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    Wyświetlanie 1-47 z 47
    Tytuł:
    Stable isotope deuterium as a natural tracer of mixing processes in rivers
    Autorzy:
    Palige, J.
    Ptaszek, S.
    Zimnicki, R.
    Chmielewski, A. G.
    Wierzchnicki, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/146756.pdf
    Data publikacji:
    2008
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    stable isotopes
    tracer
    deuterium
    oxygen-18
    river
    water flow
    Opis:
    The possibility of application of naturally existing differences in isotope contents 18O/16O, 2H/1H in waters for investigation of transport and mixing of various waters in the tributary-river system is presented. Experiments carried out on the Bug-Narew rivers-Zegrze Lake and the BugoNarew-Vistula rivers systems have indicated that the hydrogen isotope ratio 2H/1H can be used as an intrinsic tracer of natural mixing processes occurring in rivers. The IRMS methodology was used for isotope ratio measurement of water samples. The degrees of water mixing as a function of distance from the confluence point of rivers were determined. The obtained results indicate that in water systems where the natural differences in ?2H are higher than 5‰ this technique can replace the time-consuming and expensive dye (or radiotracer) dispersion tests for evaluation of pollutant transport in rivers.
    Źródło:
    Nukleonika; 2008, 53, 2; 63-67
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A study of stable isotope composition of chosen foodstuffs from the Polish market
    Autorzy:
    Malec-Czechowska, K.
    Wierzchnicki, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/148152.pdf
    Data publikacji:
    2013
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    stable isotope
    honey
    meat
    hen eggs
    food authenticity
    Opis:
    In the present work the carbon and nitrogen isotopic composition of food products bought in the retail trade in Warsaw is demonstrated. The research was carried out using meat (pork, chicken), hen eggs and honey. These products originated from the conventional and ecological farms. The values of the isotopic ratios are expressed as δ notation and correspond to the international standards (V-PDB for δ13C, and air for δ15N) according to the following general formula: δ(‰) = [(R sample / R standard) – 1] × 1000, where R represents the ratio between the less abundant and more abundant isotopes, in particular 13C/12C and 15N/14N. The results received in our laboratory, were compared with results presented in the literature for similar products. The results of the study show that the N and C stable isotope ratios in the tested products can be applied to verify their authenticity.
    Źródło:
    Nukleonika; 2013, 58, 2; 323-327
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    NMR studies of human cystatin C - stable isotope labeling of human cystatin C
    Autorzy:
    Jurczak, P.
    Maszota-Zieleniak, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/1935821.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Gdańska
    Tematy:
    NMR
    overproduction
    stable isotopes
    proteins
    labeling
    nadprodukcja
    stabilne izotopy
    białka
    etykietowanie
    Opis:
    The objective of this study was to obtain a double and triple labeled human cystatin C (hCC). Another objective was to record sets of 2D and 3D NMR spectra of the hCC dimer (in a solution) using a 700MHz spectrometer. The data obtained during attempts to determine the NMR structure should provide useful information about chemical shifts of amino acid residues. They will certainly accelerate solving the human cystatin C NMR structure. In this paper the main focus is put on triple isotopic labeling, protein overproduction and NMR analysis of hCC. The first two processes lead to obtaining hCC labeled with stable isotopes of carbon ( 13 C), nitrogen ( 15 N) and hydrogen ( 2 H) (double labeled hCC was obtained with a similar method). The obtained protein was later used for the purpose of NMR spectra.
    Źródło:
    TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 2014, 18, 4; 327--330
    1428-6394
    Pojawia się w:
    TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Stable isotope composition of carbonates in loess at the Carpathian margin (SE Poland)
    Autorzy:
    Łącka, Bożena
    Łanczont, Maria
    Komar, Maryna
    Madeyska, Teresa
    Powiązania:
    https://bibliotekanauki.pl/articles/2026059.pdf
    Data publikacji:
    2008
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    loess
    authigenic carbonates
    carbon and oxygen stable isotopes
    Vistulian
    Opis:
    Sam ples for the study were col lected from, known from the lit era ture, out crop pro files in Zar zecze, Ra dymno, Dybawka, Tarnawce and Pikulice- Nehrybka, situ ated at the Car pa thian bor der, in the vi cin ity of the Prze myoel town, close to the San River val ley (SE Po land). They rep re sent the Vis tulian loess- palaeosol se quences. Car bon ates oc cur mainly in the lo esses rep re sent ing OIS 2 and 3. Pol len analy sis, car ried out for two pro files (Tarnawce, Ra dymno), throws light on pa laeoe co logi cal con di tions of loess cover for ma tion and trans for ma tion. Iso topic analy sis of authigenic car bon ates was car ried out on car bon ate ce mented bod ies dis persed through out the loess in forms of nod ule, rhi zolith and rhi zo cre tion and on bio clasts, mainly snail shells, os tra cod valves, and sparse glob ules (proba bly the in ter nal shells of the na ked snails). In the suc ces sions stud ied, the up per Vistulian loess de pos ited in en vi ron ment with poor veg e ta tion, con tains rhizoliths and rhizocretions mainly, while in the mid dle and lower Vistulian loess with well de vel oped soils, gley ho ri zons, and in ter ca la tions of sub aque ous sed i ments, re mains of snail shells and ostracod valves pre vail. The two main forms of car bon ates dif fer mark edly in iso to pic com po si tion from one an other. These dif fer ences seem to be more im por tant than those be tween sam ples of one form of car bon ates along par tic u lar sec tions. That is the re sult of nu mer ous fac tors af fect ing the frac tion ation of car bon and, in par tic u lar, ox y gen sta ble iso topes in the en vi ron ment of pre cip i ta tion of authigenic cal cite. The iso to pic com po si tion of car bon ates ce ment ing sed i ments is con trolled mainly by biomineralization of or ganic mat ter and lo cal cli ma tic pa ram e ters which were rather slightly dif fer en ti ated dur ing the for ma tion of the stud ied sed i ments. The d13C val ues for bioclasts vary in a broader range than for calcitic ce ments. Usu ally the snail shell car bon ate is more en riched with heavier car bon iso tope than that from ostracod valves, re sult ing from the iso to pic equi lib rium with pre cip i ta tion and with sur face wa ters, re spec tively. Bas ing on our study we can con clude that fluc tu a tions of iso tope com po si tion of authigenic car bon ates make it hard to ap ply as a paleoclimatic in di ca tor. How - ever, the gen eral trend of d18O vari a tion in ana lysed car bon ate frac tions from leoss-palaeosol se quences dis plays some con nec tions with cli ma tic fluc tu a tions.
    Źródło:
    Studia Quaternaria; 2008, 25; 3-21
    1641-5558
    2300-0384
    Pojawia się w:
    Studia Quaternaria
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Estimation of soil water evaporative loss after tillage operation using the stable isotope technique
    Autorzy:
    Busari, M.A.
    Salako, F.K.
    Tuniz, C.
    Zuppi, G.M.
    Stenni, B.
    Adetunji, M.T.
    Arowolo, T.A.
    Powiązania:
    https://bibliotekanauki.pl/articles/25434.pdf
    Data publikacji:
    2013
    Wydawca:
    Polska Akademia Nauk. Instytut Agrofizyki PAN
    Opis:
    Application of stable isotopes in soil studies has improved quantitative evaluation of evaporation and other hydrological processes in soil. This study was carried out to determine the effect of tillage on evaporative loss of water from the soil. Zero tillage and conventional tillage were compared. Suction tubes were installed for soil water collection at the depths 0.15, 0.50, and 1.0 m by pumping soil water with a peristaltic pump. Soil water evaporation was estimated using stable isotopes of water. The mean isotopic composition of the soil water at 0.15 m soil depth were -1.15‰ (d18O) and -0.75‰ (dD) and were highly enriched compared with the isotopic compositions of the site precipitation. Soil water stable isotopes (d18O and dD) were more enriched near the surface under zero tillage while they were less negative down the profile under zero tillage. This suggests an occurrence of more evaporation and infiltration under conventional then zero tillage, respectively, because evaporative fractionation contributes to escape of lighter isotopes from liquid into the vapour phase leading to enrichment in heavy isotopes in the liquid phase. The annual evaporation estimated using the vapour diffusion equation ranges from 46-70 and 54-84 mm year-1 under zero and conventional tillage, respectively, indicating more evaporation under conventional tillage compared with zero tillage. Therefore, to reduce soil water loss, adoption of conservation tillage practices such as zero tillage is encouraged.
    Źródło:
    International Agrophysics; 2013, 27, 3
    0236-8722
    Pojawia się w:
    International Agrophysics
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Foraminifers and stable isotope record of the Dubivtsi chalk (upper Turonian, Western Ukraine): palaeoenvironmental implications
    Autorzy:
    Dubicka, Z.
    Peryt, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/2058968.pdf
    Data publikacji:
    2012
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Turonian
    foraminifers
    carbon isotopes
    oxygen isotopes
    biostratigraphy
    palaeoenvironments
    Opis:
    A combined micropalaeontological and stable isotope study of the Dubivtsi chalk in the Western Ukraine indicates its middle late Turonian age. One long-term and clearly distinguishable positive excursion of the isotope curve (d1318
    Źródło:
    Geological Quarterly; 2012, 56, 1; 199-214
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Stable isotope composition of carbon dioxide emitted from anthropogenic sources in the Kraków region, Southern Poland
    Autorzy:
    Zimnoch, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/148175.pdf
    Data publikacji:
    2009
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    stable isotopes
    carbon dioxide
    anthropogenic sources
    Kraków
    Opis:
    The summary of the measurements of CO2 stable isotopic composition emitted from different anthropogenic sources in the Krakow region is presented. The sources are divided into three main groups . high emission (electric and heat power plants), low emission (coal and methane burning in the households) and car traffic (gasoline, diesel and LPG supplied engines equipped and not equipped with catalyst). Presented results include two measurement campaigns made in the years 1995 and 2000. The measurements revealed three well-defined groups with respect to carbon isotope composition (delta13CVPDB): .30.60 plus-minus sign 0.37 per mille (thousand) sign (car traffic) .23.82 plus-minus sign 0.10 per mille (thousand) sign (coal burning) and .51.8 plus-minus sign 1.1per mille (thousand) sign (methane burning). The oxygen isotope composition (delta18OVPDB-CO2) of CO2 varied in a broad range, from ca. .11per mille (thousand) sign to ca. .22 per mille (thousand) sign, the most negative values being observed for coal and methane burning and the most positive for cars equipped with a catalyst. No significant isotopic shift has been observed between two measurement campaigns.
