- Tytuł:
- The Temperature and Pressure Dependence of the Free Volume in Fluoroelastomers from PALS and PVT Experiments
- Autorzy:
-
Dlubek, G.
Sen Gupta, A.
Wawryszczuk, J.
Kilburn, D.
Pionteck, J.
Krause-Rehberg, R.
Goworek, T.
Alam, M. A.
Kaspar, H.
Lochhaas, K. H. - Powiązania:
- https://bibliotekanauki.pl/articles/2042202.pdf
- Data publikacji:
- 2005-04
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
61.41.+e
78.70.-g - Opis:
- Positron lifetime and pressure-volume-temperature experiments were performed as function of T (100-485 K) and P (10$\text{}^{-5}$ Pa-500 MPa) on a fluoroelastomer. From positron annihilation lifetime spectroscopy, analyzed with LT9.0 assuming a dispersion in the e$\text{}^{+}$ (τ$\text{}_{2}$) and o-Ps (τ$\text{}_{3}$) lifetime, the mean, 〈v$\text{}_{h}$〉, and the width (standard deviation), σ$\text{}_{h}$, of the hole size distribution were calculated. The pressure-volume-temperature data were analyzed using the Simha-Somcynsky hole-lattice theory to estimate the specific hole free volume V$\text{}_{f}$. From a comparison of V$\text{}_{f}$ with 〈v$\text{}_{h}$〉 the specific hole number, N'$\text{}_{h}$, is estimated. The data from thermal expansion and pressure experiments show complete agreement when taking into account the compressibility of the occupied volume.
- Źródło:
-
Acta Physica Polonica A; 2005, 107, 4; 685-689
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł