples were dissolved in organic solvent –n-hexane and several oil concentration were prepared based on dilution method. Absorbance spectra for eachsamples of oil were registered in the range of wavelength 240-600 nm. Obtained results indicate the changes of value of absorbance in relation to the kind of oil; however, the shape of absorbance spectra is independent from the kind of oil. For studied kinds of oil, characteristic peak independent from the kind of oil located at 260 nm was determined. Based on Lambert-Beer law absorption coefficient was identified as a potential indicator to oil quality evaluation with the time of exploitation in the engine system. Preliminary test for two fresh lubricate oils allow to conclude that absorption coefficient for selected wavelength located at 260 nm could be a sensitive parameter for quick estimating the degree of deterioration of the oil in engine system.
Źródło:: Journal of KONES; 2016, 23, 1; 55-60
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 6.

Tytuł:: Ultraviolet-induced fluorescence of lubricate oils
Fluorescencja oleju smarnego wzbudzana światłem ultrafioletowym
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/134176.pdf
Data publikacji:: 2015
Wydawca:: Polskie Towarzystwo Naukowe Silników Spalinowych
Tematy:: lubricate oil
fluorescence
optical fiber
olej smarny
fluorescencja
sensor optyczny
Opis:: The paper describes the study on relationship between the engine lubricate oil quality and fluorescence phenomenon. In order to determine the Excitation-Emission spectra (EEMs) of oil samples, a spectrofluorometer combined with an optical fiber system were applied. Two methods of fluorescence measurement: when oil diluted in non-fluorescent solvent (n-hexane) is placed in the quartz-cuvette inside the spectrofluorometer, and when oil sample is placed outside the spectrofluorometer (then EEMs is measured through the optical fiber sensor) were utilized to analyze the shape of EEMs of lubricate oil. Moreover in the second case of measurement, the optical fiber sensor was placed at an angle of 45 degrees to the oil surface, similarly above the oil surface and beneath the oil surface directly submerged in oil. Preliminary measurement results presented in this paper – on one hand – indicate diversity in the shape of EEMs depending on the method of fluorescence measurement, on the other hand – indicate possibility to measure fluorescence of oil directly in engine lubricate oil circuit.
W artykule przedstawiono wyniki badań związku pomiędzy jakością oleju smarnego a zjawiskiem fluorescencji. W celu wyznaczenia widm zupełnych fluorescencji próbek oleju wykorzystano spektrofluorymetr połączony ze światłowodowym systemem pomiarowym. Zanalizowano kształt widm odnoszących się do oleju smarnego w dwóch sytuacjach, gdy: olej jest rozpuszczony w niefluoryzującym medium (n-hexan) i umieszczony jest w przyrządzie w kwarcowej kuwecie oraz gdy próbka oleju znajduje się na zewnątrz przyrządu, sygnał jest przenoszony światłowodem. Ponadto przy pomiarach z zastosowaniem światłowodu ustawiona pod kątem 45° głowica pomiarowa zestawu światłowodowego znajduje się, odpowiednio: w powietrzu nad powierzchnią oleju albo pod powierzchnię oleju. Przedstawione w niniejszym artykule wstępne wyniki badań z jednej strony wskazują na zróżnicowanie kształtów widm zupełnych fluorescencji względem metody pomiarowej, z drugiej strony – wskazują na możliwość wyznaczania fluorescencji bez wstępnej obróbki laboratoryjnej, bezpośrednio w silnikowym obiegu oleju smarnego.
Źródło:: Combustion Engines; 2015, 54, 4; 21-25
2300-9896
2658-1442
Pojawia się w:: Combustion Engines
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 7.