    Źródło:
    Nukleonika; 2009, 54, 4; 291-295
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Mineralogical, geochemical and stable isotope studies of kaolin deposits in north-west Gonabad district (eastern Iran)
    Autorzy:
    Zirjanizadeh, S.
    Rocha, F.
    Samiee, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059765.pdf
    Data publikacji:
    2018
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    kaolinite
    Iran
    REE
    O isotope composition
    Opis:
    Kaolin deposits, situated ~10 km north-west of Gonabad (eastern Iran), formed by the intrusion of hydrothermal fluids from a granite dyke in the western part of the study area, and the alteration of rhyolite, dacite and rhyodacite related to Eocene volcanism. There are four major kaolin quarries. The rocks in the investigated area are mainly slate, dacite, rhyolite, andesite-trachyandesite, and lithic and felsic tuffs. The mineralogical compositions of the kaolin deposits are dominated by quartz, kaolinite, dickite and illite with minor chlorite, montmorillonite, albite, hematite, pyrite and gypsum. Sanidine and plagioclase crystals in rhyolite-rhyodacite are sericitized and kaolinized. Whole rock chemistry of the kaolin deposits shows high contents of SiO2 and Al2O3. Enrichments of Sr in some samples demonstrate retention of Sr and depletion of Rb, Ba, Ca and K during hydrothermal alteration of sanidine and plagioclase within the volcanic units. The chondrite-normalized rare earth element patterns of the clay deposits show LREE enrichments (La/Lu)cn = 6.75 to 57.74, pointing to kaolinization in low-pH waters. The isotope composition of the kaolin (δ18O ~+5‰) is consistent with formation at isotopic equilibrium with water of hydrothermal/magmatic origin. The mineralogical composition, REE contents and elemental ratios in these deposits suggest provenance of the kaolin deposits mainly from felsic rocks and hydrothermal fluids. The O isotopic character also supports these results.
    Źródło:
    Geological Quarterly; 2018, 62, 2; 385--399
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Lateglacial-Middle Holocene stable isotope records in two coeval stalagmites from the Bihor Mountains, NW Romania
    Autorzy:
    Tamaş, T.
    Onac, B. P.
    Bojar, A. V.
    Powiązania:
    https://bibliotekanauki.pl/articles/2058899.pdf
    Data publikacji:
    2005
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    NW Romania
    Late Glacial
    Middle Holocene
    stalagmites
    stable isotopes
    uranium-thorium TIMS dating
    Opis:
    Oxygen and carbon stable isotope records of two stalagmites from NW Romania provide a continuous climatic record between 14.8 and 5.6 ka BP. The chronology is established by 21 TIMS uranium series ages. Uncertain ties in the isotope chronology range between ±20 and ±100 yr. The δ18 O values are positively correlated with temperature, whereas δ13 C fluctuations suggest changes in soil CO2 production. Lateglacial deposition of both stalagmites started at ~14.8 ka BP. The delta 18 O records subsequently show a slow decline in temperatures until 12.6 ka BP. Three warmer periods with increased soil productivity occurred at 14.5-13.9 ka BP, 13.6-13.2 ka BP, and 12.9-12.6 ka BP. Lower delta 18 O and high δ13 C values between 12.6 and 11.4 (11.7) ka BP in dicate a cold and dry climate during the Younger Dryas (GS-1). During the Early Holocene, three short cold intervals are marked on the δ 18 O profiles at 11.0-10.6, 10.5-10.2 and 9.4-9.1 ka BP. For the remainder of the Holocene sequence, the δ18 O records show less variation between 9 and 7.8 ka BP and gradual warming from 7.6-5.6 ka BP. The speleothem records correlate with the Green land ice core records and with other proxies through out Europe and the North Atlantic region.
    Źródło:
    Geological Quarterly; 2005, 49, 2; 185-194
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    K/Ar dating and stable isotope analysis of the Baszkówka and Mt. Tazerzait L5 chondrites
    Autorzy:
    Hałas, S.
    Wójtowicz, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059307.pdf
    Data publikacji:
    2001
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Baszkówka
    Tazerzait Mountains
    chondrites
    K/Ar ages
    oxygen isotopes
    sulphur isotopes
    Opis:
    We have determined the content of 40Ar* (1.49 nmol/g) and 4He (1.75 nmol/g) in the Baszkówka meteorite by static vacuum mass spectrometry. The radiogenic argon content was calculated from the measured argon spectrum using the equation: 40Ar* = 40Ar - 295.536Ar assuming a potassium content of 680 ppm wgt. We have obtained K/Ar ages of 3.78 Ga for the chondrules and 3.47 Ga for a bulk sample of Baszkówka. A similar 4He content (1.47 nmol/g) but larger 40Ar* (2.32 nmol/g) content was found for the Mt. Tazerzait bulk sample. The K/Ar age of this meteorite on the basis of the K content (732 ppm) is 4.34 Ga. Sulphur isotope analysis of troilite specimens from both meteorites reveals essentially negative delta 34S values: -1.25š0.06o/oo for Baszkówka and -1.18š0.06o/oo for Mt. Tazerzait expressed on the V-CDT scale. This indicates that both chondrites may have a common origin. The oxygen isotope data (delta 18O = 4.88š0.03o/oo and delta 17O = 3.66š0.10o/oo) suggests that Baszkówka belongs to the L chondrites.
    Źródło:
    Geological Quarterly; 2001, 45, 3; 315-318
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Note on the stable isotope values of vein calcite in the El-Seboah peralkaline granite (SW Egypt)
    Autorzy:
    Hassan, Kamaleldin M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2086490.pdf
    Data publikacji:
    2011
    Wydawca:
    Polskie Towarzystwo Mineralogiczne
    Tematy:
    δ13C
    δ18O
    carbonate-hosting veins
    peralkaline granite
    Egypt
    Opis:
    Stable isotope data for carbon (δ13C) and oxygen (δ18O) are used to constrain the environments of calcite formation in two veins in the El-Seboah peralkaline granite in south-western Egypt. Vein I with calcitemagnetite-goethite-hematite-quartz, and vein II with calcite-magnetite-goethite-kaolinite-hematite-quartz are texturally distinct. The calcite of each vein has characteristic δ13C- and δ18O-values: + 0.32 and -7.28‰ for vein I and + 1.16 and - 1.21‰ for vein II, respectively. The observed differences between the δ13C values of the two veins indicate that they represent two separate systems of primary dissolved inorganic carbon formed at or near equilibrium with atmospheric CO2. The δ18O values, on the other hand, indicate calcite deposition from meteoric waters which were fresh for vein I and brackish for vein II.
    Źródło:
    Mineralogia; 2011, 42, 2/3; 113--120
    1899-8291
    1899-8526
    Pojawia się w:
    Mineralogia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Note on the stable isotope values of vein calcite in the El-Seboah peralkaline granite (SW Egypt)
    Autorzy:
    Hassan, K. M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2086543.pdf
    Data publikacji:
    2011
    Wydawca:
    Polskie Towarzystwo Mineralogiczne
    Tematy:
    δ13C
    δ18O
    carbonate-hosting veins
    peralkaline granite
    Egypt
    Opis:
    Stable isotope data for carbon (δ13C) and oxygen (δ18O) are used to constrain the environments of calcite formation in two veins in the El-Seboah peralkaline granite in south-western Egypt. Vein I with calcitemagnetite-goethite-hematite-quartz, and vein II with calcite-magnetite-goethite-kaolinite-hematite-quartz are texturally distinct. The calcite of each vein has characteristic δ13C- and δ18O-values: + 0.32 and -7.28‰ for vein I and + 1.16 and - 1.21‰ for vein II, respectively. The observed differences between the δ13C values of the two veins indicate that they represent two separate systems of primary dissolved inorganic carbon formed at or near equilibrium with atmospheric CO2. The δ18O values, on the other hand, indicate calcite deposition from meteoric waters which were fresh for vein I and brackish for vein II.
    Źródło:
    Mineralogia; 2011, 42, 2/3; 113--120
    1899-8291
    1899-8526
    Pojawia się w:
    Mineralogia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Use of sulphur and carbon stable-isotope composition of fish scales and muscles to identify the origin of fish
    Autorzy:
    Trembaczowski, Andrzej
    Powiązania:
    https://bibliotekanauki.pl/articles/2086488.pdf
    Data publikacji:
    2011
    Wydawca:
    Polskie Towarzystwo Mineralogiczne
    Tematy:
    stable isotopes
    δ34S
    δ13C
    fish scales
    fish muscle
    food web relations
    Opis:
    δ34S and δ13C analyses were used to determine the origin of trout specimens. The isotope record of their scales and muscles are compared with a database previously obtained from wild- and reared fish coming from Polish rivers and pond farms. The comparison made it possible to find out whether the trout were wild or reared.
    Źródło:
    Mineralogia; 2011, 42, 1; 33--37
    1899-8291
    1899-8526
    Pojawia się w:
    Mineralogia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Use of sulphur and carbon stable-isotope composition of fish scales and muscles to identify the origin of fish
    Autorzy:
    Trembaczowski, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/2086538.pdf
    Data publikacji:
    2011
    Wydawca:
    Polskie Towarzystwo Mineralogiczne
    Tematy:
    stable isotopes
    δ34S
    δ13C
    fish scales
    fish muscle
    food web relations
    Opis:
    δ34S and δ13C analyses were used to determine the origin of trout specimens. The isotope record of their scales and muscles are compared with a database previously obtained from wild- and reared fish coming from Polish rivers and pond farms. The comparison made it possible to find out whether the trout were wild or reared.
    Źródło:
    Mineralogia; 2011, 42, 1; 33--37
    1899-8291
    1899-8526
    Pojawia się w:
    Mineralogia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Groundwater investigation in saharan areas using statistical and stable isotope approaches – El Golea central south of Algeria case study
    Autorzy:
    Boucenna, Fatih
    Fenazi, Bilal
    Boukoffa, Mechati
    Powiązania:
    https://bibliotekanauki.pl/articles/2201676.pdf
    Data publikacji:
    2023
    Wydawca:
    Uniwersytet Rolniczy im. Hugona Kołłątaja w Krakowie
    Tematy:
    albian aquifer
    geochemistry
    statistical approaches
    stable isotopes
    Saharan land
    warstwa wodonośna
    alb
    geochemia
    metody statystyczne
    izotopy stabilne
    Opis:
    Groundwater quality determination and age estimation in a desert landscape of El Golea province situated in the south of Algeria has been investigated in the present research paper. For this regard, 57 water samples were collected from an aquifer composed of two superimposed systems; phreatic and deep continental intercalary (CI) aquifers which are a part of the Northern Sahara Aquifer System (NWSAS). Samples were analyzed to assess the age and water quality using descriptive, multivariate statistics (PCA and HCA) and stable isotopes. It is revealed that more than 71% of the IC points are characterized by a water type (Ca2+, Mg2+) (HCO3 – )2 and more than 83% of the TC samples are defined by a water type (Ca2+, Na+) (HCO3 – , SO4 2 – ) and very high salt ions contents due to the influence of surface water, evaporate leaching and irrigation water return. The isotopic composition of samples of phreatic and CI aquifers shows a clear difference between the two qualities of water. The phreatic aquifer is characterized by the δ18O range from –4.68 to –6.1, whereas δ2H from –47.25 to –59.48 and CI with values of the δ18O range from –5.96 to –7.6, and δ2H range between –53.7 and –65.78 isotopic signature. The unconfined aquifer above IC forms a special case of a mixture of ancient water from deep horizons and recent water strongly enriched from shallow horizon lands.
    Źródło:
    Geomatics, Landmanagement and Landscape; 2023, 1; 7--21
    2300-1496
    Pojawia się w:
    Geomatics, Landmanagement and Landscape
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Unraveling cementation environment and patterns of Holocene beachrocks in the Arabian Gulf and the Gulf of Aqaba : stable isotope approach
    Autorzy:
    Koeshidayatullah, A.
    Al-Ramadan, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059746.pdf
    Data publikacji:
    2014
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    cementation
    beachrocks
    stable isotope
    Arabian Gulf
    Gulf of Aqaba
    Opis:
    This paper analyses Holocene beachrocks from the Arabian Gulf and the Gulf of Aqaba to explain the mechanisms that influence the cementation process in these areas. Holocene beachrocks in the Gulf of Aqaba are composed of predominantly terrigenous material derived from erosion of adjacent uplifted Precambrian basement, while the beachrocks in the Arabian Gulf are composed mainly of marine bioclasts and wind-blown siliciclastic sands. The cements of beachrocks in both areas show three textural varieties: (1) isopachous phreatic acicular aragonite; (2) a micritic envelope of high-Mg calcite (HMC); (3) meniscus and gravitational vadose HMC. Radiocarbon dating of beachrock samples from the Arabian Gulf yielded ages from ca. 2300 to 660 yr cal BP whereas samples from the Gulf of Aqaba range in age between 5500 and 2800 yr cal BP. Oxygen isotope values range from 2.6 to 4.4‰ respectively for the Arabian Gulf whereas the Gulf of Aqaba values range from 1.2 to 1.5‰. Carbon isotope values range from 3.2 to 5.9‰ for the Arabian Gulf whereas those from the Gulf of Aqaba range from 3.8 to 4.6‰. The values of δ18OVPDB and δ13CVPDB in the beachrocks of both areas suggest a marine origin. The beachrocks of the Arabian Gulf were precipitated under high evaporation conditions, while beachrocks from the Gulf of Aqaba were precipitated in normal shallow-marine conditions. The mineralogy and textural habits suggest that cementation of these beachrocks started within the shallow-marine phreatic zone.
    Źródło:
    Geological Quarterly; 2014, 58, 2; 207--216
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Anatomy of contaminated aquifers of an industrial site : insights from the stable isotope compositions of waters and dissolved inorganic carbon
    Autorzy:
    Vennemann, T. W.
    Angloher-Reichelt, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2058959.pdf
    Data publikacji:
    2005
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    isotope compositions
    inorganic carbon
    geological cross-section
    Opis:
    The hydrogen and oxygen isotopes of water and the carbon isotope composition of dissolved inorganic carbon (DIC) from different aquifers at an industrial site, highly contaminated by organic pollutants representing residues of the former gas production, have been used as natural tracers to characterize the hydrologic system. On the basis of their stable isotope compositions as well as the seasonal variations, different groups of waters (precipitation, surface waters, groundwaters and mineral waters) as well as seasonably variable processes of mixing between these waters can clearly be distinguished. In addition, reservoir effects and infiltration rates can be estimated. In the northern part of the site an influence of uprising mineral waters within the Quaternary aquifers, presumably along a fault zone, can be recognized. Marginal infiltration from the Neckar River in the east and surface water infiltration adjacent to a steep hill on the western edge of the site with an infiltration rate of about one month can also be resolved through the seasonal variation. Quaternary aquifers closer to the centre of the site show no seasonal variations, except for one bore hole close to a for mermill channel and an other bore hole adjacent to a rain water channel. Distinct carbon isotope compositions and concentrations of DIC for these different groups of waters reflect variable influence of different components of the natural carbon cycle: dissolution of marine carbonates in the mineral waters, biogenic, soil-derived CO2 in ground- and surface waters, as well as additional influence of atmospheric CO2 for the surface waters. Many Quaternary aquifer waters have, how ever, distinctly lower δ13CDIC values and higher DIC concentrations compared to those expected for natural waters. Given the location of contaminated groundwaters at this site but also in the industrially well-developed valley out side of this site, the most likely source for the low δ13CDIC values is a biodegradation of anthropogenic organic substances, in particular the taroils at the site.
    Źródło:
    Geological Quarterly; 2005, 49, 2; 113-126
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Carbon and oxygen isotope variability among foraminifera and ostracod carbonated shells
    Autorzy:
    Fourel, François
    Martineau, François
    Emoke Tóth, Emoke
    Görög, Agnes
    Escarguel, Gilles
    Lécuyer, Christophe
    Powiązania:
    https://bibliotekanauki.pl/articles/763395.pdf
    Data publikacji:
    2015
    Wydawca:
    Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
    Tematy:
    stable isotope
    foraminifera
    ostracod
    heterogeneity
    single shell analysis
    Opis:
    This study investigates the effect of biological and environmental inter-individual variability on the meaning of d18O and d13C values acquired on small carbonated shells. First we present data obtained with a MultiPrep automated carbonate system on small sample sizes of a homogeneous carbonate material: Carrara marble. This demonstrates the capacities of the analytical system to reliably run small amounts of carbonates even down to 10 mg. Then we present two data sets obtained on real fossil samples of various size (sensu number of individual organisms) calibrated against the NBS19 carbonate standard. Both datasets evidence a clear trend of between-biological sample standard deviation increase for both d18O and d13C measurements when the number of pooled specimens per sample decreases. According to the results obtained from a systematic study of a geologically homogeneous sample of coeval fossil Elphidium foraminifera, we estimate that there is 95% of chances to reach between-biological sample standard deviation values higher than 1.02‰ (d18O) and 1.45‰ d13C) based on single-cell measurements. Such values are one order of magnitude higher than the instrumental standard deviations associated with these stable isotope ratios. Conversely, a minimum of 35 (d18O) and 44 (d13C) pooled specimens of Elphidium appears necessary to reach a between-sample standard deviation £ 0.25‰ with a probability of 95%. Such biological intrinsic and irreducible variability between coeval individuals, and thus samples, clearly questions the interest for single-cell analyses, more precisely, for coastal marine species, such as Elphidium, subject to many environmental changes during their life-time. Indeed, strong variations in salinity or temperature, as well as biogenic fractionation, could influence the isotopic composition of an individual specimen. Results might be less problematic for an average community including several tests. This paper underlines uncertainties linked to specific environments in which selected organisms live, especially for paleoceanographic or paleoclimatic reconstruction purposes where secular oxygen and carbon isotope variations typically range from 0.5 to 1.5‰.
    Źródło:
    Annales Universitatis Mariae Curie-Skłodowska, sectio AAA – Physica; 2015, 70
    0137-6861
    Pojawia się w:
    Annales Universitatis Mariae Curie-Skłodowska, sectio AAA – Physica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Antibiotic therapy and fat digestion and absorption in cystic fibrosis
    Autorzy:
    Lisowska, Aleksandra
    Pogorzelski, Andrzej
    Oracz, Grzegorz
    Skorupa, Wojciech
    Cofta, Szczepan
    Szydłowski, Jarosław
    Socha, Jerzy
    Walkowiak, Jarosław
    Powiązania:
    https://bibliotekanauki.pl/articles/1039883.pdf
    Data publikacji:
    2011
    Wydawca:
    Polskie Towarzystwo Biochemiczne
    Tematy:
    stable isotope breath test
    malabsorption
    antibiotic therapy
    cystic fibrosis
    Opis:
    Antibiotic therapy in the cystic fibrosis (CF) mouse model has been shown to result in reduced bacterial load of the intestine and significant body mass gain. The effect was suggested to be linked to the improvement of intestinal digestion and absorption. Therefore, we aimed to assess the influence of routinely applied antibiotic therapy in CF patients on fat assimilation. Twenty-four CF patients aged 6 to 30 years entered the study. Inclusion criteria comprised confirmed exocrine pancreatic insufficiency and bronchopulmonary exacerbation demanding antibiotic therapy. Exclusion criteria comprised: antibiotic therapy six weeks prior to the test, liver cirrhosis, diabetes mellitus, oxygen dependency, the use of systemic corticosteroids. In all enrolled CF subjects, 13C-labelled mixed triglyceride breath test (13C MTG-BT) was performed to assess lipid digestion and absorption, before and after antibiotic therapy. Sixteen subjects were treated intravenously with ceftazidime and amikacin, eight patients orally with ciprofloxacin. Cumulative percentage dose recovery (CPDR) was considered to reflect digestion and absorption of lipids. The values are expressed as means (medians). The values of CPDR before and after antibiotic therapy did not differ in the whole studied group [4.6(3.3) % vs. 5.7(5.3) %, p = 0.100] as well as in the subgroup receiving them intravenously [4.6(3.2) % vs. 5.7(5.3) %, p = 0.327] or in that with oral drug administration [4.6(3.4) % vs. 5.7(5.4) %, p = 0.167]. In conclusion, antibiotic therapy applied routinely in the course of pulmonary exacerbation in CF patients does not seem to result in an improvement of fat digestion and absorption.