Tytuł:: Fluorescence of natural seawater exposed to oil pollution
Autorzy:: Otremba, Z.
Baszanowska, E.
Powiązania:: https://bibliotekanauki.pl/articles/245422.pdf
Data publikacji:: 2015
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: marine fleet exploitation
seawater
oil pollution
fluorescence spectroscopy
Opis:: The natural seawater contains both dissolved and suspended organic substances originating from natural sources and human activities – like the marine transport fleet among other. To specify the type and quantity of vitally valid as well as dangerous for properly functioning marine ecosystems substances complicated and sophisticated chemical instrumentation and methodologies must be used. Only a small number of seawater components it is possible easily to determine their concentrations – for example, the salt content is determined directly in the bulk of water through simultaneous measurement of electrolytic conductivity and temperature of water. It is worth to search similarly quick method for oil substances directly in the seawater. Taking into account seawater organic pollutants originating from natural sources inter alia crude oils, the presence of refinery petroleum substances due to their fluorescence in ultra-violet light can be determined based on fluorescence spectroscopy. The aim of this paper is to search fluorescence features of oil substances dissolved in natural seawater based on excitation-emission spectroscopy. In the paper fresh and oily contaminated seawater taken from the coastal area of the Baltic Sea were used. As an oil pollution ‘Petro-baltic’ oil were applied. The natural seawater, at first was laboratory exposed to low extremely amount of oil and then it was examined by fluorescence under UV light. The seawater from vicinity of Gdynia (Poland) were tested as fresh and after artificially contaminated by different amount of oil (from 0.5 to 500 ppm). Spectrofluorometer Hitachi F-7000 FL was applied to measure excitation-emission spectra (EEMs). Low amounts of oil (up to several ppm) cause increasing of main peak in excitation-emission spectra (EEMs). Addition of larger amounts of oil results in appearance new peaks, which originate from fluorescence of soluble fractions of oil artificially added to examined water. These specific features of oil describe the spectroscopic signatures of oil, which is the basis to development operational method of the source of oil pollution identification.
Źródło:: Journal of KONES; 2015, 22, 3; 181-186
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 8.

Tytuł:: Engine fuel characterisation through ultraviolet absorption spectra
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/245537.pdf
Data publikacji:: 2017
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: fuel
spectroscopy
absorptivity
diesel engine system
Opis:: In the article, light absorption properties of the fuel oil are considered with a view to create basis for establish optical indicator of the type and quality of this kind of crude oil derivative, in this case the Diesel fuel. The organic solvent – n-hexane – was chosen as a solvent to prepare samples of dilutions of Diesel fuel in several oil concentration. Spectrophotometer Aqualog Horiba were applied to record the absorbance spectra in the ultraviolet and visual range of the light (from 240 to 600 nm) for each previously prepared samples. Obtained results allow concluding that the changes of absorbance occur primarily in the wavelength range from 240 nm to 355 nm. Moreover, the absorbance spectra are characterized by the characteristic sharp peak located at 270 nm for excitation wavelength. Spectra of absorbance were converted to spectra of absorption coefficient based on Lambert-Beer law. Due to the independence the absorption coefficient from the fuel concentration, this parameter could be used as a potential indicator to access composition and quality Diesel fuel used in the diesel engine system. Therefore, preliminary tests allow concluding that absorption coefficient for selected wavelength located at 270 nm could be a sensitive indicator for quick access to fuel quality.
Źródło:: Journal of KONES; 2017, 24, 3; 15-19
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 9.

Tytuł:: Engine fuel characterisation based on excitation-emission spectra
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/246580.pdf
Data publikacji:: 2017
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: fuel
diesel
engine
excitation-emission spectra
fluorescence
Opis:: Considering that correctly functioning of diesel ship engine depends on the composition of applied fuel, it is necessary to easy characterise fuels in terms of quality. Therefore taking into account above mentioned, appropriate analyses have been undertaken and the intention of this article is to inform that characterisation of fuel used in marine transport can be described by the specific parameter based on fluorescence excitation-emission spectroscopy. Therefore, for this study fuel typically used in ship engine – Diesel fuel – is considered. For analysis, Diesel fuel dissolved in n-hexane was used and several oil samples for various oil concentration were prepared. Spectrofluorometer Aqualog Horiba was used to record the excitation-emission spectra (EEMs). EEM spectra determined for each of oil concentration were described by two specific peaks for this kind of oil. Based on registered EEMs, the specific indicator - the wavelength-independent fluorescence maximum – coded in two specific wavelengths – excitation and emission, respectively, described as Exmax/Emmax was determined for considered oil concentration. Obtained results indicate the independence from oil concentration only for one detected peak described by Exmax/Emmax = 240/332. Taking into account obtained results, we can conclude that the wavelength-independent fluorescence maximum detected for excitation wavelength at 240 nm corresponds to the emission wavelength at 332 nm due to the independence from the oil concentration, could be a good indicator to characterise this kind of oil – Diesel fuel. We can conclude that the changes in the composition of fuel could be detected in EEM spectra by the change of detected peaks position.
Źródło:: Journal of KONES; 2017, 24, 2; 25-30
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 10.