    Źródło:
    Acta Biochimica Polonica; 2011, 58, 3; 345-347
    0001-527X
    Pojawia się w:
    Acta Biochimica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Geochemical and stable isotope patterns of calcite cementation in the Upper Cretaceous Chalk, UK: Direct evidence from calcite-filled vugs in brachiopods
    Autorzy:
    Hu, X.
    Jeans, C.
    Dickson, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/139259.pdf
    Data publikacji:
    2012
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    cement kalcytowy
    diageneza
    historia
    izotopy stabilne
    kreda
    pierwiastki śladowe
    wpływ drobnoustrojów
    anoxia
    calcite cement
    chalk
    diagenesis
    history
    Microbial influence
    oxia
    stable isotopes
    suboxia
    trace elements
    Opis:
    The history of research into the cementation of the Upper Cretaceous Chalk of the UK is reviewed. Calcite-filled vugs within the shell cavities of terebratulid brachiopods from the Cenomanian Chalk of eastern england have been investigated by cathodoluminesence imaging, staining, electron microprobe and stable isotope analysis. This has provided the first detailed analysis of the geochemistry of the Chalk.s cement. two cement series, suboxic and anoxic, are recognized. Both start with a Mg-rich calcite with positive [delta^13]C values considered to have been precipitated under oxic conditions influenced by aerobic ammonification. The suboxic series is characterized by positive [delta^13]C values that became increasingly so as cementation progressed, reaching values of 3.5[per mil]. Manganese is the dominant trace element in the earlier cement, iron in the later cement. Mn-and Fe-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. The anoxic series is characterized by [delta^13]C values that became increasingly negative as cementation progressed, reaching values of .6.5[per mil]. Trace elements are dominated by iron and manganese. Sulphate-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. Both cement series are related closely to lithofacies and early lithification pre-dating the regional hardening of the Chalk. The suboxic series occurs in chalk which was continuously deposited and contained hematite pigment and limited organic matter. The anoxic series was associated with slow to nil deposition and hardground development inc halks that originally contained hematite pigment but no longer do so, and an enhanced supply of organic matter.
    Źródło:
    Acta Geologica Polonica; 2012, 62, 2; 143-172
    0001-5709
    Pojawia się w:
    Acta Geologica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Black "marble" in the Polish architecture - characteristics and possibility of its provenance determination: the case of the Dębnik limestone
    Autorzy:
    Marszałek, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/184492.pdf
    Data publikacji:
    2014
    Wydawca:
    Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
    Tematy:
    black limestone
    provenance
    petrography
    stable isotope geochemistry
    deterioration
    Polska
    Belgium
    Opis:
    Black limestone, also known as black "marble", was widely used in the Polish small-scale architecture and art of the 17th and 18th centuries. Besides the Devonian limestone from Dębnik near Krakow, also popular were the Netherlandish (Wallonian), Devonian to Carboniferous limestones from the Meuse River and Schelde River valleys. This paper deals with the possibility of identifying the rocks imported to Poland. Macroscopic similarities between the Netherlandish rocks and some Dębnik limestones have been highlighted for the oldest Carmelite quarry in Dębnik, exploiting the best stones. The analyses include: optical microscopy, scanning electron microscopy with EDS, X-ray diffraction, X-ray fluorescence and isotope ratio mass spectrometry (13 C and 18 O stable isotopes). Carboniferous limestones from Netherlands can be identified within and distinguished from the Dębnik limestone in the macroscopic observations. Differences, depending on the varieties, are associated primarily with the presence of white calcite fragments of fossils, calcite veins intersecting the rock in all directions or hardness of the limestones. Deeply black Devonian limestones from Wallonia and Dębnik without macrofossils and calcite veins differ in microscopic observations considering their texture, type of microfossils and inventory of non-carbonate components. The characteristic graying and whitening of the black limestones has also been discussed as a possible feature of rock provenance.
    Źródło:
    Geology, Geophysics and Environment; 2014, 40, 2; 189-205
    2299-8004
    2353-0790
    Pojawia się w:
    Geology, Geophysics and Environment
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Isotopic mass balance of metamorphic fluids in the Gogołów–Jordanów serpentinite massif, Lower Silesia, SW Poland
    Autorzy:
    Mydłowski, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/191462.pdf
    Data publikacji:
    2009
    Wydawca:
    Polskie Towarzystwo Geologiczne
    Tematy:
    serpentinization
    stable isotope
    tectonics
    numerical modelling
    Gogołów-Joradanów Massif
    SW Poland
    Opis:
    This work aims at estimation of the amount of metamorphic fluids which led to the present-day variability of isotopic compositions, ?D and ?18O, in serpentinites from the Gogołów–Jordanów Massif. This goal was achieved by means of a numerical model reproducing selected features of geological environment and a computer application supporting this model. The Gogołów–Jordanów Massif consists of peridotites transformed to a different degree into serpentinites and subject to brittle deformation that produced a complex fracture system. The potential tectonic control on the pattern of the fluid migration paths was investigated using palaeostress analysis based on slickenside measurements. Isotopic analyses were carried out for hydrogen and oxygen from serpentine, oxygen from magnetite, and hydrogen and oxygen from carbonates. The variability of ?D and ?18O in the serpentinites along the modelled migration paths demonstrates that serpentinization of peridotites was caused by fluids derived from at least three sources revealing different isotopic characteristics. Fluids produced during the magmatic-hydrothermal stage played a major role in serpetinization, since they represent approximately 95% of all fluids interacting with the rock. In contrast, oceanic water represents only 1% of fluids involved in serpenti- nization. The calculated mean amount of fluid required for serpentinization of 1 m3 of peridotite is equal to 98 × 104 kg.
    Źródło:
    Annales Societatis Geologorum Poloniae; 2009, 79, No 2; 147-158
    0208-9068
    Pojawia się w:
    Annales Societatis Geologorum Poloniae
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Origin of sulfates in the post-mining lakes in the eastern part of Muskau Arch (Polish-German borderland)
    Autorzy:
    Labus, K. M.
    Skoczyńska-Gajda, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2060557.pdf
    Data publikacji:
    2013
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    acid mine drainage
    post-mining lakes
    stable isotope analyis
    Muskau Arch
    Opis:
    Exploitation of lignites, carried out within glaciotectonic structures of Muskau Arch, led to formation of numerous post-minng lakes impacted by Acid Mine Drainage (AMD). . The isotopic analyses decribed in this paper allowed for identification of sources of the dissolved sulphates in the waters of two representative lakes. One of the sources of sulfur isotopes could be oxidation of sulphides (supplied in debris sliding from the slopes of waste dumps, which are surrounding the lakes) in the water column. The fraction of oxygen from water in forming the sulphates vary from about 5% to 25% in the first lake, while in the second it falls within the range 25%-85%. The research confirmed that the main source of sulfates in the lakes is the oxidation of pyrite.
    Źródło:
    Geological Quarterly; 2013, 57, 3; 561--566
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Assessment of Agricultural Use of the Bottom Sediments from Eutrophic Rzeszów Reservoir
    Ocena możliwości rolniczego wykorzystania osadów dennych z eutroficznego zbiornika zaporowego Rzeszów
    Autorzy:
    Bartoszek, L.
    Koszelnik, P.
    Gruca-Rokosz, R
    Powiązania:
    https://bibliotekanauki.pl/articles/1818154.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Koszalińska. Wydawnictwo Uczelniane
    Tematy:
    zbiornik zaporowy
    osady denne
    stabilne izotopy
    reservoirs
    bottom sediment
    stable isotope
    Opis:
    Zbiornik zaporowy Rzeszów na rzece Wisłok w południowo-wschodniej Polsce, został zbudowany w 1973 roku. W trakcie jego eksploatacji, niektóre strefy zbiornika zostały zamulone i zalądowione, przez co jego powierzchnia i głębokość istotnie się zmniejszyły. Pomimo kilkukrotnych rekultywacji, zbiornik jest nadal silnie zamulony i jego funkcje użytkowe są mocno ograniczone. Celem pracy jest analiza zanieczyszczeń i możliwość wykorzystania rolniczego urobku wydobytego ze zbiornika. W pracy dokonano analizy ilościowej zarówno substancji potencjalnie toksycznych jak i biogennych w próbkach osadów pobranych w ciągu ostatnich pięciu lat ze stanowisk zlokalizowanych wzdłuż osi zbiornika. Ponadto, zostało oszacowane pochodzenie materii organicznej zawartej w tych osadach. W tym celu wykorzystano analizy zawartości stabilnych izotopów N i C jak również stosunków elementarnych tych pierwiastków. Krzemionka była dominującym składnikiem osadu (około 67% suchej masy osadu), zaś materia organiczna (OM) stanowiła około 10% s.m.o. Stężenia związków biogennych: OWO, azotu ogólnego i fosforu ogólnego wynosiły średnio odpowiednio 2,31%, 0,21% i 0,031% s.m.o. Pochodzenie osadów dennych zbiornika Rzeszów jest mieszane. Niespodziewanie wysoki udział materii autochtonicznej może być wynikiem intensywnej eutrofizacji wód zbiornika. Zawartości WWA były stosunkowo niskie. Najwyższe zauważone stężenie wynosiło 0,164 ppm w przypadku benzo(k)fluorantenu. Zawartość benzo(a)pirenu była niższa od 0,14 ppm. Poziomy stężeń wybranych kongenerów PCB mieściły się w przedziale od 0,0006 do 0,003 ppm i były poniżej wartości normatywnych. Badane osady były umiarkowanie zanieczyszczone metalami ciężkimi (Cu, Cd, Cr, Zn, Ni, Pb). Średnie stężenia wszystkich metali przekraczały sporadycznie tło geochemiczne i poziom TEC, ale wartość PEC nie została przekroczona w żadnej z analizowanych próbek. Charakter badanych osadów wskazuje, że nie są one odpowiednie do stosowania w rolnictwie ze względu na zanieczyszczenie i brak żyzności. Jednak mogą one być wykorzystywane do rekultywacji gruntów nierolniczych. Istnieją metody umożliwiające usunięcie z wydobytego materiału z tych zanieczyszczeń, głównie metali ciężkich, ale z uwagi na znaczne ilości urobku proces może okazać się nieopłacalny.
    Źródło:
    Rocznik Ochrona Środowiska; 2015, Tom 17, cz. 1; 396-409
    1506-218X
    Pojawia się w:
    Rocznik Ochrona Środowiska
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Regional hardening of Upper Cretaceous Chalk in eastern England, UK: trace element and stable isotope patterns in the Upper Cenomanian and Turonian Chalk and their significance
    Autorzy:
    Jeans, C. V.
    Long, D.
    Hu, X.-F.
    Mortimore, R. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/139436.pdf
    Data publikacji:
    2014
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    chalk hardening
    trace elements
    stable isotopes
    cement modelling
    reservoir diagenesis
    history
    kreda
    hartowanie
    pierwiastki śladowe
    izotopy trwałe
    cement
    historia
    Opis:
    The regional hardening of the Late Cenomanian to Early Turonian Chalk of the Northern Province of eastern England has been investigated by examining the pattern of trace elements and stable carbon and oxygen isotopes in the bulk calcite of two extensive and stratigraphically adjacent units each 4 to 5 m thick of hard chalk in Lincolnshire and Yorkshire. These units are separated by a sequence, 0.3–1.3 m thick, of variegated marls and clayey marls. Modelling of the geochemistry of the hard chalk by comparison with the Standard Louth Chalk, combined with associated petrographic and geological evidence, indicates that (1) the hardening is due to the precipitation of a calcite cement, and (2) the regional and stratigraphical patterns of geochemical variation in the cement are largely independent of each other and have been maintained by the impermeable nature of the thin sequence of the clay-rich marls that separate them. Two phases of calcite cementation are recognised. The first phase was microbially influenced and did not lithify the chalk. It took place predominantly in oxic and suboxic conditions under considerable overpressure in which the Chalk pore fluids circulated within the units, driven by variations in compaction, temperature, pore fluid pressure and local tectonics. There is evidence in central and southern Lincolnshire of the loss of Sr and Mg-enriched pore fluids to the south during an early part of this phase. The second phase of calcite precipitation was associated with the loss of overpressure in probably Late Cretaceous and in Cenozoic times as the result of fault movement in the basement penetrating the overlying Chalk and damaging the seal between the two chalk units. This greatly enhanced grain pressures, resulting in grain welding and pressure dissolution, causing lithification with the development of stylolites, marl seams, and brittle fractures. Associated with this loss of overpressure was the penetration of the chalk units by allochthonous fluids, rich in sulphate and hydrocarbons, derived probably from the North Sea Basin. Microbial sulphate-reduction under anoxic conditions within these allochthonous fluids has been responsible for dissolving the fine-grained iron and manganese oxides within the chalk, locally enriching the Fe and Mn content of the calcite cement. The possibility is discussed that the pattern of cementation preserved in these regionally hard chalks of Late Cenomanian and Early Turonian age may be different from that preserved in the younger (late Turonian to Campanian) more basinal chalks of eastern England.
    Źródło:
    Acta Geologica Polonica; 2014, 64, 4; 419-455
    0001-5709
    Pojawia się w:
    Acta Geologica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Stanowisko mamuta – Mammuthus primigenius (Blumenbach, 1799) w górnym plejstocenie Kopalni Węgla Brunatnego Bełchatów
    Mammuthus primigenius (Blumenbach, 1799) fromUpper Pleistocene deposits of the Be³chatów Coal Mine
    Autorzy:
    Błażejowski, B.
    Jakubowski, G.
    Gieszcz, P.
    Kowalski, R.
    Hołda-Michalska, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/2075107.pdf
    Data publikacji:
    2014
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    mamut włochaty
    izotopy stabilne w zębach
    Bełchatów
    woolly mammoth
    stable isotope composition of teeth
    Opis:
    The fossil remains of juvenile woolly mammoth (Mammuthus primigenius) from Pleistocene deposits of the Be³chatów coal mine are described. Precise measurements of the excavated bones allowed for approximate reconstruction of the specimen, which turned out to be in the estimated age of 10 years. Serial samples for isotope analysis of carbon and oxygen were taken from a tooth, and the isotope record has revealed a probable change of diet due to switching from milk-based to plant-based food.
    Źródło:
    Przegląd Geologiczny; 2014, 62, 11; 755--760
    0033-2151
    Pojawia się w:
    Przegląd Geologiczny
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Tracing the signature of various frontal systems in stable isotopes (oxygen and carbon) of the planktonic foraminiferal species Globigerina bulloides in the Southern Ocean (Indian Sector)
    Autorzy:
    Khare, N.
    Chaturvedi, S.K.
    Powiązania:
    https://bibliotekanauki.pl/articles/48922.pdf
    Data publikacji:
    2012
    Wydawca:
    Polska Akademia Nauk. Instytut Oceanologii PAN
    Tematy:
    Foraminifera
    Globigerina bulloides
    stable isotope
    frontal system
    oxygen
    carbon
    foraminiferal species
    water mass
    Southern Ocean
    Opis:
    Twenty-five surficial sediment samples, collected on board ORV Sagar Kanya during her 199th and 200th cruises along a north-south transect between latitudes 9.69◦N and 55.01◦S, and longitudes 80◦E and 40◦ E were studied for isotopic variations (values of δ18O and δ13C) of the indicator planktonic species Globigerina bulloides. The results indicate that from latitudes 9.69◦N to 15◦ S both these isotopes (δ18O and δ13C) fluctuated significantly. Between latitudes from around 15◦S to 30–35◦S δ18O values steadily increased, whereas δ13C showed a decreasing trend. However, to the south of latitudes 30–35◦S, both isotope values showed a similar response with a gradual increase up to latitude 50◦S, beyond which δ18O continued to increase while δ13C declined. The characteristic patterns of the values of both isotopes indicates that the signatures of different water masses are associated with various frontal systems and/or water masses across the transect. The signature of the Polar Front at around latitude 50◦S shows the specific response of the isotopic values (δ18O and δ13C) of G. bulloides. Such a response beyond 50◦S latitude is ascribable to the general decrease in the ambient temperature, resulting in a continuous increase in δ18O values, while δ13C values decrease as a result of reduced photosynthesis in regions approaching higher latitudes owing to low light penetration. To further corroborate our results, those of many such transects from geographically distinct regions need to be studied for isotopic variations in the calcareous shells of planktonic foraminiferal species. The results have the potential to be used as a proxy to assess the movement of frontal systems in southern high latitude regions.
    Źródło:
    Oceanologia; 2012, 54, 2
    0078-3234
    Pojawia się w:
    Oceanologia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Saurichthys (Pisces, Actinopterygii) teeth from the Lower Triassic of Spitsbergen, with comments on their stable isotope composition (δ13C and δ18O) and X−ray microtomography
    Autorzy:
    Błażejowski, Błażej
    Duffin, Christopher J.
    Gieszcz, Piotr
    Małkowski, Krzysztof
    Binkowski, Marcin
    Walczak, Michał
    McDonald, Samuel A.
    Withers, Philip J.
    Powiązania:
    https://bibliotekanauki.pl/articles/2051411.pdf
    Data publikacji:
    2013
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    Arctic
    Svalbard
    fish teeth
    stable isotopes
    x−ray microtomography
    Lower Triassic
    Źródło:
    Polish Polar Research; 2013, 1; 23-38
    0138-0338
    2081-8262
    Pojawia się w:
    Polish Polar Research
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Opportunities and constraints for reconstructing palaeoenvironments from stable light isotope ratios in fossils
    Autorzy:
    Lee-Thorp, J. A.
    Sponheimer, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2060629.pdf
    Data publikacji:
    2005
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    stable light isotopes
    fossils
    vertebrates
    diagenesis
    environmental reconstruction
    Opis:
    Stable light isotope ratios (13C/12C and 18O/16O) in fossilteeth provide key archives for understanding ecology of past faunal communities and the evolution of environments during the Plio-Pleistocene. Given the inevitable processes of diagenesis during fossilisation, the integrity of isotopic in formation and the degree of detailed in formation that can be extracted, remain important issues in all fossil studies. The most appropriate tests are those in trinsic to isotopic abundances in ecosystems. They are easier to develop for 13C/12C in savanna environments where large 13C/12C differences exist between C4 tropical grasses and C3 trees and shrubs. Validating 18O/16O ratios in fossil carbonate or phosphate is more difficult, but patterned variability, mainly tracking water-related behaviour, within modern faunal communities has been replicated in several fossil as semblages. The identification of seasonal variation in 13C/12C and 18O/16O along the growth axis of a tooth crown, also applicable in areas composed solely of C3 plants, fills a dual role as a test and for providing data on seasonal amplitude. The results of studies from low- and mid-latitude African sites suggest that isotopic variation in rain fall on short timescales and ecological differences amongst animals, dominate over smaller differences in 18O16O composition due to temperature.
    Źródło:
    Geological Quarterly; 2005, 49, 2; 195-204
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Frakcjonowanie trwałych izotopów azotu w obiegu naturalnym - implikacje dla badań zanieczyszczeń wód podziemnych
    Stable isotope fractionation of nitrogen in the natural cycle - implication for the studies of groundwater pollution
    Autorzy:
    Leśniak, P.M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2074452.pdf
    Data publikacji:
    2006
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    izotop azotu
    obieg azotu
    zanieczyszczenia
    wody podziemne
    ochrona wód
    nitrate
    isotopes
    nitrogen cycle
    pollution
    Opis:
    Changes of the 15N/14N isotopic composition in the natural nitrogen cycle have been described. As the nitrogen natural cycle is heavily perturbed by humans, one of the isotopic method of identification of manures and fertilizers in groundwaters is provided.