Tytuł:: Spectrum of light absorption as the indicator of lubricate oil dispsersed in the natural water
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/247346.pdf
Data publikacji:: 2016
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: lubricate oil
absorption
absorption spectra of dispersed oil oil-in-water emulsion
Opis:: Oil pollutants in the natural water masses – especially in the seawater column – can be found in two forms, namely as dissolved oil or as dispersed one. With a broad set of methods, for studying the complex structure of petroleum products, due to the ability of petroleum products to absorb UV-light, absorbance spectra could be a relevant indicator to oil identification in aquatic environment and could support methods provided by the fluorescence technique. The intention of the study described in this article is to characterise the absorption properties of lubricate oil possible to found in the marine environment. Two types of oil as the representative of lubricate oils using in the ship engines are considered. One form of oil possible to found in the marine environment – oil-in-water emulsion was taken into account for analysis. Dispersed in water lubricate oil samples were prepared for several oil concentration for each type of oil. Spectrofluorometer Aqualog Horiba was used to register the absorbance spectra of oils. Based on the Lambert-Beer law the absorbance spectra were derived and specific parameter – absorption coefficient – for each wavelength of excitation, in the range 240-600 nm, was determined. Obtained results indicate decreasing of the oil absorbance value when excitation wavelength increases. Moreover, basing on the absorbance spectra it could be concluded that the main maximum for this kind of oils is located below 240 nm. However, in the considered range of excitation wavelength small flat peak, centred about 265 nm for both types of oils, was detected. Therefore one could conclude that absorbance of oils could be used as the indicator to detect of oil pollution in the natural environment omitting the labour intensive chemical methodology.
Źródło:: Journal of KONES; 2016, 23, 1; 61-66
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 11.

Tytuł:: Spectroscopic methods in application to oil pollution detection in the sea
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/248141.pdf
Data publikacji:: 2012
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: marine transport
oil pollution
spectroscopic methods
fluorescence
time-resolved fluorescence
Opis:: The escalating maritime transport as well as offshore crude oil exploitation and pipeline transportation leads to the increase of feasibility of the discharge of petroleum substances to the sea environment events. Therefore, it is necessary to rapidly detect of oil pollution to minimize the extent of contamination in the seawater. The aim of this study is to discuss the assumptions of the optical methods using for detection of oil pollution in the seawater. We consider the different approaches of oil-in-water detection using spectral active and passive techniques with emphasis on fluorescence techniques. The intensive development of scientific apparatus and methods in light spectroscopy leads to build various airborne or underwater specialized devices (UV-, IR-scanners, fluorosensors), which allows to detect oil pollution in relatively large areas of the sea. The possibility of measurements of oil pollution in the seawater is particularly important for monitoring, especially in very difficult weather conditions and highly waved sea surface. Such possibilities should be given by devices for in-situ measurements based on time-resolved fluorescence. Such measurements allow obtaining the significant information about presence of oil in really short time. As we show in this study, the wide-range development of fluorescence techniques opens the diagnostic opportunity not only for detection of the oil-in-water content but also for identification the type of oil directly in seawater or even determination of the source of oil pollution.
Źródło:: Journal of KONES; 2012, 19, 1; 15-20
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 12.

Tytuł:: Description of diesel fuel based on synchronous fluorescence spectroscopy
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/242632.pdf
Data publikacji:: 2017
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: synchronous fluorescence spectroscopy
total synchronous spectra
diesel fuel
wavelength-interval
offset
fluorescencyjna spektroskopia synchroniczna
widmo synchroniczne
olej napędowy
długość fali
Opis:: The purpose of the study is spectrally characterise fuel Diesel used in diesel ship engine. For description of Diesel fuel the techniques of total synchronous fluorescence spectroscopy was applied. To characterise the oil, the spectrofluorometer ‘Aqualog Horiba’, which allows performing precise measurement in a short time, was applied to measure the excitation-emission spectra. Total synchronous fluorescence spectra of oil were obtained using various wavelength intervals basing on the measured excitation-emission spectra of Diesel fuel. Total synchronous spectra of Diesel oil are considered for several oil concentration. Synchronous fluorescence spectra were used to describe the detected maxima of Diesel fuel fluorescence by the wavelength-interval fluorescence maximum, containing information about the excitation wavelength and the wavelength-interval describing the characteristic fluorescence peak position for each considered fuel sample. That approach is discussed in relation to find a universal indicator – the wavelength-interval – as a possible tool proposed to Diesel fuel description independent from the fuel concentration. Therefore, we discuss the changes of the total synchronous fluorescence spectra for different oil concentration. Obtained results indicate that the best indicator for this kind of oil characterisation seems to be the wavelength-interval for 60 nm due to the independence of the synchronous spectra from the oil concentration.
Źródło:: Journal of KONES; 2017, 24, 1; 39-45
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 13.