    Źródło:
    Przegląd Geologiczny; 2006, 54, 7; 594-596
    0033-2151
    Pojawia się w:
    Przegląd Geologiczny
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Trophic connectivity between intertidal and offshore food webs in Mirs Bay, China
    Autorzy:
    Ning, J.
    Du, F.
    Wang, X.
    Wang, L.
    Li, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/47613.pdf
    Data publikacji:
    2019
    Wydawca:
    Polska Akademia Nauk. Instytut Oceanologii PAN
    Tematy:
    intertidal zonation
    offshore zone
    food web
    different habitat
    trophic interaction
    stable isotope
    carbon isotope composition
    Mirs Bay
    China
    Źródło:
    Oceanologia; 2019, 61, 2
    0078-3234
    Pojawia się w:
    Oceanologia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Metodyka analiz izotopowych rozpuszczonego węgla nieorganicznego (DIC) i ich zastosowania w badaniach hydrogeologicznych i środowiskowych
    Methodology and application of stable isotope analysis of dissolved inorganic carbon (DIC) in hydrogeology and environmental studies
    Autorzy:
    Szynkiewicz, A.
    Drzewicki, W.
    Jędrysek, M. O.
    Powiązania:
    https://bibliotekanauki.pl/articles/2074490.pdf
    Data publikacji:
    2006
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    rozpuszczony węgiel nieorganiczny (DIC)
    izotop węgla
    dissolved inorganic carbon
    carbon isotopes
    Opis:
    The analysis of carbon isotope composition of dissolved inorganic carbon (DIC) is widely applied in hydrogeology and environmental studies. The method of analysis is simple and based on conversion of all DIC species to gaseus CO2 under acidic conditions. However, the analytical procedure may involve significant carbon isotope fractionation. Our experimental analysis showed that increasing the time of CO2 extraction influences the increase of ä13C(DIC) value as a result of re-dissolution of CO2 in the water expanded on the vacuum line or/and carbon isotope exchange between the extracted CO2 and the atmospheric CO2. The long time of sample storage yields an increase of ä13C(DIC) value and decrease of DIC concentration. The analytical precision up to š 0,1‰ may be achieved in the case of waters being analyzed few days after sampling. DIC concentration was evaluated according to height of peak 44 in the mass spectrum. The analytical precision of this method was š 2 mgCO2 per dm3. This method is very useful because the measurements of the height of peak 44 and carbon isotope composition of DIC can be performed simultaneously. However, this method is reliable for waters containing more than 4 mg CO2 per dm3
    Źródło:
    Przegląd Geologiczny; 2006, 54, 9; 797-806
    0033-2151
    Pojawia się w:
    Przegląd Geologiczny
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Migration assessment of natural gas components in the Borzecin deposit based on results of hydrogen and carbon stable isotope analyzes
    Ocena migracji składników gazu ziemnego w złożu Borzęcin na podstawie wyników analiz izotopów trwałych wodoru i węgla
    Autorzy:
    Pleśniak, Ł.
    Orion-Jędrysek, M.
    Jakubiak, M.
    Bucha, M.
    Krajniak, J.
    Matusewicz, M.
    Kufka, D.
    Matyasik, I.
    Janiga, M.
    Lojen, S.
    Zigon, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/1835283.pdf
    Data publikacji:
    2017
    Wydawca:
    Instytut Nafty i Gazu - Państwowy Instytut Badawczy
    Tematy:
    wzmożone wydobycie gazu
    metan
    ditlenek węgla
    izotopy trwałe
    enhanced gas recovery
    methane
    carbon dioxide
    stable isotopes
    Opis:
    One of the first installations in the World, based on the EGR (Enhanced Gas Recovery) operates in Borzecin (SW Poland). Thus creating the opportunity to gather experience in the development of CCS (Carbon Capture and Storage) on an industrial scale. Due to the small size of the deposit, the technology allows great research opportunity to develop Enhanced Gas Recovery and all the processes associated with the injection of CO2 and H2S are possible to observe in a relatively short time scale. The main goal of the research is tracing migration fronts of injected gases threw sampling and isotopic analysis of gases from numeral boreholes. Gathered results gave the opportunity to get an appraisal of gas migration in the Borzecin deposit. Consequently a new tool for Enhanced Gas Recovery efficiency might be constructed with the potential of being applied in CCS technologies. Isotopic composition of hydrogen (n = 63) in methane varied from –159.3 to –85.2‰ (average –114.6‰) and isotopic composition of carbon including methane (n = 92) varied from –46.93 to –17.87‰ (average –35.22‰). Isotopic composition of carbon in carbon dioxide (n = 88) varied from –23.33 to –3.11‰ (average –13.35‰).
    Jedna z pierwszych instalacji EGR (ang. Enhanced Gas Recovery – wzmożonego wydobycia gazu) na świecie funkcjonuje na złożu Borzęcin (SW Polska). Instalacja umożliwia zebranie doświadczenia w rozwoju technologii CCS (ang. Carbon Capture and Storage – wychwyt, transport oraz trwała izolacja CO2) na skalę przemysłową. Ze względu na niewielkie rozmiary złoża technologia ta daje możliwość rozwoju badawczego EGR, przy czym wszystkie procesy związane z zatłaczaniem ditlenku węgla i siarkowodoru są możliwe do obserwacji w stosunkowo niedługiej skali czasu. Głównym celem badań była próba oceny migracji zatłaczanych gazów poprzez pobór i analizę izotopów trwałych wodoru i węgla w gazach z poszczególnych otworów wiertniczych. Dzięki uzyskanym wynikom możliwa jest ocena migracji składników gazu ziemnego w złożu Borzęcin. W rezultacie przeprowadzonych badań otrzymano nowe narzędzie do oceny efektywności wzmożonej eksploatacji gazu, które następnie może być zastosowane w technologiach związanych z CCS. Skład izotopowy wodoru (n = 63) w metanie mieścił się w zakresie od –159,3‰ do – 85,2‰ (średnia –114,6‰), a skład izotopowy węgla (n = 92) w tym metanie wyniósł od –46,93‰ do –17,87‰ (średnia –35,22‰). Skład izotopowy węgla (n = 88) w ditlenku węgla osiągnął wartość od –23,33‰ do –3,11‰ (średnia –13,35‰).
    Źródło:
    Nafta-Gaz; 2017, 73, 1; 27-35
    0867-8871
    Pojawia się w:
    Nafta-Gaz
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    13C-urea breath test for detection of Helicobacter pylori and its correlation with endoscopic and histologic findings
    Autorzy:
    Hilker, E
    Domschke, W.
    Stoll, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/71128.pdf
    Data publikacji:
    1996
    Wydawca:
    Polskie Towarzystwo Fizjologiczne
    Tematy:
    gastritis
    gastric ulcer
    infection
    mucosa
    endoscopical finding
    duodenal ulcer
    urea breath test
    Helicobacter pylori
    gastric carcinoma
    lymphatic tissue
    ulcer
    stable isotope
    histological finding
    stomach
    urease
    malignant lymphoma
    Źródło:
    Journal of Physiology and Pharmacology; 1996, 47, 1
    0867-5910
    Pojawia się w:
    Journal of Physiology and Pharmacology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The use of the stable oxygen isotope (18 O) to trace the distribution and uptake of water in riparian woodlands
    Autorzy:
    Lambs, L.
    Loudes, J.
    Berthelot, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/147005.pdf
    Data publikacji:
    2002
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    oxygen isotope
    riparian forest
    water origin
    xylem sap
    Opis:
    Streamside vegetation forming narrow "corridors" in temperate regions, is typically dominated by deciduous tree species reflecting strong influences by human activities. Riparian woodlands depend on hydrological resources and have to adapt to rapid changes in water levels and soil moisture conditions. Three main water sources are typically present in the riparian zone: river water originating in the mountains, ground water and rainfall. Stable isotopes, such as oxygen-18, are useful tools which allow for water movement to be traced within the riparian zone and which help to identify water sources utilised by the trees growing in these areas.
    Źródło:
    Nukleonika; 2002, 47,suppl.1; 71-74
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Biological markers and stable carbon isotope studies of bitumen impregnating Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)
    Autorzy:
    Kotarba, M. J.
    Fabiańska, M.
    Więcław, D.
    Kowalski, A.
    Zych, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/191516.pdf
    Data publikacji:
    2009
    Wydawca:
    Polskie Towarzystwo Geologiczne
    Tematy:
    biomarkers
    stable carbon isotopes
    bitumen content
    oil origin
    woolly rhinoceros
    Starunia palaeontological site
    Carpathian region
    Ukraine
    Opis:
    Biological markers and stable carbon isotopic compositions of bitumen impregnating the Pleistocene and Holocene sediments around the Starunia palaeontological site (Carpathian region, Ukraine) near discovered remnants of a mammoth and three woolly rhinoceroses, and one almost completely preserved rhinoceros carcass found in 1907 and 1929, were investigated. The research was carried out to assess genetic connections between the bitumen and oils from the nearby deep accumulations of the Boryslav-Pokuttya and Skyba units of the Carpathians. Another aim of these geochemical studies was to reveal the secondary geochemical processes (oxidation and biodegradation) influencing the bitumen, and to determine which environments have been favourable or unfavourable for the preservation of large Pleistocene vertebrates. Bitumen included within the near-surface rocks are not genetically connected with residual organic matter present in Quaternary sediments. Geochemical features, such as distributions of pentacyclic triterpanes and steranes, biomarker parameters and isotope composition indicate that all bitumens originate from oil-prone, Type II kerogen with insignificant admixture of terrestrial Type III kerogen in the middle stage of catagenesis. The oils occurring in deep accumulations in the Starunia area were the sole source of bitumen found in the near-surface sediments. Input of immature organic matter to bitumen from Pleistocene and Holocene sediments has not been found. The main factors differentiating the bitumen were: biodegradation, water washing and/or weathering. Additional influence of transport of bitumen by brine was found. The most favourable conditions for preservation of large, extinct mammals within the Pleistocene muds exist in the vicinity of Nos 22 and 23 boreholes, where bitumen is best preserved. The worst conditions were found in the vicinity of Nos 1, 4, 4' and 15 boreholes. Intensification of biodegradation and weathering effects were followed by intensive, chaotic changes of the remnants of large Pleistocene mammals.
    Źródło:
    Annales Societatis Geologorum Poloniae; 2009, 79, No 3; 463-480
    0208-9068
    Pojawia się w:
    Annales Societatis Geologorum Poloniae
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Limitation of lignin derivatives as biomarkers of land derived organic matter in the coastal marine sediments
    Autorzy:
    Pempkowiak, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/2079190.pdf
    Data publikacji:
    2020
    Wydawca:
    Polska Akademia Nauk. Instytut Oceanologii PAN
    Tematy:
    lignin oxidation
    biomarker
    stable carbon isotope
    nonlinear analysis
    Gdansk Bay
    Southern Baltic Sea
    coastal sediment
    Opis:
    Lignin oxidation products (vanillyl, syringil and cummaryl phenols), and δ13C were measured in a variety of land and marine samples collected in Inner Puck Bay – dominated by marine vascular plants, small river run-off, and shallow bottom, and in Gdańsk Bay – characterized by large river run-off, small marine vascular plants population, and the average depth exceeding euphotic zone. Both study areas are parts of the Gdańsk Basin, Southern Baltic. Typical δ13C values (δ13C = -28‰) and both composition and concentrations of lignin phenols were measured in samples originating from land. Small, yet easily measurable amounts of lignin phenols were found in marine vascular plants biomass (Σ8 = 90 µg/100 mg organic matter). The biomass was characterized by exceptionally high δ13C values (-12‰). No lignin phenols and typical δ13C values (-22‰) were measured in marine phytoplankton biomass. δ13C and both composition and content of lignin phenols in organic matter of surface sediments collected in the study area fall in the range marked by the end members. The proportion of land derived organic matter calculated using lignin phenols, or δ13C in Gdańsk Bay were comparable, while in Puck Bay they differed substantially. It was concluded that a) in areas with substantial bottom coverage with vascular plants the two end members approach, usually employed to establish the contribution of organic matter sources, is insufficient, b) organic matter originating from three sources: riverine, phytoplankton, and vascular plants contribute to sedimentary organic matter in Puck Bay with the respective proportion 30:40:30.
    Źródło:
    Oceanologia; 2020, 62, 3; 374-386
    0078-3234
    Pojawia się w:
    Oceanologia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The origin and chemical composition of Carpathians chloride CO2-rich waters in the light of stable chlorine isotope studies (37Cl and 35Cl)
    Autorzy:
    Dembska-Sięka, Paulina
    Pelc, Andrzej
    Rajchel, Lucyna
    Powiązania:
    https://bibliotekanauki.pl/articles/2058569.pdf
    Data publikacji:
    2020
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Carpathians
    chloride CO2-rich water
    chlorine isotopes
    chemical composition
    origin
    Opis:
    Investigations into chloride CO2-rich water occurring in the Polish and Slovakian Carpathians were carried out to gain a better understanding of the Cl- sources. The primary Cl- concentration in sea water, processes accompanying diagenesis, together with water-rock-gas interactions, have undoubtedly influenced the present content of chlorides. The Cl-- concentrations in the waters analysed vary from 35.5 to 4148.3 mg/l, lower than in sea water, with a mean ~19000 mg/l. The measured δ37Cl values range from -1.15 to -0.26‰, below the typical sea water value of 0‰. It might be concluded that the chemical and isotopic composition of these waters are the result of reactions during diagenesis (e.g., ion exchange or diffusion through low-permeability clay layers) as well as meteoric water influx.
    Źródło:
    Geological Quarterly; 2020, 64, 1; 197--204
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Zróżnicowanie zawartości pierwiastków śladowych w osadach torfowisk Wolbrom i Otrębowskie Brzegi odzwierciedleniem wpływu antropopresji
    Variability of trace element concentrations in deposits of the Wolbrom and Otrębowskie Brzegi peatlands: a reflection of an anthropogenic impact
    Autorzy:
    Pawełczyk, Fatima
    Okupny, Daniel
    Michczyński, Adam
    Powiązania:
    https://bibliotekanauki.pl/articles/578347.pdf
    Data publikacji:
    2018
    Wydawca:
    Łódzkie Towarzystwo Naukowe
    Tematy:
    torf
    pierwiastki śladowe
    stabilne izotopy ołowiu
    antropopresja
    Polska Południowa
    peat
    trace elements
    stable lead isotope
    anthropogenic activity
    Southern Poland
    Opis:
    W artykule zaprezentowano analizę geochemiczną profili torfowych z dwóch torfowisk, położonych w Polsce Południowej, dokumentujących przedział czasowy od okresu atlantyckiego (od 4900 BC Wolbrom i od 4200 BC Otrębowskie Brzegi) do czasów współczesnych. Jej wyniki poddano analizie statystycznej z użyciem programu PAST, celem porównania badanych torfowisk pod względem wpływu działalności człowieka oraz położenia w różnych zlewniach, z uwzględnieniem przeprowadzonych wcześniej analiz botanicznych, datowania radiowęglowego i ołowiem-210 oraz analizy składu izotopowego Pb. Koncentracja pierwiastków w badanych profilach torfowych zależała od rodzaju osadu i była mocno zróżnicowana, wahając się w przedziale od wartości niskich, zbliżonych do lokalnego tła geochemicznego, aż do ekstremalnie wysokich (w szczególności w przypadku metali ciężkich, takich jak cynk i ołów). Przeprowadzona analiza porównawcza pozwoliła na zaobserwowanie synchronicznego zapisu lokalnych, jak i regionalnych zmian składu chemicznego w dwóch torfowiskach, różniących się lokalizacją, litologią i rodzajem torfu.
    A geochemical analysis was conducted on peat cores from two peatlands in Southern Poland that cover a time span from the Atlantic period (from 4900 BC in Wolbrom and from 4200 BC in Otrębowskie Brzegi) to modern times. The results were subjected to a statistical analysis using PAST software. The analysis was conducted taking into account previous botanical analyses, radiocarbon dating and lead-210 dating. The aim was to compare these two study sites in terms of their locations in different basins and anthropogenic activity. Elemental concentrations in the tested peat profiles were dependent on sediment type and their values range between very low (close to geochemical background values) and extremely high – especially in the case of heavy metals, like zinc and lead. The comparative analysis showed a synchronous record of local and regional changes of chemical composition in the two peatlands, which vary in terms of location, lithology and type of peat sediment.
    Źródło:
    Acta Geographica Lodziensia; 2018, 107; 175-190
    0065-1249
    Pojawia się w:
    Acta Geographica Lodziensia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Elemental and organic carbon proxies for redox conditions of the Oligocene formations in the Ropa Tectonic Window (Outer Carpathians, Poland) : palaeoenvironmental implications
    Autorzy:
    Wójcik-Tabol, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/973585.pdf
    Data publikacji:
    2017
    Wydawca:
    Polskie Towarzystwo Geologiczne
    Tematy:
    organic matter
    stable organic carbon isotope
    trace metals
    anoxia
    Grybów Succession
    Oligocene
    Opis:
    The Oligocene Grybów Succession is recognized as a counterpart of the anoxic Menilite Formation. Its comprehensive geochemical investigations are made in the key sections of the Ropa Tectonic Window (the Grybów Unit, Polish Outer Carpathians). The maceral assemblages, dominated by land-plant liptinite, vitrinite and intertinite, correspond to kerogen types II and III. A Tmax vs. HI diagram shows terrestrial kerogen type II with various additions of type III and algal kerogen type I. A variation in δ13Corg. (from –25.21 to –27.38‰) may have resulted from variations in the composition of organic matter (the content of terrestrial vs. marine organic matter), controlled by depositional setting (turbidite vs. hemipelagic). The highest TOC contents are associated with an enhanced influx of land-derived organic matter. The redox-sensitive trace elements positively correlate with TOC and TS contents. Redox conditions varied between oxic and anoxic, as was concluded from TOC-TS, V/(V+Ni) and U/Th. The turbidity currents might have ventilated the bottom waters, especially more efficiently in the proximal zone of turbidite sedimentation. Moreover, oxygenated bottom waters may have also affected the concentration of trace metals, owing to migration of the redox interface downward within the sediments.
    Źródło:
    Annales Societatis Geologorum Poloniae; 2017, 87, 1; 41-53
    0208-9068
    Pojawia się w:
    Annales Societatis Geologorum Poloniae
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Isotopic study of CO2 from industrial off-gases emission
    Autorzy:
    Wierzchnicki, R.
    Plewka, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/148644.pdf
    Data publikacji:
    2010
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    greenhouse gases
    stable isotopes
    CO2 anthropogenic emitters
    isotope ratio mass spectrometry
    Opis:
    The monitoring of greenhouse gases originating from different sources will be a crucial problem during this century. Experiments have been performed in order to obtain stable isotope composition of CO2 emitted by large industrial off-gas emitters. A special set for sample collection in field conditions was designed and tested. Two different methods of CO2 extraction were elaborated: vacuum extraction and extraction with carrier gas. Preliminary results of CO2 stable isotope composition emitted from an electric power plant during one working season are presented.
    Źródło:
    Nukleonika; 2010, 55, 2; 247-250
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Isotope effects in chemistry
    Autorzy:
    Van Hook, W. A.
    Powiązania:
    https://bibliotekanauki.pl/articles/146686.pdf
    Data publikacji:
    2011
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    isotope effects
    stable isotopes
    kinetic isotope effects
    Opis:
    Isotope effects on chemical equilibria, reaction rates and molecular properties are reviewed together with the theoretical formalism for understanding such effects.