Tytuł:: Comparison of fluorometric signatures of oil residues in both marine environment and in organic diluent
Autorzy:: Otremba, Z.
Baszanowska, E.
Powiązania:: https://bibliotekanauki.pl/articles/243211.pdf
Data publikacji:: 2015
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil pollution
seawater
excitation-emission spectra
fluorescence spectroscopy
Opis:: The significant part of petroleum substances is transferred to the marine environment after technical activities (inevitable exploitive spills, illegal discharges). However a certain part of petroleum in seawater coming from the natural sources. Therefore, to develop the safety of natural marine environment it is necessary to track not only the anthropogenic pollutants but also the natural sources of petroleum. To distinguish both source of oil the fluorescence properties of oil can be used as the tools to oil identification. The aim of the study is to describe the optical properties of crude oil after it contact with aquatic environment based on fluorescence spectroscopy. For the study, crude oil ‘Petrobaltic’ type potentially found in marine environment due to coming from natural source was applied. To dissolve oil, two different solvent – hexane and Baltic seawater form the Gdynia coast were used. To measure the excitation-emission spectra (EEMs) of oil spectrofluorometer Hitachi F-7000 FL was applied. In the paper, we discuss the changes of oil EEMs in two cases for oil dissolved in n-hexane and for oil dissolved in seawater for various oil concentration. Obtained EEMs for oil dissolved in seawater indicate that EEMs spectrum contain the main peak – describing by the wavelength – independent fluorescence maximum, which was detected for oil dissolved in n-hexane (typical for this kind of oil). However, the intensity of oil fluorescence decreases after oil contact with seawater. This approach could allow expanding the description of complex mixtures of oils as a possible tool proposed for identification the type and origin of oil found in marine environment.
Źródło:: Journal of KONES; 2015, 22, 3; 175-179
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 14.

Tytuł:: Spectrofluorimetric characteristics of used lubricating oil
Spektrofluorymetryczna charakterystyka zużytego oleju smarnego
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/328239.pdf
Data publikacji:: 2014
Wydawca:: Polska Akademia Nauk. Polskie Towarzystwo Diagnostyki Technicznej PAN
Tematy:: fluorescence
excitation-emission spectra of oil
lubricate oil
ship engine
fluorescencja
zupełne widmo fluorescencji
olej smarny
silnik okrętowy
Opis:: Deterioration of lubricate oil in combustion engines enforces measurements of parameters essential for proper operation of define driving system or to certain engine malfunctions indicate. Since the fluorescence phenomenon is known for oil excited by ultraviolet light - the question arises whether fluorescence spectra evolving with the time of exploitation of oil in the engine. In this paper the introductory studies of excitation-emission spectra (EEMs) for chosen lubricate oil are described. Both fresh and used oil (after 593 h of work in a ship engine), was used to measure EEMs. As a result of comparison of EEMs for both fresh and used lubricate oils more significant transformations in fluorescence spectra of oil caused by their exploitation are indicated. Obtained results allow to predict that spectrofluorimetry method could supplement present methods of used lubricating oil testing.
Pogarszanie się właściwości oleju smarnego w silniku spalinowym skutkuje koniecznością monitorowania jego eksploatacyjnych parametrów. Z racji wykazywania przez oleje fluorescencji w świetle ultrafioletowym - powstaje pytanie, czy widma fluorescencji ewoluują wraz z czasem przebywania oleju w obiegu smarnym silnika. W artykule opisane są wstępne analizy zmian zupełnych widm fluorescencji (EEMs) dla różnych stężeń wybranego oleju smarnego. Do pomiaru EEMs oleju użyto dwóch form oleju – świeżego i przepracowanego w silniku okrętowym w czasie 593 h. W następstwie porównania widm uzyskanych dla świeżego i przepracowanego oleju wskazano na zachodzące najbardziej znaczące zmiany we fluorescencji oleju smarnego. Uzyskane wyniki pozwalają sądzić, że spektrofluorymetria mogłaby uzupełnić obecne metody testowania przepracowanego oleju.
Źródło:: Diagnostyka; 2014, 15, 4; 65-71
1641-6414
2449-5220
Pojawia się w:: Diagnostyka
Dostawca treści:: Biblioteka Nauki

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Tytuł:: Spectrofluorymetry in application to oil-in-water emulsion characterization
Autorzy:: Otremba, Z.
Baszanowska, E.
Toczek, H.
Powiązania:: https://bibliotekanauki.pl/articles/246063.pdf
Data publikacji:: 2011
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil
fuels
lubricants
aquatic environment protection
fluorescence spectra
Opis:: The question of identifying the type of oil in exploitation of engine room is associated with both the quality of ship consumables (fuels and lubricants) and the composition and origin of oil in settling tanks or in dumping water. Related issue is the possibility of determining the origin of oil, which is detected in the marine environment. The key question is how oils vary in their ability to fluorescence, understood as the shapes of fluorescence spectra obtained for different wavelengths of light exciting fluorescence. In this paper we present spectra of fluorescence for six chosen oils. Those oils were previously dispersed (emulsified) in the seawater, then extracted into hexane. Fluorescence spectra were obtained using fluorescence spectrometer Perkin Elmer LS55, for excitation wavelengths in the range from 240 nm to 500 nm, and emission wavelengths from 300 nm to 790 nm. In this paper there is shown that in general both total intensity of fluorescence and shapes of spectra of fluorescence depend on the excitation wavelength and are differ for various kinds of oil. In order to visually show the differences in fluorescence abilities of various oils, the results of measurement were placed on a chart of fluorescence intensities in the function of both variables: the excitation wavelength and the emission wavelength (so called the total fluorescence spectra). Analyses of results of the described studies confirm that the different oils fluoresce differently and identification of type of oil is possible by fluorescence spectrophotometry.
Źródło:: Journal of KONES; 2011, 18, 3; 317-321
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Tytuł:: Adoption of the time resolved fluorescence to oil type identification
Autorzy:: Baszanowska, E.
Otremba, Z.
Rohde, P.
Zieliński, O.
Powiązania:: https://bibliotekanauki.pl/articles/247122.pdf
Data publikacji:: 2011
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil
fuels
lubricants
aquatic environment protection
time-resolved fluorescence
diagnostics
Opis:: The present development of a basic science, including physics of stimulated emission of light, opens up new diagnostic possibilities in relation to the quality of oils, including marine fuels and lubricants. In complicated chemical composition of oils both light absorbing compounds and compounds that emit light (fluorescent) are included. This causes the formation of complex structures in the spectral plots of fluorescence intensity as a function of wavelength of light exciting fluorescence and as a function of the wavelength of light emitted. Since the fluorescence excitation occurs in a short time of its disappearance. The shape of the fluorescence decay function depends on the chemical composition of oil, therefore, includes a mention of its kind, quality, level of degradation, and the like. In this paper exemplary charts of the intensity decay curves in different parts of the fluorescence spectra are shown (for light fuel). Presented charts are obtained using the experimental device constructed in Bremerhaven University of Applied Sciences (Germany) and are the attempt to use ability of oil substance to manifest its composition in the form of the fluorescence decay curve. An analysis of the chart shows that decay of fluorescence in this case is described by biexponential curve, therefore a kind of oil can be represented by two numerical values - two decay time constants. Operational use of this method will be possible only after a comparative study of different types and quality of oil in relation to the shape of the fluorescence decay curves.
Źródło:: Journal of KONES; 2011, 18, 2; 25-29
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 17.

Tytuł:: Fluorescence spectra of oil after it contacts with aquatic environment
Autorzy:: Baszanowska, E.
Otremba, Z.
Toczek, H.
Rohde, P.
Powiązania:: https://bibliotekanauki.pl/articles/245054.pdf
Data publikacji:: 2013
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil pollution
fluorescence spectroscopy
excitation-emission spectra
seawater
environment protection
Opis:: The main task for natural marine environment protection is to prevent the inflow of various contaminants including oil substances and the real challenge is the ability to rapidly detect these pollutants. Moreover important is to find the source or the maker of the oil spill. In this paper, we consider fundamental physical aspects in the area of possibility of monitoring the natural marine ecosystem based on fluorescence spectroscopy. We utilize the fluorescence ability of numerous oil components – mainly polycyclic hydrocarbons. The paper concerns the spectrofluorimetric characterization of oils have been in use during exploitation of the marine fleet, i.e. lubricate oil, fuels, transformer and hydraulic oils as well as crude oils or their residues. Every kind of oil has a chance to enter the marine environment, especially in a case of ship emergency or after collision with other vessel ore shoreline structure as well as when ship enters the stranding. After discharge of oil, some of oil components are dissolved in the water, bacteria or photochemical reactions, which results in transformation of composition of oil, degrade some. Fluorescence spectrometer Perkin Elmer LS55 was applied to obtain the fluorescence spectra using different excitation wavelength in the range from 240 nm to 500 nm. We discuss the changes of the shapes of excitationemission spectra (EEMs) of various types of oil and the EEMs spectra after contact of oil with seawater as an oil-inwater emulsion, which is the most frequent form of oil in the water column. Significant changes in the shape of spectra and displacement of the peaks are observed.
Źródło:: Journal of KONES; 2013, 20, 3; 29-34
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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