    Źródło:
    Nukleonika; 2011, 56, 3; 217-240
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Palaeoenvironmental changes recorded in the oxygen and carbon isotope composition of Kimmeridgian (Upper Jurassic) carbonates from central Poland
    Autorzy:
    Wierzbowski, Henryk
    Powiązania:
    https://bibliotekanauki.pl/articles/2058657.pdf
    Data publikacji:
    2019
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Upper Jurassic
    stable isotopes
    oysters
    Trichites
    carbonate platform
    salinity effects
    Opis:
    Oxygen and carbon isotope ratios of well-preserved calcitic bivalves from the Lower-lowermost Upper Kimmeridgian of Central Poland (SW margin of the Holy Cross Mountains) have been studied to reconstruct palaeoenvironmental conditions and variations in ancient water chemistry. Low and scattered δ18O and δ13C values of bivalve shells from shallow carbonate deposits of the Hypselocyclum and the Hypselocyclum-Divisum zone boundary (-3.5 to -1.5, and 2.6 to 4.0‰, respectively) are a result of salinity changes, and local variations in the composition of dissolved inorganic carbon (DIC) in conditions of restricted water circulation. A slight increase in bivalve δ13C values and more densely clustering of δ18O values is observed after the marine transgression at the Divisum-Mutabilis zone boundary. A global decrease of δ13C values of marine carbonates is partly recorded in Lower-lowermost Upper Kimmeridgian bulk carbonates from central Poland (from the Radomsko Elevation and the Wieluń Upland). Local negative shifts and the data scatter are, however, observed in rocks deposited in a very shallow environment of carbonate platforms during the Platynota and Hypselocyclum chrons. This interval corresponds to the uppermost part of the lowstand systems track of a major regressive trend, which had started already in the Late Oxfordian.
    Źródło:
    Geological Quarterly; 2019, 63, 2; 359--374
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Depth of the water column in relation to carbon isotope ratios in methane in fresh water sediments
    Autorzy:
    Jędrysek, M. O.
    Powiązania:
    https://bibliotekanauki.pl/articles/2058951.pdf
    Data publikacji:
    2005
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    stable carbon isotopes
    methane
    fresh water sediments
    diagenesis
    environmental record
    Opis:
    Methane was collected from the surficial sedimentary layer (0 to about 20 cm) in 45 fresh water lakes in Poland. Sampling was also carried out at various depths of the over lying water column (0.15 to 12 m) between noon and early after noon, on a seasonal basis, between 1992 and 1996. A positive correlation between the depth of the lake water, the δ13 C (CH4) value (from ca. -l.4 to -2.3% per l m depth) and the wider δ13 C (CH4) variation over the thermocline are probably due to: the time of sinking of organic particles resulting in more in tense acetate fermentation in shallower portions of the lake; the temperature variation; differences in the precursors of methane, the diffusion effect, and an increase of bioavailable DIC (dissolved inorganic carbon) at greater depths. Non-seasonal variation of isotope ratios in methane and the depth-isotope ratio correlation show that the lake system is in dynamic equilibrium on a scale of hours and days. Therefore, earlier models of methanogenesis relating and the atmospheric methane isotopic budget, proposed by other authors and based on sampling of methane from sediments, need to be revised. More over, δ13 C (CH4) values higher during seasonal over turn (mixing of benthic and surface waters) than during stagnation, have been observed. This is probably due to the fact that during over turn periods some organic compounds (methane precursors) and methane in the surficial part of sediments, are oxidized with a resalting kinetic isotope effect. It is proposed that oxidation of methane and other organic compounds during seasonal over turn may be responsible for post-depositional lamination observed as pale (autumn over turn) and dark (summer organic-rich unoxic stagnation) millimetres-thick layers in fresh water lake sediments.
    Źródło:
    Geological Quarterly; 2005, 49, 2; 151-164
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Isotope characterisation of deep aquifers in the Gwda catchment, northern Poland
    Autorzy:
    Kotowski, T.
    Satora, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/94215.pdf
    Data publikacji:
    2016
    Wydawca:
    Uniwersytet im. Adama Mickiewicza w Poznaniu
    Tematy:
    Cenozoic aquifers
    groundwater dating
    stable isotopes
    radiocarbon
    kenozoik
    poziomy wodonośne
    datowanie wód podziemnych
    stabilne izotopy
    radiowęgiel
    Opis:
    We present the results of isotope measurements (δ18O, δ D, δ13CDIC and 14C) and chemical analyses (TDS, TOC, HCO3–, SO42–, Cl–, NO3–, NH4+, Ca2+, Mg2+ Na+ and K+) conducted on groundwater samples collected from deep Cenozoic aquifers. These aquifers are the basic source of drinking water at numerous localities within the study area in northern Poland. Most of the δ18O determinations are characterised by low variability (i.e., > 70 per cent of δ18O are between –9.5‰ and –9.2‰). In most cases tritium activity was not detected or its content slightly exceeded the uncertainty of measurement (from ±0.3 T.U. to ± 0.5 T.U.). On average, 14C activity is twice higher than that under similar conditions and in hydrogeological systems. The δ13CDIC values fall within the –13.6‰ to –12.8‰ range. A slight variability is observed when considering all isotope and chemical data within the study area and under these hydrogeological conditions. In general, the results of isotope and chemical analyses seem to be homogeneous, indicating the presence of closely similar groundwaters in the system, irrespective of geological formation. It is likely that there is a significant hydraulic connection between shallow and deep aquifers in the Gwda catchment, which indicates the potential for seepage of pollutants from shallow Pleistocene to deep Miocene aquifers. This can endanger the latter by e.g., high concentrations of NO3–, SO42– and Cl– ions from shallow aquifers within the Gwda catchment.
    Źródło:
    Geologos; 2016, 22, 2; 137-147
    1426-8981
    2080-6574
    Pojawia się w:
    Geologos
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Skład izotopowy dwutlenku węgla w atmosferze Krakowa
    Isotopic composition of carbon dioxide in the atmosphere of Kraków
    Autorzy:
    Jasiek, Alina
    Zimnoch, Mirosław
    Różański, Kazimierz
    Powiązania:
    https://bibliotekanauki.pl/articles/578341.pdf
    Data publikacji:
    2016
    Wydawca:
    Łódzkie Towarzystwo Naukowe
    Tematy:
    izotopy trwałe
    dwutlenek węgla
    izotopowy bilans masy
    stable isotopes
    carbon dioxide
    isotope mass balance
    Opis:
    Izotopy trwałe stanowią doskonałe narzędzie do analizy źródeł pochodzenia gazów cieplarnianych. Znając specyficzne sygnatury izotopowe poszczególnych źródeł dwutlenku węgla można określić pochodzenie CO2 nagromadzonego w miejskiej atmosferze. Kwasi-ciągłe pomiary stężenia i składu izotopowego węgla w atmosferycznym CO2 prowadzone w 2013 roku w Krakowie pozwoliły na dokonanie analizy ich zmienności sezonowej oraz synoptycznej. Źródłem obserwowanych zimą zwiększonych stężeń CO2 w atmosferze Krakowa było spalanie, w głównej mierze gazu ziemnego w celach grzewczych. Latem zaobserwowano wpływ suszy na stężenie CO2 w miejskiej atmosferze – z powodu obumierania lokalnej biosfery zmalała jej wydajność fotosyntetyczna, prowadząc do wyższych niż normalnie stężeń tego gazu w miesią - cach letnich. Przeprowadzono również dyskusję przyczyn krótkoterminowych wzrostów stężenia dwutlenku węgla, wykorzystując pomiary jego składu izotopowego oraz analizy trajektorii wstecznych mas powietrza. Zaprezentowane dwa przypadki ilustrują sytuacje, w których za chwilowy wzrost stężenia CO2 odpowiadają źródła przemysłowe oraz komunikacyjne.
    Stable isotopes constitute a powerful tool to study the sources of greenhouse gases, especially CO2. Carbon dioxide derived from the burning of fossil fuels has a distinct 13C isotopic composition depending on the type of fuel. Therefore, one can attribute contributions of different emission sources to the total CO2 load in the urban atmosphere. Quasi-continuous measurements of the mixing ratio of atmospheric CO2 and its 13C signature were performed in Krakow in 2013 to analyze its seasonal and synoptic variability. High CO2 mixing ratios were observed in winter due to intensified burning of fossil fuels for heating purposes (mostly methane). During the summer of 2013, a slight increase in atmospheric CO2 was observed following a drought event and a subsequent suppression of the photosynthetic activity of the local biosphere. A high temporal resolution of the measurements allowed to analyze short-term increases of the measured CO2 mixing ratios. Two such events are presented and discussed. Isotopic mass balance combined with air backward trajectory analysis allowed to attribute local traffic and industry as potential sources of these events.
    Źródło:
    Acta Geographica Lodziensia; 2016, 104; 113-122
    0065-1249
    Pojawia się w:
    Acta Geographica Lodziensia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Pochodzenie mineralnych wód chlorkowo-sodowych w rejonie Rzeszowa w świetle badań izotopowych(δ18O i δD, δ13C, δ37CL) i chemicznych
    Origin of saline waters in the vicinity of Rzeszów in light of isotope and (δ18O i δD, δ13C, δ3CL) hydrochemical studies
    Autorzy:
    Baran, A.
    Pelc, A.
    Chmiel, S.
    Hałas, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2074915.pdf
    Data publikacji:
    2012
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    saline waters
    Rzeszów region
    water derivation
    stable isotopes
    bicarbonate
    chlorine ion
    nitrates
    wody mineralne
    Rzeszów
    izotopy trwałe
    dwuwęglan
    jon chlorkowy
    azotany
    Opis:
    Several decades ago during exploration for additional resources of tap water a saline water deposit (Cl-Na, J, Fe, B type) has been discovered in the area of Rzeszów hospital park. Nowadays this water is exploited for balneological purposes. In the frame-work of this study for the first time the following stable isotopes: (δ18 i δD, δ13C, δ37Cl) and radiocarbon were determined in order to elucidate the origin of water, its mineralization and quality. Oxygen and hydrogen isotope data leads to conclusion that these waters were formed in a warm pre-Pleistocene period or they are mixture of Miocene seawater with Pleistocene infiltration waters. Carbon isotopic composition (b13= –8.65‰) of bicarbonate is characteristic for deep pore waters occurring in sedimentary rocks, whereas distinctly positive and negative δ37 Cl value rather excludes origin of chlorine ion from an open sea basin. Absence of radiocarbon (in Rzeszów well) indicates no admixture of recent infiltration waters, hence these waters are well preserved from anthropogenic pollution. This is further confirmed by very low concentration of nitrate.
    Źródło:
    Przegląd Geologiczny; 2012, 60, 12; 657--664
    0033-2151
    Pojawia się w:
    Przegląd Geologiczny
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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